JPH03271206A - Antifungal, antibacterial and insecticidal emulsion and coating employed for building material - Google Patents
Antifungal, antibacterial and insecticidal emulsion and coating employed for building materialInfo
- Publication number
- JPH03271206A JPH03271206A JP2069827A JP6982790A JPH03271206A JP H03271206 A JPH03271206 A JP H03271206A JP 2069827 A JP2069827 A JP 2069827A JP 6982790 A JP6982790 A JP 6982790A JP H03271206 A JPH03271206 A JP H03271206A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- emulsion
- antibacterial
- insect repellent
- synthetic pyrethroid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 45
- 239000000839 emulsion Substances 0.000 title claims abstract description 25
- 230000000843 anti-fungal effect Effects 0.000 title claims abstract description 16
- 229940121375 antifungal agent Drugs 0.000 title claims abstract description 14
- 239000004566 building material Substances 0.000 title claims description 13
- 238000000576 coating method Methods 0.000 title abstract description 10
- 239000011248 coating agent Substances 0.000 title abstract description 8
- 230000000749 insecticidal effect Effects 0.000 title abstract description 6
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002253 acid Substances 0.000 claims abstract description 19
- 239000002728 pyrethroid Substances 0.000 claims abstract description 18
- 229960000686 benzalkonium chloride Drugs 0.000 claims abstract description 13
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 239000000077 insect repellent Substances 0.000 claims description 34
- 239000003973 paint Substances 0.000 claims description 21
- 239000004480 active ingredient Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 abstract description 18
- 241000233866 Fungi Species 0.000 abstract description 16
- 239000004570 mortar (masonry) Substances 0.000 abstract description 11
- 235000019645 odor Nutrition 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 9
- 239000004568 cement Substances 0.000 abstract description 7
- ZCVAOQKBXKSDMS-AQYZNVCMSA-N (+)-trans-allethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OC1C(C)=C(CC=C)C(=O)C1 ZCVAOQKBXKSDMS-AQYZNVCMSA-N 0.000 abstract description 5
- FMTFEIJHMMQUJI-NJAFHUGGSA-N 102130-98-3 Natural products CC=CCC1=C(C)[C@H](CC1=O)OC(=O)[C@@H]1[C@@H](C=C(C)C)C1(C)C FMTFEIJHMMQUJI-NJAFHUGGSA-N 0.000 abstract description 5
- 229940024113 allethrin Drugs 0.000 abstract description 5
- 238000005507 spraying Methods 0.000 abstract description 5
- 150000001875 compounds Chemical class 0.000 abstract description 4
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 abstract description 3
- 125000000217 alkyl group Chemical group 0.000 abstract description 3
- 229960005235 piperonyl butoxide Drugs 0.000 abstract description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 10
- 238000010276 construction Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
- 241000228245 Aspergillus niger Species 0.000 description 6
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 6
- 239000000428 dust Substances 0.000 description 6
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 239000011505 plaster Substances 0.000 description 5
- 235000002233 Penicillium roqueforti Nutrition 0.000 description 4
- 241000607768 Shigella Species 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- -1 balajichlorobenzene Chemical compound 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 3
- 239000004312 hexamethylene tetramine Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000002459 sustained effect Effects 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 241000228143 Penicillium Species 0.000 description 2
- 241000293871 Salmonella enterica subsp. enterica serovar Typhi Species 0.000 description 2
- 241000194017 Streptococcus Species 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000003429 antifungal agent Substances 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002538 fungal effect Effects 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical class CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- 241000235349 Ascomycota Species 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 244000063299 Bacillus subtilis Species 0.000 description 1
- 235000014469 Bacillus subtilis Nutrition 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 235000007516 Chrysanthemum Nutrition 0.000 description 1
- 244000189548 Chrysanthemum x morifolium Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000194036 Lactococcus Species 0.000 description 1
- 206010026749 Mania Diseases 0.000 description 1
- 241000187479 Mycobacterium tuberculosis Species 0.000 description 1
- 206010033799 Paralysis Diseases 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 241000531795 Salmonella enterica subsp. enterica serovar Paratyphi A Species 0.000 description 1
- 241000193998 Streptococcus pneumoniae Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Paints Or Removers (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、建築材料のセメント、モルタル、しつくい等
の塗壁材料、無機質あるいは有機質の建築用吹付は材料
、各種コーキング材やパテ等のシール材等に配合して使
用される防黴・防菌・防虫用乳剤、あるいは、建築材料
の表面に塗布して使用される防黴・防菌・防虫用塗料に
関する。[Detailed Description of the Invention] [Field of Industrial Application] The present invention is applicable to building materials such as cement, mortar, wall coating materials such as plaster, inorganic or organic spraying materials for construction, various caulking materials, putty, etc. This invention relates to anti-mildew, anti-bacterial and insect repellent emulsions that are used in combination with sealants, etc., and anti-mold, anti-bacterial and insect repellent paints that are used by being applied to the surfaces of building materials.
