JPS63196503A - Embrocation for controlling termite and cockroach, using boric acid - Google Patents

Embrocation for controlling termite and cockroach, using boric acid

Info

Publication number
JPS63196503A
JPS63196503A JP2696387A JP2696387A JPS63196503A JP S63196503 A JPS63196503 A JP S63196503A JP 2696387 A JP2696387 A JP 2696387A JP 2696387 A JP2696387 A JP 2696387A JP S63196503 A JPS63196503 A JP S63196503A
Authority
JP
Japan
Prior art keywords
boric acid
cockroaches
embrocation
termites
main components
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2696387A
Other languages
Japanese (ja)
Other versions
JP2517718B2 (en
Inventor
Yoshiyuki Ogushi
義之 大串
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP62026963A priority Critical patent/JP2517718B2/en
Publication of JPS63196503A publication Critical patent/JPS63196503A/en
Application granted granted Critical
Publication of JP2517718B2 publication Critical patent/JP2517718B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE:To obtain an embrocation for controlling termites and cockroaches, suppressing elution of boric acid, having improved durability of effects, by blending boric acid with compounded polyemulsion comprising carboxyl modified styrene butadiene and cyclohexyl methacrylate as main components. CONSTITUTION:(A) Boric acid which has been used an embrocation for controlling termites and cockroaches because termites and cockroaches become dehydrated state and die after they eat boric acid is blended with a main agent comprising (B) carboxyl modified styrene butadiene and cyclohexyl methacrylate as an main components or the component B and (C) silicon oxide, calcium oxide and iron oxide as main components to give an embrocation for termites and cockroaches having high adhesiveness of the embrocation to foundation, floor, pillars, walls, ceilings, cottage structure, etc., suppressing elution of the component A, maintaining effects for a long period.

Description

【発明の詳細な説明】 (イ)産業上の利用分野 本発明は、硼酸を用いた白蟻・ゴキブリ退治用塗布剤に
関する。
DETAILED DESCRIPTION OF THE INVENTION (a) Field of Industrial Application The present invention relates to a coating agent for exterminating termites and cockroaches using boric acid.

(ロ)従来技術とその問題点 白蟻やゴキブリは、硼酸を食べると脱水症状を起こして
死ぬことが発見されて以来、硼酸は白蟻・ゴキブリ退治
用塗布剤として相当用いられている。そして、通常、か
かる硼酸は、建物の土台、小屋組、床、柱、壁、天井等
、白蟻やゴキブリが活動しそうな個所にそのまま若しく
は水で薄めたものを塗布することによって用いられてい
る。
(b) Prior art and its problems Since it was discovered that termites and cockroaches die from dehydration when they eat boric acid, boric acid has been widely used as a liniment for exterminating termites and cockroaches. Such boric acid is usually used as it is or by applying it diluted with water to areas where termites and cockroaches are likely to be active, such as the foundations, roof frames, floors, pillars, walls, and ceilings of buildings.

しかし、硼酸を建物の土台等に直接塗布しても、周囲に
散逸したり、急速に有効成分が放出されて効力を失うこ
とになっていた。
However, even if boric acid was applied directly to the foundations of buildings, it would dissipate into the surrounding area, or the active ingredients would be rapidly released, resulting in a loss of effectiveness.

本発明はこのような従来技術が有する問題点を解決する
ことができる白蟻・ゴキブリ退治用塗布剤を提供するこ
とを目的とする。
An object of the present invention is to provide a coating agent for exterminating termites and cockroaches that can solve the problems of the prior art.

