JPS63179083A - Multi-ply alloy plated steel sheet having superior corrosion resistance and workability - Google Patents
Multi-ply alloy plated steel sheet having superior corrosion resistance and workabilityInfo
- Publication number
- JPS63179083A JPS63179083A JP939587A JP939587A JPS63179083A JP S63179083 A JPS63179083 A JP S63179083A JP 939587 A JP939587 A JP 939587A JP 939587 A JP939587 A JP 939587A JP S63179083 A JPS63179083 A JP S63179083A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- alloy
- workability
- corrosion resistance
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 70
- 239000000956 alloy Substances 0.000 title claims abstract description 70
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 57
- 239000010959 steel Substances 0.000 title claims abstract description 57
- 230000007797 corrosion Effects 0.000 title claims abstract description 41
- 238000005260 corrosion Methods 0.000 title claims abstract description 41
- 239000000843 powder Substances 0.000 claims abstract description 44
- 229910052751 metal Inorganic materials 0.000 claims abstract description 31
- 239000002184 metal Substances 0.000 claims abstract description 31
- 238000009713 electroplating Methods 0.000 claims abstract description 28
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- 150000002739 metals Chemical class 0.000 claims abstract description 17
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 16
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 14
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 238000007747 plating Methods 0.000 claims description 43
- 229910001297 Zn alloy Inorganic materials 0.000 claims description 19
- 238000005275 alloying Methods 0.000 claims description 14
- 239000002932 luster Substances 0.000 abstract 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 20
- 229910052742 iron Inorganic materials 0.000 description 9
- 238000000576 coating method Methods 0.000 description 6
- 229910007570 Zn-Al Inorganic materials 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910007567 Zn-Ni Inorganic materials 0.000 description 3
- 229910007614 Zn—Ni Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 230000007547 defect Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000002747 voluntary effect Effects 0.000 description 2
- 229910001369 Brass Inorganic materials 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- HEFNNWSXXWATRW-UHFFFAOYSA-N Ibuprofen Chemical compound CC(C)CC1=CC=C(C(C)C(O)=O)C=C1 HEFNNWSXXWATRW-UHFFFAOYSA-N 0.000 description 1
- 229910000655 Killed steel Inorganic materials 0.000 description 1
- 229910001199 N alloy Inorganic materials 0.000 description 1
- 229910000711 U alloy Inorganic materials 0.000 description 1
- 229910007564 Zn—Co Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は耐蝕性、加工性に優れた多層合金めっき鋼板に
関し、さらに詳しくは、自動車、家庭電気用品等に使用
される耐蝕性、加工性に優れた多層合金めっき鋼板に関
する。[Detailed Description of the Invention] [Industrial Field of Application] The present invention relates to a multilayer alloy-plated steel sheet with excellent corrosion resistance and workability, and more specifically, to a multilayer alloy-plated steel sheet with excellent corrosion resistance and workability for use in automobiles, household electrical appliances, etc. Regarding multilayer alloy plated steel sheets with excellent properties.
［従来技術］
従来、自動車、家庭電気用品等には種々の防錆鋼板が使
用されているが、そのうちＺｎの優れた犠牲防蝕作用に
よりＺｎめっき鋼板が尤も広く用いられている。[Prior Art] Conventionally, various rust-proof steel sheets have been used in automobiles, household electrical appliances, etc., but among them, Zn-plated steel sheets are particularly widely used due to the excellent sacrificial corrosion-preventing action of Zn.
しかし、荀酷な腐蝕環境下ではＺｎの溶出による消費が
早まり、めっきとしての寿命が短くなるため、他の金属
を合金化さ仕耐蝕性を向上させた７、ｎ合金めっき鋼板
か開発されてきており、需要ら益々増加の傾向を示して
いる。However, in a severely corrosive environment, Zn is leached out and consumed quickly, shortening the life of the coating. Therefore, 7,N alloy plated steel sheets have been developed that are alloyed with other metals and have improved corrosion resistance. This trend shows an increasing trend due to demand.
そして、このＺｎ合金めっき調板としては、Ｚｎ−Ｆｅ
５Ｚｎ−Ｎｉ、Ｚｎ−Ｃｏ等の合金めっき鋼板があり、
主として電気めっきにより製造されている。As this Zn alloy plating plate, Zn-Fe
There are alloy plated steel sheets such as 5Zn-Ni and Zn-Co.
Mainly manufactured by electroplating.
しかしながら、近年耐蝕性向上の要求が強くなり、これ
らの合金めっき層の厚膜化が必要となっているが、電気
めっき法では厚目付けの操作が複雑となり、かつ、コス
トが大幅に上昇するという問題がある。However, in recent years there has been a strong demand for improved corrosion resistance, and it has become necessary to thicken these alloy plating layers, but with electroplating, the operation of applying thick coatings is complicated and the cost increases significantly. There's a problem.
