JPS63184910A - Magnetic recording medium - Google Patents

Magnetic recording medium

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Publication number
JPS63184910A
JPS63184910A JP1768087A JP1768087A JPS63184910A JP S63184910 A JPS63184910 A JP S63184910A JP 1768087 A JP1768087 A JP 1768087A JP 1768087 A JP1768087 A JP 1768087A JP S63184910 A JPS63184910 A JP S63184910A
Authority
JP
Japan
Prior art keywords
film
magnetic recording
recording medium
young
modulus
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1768087A
Other languages
Japanese (ja)
Inventor
Koichi Shinohara
紘一 篠原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP1768087A priority Critical patent/JPS63184910A/en
Publication of JPS63184910A publication Critical patent/JPS63184910A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain a good envelope and to miniaturize a magnetic recording system by disposing a thin ferromagnetic metallic film to one face of a high- polymer film and disposing a thin nonmagnetic film to the other face thereof. CONSTITUTION:Ruggedness for decreasing the friction of a magnetic recording medium is formed by under coating layers 10, 11 on the high-polymer film 9. The thin ferromagnetic metallic film 12 is formed thereon by an electron beam vapor deposition, sputtering method, etc. The thin nonmagnetic film 13 having a Young's modulus E2 which is >=1.5E1 when the Young's modulus of the film 12 is designated as E1 is then formed on the opposite side. Three- dimensional tight contact is, therefore, easily obtd. and the effect of tension is decreased when a magnetic head contacts the magnetic recording medium. The good tight contact state is thereby assured and the envelope is obtd. in a good state even if the ring of rotation is diminished and the winding angle increases.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は高密度磁気記録に適する強磁性金属薄膜全磁気
記録層とする磁気記録媒体に関するものである。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a magnetic recording medium having an entire magnetic recording layer of a ferromagnetic metal thin film suitable for high-density magnetic recording.

従来の技術 回転磁気ヘッドによるヘリカル走置方式による音声、画
像の記録、再生を行なう技術は、磁気記録の中でも記録
密度が高くなってきている。そのため、今後更に短波長
化するには、新しい構成の磁気記録媒体が必要で、高分
子フィルム等の非磁性基板上に、co −crのスパッ
タリング法で得られた垂直磁化膜や、Go−Nニー0の
斜め蒸着膜を配した蒸着テープが有望視されている〔例
えば、外国論文誌アイイーイーイー トランザクション
ズ オン マグネティクス(IEEE TRANSAG
TIONSON MAGNET工C3) Vol MA
G−21、No −3、P、 P。
2. Description of the Related Art Techniques for recording and reproducing audio and images using a helical scanning method using a rotating magnetic head have a higher recording density than other magnetic recording methods. Therefore, in order to further shorten the wavelength in the future, a magnetic recording medium with a new configuration will be required. A vapor-deposited tape with a diagonal vapor-deposited film with a knee of 0 is seen as promising [For example, foreign journal IEEE Transactions on Magnetics (IEEE TRANSAG)
TIONSON MAGNET C3) Vol MA
G-21, No-3, P, P.

1217〜1220(198,5) )。1217-1220 (198,5)).

第2図は蒸着テープの一例の拡大断面図で、第2図で1
はポリエチレンテレフタレートフィルム等の高分子フィ
ルムで必要に応じて凹凸を付与するだめの下塗り層を配
したものも用いられる。2は電子ビーム蒸着法、高周波
スパッタリング法等で形成される0、06μmから0.
371m程度の強磁性金属薄膜からなる磁気記録層で、
3は保護潤滑層でアモルファスカーボン膜とフッ素オイ
ルの積層等、数多くの提案がなされているものから適宜
選択して用いることができる。4はバックコート層で、
走行性を助けるためにフィラー、潤滑剤等を含む樹脂か
らなる塗布層である 〔特公昭66−23208号公報
、特開昭58−41418号公報。
Figure 2 is an enlarged cross-sectional view of an example of a vapor deposition tape.
A polymer film such as a polyethylene terephthalate film, which is provided with an undercoat layer to provide unevenness if necessary, is also used. 2 is from 0.06 μm to 0.06 μm formed by electron beam evaporation method, high frequency sputtering method, etc.
A magnetic recording layer consisting of a ferromagnetic metal thin film of about 371 m.
Reference numeral 3 denotes a protective lubricant layer which can be appropriately selected from a number of proposals, such as a layered layer of an amorphous carbon film and a fluorine oil. 4 is the back coat layer,
This is a coating layer made of a resin containing fillers, lubricants, etc. to aid running properties.

