JPS63154605A - Emulsified type cosmetic - Google Patents
Emulsified type cosmeticInfo
- Publication number
- JPS63154605A JPS63154605A JP30108286A JP30108286A JPS63154605A JP S63154605 A JPS63154605 A JP S63154605A JP 30108286 A JP30108286 A JP 30108286A JP 30108286 A JP30108286 A JP 30108286A JP S63154605 A JPS63154605 A JP S63154605A
- Authority
- JP
- Japan
- Prior art keywords
- alcohol
- skin
- oil
- cream
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000126 substance Substances 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 claims description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 abstract description 16
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 abstract description 14
- 239000006071 cream Substances 0.000 abstract description 9
- 229960000541 cetyl alcohol Drugs 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 7
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 abstract description 7
- -1 lauryl alcohol sulfosuccinic acid ester Chemical class 0.000 abstract description 5
- 235000019198 oils Nutrition 0.000 abstract description 5
- 239000004615 ingredient Substances 0.000 abstract description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 abstract description 3
- 235000019197 fats Nutrition 0.000 abstract description 3
- 239000002884 skin cream Substances 0.000 abstract description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 abstract description 3
- 235000013336 milk Nutrition 0.000 abstract description 2
- 239000008267 milk Substances 0.000 abstract description 2
- 210000004080 milk Anatomy 0.000 abstract description 2
- 239000003883 ointment base Substances 0.000 abstract description 2
- 229920002545 silicone oil Polymers 0.000 abstract description 2
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 abstract 2
- 238000004321 preservation Methods 0.000 abstract 2
- 235000019737 Animal fat Nutrition 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 239000003906 humectant Substances 0.000 abstract 1
- 235000019871 vegetable fat Nutrition 0.000 abstract 1
- 230000001953 sensory effect Effects 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 12
- 239000003995 emulsifying agent Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 239000003945 anionic surfactant Substances 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000005856 abnormality Effects 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000014121 butter Nutrition 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 230000001815 facial effect Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000013112 stability test Methods 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- BFUTYTCDHCOXGG-UHFFFAOYSA-N 14,16,18,20,22,25,26,28,30-nonahydroxy-15,31-dimethyl-32-propan-2-yl-1-oxacyclodotriaconta-3,5,7,9,11-pentaen-2-one Chemical compound CC(C)C1OC(=O)C=CC=CC=CC=CC=CCC(O)C(C)C(O)CC(O)CC(O)CC(O)CCC(O)C(O)CC(O)CC(O)C1C BFUTYTCDHCOXGG-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004264 Petrolatum Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 241000931191 Scincidae Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003026 cod liver oil Substances 0.000 description 1
- 235000012716 cod liver oil Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 229940031569 diisopropyl sebacate Drugs 0.000 description 1
- XFKBBSZEQRFVSL-UHFFFAOYSA-N dipropan-2-yl decanedioate Chemical compound CC(C)OC(=O)CCCCCCCCC(=O)OC(C)C XFKBBSZEQRFVSL-UHFFFAOYSA-N 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 210000000245 forearm Anatomy 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 229940100463 hexyl laurate Drugs 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- VOVZXURTCKPRDQ-CQSZACIVSA-N n-[4-[chloro(difluoro)methoxy]phenyl]-6-[(3r)-3-hydroxypyrrolidin-1-yl]-5-(1h-pyrazol-5-yl)pyridine-3-carboxamide Chemical compound C1[C@H](O)CCN1C1=NC=C(C(=O)NC=2C=CC(OC(F)(F)Cl)=CC=2)C=C1C1=CC=NN1 VOVZXURTCKPRDQ-CQSZACIVSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229940066842 petrolatum Drugs 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229940080236 sodium cetyl sulfate Drugs 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- GRNNMEITWDFPOL-UHFFFAOYSA-M sodium;heptyl sulfate Chemical compound [Na+].CCCCCCCOS([O-])(=O)=O GRNNMEITWDFPOL-UHFFFAOYSA-M 0.000 description 1
- GGHPAKFFUZUEKL-UHFFFAOYSA-M sodium;hexadecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCCCOS([O-])(=O)=O GGHPAKFFUZUEKL-UHFFFAOYSA-M 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- KNANANSBRPCBAH-UHFFFAOYSA-N tetraoctadecylazanium Chemical class CCCCCCCCCCCCCCCCCC[N+](CCCCCCCCCCCCCCCCCC)(CCCCCCCCCCCCCCCCCC)CCCCCCCCCCCCCCCCCC KNANANSBRPCBAH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Chemical & Material Sciences (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Dispersion Chemistry (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（技術分野）
本発明は、皮膚刺激性がなく、保存安定性及び使用時の
官能特性（延展性、粘稠性５保湿性）に優れた油相／水
相型（以下０／Ｗ型と略記する）乳化型化粧料に関する
。Detailed Description of the Invention (Technical Field) The present invention provides an oil phase/aqueous phase type product that does not cause skin irritation and has excellent storage stability and sensory properties during use (spreadability, viscosity, and moisture retention). The present invention relates to an emulsified cosmetic (hereinafter abbreviated as 0/W type).
