JPH0380884B2 - - Google Patents
Info
- Publication number
- JPH0380884B2 JPH0380884B2 JP6956087A JP6956087A JPH0380884B2 JP H0380884 B2 JPH0380884 B2 JP H0380884B2 JP 6956087 A JP6956087 A JP 6956087A JP 6956087 A JP6956087 A JP 6956087A JP H0380884 B2 JPH0380884 B2 JP H0380884B2
- Authority
- JP
- Japan
- Prior art keywords
- vinyl chloride
- mold
- film
- glove
- glove body
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 12
- 229920005989 resin Polymers 0.000 claims description 12
- 239000012756 surface treatment agent Substances 0.000 claims description 11
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000004925 Acrylic resin Substances 0.000 claims description 8
- 229920000178 Acrylic resin Polymers 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims 1
- 239000010408 film Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- 239000000203 mixture Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- -1 phthalate ester Chemical class 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 239000003349 gelling agent Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Moulding By Coating Moulds (AREA)
- Gloves (AREA)
Description
【発明の詳細な説明】
＜産業上の利用分野＞
本発明は非粘着性を有する塩化ビニル手袋及び
それを製造する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION <Industrial Field of Application> The present invention relates to a non-stick vinyl chloride glove and a method for manufacturing the same.
＜従来技術＞
従来此種の塩化ビニル手袋は、可塑剤が配合さ
れている関係から粘着性が大きく、製造型から離
型する場合、ねばねばして離型しずらく、又、使
用時においても、手に密着して不快感を与え、手
への脱着時もその粘着性のため容易に取り外しが
出来ない等非常に使用しずらいものであつた。<Prior art> Conventionally, this kind of vinyl chloride gloves have a high degree of stickiness due to the fact that they contain plasticizers, and when they are released from the manufacturing mold, they are sticky and difficult to release, and they are also sticky during use. It was extremely difficult to use, as it adhered closely to the hand, causing discomfort, and could not be easily removed due to its adhesiveness.
これを解消するものとして、粉末や塩化ビニル
ブレンドレジンをコーテイングしたり、微粒子を
散布付着させたりするものがあるが、粉末ではこ
れが使用時に剥れてしまい、ブレンドレジンでは
物性が変化して手を荒らす欠点を有し、微粒子を
散布したのでは、表（内）面が硬く、凹凸によつ
て見栄えがよくなく、使用時には、その微粒子が
異物感を与え不快なものであつた。 To solve this problem, there are coatings with powder or vinyl chloride blend resin, or spraying and adhering fine particles, but powders peel off during use, and blend resins change their physical properties and can be easily handled. It has the disadvantage of causing roughness, and when fine particles are sprayed, the front (inner) surface is hard and has unevenness, which makes it unattractive, and when used, the fine particles give an unpleasant feeling of being a foreign body.
又、製造型を塩化ビニル樹脂ゾルに浸漬し該型
に付着したゾルをゲル化し、微粒子シリカを含有
する合成樹脂エマルジヨンに浸漬して成膜し、微
粒子シリカを固定する方法もある。しかし、これ
も基本的には前記微粒子を散布したのと同じく表
面に微粒子シリカが凹凸を形成しているため、こ
れが剥れるものである。この場合は成膜中に微粒
子シリカが存在するため散布したもののように容
易に剥れるものではないけれども、エマルジヨン
の中に無機物があるため、相溶性はなく、成膜が
とれやすく、シリカも脱落しやすいものであり、
かつ、異物感のあるものである。 There is also a method of fixing the particulate silica by immersing the production mold in a vinyl chloride resin sol to gel the sol adhering to the mold, and then immersing it in a synthetic resin emulsion containing particulate silica to form a film. However, this also basically peels off because the fine silica particles form irregularities on the surface in the same way as when the fine particles were dispersed. In this case, since fine silica particles are present during the film formation, it does not come off as easily as when sprayed, but since there are inorganic substances in the emulsion, there is no compatibility, and the film is easy to remove, and the silica also falls off. It is easy to do,
Moreover, it feels like a foreign body.
＜発明が解決しようとする問題点＞
本発明はこのような事情に鑑みてなされたもの
で、粘着性が無く、物性も変化せず、異物感を与
えない手袋を提供せんとするものである。<Problems to be Solved by the Invention> The present invention has been made in view of the above circumstances, and aims to provide gloves that are not sticky, do not change physical properties, and do not give a feeling of being a foreign body. .
