JP2813810B2 - Electrophotographic photoreceptor - Google Patents

Description

Description: BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an electrophotographic photoreceptor, and more particularly to an electrophotographic photoreceptor using a specific titanyl phthalocyanine pigment as a photoconductive material, which is effective for printers, copiers, and the like. The present invention also relates to an electrophotographic photosensitive member suitable for forming an image using a semiconductor laser light, an LED light or the like.

[Related Art] In recent years, as a photoconductive material used for an electrophotographic photoreceptor, an organic photoconductive material has been widely used instead of an inorganic photoconductive material. The reason is that, in the organic photoconductive material, a wide variety of materials can be obtained depending on the combination of synthetic substances and synthesis conditions, the degree of freedom of material selection is large, and a desired photoreceptor can be easily prepared according to the purpose. This is because it can be manufactured.

Furthermore, in the photoreceptor using the organic photoconductive material, the function separation type in which the carrier generation function and the carrier transport function are shared by different materials further expands the freedom of material selection. Improvements in electrophotographic properties such as chargeability, sensitivity, and durability have been expected.

On the other hand, in the copying industry, further improvement of image quality and image editing function are required, and development of recording apparatuses such as digital copying machines or printers corresponding to the demands has been promoted. There is a longing for improvement in the body. In the digital recording device,
Generally, a dot latent image is formed on a photoreceptor by exposing it in a dot shape using a laser beam modulated by an image signal, and the latent image is developed by a reversal development method to form an image. In this case, as the laser light, a semiconductor laser device capable of simplifying, miniaturizing, and reducing the cost of the exposure device is preferably used, and its oscillation wavelength is in the infrared region of 750 nm or more. Therefore, the photoreceptor used is required to have high sensitivity at least in the wavelength region of 750 to 850 nm.

By the way, various organic dyes or organic pigments have been proposed as a carrier-generating substance used for the function-separated type photoreceptor, for example, a polycyclic quinone pigment represented by dibromance anthrone, a pyrilium dye, and Eutectic complexes of pyrylium dyes and polycarbonates, squarium pigments, phthalocyanine pigments, azo pigments and the like have been put to practical use. Among these, JP-A-61-239248,
Nos. 61-217050, 62-67094 and 63-218
No. 768 discloses a titanyl-based phthalocyanine pigment having main sensitivity in a long wavelength region of 750 nm or more.
All of these titanyl-based phthalocyanine pigments have a specific aggregation structure or crystal structure, thereby increasing the main absorption wavelength and increasing the sensitivity.However, it is difficult to set the pigment production conditions described above. For this reason, it is not possible to obtain those satisfying all the characteristics such as charging ability, sensitivity, and repetition characteristics, and further higher sensitivity is desired in terms of sensitivity.

The present applicant has previously responded to the demand for the above-mentioned high sensitivity, as disclosed in JP-A-64-17066 and Japanese Patent Application No. 63-28653.
No. 7 (filed on November 11, 1988) proposed a high-sensitivity titanyl-based phthalocyanine photoreceptor. This photoreceptor uses a Cu-Kα characteristic X-ray (wavelength 1.
It is characterized by using a titanyl phthalocyanine pigment having a main peak at a Bragg angle 2θ of at least 27.2 ° ± 0.2 ° and 9.6 ° ± 0.2 ° with respect to 54 °). That is, this pigment has the X-ray diffraction spectrum completely different from that of a conventionally known titanyl-based phthalocyanine pigment, and has a cohesion state in which visible and near-infrared absorption spectra show maximum absorption at 780 nm to 860 nm. However, it can exhibit extremely high sensitivity to the laser light.

[Problems to be Solved by the Invention] The titanyl phthalocyanine pigment proposed by the present applicant has excellent sensitivity characteristics as described above, and is modulated by an image signal when forming an image on a photoreceptor. A dot latent image is formed on the photoreceptor by dot exposure using the laser light, and a dot-exposed portion of the latent image is reversely developed to obtain a good dot-shaped toner image. However, the sensitivity characteristics and charge retention of a photoreceptor using such a titanyl phthalocyanine pigment may be influenced by the dispersion method, and it is desired to obtain stable characteristics by establishing a dispersion method.

