JPS6313792Y2 - - Google Patents
Info
- Publication number
- JPS6313792Y2 JPS6313792Y2 JP8585383U JP8585383U JPS6313792Y2 JP S6313792 Y2 JPS6313792 Y2 JP S6313792Y2 JP 8585383 U JP8585383 U JP 8585383U JP 8585383 U JP8585383 U JP 8585383U JP S6313792 Y2 JPS6313792 Y2 JP S6313792Y2
- Authority
- JP
- Japan
- Prior art keywords
- gas
- activated carbon
- heating
- pipe
- regenerator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000007789 gas Substances 0.000 claims description 78
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 62
- 238000010438 heat treatment Methods 0.000 claims description 39
- 238000003795 desorption Methods 0.000 claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 238000006477 desulfuration reaction Methods 0.000 claims description 4
- 230000023556 desulfurization Effects 0.000 claims description 4
- 230000008929 regeneration Effects 0.000 claims description 4
- 238000011069 regeneration method Methods 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 14
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 10
- 239000003350 kerosene Substances 0.000 description 5
- 239000001294 propane Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
Description
【考案の詳細な説明】
本考案は、乾式脱硫設備における活性炭の再生
装置に関するものである。[Detailed Description of the Invention] The present invention relates to an activated carbon regeneration device in a dry desulfurization facility.
従来のこの種の装置は、たとえば第1図に示す
ような構成からなつている。 A conventional device of this type has a configuration as shown in FIG. 1, for example.
第1図において、aは活性炭再生器、bは飽和
活性炭供給ライン、cは再生活性炭排出ライン、
dは加熱管、eは活性炭充てん部、fは灯油供給
管、gは加熱用ガス発生器、hは加熱用ガス供給
管、iは液化プロパンガス供給管、jは脱離用ガ
ス発生器、kは脱離用ガス供給管、mは加熱使用
ずみガス排出管、nは二酸化硫黄リツチガス排出
ラインである。 In Figure 1, a is an activated carbon regenerator, b is a saturated activated carbon supply line, c is a recycled activated carbon discharge line,
d is a heating tube, e is an activated carbon filled part, f is a kerosene supply pipe, g is a heating gas generator, h is a heating gas supply pipe, i is a liquefied propane gas supply pipe, j is a desorption gas generator, k is a desorption gas supply pipe, m is a heated used gas discharge pipe, and n is a sulfur dioxide rich gas discharge line.
すなわち、二酸化硫黄を吸着した飽和活性炭を
再生するには、活性炭を昇温するための加熱用ガ
スと、活性炭から脱離した二酸化硫黄を再生器a
から排出するための脱離用ガスとが必要である。
ここで、活性炭は加熱管d内で高温になるため、
脱離用ガス中に酸素分が多いと燃焼するので、従
来は高価な液化プロパンガスを燃焼させて低酸素
濃度のガスを発生させ、それを脱離用ガスとして
いる。しかし、加熱用ガスは直接活性炭に接触し
ないので、低酸素濃度とする必要がなく、安価な
灯油燃焼ガスを使用している。 In other words, in order to regenerate saturated activated carbon that has adsorbed sulfur dioxide, heating gas for raising the temperature of activated carbon and sulfur dioxide desorbed from activated carbon are transferred to regenerator a.
A desorption gas is required to discharge the gas from the reactor.
Here, since the activated carbon becomes high temperature in the heating tube d,
If there is a large amount of oxygen in the desorption gas, it will burn, so conventionally expensive liquefied propane gas is combusted to generate gas with a low oxygen concentration, which is used as the desorption gas. However, since the heating gas does not come into direct contact with the activated carbon, there is no need for a low oxygen concentration, and inexpensive kerosene combustion gas is used.
このように、従来は、加熱用ガス発生器gと脱
離用ガス発生器jの2基を必要としているので、
設備費が嵩み、かつ、液化プロパンガスの使用量
が多く、運転費も嵩むという欠点があつた。 In this way, conventionally, two units, the heating gas generator g and the desorption gas generator j, are required.
The disadvantages were that the equipment costs were high, the amount of liquefied propane gas used was large, and the operating costs were high.
本考案は、ガス発生器を1つにし、かつ、高価
な液化プロパンガスを使用しなくてもよいように
することにより、設備費の低減と運転費の低減と
を図ることができる乾式脱硫設備における活性炭
の再生装置を提供することを目的とするものであ
る。 This invention is a dry desulfurization equipment that can reduce equipment costs and operating costs by using only one gas generator and eliminating the need to use expensive liquefied propane gas. The object of the present invention is to provide an activated carbon regeneration device.