＜問題点を解決するための手段＞
本発明は前記問題点を解決するために、手袋製
造型を塩化ビニル樹脂溶液に浸漬して手袋本体を
成膜した後、塩化ビニル、アクリル樹脂、塩化ゴ
ムを含有する表面処理剤に再度浸漬して手袋本体
と一体化せる皮膜を形成し、反転離型することで
ある。<Means for Solving the Problems> In order to solve the above-mentioned problems, the present invention provides a method for immersing a glove manufacturing mold in a vinyl chloride resin solution to form a film on the glove body, and then using vinyl chloride, acrylic resin, or chlorinated rubber. The first step is to immerse the glove in a surface treatment agent containing the same to form a film that can be integrated with the glove body, and then invert and release the mold.
＜作用＞
上記手段によつて、表面処理剤が手袋本体の粘
着性を防止する。<Function> By the above means, the surface treatment agent prevents the glove body from becoming sticky.
＜実施例＞
本発明の実施の一例を説明すると、手袋製造型
は此種の技術分野において周知の形態および構造
のもの例えば陶磁器又は金属で手型状に形成され
たものであり、この製造型を所定の温度に調整し
た後、塩化ビニル樹脂溶液に１回または２回浸漬
して手袋本体となる塩化ビニルペーストを附着さ
せ、引き上げてセミキユアー、冷却して型面に一
層又は二層必要によつては数層を成膜し、然る
後、これを表面処理剤に再度浸漬する。<Example> To explain an example of the implementation of the present invention, the glove manufacturing mold is of a shape and structure well known in this technical field, such as a hand-shaped mold made of ceramic or metal. After adjusting the temperature to a predetermined temperature, immerse it once or twice in a vinyl chloride resin solution to deposit the vinyl chloride paste that will become the glove body, pull it out to semi-cure it, cool it and apply one or two layers to the mold surface as necessary. Several layers are then deposited and then immersed again in the surface treatment agent.
塩化ビニル樹脂溶液は塩化ビニルペーストレジ
ンに可塑剤、安定剤、ゲル化剤、顔料など通常用
いられている各種の添加剤を配合してなる周知の
塩化ビニルペーストであり、この中に場合によつ
てはストレートレジンを配合することもあり、こ
のような粘度4000〜10000cpsとした塩化ビニルペ
ーストを手袋製造型に附着させてセミキユアー、
冷却して手袋本体となる一層もしくは二層よりな
る薄膜層を形成し、この成膜の表面に、表面処理
剤を施す。 Vinyl chloride resin solution is a well-known vinyl chloride paste made by blending various commonly used additives such as plasticizers, stabilizers, gelling agents, and pigments with vinyl chloride paste resin. Straight resin is sometimes added to the gloves, and vinyl chloride paste with a viscosity of 4,000 to 10,000 cps is attached to the glove manufacturing mold to make semi-cured,
A thin film layer consisting of one or two layers that will become the glove body is formed by cooling, and a surface treatment agent is applied to the surface of this formed film.
表面処理剤は、塩化ビニル、アクリル樹脂、塩
化ゴムを含有する粘度が10〜100cpsの溶剤タイプ
又は粘度が20〜200cpsのエマルジヨンタイプのも
のであつて、この表面処理剤に前記成膜層を有す
る手袋製造型を再度浸漬して表面処理を施し、引
き上げ、予備乾燥、キユアー、冷却を順次行つて
表面処理皮膜を設け、反転離型により手袋本体の
内面に表面処理皮膜層を形成する。この表面処理
剤における塩化ビニルは手袋本体との相溶性か
ら、塩化ビニルペーストのレジンの重合度を考慮
して、その重合度を選択するものであるが、一般
的には重合度（）は1000位がよい。アクリル樹
脂及び塩化ゴムは手袋本体中の可塑剤の移行を防
止するため分子量は大きいものがよく、5000〜
100000のものを用いる。 The surface treatment agent is a solvent type with a viscosity of 10 to 100 cps or an emulsion type with a viscosity of 20 to 200 cps containing vinyl chloride, acrylic resin, or chlorinated rubber, and the film forming layer is applied to this surface treatment agent. The glove-making mold is then immersed again for surface treatment, pulled up, pre-dried, cured, and cooled in order to form a surface-treated film, and then reversely released to form a surface-treated film layer on the inner surface of the glove body. The degree of polymerization of the vinyl chloride used in this surface treatment agent is selected based on its compatibility with the glove body, taking into account the degree of polymerization of the resin in the vinyl chloride paste, but generally the degree of polymerization () is 1000. Good rank. Acrylic resin and chlorinated rubber should preferably have a large molecular weight, 5000~ to prevent the migration of plasticizer into the glove body.
Use 100000.
