JPS6313310B2 - - Google Patents
Info
- Publication number
- JPS6313310B2 JPS6313310B2 JP53119932A JP11993278A JPS6313310B2 JP S6313310 B2 JPS6313310 B2 JP S6313310B2 JP 53119932 A JP53119932 A JP 53119932A JP 11993278 A JP11993278 A JP 11993278A JP S6313310 B2 JPS6313310 B2 JP S6313310B2
- Authority
- JP
- Japan
- Prior art keywords
- bromine
- oil
- battery
- zinc
- viscosity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 87
- 229910052794 bromium Inorganic materials 0.000 claims description 86
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 84
- 239000003792 electrolyte Substances 0.000 claims description 26
- 239000008139 complexing agent Substances 0.000 claims description 25
- 239000007788 liquid Substances 0.000 claims description 25
- 230000031709 bromination Effects 0.000 claims description 23
- 238000005893 bromination reaction Methods 0.000 claims description 23
- ZRXYMHTYEQQBLN-UHFFFAOYSA-N [Br].[Zn] Chemical compound [Br].[Zn] ZRXYMHTYEQQBLN-UHFFFAOYSA-N 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 13
- -1 ethyldimethylpropyl Chemical group 0.000 claims description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 10
- 239000003921 oil Substances 0.000 description 68
- 239000012071 phase Substances 0.000 description 19
- 150000003839 salts Chemical class 0.000 description 18
- VNDYJBBGRKZCSX-UHFFFAOYSA-L zinc bromide Chemical compound Br[Zn]Br VNDYJBBGRKZCSX-UHFFFAOYSA-L 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 14
- 238000012546 transfer Methods 0.000 description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- 239000011701 zinc Substances 0.000 description 9
- 210000004027 cell Anatomy 0.000 description 8
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 7
- 229940102001 zinc bromide Drugs 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 4
- 150000002367 halogens Chemical class 0.000 description 4
- 238000013508 migration Methods 0.000 description 4
- 230000005012 migration Effects 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000000536 complexating effect Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000005621 tetraalkylammonium salts Chemical group 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000003868 ammonium compounds Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000012935 Averaging Methods 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 210000001787 dendrite Anatomy 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- PJABQHODPAEOFU-UHFFFAOYSA-N diethyl(dipropyl)azanium Chemical class CCC[N+](CC)(CC)CCC PJABQHODPAEOFU-UHFFFAOYSA-N 0.000 description 1
- VYFNGSZRWLYKGI-UHFFFAOYSA-M diethyl(dipropyl)azanium;bromide Chemical compound [Br-].CCC[N+](CC)(CC)CCC VYFNGSZRWLYKGI-UHFFFAOYSA-M 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 231100000683 possible toxicity Toxicity 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 238000009790 rate-determining step (RDS) Methods 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical class CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- HWCKGOZZJDHMNC-UHFFFAOYSA-M tetraethylammonium bromide Chemical compound [Br-].CC[N+](CC)(CC)CC HWCKGOZZJDHMNC-UHFFFAOYSA-M 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- SEACXNRNJAXIBM-UHFFFAOYSA-N triethyl(methyl)azanium Chemical class CC[N+](C)(CC)CC SEACXNRNJAXIBM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/365—Zinc-halogen accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Secondary Cells (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83824377A | 1977-09-30 | 1977-09-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5461640A JPS5461640A (en) | 1979-05-18 |
| JPS6313310B2 true JPS6313310B2 (fr) | 1988-03-24 |
Family
ID=25276627
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11993278A Granted JPS5461640A (en) | 1977-09-30 | 1978-09-30 | Battery with bromine electrode |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPS5461640A (fr) |
| CA (1) | CA1129945A (fr) |
