JPS63142356A - Electrophotographic sensitive body - Google Patents

Electrophotographic sensitive body

Info

Publication number
JPS63142356A
JPS63142356A JP28915286A JP28915286A JPS63142356A JP S63142356 A JPS63142356 A JP S63142356A JP 28915286 A JP28915286 A JP 28915286A JP 28915286 A JP28915286 A JP 28915286A JP S63142356 A JPS63142356 A JP S63142356A
Authority
JP
Japan
Prior art keywords
sensitivity
wavelength region
dried
solution
dispersion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP28915286A
Other languages
Japanese (ja)
Inventor
Eiji Shimura
英次 志村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP28915286A priority Critical patent/JPS63142356A/en
Publication of JPS63142356A publication Critical patent/JPS63142356A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0622Heterocyclic compounds
    • G03G5/0644Heterocyclic compounds containing two or more hetero rings
    • G03G5/0646Heterocyclic compounds containing two or more hetero rings in the same ring system
    • G03G5/0653Heterocyclic compounds containing two or more hetero rings in the same ring system containing five relevant rings
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0601Acyclic or carbocyclic compounds
    • G03G5/0612Acyclic or carbocyclic compounds containing nitrogen
    • G03G5/0616Hydrazines; Hydrazones
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording members for original recording by exposure, e.g. to light, to heat, to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/06Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being organic
    • G03G5/0664Dyes
    • G03G5/0696Phthalocyanines

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photoreceptors In Electrophotography (AREA)

Abstract

PURPOSE:To obtain high uniform sensitivity in a wide wavelength region by incorporating >=2 kinds of organic photoconductors different in absorption wavelength from each other in an electric charge generating layer. CONSTITUTION:The charge generating layer contains >=2 kinds of organic photoconductors different in absorption wavelength. For example, x-type nonmetal phthalocyanine having sensitivity in a wavelength region of 550-800nm, polyvinyl butyral, and tetrahydrofuran are mixed and dispersed in a ball mill to obtain a liquid dispersion A, and quinacridone having sensitivity in a wavelength region of 420-600nm, acryl resin, and toluene are mixed and dispersed in a ball mill to obtain a liquid dispersion B, and p-diethylamino-benzaldehyde- diphenylhydrazone and polycarbonate are dissolved in tetrahydrofuran to obtain a solution C. ITO is vapor deposited on the surface of a polyester film and the film is coated with the dispersion A and dried with warm air flow, it is further coated with the dispersion B, dried likewise, and further coated with the solution C, and dried likewise, thus permitting sensitivity extremely high and uniform in the wide wavelength region of 400-800nm to be obtained.

Description

【発明の詳細な説明】 〔素業上の利用分野〕 本発明け、お)むね400?L?7L””−ら800r
Lmの広域にわたって極めて高い一様な感度を有する電
子写真感光体だ関する。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention costs 400 yen? L? 7L""-etc.800r
The present invention relates to an electrophotographic photoreceptor having extremely high uniform sensitivity over a wide range of Lm.

〔従来の技術〕[Conventional technology]

従来、積層型電子写真感光体の電荷発生1勿質(以下、
CG Mと略す)としてvi、有機第一アSン類に可溶
なモノマゾ染料・ジスマゾ染料・スフフィン酸誘導体染
料(lrf開昭52−55643号)、キノシアニン顔
料(特開昭53−42830号)、銅フタロシアニン顔
料(特開昭51−11763号)等の有機物h1多数提
示され、また、テルルヒ素アモルファスセレン(特開昭
50−15137号)、アモルファスセレン(特開昭5
2−75392号)等の無機物も提示されている。一方
近年、近赤外光(波長750nm以上)に感度を有する
CGMとして、X型無金属7タロシアニンや1色素増感
した有機物が多数提案されている。
Conventionally, charge generation in a laminated electrophotographic photoreceptor (hereinafter referred to as
(abbreviated as CGM), vi, monomaso dyes, dismazo dyes, and sulfinic acid derivative dyes soluble in organic monosulfur compounds (lrf 1985-55643), quinocyanine pigments (Japanese Patent Laid-Open No. 53-42830) , copper phthalocyanine pigment (JP-A-51-11763), and tellurium arsenide amorphous selenium (JP-A-50-15137), amorphous selenium (JP-A-50-15137), etc.
Inorganic substances such as No. 2-75392) have also been proposed. On the other hand, in recent years, many X-type metal-free 7-thalocyanines and single-dye sensitized organic substances have been proposed as CGMs sensitive to near-infrared light (wavelengths of 750 nm or more).

