JPS63199757A - Lining material containing asphalt emulsion and acrylic ester copolymer - Google Patents
Lining material containing asphalt emulsion and acrylic ester copolymerInfo
- Publication number
- JPS63199757A JPS63199757A JP3428487A JP3428487A JPS63199757A JP S63199757 A JPS63199757 A JP S63199757A JP 3428487 A JP3428487 A JP 3428487A JP 3428487 A JP3428487 A JP 3428487A JP S63199757 A JPS63199757 A JP S63199757A
- Authority
- JP
- Japan
- Prior art keywords
- lining material
- asphalt emulsion
- acrylic ester
- ester copolymer
- emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 43
- 239000010426 asphalt Substances 0.000 title claims abstract description 30
- 239000000463 material Substances 0.000 title claims abstract description 30
- 229920001577 copolymer Polymers 0.000 title claims abstract description 16
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000002131 composite material Substances 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000002075 main ingredient Substances 0.000 claims description 6
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000292 calcium oxide Substances 0.000 claims description 4
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 4
- -1 acrylic ester Chemical class 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 7
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical class C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 abstract description 5
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000377 silicon dioxide Substances 0.000 abstract description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 238000003756 stirring Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 239000004568 cement Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000005856 abnormality Effects 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000004816 latex Substances 0.000 description 4
- 229920000126 latex Polymers 0.000 description 4
- 239000004570 mortar (masonry) Substances 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 239000008234 soft water Substances 0.000 description 4
- 239000011787 zinc oxide Substances 0.000 description 4
- 235000014692 zinc oxide Nutrition 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000004471 Glycine Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- 238000004078 waterproofing Methods 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical group [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）産業上の利用分野
本発明は、土木、建築等の分野において用いることがで
きる、特に、土木建築構造物の防水材・接着材、道路橋
の防水材・防錆材、道路塗装下地の防水材、法面保護防
水材、パイプ・配管等の消音材、各種建材等に塗布また
は充填して用いる吸音・遮音材、接着材等として用いる
ことができるライニング材に関する。Detailed Description of the Invention (a) Industrial Application Field The present invention can be used in the fields of civil engineering, architecture, etc., and is particularly applicable to waterproofing materials and adhesives for civil engineering and building structures, and waterproofing materials and adhesives for road bridges. Lining materials that can be used as rust preventive materials, waterproof materials for road painting bases, slope protection waterproof materials, sound deadening materials for pipes, piping, etc., sound absorbing and sound insulating materials applied or filled with various building materials, adhesives, etc. Regarding.
（ロ）従来技術
従来、アスファルトが安価に入手できることに着目して
、アスファルトに骨材等を混合して、道路舗装材や塗装
材として用いることが一般的に知られているが、アスフ
ァルトそのものは、常温では硬くて脆い物質であるため
、使用に際しては、いったん加熱溶解して使用しなけれ
ばならず、また、防水性の面でも不充分であった。(B) Prior art Conventionally, it has been generally known that asphalt is available at a low price and is used as a road paving material or coating material by mixing aggregates with asphalt.However, asphalt itself is Since it is a hard and brittle substance at room temperature, it must be heated and melted before use, and it is also insufficient in terms of waterproofness.
かかるアスファルトの欠点を克服するべく、常温でも軟
化し、かつ防水性もアスファルト単体の場合に比較して
かなり改善した、いわゆる、ゴムアスファルトが開発さ
れ、ライニング材として利用されているが、これは未だ
耐熱性や耐寒性、即ち、耐候性に乏しく、土木・建築等
のように苛酷な使用条件下におけるライニング材として
は、充分なものとはいえなかった。In order to overcome these drawbacks of asphalt, so-called rubber asphalt, which softens even at room temperature and has considerably improved waterproof properties compared to asphalt alone, was developed and is used as a lining material, but this is still used as a lining material. It lacks heat resistance and cold resistance, that is, weather resistance, and cannot be said to be sufficient as a lining material under severe usage conditions such as in civil engineering and construction.
