JPS63179943A - Food packaging container - Google Patents
Food packaging containerInfo
- Publication number
- JPS63179943A JPS63179943A JP1123287A JP1123287A JPS63179943A JP S63179943 A JPS63179943 A JP S63179943A JP 1123287 A JP1123287 A JP 1123287A JP 1123287 A JP1123287 A JP 1123287A JP S63179943 A JPS63179943 A JP S63179943A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- container
- food packaging
- polyolefin resin
- talc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000013305 food Nutrition 0.000 title claims description 13
- 238000004806 packaging method and process Methods 0.000 title claims description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 24
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 15
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 12
- 239000000454 talc Substances 0.000 claims abstract description 12
- 229910052623 talc Inorganic materials 0.000 claims abstract description 12
- 239000000314 lubricant Substances 0.000 claims abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 6
- 239000000194 fatty acid Substances 0.000 claims abstract description 6
- 229930195729 fatty acid Natural products 0.000 claims abstract description 6
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 6
- 150000002148 esters Chemical class 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 4
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims abstract description 4
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 4
- 235000019645 odor Nutrition 0.000 claims description 18
- 239000002216 antistatic agent Substances 0.000 claims description 7
- 239000011342 resin composition Substances 0.000 claims description 4
- 238000013329 compounding Methods 0.000 abstract 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- 239000011256 inorganic filler Substances 0.000 description 5
- 229910003475 inorganic filler Inorganic materials 0.000 description 5
- -1 polypropylene, propylene-ethylene copolymer Polymers 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 2
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BMULWKLWORMXCY-UHFFFAOYSA-N 4-(2,2,4,4-tetramethylpentan-3-yl)phenol Chemical compound CC(C)(C)C(C(C)(C)C)C1=CC=C(O)C=C1 BMULWKLWORMXCY-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- NAPSCFZYZVSQHF-UHFFFAOYSA-N dimantine Chemical compound CCCCCCCCCCCCCCCCCCN(C)C NAPSCFZYZVSQHF-UHFFFAOYSA-N 0.000 description 1
- 229950010007 dimantine Drugs 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000008786 sensory perception of smell Effects 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は不快臭のない食品包装容器に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to food packaging containers that are free from unpleasant odors.
ポリオレフィンにタルクや炭酸カルシウムを添加したポ
リオレフィン樹脂組成物は、耐熱製あるいは易焼却性か
ら食品包装容器として利用されている。しかしながら、
ポリオレフィン樹脂、タルクや炭酸カルシウムそのもの
は不快臭がないが、ポリオレフィン樹脂にタルクや炭酸
カルシウムを混合したポリオレフィン樹脂組成物は不快
臭を有し、食品包装容器として使用するには問題があっ
た。特に内容物の入った容器のまま電子レンジ等で加熱
調理する際には、一層不快臭が助長されるので食品容器
として満足されうるちのではなかった。Polyolefin resin compositions made by adding talc or calcium carbonate to polyolefins are used as food packaging containers because they are heat resistant or easily incinerated. however,
Polyolefin resins, talc, and calcium carbonate themselves do not have unpleasant odors, but polyolefin resin compositions in which talc and calcium carbonate are mixed with polyolefin resins have unpleasant odors, which is problematic when used as food packaging containers. In particular, when the container containing the contents is heated in a microwave oven or the like, the unpleasant odor is further promoted, so that the container is not satisfactory as a food container.
本発明の目的は、ポリオレフィン樹脂にタルクや炭酸カ
ルシウムを混合しているにかかわらず不快臭のない食品
包装容器を提供することにある。An object of the present invention is to provide a food packaging container that does not have an unpleasant odor even though talc or calcium carbonate is mixed with the polyolefin resin.
〔問題点を解決するための手段］
本発明者らは、上記の目的を達成すべく鋭意研究した結
果、本発明に到達した。[Means for Solving the Problems] The present inventors have conducted extensive research to achieve the above object, and as a result, have arrived at the present invention.
すなわち、本発明はタルク及び／又は炭酸カルシウム１
０〜８０重量％とポリオレフィン樹脂９０〜２０重量％
とからなる組成物１００重量部に対し、帯電防止剤及び
／又は滑剤０．０５〜５重量部を含有する樹脂組成物か
らなる不快臭のない食品包装容器である。That is, the present invention provides talc and/or calcium carbonate 1
0-80% by weight and polyolefin resin 90-20% by weight
This food packaging container is free from unpleasant odors and is made of a resin composition containing 0.05 to 5 parts by weight of an antistatic agent and/or a lubricant per 100 parts by weight of the composition.