（従来技術）
従来より、（イ）高級アルコール硫酸エステル、高級ア
ルコールリン酸エステル、Ｎ−長鎖アシルグルタミン酸
等と苛性ソーダ、苛性カリ、 ｌ−リエタノールアミ
ン等とから成る塩であるアニオン型界面活性剤、（ロ）
高級アルコールの酸化エチレン付加物等のエーテル型非
イオン界面活性剤、（ハ）高級脂肪酸と多価アルコール
からなるエステル型非イオン界面活性剤等を乳化剤成分
として配合して成る０／Ｗ型乳化型化粧料が知られてい
る。(Prior art) Conventionally, (a) anionic surfactants which are salts consisting of higher alcohol sulfate esters, higher alcohol phosphate esters, N-long chain acyl glutamic acids, etc. and caustic soda, caustic potash, l-liethanolamine, etc. ,(B)
0/W type emulsion type, which is made by blending an ether type nonionic surfactant such as an ethylene oxide adduct of a higher alcohol, (c) an ester type nonionic surfactant consisting of a higher fatty acid and a polyhydric alcohol, etc. as an emulsifier component. Cosmetics are known.
しかし、上記のＯ／Ｗ型乳化型化粧料では、皮膚安全性
４保存安定性及び使用時の官能特性（延展性、粘稠性、
保湿性）の全てに亘って満足するものを得ることは困難
であった。However, the above-mentioned O/W type emulsified cosmetics have poor skin safety, storage stability, and sensory properties during use (spreadability, viscosity,
It was difficult to obtain a product that was satisfactory in all respects (moisturizing properties).
即ち、（イ）のアニオン型界面活性剤を乳化剤成分とし
て配合して成るＯ／Ｗ型乳化型化粧料は、皮膚刺激があ
り、（ロ）の乳化剤成分では皮膚刺激性が高り、（ハ）
の乳化剤成分では乳化特性が劣り、保存安定性において
満足するものは得られず、また、この乳化剤成分を高濃
度に配合して成る乳化型化粧料は官能特性に劣るなどの
欠点を有していた。That is, O/W type emulsified cosmetics containing the anionic surfactant (a) as an emulsifier component are irritating to the skin, and the emulsifier component (b) is highly irritating to the skin; )
The emulsifier component has poor emulsifying properties and cannot provide satisfactory storage stability, and emulsified cosmetics containing this emulsifier component at high concentrations have drawbacks such as poor sensory properties. Ta.