本発明はこのような従来技術が有する問題点を解決する
ことができるライニング材を提供することを目的とする
。An object of the present invention is to provide a lining material that can solve the problems of the prior art.
（八）問題点を解決するための手段
本発明は、アスファルト乳剤と、少なくともアクリル酸
エステル共重合体を主成分としてなる複合ポリマーエマ
ルジッンとを混合して製造したアスファルト乳剤とアク
リル酸エステル共重合体とを含有するライニング材、及
び、アスファルト乳剤と、少なくともアクリル酸エステ
ル共重合体を主成分としてなる複合ポリマーエマルジョ
ンと、酸化珪素、酸化カルシウム、酸化鉄を主成分とし
た主剤とを混合して製造したアスファルト乳剤とアクリ
ル酸エステル共重合体とを含有するライニング材に係る
ものである。(8) Means for solving the problem The present invention provides an asphalt emulsion and an acrylic ester copolymer produced by mixing an asphalt emulsion and a composite polymer emulsion containing at least an acrylic ester copolymer as a main component. A lining material containing a polymer, an asphalt emulsion, a composite polymer emulsion containing at least an acrylic ester copolymer as a main component, and a main agent containing silicon oxide, calcium oxide, and iron oxide as main components. The invention relates to a lining material containing an asphalt emulsion and an acrylic ester copolymer produced by the above method.
（ニ）作用及び効果
■アスファルト乳剤に充分な耐寒性を有するアクリル酸
エステル共重合体を含有する複合ポリマーエマルジョン
を混合することによって、ライニング材の耐候性を向上
することができる。(d) Actions and Effects - The weather resistance of the lining material can be improved by mixing the asphalt emulsion with a composite polymer emulsion containing an acrylic ester copolymer having sufficient cold resistance.
■アスファルト乳剤に充分な耐寒性を有するアクリル酸
エステル共重合体を含有する複合ポリマーエマルジョン
と充分な耐熱性を有する酸化珪素、酸化カルシウム、酸
化鉄を主成分とした主剤を混入することによって、さら
にライニング材の耐候性を向上することができる。■By mixing into the asphalt emulsion a composite polymer emulsion containing an acrylic ester copolymer with sufficient cold resistance and a main ingredient mainly composed of silicon oxide, calcium oxide, and iron oxide that have sufficient heat resistance, The weather resistance of the lining material can be improved.
（、（−、）実施例
以下、添付図に示す実施例に基づいて、本発明を詳説す
る。(, (-,) EXAMPLES The present invention will be explained in detail below based on examples shown in the accompanying drawings.
（第１実施例）
９０重量％のアスファルト乳剤と１０％のアクリル酸エ
ステル共重合体を含有する複合ポリマーエマルジョンと
を混合して、本発明に係るライニング材を製造した。(First Example) A lining material according to the present invention was produced by mixing 90% by weight of an asphalt emulsion and a composite polymer emulsion containing 10% of an acrylic acid ester copolymer.
ここに、アスファルト乳剤とは、アスファルトセメント
を少量の乳化剤を含んでいる水中に分散させたものであ
る。Asphalt emulsion is one in which asphalt cement is dispersed in water containing a small amount of emulsifier.
また、アクリル酸エステル共重合体を含有する複合ポリ
マーエマルジョンとして、カルボキシ変性スチレンブタ
ジェン、メタクリル酸シクロヘキシルを主成分としでな
る複合ポリマーエマルジョンを用いた。Further, as a composite polymer emulsion containing an acrylic acid ester copolymer, a composite polymer emulsion containing carboxy-modified styrene butadiene and cyclohexyl methacrylate as main components was used.