ビルディング、マンションその他のコンクリート建築物
や一般過程の木造建築物等においては、その外装や内装
に種々の黴が発生したり、あるいは、菌の繁殖や害虫の
発生が多々みられる。この様な問題は、例えば地下室、
ダストシュートの内側、台所、便所、浴場等の湿気や温
度の高い場所で多くみられ、従来においても例えば防黴
塗料や防虫塗料が使用されたり、あるいは、本発明者の
発明に係る特公昭４７−１３．５１７号公報にみられる
ように、ダストシュート製造原料のコンクリート混泥中
に防黴剤、防菌剤及び防虫剤を配合することが行われて
いる。BACKGROUND OF THE INVENTION In buildings, condominiums, other concrete structures, and wooden structures in general construction, various types of mold, fungal growth, and pests are often observed on the exterior and interior of buildings. Such problems can occur, for example, in basements,
It is often found inside dust chutes, in kitchens, toilets, bathrooms, and other places with high humidity and temperature, and in the past, for example, anti-mold paints and insect repellent paints have been used. As seen in Japanese Patent Application No. 13.517, a mold-proofing agent, a bactericidal agent, and an insect repellent are mixed into the concrete slurry used as a raw material for producing a dust chute.
しかしながら、前者の防黴塗料や防虫塗料は防黴作用あ
るいは防虫作用がそれぞれ単独で発揮されるだけであり
、防黴・防菌・防虫の各作用が要求される場合には、こ
れら防黴塗料や防虫塗料を併用しなければならず、対象
となる建築材料の表面に何度も塗料の塗布工程が必要に
なって作業が極めて面倒であるほか、防黴剤、防菌剤、
防虫剤の種類によっては併用できない場合もある。However, the former type of anti-mildew paints and insect repellent paints only have anti-fungal or insect-repellent effects, respectively, and if each of the anti-fungal, anti-bacterial and insect repellent effects is required, these anti-mildew paints In addition to requiring the use of antifungal and insect repellent paints, the process of applying paint to the surface of the target building material is extremely cumbersome, as well as the use of antifungal agents, antibacterial agents,
Depending on the type of insect repellent, it may not be possible to use them together.
また、後者の方法は、ダストシュート製造原料のコンク
リート混泥中に防黴剤、防菌剤及び防虫剤を配合するも
のであるが、有効成分として配合される粗製クレゾール
、バラジクロルベンゼン、ナフタリン、樟脳等を含有す
るため、これを使用して製造されたダストシュートから
これらの成分の臭気が発生し、ダストシュートにせっか
く防黴、防菌及び防虫の作用を付与しても、このダスト
シュートから薬品臭が生じるという問題があった。In addition, in the latter method, antifungal agents, antibacterial agents, and insect repellents are blended into the concrete slurry used as the raw material for producing dust chutes, but crude cresol, balajichlorobenzene, and naphthalene are blended as active ingredients. , camphor, etc., the odor of these components will be emitted from the dust chute manufactured using it. There was a problem that a chemical odor was generated.
このため、このダストシュート製造原料のコンクリート
混泥はその用途が制限され、しかも、特に真菌類の発生
が問題になる建物外壁用のセメントやモルタル、あるい
は、しっくい等の塗壁材料、無機質あるいは有機質の建
築用吹付は材料等においてはこれを長期に亘ってその発
生を防止することが難しく、建物の外観を損ねる重大な
原因になっていた。そして、この真菌類による汚染は、
更にこの真菌類を栄養源とするケナガコナダニ類の発生
を引起し、例えば天井からホトホト落ちてくる程、猛し
い汚染に襲われる場合もあったが、従来においては、む
しろ黴ぐらい発生するのは当たり前といった諦め感があ
るのが現状であった。For this reason, the use of concrete mixed mud, which is the raw material for producing dust chutes, is limited, and moreover, it can be used as cement or mortar for the exterior walls of buildings, where the growth of fungi is a problem, or as wall materials such as plaster, or as inorganic or organic materials. It is difficult to prevent this from occurring over a long period of time when using materials such as spraying for construction, and it has become a serious cause of spoiling the appearance of buildings. This fungal contamination is
In addition, this fungus causes an outbreak of woolly mites that feed on the fungus, and there have been cases of severe contamination, with spots falling from the ceiling, but in the past, it was only natural that mold would be produced. The current situation was that there was a sense of resignation.