(ニ)問題点を解決するための手段 本発明は、硼酸と、カルボキシ変性スチレンブタジェン
、メタクリル酸シクロヘキシルを主成分としてなる複合
ポリマーエマルジョンとを混合して製造した硼酸を用い
た白蟻・ゴキブリ退治用塗布剤、及び、硼酸と、カルボ
キシ変性スチレソイタジエン、メタクリル酸シクロヘキ
シルを主成分としてなる複合ポリマーエマルジョンと酸
化珪素、酸化カルシウム、酸化鉄を主成分とした主剤と
を混合して製造した硼酸を用いた白蟻・ゴキブリ退治用
塗布剤に係るものである。
(D) Means for Solving the Problems The present invention provides extermination of termites and cockroaches using boric acid produced by mixing boric acid with a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as main components. Boric acid produced by mixing a composite polymer emulsion containing boric acid, carboxy-modified styrene soitadiene, and cyclohexyl methacrylate as main components, and a main agent containing silicon oxide, calcium oxide, and iron oxide as main components. This relates to a liniment for exterminating termites and cockroaches using the following.

(ホ)作用及び効果 ■?lポリマーエマルジョン若しくは同複合ポリマーエ
マルジョンと主剤との混合物は十分な接着力を有するの
で、いかなる材料(コンクリート、木材、モルタル、そ
の他)からなる建物の土台、床、柱、壁、天井、小屋組
等にも本発明に係る白蟻・ゴキブリ退治用塗布剤を強力
に接着することができる。
(e) Action and effect■? l Polymer emulsion or a mixture of the composite polymer emulsion and the main agent has sufficient adhesive strength, so it can be used for foundations, floors, columns, walls, ceilings, roof frames, etc. of buildings made of any material (concrete, wood, mortar, etc.) The coating agent for exterminating termites and cockroaches according to the present invention can be strongly adhered to these materials.

■硼酸は複合ポリマーエマルジョン若しくは同複合ポリ
マーエマルジョンと主剤との混合物中に混和されている
ので、硼酸成分はじわじわとしか外部に溶出せず、効力
を長年月にわたって持続することができる。
(2) Since boric acid is mixed into the composite polymer emulsion or the mixture of the composite polymer emulsion and the base agent, the boric acid component is only gradually eluted to the outside, and its efficacy can be maintained for many years.

(へ)実施例 以下、実施例に基づいて、本発明を具体的に説明する。(f) Example The present invention will be specifically described below based on Examples.

〔第1実施例〕 硼酸を複合ポリマーエマルジョンを、1:1の割合で混
合して、本発明に係る白蟻・ゴキブリ退治用塗布剤を製
造した。
[First Example] A coating agent for exterminating termites and cockroaches according to the present invention was prepared by mixing boric acid and a composite polymer emulsion at a ratio of 1:1.

ここに、硼酸は粉末状の硼酸(acidum bori
cum)を用いた。
Here, boric acid is powdered boric acid (acidum boric acid).
cum) was used.

また、複合ポリマーエマルジョンは、カルボキシ変性ス
チレンブタジェン、メタクリル酸シクロヘキシルを主成
分としてなる複合ポリマーエマルジョンと、酸化珪素、
酸化カルシウム、酸化鉄を主成分とした主剤に混合して
製造したものを用いた。
In addition, the composite polymer emulsion consists of a composite polymer emulsion whose main components are carboxy-modified styrene butadiene and cyclohexyl methacrylate, silicon oxide,
A product prepared by mixing calcium oxide and iron oxide with a main ingredient was used.

複合ポリマーエマルジョンの好ましい配合例及び配合順
序を、2例説明すると、 例1)                (重量)カル
ボキシ変性スチレンブタジェン 13  %メタクリル
酸シクロヘキシルー   56  %スチレン重合体 脂肪酸ソーダ石鹸         1 %水    
                 30  %この配
合順序は、まず、蒸留水または軟水に脂肪酸ソーダ石鹸
を入れて溶解し、次にカルボキシ変性スチレンブタジェ
ンを徐々に加えて混合、攪拌し、次ぎにメタクリル酸シ
クロヘキシル−スチレンブタジェン共重合体ラテックス
を徐々に加えて、混合攪拌し、各ポリマーの水中分散液
とする。
Two examples of preferred blending examples and blending order of composite polymer emulsions are explained below: Example 1) (Weight) Carboxy modified styrene butadiene 13% cyclohexyl methacrylate 56% styrene polymer fatty acid soda soap 1% water
30% This blending order is as follows: first, add fatty acid soda soap to distilled or soft water and dissolve it, then gradually add carboxy-modified styrene-butadiene, mix and stir, and then add cyclohexyl methacrylate-styrene-butadiene together. Gradually add the polymer latex and mix and stir to obtain a dispersion of each polymer in water.

