JPS63159587A - Opearl processing method of polyester cloth - Google Patents

Opearl processing method of polyester cloth

Info

Publication number
JPS63159587A
JPS63159587A JP61303255A JP30325586A JPS63159587A JP S63159587 A JPS63159587 A JP S63159587A JP 61303255 A JP61303255 A JP 61303255A JP 30325586 A JP30325586 A JP 30325586A JP S63159587 A JPS63159587 A JP S63159587A
Authority
JP
Japan
Prior art keywords
acid
polyester
polyester fibers
fibers
fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP61303255A
Other languages
Japanese (ja)
Inventor
森 辰治郎
芝田 光雄
義則 佐藤
西沢 洋和
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Rayon Co Ltd
Original Assignee
Mitsubishi Rayon Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Rayon Co Ltd filed Critical Mitsubishi Rayon Co Ltd
Priority to JP61303255A priority Critical patent/JPS63159587A/en
Publication of JPS63159587A publication Critical patent/JPS63159587A/en
Pending legal-status Critical Current

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  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Decoration Of Textiles (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 (激業上の利用分野) 本発明は、オパール加工法に係り、更に詳しくは、レギ
ュラーポリエステル繊維と常圧可染型ポリエステル繊維
よりll成された布帛に、透し模様を付与するポリエス
テル布帛のオパール加工法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of practical application) The present invention relates to an opal processing method, and more specifically, the present invention relates to an opal processing method, and more specifically, to a fabric made of regular polyester fibers and atmospheric pressure dyeable polyester fibers. This invention relates to an opal processing method for polyester fabric that imparts a pattern.

(従来の技術) 従来、オパール加工は耐薬品性のある繊維、例えばポリ
エステル繊維と硫酸等の薬品により分解又は溶解する繊
維、例えはジアセテート繊維を交撚、もしくは交織編さ
れた布帛をその一方の繊維を薬品で抜食して布帛の一部
に透し模様を得る方法である。
(Prior art) Conventionally, opal processing involves fabrics made by twisting or knitting chemically resistant fibers, such as polyester fibers, and fibers that can be decomposed or dissolved by chemicals such as sulfuric acid, such as diacetate fibers. This is a method to obtain a transparent pattern on a part of the fabric by removing the fibers with chemicals.

しかし、これらの方法は著しく性質の異なった繊維を使
用するため、色合せの困難度、染色竪牢度、物性特に収
縮差等の品質問題かあった。
However, since these methods use fibers with significantly different properties, there are quality problems such as difficulty in color matching, dyeing depth, and differences in physical properties, especially shrinkage.

一方、近年、ポリエステル繊維100僑からなる布帛の
抜食加工法(%公開61−27518号公報〕が提案さ
れているが、同方法だと、一方のレギュラーポリエステ
ル繊維も同時に減量され、透し模様部分の強度が低下し
、物性面からも満足するに至っていない。
On the other hand, in recent years, a method for cutting out fabrics made of 100 polyester fibers has been proposed (% Publication No. 61-27518), but with this method, one of the regular polyester fibers is also reduced at the same time, resulting in a transparent pattern. The strength of the part decreased, and the physical properties were not satisfactory.

(発明が解決しようとする問題点) 本発明は、ポリエステル繊維100%からなる布帛にお
けるこの様な問題点を解決し、ポリエステル繊維の優れ
た機能を保持した透し模様を有するポリエステル布帛を
得る方法を提供するものである。
(Problems to be Solved by the Invention) The present invention solves these problems in fabrics made of 100% polyester fibers, and provides a method for obtaining polyester fabrics with openwork patterns that retain the excellent functions of polyester fibers. It provides:

(問題点を解決するための手段) 本発明はレギュラーポリエステル繊維と常圧可染型ポリ
エステル繊維より構成され九布帛に、有機酸又は無機酸
を含む捺染糊を印捺し常圧可染型ポリエステル繊維のみ
を脆化させたのち、金属水酸化物によジアルカリ減量を
行ない常圧可染型ポリエステル繊維を抜食せしめること
を特徴とするポリエステル布帛のオパール加工法にある
(Means for Solving the Problems) The present invention consists of regular polyester fibers and atmospheric pressure dyeable polyester fibers, and printing paste containing organic acid or inorganic acid is printed on nine fabrics to produce atmospheric pressure dyeable polyester fibers. The present invention is directed to an opal processing method for polyester fabric, which is characterized in that after embrittling the polyester fabric, dialkali reduction is performed using a metal hydroxide to remove the pressure-dyeable polyester fiber.