そのため、この問題を解決した鋼板としては、従来より
次のような粉末めっき法を適用した鋼板がある。Therefore, as steel sheets that have solved this problem, there are conventional steel sheets to which the following powder plating method is applied.
■）特開昭４９−０１１７３７号公報には、Ｃｕめっき
した鋼板上にＺｎ粉末を付着被覆後、加熱してめっきＣ
ｕとＺｎ粉末を完全に拡散させることによってＺｎ−Ｃ
ｕ合金めっき（黄銅めっき）を施した鋼板が記載されて
いる（従来例Ａ）。■) Japanese Patent Application Laid-Open No. 49-011737 discloses that after Zn powder is adhered and coated on a Cu-plated steel plate, the plated C is coated by heating.
Zn-C by completely diffusing u and Zn powder
A steel plate with U alloy plating (brass plating) is described (Conventional Example A).
２）特開昭５３−０４６４３９号公報には、薄いＺｎめ
っきを施し、錆等の表面欠陥の発生を防止した鋼板上に
、ＡＩまたはＺｎ−Ａｌ合金粉末を付着被覆後、加熱、
焼結させることによってＡＩまたはＺｎ−Ａｌ合金めっ
きを施した綱板が記載されている（従来例Ｂ）。2) Japanese Patent Application Laid-Open No. 53-046439 discloses that after coating a steel plate with thin Zn plating to prevent surface defects such as rust, coating with AI or Zn-Al alloy powder, heating,
A steel plate plated with AI or Zn-Al alloy by sintering is described (Conventional Example B).
しかし、上記した従来例Ａ、Ｂ共に、加工性については
以下説明するような共通の問題をＩｒＬでいる。即ち、
操業中の加熱条件の僅かの変動によっても容易に従来例
Ａでは粉末Ｚｎの一部が素地鉄中に拡散し、また、従来
例日ではめっきＺｎの一部が素地鉄中に拡散し、めっき
層の素地鉄の界面に硬く、かつ、脆いＺｎ−Ｆｅ合金層
を形成するため、加工性が同一板厚、或いは、チャンス
毎でも大きくばらつく。However, both conventional examples A and B described above have a common problem with IrL in terms of workability, as will be explained below. That is,
In Conventional Example A, part of the powdered Zn easily diffuses into the base iron due to slight fluctuations in heating conditions during operation, and in Conventional Example A, part of the plated Zn diffuses into the base iron, causing the plating to deteriorate. Since a hard and brittle Zn--Fe alloy layer is formed at the interface of the base iron of the layer, the workability varies greatly even for the same sheet thickness or from one chance to another.
また、従来例ＢではＺｎ−Ａｌ合金粉末を使う場合、加
熱が不充分であると、合金粉末同士の接触面での拡散反
応が優先的に進むため、めっき層表面に組成むらが生じ
、ガルバニック腐蝕が起こり耐蝕性が劣化するという問
題がある。In addition, when using Zn-Al alloy powder in Conventional Example B, if heating is insufficient, the diffusion reaction proceeds preferentially at the contact surface between the alloy powders, resulting in compositional unevenness on the surface of the plating layer and galvanic There is a problem that corrosion occurs and corrosion resistance deteriorates.
第２図（ａＸｂ）に上記した従来例ＡおよびＢの断面図
を示しであるが、第２図（ａ）の従来例Ａにおいては、
素地鉄１１とＺｎ−Ａｌ合金層１３の間にＺｎ−Ｆｃ合
金層１２か存在しており、また、第２図（ｂ）の従来例
Ｂにおいては、素地鉄１１の上にＺｎの電気めっき層１
４およびその上にＺｎ−Ａｌ合金層１５を（ｆしている
が、素地鉄１１とＺｎ電気めっき層１４の間にＺｎ−Ｆ
ｅ合金層１４が存在していることがわかる。そして、ボ
ールインパクト試験によれば、従来例ＡＳＢともに広い
範囲に剥離が認められるランク４であり、表面光沢は［
」視によると従来例へではやや不良、従来例Ｂでは良好
であった。FIG. 2(aXb) shows cross-sectional views of the conventional examples A and B described above, and in the conventional example A of FIG. 2(a),
A Zn-Fc alloy layer 12 exists between the base iron 11 and the Zn-Al alloy layer 13, and in conventional example B shown in FIG. 2(b), Zn electroplating is performed on the base iron 11. layer 1
4 and a Zn-Al alloy layer 15 thereon (f), but between the base iron 11 and the Zn electroplated layer 14
It can be seen that the e-alloy layer 14 is present. According to the ball impact test, both conventional ASBs were ranked 4 with peeling observed in a wide range, and the surface gloss was [
According to the results, the conventional example was slightly poor, and the conventional example B was good.