このため、本考案の構成は、頂部に接続された
飽和活性炭供給ラインと、底部に接続された再生
活性炭排出ラインと、内部に活性炭を通して外部
から加熱する加熱管を有する活性炭再生器におい
て、前記再生器の外部に設けられて低酸素濃度の
加熱用ガスを発生するガス発生器と、このガス発
生器からの加熱用ガスを前記加熱管の外部に供給
する加熱用ガス供給管と、加熱使用ずみのガスを
前記再生器から排出する加熱使用ずみガス排出管
と、このガス排出管の途中から分岐状に設けられ
て該ガス排出管からの加熱使用ずみのガスの一部
を前記加熱管内に供給する脱離用ガス供給管とを
備えていることを特徴としている。 For this reason, the configuration of the present invention is such that the activated carbon regenerator has a saturated activated carbon supply line connected to the top, a recycled activated carbon discharge line connected to the bottom, and a heating tube that heats the activated carbon from the outside through the activated carbon inside. a gas generator that is installed outside the vessel and generates a heating gas with a low oxygen concentration; a heating gas supply pipe that supplies the heating gas from the gas generator to the outside of the heating tube; a heated used gas discharge pipe for discharging the gas from the regenerator, and a part of the heated used gas discharged from the gas discharge pipe branched from the middle of the gas discharge pipe to supply a part of the heated used gas from the gas discharge pipe to the heating pipe. The invention is characterized in that it is equipped with a desorption gas supply pipe.
以下、本考案の一実施例について、第2図を参
照しながら説明する。 An embodiment of the present invention will be described below with reference to FIG.
第2図において、1は活性炭再生器、2は該再
生器1の頂部に接続された飽和活性炭供給ライ
ン、3は該再生器1の底部に接続された再生活性
炭排出ライン、4は内部に活性炭を通して外部か
ら加熱する加熱管、5は活性炭充てん部、6は灯
油供給管、7は該再生器1の外部に設けられて低
酸素濃度の加熱用ガスを発生するガス発生器、8
は該ガス発生器7からの加熱用ガスを前記加熱管
4の外部に供給する加熱用ガス供給管、9は加熱
使用ずみのガスを前記再生器1から排出する加熱
使用ずみガス排出管、10は該ガス排出管9の途
中から分岐状に設けられて該ガス排出管9からの
加熱使用ずみのガスの一部を前記加熱管4の内部
に供給する脱離ガス供給管、11は二酸化硫黄リ
ツチガス排出ラインである。 In FIG. 2, 1 is an activated carbon regenerator, 2 is a saturated activated carbon supply line connected to the top of the regenerator 1, 3 is a recycled activated carbon discharge line connected to the bottom of the regenerator 1, and 4 is an activated carbon inside. 5 is an activated carbon filled part, 6 is a kerosene supply pipe, 7 is a gas generator installed outside the regenerator 1 and generates a heating gas with a low oxygen concentration, 8
9 is a heating gas supply pipe that supplies the heating gas from the gas generator 7 to the outside of the heating tube 4; 9 is a heated used gas discharge pipe that discharges the heated used gas from the regenerator 1; 10 11 is a desorption gas supply pipe that is branched from the middle of the gas exhaust pipe 9 and supplies a part of the heated and used gas from the gas exhaust pipe 9 to the inside of the heating pipe 4; 11 is a sulfur dioxide supply pipe; This is the rich gas discharge line.
第2図に示すように構成された乾式脱硫設備に
おける活性炭の再生装置においては、図示されて
いない吸着塔で排煙中の硫黄酸化物を吸着した飽
和活性炭は飽和活性炭供給ライン2から活性炭再
生器1の頂部に入り、加熱管4の内部を流下する
間に、後述する加熱用ガスで加熱管4の外部から
間接的に加熱され、350〜420℃程度まで昇温さ
れ、活性炭中の二酸化硫黄を放出する。再生され
た活性炭は再活性炭排出ライン3から排出され、
硫黄酸化物吸着用として再使用される。一方、加
熱用ガス発生器7では灯油供給ライン6からの灯
油を燃焼させ、酸素濃度が1.5%以下の加熱用ガ
スになるように制御される。そして該ガス発生器
7で発生された加熱用ガスは加熱用ガス供給管8
を経て加熱管4の外部に供給され、加熱管4の内
部を通る活性炭を前述のように加熱する。加熱ず
みのガスは温度が下がつて加熱使用ずみガス排出
管9から排出されるが、その一部は脱離用ガス供
給管10を経て該再生器1の上部および下部から
加熱管4の内部に供給され、加熱管4の内部で放
出された二酸化硫黄を同伴し、二酸化硫黄リツチ
ガスとなつて排出ライン11から排出され、次工
程へ送られる。 In the activated carbon regeneration device in the dry desulfurization equipment configured as shown in FIG. 1, and while flowing down inside the heating tube 4, it is indirectly heated from the outside of the heating tube 4 by the heating gas described later, and the temperature is raised to about 350 to 420℃, and the sulfur dioxide in the activated carbon is heated. emit. The regenerated activated carbon is discharged from the reactivated carbon discharge line 3,
Reused for adsorption of sulfur oxides. On the other hand, the heating gas generator 7 burns kerosene from the kerosene supply line 6 and is controlled so that the heating gas has an oxygen concentration of 1.5% or less. The heating gas generated by the gas generator 7 is supplied to a heating gas supply pipe 8.