かかる複合ポリマーエマルジョンの配合例及び配合順序
を、２ ｆｆ１ｌ説明すると、例１）
（重ｆ１）カルボキシ変性スチレンブ
タジェン １３ ％メタクリル酸シクロヘキシルー
５６ ％スチレン重合体
脂肪酸ソーダ石鹸 １ ％水
３０ ％この配
合順序は、まず、蒸留水または軟水に脂肪酸ソーダ石鹸
を入れて溶解し、次にカルボキシ変性スチレンブタジェ
ンを徐々に加えて混合、攪拌し、次ぎにメタクリル酸シ
クロヘキシル−スチレンブタジェン共重合体ラテックス
を徐々に加えて、混合攪拌し、各ポリマーの水中分散液
とする。Example 1)
(Heavy f1) Carboxy-modified styrene butadiene 13% cyclohexyl methacrylate
56% styrene polymer fatty acid soda soap 1% water
30% This blending order is as follows: first, add fatty acid soda soap to distilled or soft water and dissolve it, then gradually add carboxy-modified styrene-butadiene, mix and stir, and then add cyclohexyl methacrylate-styrene-butadiene together. Gradually add the polymer latex and mix and stir to obtain a dispersion of each polymer in water.
例２） （重量）カ
ルボキシ変性スチレンブタジェン １３ ％スチレン
２８ ％メタクリル酸シ
クロヘキシル ２８ ％脂肪酸ソーダ石鹸
１ ％水
３０ ％この配合順序は、まず、蒸留
水または軟水に脂肪酸ソーダ石鹸を入れて溶解し、次に
カルボキシ変性スチレンブタジェンを徐々に加えて混合
、攪拌し、次ぎにスチレンラテックスを加えて攪拌し、
次にメタクリル酸シクロヘキシルを徐々に加えて、混合
攪拌し、各ポリマーの水中分散液とする。Example 2) (Weight) Carboxy modified styrene butadiene 13% styrene 28% cyclohexyl methacrylate 28% fatty acid soda soap
1% water
30% This blending order is: first, add fatty acid soda soap to distilled water or soft water and dissolve it, then gradually add carboxy-modified styrene butadiene, mix and stir, then add styrene latex and stir,
Next, cyclohexyl methacrylate is gradually added and mixed and stirred to form a dispersion of each polymer in water.
次に、上記したアスファルト乳剤と複合ポリマーエマル
ジａンを混合してライニング材を製造すル方法の１例に
ついて説明すると、アスファルト乳剤９００ｇと複合ポ
リマーエマルジッン１００ｇとを混合するものであり、
この混合順序は、まず、複合ポリマーエマルジッンを容
器に入れ、次に同複合ポリマーエマルジッンにアスファ
ルト乳剤を徐々に加えながら３分〜５分攪拌し・更に・
蒸留水又は軟水又は水道水を適量加えて希釈し、攪拌し
ながら施工する。Next, an example of a method for manufacturing a lining material by mixing the above-mentioned asphalt emulsion and composite polymer emulsion a is described. 900 g of asphalt emulsion and 100 g of composite polymer emulsion are mixed,
The mixing order is as follows: First, put the composite polymer emulsion into a container, then gradually add the asphalt emulsion to the same composite polymer emulsion and stir for 3 to 5 minutes.
Dilute by adding an appropriate amount of distilled water, soft water, or tap water, and apply while stirring.
なお、前記各ラテックスの固形分は全て約４０〜５０％
程度のものを用いている。The solid content of each latex is approximately 40 to 50%.
I am using something of a certain degree.
このように製造されたライニング材は、充分な耐熱性、
耐寒性等の耐候性、接着性、防水性等を示した。The lining material manufactured in this way has sufficient heat resistance,
It exhibited weather resistance such as cold resistance, adhesion, and waterproof properties.
なお、本実施例に係るライニング材の物理特性に関して
試験を行ったので、その結果を以下に示す。Note that tests were conducted regarding the physical properties of the lining material according to this example, and the results are shown below.
〔耐候性〕 コンクリート壁に付着させた後、表面温度
を５０℃に加熱しても、垂れる
ことがなく、また、雰囲気温度を一
３０℃にしても、表面にひび割れを生
じなかった。[Weather resistance] After being attached to a concrete wall, even when the surface temperature was heated to 50°C, it did not sag, and even when the ambient temperature was -30°C, no cracks were formed on the surface.
