JPH0327642B2 - - Google Patents
Info
- Publication number
- JPH0327642B2 JPH0327642B2 JP24047586A JP24047586A JPH0327642B2 JP H0327642 B2 JPH0327642 B2 JP H0327642B2 JP 24047586 A JP24047586 A JP 24047586A JP 24047586 A JP24047586 A JP 24047586A JP H0327642 B2 JPH0327642 B2 JP H0327642B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- resin
- chloride resin
- thin film
- mixed emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011347 resin Substances 0.000 claims description 49
- 229920005989 resin Polymers 0.000 claims description 49
- 239000000839 emulsion Substances 0.000 claims description 35
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 33
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 5
- 239000000919 ceramic Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 36
- 239000010409 thin film Substances 0.000 description 24
- 239000007788 liquid Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000000428 dust Substances 0.000 description 7
- 229920003002 synthetic resin Polymers 0.000 description 7
- 239000000057 synthetic resin Substances 0.000 description 7
- 230000001070 adhesive effect Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- -1 acrylic ester Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000012791 sliding layer Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/04—Appliances for making gloves; Measuring devices for glove-making
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D99/00—Subject matter not provided for in other groups of this subclass
- B29D99/0064—Producing wearing apparel
- B29D99/0067—Gloves
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
- A41D19/0058—Three-dimensional gloves
- A41D19/0062—Three-dimensional gloves made of one layer of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
Description
【発明の詳細な説明】
産業上の利用分野
本発明は無塵手袋の製造方法に関するものであ
る。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for manufacturing dust-free gloves.
従来の技術
塩化ビニル樹脂製の手袋は従来から炊事用、洗
濯用などの家庭用手袋で知られているが、最近に
なつて精密工業における作業用手袋が知られるよ
うになつている。PRIOR ART Gloves made of vinyl chloride resin have long been known as household gloves for cooking, laundry, etc., but recently they have become known as work gloves in the precision industry.
塩化ビニル樹脂製の手袋は柔軟性を与えるため
に可塑剤が多量に使用されており、そのため表面
の粘着性が強く滑りが悪くて製造時において手型
から反転離型させるときに手袋の表面が密着し合
うなどして手型からの離型が困難であり、また使
用時における手に対する着脱性も極めて悪く、非
常に使いにくい。そこで、手袋の内面にバイルを
植毛したり、炭酸カルシウム、炭酸マグネシウ
ム、雲母粉末などの粉末を打粉しているが、集積
回路工場やバイオテクノロジー関連工場のクリー
ンルーム内で作業用手袋として使用する場合には
植毛した繊維や打粉した粉末が塵発生の原因とな
り、使用には適さない。 Gloves made of vinyl chloride resin contain a large amount of plasticizer to give them flexibility, and as a result, the surface of the gloves is highly sticky and does not slip easily. It is difficult to release the mold from the hand mold because they stick together, and the ease of attaching and removing the mold from the hand during use is also extremely poor, making it extremely difficult to use. Therefore, the inner surface of the gloves is flocked with vile or powdered with calcium carbonate, magnesium carbonate, mica powder, etc., but when used as work gloves in the clean rooms of integrated circuit factories and biotechnology-related factories. is not suitable for use because the flocked fibers and powdered powder cause dust.
そのために、クリーンルーム内で使用する作業
用手袋として塵発生がなく着脱容易な手袋が要望
され、特開昭60−119204号公報で示される手袋が
提案されている。同公報に示される無塵手袋の製
造方法は、金属製または陶磁器製手型を塩化ビニ
ル樹脂ゾルに浸漬し、引き揚げて後、加熱して、
手型に付着した塩化ビニル樹脂ゾルをゲル化し、
これを均一に分散した微粒化シリカを0.1〜８重
量％含有する合成樹脂エマルジヨンに浸漬して、
ゲル化塩化ビニル樹脂層の外周に付着させ、再度
加熱して、塩化ビニル樹脂を溶融させると同時
に、外側に付着する合成樹脂エマルジヨンを成膜
させて、塩化ビニル樹脂層と一体化させると共に
含有する微粒子シリカを固定し、冷却後反転脱型
して無塵手袋を製造する方法である。 For this reason, there is a demand for work gloves for use in clean rooms that do not generate dust and are easy to put on and take off, and a glove disclosed in Japanese Patent Application Laid-open No. 119204/1983 has been proposed. The method for manufacturing dust-free gloves disclosed in the publication involves immersing a metal or ceramic hand mold in vinyl chloride resin sol, pulling it up, and heating it.