On the other hand, in a normal electrophotographic photoreceptor, the electrical contact between the grounded conductive layer and the photosensitive layer is not microscopically uniform, for example, because carrier injection from the conductive layer side varies depending on the location. Then, a local difference occurs in the distribution of charges held on the photoconductor surface. This becomes apparent as an image defect after development, and becomes a white spot on a black background in the positive development system, and a black spot on a white background in the negative reversal development system. In particular, black spots in the reversal development method, as well as background fogging, significantly impair image quality.
This problem occurs particularly sharply in the above-mentioned photosensitive member having a high sensitivity, and the occurrence of black spots in the reversal developing method becomes remarkable.

SUMMARY OF THE INVENTION The present invention has been made in view of the above-mentioned conventional problems, and has as its object to have high sensitivity characteristics, particularly to long-wavelength light such as a semiconductor laser, good charge retention, and furthermore, image defects, especially inversion. An object of the present invention is to provide an electrophotographic photoreceptor having few black spots during development.

Means for Solving the Problems In order to achieve the above object, an electrophotographic photoreceptor of the present invention comprises an electrophotographic photoreceptor having a photosensitive layer on a conductive support, wherein the photosensitive layer has Cu-Kα characteristics. X-ray (wavelength 1.54Å)
Main peak at Bragg angle 2θ of at least 9.6
It contains a titanyl phthalocyanine pigment at ゜ ± 0.2 ゜ and 27.2 ゜ ± 0.2 ゜ and a binder containing a modified silicone resin as a main component, wherein the modified silicone resin is a polyester-modified silicone resin, an epoxy-modified silicone resin, an acryl-modified silicone resin. It is characterized by being at least one selected from.

The titanyl phthalocyanine pigment according to the present invention is different from the titanyl phthalocyanine pigment known in each of the above-mentioned publications in the aggregation state of the pigment crystal, and is different from the third example in Examples described later.
It has a unique X-ray diffraction spectrum as shown in FIGS.
It has an agglomerated state showing maximum absorption at m to 860 nm, and can exhibit extremely high sensitivity to semiconductor laser light and the like. The basic structure of the titanyl phthalocyanine pigment according to the present invention is represented by the following general formula.

In the formula, X ¹ , X ² , X ³ and X ⁴ each represent a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, and n, m,
l and k each represent an integer of 0 to 4.

The above X-ray diffraction spectrum was measured under the following conditions (the same applies hereinafter).

X-ray tube Cu voltage 40.0 KV current 100.0 mA Start angle 6.00 deg. Stop angle 35.00 deg. Step angle 0.020 deg. Measurement time 0.50 sec. In addition, the above X-ray diffraction spectrum is described as "320 type self-recording spectrophotometer" ( And a reflection type diffraction spectrum.

The titanyl phthalocyanine pigment according to the present invention has a main peak of the black angle 2θ of 9.6 ° ± 0.2 ° and 27.2 ° ± 0.
2 ゜, but in addition to these characteristic peaks, 11.7 ゜ ± 0.2 ゜, 15.0 ゜ ± 0.2 ゜, 23.5 ゜ ± 0.2 ゜ and 24.1 ゜ ±
It also has a peak at 0.2 ゜.

Among the titanyl phthalocyanine pigments according to the present invention, those in which the peak intensity at 9.6 ° ± 0.2 ° of the Bragg angle 2θ is 40% or more of the peak intensity at 27.2 ° ± 0.2 ° are particularly preferable in terms of sensitivity, chargeability and the like. .

Next, a method for producing the titanyl phthalocyanine according to the present invention will be described. For example, 1,3-diiminoisoindoline and sulfolane are mixed, titanium tetrapropoxide is added thereto, and the mixture is reacted under a nitrogen atmosphere. The reaction temperature is from 80C to 300C, preferably from 100C to 260C. After completion of the reaction, the mixture is left to cool, and the precipitate is collected by filtration to obtain titanyl phthalocyanine. Next, by subjecting this to a solvent treatment, the desired crystal form of titanyl phthalocyanine shown in FIGS. 3 to 6 can be obtained. , A disperser, an agitator, a ball mill, a sand mill, an attritor, or the like.

In the present invention, in addition to the above-mentioned titanyl phthalocyanine as a carrier generating substance, other carrier generating substances may be used in combination as long as the effects of the present invention are not impaired. Such a carrier generating substance that can be used in combination is different from the titanyl phthalocyanine of the present invention in a crystal form, for example, α
And phthalocyanine pigments, azo pigments, anthraquinone pigments, perylene pigments, polycyclic quinone pigments, squarium pigments, etc., in addition to titanyl phthalocyanines of the type, β type, α, β mixed type, amorphous type and the like.

