JP2517718B2 - A coating agent for combating termites and cockroaches using boric acid - Google Patents
A coating agent for combating termites and cockroaches using boric acidInfo
- Publication number
- JP2517718B2 JP2517718B2 JP62026963A JP2696387A JP2517718B2 JP 2517718 B2 JP2517718 B2 JP 2517718B2 JP 62026963 A JP62026963 A JP 62026963A JP 2696387 A JP2696387 A JP 2696387A JP 2517718 B2 JP2517718 B2 JP 2517718B2
- Authority
- JP
- Japan
- Prior art keywords
- boric acid
- cockroaches
- coating agent
- polymer emulsion
- composite polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
【発明の詳細な説明】 （イ）産業上の利用分野 本発明は、硼酸を用いた白蟻・ゴキブリ退治用塗布剤
に関する。TECHNICAL FIELD The present invention relates to a coating agent for combating termites and cockroaches using boric acid.
（ロ）従来技術とその問題点 白蟻やゴキブリは、硼酸を食べると脱水症状を起こし
て死ぬことが発見されて以来、硼酸は白蟻・ゴキブリ退
治用塗布剤として相当用いられている。そして、通常、
かかる硼酸は、建物の土台、小屋組、床、柱、壁、天井
等、白蟻やゴキブリが活動しそうな個所にそのまま若し
くは水で薄めたものを塗布することによって用いられて
いる。(B) Prior art and its problems Since it was discovered that termites and cockroaches die of dehydration when eaten with boric acid, boric acid has been considerably used as a coating agent for combating termites and cockroaches. And usually
Such boric acid is used as it is or by diluting it with water on a place such as a building base, a roof truss, a floor, a pillar, a wall, or a ceiling where a termite or a cockroach is likely to be active.
しかし、硼酸を建物の土台等に直接塗布しても、周囲
に散逸したり、急速に有効成分が放出されて効力を失う
ことになっていた。However, even if boric acid was directly applied to the foundation of a building, it was dissipated to the surroundings or the active ingredient was rapidly released to lose its effect.
本発明はこのような従来技術が有する問題点を解決す
ることができる白蟻・ゴキブリ退治用塗布剤を提供する
ことを目的とする。An object of the present invention is to provide a coating agent for combating termites and cockroaches, which can solve the problems of the prior art.
（ニ）問題点を解決するための手段 本発明は、本発明は硼酸と、カルボキシ変性スチレン
ブタジエン、メタクリル酸シクロヘキシルを主成分とし
てなる複合ポリマーエマルジョンとを混合して製造し、
前記硼酸の溶出を緩慢に抑制したことを特徴とする硼酸
を用いた白蟻・ゴキブリ退治用塗布剤、及び、硼酸と、
カルボキシ変性スチレンブダジエン、、メタクリル酸シ
クロヘキシルを主成分としてなる複合ポリマーエマルジ
ョンと、酸化珪素、酸化カルシウム、酸化鉄を主成分と
した主剤とを混合して製造し、前記硼酸の溶出を緩慢に
抑制したことを特徴とする硼酸を用いた白蟻・ゴキブリ
退治用塗布剤に係るものである。(D) Means for Solving the Problems The present invention is produced by mixing boric acid with a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as a main component,
A coating agent for combating termites and cockroaches using boric acid, characterized by slowly suppressing the elution of boric acid, and boric acid,
A complex polymer emulsion containing carboxy-modified styrene-budadiene and cyclohexyl methacrylate as a main component was mixed with a main component containing silicon oxide, calcium oxide, and iron oxide as main components, and the dissolution of boric acid was slowly suppressed. The present invention relates to a coating agent for combating termites and cockroaches, which comprises boric acid.