The vinyl chloride resin sol attached to the hand mold is turned into a gel,
This is immersed in a synthetic resin emulsion containing 0.1 to 8% by weight of finely divided silica that is uniformly dispersed.
It is attached to the outer periphery of the gelled vinyl chloride resin layer and heated again to melt the vinyl chloride resin, and at the same time, a synthetic resin emulsion that adheres to the outside is formed into a film to be integrated with the vinyl chloride resin layer and to contain it. This is a method of manufacturing dust-free gloves by fixing fine silica particles, cooling, and then inverting and removing the mold.
発明が解決しようとする問題点
上記特開昭60−119204号公報で示される製造方
法において、微細なシリカを使用してもそれを一
次粒径で分散させることは不可能で、実際は二次
粒径のミクロン単位（１〜5μ）で分散されるこ
とになる。従つて、塩化ビニル樹脂層上に極く薄
くシリカ分散合成樹脂層を形成すると、シリカ粒
子が合成樹脂層上に突出することになり、長時間
使用しているとシリカの突起部がこすり取られて
塵の発生の原因となるという問題があつた。Problems to be Solved by the Invention In the manufacturing method shown in the above-mentioned Japanese Patent Application Laid-open No. 60-119204, even if fine silica is used, it is impossible to disperse it with a primary particle size, and in reality, it is impossible to disperse it with a primary particle size. It will be dispersed in micron units (1 to 5 μ) in diameter. Therefore, if an extremely thin silica-dispersed synthetic resin layer is formed on a vinyl chloride resin layer, the silica particles will protrude onto the synthetic resin layer, and if used for a long time, the silica protrusions will be scraped off. There was a problem that it caused dust to be generated.
本発明はこのような問題点を解決するもので、
製造時において手型から離型し易く、しかも手に
対する着脱が容で、塵が生しない手袋が得られる
ようにすることを目的とするものである。 The present invention solves these problems,
The object of the present invention is to provide a glove that is easy to release from the hand mold during manufacturing, is easy to put on and take off from the hand, and does not generate dust.
問題点を解決するための手段
この問題点を解決するために本発明は、金属製
または陶磁器製手型を塩化ビニル樹脂ゾルに浸漬
し、引き揚げて後、加熱して手型に付着した塩化
ビニル樹脂ゾルをゲル化し、これを塩化ビニル樹
脂に対して接着性のある合成樹脂エマルジヨンに
メタメチルアクリレート樹脂などの硬度の高い樹
脂をエマルジヨンの状態で混合した混合エマルジ
ヨン液に浸漬してゲル化塩化ビニル樹脂層の外面
に混合エマルジヨン液を付着させ、引き上げて
後、再度加熱して塩化ビニル樹脂を溶融させると
同時に外面に付着する混合エマルジヨンを成膜さ
せて、塩化ビニル樹脂層の外側に一体の滑性を有
する層を形成し、冷却後反転離型するものであ
る。Means for Solving the Problem In order to solve this problem, the present invention immerses a metal or ceramic hand mold in a vinyl chloride resin sol, pulls it up, heats it, and removes the vinyl chloride attached to the hand mold. The resin sol is gelled, and this is immersed in a mixed emulsion solution, which is a mixture of a synthetic resin emulsion that has adhesive properties to vinyl chloride resin and a resin with high hardness such as methmethyl acrylate resin in an emulsion state. The mixed emulsion liquid is applied to the outer surface of the resin layer, and after being pulled up, it is heated again to melt the vinyl chloride resin. At the same time, the mixed emulsion liquid that adheres to the outer surface is formed into a film, and an integral sliding layer is formed on the outer surface of the vinyl chloride resin layer. After cooling, the layer is inverted and released from the mold.
作 用
この構成により、作られた手袋の内面は硬度の
高い樹脂を含有する混合エマルジヨン液を材料と
して形成された滑性を有する層が位置しており、
使用時の着脱が容易で使い勝手が良く、使用中に
飛散する付着物がないので塵の発生もない。しか
も手袋を手型から反転離型させるとき、前記混合
エマルジヨン液を材料とする滑性を有する層が表
側に位置しているので表面が密着し合うようなこ
となく、手型から離型し易い。Effect With this configuration, the inner surface of the glove made is coated with a slippery layer formed from a mixed emulsion liquid containing a highly hard resin.