本発明で用いるポリオレフィン樹脂としては、ポリプロ
ピレン、プロピレン−エチレン共重合体、高密度ポリエ
チレン、低密度ポリエチレン、エチレン−酢酸ビニル共
重合体、ポリブテンなどを挙げることができ、これらは
単独あるいは混合して用いられる。Examples of the polyolefin resin used in the present invention include polypropylene, propylene-ethylene copolymer, high-density polyethylene, low-density polyethylene, ethylene-vinyl acetate copolymer, polybutene, etc., and these may be used alone or in combination. It will be done.
本発明においては、無機フィラーとしてタルクおよび炭
酸カルシウムを何れか一方或いは混合して用いる。In the present invention, talc and calcium carbonate are used as the inorganic filler, either alone or in combination.
ポリオレフィン樹脂と無機フィラーの割合は、無機フィ
ラー１０〜８０重量％とポリオレフィン樹脂９０〜２０
重量％であり、ポリオレフィン樹脂が９０重量％以上で
は電子レンジなどで加熱する場合に耐熱性に劣り、また
２０重量％以下では熱成形が困難となり均一な肉厚を持
った容器が得られない。The ratio of polyolefin resin and inorganic filler is 10 to 80% by weight of inorganic filler and 90 to 20% by weight of polyolefin resin.
If the polyolefin resin is 90% by weight or more, the heat resistance will be poor when heated in a microwave oven or the like, and if it is less than 20% by weight, thermoforming will be difficult and a container with uniform wall thickness will not be obtained.
本発明で用いる帯電防止剤としては、脂肪酸の低級アル
コールエステル、脂肪酸の多価アルコールエステル、ポ
リオキシエチレン−アルキルアミン、ポリオキシエチレ
ン−アルキルエーテル、アルキルフォスフェート、４級
アンモニウム塩などが挙げられ、特にグリセリンモノス
テアレート、ポリオキシエチレングリセリンモノステア
レートなどの脂肪酸の多価アルコールエステルが好まし
い。Examples of the antistatic agent used in the present invention include lower alcohol esters of fatty acids, polyhydric alcohol esters of fatty acids, polyoxyethylene-alkylamines, polyoxyethylene-alkyl ethers, alkyl phosphates, quaternary ammonium salts, etc. Particularly preferred are polyhydric alcohol esters of fatty acids such as glycerin monostearate and polyoxyethylene glycerin monostearate.
また滑剤としては不飽和脂肪酸アミド、脂肪酸流動パラ
フィン、金属セッケン等が挙げられ、特にオレイン酸ア
ミド、エルカ酸アミドなどの不飽和脂肪酸アミドが好ま
しい。Examples of lubricants include unsaturated fatty acid amides, fatty acid liquid paraffins, metal soaps, etc., and unsaturated fatty acid amides such as oleic acid amide and erucic acid amide are particularly preferred.
これら帯電防止剤や滑剤は単独でまたは併用して添加さ
れる。添加量は前記無機フィラーとポリオレフィン樹脂
の合計１００重量部に対して０．０５〜５重量部の範囲
、好ましくは０．１〜３重量部の範囲である。０．０５
重量部未満では不快臭の防止効果が殆ど得られず、また
１０重量部を越える添加では添加剤の臭いが強くなり逆
に不快臭を生じるので好ましくない。These antistatic agents and lubricants may be added alone or in combination. The amount added is in the range of 0.05 to 5 parts by weight, preferably in the range of 0.1 to 3 parts by weight, based on a total of 100 parts by weight of the inorganic filler and polyolefin resin. 0.05
If it is less than 1 part by weight, the effect of preventing unpleasant odor will hardly be obtained, and if it is added in excess of 10 parts by weight, the odor of the additive will become strong and cause an unpleasant odor, which is not preferable.
本発明の食品包装容器は、−ｇのプラスチック容器を製
造するのと同様の方法で製造しうる。例えば、ポリオレ
フィンパウダーとタルク及び／又は炭酸カルシウム、ポ
リオレフィン酸化防止剤、帯電防止剤及び／又は滑剤を
ヘンシェルミキサー等で撹拌した後、押出機によりペレ
ット化し、次いでＴダイ付押出機に投入してシート状に
押出した後、所望の形状に該シートを熱成形して本発明
の食品包装容器を製造する。The food packaging container of the present invention can be manufactured in the same manner as the plastic container of -g. For example, polyolefin powder, talc and/or calcium carbonate, a polyolefin antioxidant, an antistatic agent, and/or a lubricant are stirred in a Henschel mixer or the like, pelletized by an extruder, and then fed into an extruder with a T-die to form a sheet. After extruding into a shape, the sheet is thermoformed into a desired shape to produce the food packaging container of the present invention.
