JPS63130789A - Improved electrolytic cell - Google Patents
Improved electrolytic cellInfo
- Publication number
- JPS63130789A JPS63130789A JP61276794A JP27679486A JPS63130789A JP S63130789 A JPS63130789 A JP S63130789A JP 61276794 A JP61276794 A JP 61276794A JP 27679486 A JP27679486 A JP 27679486A JP S63130789 A JPS63130789 A JP S63130789A
- Authority
- JP
- Japan
- Prior art keywords
- partition plate
- gas
- anode
- electrolytic cell
- cathode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000005192 partition Methods 0.000 claims abstract description 37
- 239000011248 coating agent Substances 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 238000005868 electrolysis reaction Methods 0.000 abstract description 7
- 150000003839 salts Chemical class 0.000 abstract description 7
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000004880 explosion Methods 0.000 abstract description 5
- -1 polytetrafluoroethylene Polymers 0.000 abstract description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 38
- 210000004027 cell Anatomy 0.000 description 14
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 8
- GVGCUCJTUSOZKP-UHFFFAOYSA-N nitrogen trifluoride Chemical compound FN(F)F GVGCUCJTUSOZKP-UHFFFAOYSA-N 0.000 description 5
- 239000011698 potassium fluoride Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 235000003270 potassium fluoride Nutrition 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 210000005056 cell body Anatomy 0.000 description 3
- 239000002360 explosive Substances 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229920001780 ECTFE Polymers 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 229920000840 ethylene tetrafluoroethylene copolymer Polymers 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- QKCGXXHCELUCKW-UHFFFAOYSA-N n-[4-[4-(dinaphthalen-2-ylamino)phenyl]phenyl]-n-naphthalen-2-ylnaphthalen-2-amine Chemical compound C1=CC=CC2=CC(N(C=3C=CC(=CC=3)C=3C=CC(=CC=3)N(C=3C=C4C=CC=CC4=CC=3)C=3C=C4C=CC=CC4=CC=3)C3=CC4=CC=CC=C4C=C3)=CC=C21 QKCGXXHCELUCKW-UHFFFAOYSA-N 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、溶融塩電解法による三弗化窒素ガス（ＮＦｓ
）や弗素ガス（Ｆ２）の製造の際に使用される電解槽の
改良に関する。Detailed Description of the Invention (Industrial Field of Application) The present invention is directed to the production of nitrogen trifluoride gas (NFs) by molten salt electrolysis.
) and fluorine gas (F2).
（従来の技術）
酸性フッ化アンモニウムまたはフッ化アンモニウムと弗
化水素を原料とするＮ）ｌ、Ｆ・ＩＰ系や、これに更に
酸性フッ化カリウムまたはフッ化カリウムを原料として
加えたにＦ−ＮＨａＦ−ＨＦ系溶融塩電解法によるＮＦ
３ガスの製造、並びに酸性フッ化カリウムまたは弗化カ
リウムと弗化水素を原料とするＫＦ・肝系溶融塩電解法
によるＦ２ガスの製造を行なう場合、電解槽には陽極か
ら発生するガスと陰極から発生するガスを隔離するため
の隔板が設けられている。(Prior art) N)l, F-IP system using acidic ammonium fluoride or ammonium fluoride and hydrogen fluoride as raw materials, and N-F-IP system in which acidic potassium fluoride or potassium fluoride is further added as a raw material. NF by NHaF-HF molten salt electrolysis method
When producing F2 gas by the KF/liver-based molten salt electrolysis method using acidic potassium fluoride or potassium fluoride and hydrogen fluoride as raw materials, the electrolytic cell contains the gas generated from the anode and the cathode. A diaphragm is provided to isolate gases generated from the
上記電解槽においては、陽極からはＮＦ３ガスまたはＦ
２ガスが、陰極からは水素ガス（Ｆ２）が発生する。こ
の二種類のガス、即ち、ＮＦ３ガスまたはＦ２ガスとＦ
２ガスは、混合すると爆発の危険性が極めて大きいので
、発生した二種類のガスの電解槽内での混合を防ぐ目的
で、陽極と陰極を隔離するための隔板が設けられている
。さらに、この隔板には電解浴に腐蝕されにくい鉄、銅
、ニッケルなどの金属板が通常使用されている。In the above electrolytic cell, NF3 gas or F
Hydrogen gas (F2) is generated from the cathode. These two types of gas, namely NF3 gas or F2 gas and F2 gas,
Since there is an extremely high risk of explosion when the two gases are mixed, a partition plate is provided to separate the anode and cathode in order to prevent the two gases from mixing in the electrolytic cell. Furthermore, a metal plate made of iron, copper, nickel, or the like, which is not easily corroded by an electrolytic bath, is usually used for this partition plate.