以下本発明を更に詳しく説明する。The present invention will be explained in more detail below.

本発明は、レギュラーポリエステル繊維と常圧可染型ポ
リエステル繊維より構成した布帛を酸を含む捺染糊で印
捺、蒸熱処理により、その部分の常圧可染をポリエステ
ル繊維を脆化せしめる、この時レギュラーポリエステル
繊維は何ら変化せず、その物性も安定している。しかる
後、金属水酸化物によりアルカリ減量を行ない、常圧可
染型ポリエステル繊維のみを抜食して、透し模様を得る
ものである。
The present invention involves printing a fabric composed of regular polyester fibers and pressure-dyeable polyester fibers with a printing paste containing an acid, and applying heat treatment to make the pressure-dyeable polyester fibers brittle. Regular polyester fibers do not change at all and their physical properties are stable. Thereafter, alkali reduction is performed using a metal hydroxide, and only the pressure-dyeable polyester fibers are extracted to obtain a transparent pattern.

本発明において、レギュラーポリエステル繊維とは、一
般の衣料用ポリエステル繊維であシテレフタル酸を主た
る酸成分とし、炭素数2〜6のアルキレングリコール、
特に好ましくはエチレングリコール又はテトラメチレン
グリコールを主たるグリコール成分とするポリエステル
からなる繊維である。一方、常圧可染型ポリエステル繊
維とは、上記ポリエステルに第三成分として種々の改良
物質を共重合した重合体からなる繊維であり、具体的に
5−ナトリウムスルホイン7タル酸、インフタル酸、ア
ジピン酸、スルホインフタル酸、P−オキシ安息香酸、
ナフタリン−2,6−ジカルボン酸、セパチン酸、1−
4ブタンジオール、P−Bオキシエトキシ安息香酸、シ
クロヘキサンジカルボン酸、ネオペンチルグリコール等
公矧の共重合成分をあげることができる。特に本発明で
はスルホン酸基を含む物質を共重合させた塩基性可染型
ポリエステル繊維が好ましく用いられる0本発明で使用
する捺染糊に含まれる酸とは、水溶液中に水素イオンを
生じてリドマス試験紙で酸性反応を呈するものであや、
使用する酸として、無機類では塩酸、硫酸、ギ酸等があ
り、有機酸類として修酸、酒石酸等をあけることができ
る。
In the present invention, regular polyester fibers are general polyester fibers for clothing that contain cyterephthalic acid as the main acid component, alkylene glycol having 2 to 6 carbon atoms,
Particularly preferred are fibers made of polyester whose main glycol component is ethylene glycol or tetramethylene glycol. On the other hand, atmospheric pressure dyeable polyester fiber is a fiber made of a polymer obtained by copolymerizing the above polyester with various improving substances as a third component, and specifically, 5-sodium sulfoin heptathalic acid, inphthalic acid, Adipic acid, sulfoinphthalic acid, P-oxybenzoic acid,
naphthalene-2,6-dicarboxylic acid, cepatic acid, 1-
Examples include common copolymerization components such as 4-butanediol, P-B oxyethoxybenzoic acid, cyclohexanedicarboxylic acid, and neopentyl glycol. In particular, in the present invention, basic dyeable polyester fibers copolymerized with a substance containing sulfonic acid groups are preferably used. The acid contained in the printing paste used in the present invention is the acid that produces hydrogen ions in an aqueous solution and produces lidomas. It is a substance that exhibits an acidic reaction with the test paper.
Examples of acids that can be used include inorganic acids such as hydrochloric acid, sulfuric acid, and formic acid, and organic acids such as oxalic acid and tartaric acid.

