JPH0219203B2 - - Google Patents
Info
- Publication number
- JPH0219203B2 JPH0219203B2 JP22273183A JP22273183A JPH0219203B2 JP H0219203 B2 JPH0219203 B2 JP H0219203B2 JP 22273183 A JP22273183 A JP 22273183A JP 22273183 A JP22273183 A JP 22273183A JP H0219203 B2 JPH0219203 B2 JP H0219203B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- chloride resin
- gloves
- mold
- sol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 22
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 229920003002 synthetic resin Polymers 0.000 claims description 12
- 239000000057 synthetic resin Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 10
- 239000000377 silicon dioxide Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000010419 fine particle Substances 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 description 8
- 239000010408 film Substances 0.000 description 7
- 239000000428 dust Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000010409 thin film Substances 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 239000011163 secondary particle Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
Landscapes
- Gloves (AREA)
Description
【発明の詳細な説明】
この発明は着脱が容易で塵が発生しない塩化ビ
ニル樹脂製手袋の製造方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing vinyl chloride resin gloves that are easy to put on and take off and do not generate dust.
ゴム製手袋や塩化ビニル樹脂製手袋は主として
炊事用、洗濯用等の家庭用手袋として使用されて
いるが、近時、精密工業に於ける作業用手袋とし
ても使用される様になつたのである。塩化ビニル
樹脂製手袋は柔軟性を与えるために可塑剤が多量
に使用されており、その侭では表面の粘着性が強
く滑りが悪くて、手型からの離型が困難であり、
使用時の着脱性が極めて劣り、非常に使いにくい
ので、内面にパイルを植毛したり、炭酸カルシウ
ム、炭酸マグネシウム、雲母粉末等の主として無
機物微粉末を打粉しているが、これを最近使用が
増加した集積回路工場やバイオテクノロジー関連
工場のクリーンルーム内で作業用手袋として使用
する場合には、植毛した繊維や打粉した粉末が塵
発生の原因となるため使用が不適当であり、塵発
生のない手袋が要望されているのである。 Rubber gloves and vinyl chloride resin gloves are mainly used as household gloves for cooking, laundry, etc., but recently they have also come to be used as work gloves in the precision industry. . PVC resin gloves use a large amount of plasticizer to give them flexibility, and as a result, the surface is sticky and slippery, making it difficult to release from the hand mold.
Since it is extremely difficult to put on and take off during use, the inner surface is flocked with pile, or powdered with mainly inorganic fine powder such as calcium carbonate, magnesium carbonate, mica powder, etc., but the use of this has increased recently. When used as work gloves in the clean room of an integrated circuit factory or a biotechnology-related factory, it is inappropriate to use them because flocked fibers and powdered powder can cause dust, so gloves that do not generate dust are unsuitable. is being requested.
この発明は従来使用されたゴム製手袋や塩化ビ
ニル製手袋に於ける上述の要望に答えるために離
型性が良く、手への着脱が容易に出来、而も、塵
の発生が無い、塩化ビニル樹脂製手袋が製造出来
る方法を得ることを目的とするものである。 In order to meet the above-mentioned needs for the conventionally used rubber gloves and vinyl chloride gloves, this invention has good mold release properties, can be easily put on and taken off the hands, and does not generate dust. The purpose of this invention is to obtain a method for manufacturing vinyl resin gloves.
この発明の方法は、金属製又は陶磁器製の手型
を、塩化ビニルペーストレンジンに、通常用いら
れる可塑剤、安定剤、顔料、必要に応じてゲル化
剤、稀釈剤、充填剤等を添加混練して得られる塩
化ビニル樹脂ゾルに浸漬して、手型に塩化ビニル
樹脂ゾルの薄膜層を付着させて引き揚げ、外周に
塩化ビニル樹脂ゾルの薄膜層が付着した手型を加
熱して付着した塩化ビニル樹脂ゾルの薄膜層をゲ
ル化させ、次いで、塩化ビニル樹脂、塩化ビニリ
デン樹脂、（メタ）アクリル酸エステル樹脂、塩
化ビニル―（メタ）アクリル酸エステル共重合
体、塩化ビニル―塩化ビニリデン共重合体、塩化
ビニリデン―（メタ）アクリル酸エステル共重合
体等から選んだ単独又は二種以上の混合物の適宜
濃度の水分散体に、必要な場合には通常用いられ
る界面活性剤、増粘剤、消泡剤等を添加し、一次
粒径が５−50mμで、二次粒径が１−10μの乾式法
或は湿式法で得られる非晶質微粒子シリカを手袋
皮膜の滑り効果が充分に得られ、かつ、エマルジ
ヨン系の安定性を損なわず、また加熱時皮膜に亀
裂を生じたり、或は得られた手袋の風合を悪くし
たりすることのない、均一な厚みの合成樹脂薄膜
層を得るに必要な粘度を保つ量、即ち、0.1〜８
重量％を均一に分散含有させた、合成樹脂エマル
ジヨン中に浸漬して、手型外周に付着するゲル化
した塩化ビニル樹脂薄膜層の外側に微粒子シリカ
を含む合成樹脂エマルジヨンの薄膜層を付着さ
せ、再度加熱して、塩化ビニル樹脂を溶融させる
と同時に外側に付着した合成樹脂エマルジヨンを
成膜させ、塩化ビニル樹脂層と一体化して、手袋
皮膜を構成し、含有する微粒子シリカを合成樹脂
薄膜層の内部に固定すると共に内部に固定した微
粒子シリカに依つて多数の微小凹凸を表面に形成