In order to prepare the photoreceptor of the present invention, for example, the titanyl phthalocyanine pigment according to the present invention is mixed and dispersed in a solution obtained by dissolving a binder resin in a solvent, and a coating obtained by dissolving a carrier transporting material described below in this is coated. The solution is applied on a conductive support provided with an undercoat layer in advance according to need by, for example, a dip coating, spray coating, or spiral coating method to obtain a photoconductor having a single-layer structure shown in FIG. . In addition, 1 in the figure is a conductive support,
Reference numeral 2 denotes a photosensitive layer having a single-layer structure, and reference numeral 3 denotes an undercoat layer.

However, from the standpoint of obtaining a photosensitive member having high sensitivity characteristics and high durability, it is preferable to use a function-separated type photosensitive member having a two-layer structure shown in FIG. In this case, after applying the coating liquid obtained by mixing and dispersing the pigment in a solution in which a binder resin is dissolved, the carrier generation layer 5 is formed by applying the coating liquid on the support 1 having the undercoat layer as necessary. A coating solution containing a carrier transporting material is applied on the carrier generating layer to form a carrier transporting layer 6 to form a two-layer photosensitive layer 4. Below, 2
The following description focuses on the photoconductor having a layer structure.

To form the carrier generation layer 5 of the photosensitive layer 4 having the two-layer structure, a binder resin is mixed and dissolved in an appropriate solvent or dispersion medium, and the titanyl phthalocyanine pigment is mixed in the obtained solution. It is dispersed by a mixer, a ball mill, an ultrasonic disperser, or the like to prepare a coating liquid containing the fine particles of the pigment, and is coated on the undercoat layer 3 provided on the surface of the conductive support 1.

In forming the carrier generating layer in the two-layered photoconductor, the modified silicone resin is dispersed in the dispersion liquid of the titanyl phthalocyanine pigment, and for stabilizing the crystallinity and cohesion after the layer is formed, a modified silicone resin is used. It has been found to be advantageous as a binder resin.

As the modified silicone resin used in the present invention, for example, polyester-modified silicone resin, epoxy-modified silicone resin, acryl-modified silicone resin and the like can be preferably used. Specific examples of the polyester-modified silicone resin preferably used in the present invention include AY42-125 (manufactured by Toray Silicone); specific examples of the epoxy-modified silicone resin include SR2145 (manufactured by Toray Silicone); acrylic-modified Specific examples of the silicone resin include AY42-135 (manufactured by Toray Silicone Co., Ltd.).

The binder resin used for the carrier generation layer 5 can be used alone or as a mixture of two or more kinds. The ratio of the carrier generating substance to the binder resin is preferably 10 to 600% by weight, more preferably 50 to 4% by weight.
00% by weight.

As the solvent or the dispersion medium used for forming the carrier generation layer, any one can be widely used. For example, n-butylamine, ethylenediamine, N, N-dimethylformamide, acetone, methyl ethyl ketone,
Cyclohexanone, tetrahydrofuran, dioxane,
Ethyl acetate, butyl acetate, methylcellosolve, ethylcellosolve, ethylene glycol dimethyl ether, toluene, xylene, acetophenone, chloroform, dichloromethane, dichloroethane, trichloroethane, methanol, ethanol, propanol, butanol and the like.

The thickness of the carrier generation layer 5 thus formed is
It is preferably 0.01 to 20 μm, more preferably
0.05 to 5 μm.

When the carrier generating material is dispersed to form the carrier generating layer 5, the carrier generating material is preferably a powder having an average particle diameter of 2 μm or less, preferably 1 μm or less. That is, if the particle size is too large, the dispersion in the layer becomes poor, and the particles partially protrude from the surface, resulting in poor surface smoothness. In some cases, discharge occurs at the protruding portions of the particles, or The toner particles tend to adhere to the toner and a toner filming phenomenon easily occurs.

Next, a photoreceptor is prepared by providing a carrier transport layer 6 on the carrier generation layer 5. As a solvent used in a coating solution for forming the carrier transport layer 6, a binder resin and a carrier described later are used. A material that dissolves a transport substance or the like but does not dissolve or erode the lower carrier generation layer 5 is selected.

As the carrier transporting substance, various substances can be used, and as typical examples, for example, oxazole,
Compounds having a nitrogen-containing heterocyclic nucleus represented by oxadiazole, titazole, thiadiazole, imidazole and the like and a condensed ring nucleus thereof, a polyarylalkane compound,
Pyrazoline compounds, hydrazone compounds, triarylamine compounds, styryl compounds, styryltriphenylamine compounds, β-phenylstyryltriphenylamine compounds, butadiene compounds, hexatriene compounds, carbazole compounds, polycondensates Ring compounds and the like can be mentioned.