例2)                 (重量)カ
ルボキシ変性スチレンブタジェン 13  %スチレン
             28  %メタクリル酸シ
クロヘキシル    28  %脂肪酸ソーダ石鹸  
       1 %水              
      30  %この配合順序は、まず、蒸留水
または軟水に脂肪酸ソーダ石鹸を入れて溶解し、次にカ
ルボキシ変性スチレンブタジェンを徐々に加えて混合、
攪拌し、次ぎにスチレンラテックスを加えて攪拌し、次
にメタクリル酸シクロヘキシルを徐々に加えて、混合攪
拌し、各ポリマーの水中分散液とする。
Example 2) (Weight) Carboxy modified styrene butadiene 13% styrene 28% cyclohexyl methacrylate 28% fatty acid soda soap
1% water
30% This blending order is as follows: First, add fatty acid soda soap to distilled water or soft water and dissolve it, then gradually add carboxy-modified styrene butadiene and mix.
Stir, then add styrene latex and stir, then gradually add cyclohexyl methacrylate and mix and stir to obtain a dispersion of each polymer in water.

次ぎに、上記した硼酸と複合ポリマーエマルジョンを混
合して表面塗布剤を製造する方法の1例について説明す
ると、硼酸190gと複合ポリマーエマルジョン190
 L それに軟水6gを入れて混合するものであり、こ
の混合順序は、まず、複合ボリマーエマルジッンを容器
に入れ、次に硼酸を徐々に加えながら3分〜5分攪拌し
、更に、蒸留水又は軟水又は水道水を適量加えて希釈し
、攪拌しながら白蟻・ゴキブリ退治用塗布剤を製造した
。   −かかる塗布剤を一般住宅の木製土台に塗布し
て、硼酸の効力を調べた所、5年経過しても効力を持続
していた。
Next, an example of a method for producing a surface coating agent by mixing the above-mentioned boric acid and a composite polymer emulsion will be described.
6g of soft water is added to it and mixed.The mixing order is: First, put the composite polymer emulsion into a container, then gradually add boric acid and stir for 3 to 5 minutes, and then add distillation. It was diluted by adding an appropriate amount of water, soft water, or tap water and stirred to produce a liniment for exterminating termites and cockroaches. - When we tested the effectiveness of boric acid by applying this coating to the wooden foundations of ordinary houses, we found that it remained effective even after 5 years.

これは、複合ポリマーエマルジョンとの混合によって、
硼酸の溶出が抑制され、極めて緩慢にした溶出しなかっ
たことを示している。
This is achieved by mixing with a composite polymer emulsion.
This shows that the elution of boric acid was suppressed, extremely slow, and no elution occurred.

〔第2実施例〕 硼酸と、複合ポリマーエマルジョンと、酸化珪素、酸化
カルシウム、酸化鉄を主成分とした主剤とを、1:2:
2の割合で混合して、本発明に係る白蟻・ゴキブリ退治
用塗布剤を製造した。
[Second Example] Boric acid, a composite polymer emulsion, and a main ingredient mainly composed of silicon oxide, calcium oxide, and iron oxide were mixed in a ratio of 1:2:
A coating agent for exterminating termites and cockroaches according to the present invention was prepared by mixing the above ingredients in a ratio of 2 to 2.

本実施例では、硼酸及び複合ポリマーエマルジョンは、
第1実施例と同一のものを用いた。
In this example, the boric acid and composite polymer emulsion were
The same material as in the first example was used.