しかし、この様に電解槽には隔板を設けているにもかか
わらず、この電解槽を用いてＮＦ３ガスやＦ２ガスの製
造を行なう場合、陽極から発生するＮＦ、ガスまたはＦ
２ガス中に少なからずＦ２ガスが混在してきて、爆発限
界内のガスが生成する場合がある。これは、溶融塩電解
時に隔板の複極化現象が起こり、複極化した隔板の陽極
と相対する面からＨ２ガスが発生し、この■２ガスがＮ
Ｆ３ガスまたはＦｚガスと混合し、爆発限界内の混合ガ
スを生成するからである。However, even though the electrolytic cell is equipped with a diaphragm in this way, when producing NF3 gas or F2 gas using this electrolytic cell, NF, gas, or F2 gas generated from the anode is
A considerable amount of F2 gas may be mixed in with the two gases, and gas within the explosive limit may be generated. This is because bipolarization of the diaphragm occurs during molten salt electrolysis, H2 gas is generated from the surface of the bipolar diaphragm facing the anode, and this 2 gas is
This is because it mixes with F3 gas or Fz gas to produce a mixed gas within the explosive limit.
そこで、このような爆発限界内の混合ガスの生成を防止
するため、従来は陽極発生ガス中にＮ２等の不活性ガス
を混入させ、陽極発生ガス中に混入するＨ２ガスの濃度
を低下させることで爆発の危険を回避する方法が取られ
て来た。Therefore, in order to prevent the generation of such a mixed gas within the explosive limit, conventional methods have been to mix an inert gas such as N2 into the anode generated gas to reduce the concentration of H2 gas mixed into the anode generated gas. Measures have been taken to avoid the risk of explosion.
（発明が解決しようとする問題点）
しかし、この方法は隔板の複極化を防止するという方法
ではないので、ＮＦ３ガスまたはＦ２ガス中に水素ガス
が混入したままであり、根本的な問題解決にはならず、
電解条件によっては依然爆発の危険性は残っている。更
に、隔板は、前記の通りその材質が鉄、銅、ニッケルな
どの金属板であるので、電解浴に腐蝕されにくいとはい
え、若干の腐蝕は免れ難いという問題もある。(Problem to be solved by the invention) However, since this method does not prevent bipolarization of the diaphragm, hydrogen gas remains mixed in the NF3 gas or F2 gas, which is a fundamental problem. It's not a solution,
Depending on the electrolysis conditions, there is still a risk of explosion. Furthermore, as mentioned above, the material of the partition plate is a metal plate made of iron, copper, nickel, etc., so although it is not easily corroded by the electrolytic bath, there is a problem that some corrosion is inevitable.
（問題点を解決するための手段）
本発明者等は、根本的な解決手段である隔板の複極化防
止について種々検討を重ねた結果、隔板の少なくとも片
面をフッ素系樹脂で被覆すれば隔板の複極化を防止する
ことが可能で、しかも隔板も腐蝕されないことを見出し
、本発明を完成させるに至ったのである。(Means for solving the problem) As a result of various studies on preventing bipolarization of the partition plate, which is a fundamental solution, the inventors of the present invention discovered that at least one side of the partition plate should be coated with a fluororesin. They discovered that it is possible to prevent bipolarization of the diaphragm and that the diaphragm is not corroded, leading to the completion of the present invention.