次に具体的な実施態様について説明すると、下
記配合(イ)による液温35℃の塩化ビニルペースト
に、型温50℃に調整された手袋製造型を浸漬し、
引き上げた後170℃４分セミキユアーし、型温ま
で冷却する。 Next, to explain a specific embodiment, a glove manufacturing mold adjusted to a mold temperature of 50°C is immersed in a vinyl chloride paste with a liquid temperature of 35°C according to the following formulation (a),
After lifting, semi-cure at 170℃ for 4 minutes and cool to mold temperature.
−配合(イ)−
塩化ビニルペーストレジン（＝1650） 100PHR
可塑剤（フタル酸エステル、ポリエステル）
100PHR
安定剤（Ca−Ba−Zn） 2PHR
ゲル化剤（Ca／Si） 4PHR
顔 料 1PHR
次いで下記配合(ロ)の溶剤タイプ及び配合(ハ)のエ
マルジヨンタイプの表面処理剤（液温25℃）に
別々に浸漬し、引き上げ後、60〜140℃２分予備
乾燥、220℃８分キユアーして型温70℃まで冷却
後、反転離型し、二つの塩化ビニル手袋を得た。-Composition (a)- Vinyl chloride paste resin (=1650) 100PHR Plasticizer (phthalate ester, polyester)
100PHR Stabilizer (Ca-Ba-Zn) 2PHR Gelling agent (Ca/Si) 4PHR Pigment 1PHR Next, the solvent type of the following formulation (B) and the emulsion type surface treatment agent of the formulation (C) (liquid temperature 25℃) ), and after pulling up, pre-drying for 2 minutes at 60-140°C, curing for 8 minutes at 220°C, cooling to a mold temperature of 70°C, and then inverting and releasing the mold to obtain two vinyl chloride gloves.
いずれも粘着性がなく、離型及び手の脱着が容
易であつた。 All of them had no stickiness and were easy to release from the mold and to attach and remove by hand.
−配合(ロ)−
塩化ビニル 9PHR
アクリル酸エステル ６ 〃
塩化ゴム 7.5 〃
トルエン 42.5 〃
MEK 42.5 〃 キシレン 100
（固形分10.8％）
−配合(ハ)−
塩化ビニル 9PHR
アクリル酸エステル ６
塩化ゴム 7.5
分散剤 １
安定剤 １
界面活性剤 １水 100
（固形物18％）
＜効果＞
本発明は手袋製造型を塩化ビニル樹脂溶液に浸
漬して手袋本体を成膜した後、塩化ビニル、アク
リル樹脂、塩化ゴムを含有する表面処理剤に再度
浸漬して手袋本体と一体化せる皮膜を形成し反転
離型することによつて、手袋本体の内面に塩化ゴ
ムを含有し、かつその手袋本体と一体化した皮膜
を設けた塩化ビニル手袋を提供し得るものであ
り、この表面処理剤による皮膜における塩化ビニ
ルとアクリル樹脂が手袋本体との接着性を上げる
バインダー的要素となり、該皮膜が剥れることが
なく、分子量の大きい塩化ゴムが塩化ビニルと相
溶性を有しないため、粒子の役割を果し、表面が
微凹凸となると共に、この塩化ゴムは有機物であ
るためアクリル樹脂や手袋本体に含まれている可
塑剤と相溶性があるため、従来の微粒子を散布し
たり、無機物の微粒子シリカを含有するエマルジ
ヨンに浸漬して該シリカを固定したものとは基本
的に異なり、脱落したり、剥れたりすることが全
くない。しかも、物性の低下、風合の低下、硬化
もなく、耐薬品性は上昇し、非粘着性でありなが
ら異物感が無く、使用感の良好な滑性を有する手
袋を提供することが出来るものである。-Blend (B)- Vinyl chloride 9PHR Acrylic ester 6 Chlorinated rubber 7.5 Toluene 42.5 MEK 42.5 Xylene 100 (Solid content 10.8%) -Blend (C)- Vinyl chloride 9PHR Acrylic ester 6 Chlorinated rubber 7.5 Dispersant 1 Stabilizer 1 Surfactant 1 Water 100 (solid matter 18%) <Effects> The present invention involves immersing a glove manufacturing mold in a vinyl chloride resin solution to form a film on the glove body, and then using vinyl chloride, acrylic resin, or chlorinated rubber. By dipping it again in a surface treatment agent containing chlorinated rubber to form a film that is integrated with the glove body and then inverting the mold, a film that contains chlorinated rubber on the inner surface of the glove body and is integrated with the glove body can be created. The vinyl chloride and acrylic resin in the film formed by this surface treatment agent act as binder elements that increase the adhesion to the glove body, preventing the film from peeling off and reducing the molecular weight. Since chlorinated rubber with a large amount of chloride is not compatible with vinyl chloride, it acts as a particle, resulting in a slightly uneven surface, and since this chlorinated rubber is an organic substance, it may cause problems with plasticizers contained in acrylic resin and the glove body. Because it is compatible with silica, it is fundamentally different from conventional methods in which silica is fixed by scattering fine particles or immersing it in an emulsion containing inorganic fine silica particles, and it does not fall off or peel. Not at all. Furthermore, it is possible to provide gloves that have improved chemical resistance without deterioration in physical properties, deterioration in texture, or hardening, and have non-adhesion, no foreign body feeling, and smoothness that provides a good feeling of use. It is.