また、硼酸及び複合ポリマーエマルジョンと混合すべき
主剤の配合例及び配合手順について説明すると、配合例
は、 (M量) 白色セメント          28.0  %珪砂
(S i 02 )        、71.0  %
鉄粉(F e304 )        0.2  %
亜鉛華(ZnO)         0.1  %チタ
ン白(TiO2)       0.1  %グリシン
他          0.6  %であり、上記白色
セメントの成分重量比は、(重量) Ca O65,4% 5i02           23.1  %Fe2
03              0.2  %I g
 l o s s              2.7
  %t  n s  o  l          
       0.2  %Al2O34,3% M g O0,6% SO32,8% その他             0.7  %であり
、上記主剤の配合手順は、まず珪砂を焼いて有機物を取
り除き、粒度を50〜150μmに整え、この珪砂をミ
キサーに投入し、白色セメントを徐々に加えて混合させ
、更に、鉄粉(Fe304)、亜鉛華(ZnO)、チタ
ン白 (TiO2)、グリシン他の順で加えながら、均
一に成るように混合する。
Also, to explain the blending example and blending procedure of the main ingredient to be mixed with boric acid and the composite polymer emulsion, the blending example is as follows: (M amount) White cement 28.0% Silica sand (S i 02) 71.0%
Iron powder (Fe304) 0.2%
Zinc white (ZnO) 0.1% Titanium white (TiO2) 0.1% Glycine and others 0.6%, and the component weight ratio of the above white cement is (by weight) Ca O65.4% 5i02 23.1% Fe2
03 0.2%I g
los s 2.7
%t n s o l
0.2% Al2O34.3% M g O0.6% SO32.8% Others 0.7%, and the procedure for blending the above main ingredient is to first burn silica sand to remove organic matter, adjust the particle size to 50 to 150 μm, This silica sand was put into a mixer, white cement was gradually added and mixed, and then iron powder (Fe304), zinc white (ZnO), titanium white (TiO2), glycine, etc. were added in that order until it became uniform. Mix with

次ぎに、上記した硼酸、複合ポリマーエマルシロン及び
主剤を混合して本発明に係る塗布剤を製造する方法の1
例について説明すると、塗膜厚さが0.6〜1.Onで
塗布面積が1rrrの場合、主剤760gと複合ポリマ
ーエマルジョン760 g、硼酸380g、それに軟水
6gを入れて混合するものであり、この混合順序は、ま
ず、複合ポリマーエマルジョンを容器に入れ、次に主剤
及び硼酸を徐々に加えながら3分〜5分攪拌し、更に、
蒸留水又は軟水又は水道水を適量加えて希釈し、攪拌し
ながら製造するものである。
Next, a method of manufacturing a coating agent according to the present invention by mixing the above-mentioned boric acid, composite polymer emulsilone, and a main ingredient will be described.
To explain an example, the coating film thickness is 0.6 to 1. When the application area is 1 rrr with On, 760 g of the base material, 760 g of the composite polymer emulsion, 380 g of boric acid, and 6 g of soft water are mixed.The mixing order is: first, put the composite polymer emulsion in a container, then While gradually adding the main ingredient and boric acid, stir for 3 to 5 minutes, and
It is manufactured by adding an appropriate amount of distilled water, soft water, or tap water to dilute it and stirring.

なお、白セメントに代えて、ポルトランドセメントを用
いることもできる。
Note that portland cement can also be used instead of white cement.

以上のようにして製造された塗布剤を一般住宅の木製土
台に塗布して、硼酸の効力を調べた所、10年経過して
も効力を持続していた。
When the coating agent manufactured as described above was applied to the wooden foundations of ordinary houses and the efficacy of boric acid was examined, it remained effective even after 10 years.

これは、複合ポリマーエマルジョンと硼酸のみの場合と
比べて二倍の寿命であり、主剤との混合によって、硼酸
の溶出がさらに抑制されたことを示している。
This is twice the life of the composite polymer emulsion and boric acid alone, indicating that the elution of boric acid was further suppressed by mixing with the main agent.