［発明か解決しようとする問題点］
本発明は上記に説明したような従来技術における種々の
問題点に鑑み、本発明考が鋭き研究を行い、検討を重ね
た結果、従来のめっき鋼板に比較して加工性に選れ、さ
らに、耐蝕性においてら優れ、その上、表面光沢ら良好
な耐蝕性、加工性に優れた多層合金めっき鋼板を開発し
たのである。[Problems to be Solved by the Invention] In view of the various problems in the prior art as explained above, the inventors of the present invention conducted intensive research and repeated examinations, and as a result, compared to conventional plated steel sheets, We have developed a multilayer alloy-plated steel sheet that has excellent processability, excellent corrosion resistance, and excellent surface gloss and excellent corrosion resistance and processability.
［問題点を解決するための手段］
本発明に係る耐蝕性、加工性に優れた多層合金めっき鋼
板は、
（１）Ｅ板上に、第１層としてＮｉ、 Ｃｏ、 Ｃｒ、
Ｃｕの純金属またはこれら純金属２種以上からなる合
金電気めっき芭、その上に、第２層として第１層の電気
めっき層の一部とＺｎ粉末の加熱合金化したＺｎ合金め
っき層を有していることを特徴とする耐蝕性、加工性に
優れた多層合金めっき鋼板を第１の発明とし、
（２）Ｂ板上に、第１層としてＮｌ、 Ｃｏ、 Ｃｒ、
Ｃｕの純金属またはこれら純金属２種以上からなる合金
と、Ｚｎとの合金の電気めっき層、その上に、第２層と
して第１層の電気めっき層の一部とＺｎ粉末の加熱合金
化したＺｎ合金めっき層を有していることを特徴とする
耐蝕性、加工性に優れた多層合金めっき鋼板を第２の発
明とし、
（３）ｌｉ板上に、第１層としてＮｉ、 Ｃｏ、Ｃｒ、
Ｃｕの純金属またはこれら純金属２種以上からなる合
金電気めっき層、その上に、第２層として第１層の電気
めっき層の一部とＺｎ粉末の加熱合金化したＺｎ合金め
っき層、さらに、その上に、Ｚｎ粉末を加熱したＺｎめ
っき層を有していることを特徴とする耐蝕性、加工性に
優れた多層合金めっき鋼板を第３の発明とし、
（４）ｗ４板上に、第１層としてＮｉ、 Ｃｏ、 Ｃｒ
、 Ｃｕの純金属またはこれら純金属２種以上からなる
合金と、Ｚｎとの合金の電気めっき層、その上に、第２
層として第１層の電気めっき層の一部とＺｒ。[Means for solving the problems] The multilayer alloy plated steel sheet with excellent corrosion resistance and workability according to the present invention includes: (1) Ni, Co, Cr, as the first layer on the E plate;
A pure metal of Cu or an alloy electroplating layer made of two or more of these pure metals, and a Zn alloy plating layer formed by heating and alloying a part of the electroplating layer of the first layer and Zn powder as a second layer thereon. The first invention is a multilayer alloy plated steel sheet with excellent corrosion resistance and workability, which is characterized by: (2) Nl, Co, Cr, Nl, Co, Cr,
An electroplated layer of a pure metal of Cu or an alloy of two or more of these pure metals and an alloy of Zn, and on top of that, a part of the electroplated layer of the first layer and Zn powder are heated and alloyed as a second layer. A second invention provides a multilayer alloy-plated steel sheet with excellent corrosion resistance and workability, which is characterized by having a Zn alloy plating layer, and (3) Ni, Co, as the first layer on the Li plate. Cr,
A pure metal of Cu or an alloy electroplating layer made of two or more of these pure metals; on top of that, a Zn alloy plating layer formed by heating and alloying Zn powder with a part of the electroplating layer of the first layer as a second layer; A third invention provides a multilayer alloy plated steel sheet with excellent corrosion resistance and workability, which is characterized by having a Zn plating layer formed by heating Zn powder thereon, (4) on a W4 plate, Ni, Co, Cr as the first layer
, an electroplated layer of a pure metal of Cu or an alloy of two or more of these pure metals, and an alloy of Zn;
A part of the electroplating layer of the first layer and Zr as a layer.