（ホ）作用及び効果 複合ポリマーエマルジョン若しくは同複合ポリマー
エマルジョンと主剤との混合物は十分な接着力を有する
ので、いかなる材料（コンクリート、木材、モルタル、
その他）からなる建物の土台、床、柱、壁、天井、小屋
組等にも本発明に係る白蟻・ゴキブリ退治用塗布剤を強
力に接着することができる。(E) Action and effect Since the composite polymer emulsion or the mixture of the composite polymer emulsion and the main agent has sufficient adhesive force, any material (concrete, wood, mortar,
It is possible to strongly adhere the termite / cockroach eradicating coating agent according to the present invention to the base, floor, pillar, wall, ceiling, shed, etc. of a building consisting of (others).
硼酸は複合ポリマーエマルジョン若しくは同複合ポ
リマーエマルジョンと主剤との混合物中に混和されてい
るので、硼酸の溶出が緩慢に抑制され、硼酸成分はじわ
じわとしか外部に溶出せず、効力を長年月にわたって持
続することができる。Since boric acid is mixed in the complex polymer emulsion or the mixture of the complex polymer emulsion and the main agent, the elution of boric acid is slowly suppressed, and the boric acid component slowly elutes to the outside, maintaining its efficacy for many years. can do.
（ヘ）実施例 以下、実施例に基づいて、本発明を具体的に説明す
る。(F) Examples Hereinafter, the present invention will be specifically described based on Examples.
〔第１実施例〕 硼酸を複合ポリマーエマルジョンを、1:1の割合で混
合して、本発明に係る白蟻・ゴキブリ退治用塗布剤を製
造した。[First Example] A composite polymer emulsion of boric acid was mixed at a ratio of 1: 1 to produce a coating agent for combating termites and cockroaches according to the present invention.
ここに、硼酸は粉末状の硼酸（acidum boricum）を用
いた。Here, boric acid used was powdery boric acid.
また、複合ポリマーエマルジョンは、カルボキシ変性
スチレンブタジエン、メタクリル酸シクロヘキシルを主
成分としてなる複合ポリマーエマルジョンと、酸化珪
素、酸化カルシウム、酸化鉄を主成分とした主剤に混合
して製造したものを用いた。The composite polymer emulsion used was prepared by mixing the composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as the main components with the main component containing silicon oxide, calcium oxide and iron oxide as the main components.
複合ポリマーエマルジョンの好ましい配合例及び配合
順序を、２例説明すると、 例１） （重量） カルボキシ変性スチレンブタジエン 13％ メタクリル酸シクロヘキシル 56％ スチレン重合体 脂肪酸ソーダ石鹸 １％ 水 30％ この配合順序は、まず、蒸留水または軟水に脂肪酸ソ
ーダ石鹸を入れて溶解し、次にカルボキシ変性スチレン
ブダジエンを徐々に加えて混合、攪拌し、次ぎにメタク
リル酸シクロヘキシル−スチレンブダジエン共重合体ラ
テックスを徐々に加えて、混合攪拌し、各ポリマーの水
中分散液とする。Two examples of preferable compounding examples and compounding sequences of the composite polymer emulsion will be explained. Example 1) (weight) Carboxy-modified styrene butadiene 13% Cyclohexyl methacrylate 56% Styrene polymer Fatty acid soda soap 1% Water 30% This compounding sequence is First, a fatty acid soda soap was dissolved in distilled water or soft water, and then carboxy-modified styrene-budadiene was gradually added and mixed, and then stirred, and then cyclohexyl methacrylate-styrene budadiene copolymer latex was gradually added, Mix and stir to obtain a dispersion of each polymer in water.
例２） （重量） カルボキシ変性スチレンブダジエン 13％ スチレン 28％ メタクリル酸シクロヘキシル 28％ 脂肪酸ソーダ石鹸 １％ 水 30％ この配合順序は、まず、蒸留水または軟水に脂肪酸ソ
ーダ石鹸を入れて溶解し、次にカルボキシ変性スチレン
ブダジエンを徐々に加えて混合、攪拌し、次ぎにスチレ
ンラテックスを加えて攪拌し、次にメタクリル酸シクロ
ヘキシルを徐々に加えて、混合攪拌し、各ポリマーの水
中分散液とする。Example 2) (Weight) Carboxy-modified styrene-budadiene 13% Styrene 28% Cyclohexylmethacrylate 28% Fatty acid soda soap 1% Water 30% This compounding order is as follows: first add the fatty acid soda soap to distilled water or soft water and dissolve it, then The carboxy-modified styrene-budadiene is gradually added to and mixed and stirred, then styrene latex is added and stirred, and then cyclohexyl methacrylate is gradually added and mixed and stirred to obtain a dispersion liquid of each polymer in water.