特開昭61−151835号公報、特開昭61−187
122号公報等〕。
JP-A-61-151835, JP-A-61-187
Publication No. 122, etc.].

又、磁気テープは体積記録密度が大きくできることも特
徴であり、長時間記録の手段として、テープの薄型化の
動向も重要であり、その点からみても蒸着テープは、薄
型化に有利で開発が進められているのが現状である。
Another feature of magnetic tape is that it can have a large volumetric recording density, and as a means of long-term recording, the trend toward thinner tapes is also important.From this point of view, vapor-deposited tapes are advantageous for thinning and are difficult to develop. The current situation is that progress is being made.

確かに磁気記録層が従来の塗布型磁性層に比べて1/1
0  ぐらいに薄くなるのと、磁気記録層のヤング率が
10倍以上大きいので、全厚を薄くできると考えられる
が、広範囲の温度範囲での実用化を目積した時、バイメ
タル構造となっている不利な面が目立ってぐるので、両
面に蒸着層を配したテープ構成も提案されている〔特開
昭61−110343号公報〕。
It is true that the magnetic recording layer is 1/1 that of the conventional coated magnetic layer.
0 and the Young's modulus of the magnetic recording layer is more than 10 times larger, so it is thought that the total thickness can be made thinner, but when aiming for practical use over a wide temperature range, it becomes a bimetallic structure. Therefore, a tape structure having vapor deposited layers on both sides has been proposed [JP-A-61-110343].

第3図は、両面蒸着型の磁気テープの拡大断面図の一例
で、第3図で、6は高分子フィルムで両面にミミズ状の
凹凸を配したポリエチレンテレフタレートフィルム等が
用いられる。6は垂直磁化膜、斜め蒸着膜等の強磁性金
属薄膜から成る磁気記録層で、了は両面アクセス型とす
る場合は、強磁性金属薄膜から構成し、片面アクセスの
場合は、SiO、5i02 、 Al2O5、MgF2
等の非磁性薄膜で、反応性蒸着、高周波スパッタリング
等の方法で形成されるもので8は保護潤滑膜である。
FIG. 3 is an example of an enlarged cross-sectional view of a double-sided vapor-deposited magnetic tape. In FIG. 3, reference numeral 6 denotes a polymer film, such as a polyethylene terephthalate film having earthworm-like irregularities on both sides. 6 is a magnetic recording layer made of a ferromagnetic metal thin film such as a perpendicularly magnetized film or an obliquely deposited film; in the case of double-sided access, it is made of a ferromagnetic metal thin film; in the case of single-sided access, it is made of SiO, 5i02, Al2O5, MgF2
8 is a protective lubricant film, which is formed by a method such as reactive vapor deposition or high frequency sputtering.

発明が解決しようとする問題点 しかしながら両面蒸着型の磁気テープは、全厚が8μm
以下になると、カール状態の温度変化は小さくできるが
、回転磁気ヘッドに巻きつけ角を大きくして記録再生を
行う系で、回転シリンダの直径を小さくしていき、且つ
短波長化していくと、エンベロープが巻きつけ角全域に
渡って良好な状態を保てなくなるため改善が望まれてい
た。
Problems to be Solved by the Invention However, the double-sided vapor-deposited magnetic tape has a total thickness of 8 μm.
If the temperature is below, the temperature change in the curl state can be reduced, but if the diameter of the rotating cylinder is made smaller and the wavelength is made shorter in a system where recording and reproduction is performed by wrapping the magnetic head around a rotating magnetic head at a larger angle, Improvements have been desired since the envelope cannot maintain a good condition over the entire wrapping angle.