Claims (1)

【特許請求の範囲】 1、硼酸と、カルボキシ変性スチレンブタジエン、メタ
クリル酸シクロヘキシルを主成分としてなる複合ポリマ
ーエマルジョンとを混合して製造した硼酸を用いた白蟻
・ゴキブリ退治用塗布剤。 2、硼酸と、カルボキシ変性スチレンブタジエン、メタ
クリル酸シクロヘキシルを主成分としてなる複合ポリマ
ーエマルジョンと、酸化珪素、酸化カルシウム、酸化鉄
を主成分とした主剤とを混合して製造した硼酸を用いた
白蟻・ゴキブリ退治用塗布剤。
[Scope of Claims] 1. A coating agent for exterminating termites and cockroaches using boric acid produced by mixing boric acid with a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as main components. 2. Termite treatment using boric acid produced by mixing a composite polymer emulsion whose main components are boric acid, carboxy-modified styrene butadiene, and cyclohexyl methacrylate, and a main ingredient whose main components are silicon oxide, calcium oxide, and iron oxide. A liniment for exterminating cockroaches.
JP62026963A 1987-02-07 1987-02-07 A coating agent for combating termites and cockroaches using boric acid Expired - Fee Related JP2517718B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP62026963A JP2517718B2 (en) 1987-02-07 1987-02-07 A coating agent for combating termites and cockroaches using boric acid

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP62026963A JP2517718B2 (en) 1987-02-07 1987-02-07 A coating agent for combating termites and cockroaches using boric acid

Publications (2)

Publication Number Publication Date
JPS63196503A true JPS63196503A (en) 1988-08-15
JP2517718B2 JP2517718B2 (en) 1996-07-24

Family

ID=12207810

Family Applications (1)

Application Number Title Priority Date Filing Date
JP62026963A Expired - Fee Related JP2517718B2 (en) 1987-02-07 1987-02-07 A coating agent for combating termites and cockroaches using boric acid

Country Status (1)

Country Link
JP (1) JP2517718B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02282302A (en) * 1988-12-19 1990-11-19 Dow Chem Co:The Stable emulsion compound of water-insoluble organic insecticide and use and preparation thereof
JP2004083572A (en) * 2002-06-28 2004-03-18 Nobuo Saito Ant proof composition
AU2012100077B4 (en) * 2009-11-11 2012-08-16 Raydiate Pty Ltd Method for the control of crawling insects
JP2012184209A (en) * 2011-03-08 2012-09-27 Sumitomo Chemical Co Ltd Pesticidal composition
AU2009236007B2 (en) * 2009-11-11 2013-12-19 Creepy Crawly Pest Control Pty Ltd Insecticide Treated Insulation and Surrounds

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57174357A (en) * 1981-04-20 1982-10-27 Kikusui Kagaku Kogyo Kk Paint composition
JPS6065043A (en) * 1983-09-20 1985-04-13 Yoshiyuki Ogushi Preparation of surface coating material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57174357A (en) * 1981-04-20 1982-10-27 Kikusui Kagaku Kogyo Kk Paint composition
JPS6065043A (en) * 1983-09-20 1985-04-13 Yoshiyuki Ogushi Preparation of surface coating material

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02282302A (en) * 1988-12-19 1990-11-19 Dow Chem Co:The Stable emulsion compound of water-insoluble organic insecticide and use and preparation thereof
JP2004083572A (en) * 2002-06-28 2004-03-18 Nobuo Saito Ant proof composition
AU2012100077B4 (en) * 2009-11-11 2012-08-16 Raydiate Pty Ltd Method for the control of crawling insects
AU2009236007B2 (en) * 2009-11-11 2013-12-19 Creepy Crawly Pest Control Pty Ltd Insecticide Treated Insulation and Surrounds
JP2012184209A (en) * 2011-03-08 2012-09-27 Sumitomo Chemical Co Ltd Pesticidal composition

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