Specific examples of these carrier transporting substances include, for example, the carrier transporting substances described in JP-A-61-107356, and the structures of particularly typical ones are shown below.

As the binder resin for forming the carrier transporting layer together with the carrier transporting material, any binder resin can be selected, and it is assumed that the binder resin is hydrophobic and has a film-forming ability.

Polycarbonate Polycarbonate Z resin Acrylic resin Methacrylic resin Polyvinyl chloride Polyvinylidene chloride Polystyrene Styrene-butadiene copolymer Polyvinyl acetate Polyvinylcarbazole Styrene-alkyd resin Silicone resin Silicone-alkyd resin Polyester Phenol resin Polyurethane Epoxy resin Vinylidene chloride-acrylonitrile copolymer Chloride Vinyl-vinyl acetate copolymer Vinyl chloride-vinyl acetate-maleic anhydride copolymer A wide variety of solvents or dispersion media can be used for forming the carrier transport layer. For example,
n-butylamine, ethylenediamine, N, N-dimethylformamide, acetone, methyl ethyl ketone, cyclohexanone, tetrahydrofuran, dioxane, ethyl acetate, butyl acetate, methyl cellosolve, ethyl cellosolve, ethylene glycol dimethyl ether, toluene,
Xylene, acetophenone, chloroform, dichloromethane, dichloroethane, trichloroethane, methanol, ethanol, propanol, butanol and the like.

The ratio of the carrier transporting substance to the binder resin is preferably from 10 to 500% by weight, and the thickness of the carrier transporting layer is preferably from 1 to 100 µm, more preferably from 5 to 3%.
0 μm.

The photosensitive layer of the photoreceptor of the present invention may contain an electron accepting substance for the purpose of improving sensitivity, reducing residual potential, or reducing fatigue upon repeated use. Examples of such an electron accepting substance include succinic anhydride, maleic anhydride, dibromosuccinic anhydride, phthalic anhydride, tetrachlorophthalic anhydride, tetrabromophthalic anhydride, and 3-bromophthalic anhydride.
Nitrophthalic anhydride, 4-nitrophthalic anhydride, pyromellitic anhydride, melitic anhydride, tetracyanoethylene, tetracyanoquinodimethane, o-dinitrobenzene, m-dinitrobenzene, 1,3,5-trinitrobenzene, p-nitrobenzonitrile, picryl chloride,
Quinone chlorimide, chloranil, bromanyl, dichlorodicyano-p-benzoquinone, anthraquinone, dinitroanthraquinone, 9-fluorenylidenemalonodinitrile, polynitro-9-fluorenylidenemalonodinitrile, picric acid, o-nitrobenzoic acid, Examples thereof include p-nitrobenzoic acid, 3,5-dinitrobenzoic acid, pentafluorobenzoic acid, 5-nitrosalicylic acid, 3,5-dinitrosalicylic acid, phthalic acid, melitic acid, and other compounds having a high electron affinity. The addition ratio of the electron accepting substance is 0.01 to 200 with respect to the weight of the carrier generating substance 100.
And more preferably 0.1 to 100.

Further, the photosensitive layer may contain a deterioration inhibitor such as an antioxidant and a light stabilizer for the purpose of improving storage stability, durability and environmental dependency.

Incidentally, in the photoconductor having a single-layer structure shown in FIG.
The carrier generating substance using the photosensitive layer 2 is titanyl phthalocyanine or the like according to the present invention, and the carrier transporting substance may be selected from those described above. The binder resin of the photosensitive layer 2 uses a modified silicone resin at least as a main component. In addition, the additive substance to the photosensitive layer 2 may be the same as described above.

As the conductive support, a metal plate, a metal drum, or the like is used, and a conductive polymer or a conductive compound such as indium oxide, or a thin layer of a metal such as aluminum or palladium is applied, deposited, or laminated. Is provided on paper or a plastic film.

Although the configuration of the photoreceptor of the present invention has been exemplified above, as is apparent from the following examples, the photoreceptor has high sensitivity characteristics as a photoreceptor using a laser beam as an exposure unit, and has black spots during reversal development. It has excellent characteristics that do not cause the drawbacks described above.

[Examples] Hereinafter, the present invention will be described in more detail with reference to Examples.

First, synthesis examples of various titanyl phthalocyanine pigments will be described.