〔発明が解決しようとする問題点〕[Problem that the invention seeks to solve]

しかしこれらOGMは、ある特定の波長域の光にしか高
い感度を示さず、つまり、光源の光の大部分はキャリア
発生に寄与しないこととなり、効率hS悪いとい5欠点
を有する。あるいは、CGMの吸収波長域の波長を有す
る光源を利用しないといけないといへ欠点も有する。
However, these OGMs exhibit high sensitivity only to light in a specific wavelength range, that is, most of the light from the light source does not contribute to carrier generation, and has five drawbacks such as poor hS efficiency. Another disadvantage is that a light source having a wavelength in the CGM absorption wavelength range must be used.

そこで、本発明は上記の問題点を解決するものであって
、その目的とするところは、おおむね400717FL
から800?L?FL の広域にわたって極めて高い一
様な感電を有するCGLを構成要素とする電子写真感光
体を提供するところにある。
Therefore, the present invention is intended to solve the above problems, and its purpose is to
From 800? L? An object of the present invention is to provide an electrophotographic photoreceptor including a CGL as a component which has an extremely high uniform electric shock over a wide range of FL.

〔問題点を解決する定めの手段〕[Defined means of solving problems]

未発明の電子写真感光体は、c G L b;吸収波長
の具なるZff類以上の有鳴光導電性物質を含有するこ
とを特徴とする。
The uninvented electrophotographic photoreceptor is characterized in that it contains a photoconductive substance with a photoconductive signal having an absorption wavelength equal to or higher than that of the Zff class.

〔実施例〕〔Example〕

以下(C本発明について、実施例にもとづいて詳細:f
C説明する。なお、C!GM−OGMの組合せ、CTM
、バインダ樹脂、溶剤等は本実施例に限定されない。
Below (CDetails of the present invention based on examples: f
C.Explain. In addition, C! GM-OGM combination, CTM
, binder resin, solvent, etc. are not limited to those in this example.

′j!識例1 550nmから8QQnmまで感光波長を有する大型年
金<7タロシアニン(犬日本インキ)2j、ポリビニル
ブチラール(S−LEO−BM−8−噴水化学)2g、
テトラヒドロフラン60.9を混合し、ボールミル?(
て6時間分散した液をA液とする。
'j! Case 1 Large pension <7 talocyanin (Inu Nippon Ink) 2j, polyvinyl butyral (S-LEO-BM-8-Fountain Chemical) 2g, with photosensitive wavelengths from 550nm to 8QQnm,
Mix 60.9% of tetrahydrofuran and ball mill? (
The solution dispersed for 6 hours is called Solution A.

A20nmから600nmまで感光波長を有するそナク
リドン(Rubicron7Redu50t3 F、 
s東洋曹達工業)2I、アクリル(アクリベット、三菱
レーヨン)21、トルエン60Iを混合し、ボールミル
にて12蒔間分散した液をB液とする。P−ジエチルア
ミノベンツアルデヒドジフェニルヒドラゾン(CTC−
236阿南香料)5g、ポリカーボネート(N0VAR
E乙口三菱化成)5I、テトラヒドロ7ラン100 !
1に溶解した液をC液とする。
A Sonacridone (Rubicron7Redu50t3F,
Toyo Soda Kogyo) 2I, acrylic (Acrivet, Mitsubishi Rayon) 21, and toluene 60I were mixed and dispersed in a ball mill for 12 minutes, and the solution was designated as Solution B. P-diethylaminobenzaldehyde diphenylhydrazone (CTC-
236 Anan fragrance) 5g, polycarbonate (N0VAR
E Otsuguchi Mitsubishi Kasei) 5I, Tetrahydro 7 Run 100!
The solution dissolved in 1 is called Solution C.