粉末の加熱合金化したＺｎ合金めっき層、さらに、その
上に、Ｚｎ粉末を加熱したＺｎめっき層を有しているこ
とを特徴とする耐蝕性、加工性に優れた多層合金めっき
鋼板を第４の発明とする４つの発明よりなるものである
。A fourth multilayer alloy-plated steel sheet with excellent corrosion resistance and workability, which is characterized by having a Zn alloy plating layer made by heating and alloying powder, and furthermore, a Zn plating layer made by heating Zn powder. This invention consists of four inventions.
本発明体る耐蝕性、加工性に浸れた多層合金めっき鋼板
について以下詳細に説明する。The multilayer alloy-plated steel sheet of the present invention, which has excellent corrosion resistance and workability, will be described in detail below.
即ち、Ｚｎ以外の特定の金属または合金或いはこれらの
金属、合金とＺｎとの合金を電気めっきした鋼板上にＺ
ｎ粉末を付着後、電気めっき層の一部が残存するように
加熱合金化して、Ｚｎ合金めっき層を有する鋼板は、加
工性が大幅に向上し、また、このＺｎ合金めっき層の上
にＺｎ粉末を加熱したＺｎめっき層を設けることにより
表面光沢も改善されるものである。That is, Z is applied onto a steel plate electroplated with a specific metal or alloy other than Zn, or an alloy of these metals or alloys with Zn.
After adhering the Zn powder, the steel plate is heated and alloyed so that a part of the electroplated layer remains, and the workability of the steel plate having the Zn alloy plating layer is greatly improved. Surface gloss is also improved by providing a Zn plating layer formed by heating the powder.
先ず、本発明に係る耐蝕性、加工性のに優れた多層合金
めっき鋼板の第１層について説明する。First, the first layer of the multilayer alloy plated steel sheet having excellent corrosion resistance and workability according to the present invention will be explained.
好適なめっき法としては、１）めっき欠陥の少ないこと
。２）付着量のコントロールが容易なこと。Suitable plating methods include: 1) Fewer plating defects. 2) The amount of adhesion can be easily controlled.
３）第１層金属または合金（Ｚｎとの合金も含む。）が
めつき可能なこと。3) The first layer metal or alloy (including alloy with Zn) can be plated.
が挙げられる。そして、種々のめっき法を検討したとこ
ろ、通常行なわれている電気めっき法が最適であること
がわかった。can be mentioned. After examining various plating methods, it was found that the commonly used electroplating method was optimal.
また、電気めっきする金属としては純ＺｎのようにＦｅ
と脆い合金層を作らず、かつ、Ｚｎ粉末と合金化した際
Ｚｎに比べて耐蝕性が著しく向上し、さらに、Ｚｎと素
地鉄との拡散合金化のバリア一層となり得るものとして
、Ｎｉ、Ｃｏ、Ｃｒ１Ｃｕの純金属またはこれらの金属
の２種以上の合金、また、上記した純金属、合金とＺｎ
との合金が好適なしのである。Also, as a metal to be electroplated, Fe like pure Zn is used.
Ni and Co do not form a brittle alloy layer and have significantly improved corrosion resistance compared to Zn when alloyed with Zn powder. , CrCu, or alloys of two or more of these metals, and the above pure metals, alloys, and Zn.
An alloy with is not suitable.
次に、第２層としては、電気めっき層の一部とＺｎ粉末
を加熱合金化して得られたＺｎ合金めっき層とするのは
、拡散によって得られる合金めっき層は、電気めっき法
により得られた合金めっき層に比べて表面の凹凸が大き
いため、そのアンカー効果により塗膜密着性が向上する
からである。Next, the second layer is a Zn alloy plating layer obtained by heating and alloying a part of the electroplating layer and Zn powder. This is because the surface roughness is larger than that of the alloy plating layer, so the anchor effect improves the adhesion of the coating.
さらに、第２層の上に第３層としてＺｎ粉末を加熱して
得られたＺｎめっき層を設けるのは、上記したように、
加熱により加熱合金化させためっき表面は、塗膜密着性
は良好ではあるが、表面光沢に劣る。従って、外観特性
が要求される時には、非拡散層のＺｎ粉末めっき層を設
けておくのである。ただし、合金粉末では粉末粒子の接
触面の近傍と内部の組成差が生じ易く、耐蝕性が劣化す
るのに対し、単一金属の粉末ではこれが防止できるので
、粉末としては純Ｚｎ粉末を使用するのである。また、
表面光沢をさらに向上させるためには、加熱前或いは加
熱後に冷間圧延を行うと良い。Furthermore, as mentioned above, providing the Zn plating layer obtained by heating Zn powder as the third layer on the second layer is
The plated surface alloyed by heating has good coating film adhesion, but is poor in surface gloss. Therefore, when appearance characteristics are required, a Zn powder plating layer as a non-diffusion layer is provided. However, with alloy powders, composition differences tend to occur between the vicinity of the contact surface and inside the powder particles, which deteriorates corrosion resistance, whereas with single metal powders this can be prevented, so pure Zn powder is used as the powder. It is. Also,
In order to further improve the surface gloss, cold rolling may be performed before or after heating.