本発明は上記した事情に鑑みなされたもので、より小型
化された機器で短波長記録再生を可能にする全厚の薄い
磁気記録媒体を提供するものである。
The present invention has been made in view of the above-mentioned circumstances, and it is an object of the present invention to provide a magnetic recording medium with a thin overall thickness that enables recording and reproduction of short wavelengths with smaller equipment.

問題点を解決するだめの手段 上記した問題点を解決するため、本発明の磁気記録媒体
は、高分子フィルムの一方にヤング率E1の強磁性金属
薄膜を配し、高分子フィルムの他方にヤング率E2が1
.511以上の非磁性薄膜を配したものである。
Means for Solving the Problems In order to solve the above problems, the magnetic recording medium of the present invention includes a ferromagnetic metal thin film having a Young's modulus of E1 on one side of the polymer film, and a Young's modulus on the other side of the polymer film. Rate E2 is 1
.. 511 or more nonmagnetic thin films are arranged.

作用 本発明の磁気記録媒体は、上記した構成により、磁気ヘ
ッドと磁気記録媒体が接触した時に、3次元的に密着し
やすくなるため、テンシコンの影響が小さくでき、回転
シリングが小さくなって巻きつけ角が大きくなっても、
良好な密着状態が確保できエンベロープを良好な状態で
得られることになる。
Effect The magnetic recording medium of the present invention has the above-described structure, so that when the magnetic head and the magnetic recording medium come into contact, they are likely to come into close contact three-dimensionally, so that the influence of the tensicon can be reduced, and the rotational spooling can be reduced, making it easier to wrap the magnetic recording medium. Even if the angle becomes larger,
Good adhesion can be ensured and the envelope can be obtained in good condition.

実施例 以下、図面kE”照しながら本発明の実施例について説
明する。第1図は本発明の磁気記録媒体の拡大断面図で
、第1図で9は厚み7.6μmから3μmのポリエチレ
ンテレフタレー)、ホlJエチレンナフタレート、ボリ
フヱニレンサルファイド、ポリサルフオン、ポリアミド
イミド、ポリイミド等の高分子フィルムで、ヤング率は
通常それぞれの材料で延伸強化できる範囲内で用いれば
良い。10゜11は下塗り層で一磁気記碌媒体の摩擦を
低減するため、凹凸を形成するもので、形状はミミズ状
Embodiments Embodiments of the present invention will be described below with reference to drawings ``kE''. Fig. 1 is an enlarged cross-sectional view of a magnetic recording medium of the present invention, and in Fig. 1, 9 is a polyethylene terephthalate film having a thickness of 7.6 μm to 3 μm. For polymer films such as HolJ ethylene naphthalate, polyethylene naphthalate, polyvinylene sulfide, polysulfone, polyamideimide, and polyimide, the Young's modulus should normally be within the range that can be stretched and strengthened for each material. The undercoat layer forms unevenness in order to reduce the friction of the magnetic recording medium, and is earthworm-shaped.

粒状、その組み合わせ等から適宜選択され、微粒子とし
てはA7!205 、5i02 、 CaCO3、Ba
SO4。
The particles are appropriately selected from granules, combinations thereof, etc., and fine particles include A7!205, 5i02, CaCO3, Ba
SO4.

TiO2、Fe2O2、CrO2、カーボン等、ポリエ
ステル球、ポリエチレン球等が用いられる。
TiO2, Fe2O2, CrO2, carbon, etc., polyester balls, polyethylene balls, etc. are used.

12はGo−Ni 、 Go−ye 、 Fe−Ag 
、 Go−Ta 。
12 is Go-Ni, Go-ye, Fe-Ag
, Go-Ta.

Go−Ti 、 Go−Or 、 Go−Or−Nb 
、 Go−Cr −P。
Go-Ti, Go-Or, Go-Or-Nb
, Go-Cr-P.