工TOff表面に蒸着し之ポリエステルフィルム(ハイ
ビーム100 L −BKO2東し)上に、A液を塗工
、温風乾燥し、その上からB液を塗工、温風乾燥し、2
層からなる厚み0.5μm(各層の厚み0.25μm)
のOGLを形成した。さらに、その上にOTLとして、
C液を塗工、温風乾燥し念、、cTLの膜厚け18μm
とした。
Coat liquid A on the polyester film (high beam 100 L-BKO2 east side) vapor-deposited on the surface of the TOff and dry with warm air, then apply liquid B on top of that and dry with warm air.
Thickness of 0.5 μm consisting of layers (thickness of each layer 0.25 μm)
OGL was formed. Furthermore, as an OTL,
Coat liquid C, dry with warm air, and make cTL film thickness 18 μm.
And so.

このようにして形成した電子写Jlc感光体について、
静電複写紙試験装置EIP−428型(川口電気製作所
)を用いて電子写真特性を組1定した。測定は一5KV
のコロナ帯電を5秒間行ない、タングステンランプによ
り光照射して半減露光量E3Aを調べさちに、干渉フィ
ルターによりモノクロ化し次光(光の半値巾〜7πm)
を照射して分光特性を調べfc、白色光による電子写真
特性及び感光波長を第1表に、分光特性を第1図に示す
。縦軸は感♂(F、%)1(c!n2/μJ)、横軸は
光の波長(諧)である。
Regarding the electrophotographic JLC photoconductor formed in this way,
The electrophotographic properties were determined using an electrostatic copying paper tester model EIP-428 (Kawaguchi Denki Seisakusho). Measurement is -5KV
After corona charging for 5 seconds, irradiate with light using a tungsten lamp to check the half-decreased exposure amount E3A, and then convert it into monochrome using an interference filter.
The spectral characteristics were investigated by irradiating fc with white light, and the electrophotographic characteristics and photosensitive wavelength are shown in Table 1, and the spectral characteristics are shown in FIG. The vertical axis is the sensitivity (F, %) 1 (c!n2/μJ), and the horizontal axis is the wavelength (tone) of light.

グラフより、420〜8[]Q71?7Lまでパンクロ
な光感度を有する電子写真感光体h″−できていること
がわかる。
From the graph, it can be seen that the electrophotographic photoreceptor h''- has a panchromatic photosensitivity of 420~8[]Q71~7L.

実施例2゜ X型無金属フタロシアニン2g、キナクリドン2g、ポ
リビニルブチラール31.ポリエステル(パイロン20
0  東洋紡)1g、テトラヒドロフラン100gを混
合し、ボールミルにて12時間分散した液をD液とする
Example 2゜Type X metal-free phthalocyanine 2g, quinacridone 2g, polyvinyl butyral 31. Polyester (pylon 20
0 (Toyobo) and 100 g of tetrahydrofuran were mixed and dispersed in a ball mill for 12 hours, and the resulting solution was designated as Solution D.

ITOを表面に蒸着したポリエスルフィルム上IcD液
を塗工t7、温風乾燥させ、厚み0.4μmのCGLを
形成した。さらにC液をCTLとして塗工。
The IcD solution was coated on the polyester film on which ITO was vapor-deposited at t7, and dried with warm air to form a CGL with a thickness of 0.4 μm. Furthermore, apply C liquid as CTL.