以下、本発明を実施例にて詳しく説明する。 Hereinafter, the present invention will be explained in detail with reference to Examples.
実施例１
ポリプロピレンパウダー（メルトフローインデックス０
．５ｇ／１０分）６０重量部とタルク４０重量部に対し
てグリセリンモノステアレート０．１重量部、２．６−
ジーｔ−ブチル−４−ヒドロキシトルエン０．１重量部
とテトラキス〔メチレン−３−（３’ 、５’−ジ−ｔ
−ブチル−４′−ヒドロキシフェニル）プロピオネート
ラメタフ０．１重量部を添加し、ヘンシェルミキサーで
混合した後、押出温度２３０″Ｃでペレット化した。Example 1 Polypropylene powder (melt flow index 0
．． 0.1 part by weight of glycerin monostearate, 2.6-
0.1 part by weight of di-t-butyl-4-hydroxytoluene and tetrakis[methylene-3-(3',5'-di-t
-Butyl-4'-hydroxyphenyl)propionate 0.1 part by weight of trameth was added, mixed in a Henschel mixer, and then pelletized at an extrusion temperature of 230''C.
該ペレットをＴダイ付押出機でシート状に押出した後、
該シートを熱成形し、長さ２０ｃｍ、幅１０ＣＩ１１、
深さ３（２）の容器を得た。After extruding the pellets into a sheet using an extruder with a T-die,
The sheet was thermoformed to have a length of 20 cm, a width of 10 CI11,
A container with a depth of 3 (2) was obtained.
得られた容器の臭いを試験人１０人の臭覚により判定し
た（室温、容器を１４０°Ｃに加熱した時）。The odor of the resulting container was judged by the sense of smell of 10 testers (at room temperature, when the container was heated to 140° C.).
結果を表１に示す。The results are shown in Table 1.
実施例２
グリセリンモノステアレートに代えてオレイン酸アマイ
ドを用いる以外は実施例１と同様にして容器を作成し、
匂を調べた。Example 2 A container was created in the same manner as in Example 1 except that oleic acid amide was used instead of glycerin monostearate,
I investigated the smell.
結果を表１に示す。The results are shown in Table 1.
実施例３
タルクに代えて炭酸カルシウムを用いる以外は実施例１
と同様にして容器を作成し、匂を調べた。Example 3 Example 1 except that calcium carbonate is used instead of talc
A container was made in the same manner as above, and the odor was investigated.
結果を表１に示す。The results are shown in Table 1.
実施例４
グリセリンモノステアレートに代えて、帯電防止剤であ
るジメチルステアリルアミン０．３重量部と滑剤である
エルカ酸アマイド０．３重量部を用いる以外は実施例１
と同様にして容器を作成し、匂を８周べた。Example 4 Example 1 except that 0.3 parts by weight of dimethylstearylamine as an antistatic agent and 0.3 parts by weight of erucic acid amide as a lubricant were used in place of glycerin monostearate.
A container was made in the same manner as above, and the odor was applied 8 times.
結果を表１に示す。The results are shown in Table 1.
比較例１
グリセリンモノステアレートを添加せずに実施例１と同
様にして容器を作成し、匂を調べた。Comparative Example 1 A container was prepared in the same manner as in Example 1 without adding glycerin monostearate, and the odor was examined.
結果を表１に示す。The results are shown in Table 1.
比較例２
グリセリンモノステアレートの添加量を７重量部とする
以外は実施例１と同様にして容器を作成し、匂を８周べ
た。Comparative Example 2 A container was prepared in the same manner as in Example 1, except that the amount of glycerin monostearate added was 7 parts by weight, and the odor was applied 8 times.
結果を表１に示す。The results are shown in Table 1.
参考例
ポリプロピレンパウダー、タルク及び炭酸カルシウムを
それぞれ２３０°Ｃで１０分加熱し、匂を調べたが、不
快臭はなかった。Reference Example Polypropylene powder, talc, and calcium carbonate were each heated at 230°C for 10 minutes and examined for odor, but no unpleasant odor was found.
本発明の食品包装容器は無機フィラーを含有しているに
もかかわらず不快臭がないため、電子レンジ用容器とし
て好適に用いうるものである。The food packaging container of the present invention has no unpleasant odor even though it contains an inorganic filler, so it can be suitably used as a container for microwave ovens.