第１図（ａＸｂ）に本発明に係る耐蝕性、加工性に優れ
た多層合金めっき鋼板の断面図を示す。FIG. 1 (aXb) shows a cross-sectional view of a multilayer alloy-plated steel sheet having excellent corrosion resistance and workability according to the present invention.
第１図（ａ）は素地鉄ｌの上にＮｉの電気めっき層２、
さらに、その上に、Ｚｎ−Ｎｉ合金層３が設けられてい
る。FIG. 1(a) shows a Ni electroplating layer 2 on a base iron l,
Furthermore, a Zn-Ni alloy layer 3 is provided thereon.
第１図（ｂ）は素地鉄ｌの上にＮｉの電気めっき層２、
その上に、Ｚｎ−Ｎｉ合金層３、さらに、その上に、Ｚ
ｎ粉末によるめっき層４が設けられている。FIG. 1(b) shows a Ni electroplating layer 2 on a base iron l,
On top of that, a Zn-Ni alloy layer 3, and further on top of that, a Zn-Ni alloy layer 3.
A plating layer 4 made of n powder is provided.
この本発明に係る耐蝕性、加工性に優れた多層合金めっ
き鋼板の第１図（ａＸｂ）は、ボールインパクト試験に
よると、加工性は亀裂、剥離が認められないランクｌで
あり、表面光沢は目視により第１図（ａ）はやや不良、
第１図（ｂ）は良好である。因に、ランク２は亀裂はあ
るが剥離は認められない。Figure 1 (aXb) of the multi-layer alloy coated steel sheet according to the present invention, which has excellent corrosion resistance and workability, shows that according to the ball impact test, the workability is rank 1 with no cracks or peeling observed, and the surface gloss is By visual inspection, Fig. 1 (a) is slightly defective.
FIG. 1(b) is good. Incidentally, rank 2 has cracks but no peeling is observed.
ランク３は僅かに剥離が認められる。５は大部分剥離し
ている（このランクは第２図の場合も同じである）。Rank 3 shows slight peeling. No. 5 is mostly peeled off (this rank is the same in the case of FIG. 2).
［実 施 例コ
本発明に係る耐蝕性、加工性に優れた多層合金めっき鋼
板の実施例を説明する。[Example] An example of a multilayer alloy-plated steel plate having excellent corrosion resistance and workability according to the present invention will be described.
実施例
板厚０ 、８ ｍｍのアルミニウムキルド鋼を素材とし
、第１表に示す条件によって製造した本発明に係る耐蝕
性、加工性に優れた多層合金めっき鋼板と比較材の各種
特性の比較結果を第２表に示す。Comparison results of various properties of a multilayer alloy plated steel sheet with excellent corrosion resistance and workability according to the present invention manufactured using aluminum killed steel with a thickness of 0 or 8 mm under the conditions shown in Table 1 and a comparative material. are shown in Table 2.
この第２表から、本発明に係る耐蝕性、加工性に優れた
多層合金めっき鋼板は、比較材に比べて加工性に優れて
おり、かつ、他の特性についても同等以上の効果がある
ことがわかる。From this Table 2, it can be seen that the multilayer alloy-plated steel sheet of the present invention, which has excellent corrosion resistance and workability, has excellent workability compared to comparative materials, and has the same or better effects on other properties. I understand.
［発明の効果コ
以上説明したように、本発明に係る耐蝕性、加工性に優
れた多層合金めっき鋼板は上記の構成であるから、耐蝕
性および加工性に極めて優れており、さらに、表面光沢
にも優れた効果を有するものである。[Effects of the Invention] As explained above, the multilayer alloy-plated steel sheet of the present invention, which has excellent corrosion resistance and workability, has the above structure, so it has extremely excellent corrosion resistance and workability, and also has a high surface gloss. It also has excellent effects.
