JPS63235508A - Vinyl chloride glove and its production - Google Patents
Vinyl chloride glove and its productionInfo
- Publication number
- JPS63235508A JPS63235508A JP62069560A JP6956087A JPS63235508A JP S63235508 A JPS63235508 A JP S63235508A JP 62069560 A JP62069560 A JP 62069560A JP 6956087 A JP6956087 A JP 6956087A JP S63235508 A JPS63235508 A JP S63235508A
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- glove
- mold
- film
- glove body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 239000012756 surface treatment agent Substances 0.000 claims description 13
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000004925 Acrylic resin Substances 0.000 claims description 10
- 229920000178 Acrylic resin Polymers 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 229920000915 polyvinyl chloride Polymers 0.000 claims 1
- 239000004800 polyvinyl chloride Substances 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
- 239000000203 mixture Substances 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- -1 acrylic ester Chemical class 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Gloves (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は非粘着性を有する塩化ビニル及びそれを製造す
る方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to vinyl chloride having non-stick properties and a method for producing the same.
〈従来技術〉
従来此種の塩化ビニル手袋は、可塑剤が配合されている
関係から粘着性が大きく、製造型から離型する場合、ね
ばねばして離型しずらく、又、使用時においても、手に
密着して不快感を与え、手への脱着時もその粘着性のた
め容易に取り外しが出来ない等非常に使用しすらいもの
であった。<Prior art> Conventionally, this kind of vinyl chloride gloves have a high degree of stickiness due to the inclusion of plasticizers, and when released from the manufacturing mold, they are sticky and difficult to release, and even during use. It was very difficult to use, as it adhered closely to the hand, causing discomfort, and even when attached to and detached from the hand, it could not be easily removed due to its adhesiveness.
これを解消するものとして、粉末や塩化ビニルブレンド
レジンをコーティングしたり、微粒子を散布付着させた
りするものがあるが、粉末ではこれが使用時に剥れてし
まい、ブレンドレジンでは物性が変化して手を荒らす欠
点を有し、微粒子を散布したのでは、表（内）面が硬く
、凹凸によって見栄えがよくなく、使用時には、その微
粒子が異物感を与え不快なものであった。To solve this problem, there are coatings with powder or vinyl chloride blend resin, or spraying and adhering fine particles, but with powder, this peels off during use, and with blend resin, the physical properties change and it is difficult to handle. It has the disadvantage of causing roughness, and when fine particles are scattered, the front (inner) surface is hard and uneven, resulting in an unsightly appearance, and when used, the fine particles give an unpleasant feeling of being a foreign body.
又、製造型を塩化ビニル樹脂ゾルに浸漬し類型に付着し
たゾルをゲル化し、微粒子シリカを含有する合成樹脂エ
マルジョンに浸漬して成膜し、微粒子シリカを固定する
方法もある。しかし、これも基本的には前記微粒子を散
布したのと同じく表面に微粒子シリカが凹凸を形成して
いるため、これが剥れるものである。この場合は成膜中
に微粒子シリカが存在するため散布したもののように容
易に剥れるものではないけれども、エマルジョンの中に
無機物があるため、相溶性はなく、成膜がとれやすく、
シリカも脱落しやすいものであり、かつ、異物感のある
ものである。Another method is to immerse the production mold in a vinyl chloride resin sol to gel the sol adhering to the mold, and then immerse it in a synthetic resin emulsion containing fine silica particles to form a film and fix the fine silica particles. However, this also basically peels off because the fine silica particles form irregularities on the surface in the same way as when the fine particles were dispersed. In this case, since fine silica particles are present during the film formation, it does not come off as easily as with sprayed silica, but since there are inorganic substances in the emulsion, there is no compatibility and the film is easy to remove.
Silica also easily falls off and feels like a foreign body.