Claims (1)
とポリオレフィン樹脂９０〜２０重量％とからなる組成
物１００重量部に対し、帯電防止剤及び／又は滑剤０．
０５〜５重量部を含有する樹脂組成物からなることを特
徴とする不快臭のない食品包装容器。 ２、帯電防止剤が脂肪酸の多価アルコールエステルであ
る特許請求の範囲第１項記載の食品包装容器。 ３、滑剤が不飽和脂肪酸アミドである特許請求の範囲第
１項記載の食品包装容器。[Claims] 1. Talc and/or calcium carbonate 10-80% by weight
and 90 to 20% by weight of a polyolefin resin, 0.0% of an antistatic agent and/or a lubricant is added to 100 parts by weight of a composition consisting of 90 to 20% by weight of a polyolefin resin.
1. A food packaging container free of unpleasant odors, characterized in that it is made of a resin composition containing 0.5 to 5 parts by weight. 2. The food packaging container according to claim 1, wherein the antistatic agent is a polyhydric alcohol ester of fatty acid. 3. The food packaging container according to claim 1, wherein the lubricant is an unsaturated fatty acid amide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62011232A JPH07116329B2 (en) | 1987-01-22 | 1987-01-22 | Food packaging container |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62011232A JPH07116329B2 (en) | 1987-01-22 | 1987-01-22 | Food packaging container |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63179943A true JPS63179943A (en) | 1988-07-23 |
| JPH07116329B2 JPH07116329B2 (en) | 1995-12-13 |
Family
ID=11772193
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62011232A Expired - Lifetime JPH07116329B2 (en) | 1987-01-22 | 1987-01-22 | Food packaging container |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH07116329B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100930A (en) * | 1989-07-07 | 1992-03-31 | Sumitomo Chemical Company, Limited | Food container |
| JP2005171202A (en) * | 2003-12-15 | 2005-06-30 | Lonseal Corp | Offset printing olefin film |
| JP2008094998A (en) * | 2006-10-13 | 2008-04-24 | Toyo Ink Mfg Co Ltd | Colored resin composition |
| WO2024080123A1 (en) * | 2022-10-11 | 2024-04-18 | 住友化学株式会社 | Composition |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10308852B2 (en) | 2015-03-30 | 2019-06-04 | Adeka Corporation | Antistatic resin composition and polyolefin antistatic fiber for container and pipe for organic solvent |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50139836A (en) * | 1974-04-27 | 1975-11-08 | ||
| JPS51145554A (en) * | 1975-05-26 | 1976-12-14 | Lion Corp | Polyolefin resin composition |
| JPS53142455A (en) * | 1977-05-17 | 1978-12-12 | Iwao Hishida | Particulate inorganic material and molding resin composition using same |
| JPS5487745A (en) * | 1977-12-26 | 1979-07-12 | Idemitsu Petrochemical Co | Method of making polypropylene composition |
| JPS5545733A (en) * | 1978-09-27 | 1980-03-31 | Lion Corp | Odorless resin composition |
| JPS564642A (en) * | 1979-06-26 | 1981-01-19 | Mitsubishi Petrochem Co Ltd | Propylene polymer film |
| JPS63145350A (en) * | 1986-12-08 | 1988-06-17 | Mitsubishi Kasei Corp | Polyolefin resin composition |
-
1987
- 1987-01-22 JP JP62011232A patent/JPH07116329B2/en not_active Expired - Lifetime
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50139836A (en) * | 1974-04-27 | 1975-11-08 | ||
| JPS51145554A (en) * | 1975-05-26 | 1976-12-14 | Lion Corp | Polyolefin resin composition |
| JPS53142455A (en) * | 1977-05-17 | 1978-12-12 | Iwao Hishida | Particulate inorganic material and molding resin composition using same |
| JPS5487745A (en) * | 1977-12-26 | 1979-07-12 | Idemitsu Petrochemical Co | Method of making polypropylene composition |
| JPS5545733A (en) * | 1978-09-27 | 1980-03-31 | Lion Corp | Odorless resin composition |
| JPS564642A (en) * | 1979-06-26 | 1981-01-19 | Mitsubishi Petrochem Co Ltd | Propylene polymer film |
| JPS63145350A (en) * | 1986-12-08 | 1988-06-17 | Mitsubishi Kasei Corp | Polyolefin resin composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5100930A (en) * | 1989-07-07 | 1992-03-31 | Sumitomo Chemical Company, Limited | Food container |
| JP2005171202A (en) * | 2003-12-15 | 2005-06-30 | Lonseal Corp | Offset printing olefin film |
| JP4521752B2 (en) * | 2003-12-15 | 2010-08-11 | ロンシール工業株式会社 | Olefin film for offset printing |
| JP2008094998A (en) * | 2006-10-13 | 2008-04-24 | Toyo Ink Mfg Co Ltd | Colored resin composition |
| WO2024080123A1 (en) * | 2022-10-11 | 2024-04-18 | 住友化学株式会社 | Composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07116329B2 (en) | 1995-12-13 |
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