It is easy to put on and take off during use, making it convenient to use, and since there are no deposits that fly off during use, there is no generation of dust. Moreover, when the glove is inverted and released from the hand mold, the slippery layer made of the mixed emulsion liquid is located on the front side, so the surfaces do not come into close contact with each other and are easily released from the hand mold. .
実施例 以下、本発明の一実施例について説明する。Example An embodiment of the present invention will be described below.
まず、金属製または陶磁器製の手型を、塩化ビ
ニルペーストレジンに通常用いられる可塑剤、安
定剤、顔料、必要に応じてゲル化剤、稀釈剤、充
填剤などを添加混練して得られる塩化ビニル樹脂
ゾルに浸漬して、手型に塩化ビニル樹脂ゾルの薄
膜層を付着させて引き上げ、外面に塩化ビニル樹
脂ゾルの薄膜層が付着した手型を約250℃の加熱
炉内で回転させ乍ら１分間加熱して前記薄膜層を
ゲル化させる。次に塩化ビニル樹脂に対して接着
性のある塩化ビニル樹脂、アクリル酸エステル樹
脂、塩化ビニル樹脂−アクリル酸エステル共重合
樹脂などの合成樹脂エマルジヨンにメタメチルア
クリレート樹脂などの硬度の高い樹脂をエマルジ
ヨンの状態で混合して作られた混合エマルジヨン
液に、前記ゲル化された薄膜層が外面に形成され
た手型を浸漬させて薄膜層の外面に混合エマルジ
ヨン液を付着させる。この混合エマルジヨン液に
使用する硬度の高い樹脂は粒径が0.05μ〜0.5μの
ものを使用する。また混合エマルジヨン液の樹脂
の混合割合は、このエマルジヨン液によつて作ら
れるコーテイング層の滑性と塩化ビニル樹脂の薄
膜層への接着性を満足させるために次のように設
定している。即ち、接着のための樹脂(A)〔接着性
樹脂〕と、滑性のための樹脂(B)〔メタメチルアク
リレート樹脂などの樹脂〕との割合は、(A)：(B)＝
30〜60：70〜40の範囲で適宜選べば良い。そして
この混合エマルジヨン液に必要に応じて界面活性
剤、増粘剤、消泡剤、水などを添加し、この水分
散体の濃度、粘度をコーテイング層が薄く形成で
きるように調整する。即ち、水に対する混合樹脂
の濃度を３％〜15％位い、粘度150センチポイズ
位いに調整する。このような混合エマルジヨン液
から引き上げた手型外面の薄膜層の外面には混合
エマルジヨンの薄膜層が付着しており、再度加熱
して塩化ビニル樹脂の薄膜層を溶融させると同時
に混合エマルジヨンの薄膜層を成膜させて塩化ビ
ニル樹脂の薄膜層と一体化させる。これにより塩
化ビニル樹脂の薄膜層の外側に混合エマルジヨン
を材料とする滑性を有する薄膜層が一体に形成さ
れたことになり、その後冷却させたあとで前記両
薄膜層が一体となつた手袋を手型から反転離型す
る。これにより手袋の製造が完了し、前記滑性を
有する薄膜層は内面に位置する。 First, a metal or ceramic hand mold is mixed with plasticizers, stabilizers, pigments, gelling agents, diluents, fillers, etc. commonly used in vinyl chloride paste resin. The hand mold is immersed in vinyl resin sol, a thin film layer of vinyl chloride resin sol is attached to the hand mold, and then pulled up.The hand mold with a thin film layer of vinyl chloride resin sol adhered to the outer surface is rotated in a heating furnace at approximately 250°C. The thin film layer is gelled by heating for 1 minute. Next, a highly hard resin such as methmethyl acrylate resin is added to the emulsion of a synthetic resin such as vinyl chloride resin, acrylic ester resin, or vinyl chloride resin-acrylic ester copolymer resin, which has adhesive properties to vinyl chloride resin. The hand mold having the gelled thin film layer formed on the outer surface is immersed in the mixed emulsion solution prepared by mixing the mixed emulsion solution on the outer surface of the thin film layer. The highly hard resin used in this mixed emulsion liquid has a particle size of 0.05 μm to 0.5 μm. The mixing ratio of the resins in the mixed emulsion liquid is set as follows in order to satisfy the lubricity of the coating layer formed by the emulsion liquid and the adhesion to the vinyl chloride resin thin film layer. In other words, the ratio of resin for adhesion (A) [adhesive resin] and resin for slipperiness (B) [resin such as methmethyl acrylate resin] is (A):(B)=