そこで、本発明者は、薬品臭が可及的に少なく、しかも
、コンクリートやモルタル等の壁面に最も発生し易いと
されているアスペルギルス（Ａｓｐｅｒｇｉｌｌｕｓ）
属、タラトスポリウム（ｃ １ａｄｏｓｐｏｒ ｉｕｍ
）属等の黒コウジ菌や、ペニシリウム（Ｐｅｎ ｉｃ
ｉ １１ ｉｕｍ属等の青カビ菌に対して特に有効であ
り、長期間に亘って防黴、防菌及び防虫の優れた作用を
発揮する建築材料に使用する防黴・防菌・防虫用乳剤や
塗料について鋭意研究を重ねた結果、従来においては界
面活性剤として利用されているポリアミノモノカルボン
酸が黒コウジ菌や青カビ菌等の真菌類に対して強い殺菌
力を有し、しかも、このポリアミノモノカルボン酸は極
めて安定な化合物で長期間に亘って強い殺菌力を維持で
き、また、このポリアミノモノカルボン酸が殺菌力に優
れた塩化ベンザルコニウム、防黴力に優れたホルマリン
、防虫作用に優れたアレスリン等の合成ピレスロイド等
と併用使用することができることを見出し、更に、これ
らを混合して得られる防黴・防菌・防虫用乳剤を建物外
壁用のセメントやモルタル、あるいは、しっくい等の塗
壁材料、無機質あるいは有機質の建築用吹付は材料に配
合した場合、あるいは、これらを混合して得られる防黴
・防菌・防虫塗料が、徐放的に長期に亘ってそれぞれの
効力を発揮することを見出し、本発明を完成した。Therefore, the present inventor developed a method using Aspergillus, which has as little chemical odor as possible and is said to be most likely to occur on walls such as concrete and mortar.
Genus, Talatosporium (c 1adosporium)
) genus Aspergillus niger and Penicillium (Penicillium).
Anti-mildew, anti-bacterial and insect repellent emulsions for use in building materials that are particularly effective against blue mold fungi such as those of the 11ium genus and exhibit excellent anti-mold, anti-bacterial and insect repellent effects over a long period of time. As a result of extensive research into paints, we found that polyaminomonocarboxylic acid, which has traditionally been used as a surfactant, has strong bactericidal activity against fungi such as Aspergillus niger and Aeruginosa. Carboxylic acid is an extremely stable compound that can maintain strong bactericidal power over a long period of time, and this polyaminomonocarboxylic acid is also used in the production of benzalkonium chloride, which has excellent bactericidal power, formalin, which has excellent fungicidal power, and insect repellent power. It was discovered that it can be used in combination with synthetic pyrethroids such as allethrin, and furthermore, the anti-mildew, anti-bacterial and insect repellent emulsion obtained by mixing these can be used in cement and mortar for external walls of buildings, as well as in plaster and other coatings. When spraying for wall materials, inorganic or organic construction is mixed with materials, or the anti-mold, anti-bacterial and insect repellent paints obtained by mixing these exhibit their respective effects in a slow-release manner over a long period of time. They discovered this and completed the present invention.
従って、本発明の目的は、薬品臭が可及的に少なく、し
かも、建物外壁用のセメントやモルタル、あるいは、し
っくい等の塗壁材料、無機質あるいは有機質の建築用吹
付は材料に配合した場合に徐放的に長期に亘って防黴作
用、防菌作用、防虫作用を発揮する防黴・防菌・防虫用
乳剤を提供することにある。Therefore, it is an object of the present invention to have as little chemical odor as possible, and to make it possible to use cement and mortar for building exterior walls, wall coating materials such as plaster, and inorganic or organic construction sprays when mixed with materials. The object of the present invention is to provide an antifungal, antibacterial, and insecticidal emulsion that exhibits antifungal, antibacterial, and insecticidal effects in a sustained manner over a long period of time.
また、本発明の他の目的は、特に真菌類に対して優れた
防菌作用を発揮する建築材料のための防黴・防菌・防虫
用乳剤を提供することにある。Another object of the present invention is to provide an anti-mold, anti-bacterial and anti-insect emulsion for building materials which exhibits an excellent anti-bacterial effect, particularly against fungi.
更に、本発明の目的は、薬品臭が可及的に少なく、特に
真菌類に対して優れた防菌作用を発揮し、しかも、種々
の建築材料に使用でき、徐放的に長期に亘って防黴作用
、防菌作用、防虫作用を発揮する防黴・防菌・防虫塗料
を提供することにある。Furthermore, it is an object of the present invention to have as little chemical odor as possible, to exhibit an excellent antibacterial effect especially against fungi, to be usable in various building materials, and to be able to be released in a sustained manner over a long period of time. The purpose of the present invention is to provide an antifungal, antibacterial, and insect repellent paint that exhibits antifungal, antibacterial, and insecticidal effects.