| DE (1) | DE2842500A1 (fr) |
| FR (1) | FR2404928A1 (fr) |
| GB (1) | GB2005064B (fr) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6318819U (fr) * | 1986-07-22 | 1988-02-08 |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0091520B1 (fr) * | 1982-04-14 | 1986-12-10 | Kabushiki Kaisha Meidensha | Batterie secondaire métal-halogène avec circuit de circulation de l'électrolyte |
| EP0109223B1 (fr) * | 1982-11-02 | 1987-07-22 | Kabushiki Kaisha Meidensha Meidensha Electric Mfg. Co., Ltd. | Electrolyte pour accumulateurs zinc-brome |
| US4491625A (en) * | 1984-03-26 | 1985-01-01 | Exxon Research & Engineering Co. | Zinc-bromine batteries with improved electrolyte |
| MX2017004379A (es) * | 2014-10-06 | 2017-07-04 | Eos Energy Storage Llc | Montaje de terminal para bateria o celda electroquimica bipolar. |
| CN107077975A (zh) * | 2014-11-03 | 2017-08-18 | 塞克姆公司 | 用于电能储存和发电装置的基于混合的烷基季铵盐或鏻盐的电解质组合物 |
| WO2016080300A1 (fr) * | 2014-11-18 | 2016-05-26 | 国立大学法人 長崎大学 | Pile rechargeable |
| JP6457825B2 (ja) | 2015-01-29 | 2019-01-23 | 日東電工株式会社 | 粘着シート、及び、光学部材 |
| JP6955446B2 (ja) | 2015-05-11 | 2021-10-27 | ブローミン コンパウンズ リミテッド | フロー電池の添加物 |
| US11394069B2 (en) | 2015-11-10 | 2022-07-19 | Bromine Compounds Ltd. | Additives for a flow battery |
| US10892524B2 (en) | 2016-03-29 | 2021-01-12 | Eos Energy Storage, Llc | Electrolyte for rechargeable electrochemical cell |
| US11888164B2 (en) * | 2018-09-12 | 2024-01-30 | Gelion Technologies Pty Ltd | Battery with halogen sequestering agent |
| JP7292859B2 (ja) | 2018-11-19 | 2023-06-19 | 藤森工業株式会社 | 表面保護フィルム、及びそれが貼着された光学部品 |
| CN114621496B (zh) * | 2020-12-10 | 2022-11-15 | 中国科学院大连化学物理研究所 | 一种具有阻溴固溴功能Daramic复合离子传导膜的制备和应用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4981838A (fr) * | 1972-11-17 | 1974-08-07 | ||
| JPS52114927A (en) * | 1976-03-17 | 1977-09-27 | Eco Control | Halogen complexed ether |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH509672A (it) * | 1969-04-23 | 1971-06-30 | Consiglio Nazionale Ricerche | Elettrodo per accumulatori elettrici a alogenuro di zinco in elettrolita acquoso del tipo a catodo solubile ed anodo disciolto |
| US3944430A (en) * | 1970-09-18 | 1976-03-16 | Union Carbide Corporation | Rechargeable galvanic cell and electrolyte therefor-II |
| US3915744A (en) * | 1971-08-31 | 1975-10-28 | Consiglio Nazionale Ricerche | Electric battery |
| CH554078A (fr) * | 1971-08-31 | 1974-09-13 | Consiglio Nazionale Ricerche | Accumulateur electrique. |
| US4038459A (en) * | 1976-03-17 | 1977-07-26 | Eco-Control, Inc. | Halogen complexing alcohols and nitriles |
| US4105829A (en) * | 1976-04-07 | 1978-08-08 | Exxon Research & Engineering Co. | Metal halogen batteries and method of operating same |
| US4064324A (en) * | 1976-04-07 | 1977-12-20 | Exxon Research & Engineering Co. | Metal-Halogenelectrochemical cell |
| US4104447A (en) * | 1977-09-26 | 1978-08-01 | Eco-Control, Inc. | Halogen complexing alkyl salts for use in halogen cells |
-
1978
- 1978-09-19 CA CA311,588A patent/CA1129945A/fr not_active Expired
- 1978-09-29 GB GB7838781A patent/GB2005064B/en not_active Expired
- 1978-09-29 DE DE19782842500 patent/DE2842500A1/de active Granted
- 1978-09-30 JP JP11993278A patent/JPS5461640A/ja active Granted
- 1978-10-02 FR FR7828086A patent/FR2404928A1/fr active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4981838A (fr) * | 1972-11-17 | 1974-08-07 | ||
| JPS52114927A (en) * | 1976-03-17 | 1977-09-27 | Eco Control | Halogen complexed ether |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6318819U (fr) * | 1986-07-22 | 1988-02-08 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1129945A (fr) | 1982-08-17 |
| JPS5461640A (en) | 1979-05-18 |
| FR2404928A1 (fr) | 1979-04-27 |
| DE2842500C2 (fr) | 1987-10-15 |
| FR2404928B1 (fr) | 1983-07-29 |
| DE2842500A1 (de) | 1979-04-12 |
| GB2005064A (en) | 1979-04-11 |
| GB2005064B (en) | 1982-01-27 |
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