You can choose as appropriate in the range of 30-60:70-40. Then, a surfactant, a thickener, an antifoaming agent, water, etc. are added to this mixed emulsion liquid as necessary, and the concentration and viscosity of this aqueous dispersion are adjusted so that a thin coating layer can be formed. That is, the concentration of the mixed resin relative to water is adjusted to about 3% to 15%, and the viscosity is adjusted to about 150 centipoise. A thin film layer of the mixed emulsion is attached to the outer surface of the thin film layer on the outer surface of the hand mold pulled up from the mixed emulsion liquid, and the thin film layer of the mixed emulsion is melted by heating again to melt the thin film layer of the vinyl chloride resin. is formed into a film and integrated with a thin film layer of vinyl chloride resin. As a result, a slippery thin film layer made of mixed emulsion is integrally formed on the outside of the vinyl chloride resin thin film layer, and after cooling, the glove with both the thin film layers integrated is formed. Invert and release from the hand mold. This completes the production of the glove, and the slippery thin film layer is located on the inner surface.
ところで前記混合エマルジヨン液の材料として
使用されているメタメチルアクリレート樹脂など
の硬度の高い樹脂の粒径は前述のように0.05μ〜
0.5μであり、その粒子は混合エマルジヨン液中に
分散されている。従つて混合エマルジヨン液を前
記塩化ビニル樹脂の薄膜層の上に薄くコーテイン
グしたとき、塩化ビニルの薄膜層と一体化された
混合エマルジヨンを材料とする薄膜層中の硬度の
高い樹脂の粒子はその混合エマルジヨンを材料と
する薄膜層から突出することなく、均一に分散さ
れている。これにより混合エマルジヨンを材料と
する薄膜層は滑性を有し、使用時において手に対
する着脱性が良い。しかも前記硬度の高い樹脂は
突出することなく均一に分散されているので、長
時間使用しても削り取られることはない。また混
合エマルジヨンを材料とする薄膜層は塩化ビニル
樹脂に対して接着性のある合成樹脂エマルジヨン
を接着剤として混合使用していることから、この
薄膜層自体が塩化ビニル樹脂の薄膜層から剥離す
ることがない。このようにして作られた手袋は手
型から表面が密着し合うようなことなく離型し易
く、また使用時において塵の発生がなく、且つ手
に対して着脱容易となる。 By the way, the particle size of the resin with high hardness such as methmethyl acrylate resin used as the material of the mixed emulsion liquid is 0.05μ~ as mentioned above.
0.5μ, and the particles are dispersed in the mixed emulsion liquid. Therefore, when the mixed emulsion liquid is thinly coated on the vinyl chloride resin thin film layer, the particles of the hard resin in the thin film layer made of the mixed emulsion integrated with the vinyl chloride thin film layer are mixed with the thin film layer of vinyl chloride resin. It is uniformly dispersed without protruding from the thin film layer made of emulsion. As a result, the thin film layer made of the mixed emulsion has lubricity and is easily attached to and removed from the hand during use. Moreover, since the high hardness resin is uniformly dispersed without protruding, it will not be scraped off even if used for a long time. In addition, since the thin film layer made of mixed emulsion uses a synthetic resin emulsion that has adhesive properties to vinyl chloride resin as an adhesive, this thin film layer itself may peel off from the thin film layer of vinyl chloride resin. There is no. Gloves made in this way can be easily released from the hand mold without causing the surfaces to come into close contact with each other, do not generate dust during use, and are easy to put on and take off from the hand.
発明の効果
以上のように本発明によれば、次に述べるよう
な効果が得られる。Effects of the Invention As described above, according to the present invention, the following effects can be obtained.