対コンクリート１１．０〜１９．２７ ｋｇｆ／ａＪ〔
耐屈曲性〕
ＪＩＳ−に−５４００）タン塗布０．３鴫心棒２■
１８０°折り曲げ異常なし
〔衝撃試験〕
ＪＩＳ−Ｇ−３４９２５５０ｇ １１球２．４−落下
異常なし
〔透水量〕
ＪＩＳ−＾−１４０４水圧３ ｋｇ／−モルタルとの比
較
１時間後 モルタル ２３．０ ｇ
本実施例 １．１ 。Against concrete 11.0-19.27 kgf/aJ [
Flexibility] JIS-5400) Tan coated 0.3 tin core 2 ■ 180° bending no abnormalities [Impact test] JIS-G-3492550g 11 balls 2.4 - No falling abnormalities [Water permeability] JIS-＾- Comparison with 1404 water pressure 3 kg/- mortar After 1 hour Mortar 23.0 g Present Example 1.1.
〔第２実施例〕
５重量％のアスファルト乳剤と、１５重量％のアクリル
酸エステル共重合体を含有する複合ポリマーエマルジツ
ンと、８０重量％の酸化珪素、酸化カルシウム、酸化鉄
を主成分とした主剤とを混合して、本発明に係るライニ
ング材を製造した。[Second Example] A composite polymer emulsion containing 5% by weight of an asphalt emulsion, 15% by weight of an acrylic acid ester copolymer, and 80% by weight of silicon oxide, calcium oxide, and iron oxide as main components. A lining material according to the present invention was produced by mixing the main ingredients obtained above.
本実施例では、アスファルト乳剤と複合ポリマーエマル
ジョンは、第１実施例と同一ノモノヲ用いた。In this example, the same asphalt emulsion and composite polymer emulsion were used as in the first example.
また、アスファルト乳剤及び複合ポリマーエマルジョン
と混合すべき主剤の配合例及び配合手順について説明す
ると、配合例は、
（重量）
白色セメント １８．０ ％珪砂
（Ｓ ｉ ０２ ） ７１．０ ％鉄
粉（Ｆ ｅ３０４ ） ０．２ ％フ
ライアッシェ １０．０ ％亜鉛華（
ＺｎＯ） Ｑ、１ ％チタン白（Ｔ
ｉＯ２） ０．１ ％グリシン偽
０．６ ％であり、上記白色セメ
ントの成分重量比は、（ｆｆｉｌ）
Ｃａ Ｏ６５，４％
５ｉ０２ ２３．１ ％Ｆｅ
２ Ｑ３ ０．２ ％Ｉ ｇ
ｌ ｏ ｓ ｓ ２．７ ％ｉ
ｎ ｓ ｏ １
０．２ ％Ａｌｚ０３
４．３ ％Ｍ ｇ Ｏ０，６％
ＳＯ３２，８％
その他 ０．７ ％であり
、上記主剤の配合手順は、まず珪砂を焼いて有機物を取
り除き、粒度を５０〜１５０μ鋤に整え、この珪砂をミ
キサーに投入し、白色セメントを徐々に加えて混合させ
、更に、鉄粉（Ｆｅ２Ｏ２）、フライアッシェ、亜鉛華
（ＺｎＯ）、チタン白（Ｔ １０２ ） 、グリシン他
の順で加えながら、均一に成るように混合する。In addition, to explain the blending example and blending procedure of the main ingredient to be mixed with the asphalt emulsion and composite polymer emulsion, the blending example is as follows: (by weight) White cement 18.0% Silica sand (S i 02 ) 71.0% Iron powder (F e304) 0.2% fly ash 10.0% zinc white (
ZnO) Q, 1% titanium white (T
iO2) 0.1% glycine sham
0.6%, and the component weight ratio of the above white cement is (ffil) Ca O65.4% 5i02 23.1% Fe
2 Q3 0.2%I g
l o s s 2.7 %i
ns o 1
0.2% Alz03
4.3%Mg O0.6% SO32.8% Others 0.7%, and the procedure for blending the above main ingredient is to first burn silica sand to remove organic matter, adjust the particle size to 50 to 150μ, and then process this silica sand. Pour into a mixer, gradually add white cement and mix, then add iron powder (Fe2O2), fly asche, zinc white (ZnO), titanium white (T102), glycine, etc. in that order until it becomes uniform. Mix as shown.