（発明の開示）
本発明者等は上記の事情に鑑み鋭意研究した結果、ラウ
リルアルコールスルホコハク酸エステルジナトリウム塩
（以下ＬＳＳ−２Ｎａ塩と略記する）の乳化剤成分を配
合して成るＯ／Ｗ型乳化型化粧料は、従来の欠点を解消
すると共に使用時に優れた官能特性を有することを見出
し本発明を完成した。(Disclosure of the Invention) As a result of intensive research in view of the above circumstances, the present inventors have found that an O/W type compound containing an emulsifier component of lauryl alcohol sulfosuccinate disodium salt (hereinafter abbreviated as LSS-2Na salt) The present invention was completed based on the discovery that emulsified cosmetics overcome the conventional drawbacks and have excellent sensory properties when used.
（発明の目的）
本発明の目的は、皮膚安全性、保存安定性及び使用時の
官能特性（延展性、粘稠性、保湿性）に優れた。Ｏ／Ｗ
型乳化型化粧料を提供するにある。(Objective of the Invention) The object of the present invention is to have excellent skin safety, storage stability, and sensory properties during use (spreadability, viscosity, moisture retention). O/W
To provide emulsified cosmetics.
（発明の構成）
本発明は、ＬＳＳ−２Ｎａ塩と、高級アルコールと、油
性物質と、水とを必須構成成分として配合して成るＯ／
Ｗ型乳化型化粧料である。(Structure of the Invention) The present invention provides an O/
It is a W-type emulsion type cosmetic.
（構成の具体的な説明）
本発明に使用されるＬＳＳ−２Ｎａ塩は公知の物質であ
って、下記の式（１）で
示される化合物である。(Specific description of structure) LSS-2Na salt used in the present invention is a known substance, and is a compound represented by the following formula (1).
ＬＳＳ−２Ｎａ塩の配合量は当該化粧料の総量を基準と
して０．３〜５．０重量％（以下ｗｔ％好ましくは０．
５〜３ｗｔ％である。０．３％ｗｔ％ 未満では保存安
定性が低下しやすく、５．０ｗｔ％を越えては剤型の外
観特性及び粘稠性等の使用時の官能特性がわるくなりや
すい。The amount of LSS-2Na salt blended is 0.3 to 5.0% by weight (hereinafter wt%, preferably 0.3% by weight, based on the total amount of the cosmetic).
It is 5 to 3 wt%. If it is less than 0.3 wt%, storage stability tends to decrease, and if it exceeds 5.0 wt%, the appearance characteristics of the dosage form and the organoleptic properties during use, such as viscosity, tend to deteriorate.
高級アルコールは、炭素数１４〜２２のアルコールであ
って、例えばミリスチル、アルコール。Higher alcohols are alcohols having 14 to 22 carbon atoms, such as myristyl and alcohol.
セチルアルコール、ステアリルアルコール、セトステア
リルアルコール、ベヘニルアルコール等を挙げることが
でき、好ましくは炭素数１６〜１８のアルコールであっ
て例えば、セチルアルコール。Cetyl alcohol, stearyl alcohol, cetostearyl alcohol, behenyl alcohol, etc. can be mentioned, preferably alcohol having 16 to 18 carbon atoms, such as cetyl alcohol.
ステアリルアルコール、セトステアリルアルコール等を
挙げることができ、特に好ましくは、セチルアルコール
とステアリルアルコールの配合比率が３＝７〜７：３の
重量比のものが好ましい。Examples include stearyl alcohol and cetostearyl alcohol, and particularly preferred is one in which the weight ratio of cetyl alcohol to stearyl alcohol is 3=7 to 7:3.
本発明のＯ／Ｗ型乳化型化粧料には上記高級アルコール
を当該化粧料の総量を基準として配合量は０．１〜７．
０ｗｔ％、好ましくは０．３〜ｓ、ｏｗｔ％である。The O/W type emulsified cosmetic of the present invention contains the above-mentioned higher alcohol in an amount of 0.1 to 7.0% based on the total amount of the cosmetic.
0 wt%, preferably 0.3 to s, owt%.