次ぎに、上記した硼酸と複合ポリマーエマルジョンを
混合して表面塗布剤を製造する方法の１例について説明
すると、硼酸190gと複合ポリマーエマルジョン190g,そ
れに軟水6gを入れて混合するものであり、この混合順序
は、まず、複合ポリマーエマルジョンを容器に入れ、次
に硼酸を徐々に加えながら３分〜５分攪拌し、更に、蒸
留水又は軟水又は水道水を適量加えて希釈し、攪拌しな
がら白蟻・ゴキブリ退治用塗布剤を製造した。Next, an example of a method for producing a surface coating agent by mixing the above-mentioned boric acid and the composite polymer emulsion will be described. 190 g of boric acid, 190 g of the composite polymer emulsion and 6 g of soft water are added and mixed. The order is as follows. First, put the complex polymer emulsion in a container, then stir for 3 to 5 minutes while gradually adding boric acid, and further dilute by adding an appropriate amount of distilled water or soft water or tap water, and stir while stirring. A coating composition for combating cockroaches was produced.
かかる塗布剤を一般住宅の木製土台に塗布して、硼酸
の効力を調べた所、５年経過しても効力を持続してい
た。When this coating agent was applied to a wooden base of a general house and the effect of boric acid was examined, the effect was maintained even after 5 years.
これは、複合ポリマーエマルジョンとの混合によっ
て、硼酸の溶出が抑制され、極めて緩慢にした溶出しな
かったことを示している。This indicates that the mixing with the complex polymer emulsion suppressed the elution of boric acid and did not cause a very slow elution.
〔第２実施例〕 硼酸と、複合ポリマーエマルジョンと、酸化珪素、酸
化カルシウム、酸化鉄を主成分とした主剤とを、1:2:2
の割合で混合して、本発明に係る白蟻・ゴキブリ退治用
塗布剤を製造した。[Second Example] Boric acid, a composite polymer emulsion, and a main agent containing silicon oxide, calcium oxide, and iron oxide as main components were mixed in a ratio of 1: 2: 2.
The mixture was mixed at a ratio of 1 to prepare a coating agent for combating termites and cockroaches according to the present invention.
本実施例では、硼酸及び複合ポリマーエマルジョン
は、第１実施例と同一のものを用いた。In this example, the same boric acid and complex polymer emulsion as in Example 1 were used.
また、硼酸及び複合ポリマーエマルジョンと混合すべ
き主剤の配合例及び配合手順について説明すると、配合
例は、 （重量） 白色セメント 28.0％ 珪砂（SiO2） 71.0％ 鉄粉（Fe3O4） 0.2％ 亜鉛華（ZnO） 0.1％ チタン白（TiO2） 0.1％ グリシン他 0.6％ であり、上記白色セメントの成分重量比は、 （重量） CaO 65.4％ SiO2 23.1％ Fe2O3 0.2％ igloss 2.7％ insol 0.2％ Al2O3 4.3％ MgO 0.6％ SO3 2.8％ その他 0.7％ であり、上記主剤の配合手順は、まず硅砂を焼いて有機
物を取り除き、粒度を50〜150μｍに整え、この硅砂を
ミキサーに投入し、白色セメントを徐々に加えて混合さ
せ、更に、鉄粉（Fe3O4）、亜鉛華（ZnO）、チタン白
（TiO2）、グリシン他の順で加えながら、均一に成るよ
うに混合する。In addition, a compounding example of the main agent to be mixed with boric acid and the composite polymer emulsion and a compounding procedure will be described. The compounding example is (weight) white cement 28.0% silica sand (SiO 2 ) 71.0% iron powder (Fe 3 O 4 ) 0.2% Zinc white (ZnO) 0.1% Titanium white (TiO 2 ) 0.1% Glycine and other 0.6%. The component weight ratio of the above white cement is (weight) CaO 65.4% SiO 2 23.1% Fe 2 O 3 0.2% igloss 2.7% insol 0.2% Al 2 O 3 4.3% MgO 0.6% SO 3 2.8% Others 0.7%. The main compounding procedure is as follows: first burn silica sand to remove organic substances, adjust the particle size to 50-150 μm, and mix this silica sand with a mixer. , Gradually add white cement and mix, and then add iron powder (Fe 3 O 4 ), zinc white (ZnO), titanium white (TiO 2 ), glycine, etc. in that order to obtain a uniform mixture. To mix.