なお、白セメントに代えて、ポルトランドセメントを用
いることもできる。Note that portland cement can also be used instead of white cement.
次ぎに、上記した主剤、アスファルト乳剤及び複合ポリ
マーエマルシロンを混合してライニング材を製造する方
法の１例について説明すると、主剤８００ｇと、アスフ
ァルト乳剤５０ ｇと、複合ポリマーエマルジョン１５
０ｇ を混合するものであリ・この混合順序は、まず
、アスファルト乳剤と複合ポリマーエマルジョンを容器
に入れて攪拌し、次に主剤を徐々に加えながら３分〜５
分攪拌し、更に、蒸留水又は軟水又は水道水を適量加え
て希釈しく攪拌しながら施工する。Next, an example of a method for manufacturing a lining material by mixing the above-mentioned base material, asphalt emulsion, and composite polymer emulsion will be explained.
The mixing order is as follows: first, asphalt emulsion and composite polymer emulsion are placed in a container and stirred, and then the main ingredient is gradually added while stirring for 3 to 5 minutes.
Stir for 1 minute, then add an appropriate amount of distilled water, soft water, or tap water and apply while stirring to dilute.
なお、前記各ラテックスの固形分は全て約４０〜５０％
程度のものを用いている。The solid content of each latex is approximately 40 to 50%.
I am using something of a certain degree.
このように製造されたライニング材は、充分な耐熱性、
耐寒性等の耐候性、接着性、防水性等を示した。The lining material manufactured in this way has sufficient heat resistance,
It exhibited weather resistance such as cold resistance, adhesion, and waterproof properties.
なお、本実施例に係るライニング材の物理特性に関して
も試験を行ったので、その結果を以下に示す。Note that tests were also conducted regarding the physical properties of the lining material according to this example, and the results are shown below.
〔耐候性〕 コンクリート壁に付着させた後、表面温度
を９０℃に加熱しても、垂れる
ことがなく、また、雰囲気温度を−
３０℃にしても、表面にひび割れを生
じなかった。[Weather resistance] After being attached to a concrete wall, even when the surface temperature was heated to 90°C, it did not sag, and even when the ambient temperature was -30°C, no cracks were formed on the surface.
対コンクリート１２．０〜２０．１１ ｋｇｆ／ｃｄ〔
耐屈曲性〕
ＪＩＳ−に−５４００）タン塗布０．３龍心棒５ＩＩｍ
１８０°折り曲げ異常なし
〔衝撃試験〕
ＪＩＳ−Ｇ−３４９２５５０ｇ 鋼球２．４＋＋＋落
下異常なし
〔透水量〕
ＪＩＳ−Ａ−１４０４水圧３ ｋｇ／ｃｊ モルタル
との比較
１時間後 モルタル ２３．０ ｇ
本実施例 ２．１ｇAgainst concrete 12.0-20.11 kgf/cd [
Bending resistance] JIS-5400) Tan coating 0.3 Dragon core 5IIm 180° bending No abnormality [Impact test] JIS-G-3492550g Steel ball 2.4+++ No falling abnormality [Water permeability] JIS-A-1404 Water pressure 3 kg/cj Comparison with mortar 1 hour later Mortar 23.0 g Present example 2.1 g
Claims (1)
ル共重合体を主成分としてなる複合ポリマーエマルジョ
ンとを混合して製造したアスファルト乳剤とアクリル酸
エステル共重合体とを含有するライニング材。 ２、アスファルト乳剤と、少なくともアクリル酸エステ
ル共重合体を主成分としてなる複合ポリマーエマルジョ
ンと、酸化珪素、酸化カルシウム、酸化鉄を主成分とし
た主剤とを混合して製造したアスファルト乳剤とアクリ
ル酸エステル共重合体とを含有するライニング材。[Scope of Claims] 1. A lining material containing an asphalt emulsion and an acrylic ester copolymer produced by mixing an asphalt emulsion and a composite polymer emulsion containing at least an acrylic ester copolymer as a main component. 2. An asphalt emulsion and acrylic ester produced by mixing an asphalt emulsion, a composite polymer emulsion containing at least an acrylic ester copolymer as a main component, and a main ingredient containing silicon oxide, calcium oxide, and iron oxide as main components. A lining material containing a copolymer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62034284A JP2700133B2 (en) | 1987-02-16 | 1987-02-16 | Lining material containing asphalt emulsion and acrylate copolymer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62034284A JP2700133B2 (en) | 1987-02-16 | 1987-02-16 | Lining material containing asphalt emulsion and acrylate copolymer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63199757A true JPS63199757A (en) | 1988-08-18 |