本発明に係る油性物質としては、例えば高級脂肪族炭化
水素類、動物油脂類、植物油脂類、ロウ類１合成エステ
ル油、シリコン油等を挙げることができる。高級脂肪族
炭化水素類としては、例えば流動パラフィン、スクワラ
ン、ワセリン、セレシン等、植物油脂類としては例えば
オリーブ油。Examples of the oily substance according to the present invention include higher aliphatic hydrocarbons, animal oils, vegetable oils, wax 1 synthetic ester oils, silicone oils, and the like. Examples of higher aliphatic hydrocarbons include liquid paraffin, squalane, petrolatum, and ceresin, and examples of vegetable oils include olive oil.
ヒマシ油、カカオ脂、パーム油等、動物油脂としてはタ
ラ肝油、牛脂、バター脂等、ロウ類としては、例えば、
蜜ロウ、カルナウバロウ等２合成エステル油としては、
例えばブチルステアレート。Castor oil, cacao butter, palm oil, etc.; animal fats and oils include cod liver oil, beef tallow, and butter fat; waxes include, for example,
2 synthetic ester oils such as beeswax and carnauba wax,
For example, butyl stearate.
ヘキシルラウレート、オクチルドデシルミリステート、
ジイソプロピルアジベート、ジイソプロピルセバケート
等の直鎖エステル、分岐鎖エステル等を挙げること、が
できる。hexyl laurate, octyldodecyl myristate,
Straight chain esters such as diisopropyl adibate and diisopropyl sebacate, branched chain esters and the like can be mentioned.
上記の油性物質の配合量は、当該化粧料の総量を基準と
して、また、水の配合量は、処方成分の総量を基準とし
て２０〜９０ｗｔ％が好適である。The blending amount of the above-mentioned oily substance is preferably 20 to 90 wt% based on the total amount of the cosmetic, and the blending amount of water is preferably 20 to 90 wt% based on the total amount of prescription ingredients.
本発明は上記の如く構成するものであるが、必要に応じ
て界面活性剤、香料９着色剤、防腐剤。The present invention is constructed as described above, but if necessary, surfactants, fragrances, colorants, and preservatives are added.
顔料等を本発明の目的を達成する範囲で適宜配合するこ
ともできる。Pigments and the like can also be appropriately blended within a range that achieves the object of the present invention.
本発明のＯ／Ｗ型乳化型化粧料は、軟膏基剤。The O/W type emulsified cosmetic of the present invention is an ointment base.
乳化型化粧料であるスキンミルク、スキンクリーム、ト
リートメントへアークリーム、ファンデーションクリー
ム、洗顔クリーム、マツサージクリーム等に適用される
。It is applied to emulsified cosmetics such as skin milk, skin cream, treatment hair cream, foundation cream, facial cleansing cream, and pine surge cream.
（発明の実施例） 以下、実施例にて本発明を説明する。(Example of the invention) The present invention will be explained below with reference to Examples.
実施例に記載の保存安定性試験、ヒト皮膚バッチテスト
、使用時の官能特性（延展性、粘稠性。Storage stability test, human skin batch test, sensory properties during use (spreadability, viscosity, etc.) described in Examples.
保湿性）の試験方法或は測定方法を下記に示す。The test method or measurement method for moisture retention) is shown below.
（１） 保存安定性試験
試料を４５℃の恒温槽に入れ、１０日間放置後の乳化状
態、外観を観察し、異常が認められる場合（油が分離し
た場合、粒子が粗大になった場合）×で表わし、１ケ月
間放置後異常が認められる場合△で表わし、３ケ月間放
置後異常が認められる場合Ｏで表わし、４ヶ月間放置後
異常が認められない場合（乳化＝６−
状態が均一で均質なエマルジョンを形成している場合）
は良好とし◎で表わした。(1) Place the storage stability test sample in a constant temperature bath at 45℃ and observe the emulsification state and appearance after leaving it for 10 days. If any abnormalities are observed (if oil separates, if particles become coarse) If an abnormality is observed after being left for 1 month, it is represented by △. If an abnormality is found after being left for 3 months, it is represented by O. If no abnormality is found after being left for 4 months (emulsification = 6- condition) forming a uniform and homogeneous emulsion)
It is considered good and is indicated by ◎.