(Synthesis example 1) 29.2 g of 1,3-diiminoisoindoline and 200 m of sulfolane
were mixed, 17.0 g of titanium tetraisopropoxide was added, and the mixture was reacted at 140 ° C. for 2 hours under a nitrogen atmosphere. After allowing to cool, the precipitate is collected by filtration, washed with chloroform, washed with a 2% aqueous hydrochloric acid solution, washed with water and methanol, and dried.
25.5 g (88.5%) of titanyl phthalocyanine were obtained.

The product was dissolved in 20 volumes of concentrated sulfuric acid, poured into 100 volumes of water to precipitate out, filtered, and then the wet cake was dried in 1,2-
It was heated at 50 ° C. for 10 hours in dichloroethane to obtain a crystal form having an X-ray diffraction spectrum shown in FIG. This crystal has a Bragg angle 2θ peak intensity at 9.6 ° of 102 °
%Met.

(Synthesis Example 2) 29.2 g of 1,3-diiminoisoindoline and 200 m of sulfolane
were mixed, 17.0 g of titanium tetraisopropoxide was added, and the mixture was reacted at 140 ° C. for 2 hours under a nitrogen atmosphere. After allowing to cool, the precipitate is collected by filtration, washed with chloroform, washed with a 2% aqueous hydrochloric acid solution, washed with water and methanol, and dried.
25.5 g (88.5%) of titanyl phthalocyanine were obtained.

The product was dissolved in 20 volumes of concentrated sulfuric acid, poured into 100 volumes of water to precipitate out, filtered, and then the wet cake was dried in 1,2-
The mixture was stirred at room temperature for 1 hour with dichloroethane to obtain a crystal form having an X-ray diffraction spectrum shown in FIG. This crystal has a peak intensity at 9.6 ° of Bragg angle 2θ of 75 at 27.2 °.
%Met.

(Synthesis Example 3) 25.6 g of phthalodinitrile and 150 ml of α-chloronaphthalene
6.5 ml of titanium tetrachloride was added dropwise to the above mixture under a nitrogen stream, and reacted at a temperature of 200 to 220 ° C. for 5 hours. The precipitate was collected by filtration, washed with α-chloronaphthalene, washed with chloroform, and then washed with methanol. Then, reflux in ammonia water to complete the hydrolysis, washing with water,
After washing with methanol and drying, titanyl phthalocyanine 21.8
g (75.6%).

The product is dissolved in 10 times the volume of concentrated sulfuric acid, poured into 100 volumes of water to precipitate out, and after filtration, the wet cake is dried.
The mixture was stirred at room temperature for 1 hour with dichloroethane to obtain a crystal form having an X-ray diffraction spectrum shown in FIG. This crystal has a peak intensity at 9.6 ° of Bragg angle 2θ of 45 at 27.2 °.
%Met.

(Synthesis Example 4) 25.6 g of phthalodinitrile and 150 ml of α-chloronaphthalene
6.5 ml of titanium tetrachloride was added dropwise to the above mixture under a nitrogen stream, and reacted at a temperature of 200 to 220 ° C. for 5 hours. The precipitate was collected by filtration, washed with α-chloronaphthalene, washed with chloroform, and then washed with methanol. Then, reflux in ammonia water to complete the hydrolysis, washing with water,
After washing with methanol and drying, titanyl phthalocyanine 21.8
g (75.6%).

The product was dissolved in 10 volumes of concentrated sulfuric acid, poured into 100 volumes of water to precipitate out, filtered, and the wet cake was stirred with o-dichlorobenzene for 1 hour at room temperature to obtain the product shown in FIG. It was a crystal form having the X-ray diffraction spectrum shown. This crystal has a peak intensity at 9.6 ° of Bragg angle 2θ of 35 at 27.2 °.
%Met.

(Comparative Synthesis Example 1) After the wet cake of Synthesis Example 1 was dried and heated and stirred using α-chloronaphthalene, β-type titanyl phthalocyanine as shown in FIG. 7 was obtained.

Example 1 3 parts (parts by weight; hereinafter the same) of a copolymerized polyamide “Lacamide 5003” (manufactured by Dainippon Ink and Chemicals, Inc.) were dissolved in 100 parts of methanol by heating, filtered through a 0.6 μm filter, and then permeated. The coating was applied on an aluminum drum by a coating method to form an undercoat layer having a thickness of 0.5 μm.