第１図は本発明に係る耐蝕性、加工性に優れた多層合金
めっき鋼板の概略断面図、第２図は比較例の概略断面図
である。
１．１１〜鉄素地、２．１４〜電気めっき層、３．１３
．１５〜合金合金４〜粉末層。
１′１ Ｎ
矛２図
手続補正書（自発）
１、事件の表示
昭和６２年特許願第００９３９５号
２、発明の名称
耐蝕性、加工性に優れた多層合金めっき鋼板３、補正を
する者
事件との関係 特許出願人
住所 神戸市中央区脇浜町Ｉ下目３番！８号名称 （１
１９） 株式会社 神戸製鋼所代表者 牧 冬
彦
４、代理人
住所 東京都江東区南砂２丁目２番１５号藤和東陽町コ
ープ９０１号
〒１３６電話（６４６） ６１９４
−１、氏名 弁理士 （６９３７） 丸 木 良
久５、補正命令の日付 （自発）
６、補正の対象
（１）明細書の特許請求の範囲の欄
（２）明細書の発明の詳細な説明の欄
７、補正の内容
別紙の通り
（１）特許請求の範囲を次のように補正する。
「（１）鋼板上に、第１層としてＮｊ、Ｃｏ１Ｃｒ１Ｃ
ｕの純金属またはこれら純金属２種以上からなる合金電
気めっき層、その上に、第２層として第１層の電気めっ
き層の一部とＺｎ粉末の加熱合金化したＺｎ合金めっき
層を有していることを特徴とする耐蝕性、加工性に優れ
た多層合金めっき鋼板。
（２）鋼板上に、第１層としてＮｉ、Ｃｏ、Ｃｒ５Ｃｕ
の１種または２種以上と、Ｚｎとの合金の電気めっき層
、その上に、第２層として第１層の電気めっき層の一部
とＺｎ粉末の加熱合金化したＺｎ合金めっき層を有して
いることを特徴とする耐蝕性、加工性に優れた多層合金
めっき鋼板。
（３）鋼板上に、第１層としてＮｉ、 Ｃｏ、 Ｃｒ、
Ｃｕの純金属またはこれら純金属２種以上からなる合金
電気めっき層、その上に、第２層として第１層の電気め
っき層の一部とＺｎ粉末の加熱合金化１゜たＺｎ合金め
っき層、さらに、その上に、Ｚｎ粉末を加熱したＺｎめ
っき層を有していることを特徴とする耐蝕性、加工性に
優れた多層合金めっき鋼（４）＄１板上に、第１層とし
てＮｉ、 Ｃｏ、 Ｃｒ、 Ｃｕの１種または２種以上
と、Ｚｎとの合金の電気めっき層、その上に、第２層と
して第１層の電気めっき層の一部とＺｎ粉末の加熱合金
化したＺｎ合金めっき層、さらに、その上に、Ｚｎ粉末
を加熱したＺｎめっき層を有していることを特徴とする
耐蝕性、加工性に優れた多層合金めっき鋼板。」（２）
明細書第５頁９行のｒＺｎ−Ａ１合金層１３Ｊを「Ｚｎ
−Ｃｕ合金層＋３Ｊと補正する。
（３）明細書第６頁８行〜同第７頁２０行の「本発明に
・・・発明よりなるものである。」を「本発明に係る耐
蝕性、加工性に優れた多層合金めっき鋼板は、
（１）Ｉ板上に、第１層としてＮｉ、 Ｃｏ、 Ｃｒ、
Ｃｕの純金属またはこれら純金属２種以上からなる合
金電気めっき層、その上に、第２層として第１層の電気
めっき層の一部とＺｎ粉末の加熱合金化したＺｎ合金め
っき層を有していることを特徴とする耐蝕性、加工性に
優れた多層合金めっき鋼板を第１の発明とし、
（２）鋼板上に、第１層としてＮｉ、 Ｃｏ、Ｏｒ、
Ｃｕの１種または２種以上と、Ｚｎとの合金の電気めっ
き層、その上に、第２層として第１層の電気めっき層の
一部とＺｎ粉末の加熱合金化したＺｎ合金めっき層を有
していることを特徴とする耐蝕性、加工性に優れた多層
合金めっき鋼板を第２の発明とし、（３）８板上に、第
１層としてＮｉ５Ｃｏ、Ｃｒ、Ｃｕの純金属または、こ
れら純金属２種以上からなる合金電気めっき層、その上
に、第２層として第１層の電気めっき層の一部とＺｎ粉
末の加熱合金化したＺｎ合金めっき層、さらに、その上
に、Ｚｎ粉末を加熱したＺｎめっき層を有していること
を特徴とする耐蝕性、加工性に優れた多層合金めっき鋼
板を第３の発明とし、
（４）鋼板上に、第１層としてＮｉ５Ｃｏ、Ｃｒ、Ｃｕ
の１種または２種以上と、Ｚｎとの合金の電気めっき層
、その上に、第２層として第１層の電気めっき層の一部
とＺｎ粉末の加熱合金化したＺｎ合金めっき層、さらに
、その上に、Ｚｎ粉末を加熱したＺｎめっき層を有して
いることを特徴とする耐蝕性、加工性に優れた多層合金
めっき鋼板を第４の発明とする４つの発明よりなるもの
である。」と補正する。FIG. 1 is a schematic sectional view of a multilayer alloy plated steel sheet with excellent corrosion resistance and workability according to the present invention, and FIG. 2 is a schematic sectional view of a comparative example. 1.11 ~ iron base, 2.14 ~ electroplating layer, 3.13
．． 15~Alloy Alloy 4~Powder layer. 1'1 N Procedural amendment to Figure 2 (voluntary) 1. Indication of the case 1988 Patent Application No. 009395 2. Name of the invention Multi-layer alloy plated steel plate with excellent corrosion resistance and workability 3. Case of the person making the amendment Relationship with Patent Applicant Address No. 3, Wakihama-cho I, Chuo-ku, Kobe City! No. 8 name (1
19) Kobe Steel, Ltd. Representative: Fuyuhiko Maki 4, Agent Address: 901 Fujiwa Toyocho Co-op, 2-2-15 Minamisuna, Koto-ku, Tokyo Address: 136 Telephone (646) 6194-1 Name: Patent Attorney (6937) Ryo Maruki
5. Date of amendment order (voluntary) 6. Subject of amendment (1) Scope of claims in the specification (2) Detailed explanation of the invention in the specification ) The scope of claims is amended as follows. (1) Nj, Co1Cr1C as the first layer on the steel plate
A pure metal or an alloy electroplating layer made of two or more of these pure metals, and on top of that, a Zn alloy plating layer formed by heat-alloying Zn powder with a part of the electroplating layer of the first layer as a second layer. A multilayer alloy plated steel sheet with excellent corrosion resistance and workability. (2) Ni, Co, Cr5Cu as the first layer on the steel plate