（２） ヒト皮膚バッチテスト
被検者２５名の前腕圧側部皮膚に、試料０．０５ｇを直
径１．０ｃｍの円型のリント布のついたパンチテスト用
絆創膏を用いて２４時間閉塞貼布した後、下記の判定基
準に従い、各試料について被検者２５名の皮膚の状態を
評価判定した。判定結果は、絆創膏除去１時間後及び２
４時間後のうち反応の強い方を採用し、評価が（±）以
上の人の数で示した。尚、洗顔クリームでは、クリーム
のｏ、ｓ’ｗｔ％水溶液を試料とした。(2) Human Skin Batch Test 0.05 g of the sample was applied to the skin of the forearm pressure side of 25 subjects using a punch test bandage with a circular lint cloth with a diameter of 1.0 cm for 24 hours. Thereafter, the skin condition of 25 subjects was evaluated for each sample according to the following criteria. The judgment results are 1 hour after removal of the bandage and 2 hours after removal of the bandage.
The one with the strongest reaction after 4 hours was selected and indicated by the number of people who gave an evaluation of (±) or higher. In addition, for the facial cleansing cream, an o, s'wt% aqueous solution of the cream was used as a sample.
（３）使用時の官能特性（延展性９才を稠性、保湿性）
被験者２０名が試料を１０日間を運用した後、試料の特
性を評価した。(3) Sensory properties during use (spreadability, consistency, moisture retention) After 20 test subjects used the sample for 10 days, the properties of the sample were evaluated.
試験結果は、延展性、粘稠性、保湿性等の試験項目に対
して、各々「塗布時の伸び力＜良い」、「べとつき感ま
たはぬめり惑が無し１」。The test results for test items such as spreadability, viscosity, and moisture retention were ``Extensibility during application <Good'' and ``No sticky or slimy feeling 1.''
［皮膚がしっとりとする］と回答した人数で示した。Shown by the number of people who answered that their skin feels moist.
実施例１〜７．比較例１〜１０
〔０／Ｗ型スギンクリーム〕
下記の組成のごとく、乳化剤成分の種類及び量、高級ア
ルコールの種類及び量を第１表番こ君己載の通りに配合
して各々のＯ／Ｗ型スキンクＩノ−ムを８周製し、前記
の諸試験を実施した。Examples 1-7. Comparative Examples 1 to 10 [0/W Type Sugin Cream] As shown in the composition below, the type and amount of the emulsifier component and the type and amount of the higher alcohol were blended as listed in Table 1. The O/W type skink I gnome was produced eight times and the various tests described above were conducted.
（１） 組 成
（２） 調製方法
成分内と成分（Ｉ３）を各々温度８０℃にて均一に溶解
し、成分囚を攪拌しながら成分（Ｂ）を注入して乳化分
散した後、攪拌しながら温度３０℃まで冷却して調製す
る。(1) Composition (2) Preparation method Ingredients and component (I3) are each dissolved uniformly at a temperature of 80°C, and while stirring the component mixture, component (B) is injected to emulsify and disperse, and then stirred. The mixture is prepared by cooling to a temperature of 30°C.
（３） 特性 各実施例、比較例に係る前記緒特性を試験−９＝ した結果を第１表に記載する。(3) Characteristics Testing the characteristics of each Example and Comparative Example-9= The results are listed in Table 1.