Go−Ni−0等の強磁性金属薄膜で、電子ビーム蒸着
法、スパッタリング法等で形成されるもので、0.06
μmから0.2μmの範囲で、ヤング率’x E 1と
するとElは8,000〜16,000 (kg /y
i ) C1範囲(C入るものが殆んどである。13は
強磁性金属薄膜のヤング率kE−+とじた時1,6Ej
以上となるヤング率Kze有する非磁性薄膜から構成さ
れるもので、材質、製法を適宜最適化し、K2i1.5
E1から3K。
A ferromagnetic metal thin film such as Go-Ni-0, formed by electron beam evaporation method, sputtering method, etc., with a diameter of 0.06
In the range from μm to 0.2 μm, if Young's modulus 'x E is 1, then El is 8,000 to 16,000 (kg/y
i) C1 range (most things fall into C. 13 is the Young's modulus of the ferromagnetic metal thin film kE-+, which is 1.6Ej
It is composed of a non-magnetic thin film with a Young's modulus Kze of
E1 to 3K.

の範囲に構成すればよい。勿論3E、以上であってもよ
いが、製法上に生産性が極端に小さくなるなどの不具合
が生ずるので、1.6E1から21.の範囲で構成する
のが好ましい。1.51j以下では何故ヘッドタッチが
不安定になるかは明らかではないが、実験的には臨界が
明確に存在しているものである。
It should be configured within the range of . Of course, it may be 3E or higher, but this will cause problems such as extremely low productivity in the manufacturing process, so the range should be from 1.6E1 to 21. It is preferable to configure it within the range of . It is not clear why head touch becomes unstable below 1.51j, but experimentally a criticality clearly exists.

14は潤滑剤で、脂肪酸、脂肪酸アミド、弗素化合物等
、適宜選択されプラズマ重合膜、アモルファスカーボン
膜との積層としてもよい。以下、更に具体的に比較例と
の対比で本実施例の優れている点について説明する。厚
み7μmのポリエチレンテレフタレートフィルム(ヤン
グ率は670kg/gNOものを用いた)上に、直径1
00人の8102微粒子を16ケ/(μm)2の密度で
ポリエステル樹脂で分散固定した上に、直径1mの円筒
キャンに沿わせて5.3 X 1O−5(Torr)の
酸素雰囲気中で最小入射角40度でGo−Ni (Ni
 、 20 wt%)を電子ビーム蒸着して、0.13
μmのGo−Ni−0膜を配した。このGo−Ni−0
膜は保磁力120o (Oe)で、ヤング率E1ば9,
200(kg/i)であった。
Reference numeral 14 denotes a lubricant, which is appropriately selected from fatty acids, fatty acid amides, fluorine compounds, etc., and may be laminated with a plasma polymerized film or an amorphous carbon film. In the following, the superiority of this example will be explained in more detail in comparison with a comparative example. A film with a diameter of 1
8102 fine particles of 00 people were dispersed and fixed in polyester resin at a density of 16 particles/(μm)2, and then placed along a cylindrical can with a diameter of 1 m in an oxygen atmosphere of 5.3 x 1O-5 (Torr). Go-Ni (Ni
, 20 wt%) was electron beam evaporated to give 0.13
A μm Go-Ni-0 film was arranged. This Go-Ni-0
The film has a coercive force of 120o (Oe) and a Young's modulus of E1, 9,
It was 200 (kg/i).

Go−Ni−0膜と反対側にイオンビームデポジション
法でBei蒸着した。その際、基板温度ヲ2゜°Cから
100°Cまでの範囲、イオン密度全10(μA/c4
 )から320(μA/c祷)の範囲で調整して、0.
171mのBe薄膜のヤング率Ez’k 9,500 
(kg/J 。
Bei was deposited on the opposite side of the Go-Ni-0 film by ion beam deposition. At that time, the substrate temperature ranged from 2°C to 100°C, and the ion density totaled 10 (μA/c4
) to 320 (μA/c).
Young's modulus of 171m Be thin film Ez'k 9,500
(kg/J.