次ぎに、上記した硼酸、複合ポリマーエマルジョン及
び主剤を混合して本発明に係る塗布剤を製造する方法の
１例について説明すると、塗膜厚さが0.6〜1.0mmで塗布
面積が１m2の場合、主剤760gと複合ポリマーエマルジョ
ン760g,硼酸380g、それに軟水6gを入れて混合するもの
であり、この混合順序は、まず、複合ポリマーエマルジ
ョンを容器に入れ、次に主剤及び硼酸を徐々に加えなが
ら３分〜５分攪拌し、更に、蒸留水又は軟水又は水道水
を適量加えて希釈し、攪拌しながら製造するものであ
る。Next, an example of a method for producing the coating agent according to the present invention by mixing the above-mentioned boric acid, the composite polymer emulsion and the main agent will be explained. In the case where the coating film thickness is 0.6 to 1.0 mm and the coating area is 1 m 2 . 760 g of the main agent, 760 g of the composite polymer emulsion, 380 g of boric acid, and 6 g of soft water are added and mixed. First, the composite polymer emulsion is put in a container, and then the main agent and boric acid are gradually added to the mixture. After stirring for 5 minutes to 5 minutes, an appropriate amount of distilled water, soft water or tap water is added to dilute, and the mixture is manufactured with stirring.
なお、白セメントに代えて、ポルトランドセメントを
用いることもできる。Portland cement can be used instead of white cement.
以上のようにして製造された塗布剤を一般住宅の木製
土台に塗布して、硼酸の効力を調べた所、10年経過して
も効力を持続していた。When the coating agent produced as described above was applied to a wooden base of a general house and the effect of boric acid was examined, the effect was maintained even after 10 years.
これは、複合ポリマーエマルジョンと硼酸のみの場合
と比べて二倍の寿命であり、主剤との混合によって、硼
酸の溶出がさらに抑制されたことを示している。This is twice the life as compared with the case where only the composite polymer emulsion and boric acid are used, which shows that the elution of boric acid was further suppressed by mixing with the main agent.
Claims (2)
ン、メタクリル酸シクロヘキシルを主成分としてなる複
合ポリマーエマルジョンとを混合して製造し、前記硼酸
の溶出を緩慢に抑制したことを特徴とする硼酸を用いた
白蟻・ゴキブリ退治用塗布剤。1. A boric acid which is produced by mixing boric acid with a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as a main component to slowly suppress the elution of the boric acid. A coating agent for combating termites and cockroaches.