第−表に記載の如く、乳化剤成分としてポリオキシセチ
ルエーテルのノニオン型界面活性剤を用いた比較例１の
Ｏ／Ｗ型スキスキンクリーム存安定性は良好であるが皮
膚安全性、官能特性は悪く、テトラステアリルアンモニ
ウム塩のカチオン型界面活性剤を用いた比較例２は保存
安定性、皮宥安全性、官能特性ともに悪＜、Ｎ−ステロ
イル−グルタミン酸ナトリウムのアニオン型界面活性剤
を用いた比較例３は皮膚安全性は良好であるが保存安定
性、官能特性はあまり良くなく、セチル硫酸ナトリウム
のアニオン型界面活性剤を用いた比較例４は保存安定性
、官能特性はほぼ良好であるが、皮膚安全性は悪い。As shown in Table 1, the stability of the O/W skin cream of Comparative Example 1 using a nonionic surfactant of polyoxycetyl ether as the emulsifier component was good, but the skin safety and sensory properties were poor. Comparative Example 2 using a cationic surfactant of tetrastearylammonium salt had poor storage stability, skin comfort, and sensory properties. Comparison using an anionic surfactant of sodium N-steroyl-glutamate Example 3 has good skin safety, but the storage stability and sensory properties are not very good, while Comparative Example 4, which uses an anionic surfactant of sodium cetyl sulfate, has almost good storage stability and sensory properties. , skin safety is poor.
また、比較例５，７．８で明らかな如＜ ＬＳＳ−２Ｎ
ａ、高級アルコールの配合量がそれぞれ０．３，０．１
ｗｔ％を下回る場合は保存安定性。In addition, as is clear from Comparative Examples 5 and 7.8, < LSS-2N
a, the blended amount of higher alcohol is 0.3 and 0.1, respectively
If it is less than wt%, it indicates storage stability.
官能特性が劣り比較例９，１０の如＜ ＬＳＳ−２Ｎａ
、高級アルコールの配合量がそれぞれ５．０゜７．０ｗ
ｔ％を超える場合は保存安定性は良好で＝ １０−
あるが、官能特性は劣る。更に、ＬＳＳ−２Ｎａのアニ
オン型界面活性剤とポリオキシセチルエーテルのノニオ
ン型界面活性剤の併用は保存安定性は改良されるが、皮
膚安全性、官能特性に劣る。LSS-2Na has poor sensory characteristics and is similar to Comparative Examples 9 and 10.
, the blended amount of higher alcohol is 5.0°7.0w, respectively.
If it exceeds t%, the storage stability is good (=10-), but the sensory properties are poor. Furthermore, the combined use of an anionic surfactant such as LSS-2Na and a nonionic surfactant such as polyoxycetyl ether improves storage stability, but is inferior in skin safety and sensory properties.
一方、乳化剤成分としてＬＳＳ−’２Ｎ’ａ、高級アル
コールとしてセチルアルコール、ステアリルアルコール
それぞれ０．３〜５．０，０．１〜７．０ｗｔ％を用い
た本発明の実施例１〜７は、保存安定性、皮膚安全性及
び官能特性が優れる、特にステアリルアルコールとセチ
ルアルコールの配合比が３ニア〜７：３の範囲にある場
合が非常に優れている。On the other hand, Examples 1 to 7 of the present invention used LSS-'2N'a as an emulsifier component and 0.3 to 5.0 and 0.1 to 7.0 wt% of cetyl alcohol and stearyl alcohol as higher alcohols, respectively. The storage stability, skin safety and organoleptic properties are excellent, especially when the blending ratio of stearyl alcohol and cetyl alcohol is in the range of 3 to 7:3.
実施例８〜１２．比較例１）〜１５
〔０／Ｗ型メイクアツプベース〕
実施例１と同様に、下記の組成にて、各々の０／Ｗ型メ
イクアツプベースを調製し、諸試験を実施した。Examples 8-12. Comparative Examples 1) to 15 [0/W type makeup base] In the same manner as in Example 1, each 0/W type makeup base was prepared with the following composition and various tests were conducted.
（１） 組 成
（２） 調製方法
成分囚と成分（Ｂ＋を各々温度８０℃にて均一に溶解し
、成分囚を攪拌しながら成分側を注入して乳化分散した
後、撹拌しながら温度３０℃まで冷却して調整する。(1) Composition (2) Preparation method Ingredients and component (B+) were each dissolved uniformly at a temperature of 80°C, and the component side was poured while stirring to emulsify and disperse. Cool and adjust to ℃.