乾燥させ、18μmの模を形成した。It was dried to form a pattern of 18 μm.

この電子写真感光体について、実施例1と同様の評価を
行なった。白色光による電子写真特性及び感光波長を第
1表に示す。分光特性は、実施例1とほぼ同様に420
nmから800nmにわたってノ<・ノクロな光感度を
もった。
This electrophotographic photoreceptor was evaluated in the same manner as in Example 1. Table 1 shows the electrophotographic properties and sensitive wavelengths using white light. The spectral characteristics are almost the same as in Example 1.
It had excellent photosensitivity over the wavelength range of 800 nm to 800 nm.

実施例3゜ 500nmから850nmに感光波長を有するアルミク
Ohフタσシアニン1p、400nmから600nm 
 に感光波長を有するテトラメチル) +1フエノジオ
千斗ジン(東洋曹達工業)2F、フヱノキシ樹1fff
(STX−07東都化成)05g、ポリビニルブチラー
ル(S  LEC−BM−8,w積木化学)051、ポ
リカーボネート(N0VARKX  三菱化成)2g、
メチルエチルケトン/トルエン(=1/1 )80gに
混合し、ボールミルにて18時間分散した液をB液とす
る。
Example 3 Aluminum Oh lid σ cyanine 1p with photosensitive wavelength from 500 nm to 850 nm, 400 nm to 600 nm
(Tetramethyl having a photosensitive wavelength)
(STX-07 Toto Kasei) 05g, polyvinyl butyral (S LEC-BM-8, w Building Chemical) 051, polycarbonate (N0VARKX Mitsubishi Chemical) 2g,
The solution was mixed with 80 g of methyl ethyl ketone/toluene (=1/1) and dispersed in a ball mill for 18 hours, and the solution was designated as Solution B.

この分散液E液をOGLとして塗工し、乾燥させ0.5
μmの厚さとし、その土足、実施例1と同様(てCTL
%−塗工した。
This dispersion liquid E was applied as OGL and dried to give a 0.5
The thickness was 1 μm, and the shoes were the same as in Example 1 (CTL
%-Coated.

この電子写真感光体疋ついて実施例1と同様に評価した
結果を第1表に示す。また、分光特性はAOOnmから
850nmにわたってパンクロな光感度をも  っ l
ヒ 。
This electrophotographic photoreceptor was evaluated in the same manner as in Example 1, and the results are shown in Table 1. In addition, the spectral characteristics have panchromatic photosensitivity from AOOnm to 850nm.
Hi.

比較例 液Aを工TO蒸着フィルム上に04μm塗工し。Comparative example Coat liquid A to a thickness of 04 μm on the TO vapor-deposited film.

さらに、液Cを18μm塗工し、比較用電子写真感光体
を形成し之。
Furthermore, 18 μm of liquid C was applied to form an electrophotographic photoreceptor for comparison.

この比較用電子写真感光体について、実施例1と同様に
して評価しt結果を第2図、第1表に示す。
This comparative electrophotographic photoreceptor was evaluated in the same manner as in Example 1, and the results are shown in FIG. 2 and Table 1.

第  1  表 〔発明の効果〕 以上述べ念ように1本発明だよれば、CGLとして吸収
波長域の異なる2種類以上の有機光導電性物質を含有す
ることによって、b、t、−むね4QOnmからBOQ
nmの広域にわたって極めて高い一様な感変な有する電
子写真感光体を形成できる。
Table 1 [Effects of the Invention] As mentioned above, according to the present invention, by containing two or more types of organic photoconductive substances with different absorption wavelength ranges as a CGL, it is possible to obtain a photoconductivity from b, t, -4Q Onm. BOQ
An electrophotographic photoreceptor having extremely high uniform sensitivity over a wide range of nm can be formed.