即ち、本発明の方法によつて作られた手袋の内
面は硬度の高い樹脂を含有する混合エマルジヨン
液を材料として形成された滑性を有する層が位置
しており、使用時の着脱が容易で使い勝手が良
く、使用中に飛散する付着物がないので塵の発生
もない。しかも手袋を手型から反転離型させると
き、前記混合エマルジヨン液を材料とする滑性を
有する層が表側に位置しているので表面が密着し
合うようなことなく、手型から離型し易い。 That is, the inner surface of the glove made by the method of the present invention has a slippery layer formed from a mixed emulsion liquid containing a highly hard resin, making it easy to put on and take off during use. It is easy to use and does not generate dust as there is no deposit that scatters during use. Moreover, when the glove is inverted and released from the hand mold, the slippery layer made of the mixed emulsion liquid is located on the front side, so the surfaces do not come into close contact with each other and are easily released from the hand mold. .
Claims (1)
ゾルに浸漬し、引き揚げて後、加熱して手型に付
着した塩化ビニル樹脂ゾルをゲル化し、これを塩
化ビニル樹脂に対して接着性のある合成樹脂エマ
ルジヨンにメタメチルアクリレート樹脂などの硬
度の高い樹脂をエマルジヨンの状態で混合した混
合エマルジヨン液に浸漬してゲル化塩化ビニル樹
脂層の外面に混合エマルジヨン液を付着させ、引
き上げて後、再度加熱して塩化ビニル樹脂を溶融
させると同時に外面に付着する混合エマルジヨン
を成膜させて、塩化ビニル樹脂層の外側に一体の
滑性を有する層を形成し、冷却後反転離型するこ
とを特徴とする無塵手袋の製造方法。1. A metal or ceramic hand mold is immersed in vinyl chloride resin sol, pulled up, heated, and the vinyl chloride resin sol adhering to the hand mold is gelled. The resin emulsion is immersed in a mixed emulsion solution in which a highly hard resin such as metamethyl acrylate resin is mixed in the form of an emulsion to adhere the mixed emulsion solution to the outer surface of the gelled vinyl chloride resin layer, then pulled out and heated again. The method is characterized by melting the vinyl chloride resin and simultaneously forming a mixed emulsion that adheres to the outer surface to form an integral slippery layer on the outside of the vinyl chloride resin layer, and then inverting and releasing the mold after cooling. Method of manufacturing dust-free gloves.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61240475A JPS6399303A (en) | 1986-10-09 | 1986-10-09 | Production of dustproof glove |
| KR8710914A KR920006576B1 (en) | 1986-10-09 | 1987-09-30 | Method of manufacturing dust-free gloves |
| GB8723561A GB2195921B (en) | 1986-10-09 | 1987-10-07 | Method of manufacturing dust-free gloves |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61240475A JPS6399303A (en) | 1986-10-09 | 1986-10-09 | Production of dustproof glove |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6399303A JPS6399303A (en) | 1988-04-30 |
| JPH0327642B2 true JPH0327642B2 (en) | 1991-04-16 |
Family
ID=17060069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61240475A Granted JPS6399303A (en) | 1986-10-09 | 1986-10-09 | Production of dustproof glove |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS6399303A (en) |
| KR (1) | KR920006576B1 (en) |
| GB (1) | GB2195921B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0753922B2 (en) * | 1990-08-31 | 1995-06-07 | ハニー化成株式会社 | Method for manufacturing gloves made of vinyl chloride resin |
| JP2747117B2 (en) * | 1991-01-18 | 1998-05-06 | 株式会社東和コーポレーション | Glove manufacturing method and gloves |
| GB2484066B (en) | 2010-09-22 | 2013-01-09 | Siemens Plc | Adhesively bonded cylindrical magnets comprising annular coils, and method of manufacture thereof |
| KR102140611B1 (en) * | 2018-06-05 | 2020-08-03 | (주)광장이노텍 | aerogel gloves and method of making the same |
-
1986
- 1986-10-09 JP JP61240475A patent/JPS6399303A/en active Granted
-
1987
- 1987-09-30 KR KR8710914A patent/KR920006576B1/en not_active IP Right Cessation
- 1987-10-07 GB GB8723561A patent/GB2195921B/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| GB2195921A (en) | 1988-04-20 |
| JPS6399303A (en) | 1988-04-30 |
| GB2195921B (en) | 1990-08-22 |
| KR880004768A (en) | 1988-06-27 |
| KR920006576B1 (en) | 1992-08-10 |
| GB8723561D0 (en) | 1987-11-11 |
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