an electroplated layer of an alloy of one or more of the above and Zn, and a Zn alloy plating layer formed by heat-alloying a part of the electroplated layer of the first layer and Zn powder as a second layer thereon. A multilayer alloy plated steel sheet with excellent corrosion resistance and workability. (3) Ni, Co, Cr, as the first layer on the steel plate
A pure metal of Cu or an alloy electroplating layer made of two or more of these pure metals, and on top of that, a Zn alloy plating layer formed by heat alloying 1° of Zn powder with a part of the electroplating layer of the first layer as a second layer. , Furthermore, a multilayer alloy plated steel with excellent corrosion resistance and workability, which is characterized by having a Zn plating layer made by heating Zn powder thereon (4) $1 As the first layer on the plate. An electroplated layer of an alloy of one or more of Ni, Co, Cr, and Cu and Zn, and on top of that, a part of the first electroplated layer and Zn powder are heated and alloyed as a second layer. A multilayer alloy-plated steel sheet having excellent corrosion resistance and workability, characterized in that it has a Zn alloy plating layer and further a Zn plating layer formed by heating Zn powder. ”(2)
The rZn-A1 alloy layer 13J on page 5, line 9 of the specification is
-Cu alloy layer +3J is corrected. (3) From page 6, line 8 to page 7, line 20 of the specification, "the present invention consists of..." was replaced with "the multilayer alloy plating with excellent corrosion resistance and workability according to the present invention." The steel plate includes: (1) Ni, Co, Cr, as the first layer on the I plate;
A pure metal of Cu or an alloy electroplating layer made of two or more of these pure metals, and a Zn alloy plating layer formed by heating and alloying Zn powder with a part of the electroplating layer of the first layer as a second layer. The first invention is a multilayer alloy plated steel sheet with excellent corrosion resistance and workability, which is characterized by: (2) Ni, Co, Or, Ni, Co, Or,
An electroplated layer of an alloy of one or more types of Cu and Zn, and on top of that, a Zn alloy plating layer that is heat-alloyed with a part of the electroplated layer of the first layer and Zn powder as a second layer. A second invention provides a multilayer alloy plated steel sheet with excellent corrosion resistance and workability, and (3) on the 8 sheets, a pure metal of Ni5Co, Cr, Cu or, An alloy electroplating layer made of two or more of these pure metals, on top of which a second layer a Zn alloy plating layer formed by heating and alloying Zn powder with a part of the electroplating layer of the first layer, further on top of that, A third invention provides a multilayer alloy plated steel sheet with excellent corrosion resistance and workability, which is characterized by having a Zn plating layer made by heating Zn powder, (4) Ni5Co as a first layer on the steel sheet, Cr,Cu
an electroplated layer of an alloy of one or more of the above and Zn; on top of that, a second layer of a Zn alloy plating layer formed by heating and alloying Zn powder with a part of the electroplating layer of the first layer; The fourth invention is a multilayer alloy-plated steel sheet with excellent corrosion resistance and workability, which is characterized by having a Zn plating layer formed by heating Zn powder thereon. . ” he corrected.