〈発明が解決しようとする問題点〉
本発明はこのような事情に鑑みてなされたもので、粘着
性が無く、物性も変化せず、異物感を与えない手袋を提
供せんとするものである。<Problems to be Solved by the Invention> The present invention has been made in view of the above circumstances, and aims to provide gloves that are not sticky, do not change physical properties, and do not give the feeling of being a foreign body. .
〈問題点を解決するための手段〉
本発明は前記問題点を解決するために、手袋製造型を塩
化ビニル樹脂溶液に浸漬して手袋本体を成膜した後、塩
化ビニル、アクリル樹脂、塩化ゴムを含有する表面処理
剤に再度浸漬して手袋本体と一体化せる皮膜を形成し、
反転離型することである。<Means for Solving the Problems> In order to solve the above-mentioned problems, the present invention provides a method for immersing a glove manufacturing mold in a vinyl chloride resin solution to form a film on the glove body, and then using vinyl chloride, acrylic resin, or chlorinated rubber. dipped again in a surface treatment agent containing
This is done by inverting and releasing the mold.
〈作用〉
上記手段によって、表面処理剤が手袋本体の粘着性を防
止する。<Function> By the above means, the surface treatment agent prevents the glove body from becoming sticky.
〈実施例〉
本発明の実施の一例を説明すると、手袋製造型は此種の
技術分野において周知の形態および構造のもの例えば陶
磁器又は金属で半型状に形成されたものであり、この製
造型を所定の型温調整した後、塩化ビニル樹脂溶液に１
回または２回浸漬して手袋本体となる塩化ビニルペース
トを附着させ、引き上げてセミキュアー、冷却して型面
に一層又は二層必要によっては数層を成膜し、然る後、
これを表面処理剤に再度浸漬する。<Example> To explain an example of the implementation of the present invention, the glove manufacturing mold has a shape and structure well known in this type of technical field, for example, is formed into a half mold shape from ceramic or metal. After adjusting the mold temperature to the specified temperature, add 1 to the vinyl chloride resin solution.
Dip it once or twice to deposit the vinyl chloride paste that will become the glove body, pull it out to semi-cure, cool it and deposit one or two layers on the mold surface, and if necessary, several layers.
This is dipped in the surface treatment agent again.
塩化ビニル樹脂溶液は塩化ビニルベーストレジンに可塑
剤、安定剤、ゲル化剤、顔料など通常用いられている各
種の添加剤を配合してなる周知の塩化ビニルペーストで
あり、この中に場合によってはストレートレンジを配合
することもあり、このような粘度４０００〜１０，００
０ＣｐＳとした塩化ビニルペーストを手袋製造型に附着
させてセミキュアー、冷却して手袋本体となる一層もし
くは二層よりなる薄゛ＷＡ層を形成し、この成膜の表面
に、表面処理剤を施す。Vinyl chloride resin solution is a well-known vinyl chloride paste made by blending a vinyl chloride base resin with various commonly used additives such as plasticizers, stabilizers, gelling agents, and pigments. Straight range may be blended, such viscosity 4000~10,00
A vinyl chloride paste of 0 CpS is applied to a glove manufacturing mold, semi-cured, and cooled to form a thin WA layer consisting of one or two layers that will become the glove body, and a surface treatment agent is applied to the surface of this film.