（３） 特性
各実施例、比較例に係る前記緒特性を試験゛した結果を
第２表に記載する。(3) Characteristics Table 2 shows the results of testing the above-mentioned characteristics for each example and comparative example.
第２表に記載されている如く、乳化剤成分として七チル
硫酸ナトリウムのアニオン型界面活性剤を用いた比較例
１）のＯ／Ｗ型メイクアップベースは保存安定性、官能
特性はは□ぼ良好であるが、皮膚安全性は悪い。比較例
１２．１３の如くＬ’５Ｓ−２’Ｎａ、高級アルコール
がそれぞれ０．３，０．１を下回る場合は皮膚安全性は
良好であるが、保存安定性、官能特性は劣る。比較例１
４．１５の如＜ＬＳＳ−２Ｎ・、高級アルコニルがそれ
ぞれ５．０，７．０ｗｔ％を上回る場合は保存安定性は
良好であるが官能特性は劣る。As shown in Table 2, the O/W makeup base of Comparative Example 1) using an anionic surfactant of sodium heptyl sulfate as an emulsifier component has excellent storage stability and sensory properties. However, skin safety is poor. When L'5S-2'Na and higher alcohol are less than 0.3 and 0.1, respectively, as in Comparative Example 12.13, the skin safety is good, but the storage stability and sensory properties are poor. Comparative example 1
4.15<LSS-2N. When the higher alconyl content exceeds 5.0 and 7.0 wt%, respectively, the storage stability is good, but the organoleptic properties are poor.
一方、乳化剤成分としてＬＳＳ−２Ｎａ、高級アルコー
ル
アルコールそれぞれ３ニア〜７：３を用いた実施例８〜
１２は保存安定性，皮膚安全性及び官能時性に優れる。On the other hand, Example 8 using LSS-2Na and higher alcohol alcohol in a ratio of 3 to 7:3 as an emulsifier component.
No. 12 has excellent storage stability, skin safety, and organoleptic properties.
特にステアリルアルコールとセチルアルコールの配合比
が３ニア〜７：３にある場合＝ １ ４ −
（発明の効果）
以」＝記載の如く、本発明のＯ／Ｗ型乳化型化粧料は、
皮膚安全性、保存安定性及び使用時の官能特性に優れ、
有用性の高いものである。In particular, when the blending ratio of stearyl alcohol and cetyl alcohol is between 3 and 7:3 = 1 4 - (Effects of the invention) As described above, the O/W emulsion cosmetic of the present invention has the following properties:
Excellent skin safety, storage stability, and sensory properties during use.
It is highly useful.
１７一171
Claims (2)
トリウム塩と、高級アルコールと、油性物質と、水とを
主要構成成分として配合して成る油相／水相型乳化型化
粧料。(1) An oil phase/water phase emulsified cosmetic comprising lauryl alcohol sulfosuccinate disodium salt, a higher alcohol, an oily substance, and water as main components.
ルである、特許請求の範囲第（１）項記載の乳化型化粧
料。(2) The emulsified cosmetic according to claim (1), wherein the higher alcohol is an alcohol having 14 to 22 carbon atoms.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30108286A JPS63154605A (en) | 1986-12-16 | 1986-12-16 | Emulsified type cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30108286A JPS63154605A (en) | 1986-12-16 | 1986-12-16 | Emulsified type cosmetic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63154605A true JPS63154605A (en) | 1988-06-27 |
Family
ID=17892648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30108286A Pending JPS63154605A (en) | 1986-12-16 | 1986-12-16 | Emulsified type cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63154605A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892059A (en) * | 1994-09-20 | 1996-04-09 | Shiseido Co Ltd | Transparent face lotion |
-
1986
- 1986-12-16 JP JP30108286A patent/JPS63154605A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892059A (en) * | 1994-09-20 | 1996-04-09 | Shiseido Co Ltd | Transparent face lotion |
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