すなわち、本発明は、防黴、防菌及び防虫の有効成分と
してポリアミノモノカルボン酸、塩化ベンザルコニウム
、合成ピレスロイド及びホルマリンを含有し、かつ、乳
化剤及び上記合成ピレスロイドの共力剤を含有する建築
材料に使用する防黴・防菌・防虫用乳剤であり、また、
これらの有効成分の使用量がポリアミノモノカルボン酸
０．３〜５．０重量％、塩化ベンザルコニウム０．１〜
１．５重量％、合成ピレスロイド０．５〜５．０重量％
、この合成ピレスロイドの共力剤３．０〜１５．０重量
％及びホルマリン２〜７重量％の範囲である防黴・防菌
・防虫用乳剤である。That is, the present invention provides a construction containing polyaminomonocarboxylic acid, benzalkonium chloride, synthetic pyrethroid, and formalin as active ingredients for antifungal, antibacterial, and insect repellent, and also contains an emulsifier and a synergist for the synthetic pyrethroid. It is an anti-mold, anti-bacterial and insect repellent emulsion used in materials, and
The amounts used of these active ingredients are 0.3 to 5.0% by weight of polyaminomonocarboxylic acid and 0.1 to 5.0% by weight of benzalkonium chloride.
1.5% by weight, synthetic pyrethroid 0.5-5.0% by weight
This is an antifungal, antibacterial, and insect repellent emulsion containing 3.0 to 15.0% by weight of the synergist of this synthetic pyrethroid and 2 to 7% by weight of formalin.
また、本発明は、このような有効成分を含有する建築材
料に使用する防黴・防菌・防虫塗料である。Furthermore, the present invention is an anti-mildew, anti-bacterial and anti-insect paint for use in building materials containing such active ingredients.
ここで、本発明で使用するポリアミノモノカルボン酸は
、下記一般式（Ｉ）〜（ＩＩＩ）（Ｒ−Ｎ−ＣＨ２ＣＨ
２）２Ｎ−ＣＨ２ＣＯＯＨ（ｆｆ）
（但し、式中Ｒはアルキル基を示す）で表される化合物
であり、例えば、上記一般式（Ｉ）で示されるポリアミ
ノモノカルボン酸系両性界面活性剤であるアノンＬＧ
（日本油脂■裂開品名）の殺菌性は、その３ＯＮ−水溶
液のフェノール系数が２５〜３５を示すものである。Here, the polyaminomonocarboxylic acid used in the present invention has the following general formulas (I) to (III) (R-N-CH2CH
2) A compound represented by 2N-CH2COOH(ff) (wherein R represents an alkyl group), for example, a polyaminomonocarboxylic acid-based amphoteric surfactant represented by the above general formula (I). Anon LG
The bactericidal property of (NOF ■Cracked Product Name) is that its 3ON-aqueous solution has a phenolic number of 25 to 35.
なお、１０分間で殺菌の繁殖しないポリアミノモノカル
ボン酸の最大希釈倍数を示すと次の通りである。The maximum dilution ratio of polyaminomonocarboxylic acid that does not cause sterilization in 10 minutes is as follows.
黒コウジ菌 １，０００倍
青カビ菌 ２０，０００倍
赤痢菌 １０，０００倍
パラ赤痢菌 ５，０００倍
チフス菌 ２０，０００倍
パラチフス菌 ５，０００倍
大腸菌 ５，０００倍
線膿菌 ５，０００倍
肺炎双球菌 １０，０００倍
枯草菌 ２０，０００倍
炭素菌製画 ５０，０００倍
連鎖状球菌 １，０００倍
乳酸球菌 ２，０００倍
黄色ブドウ状球菌 ２０，０００倍
結核菌 ２０，０００倍
白組菌 ２，０００倍
跡間菌 １０，０００倍
ケイ表皮菌 １０，０００倍
また、その毒性については、マウス経口致死量（ｇ／ｋ
ｇ）において、フェノールが０．２５であって、逆性石
鹸が０．５であるのに対し、上記ポリアミノモノカルボ
ン酸系両性界面活性剤は３０であり、その毒性が極めて
低いものである。Aspergillus niger 1,000 times Blue mold 20,000 times Shigella 10,000 times Shigella paralysis 5,000 times Salmonella typhi 20,000 times Salmonella paratyphi 5,000 times Escherichia coli 5,000 times Pseudomonas Streptococcus 5,000 times Diplococcus pneumoniae 10,000x Bacillus subtilis 20,000x carbon bacteria 50,000x Streptococcus 1,000x Lactococcus 2,000x Staphylococcus aureus 20,000x Mycobacterium tuberculosis 20,000x white Bacteria: 2,000 times Remaining bacteria: 10,000 times Silica epidermidis: 10,000 times
In g), the toxicity of the polyaminomonocarboxylic acid-based amphoteric surfactant is 30, whereas that of phenol is 0.25 and that of inverse soap is 0.5, indicating that its toxicity is extremely low.