表面処理剤は、塩化ビニル、アクリル樹脂、塩化ゴムを
含有する粘度が１０〜１００ＣｐＳの溶剤タイプ又は粘
度が２０〜２００ｃｐｓのエマルジョンタイプのもので
あって、この表面処理剤に前記成膜層を有する手袋製造
型を再度浸漬して表面処理を施し、引き上げ、予備乾燥
、キュアー、冷却を順次行って表面処理皮膜を設け、反
転離型により手袋本体の内面に表面処理皮膜層を形成す
る。この表面処理剤における塩化ビニルは手袋本体との
相溶性から、塩化ビニルペーストのレジンの重合度を考
慮して、その重合度を選択するものであるが、一般的に
は重合度（Ｐ）は１０００位がよい。アクリル樹脂及び
塩化ゴムは手袋本体中の可塑剤の移行を防止するため分
子量は大きいものがよく、ｓ、ｏｏｏ〜１００、０００
のものを用いる。The surface treatment agent is a solvent type with a viscosity of 10 to 100 Cps or an emulsion type with a viscosity of 20 to 200 Cps containing vinyl chloride, acrylic resin, and chlorinated rubber, and the surface treatment agent has the film forming layer. The glove manufacturing mold is immersed again to perform a surface treatment, then pulled up, pre-dried, cured, and cooled in order to form a surface treatment film, and then reverse mold release to form a surface treatment film layer on the inner surface of the glove body. The degree of polymerization of vinyl chloride in this surface treatment agent is selected in consideration of the degree of polymerization of the resin in the vinyl chloride paste in view of its compatibility with the glove body, but generally the degree of polymerization (P) is 1000th place is better. The acrylic resin and chlorinated rubber preferably have a large molecular weight in order to prevent the plasticizer from migrating into the glove body, and range from s,ooo to 100,000.
Use the one.
次に具体的な実施態様について説明すると、下記配合（
イ）による液温３５℃の塩化ビニルペーストに、型温５
０℃に調整された手袋製造型を浸漬し、引き上げた後１
７０℃４分セミキュアーし、型温まで冷却する。Next, to explain a specific embodiment, the following formulation (
B) to the vinyl chloride paste with a liquid temperature of 35℃, mold temperature 5℃
After dipping the glove manufacturing mold adjusted to 0°C and pulling it up, 1
Semi-cure at 70°C for 4 minutes and cool to mold temperature.
一配合（イ）−
塩化ビニルベーストレジン（１５＝ １６５０） １０
０ＰＨＲ可塑剤（フタル酸、ポリエステル） １０
０ＰＨＲ安定剤（Ｃａ−Ｂａ−Ｚｎ ）
４ＰＨＲゲル化剤（Ｃａ／Ｓｉ ）
４ＰＨＲ顔料
ＩＰＨＲ次いで下記配合（ロ）の溶剤タイプ及
び配合（ハ）のエマルジョンタイプの表面処理剤（液温
２５℃）に別々に浸漬し、引き上げ後、６０〜１４０℃
２分子備乾燥、２２０℃８分キュアーして型温７０℃ま
で冷却後、反転離型し、二つの塩化ビニル手袋を得た。One combination (a) - vinyl chloride based resin (15=1650) 10
0PHR plasticizer (phthalic acid, polyester) 10
0PHR stabilizer (Ca-Ba-Zn)
4PHR gelling agent (Ca/Si)
4PHR pigment
IPHR, then separately immersed in a solvent type surface treatment agent of the following formulation (B) and an emulsion type surface treatment agent of the formulation (C) (liquid temperature 25℃), and after lifting, 60 to 140℃
After drying the two molecules and curing them at 220°C for 8 minutes and cooling them to a mold temperature of 70°C, the molds were inverted and released to obtain two vinyl chloride gloves.
いずれも粘着性がなく、離型及び手の脱着が容易であっ
た。All of them had no stickiness and were easy to release from the mold and to attach and remove by hand.
一配合（ロ）−
塩化酸ビニル ９ｐＨＲアクリ
ル酸エステル ６〃塩化ゴム
７，５／／トルエン
４２．５Ｍ Ｅ Ｋ
４２．５キシレン
ｉｏ。One formulation (b) - Vinyl chloride 9 pHR acrylic ester 6 Chlorinated rubber
7,5//Toluene
42.5M EK
42.5 xylene
io.