12.600 Ckg/mff1〕、 14.ooo 
[kg/mff1:] 、 17,8o。
12.600 Ckg/mff1], 14. ooooo
[kg/mff1:] , 17.8o.

(kg/mA)の4種類についてテープ化した。尚、潤
滑剤は40人のステアリン酸の蒸着膜である。この4種
類について、3.8 ミ!J幅にスリットした後、シリ
ンダ径3001[11の回転シリンダにギャップ長0.
14μmのフェライトヘッドを搭載して、巻きつけ角を
200度と290度の2水準とし、記録波長0.6μm
=2記録し再生波形のエンベロープの平坦率を比較した
。その結果を表にまとめて示した。
(kg/mA) were made into tapes. The lubricant was a vapor-deposited film of stearic acid by 40 people. Regarding these four types, 3.8 mi! After slitting to J width, a gap length of 0.
Equipped with a 14 μm ferrite head, has two winding angles of 200 degrees and 290 degrees, and has a recording wavelength of 0.6 μm.
= 2 were recorded and the flatness ratio of the envelope of the reproduced waveform was compared. The results are summarized in a table.

発明の効果 以上のように本発明によれば、回転シリンダ径を小さく
して、短波長記録再生を行っても良好なエンベロープを
得ることができ、磁気記録システスの超小型化を可能に
するといったすぐれた効果がある。
Effects of the Invention As described above, according to the present invention, it is possible to obtain a good envelope even when recording and reproducing short wavelengths by reducing the diameter of the rotating cylinder, and it is possible to miniaturize the magnetic recording system. It has excellent effects.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の磁気記録媒体の一例の拡大断面図、第
2図2よび第3図は従来の磁気記録媒体の拡大断面図で
ある。 9・・・・・・高分子フィルム、10.11・・・・・
・下塗り層、12・・・・・・強磁性金属薄膜(ヤング
率に+)、13・・・・・・非磁性薄膜(ヤング率1.
61に、以上)。 代理人の氏名 弁理士 中 尾 敏 男 ほか1名9−
搾り分号フィルム (〒ンク゛率/、、5 Ez以上) 第2図 第3図
FIG. 1 is an enlarged sectional view of an example of the magnetic recording medium of the present invention, and FIGS. 2 and 3 are enlarged sectional views of a conventional magnetic recording medium. 9...Polymer film, 10.11...
- Undercoat layer, 12...Ferromagnetic metal thin film (Young's modulus is +), 13...Nonmagnetic thin film (Young's modulus 1.
61, above). Name of agent: Patent attorney Toshio Nakao and 1 other person9-
Squeeze number film (〒ink rate/,,5 Ez or more) Figure 2 Figure 3

Claims (1)

【特許請求の範囲】 高分子フィルムの一方にヤング率E_1の強磁性金属薄
膜を配し、前記高分子フィルムの他方にヤング率K_2
が1.5K_1薄膜を配した ことを 特徴とする磁気記録媒体。
[Claims] A ferromagnetic metal thin film with a Young's modulus of E_1 is disposed on one side of the polymer film, and a Young's modulus of K_2 is placed on the other side of the polymer film.
A magnetic recording medium characterized by disposing a 1.5K_1 thin film.
JP1768087A 1987-01-28 1987-01-28 Magnetic recording medium Pending JPS63184910A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1768087A JPS63184910A (en) 1987-01-28 1987-01-28 Magnetic recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1768087A JPS63184910A (en) 1987-01-28 1987-01-28 Magnetic recording medium

Publications (1)

Publication Number Publication Date
JPS63184910A true JPS63184910A (en) 1988-07-30

Family

ID=11950555

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1768087A Pending JPS63184910A (en) 1987-01-28 1987-01-28 Magnetic recording medium

Country Status (1)

Country Link
JP (1) JPS63184910A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04195919A (en) * 1990-11-28 1992-07-15 Matsushita Electric Ind Co Ltd Magnetic recording medium

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04195919A (en) * 1990-11-28 1992-07-15 Matsushita Electric Ind Co Ltd Magnetic recording medium

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