このポリアミノモノカルボン酸の使用量は、通常０．３
〜５．０重量％、好ましくは０．５〜２゜０重量％の範
囲である。The amount of polyaminomonocarboxylic acid used is usually 0.3
-5.0% by weight, preferably 0.5-2.0% by weight.
更に、上記塩化ペンサルコニウムは、下記一般式
（３
％式％
（但し、式中Ｒはアルキル基を示す）で表される化合物
であり、殺菌剤、消毒剤、防腐剤、創傷洗浄剤等として
、広く使用されているものであり、その１０分間で細菌
の繁殖しない液の最大希釈倍数を示すと、以下の通りで
ある。Furthermore, the above-mentioned pensalkonium chloride is a compound represented by the following general formula (3% formula% (in the formula, R represents an alkyl group), and is used as a bactericidal agent, disinfectant, preservative, wound cleansing agent, etc. It is widely used as a diluent, and the maximum dilution ratio of the solution that does not allow bacteria to grow in 10 minutes is as follows.
赤痢菌 ３０，０００倍
チフス菌 ”１８，０００倍大腸菌
２０，０００倍
黄色ブドウ状球菌 ２５，０００倍
白癖菌 １，０００倍
上記ポリアミノモノカルボン酸及び塩化ベンザルコニウ
ムの最大希釈倍数を比較して明らかなように、前者のポ
リアミノモノカルボン酸は白組菌、跡間菌、青カビ等の
黴類に対する殺菌力に優れ、また、後者の塩化ベンザル
コニウムは黄色ブドウ状球菌、大腸菌、赤痢菌等の細菌
類に対する殺菌力に優れている。Shigella 30,000 times Salmonella Typhi 18,000 times Escherichia coli
20,000 times Staphylococcus aureus 25,000 times White mania 1,000 times It has excellent bactericidal activity against molds such as Ascomycota, Atomibacterium, and Blue Mold, and the latter, benzalkonium chloride, has excellent bactericidal activity against bacteria such as Staphylococcus aureus, Escherichia coli, and Shigella.
この塩化ベンザルコニウムの使用量は、通常０゜１〜１
．５重量％、好ましくは０．２〜１．０重量％の範囲で
ある。The amount of benzalkonium chloride used is usually 0°1 to 1
．． 5% by weight, preferably in the range of 0.2-1.0% by weight.
更に、本発明においては、上記の他に、合成ピレスロイ
ドを０．５〜５．０重量％の範囲で及びホルマリンを２
〜７重量％の範囲で含有し、かつ、乳化剤及び上記合成
ピレスロイドの共力剤を含有する。Furthermore, in the present invention, in addition to the above, synthetic pyrethroids are added in a range of 0.5 to 5.0% by weight, and formalin is added in an amount of 2% by weight.
It contains in the range of 7% by weight, and also contains an emulsifier and a synergist for the synthetic pyrethroid.
合成ピレスロイドとしては、例えば代表的には第−菊酸
のエステルとして優れた防虫作用を有するピレスロイド
系アレスリン（ａｌｌｅｔｈｒｉｎ）等があり、その共
力剤しては、代表的にはピペニールブトキシド（ｐｉｐ
ｅｎｙｌ ｂｕｔｏｘｉｄｅ）があり、これらは通常そ
の重量比１：１０の混合体として使用される。Synthetic pyrethroids include, for example, pyrethroid allethrin, which is typically an ester of chrysanthemum acid and has an excellent insect repellent effect, and its synergist is typically pipenyl butoxide (pip).
enyl butoxide), which are usually used as a mixture in a weight ratio of 1:10.
また、ホルマリンは、優れた防黴作用、殺菌作用を得る
上で併用することが必須であるが、薬品臭があるのでそ
の使用量は上記２〜７重量％の範囲内とする必要がある
。更に、乳化剤としては、例えば、カルボキシメチルセ
ルロース、アラビアゴム、アルギン酸塩、ポリアクリル
酸塩、酢酸ビニル等の単体又はこれら２種以上の混合物
を挙げることができ、更に、この乳化剤の助剤として、
例えばヘキサメチレンテトラミンを１〜６重量％の範囲
内で添加してもよい。Furthermore, it is essential to use formalin in combination in order to obtain excellent antifungal and bactericidal effects, but since it has a chemical odor, the amount used must be within the above range of 2 to 7% by weight. Furthermore, examples of emulsifiers include carboxymethylcellulose, gum arabic, alginates, polyacrylates, vinyl acetate, etc. alone or mixtures of two or more thereof, and further, as an auxiliary agent for this emulsifier,
For example, hexamethylenetetramine may be added in an amount of 1 to 6% by weight.