（固型分１０．８％）
一配合（ハ）−
塩化ビニル ９ Ｐ ＨＲ
アクリル酸エステル ６塩化ゴム
７．５分散剤
１安定剤
１界面活性剤
１（固型分１８％）
〈効果〉
本発明は手袋製造型を塩化ビニル樹脂溶液に浸漬して手
袋本体を成膜した後、塩化ビニル、アクリル樹脂、塩化
ゴムを含有する表面処理剤に再度浸漬して手袋本体と一
体化せる皮膜を形成し反転離型することによって、手袋
本体の内面に塩化ゴムを含有し、かつその手袋本体と一
体化した皮膜を設けた塩化ビニル手袋を提供し得るもの
であり、この表面処理剤による皮膜における塩化ビニル
とアクリル樹脂が手袋本体との接着性を上げるバインダ
ー的要素となり、該皮膜が剥れることがなく、分子間の
大きい塩化ゴムが塩化ビニルと相溶性を有しないため、
粒子の役割を果し、表面が微凹凸となると共に、この塩
化ゴムは有機物であるためアクリル樹脂や手袋本体に含
まれている可塑剤と相溶性があるため、従来の微粒子を
散布したり、無機物の微粒子シリカを含有するエマルジ
ョンに浸漬して該シリカを固定したものとは基本的に異
なり、脱落したり、剥れたりすることが全くない。(Solid content 10.8%) One combination (c) - Vinyl chloride 9 P HR
Acrylic ester hexachloride rubber
7.5 Dispersant
1 stabilizer
1 surfactant
1 (Solid content: 18%) <Effects> The present invention involves dipping a glove manufacturing mold in a vinyl chloride resin solution to form a film on the glove body, and then dipping it in a surface treatment agent containing vinyl chloride, acrylic resin, and chlorinated rubber again. By dipping to form a film that is integrated with the glove body and then inverting and releasing it, it is possible to provide a vinyl chloride glove that contains chlorinated rubber on the inner surface of the glove body and has a film that is integrated with the glove body. The vinyl chloride and acrylic resin in the film created by this surface treatment agent act as binder elements that increase the adhesion to the glove body, preventing the film from peeling off and allowing the large chloride rubber molecules to interact with the vinyl chloride. Because it has no solubility,
It plays the role of particles and has a slightly uneven surface, and since this chlorinated rubber is an organic substance, it is compatible with acrylic resin and the plasticizer contained in the glove body, so it can be used instead of spraying conventional fine particles. This is fundamentally different from the case where the silica is fixed by immersing it in an emulsion containing fine inorganic silica particles, and does not fall off or peel off at all.
しかも、物性の低下、風合の低下、硬化もなく、耐薬品
性は上昇し、非粘着性でありながら異物感が無く、使用
感の良好な滑性を有する手袋を提供することが出来るも
のである。Furthermore, it is possible to provide gloves that have improved chemical resistance without deterioration in physical properties, deterioration in texture, or hardening, and have non-adhesion, no foreign body feeling, and smoothness that provides a good feeling of use. It is.
特許出願人 オカモト株式会社手続補正書
昭和６２年 ５月 ８日
塩化ビニル手袋及びその製造方法
氏名（名称’） （０５５）オカモト株式会
社昭和 年 月 日
（２）明１１ｉ１”の発明の詳細な説明の欄補 正
書
本願明１１１書中を下記の通り補止します。Patent Applicant Okamoto Co., Ltd. Procedural Amendment May 8, 1986 Vinyl chloride gloves and method for manufacturing the same Name (Name') (055) Detailed description of the invention of Okamoto Co., Ltd. Amendment to the column The following amendments have been made to the main application form 111.
（１）特許請求の範囲を別紙の通り補正しまず。(1) First, amend the claims as shown in the attached sheet.
（２）第１頁第１６行目の「塩化ビニル及び」を「塩化
ビニル手袋及び」と補正します。(2) "Vinyl chloride and" on page 1, line 16 will be corrected to "vinyl chloride gloves and".
（３）第４頁第５行目の「型温調整」を「温度に調整」
と補正します。(3) "Mold temperature adjustment" on page 4, line 5, "adjust to temperature"
I will correct it.