Claims (1)
脂、塩化ゴムを含有する被膜を設けた塩化ビニル
手段。 ２ 手袋製造型を塩化ビニル樹脂溶液に浸漬して
手袋本体を成膜した後、塩化ビニル、アクリル樹
脂、塩化ゴムを含有する表面処理剤に再度浸漬し
て手袋本体と一体化せる被膜を形成し、反転離型
すことを特徴とする塩化ビニル手袋の製造方法。[Scope of Claims] 1. A vinyl chloride means in which a coating containing vinyl chloride, acrylic resin, and chlorinated rubber is provided on the inner surface of the glove body. 2. After dipping the glove manufacturing mold in a vinyl chloride resin solution to form a film on the glove body, the mold is dipped again in a surface treatment agent containing vinyl chloride, acrylic resin, and chlorinated rubber to form a film that is integrated with the glove body. , a method for producing vinyl chloride gloves characterized by inversion mold release.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62069560A JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62069560A JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63235508A JPS63235508A (en) | 1988-09-30 |
| JPH0380884B2 true JPH0380884B2 (en) | 1991-12-26 |
Family
ID=13406259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62069560A Granted JPS63235508A (en) | 1987-03-23 | 1987-03-23 | Vinyl chloride glove and its production |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63235508A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02229205A (en) * | 1989-03-01 | 1990-09-12 | Chiyoda Kasei Kogyo Kk | Vinyl chloride gloves |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS532468A (en) * | 1976-06-15 | 1978-01-11 | Otsuka Chem Co Ltd | 2,2-bis(3,4-epoxy-5-oxotetrahydropyrane)-ethers and method of preparing the same |
-
1987
- 1987-03-23 JP JP62069560A patent/JPS63235508A/en active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS532468A (en) * | 1976-06-15 | 1978-01-11 | Otsuka Chem Co Ltd | 2,2-bis(3,4-epoxy-5-oxotetrahydropyrane)-ethers and method of preparing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63235508A (en) | 1988-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3768248B2 (en) | Improved smooth gloves and method for making the same | |
| US3140195A (en) | Process for providing a coated surface | |
| GB995404A (en) | Method of making molded article | |
| JPH0380884B2 (en) | ||
| US2997746A (en) | Method of making roughened rubber product | |
| US3246069A (en) | Rotational method of making a hollow molded multilayered article | |
| JP3197943B2 (en) | Brushed product made of natural rubber and method for producing the same | |
| JPH0610202A (en) | Glove made from polyvinyl chloride | |
| JPH0219203B2 (en) | ||
| JPH02229205A (en) | Vinyl chloride gloves | |
| JPH062204A (en) | Polyvinyl chloride gloves and its production | |
| JP3272783B2 (en) | Manufacturing method of vinyl chloride gloves | |
| JPH01221501A (en) | Vinyl chloride resin glove and production thereof | |
| JPS5836447A (en) | Heat-resisting coating structure | |
| JPH11509257A (en) | Metal substrate with enhanced corrosion resistance and improved paint adhesion | |
| JP2002285414A (en) | Method for producing rubber glove | |
| JP3669714B2 (en) | Vinyl chloride gloves and method for producing the same | |
| JPS61249717A (en) | Manufacture of powder-free vinyl chloride glove, to surface thereof sliding characteristic giving treatment is not executed | |
| JP3516080B2 (en) | Resin composition for gloves made of vinyl chloride resin and method for producing gloves made of vinyl chloride resin | |
| JPS5940410Y2 (en) | anti-slip work gloves | |
| JPS6285003A (en) | Production of plastic glove without dusting | |
| JP2001512532A (en) | High strength aluminum surface treatment method | |
| JPS5887196A (en) | Matte-finishing thin film type parting agent for use in molding of fiber-reinforced thermosetting resin article | |
| JPS60105519A (en) | Manufacture of packing material for food vessel | |
| JPH04289203A (en) | Glove and production thereof |