本発明の防黴・防菌・防虫用乳剤及び塗料を調製するに
は、上記有効成分や乳化剤及び合成ピレスロイドの共力
剤を水中に添加し、弱酸性の条件下で混合して乳剤とす
るか、あるいは、塗料基材中に添加し、均一に混合して
塗料とすればよい。To prepare the anti-mold, anti-bacterial and insect repellent emulsions and paints of the present invention, the above active ingredients, emulsifiers and synthetic pyrethroid synergists are added to water and mixed under weakly acidic conditions to form an emulsion. Alternatively, it may be added to a paint base material and mixed uniformly to form a paint.
本発明の防黴・防菌・防虫用乳剤及び塗料は、その有効
成分であるポリアミノカルボン酸と塩化ベンザルコニウ
ムとが殺菌剤として作用し、特に黒コウジ菌や青カビ菌
に対して優れた防黴作用、殺菌作用を発揮するほか、合
成ピレスロイドが優れた殺虫作用を発揮する。The antifungal, antibacterial, and insect repellent emulsions and coatings of the present invention have active ingredients such as polyaminocarboxylic acid and benzalkonium chloride that act as bactericidal agents, and are particularly effective against Aspergillus niger and Aeruginosa. In addition to having fungicidal and bactericidal effects, the synthetic pyrethroids have excellent insecticidal effects.
また、本発明の防黴・防菌・防虫用乳剤及び塗料は、空
気中に放置しても数十余年に亘って防黴・防菌・防虫の
作用を発揮するが、これは、その乳剤中であるいは塗料
組成物中で、防黴・防菌・防虫の有効成分であるポリア
ミノモノカルボン酸、塩化ペンサルコニウム、合成ピレ
スロイドが、網目構造状の中にマイクロカプセル状に、
又は、ポリマー状に分散し、これが湿度、水、光、温度
等の環境変化により徐々に破壊され、長期間に亘って徐
放的に放散されるためであると考えられる。Furthermore, the anti-mildew, anti-bacterial and insect repellent emulsions and paints of the present invention exhibit anti-mildew, anti-bacterial and insect repellent effects for over several decades even when left in the air; In the emulsion or paint composition, polyaminomonocarboxylic acid, pensalkonium chloride, and synthetic pyrethroids, which are active ingredients for mold prevention, fungus prevention, and insect repellency, are microcapsulated in a network structure.
Alternatively, it is thought that this is because the polymer is dispersed in the form of a polymer, which is gradually destroyed by environmental changes such as humidity, water, light, and temperature, and is released in a sustained manner over a long period of time.
以下、実施例に基づいて、本発明を具体的に説明する。 Hereinafter, the present invention will be specifically explained based on Examples.
実施例１
以下の処方に従って、コンクリート外壁を形成するコン
クリートや、室内の壁面を形成するモルタルに配合して
使用するための防黴・防菌・防虫用乳剤を調製した。Example 1 An anti-mold, anti-bacterial and anti-insect emulsion was prepared according to the following formulation to be used by mixing it with concrete for forming external concrete walls and mortar for forming indoor walls.
（乳剤の処方）
ポリアミノモノカルボン酸３ＯＮ−水溶液 ５〇−塩化
ペンザルコニウム１０Ｘ−水溶液 ５０１ｎｌヘキ
サメチレンテトラミン ３０ｇホルマリン
１００７ＩＴｌカルボキシメチ
ルセルロース ２０ｇ水
１，６００１１１１合成ピレス
ロイド（アレスリン等） ２０７７＋７！共力剤
１８０１ｎｌ先ず、ヘキ
サメチレンテトラミン３０ｇを微細化し、これにカルボ
キシメチルセルロース２０ｇを加えて均一に混合し、更
にポリアミノモノカルボン酸３ＯＮ−水溶液５０−と塩
化ベンザルコニウム１０％−水溶液５０−を水２００−
に混合したものとを一気に混合し、充分に攪拌混合して
全体が均一になったところで、更に２００−の水を加え
て均一に混合し、更に２００−の水を加えて均一に混合
した。(Formulation of emulsion) Polyaminomonocarboxylic acid 3ON-aqueous solution 50-penzalkonium chloride 10X-aqueous solution 501nl hexamethylenetetramine 30g formalin
1007ITl carboxymethylcellulose 20g water
1,6001111 Synthetic pyrethroids (allethrin, etc.) 2077+7! Synergist 1801nl First, 30g of hexamethylenetetramine was micronized, 20g of carboxymethylcellulose was added thereto, and mixed uniformly.Furthermore, 50% of an aqueous solution of polyaminomonocarboxylic acid 3ON and 50% of a 10% benzalkonium chloride solution were mixed with water. 200-
When the mixture was thoroughly stirred and mixed until the whole was uniform, 200-ml water was further added and mixed uniformly, and further 200-ml water was added and mixed uniformly.