させ型離れを良くし、使用時の着脱が容易に出来
る様にし、而も、塵となつて飛散する付着物の無
い手袋が製造出来る様にしたものである。 The method of this invention involves kneading a metal or ceramic hand mold into vinyl chloride paste resin by adding commonly used plasticizers, stabilizers, pigments, and if necessary gelling agents, diluents, fillers, etc. The hand mold is immersed in the resulting vinyl chloride resin sol, a thin film layer of vinyl chloride resin sol is attached to the hand mold, and the hand mold is pulled up. A thin film layer of vinyl resin sol is gelled, and then vinyl chloride resin, vinylidene chloride resin, (meth)acrylic acid ester resin, vinyl chloride-(meth)acrylic acid ester copolymer, vinyl chloride-vinylidene chloride copolymer , vinylidene chloride-(meth)acrylic acid ester copolymer, etc., or a mixture of two or more of them at an appropriate concentration, and if necessary, commonly used surfactants, thickeners, and erasers. Amorphous fine particle silica obtained by a dry method or a wet method with a primary particle size of 5-50 μm and a secondary particle size of 1-10 μm by adding a foaming agent etc. can be used to obtain a sufficient slipping effect of the glove film. , and obtain a synthetic resin thin film layer of uniform thickness without impairing the stability of the emulsion system, causing cracks in the film during heating, or deteriorating the feel of the gloves obtained. The amount to maintain the necessary viscosity, i.e. 0.1 to 8
A thin film layer of a synthetic resin emulsion containing particulate silica is attached to the outside of a gelled vinyl chloride resin thin film layer attached to the outer periphery of the hand mold by immersing it in a synthetic resin emulsion containing a uniformly dispersed amount of silica, By heating again, the vinyl chloride resin is melted and at the same time the synthetic resin emulsion adhering to the outside is formed into a film, which is integrated with the vinyl chloride resin layer to form the glove film, and the contained fine silica is transferred to the synthetic resin thin film layer. The particulate silica fixed inside the interior forms a large number of minute irregularities on the surface, which improves mold release and makes it easy to attach and detach during use. This made it possible to manufacture gloves without a kimono.
この発明の方法を実施して手袋を作つた場合の
実施例を以下に記述する。 Examples of gloves made by implementing the method of this invention will be described below.
塩化ビニルペーストレジン ゼオン121
100重量部
可塑剤 DOP 100重量部
安定剤 Ba／zn複合 ３重量部
顔 料 １重量部
を配合して得られるゾル中に磁器製手型を浸漬し
てゾルが滴下しない程度の速さで引き揚げ、雰囲
気温度250℃の加熱炉に入れて回転しながら１分
間加熱して、ゾル状塩化ビニル樹脂をゲル化させ
これを超微粒子シリカ２重量％含有する合成樹脂
エマルジヨン、（塩化ビニル、エチルアクリレー
ト共重合体の水分散体固型分濃度７重量％、粘度
450センチポイズ）中に浸漬して、手型の外周に
付着している塩化ビニル樹脂層の外周に合成樹脂
エマルジヨン層を付着させ、手型を引き揚げて雰
囲気温度180℃の加熱炉内で７分間加熱し、冷却
後手型から反転離型させて、塩化ビニル樹脂製手
袋を得たものである。 Vinyl chloride paste resin Zeon 121
100 parts by weight Plasticizer DOP 100 parts by weight Stabilizer Ba/zn composite 3 parts by weight A porcelain hand mold is immersed in the sol obtained by blending 1 part by weight with the sol and pulled up at a speed that prevents the sol from dripping. The sol-form vinyl chloride resin was heated for 1 minute while rotating in a heating furnace at an ambient temperature of 250°C, and this was converted into a synthetic resin emulsion containing 2% by weight of ultrafine particle silica (both vinyl chloride and ethyl acrylate). Polymer aqueous dispersion solid content concentration 7% by weight, viscosity
450 centipoise) to adhere a synthetic resin emulsion layer to the outer periphery of the vinyl chloride resin layer that adheres to the outer periphery of the hand mold, then lift the hand mold and heat it in a heating furnace at an ambient temperature of 180°C for 7 minutes. After cooling, the gloves were inverted and released from the mold to obtain vinyl chloride resin gloves.