| JP2700133B2 JP2700133B2 (en) | 1998-01-19 |
Family
ID=12409859
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62034284A Expired - Fee Related JP2700133B2 (en) | 1987-02-16 | 1987-02-16 | Lining material containing asphalt emulsion and acrylate copolymer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2700133B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0439374A (en) * | 1990-06-02 | 1992-02-10 | Yoshiyuki Ogushi | Adhesive and surface coating agent |
| JP2000160064A (en) * | 1998-12-01 | 2000-06-13 | Nippon Nsc Ltd | Emulsion baking rust preventive |
| KR20030073920A (en) * | 2002-03-14 | 2003-09-19 | 중앙산업 (주) | Ceramics composition of rebirth and new pipe inside lining for water and sewage pipe |
| CN109504301A (en) * | 2018-10-31 | 2019-03-22 | 山东清池防水材料股份有限公司 | A kind of prespreading waterproof roll and preparation method thereof |
| CN110358499A (en) * | 2019-05-14 | 2019-10-22 | 哈尔滨工业大学 | A kind of high-performance road broad extrusion base joint grouting glue |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59221357A (en) * | 1983-05-19 | 1984-12-12 | ハ−キユリ−ズ・インコ−ポレ−テツド | Composition for maintaining or repairing pavement containingasphalt or rubber and property improving method |
| JPS6126819A (en) * | 1984-07-17 | 1986-02-06 | Ohkura Electric Co Ltd | Method and device for identifying channel of depressor bar type recorder |
-
1987
- 1987-02-16 JP JP62034284A patent/JP2700133B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59221357A (en) * | 1983-05-19 | 1984-12-12 | ハ−キユリ−ズ・インコ−ポレ−テツド | Composition for maintaining or repairing pavement containingasphalt or rubber and property improving method |
| JPS6126819A (en) * | 1984-07-17 | 1986-02-06 | Ohkura Electric Co Ltd | Method and device for identifying channel of depressor bar type recorder |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0439374A (en) * | 1990-06-02 | 1992-02-10 | Yoshiyuki Ogushi | Adhesive and surface coating agent |
| JP2000160064A (en) * | 1998-12-01 | 2000-06-13 | Nippon Nsc Ltd | Emulsion baking rust preventive |
| KR20030073920A (en) * | 2002-03-14 | 2003-09-19 | 중앙산업 (주) | Ceramics composition of rebirth and new pipe inside lining for water and sewage pipe |
| CN109504301A (en) * | 2018-10-31 | 2019-03-22 | 山东清池防水材料股份有限公司 | A kind of prespreading waterproof roll and preparation method thereof |
| CN110358499A (en) * | 2019-05-14 | 2019-10-22 | 哈尔滨工业大学 | A kind of high-performance road broad extrusion base joint grouting glue |
| CN110358499B (en) * | 2019-05-14 | 2020-11-17 | 哈尔滨工业大学 | Wide-area asphalt crack pouring adhesive for high-performance road |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2700133B2 (en) | 1998-01-19 |
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