この様にして得られた混合液中にホルマリン１００−を
加えて攪拌した後、合成ピレスロイドのアレスリンと共
力剤とを重量比１：１０の割合で混合して得られたもの
２００−を加え、全体をよく攪拌した後、残りの水１．
０００−を加えて充分に攪拌混合し乳剤とした。After adding formalin 100- to the mixture thus obtained and stirring, 200-, which was obtained by mixing allethrin, a synthetic pyrethroid, and a synergist at a weight ratio of 1:10, was added. , After stirring the whole well, add the remaining water 1.
000- was added and thoroughly stirred and mixed to form an emulsion.
次に、上記のようにして調製した防黴・防菌・防虫用乳
剤１００重量部を使用し、セメント１゜０重量部、砂３
００重量部、砂利５００重量部及び水２００重量部と共
に混練して外装用コンクリートを調製した。Next, using 100 parts by weight of the anti-mildew, anti-bacterial and insect repellent emulsion prepared as described above, 1.0 parts by weight of cement and 3 parts by weight of sand.
00 parts by weight, 500 parts by weight of gravel, and 200 parts by weight of water to prepare exterior concrete.
また、上記のようにして調製した防黴・防菌・防虫用乳
剤を全体の１０重量％程度となるようにモルタル中に配
合して吹付は材を調製した。Further, the anti-mildew, anti-bacterial and insect repellent emulsion prepared as described above was blended into mortar at a concentration of about 10% by weight to prepare a sprayed material.
この様にして調製した外装用コンクリートとモルタル吹
付は材について、これらを厚さ０．５〜１ ａｍ程度に
塗装し、放置して黒コウジ菌、青カビ菌その他の真菌類
の発生を調べたところ、これら真菌類の発生は認められ
なかった。また、これら外装用コンクリートとモルタル
吹付は材とを使用し、ダストシュートを製造し、長期間
に亘って黒コウジ菌、青カビ菌その他の真菌類の発生の
ほか、悪臭を発生状況、蝿や姐の発生状況を調べた結果
、真菌類の発生、悪臭を発生、蝿、姐等の害虫の発生を
効果的に防止できることが判明した。The exterior concrete and mortar sprayed materials prepared in this manner were coated to a thickness of approximately 0.5 to 1 am, and left to stand to examine the occurrence of Aspergillus niger, blue mold, and other fungi. However, no occurrence of these fungi was observed. In addition, these exterior concrete and mortar spraying materials are used to manufacture dust chutes, which over a long period of time can prevent the growth of Aspergillus niger, blue mold, and other fungi, as well as odor, flies, and insects. As a result of investigating the occurrence of fungi, it was found that it can effectively prevent the occurrence of fungi, bad odors, and pests such as flies and insects.
本発明の防黴・防菌・防虫用乳剤は、薬品臭が可及的に
少なく、しかも、建物外壁用のセメントやモルタル、あ
るいは、しっくい等の塗壁材料、無機質あるいは有機質
の建築用吹付は材料に配合した場合、徐放的に長期に亘
って防黴作用、防菌作用、防虫作用を発揮し、特に真菌
類に対して優れた防菌作用を発揮するため、建物外壁等
をこの真菌類等の汚染から長期に亘って保護することが
できる。また、これを塗料用に調製すれば、例えば建築
用木材の表面にこの防黴・防菌・防虫用塗料を塗布する
ことにより、黴や菌類あるいは害虫に強く、しかも、薬
品臭が少ない建築材料とすることができる。The anti-mold, anti-bacterial and insect repellent emulsion of the present invention has as little chemical odor as possible, and is suitable for use in cement and mortar for external walls of buildings, wall coating materials such as plaster, and inorganic or organic construction sprays. When added to materials, it exerts anti-mold, anti-bacterial and insect-repellent effects over a long period of time in a slow-release manner, and has particularly excellent anti-bacterial effects against fungi. can provide long-term protection from contamination such as In addition, if this is prepared as a paint, for example, by applying this anti-mold, anti-bacterial, and insect-repellent paint to the surface of construction wood, it can be used as a building material that is resistant to mold, fungi, and pests, and has less chemical odor. It can be done.