Claims (3)
の純金属またはこれら純金属２種以上からなる合金電気
めっき層、その上に、第２層として第１層の電気めっき
層の一部とＺｎ粉末の加熱合金化したＺｎ合金めっき層
を有していることを特徴とする耐蝕性、加工性に優れた
多層合金めっき鋼板。(1) Ni, Co, Cr, Cu as the first layer on the steel plate
A pure metal or an alloy electroplating layer made of two or more of these pure metals, and a Zn alloy plating layer formed by heat-alloying Zn powder with a part of the electroplating layer of the first layer as a second layer thereon. A multilayer alloy plated steel sheet with excellent corrosion resistance and workability.
の純金属またはこれら純金属２種以上からなる合金と、
Ｚｎとの合金の電気めっき層、その上に、第２層として
第１層の電気めっき層の一部とＺｎ粉末の加熱合金化し
たＺｎ合金めっき層を有していることを特徴とする耐蝕
性、加工性に優れた多層合金めっき鋼板。(2) Ni, Co, Cr, Cu as the first layer on the steel plate
or an alloy consisting of two or more of these pure metals,
Corrosion resistant, characterized in that it has an electroplated layer of an alloy with Zn, and a Zn alloy plating layer formed by heat-alloying Zn powder with a part of the electroplated layer of the first layer as a second layer thereon. Multi-layer alloy plated steel sheet with excellent strength and workability.
の純金属またはこれら純金属２種以上からなる合金電気
めっき層、その上に、第２層として第１層の電気めっき
層の一部とＺｎ粉末の加熱合金化したＺｎ合金めっき層
、さらに、その上に、Ｚｎ粉末を加熱したＺｎめっき層
を有していることを特徴とする耐蝕性、加工性に優れた
多層合金めっき鋼板。（４）鋼板上に、第１層としてＮ
ｉ、Ｃｏ、Ｃｒ、Ｃｕの純金属またはこれら純金属２種
以上からなる合金と、Ｚｎとの合金の電気めっき層、そ
の上に、第２層として第１層の電気めっき層の一部とＺ
ｎ粉末の加熱合金化したＺｎ合金めっき層、さらに、そ
の上に、Ｚｎ粉末を加熱したＺｎめっき層を有している
ことを特徴とする耐蝕性、加工性に優れた多層合金めっ
き鋼板。(3) Ni, Co, Cr, Cu as the first layer on the steel plate
A pure metal or an alloy electroplating layer made of two or more of these pure metals, on which, as a second layer, a Zn alloy plating layer formed by heating and alloying Zn powder with a part of the electroplating layer of the first layer, further, A multilayer alloy plated steel sheet with excellent corrosion resistance and workability, characterized by having a Zn plating layer formed by heating Zn powder thereon. (4) N as the first layer on the steel plate
i, Co, Cr, Cu, or an alloy consisting of two or more of these pure metals, and an electroplated layer of an alloy with Zn, and on top of that, a part of the first electroplated layer as a second layer. Z
A multilayer alloy-plated steel sheet with excellent corrosion resistance and workability, characterized by having a Zn alloy plating layer formed by heating and alloying N powder, and further thereon a Zn plating layer formed by heating Zn powder.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP939587A JPH0639716B2 (en) | 1987-01-19 | 1987-01-19 | Multi-layer alloy plated steel sheet with excellent corrosion resistance and workability |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP939587A JPH0639716B2 (en) | 1987-01-19 | 1987-01-19 | Multi-layer alloy plated steel sheet with excellent corrosion resistance and workability |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63179083A true JPS63179083A (en) | 1988-07-23 |
| JPH0639716B2 JPH0639716B2 (en) | 1994-05-25 |
Family
ID=11719237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP939587A Expired - Lifetime JPH0639716B2 (en) | 1987-01-19 | 1987-01-19 | Multi-layer alloy plated steel sheet with excellent corrosion resistance and workability |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0639716B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020120701A1 (en) * | 2018-12-14 | 2020-06-18 | Volkswagen Aktiengesellschaft | Sheet metal blank for producing a heat-shaped and press-hardened steel sheet component and heat-shaping method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4942972B2 (en) * | 2005-09-27 | 2012-05-30 | 株式会社ジェイテクト | Ball bearing cage and ball bearing |
-
1987
- 1987-01-19 JP JP939587A patent/JPH0639716B2/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020120701A1 (en) * | 2018-12-14 | 2020-06-18 | Volkswagen Aktiengesellschaft | Sheet metal blank for producing a heat-shaped and press-hardened steel sheet component and heat-shaping method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0639716B2 (en) | 1994-05-25 |
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