これKよって、光のエネルH−h′−有効にモヤ1フ 光感度が良くなった。さらに、この電子写真感光体げ、
光源にとら゛われることのない、つまり、レーザー用と
しても,白色光用としても使用可能であり,全く新しい
タイプの電子写貫感元体h;実現で芦た。
Due to this, the light energy H-h'-effectively improved the haze light sensitivity. Furthermore, this electrophotographic photoreceptor,
It is not dependent on the light source, that is, it can be used for both laser and white light, creating a completely new type of electronic photosensitive element.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の実施例1の電子写真感光体の分光特
性を示す図。 第2図は,比較例の電子写真感光体の分光特性を示す図
。 以  上 出頓入  セイコーエプソン株式会社 須玉(1 411) 第1rjtJ 貼イ、 齋2t!1
FIG. 1 is a diagram showing the spectral characteristics of the electrophotographic photoreceptor of Example 1 of the present invention. FIG. 2 is a diagram showing the spectral characteristics of an electrophotographic photoreceptor of a comparative example. Seiko Epson Corporation Sutama (1 411) 1st rjtJ pasted, sai 2t! 1

Claims (1)

【特許請求の範囲】[Claims] 導電性支持体上に、電荷発生層(以下、CGLと略す)
と電荷輸送層(以下、CTLと略す)とからなる積層型
電子写真感光体において、CGLが吸収波長の異なる2
種類以上の有機光導電性物質を含有することを特徴とす
る電子写真感光体。
A charge generation layer (hereinafter abbreviated as CGL) is provided on the conductive support.
In a laminated electrophotographic photoreceptor consisting of a CGL and a charge transport layer (hereinafter abbreviated as CTL), the CGL has two different absorption wavelengths.
An electrophotographic photoreceptor characterized by containing more than one type of organic photoconductive substance.
JP28915286A 1986-12-04 1986-12-04 Electrophotographic sensitive body Pending JPS63142356A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP28915286A JPS63142356A (en) 1986-12-04 1986-12-04 Electrophotographic sensitive body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP28915286A JPS63142356A (en) 1986-12-04 1986-12-04 Electrophotographic sensitive body

Publications (1)

Publication Number Publication Date
JPS63142356A true JPS63142356A (en) 1988-06-14

Family

ID=17739435

Family Applications (1)

Application Number Title Priority Date Filing Date
JP28915286A Pending JPS63142356A (en) 1986-12-04 1986-12-04 Electrophotographic sensitive body

Country Status (1)

Country Link
JP (1) JPS63142356A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0345005A2 (en) * 1988-05-31 1989-12-06 Somar Corporation Electrophotographic photosensitive element and method of preparing same
EP0402979A1 (en) * 1989-06-16 1990-12-19 Agfa-Gevaert N.V. Electrophotographic recording material
JPH0566595A (en) * 1991-02-01 1993-03-19 Canon Inc Electrophotographic sensitive body
US5312705A (en) * 1990-07-27 1994-05-17 Matsushita Electric Industrial Co., Ltd. Photosensitive materials for electrophotography having a double-layer structure of a charge generation layer and a charge transport layer
US5328788A (en) * 1990-07-26 1994-07-12 Matsushita Electric Industrial Co., Ltd. Organic photoconductive material for electrophotography and method for making the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0345005A2 (en) * 1988-05-31 1989-12-06 Somar Corporation Electrophotographic photosensitive element and method of preparing same
EP0402979A1 (en) * 1989-06-16 1990-12-19 Agfa-Gevaert N.V. Electrophotographic recording material
US5328788A (en) * 1990-07-26 1994-07-12 Matsushita Electric Industrial Co., Ltd. Organic photoconductive material for electrophotography and method for making the same
US5312705A (en) * 1990-07-27 1994-05-17 Matsushita Electric Industrial Co., Ltd. Photosensitive materials for electrophotography having a double-layer structure of a charge generation layer and a charge transport layer
JPH0566595A (en) * 1991-02-01 1993-03-19 Canon Inc Electrophotographic sensitive body

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