この実施例に於て得られた手袋は、手型から離
脱させる作業が容易に出来、手への着脱が容易で
塵が発散しないものであつた。 The gloves obtained in this example were easy to remove from the hand mold, easy to put on and take off from the hand, and did not generate dust.
この発明の手袋の製造方法は上述の様に手型の
外周に付着させた塩化ビニル樹脂ゾルを加熱して
ゲル化し、その外側に微粒子シリカを0.1〜８重
量％含有させた合成樹脂エマルジヨン層を付着さ
せ再度加熱して、塩化ビニル樹脂層を溶融させる
と同時に合成樹脂エマルジヨンを成膜化させ、両
者を一体化して手袋皮膜を構成させ、含有する微
粒子シリカを合成樹脂膜層の内部に固定させて、
多数の微小凹凸を表面に形成させ反転離型して、
手型に付着した表面を内面にして使用するもので
あるから、この方法で作られた手袋は内面の微小
凹凸で滑りが良く、離型性及び使用時の着脱が容
易で使い勝手が良く、使用中に飛散する付着物が
ないので、塵が発生しない等の効果があるのであ
る。 As described above, the method for manufacturing gloves of the present invention involves heating and gelling the vinyl chloride resin sol attached to the outer periphery of the hand mold, and then applying a synthetic resin emulsion layer containing 0.1 to 8% by weight of finely divided silica on the outside of the vinyl chloride resin sol. The polyvinyl chloride resin layer is melted and the synthetic resin emulsion is formed into a film by attaching and heating again, and the two are integrated to form a glove film, and the fine particle silica contained is fixed inside the synthetic resin film layer. hand,
A large number of minute irregularities are formed on the surface and the mold is inverted and released.
Since the surface adhered to the hand mold is used as the inner surface, the gloves made using this method have minute irregularities on the inner surface, making them slippery, easy to release from the mold, and easy to put on and take off during use, making them easy to use. Since there are no deposits scattered inside, there are effects such as no dust generation.
Claims (1)
ルに浸漬し、引き揚げて後、加熱して、手型に付
着した塩化ビニル樹脂ゾルをゲル化し、これを均
一に分散した微粒子シリカを0.1〜８重量％含有
する合成樹脂エマルジヨンに浸漬して、ゲル化塩
化ビニル樹脂層の外周に付着させ、再度加熱し
て、塩化ビニル樹脂を溶融させると同時に、外側
に付着する合成樹脂エマルジヨンを成膜させて、
塩化ビニル樹脂層と一体化させると共に含有する
微粒子シリカを固定し、冷却後反転脱型すること
を特徴とする、着脱の容易な無塵手袋の製造方
法。1 A metal or ceramic hand mold is immersed in a vinyl chloride resin sol, pulled up, heated, and the vinyl chloride resin sol attached to the hand mold is gelled, and this is uniformly dispersed with fine particle silica of 0.1-8 % by weight of the synthetic resin emulsion to adhere to the outer periphery of the gelled vinyl chloride resin layer, and heat it again to melt the vinyl chloride resin and at the same time form a synthetic resin emulsion that adheres to the outside. ,
A method for producing dust-free gloves that are easy to put on and take off, characterized by integrating them with a vinyl chloride resin layer, fixing the fine particle silica contained therein, and then inverting and removing the mold after cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58222731A JPS60119204A (en) | 1983-11-25 | 1983-11-25 | Production of easily detachable dustless glove |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58222731A JPS60119204A (en) | 1983-11-25 | 1983-11-25 | Production of easily detachable dustless glove |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60119204A JPS60119204A (en) | 1985-06-26 |
| JPH0219203B2 true JPH0219203B2 (en) | 1990-05-01 |
Family
ID=16787012
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58222731A Granted JPS60119204A (en) | 1983-11-25 | 1983-11-25 | Production of easily detachable dustless glove |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60119204A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6285002A (en) * | 1985-10-03 | 1987-04-18 | エステ−化学株式会社 | Production of glove made of vinyl chloride |
| JPH02229205A (en) * | 1989-03-01 | 1990-09-12 | Chiyoda Kasei Kogyo Kk | Vinyl chloride gloves |
| JP2747117B2 (en) * | 1991-01-18 | 1998-05-06 | 株式会社東和コーポレーション | Glove manufacturing method and gloves |
| JP2006233350A (en) * | 2005-02-23 | 2006-09-07 | Seikoh Chem Co Ltd | Method for producing glove made of vinyl chloride resin |
| JP3198512U (en) * | 2015-03-09 | 2015-07-09 | 日本コルマー株式会社 | Beauty work gloves |
-
1983
- 1983-11-25 JP JP58222731A patent/JPS60119204A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS60119204A (en) | 1985-06-26 |
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