又、本発明において使用する金属水酸化物とは、ナトリ
ウム、カリウム、バリウム等水酸基とだけ結合した化合
物であり、リドマス試験紙でアルカリ性を呈するもので
ある。更に本発明で使用する捺染糊に用いる糊剤は、プ
リント時に使用する糊剤であり、薬品、助剤染料等と混
合しても、それ自体か反応することのない不活性のもの
が良好であり、繊維に対して接着性がよく、除去しやす
いもので、トラカントゴム、アルギン酸ンーダ、ローカ
ストビーンガム、メチルセルロース、ナフカクリスタル
ガム、澱粉等があげられる。
Further, the metal hydroxide used in the present invention is a compound bonded only to a hydroxyl group such as sodium, potassium, barium, etc., and exhibits alkalinity on Lidomus test paper. Furthermore, the sizing agent used in the printing paste used in the present invention is the sizing agent used during printing, and is preferably an inert material that does not react with itself even when mixed with chemicals, auxiliary dyes, etc. They have good adhesion to fibers and are easy to remove, such as tracanth gum, alginate, locust bean gum, methyl cellulose, naphka crystal gum, and starch.

上記の様な、酸と糊剤を配合してなる捺染糊をポリエス
テル布帛に印捺し、乾燥後、湿熱にて加熱処理して、常
圧可染型ポリエステル繊維を脆化させ、金属水酸化物に
よるアルカリ減量により、常圧可染型ポリエステル繊維
のみを溶解除去し透し模様を得る。
A printing paste made by blending an acid and a sizing agent as described above is printed on a polyester fabric, and after drying, it is heat-treated with moist heat to embrittle the atmospheric pressure dyeable polyester fiber and produce metal hydroxide. Due to alkali weight loss, only the pressure-dyeable polyester fibers are dissolved and removed to obtain a transparent pattern.

(作用) 以上説明したように、本発明では、印捺部分の常圧可染
型ポリエステル繊維のみを溶解し、レギュラーポリエス
テル繊維も同時にアルカリ減量され、艮好な風合の布帛
が得られ、しかも透し模様の部分の強夏低下もなく、形
態安定性もよい、又、布帛構成自体がポリエステル繊維
100%布帛のため、染色堅牢度、物性関係も製品とし
て何ら遜色のないものである。
(Function) As explained above, in the present invention, only the pressure-dyeable polyester fibers in the printing area are dissolved, and the regular polyester fibers are also reduced by alkali at the same time, and a fabric with a nice texture is obtained. There is no loss of strength in the transparent pattern area, and the shape stability is good.Also, since the fabric itself is made of 100% polyester fiber, the color fastness and physical properties are comparable to those of other products.

(実施例) 次に、本発明を実施例をあげ説明する。(Example) Next, the present invention will be explained by giving examples.

実施例 経糸にSod/24fのレギュラーポリエステル糸と5
0d156fの5−ナトリウムスルホ1ン7タル酸共重
合の塩基性可染型ポリエステル糸を、600T/Mの撚
をかけ、緯糸には経糸と同じものを使用し、経密度12
0本/寸、緯@反120本/寸の平織物を50m製織し
た。
Example Warp: Sod/24f regular polyester yarn and 5
0d156f 5-sodium sulfone 7-talic acid copolymerized basic dyeable polyester yarn is twisted at 600T/M, the weft is the same as the warp, and the warp density is 12.
50 m of plain woven fabric with a weft of 0 threads/dimension and a weft of 120 threads/dimension was woven.

この生機を、通常のプリント下晒工程で加工し、本発明
による処理による方法と、通常の下記の様な工程及び条
件で加工した。
This gray fabric was processed through a normal print pre-bleaching process, and processed using the treatment method according to the present invention and the normal process and conditions described below.

加工工程: 生機−糊抜一精練一仕上セット 加工条件: 糊抜、精練、仕上セット(160℃)は通常のレギュラ
ーポリエステル繊維100嗟の加工条件に準拠した。
Processing process: Gray fabric - desizing, scouring, and finishing set Processing conditions: Desizing, scouring, and finishing set (160°C) were based on the processing conditions for 100 hours of normal regular polyester fiber.

次いで、下記組成の捺染糊を印捺し、捺染台上にて風乾
し、スタースチーマ−にて120℃で20分間蒸熱処理
を行ない、水洗乾燥した。
Next, a printing paste having the following composition was printed, air-dried on a printing table, steamed at 120° C. for 20 minutes in a star steamer, and washed with water and dried.