The activated carbon is supplied to the outside of the heating tube 4 through the heating tube 4, and the activated carbon passing through the inside of the heating tube 4 is heated as described above. The heated gas cools down and is discharged from the heated used gas discharge pipe 9, but part of it passes through the desorption gas supply pipe 10 and is discharged from the upper and lower parts of the regenerator 1 into the heating pipe 4. The sulfur dioxide released inside the heating tube 4 is entrained in the sulfur dioxide rich gas, which is discharged from the discharge line 11 and sent to the next process.
このように、本考案によれば、従来のような脱
離用ガス発生器を設ける必要がなくなり、したが
つて、脱離用ガス発生器およびその付帯設備を省
略することができ、それだけ設備費を低減するこ
とができるうえ、脱離用ガスとして高価な液化プ
ロパンガスを使用する必要がなくなり、脱離用ガ
スとしては、すべて加熱使用ずみのガスを利用す
るので、運転費が著しく低減されるなど、本考案
の奏する効果は、きわめて大きい。 As described above, according to the present invention, there is no need to provide a desorption gas generator like in the past, and therefore, the desorption gas generator and its ancillary equipment can be omitted, and the equipment cost can be reduced accordingly. In addition to eliminating the need to use expensive liquefied propane gas as the desorption gas, operating costs are significantly reduced because all heated gas is used as the desorption gas. The effects of this invention are extremely large.
第1図は従来の装置の一例を示した説明図、第
2図は本考案の一実施例を示した説明である。
1……活性炭再生器、2……飽和活性炭供給ラ
イン、3……再生活性炭排出ライン、4……加熱
管、7……ガス発生器、8……加熱用ガス供給
管、9……加熱使用ずみガス排出管、10……脱
離用ガス供給管。
FIG. 1 is an explanatory diagram showing an example of a conventional device, and FIG. 2 is an explanatory diagram showing an embodiment of the present invention. 1...Activated carbon regenerator, 2...Saturated activated carbon supply line, 3...Regenerated activated carbon discharge line, 4...Heating tube, 7...Gas generator, 8...Heating gas supply pipe, 9...Heating use desorption gas discharge pipe, 10... gas supply pipe for desorption.
Claims (1)
部に接続された再生活性炭排出ラインと、内部に
活性炭を通して外部から加熱する加熱管とを有す
る活性炭再生器において、前記再生器の外部に設
けられて低酸素濃度の加熱用ガスを発生するガス
発生器と、このガス発生器からの加熱用ガスを前
記加熱管の外部に供給する加熱用ガス供給管と、
加熱使用ずみのガスを前記再生器から排出する加
熱使用ずみガス排出管と、このガス排出管の途中
から分岐状に設けられて該ガス排出管からの加熱
使用ずみのガスの一部を前記加熱管内に供給する
脱離用ガス供給管とを備えていることを特徴とす
る、乾式脱硫設備における活性炭の再生装置。 In an activated carbon regenerator having a saturated activated carbon supply line connected to the top, a recycled activated carbon discharge line connected to the bottom, and a heating tube for passing activated carbon inside and heating from the outside, a gas generator that generates a heating gas having an oxygen concentration; a heating gas supply pipe that supplies the heating gas from the gas generator to the outside of the heating tube;
A heated used gas exhaust pipe for discharging the heated used gas from the regenerator, and a heated used gas exhaust pipe provided in a branch shape from the middle of the gas exhaust pipe to discharge a part of the heated used gas from the gas exhaust pipe to the heated used gas. 1. An activated carbon regeneration device in a dry desulfurization facility, comprising a desorption gas supply pipe that is supplied into the pipe.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8585383U JPS59193534U (en) | 1983-06-07 | 1983-06-07 | Activated carbon regeneration device in dry desulfurization equipment |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8585383U JPS59193534U (en) | 1983-06-07 | 1983-06-07 | Activated carbon regeneration device in dry desulfurization equipment |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59193534U JPS59193534U (en) | 1984-12-22 |
JPS6313792Y2 true JPS6313792Y2 (en) | 1988-04-19 |
Family
ID=30215811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8585383U Granted JPS59193534U (en) | 1983-06-07 | 1983-06-07 | Activated carbon regeneration device in dry desulfurization equipment |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59193534U (en) |
-
1983
- 1983-06-07 JP JP8585383U patent/JPS59193534U/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS59193534U (en) | 1984-12-22 |
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