（４）第６頁第３行目の「フタル酸Ｊを「フタル酸ニス
デル」と補正しまり。(4) Page 6, line 3, ``Phthalic acid J is corrected to ``Nisdel phthalate.''
（５）同頁第４行目の「４ｐＨＲＪを「２ＰＨＲＪど補
正します。(5) Correct "4pHRJ" on the 4th line of the same page to "2PHRJ."
（６）同頁第４行目の［塩化酸ビニル］を「塩化ビニル
」と補正します。(6) Correct [vinyl chloride] in the fourth line of the same page to "vinyl chloride."
（７）第７頁第２行目及び第１１行目の「固型分」を「
固形分」と夫々補正します。(7) “Solid content” on page 7, line 2 and line 11 is changed to “
Corrected as "solid content" respectively.
特許出願人 オカモト株式会社 特許請求の範囲 （１）手袋本体の内面に塩化ビニル、アクリル樹脂。Patent applicant: Okamoto Co., Ltd. Scope of claims (1) Vinyl chloride and acrylic resin on the inside of the glove body.
塩化ゴムを含有する被膜を設けた塩化ビニル手袋。Vinyl chloride gloves with a coating containing chlorinated rubber.
（２）手袋製造型を塩化ビニル樹脂Ｗ３：／＆に浸漬し
て手袋本体を成膜した後、塩化ビニル、アクリル樹脂、
塩化ゴムを含有する表面処理剤に再度浸漬して手袋本体
と一体化せる被膜を形成し、反転離型すことを特徴とす
る塩化ビニル手袋の製造方法。(2) After forming the glove body by immersing the glove manufacturing mold in vinyl chloride resin W3:/&, vinyl chloride, acrylic resin,
A method for manufacturing vinyl chloride gloves, which comprises dipping them again in a surface treatment agent containing chlorinated rubber to form a film that can be integrated with the glove body, and then inverting and releasing the mold.
Claims (2)
化ゴムを含有する皮膜を設けた塩化ビニル手袋。(1) Vinyl chloride gloves with a film containing vinyl chloride, acrylic resin, and chlorinated rubber on the inner surface of the glove body.
本体を成膜した後、塩化ビニル、アクリル樹脂、塩化ゴ
ムを含有する表面処理剤に再度浸漬して手袋本体と一体
化せる皮膜を形成し、反転離型することを特徴とする塩
化ビニル手袋の製造方法。(2) After forming a film on the glove body by immersing the glove manufacturing mold in a vinyl chloride resin solution, the film is integrated with the glove body by dipping it again in a surface treatment agent containing vinyl chloride, acrylic resin, and chlorinated rubber. 1. A method for manufacturing vinyl chloride gloves, characterized by forming a polyvinyl chloride glove and then inverting and releasing the mold.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62069560A JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62069560A JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63235508A true JPS63235508A (en) | 1988-09-30 |
| JPH0380884B2 JPH0380884B2 (en) | 1991-12-26 |
Family
ID=13406259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62069560A Granted JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63235508A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02229205A (en) * | 1989-03-01 | 1990-09-12 | Chiyoda Kasei Kogyo Kk | Vinyl chloride gloves |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS532468A (en) * | 1976-06-15 | 1978-01-11 | Otsuka Chem Co Ltd | 2,2-bis(3,4-epoxy-5-oxotetrahydropyrane)-ethers and method of preparing the same |
-
1987
- 1987-03-23 JP JP62069560A patent/JPS63235508A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS532468A (en) * | 1976-06-15 | 1978-01-11 | Otsuka Chem Co Ltd | 2,2-bis(3,4-epoxy-5-oxotetrahydropyrane)-ethers and method of preparing the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02229205A (en) * | 1989-03-01 | 1990-09-12 | Chiyoda Kasei Kogyo Kk | Vinyl chloride gloves |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0380884B2 (en) | 1991-12-26 |
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