捺染糊組成 糊剤 ラメクリスタルガム   70部酸  酒石酸 
        20 計           100部(重量)さらに水酸
化ナトリウム201/を水溶液にて、90℃で60分、
アルカリ減量を行なったところ、印捺部分の塩基性可染
製ポリエステルが俗解除去される同時に、レギュラーポ
リエステル繊維も減量され、艮好な透し模様のある艮好
な風合のポリエステル布帛が得られた。
Printing paste composition Thickening agent Lame crystal gum 70 parts acid Tartaric acid
20 A total of 100 parts (weight) and 201 parts of sodium hydroxide in an aqueous solution at 90°C for 60 minutes.
When alkali weight loss was carried out, the basic dyeable polyester in the printed area was removed, and at the same time, the regular polyester fibers were also reduced, resulting in a polyester fabric with a nice texture and a nice transparent pattern. It was done.

尚、同捺染糊のみでは、透し模様は得られなかった。Note that a transparent pattern could not be obtained using the same printing paste alone.

この布帛に透し模様を得るためには、水酸化ナトリウム
の使用量を25部以上必登とし、この条件で加工した場
合は、レギュラーポリエステル糸も加水分解され、この
ため、柄部分の強度が低下したものであった。
In order to obtain an openwork pattern on this fabric, the amount of sodium hydroxide used must be at least 25 parts, and when processed under these conditions, the regular polyester thread will also be hydrolyzed, which will reduce the strength of the pattern. It was a decline.

(発明の効果) 本発明によれは、ポリエステル布帛に透し模様のある繊
維製品を得ることができ、その構成繊維がポリエステル
繊維100%からなるため強度等の物性、及び染色堅牢
度の艮好なものが得られ、しかも、アルカリ減量、熱処
理等の風合変化を付与することも容易でちゃ、広範囲に
用途展開が可能である。
(Effects of the Invention) According to the present invention, it is possible to obtain a textile product with a see-through pattern on a polyester fabric, and since its constituent fibers are made of 100% polyester fiber, physical properties such as strength and color fastness are improved. It can be used in a wide range of applications because it can be easily modified by alkali weight loss, heat treatment, etc.

代理人 弁理士  告 沢 敏 夫 手続補正書 昭和62年6月 1日Agent: Patent Attorney: Toshio Sawa Procedural amendment June 1, 1985

Claims (1)

【特許請求の範囲】[Claims] レギュラーポリエステル繊維と常圧可染型ポリエステル
繊維より構成された布帛に、有機酸又は無機酸類を含む
捺染糊を印捺し常圧可染型ポリエステル繊維を脆化させ
たのち、金属水酸化物によりアルカリ減量を行ない常圧
可染型ポリエステル繊維を抜食せしめることを特徴とす
るポリエステル布帛のオパール加工法。
A fabric made of regular polyester fibers and pressure-dyeable polyester fibers is printed with a printing paste containing organic or inorganic acids to make the pressure-dyeable polyester fibers brittle, and then dyed with alkali using metal hydroxide. A method for opalizing polyester fabric, which is characterized by reducing the weight and eliminating the pressure-dyeable polyester fiber.
JP61303255A 1986-12-19 1986-12-19 Opearl processing method of polyester cloth Pending JPS63159587A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61303255A JPS63159587A (en) 1986-12-19 1986-12-19 Opearl processing method of polyester cloth

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61303255A JPS63159587A (en) 1986-12-19 1986-12-19 Opearl processing method of polyester cloth

Publications (1)

Publication Number Publication Date
JPS63159587A true JPS63159587A (en) 1988-07-02

Family

ID=17918749

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61303255A Pending JPS63159587A (en) 1986-12-19 1986-12-19 Opearl processing method of polyester cloth

Country Status (1)

Country Link
JP (1) JPS63159587A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04106319A (en) * 1990-08-28 1992-04-08 Matsushita Electric Ind Co Ltd Electrical cooking device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04106319A (en) * 1990-08-28 1992-04-08 Matsushita Electric Ind Co Ltd Electrical cooking device

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