ン、メタクリル酸シクロヘキシルを主成分としてなる複
合ポリマーエマルジョンと、酸化珪素、酸化カルシウ
ム、酸化鉄を主成分とした主剤とを混合して製造し、前
記硼酸の溶出を緩慢に抑制したことを特徴とする硼酸を
用いた白蟻・ゴキブリ退治用塗布剤。2. Boric acid, a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as a main component, and a main agent containing silicon oxide, calcium oxide and iron oxide as main components are mixed to produce boric acid. A coating agent for combating termites and cockroaches using boric acid, which is characterized by slowly suppressing the elution of
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62026963A JP2517718B2 (en) | 1987-02-07 | 1987-02-07 | A coating agent for combating termites and cockroaches using boric acid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62026963A JP2517718B2 (en) | 1987-02-07 | 1987-02-07 | A coating agent for combating termites and cockroaches using boric acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63196503A JPS63196503A (en) | 1988-08-15 |
| JP2517718B2 true JP2517718B2 (en) | 1996-07-24 |
Family
ID=12207810
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62026963A Expired - Fee Related JP2517718B2 (en) | 1987-02-07 | 1987-02-07 | A coating agent for combating termites and cockroaches using boric acid |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2517718B2 (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0374796B1 (en) * | 1988-12-19 | 1994-10-19 | Dowelanco | Stable emulsion formulations of water-insoluble organic pesticides, their use and preparation |
| JP4177719B2 (en) * | 2002-06-28 | 2008-11-05 | 信夫 齋藤 | Anti-ant composition |
| AU2009236007B2 (en) * | 2009-11-11 | 2013-12-19 | Creepy Crawly Pest Control Pty Ltd | Insecticide Treated Insulation and Surrounds |
| AU2012100077B4 (en) * | 2009-11-11 | 2012-08-16 | Raydiate Pty Ltd | Method for the control of crawling insects |
| JP5729025B2 (en) * | 2011-03-08 | 2015-06-03 | 住友化学株式会社 | Agrochemical composition |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57174357A (en) * | 1981-04-20 | 1982-10-27 | Kikusui Kagaku Kogyo Kk | Paint composition |
| JPS6065043A (en) * | 1983-09-20 | 1985-04-13 | Yoshiyuki Ogushi | Preparation of surface coating material |
-
1987
- 1987-02-07 JP JP62026963A patent/JP2517718B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPS63196503A (en) | 1988-08-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US5746822A (en) | Ready-mixed setting type joint compound | |
| US6528563B2 (en) | Low solids, high strength multi-use gelled adhesives and adhesive mastics | |
| MXPA06014916A (en) | Composition and application of novel sprayable phosphate cement that bonds to styrofoam. | |
| US4391647A (en) | Spackeling composition | |
| JPH01301548A (en) | Production of mixture based on cement, meta-kaolin, glass fiber and polymer | |
| US4402752A (en) | Dry-set mortar composition having enhanced bonding characteristics | |
| JP2517718B2 (en) | A coating agent for combating termites and cockroaches using boric acid | |
| CA2456435A1 (en) | Composite light weight building panel and core material therefor | |
| US2934932A (en) | Hydraulic cement mortar compositions and methods of use | |
| US2890965A (en) | Additive for binding agents hardened by hydration and process of forming the same | |
| US6448317B1 (en) | Dual function gelled mastic adhesive and gelled mastic adhesive mortar | |
| JP2700133B2 (en) | Lining material containing asphalt emulsion and acrylate copolymer | |
| CN112777961A (en) | Multifunctional mortar bonding additive and preparation method thereof | |
| US1720032A (en) | Cellular plaster | |
| JPS6016855A (en) | Plaster composition | |
| JPS60228586A (en) | Waterproofing composition which prevent water from both oozing out of concrete body and penetrating through its surface thereinto and waterproofing method | |
| US1627952A (en) | Plastic cementitious material | |
| WO2001021689A1 (en) | Dual function gelled mastic adhesive and gelled mastic adhesive mortar | |
| JPH0377829B2 (en) | ||
| JP2799383B2 (en) | Electrical stimulus-responsive microcapsule-type cement admixture and method for controlling setting of cement | |
| US1015365A (en) | Size. | |
| RU2184097C1 (en) | Decorative color stucco dry mixture | |
| JPS608373A (en) | Instantly solidifying coating composition of two-pack type | |
| JP2004324180A (en) | Fire resisting construction and method of producing the same | |
| JPS63238171A (en) | Heat insulating material having dew condensation preventing function |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 19960206 |
|
| LAPS | Cancellation because of no payment of annual fees | ||
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313113 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R370 | Written measure of declining of transfer procedure |
Free format text: JAPANESE INTERMEDIATE CODE: R370 |