On the other hand, 3 parts of titanyl phthalocyanine having the X-ray diffraction pattern of FIG. 3 obtained in Synthesis Example 1 and a polyester-modified silicone resin "AY42-12" as a binder resin
5 "(manufactured by Toray Silicone Co., Ltd.) A liquid obtained by dispersing 3 parts of solid content and 100 parts of methyl isobutyl ketone as a dispersion medium by using a sand mill is applied on the undercoat layer by a permeation coating method. A carrier generation layer having a thickness of 0.2 μm was formed. Next, 1 part of the carrier transporting substance T-1, 1.5 parts of a polycarbonate resin “Iupilon Z 200” (manufactured by Mitsubishi Gas Chemical Company) and a small amount of silicone oil “KF-54” (manufactured by Shin-Etsu Chemical Co., Ltd.) were added to 1,2- Using a solution dissolved in 10 parts of dichloroethane, the solution was permeated and dried, and then a carrier transport layer having a thickness of 25 μm was formed. The photoconductor thus obtained is referred to as Sample 1.

(Examples 2 to 5) Four types of photoconductors were obtained in the same manner as in Example 1 except that the type of the carrier generating substance and the type of the resin of the carrier generating layer were as shown in Table 2, and these were used as Sample 2. To 5.

(Comparative Examples 1 to 3) Three types of photoconductors were obtained in the same manner as in Example 1 except that the type of the carrier generating substance and the type of the resin of the carrier generating layer were as shown in Table 2, and these were used as comparative samples. 1 to 3.

(Evaluation) The samples 1 to 5 and the comparative samples 1 to 3 were referred to as “U-Bix 155”.
0 "mounted on (manufactured by Konica Corp.) (semiconductor laser light source mounting) modified machine, non-exposed portion potential V _H is adjusted grid potential V _G to be -600 [V], exposure for the irradiation of 0.7mW Section potential V
_L was measured. In addition, reversal development was performed at a developing bias of -560 [V], and black spots on a white background portion of the copied image were evaluated.

The evaluation of black spots was performed using the image analysis system "Omnicon 30
The particle size and number of black spots were measured using a “Type 00” (manufactured by Shimadzu Corporation), and the number of black spots having a φ (diameter) of 0.05 mm or more was determined based on the number of black spots per cm ² . The criteria for black spot evaluation are as shown in Table 1 below.

Table 2 shows the results of the evaluation.

From Table 2, it can be seen that the photoreceptor of the present invention has higher sensitivity characteristics than the comparative photoreceptor, has good charge retention, has few image defects, and has few black spots during reversal development. .

[Effects of the Invention] As described above in detail, according to the photoreceptor of the present invention, occurrence of black spots and the like during reversal development is small, and a high-sensitivity, high-quality image can be stably obtained.

BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1 and 2 are cross-sectional views illustrating the layer structure of the photoreceptor of the present invention, respectively, and FIGS. 3 to 6 are Xs of the titanyl phthalocyanine pigment of the examples of the present invention, respectively. FIG. 7 is an X-ray diffraction spectrum of a titanyl phthalocyanine pigment of a comparative example. DESCRIPTION OF SYMBOLS 1 ... Conductive support 2 ... Single layer photosensitive layer 3 ... Undercoat layer 4 ... Double layer photosensitive layer 5 ... Carrier generating layer 6 ... Carrier transport layer

────────────────────────────────────────────────── ─── Continuation of the front page (72) Inventor Yoshihide Fujimaki 2970 Ishikawacho, Hachioji-shi, Tokyo Inside Konica Corporation (56) References JP-A-64-82045 (JP, A) JP-A-64-82046 (JP) , A) (58) Field surveyed (Int. Cl. ⁶ , DB name) G03G 5/06 G03G 5/05

Claims (2)

(57) [Claims] 1. An electrophotographic photosensitive member having a photosensitive layer on a conductive support, wherein the photosensitive layer has a Cu-Kα characteristic X-ray (wavelength
1.54 °) containing a titanyl phthalocyanine pigment having a main peak of Bragg angle 2θ of at least 9.6 ° ± 0.2 ° and 27.2 ° ± 0.2 °, and a binder containing a modified silicone resin as a main component, wherein the modified silicone resin is modified with a polyester. An electrophotographic photosensitive member comprising at least one selected from a silicone resin, an epoxy-modified silicone resin, and an acryl-modified silicone resin. 2. The electrophotographic photosensitive member according to claim 1, wherein said photosensitive layer is formed by laminating a carrier generating layer and a carrier transporting layer in this order, and said carrier generating layer contains said titanyl phthalocyanine pigment and said modified silicone resin. body.