Claims (4)
モノカルボン酸、塩化ベンザルコニウム、合成ピレスロ
イド及びホルマリンを含有し、かつ、乳化剤及び上記合
成ピレスロイドの共力剤を含有することを特徴とする建
築材料に使用する防黴・防菌・防虫用乳剤。(1) Contains polyaminomonocarboxylic acid, benzalkonium chloride, synthetic pyrethroid, and formalin as active ingredients for antifungal, antibacterial, and insect repellent, and also contains an emulsifier and a synergist for the synthetic pyrethroid. Anti-mildew, anti-bacterial and insect repellent emulsion used in building materials.
％、塩化ベンザルコニウムを０．１〜１．５重量％、合
成ピレスロイドを０．５〜５．０重量％、この合成ピレ
スロイドの共力剤を３．０〜１５．０重量％及びホルマ
リンを２〜７重量％の範囲で含有する請求項１記載の建
築材料に使用する防黴・防菌・防虫用乳剤。(2) 0.3 to 5.0% by weight of polyaminomonocarboxylic acid, 0.1 to 1.5% by weight of benzalkonium chloride, and 0.5 to 5.0% by weight of synthetic pyrethroid. The anti-mold, anti-bacterial and anti-insect emulsion for use in building materials according to claim 1, which contains a synergist in an amount of 3.0 to 15.0% by weight and formalin in an amount of 2 to 7% by weight.
モノカルボン酸、塩化ベンザルコニウム、合成ピレスロ
イド及びこの合成ピレスロイドの共力剤並びにホルマリ
ンを含有することを特徴とする建築材料に使用する防黴
・防菌・防虫用塗料。(3) Anti-fungal, antibacterial and insect repellent active ingredients for use in building materials characterized by containing polyaminomonocarboxylic acid, benzalkonium chloride, a synthetic pyrethroid, a synergist for this synthetic pyrethroid, and formalin. Anti-mold, antibacterial, and insect repellent paint.
％、塩化ベンザルコニウムを０．１〜１．５重量％、合
成ピレスロイドを０．５〜５．０重量％、この合成ピレ
スロイドの共力剤を３．０〜１５．０重量％及びホルマ
リンを２〜７重量％の範囲で含有する請求項３記載の建
築材料に使用する防黴・防菌・防虫用塗料。(4) 0.3 to 5.0% by weight of polyaminomonocarboxylic acid, 0.1 to 1.5% by weight of benzalkonium chloride, and 0.5 to 5.0% by weight of synthetic pyrethroid. The anti-mildew, anti-bacterial and insect repellent paint for use in building materials according to claim 3, which contains a synergist in an amount of 3.0 to 15.0 weight % and formalin in an amount of 2 to 7 weight %.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2069827A JPH03271206A (en) | 1990-03-22 | 1990-03-22 | Antifungal, antibacterial and insecticidal emulsion and coating employed for building material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2069827A JPH03271206A (en) | 1990-03-22 | 1990-03-22 | Antifungal, antibacterial and insecticidal emulsion and coating employed for building material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03271206A true JPH03271206A (en) | 1991-12-03 |
Family
ID=13413986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2069827A Pending JPH03271206A (en) | 1990-03-22 | 1990-03-22 | Antifungal, antibacterial and insecticidal emulsion and coating employed for building material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03271206A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0664081A3 (en) * | 1994-01-20 | 1996-10-02 | Hoechst Schering Agrevo Gmbh | Synergistic combinations of ammonium salts. |
| JP2002114946A (en) * | 2000-10-06 | 2002-04-16 | Takeda Chem Ind Ltd | Coating composition |
| GB2397021A (en) * | 2002-12-30 | 2004-07-14 | Inst Medical Res | Insecticidal Paint Composition |
| JP2007032073A (en) * | 2005-07-26 | 2007-02-08 | Matsushita Electric Works Ltd | House structure |
-
1990
- 1990-03-22 JP JP2069827A patent/JPH03271206A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0664081A3 (en) * | 1994-01-20 | 1996-10-02 | Hoechst Schering Agrevo Gmbh | Synergistic combinations of ammonium salts. |
| JP2002114946A (en) * | 2000-10-06 | 2002-04-16 | Takeda Chem Ind Ltd | Coating composition |
| GB2397021A (en) * | 2002-12-30 | 2004-07-14 | Inst Medical Res | Insecticidal Paint Composition |
| GB2397021B (en) * | 2002-12-30 | 2006-09-13 | Inst Medical Res | Insecticidal paint composition |
| JP2007032073A (en) * | 2005-07-26 | 2007-02-08 | Matsushita Electric Works Ltd | House structure |
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