すなわち、本発明は、陽極から発生するガスと陰極から
発生するガスを隔離するための隔板の少なくとも片面が
フッ素系樹脂被膜で覆われてなることを特徴とする改良
された電解槽であって、特には隔板の両面がフッ素系樹
脂被膜で覆われている。That is, the present invention is an improved electrolytic cell characterized in that at least one side of a partition plate for separating gas generated from the anode and gas generated from the cathode is covered with a fluororesin coating. In particular, both sides of the partition plate are covered with a fluororesin coating.
本発明を図面に基いて更に詳細に説明する。The present invention will be explained in more detail based on the drawings.
陽極から発生するガスと陰極から発生するガスを隔離す
るための隔板の形状には色々なものがある。例えば、隔
板が平板状である場合、隔板が陽極または陰極を取り巻
く形状である場合などがあり、特殊な例としては、蓋板
の中央部が下方にＵ字形に折曲っていてこの折曲り部が
隔板の役割を果す形状のものもある。There are various shapes of the partition plate for separating the gas generated from the anode and the gas generated from the cathode. For example, the diaphragm may be flat, or the diaphragm may be shaped to surround an anode or a cathode. In special cases, the center of the lid plate may be bent downward into a U-shape. Some have a shape in which the bent portion acts as a partition.
第１図、第３図、第５図は隔板が平板状である場合の、
第７図は隔板が陽極を取り巻く形状である場合の、第９
図は隔板が陰極を取り巻く形状である場合の、第１１図
は隔板が陽極を取り巻く形状でありかつ電解槽本体が陰
極である場合の、第１３図は蓋板の中央部がＵ字形に折
曲っていて該折曲り部が隔板の役割を果たす形状の場合
の、夫々の電解槽の縦断面図であり、第２図は第１図の
、第４図は第３図の、第６図は第５図の、第８図は第７
図の、第１０図は第９図の、第１２図は第１１図の第１
４図は第１３図のＡ−Ａゝ矢視図を示す。Figures 1, 3, and 5 show the case where the diaphragm is in the form of a flat plate.
Figure 7 shows the ninth case where the diaphragm is shaped to surround the anode.
Figure 11 shows the case where the partition plate is shaped to surround the cathode, Figure 11 shows the case where the partition plate is shaped to surround the anode and the electrolytic cell body is the cathode, and Figure 13 shows the case where the center part of the lid plate is U-shaped. FIG. 2 is a vertical cross-sectional view of each electrolytic cell in the case where the bent portion is bent to act as a partition plate, and FIG. 2 is the same as that in FIG. 1, FIG. 4 is the same as that in FIG. Figure 6 is Figure 5, Figure 8 is Figure 7.
Figure 10 is Figure 9, Figure 12 is Figure 11, Figure 1.
FIG. 4 shows a view taken along the line A-A in FIG. 13.
第１図及び第２図はフッ素系樹脂被膜１１が隔板１０の
陽極５に相対する面を覆っている図、第３図及び第４図
は逆に隔板１０の陰極６に相対する面を覆っている図、
第５図及び第６図は隔板１０の両面を覆っている図であ
り、何れも本発明の目的を達することが出来る。1 and 2 are views in which the fluororesin coating 11 covers the surface of the diaphragm 10 facing the anode 5, and FIGS. 3 and 4 conversely show the surface of the diaphragm 10 facing the cathode 6. A diagram covering the
5 and 6 are views covering both sides of the diaphragm 10, and both can achieve the object of the present invention.
第７図及び第８図は隔板１０が陽極５を取り巻く形で設
けられていてフッ素系樹脂被膜１１が該隔板１０の外側
面を覆っている図であり、第９回及び第１０図は隔板１
０が陰極６を取り巻く形で設けられていてフッ素系樹脂
被１ｕｌｌが該隔板１０の外側面を覆っている図であり
、また第１１図及び第１２図は隔板１０が陽極５を取り
巻く形で設けられていてフッ素系樹脂被膜１１が該隔板
１０の外側面を覆いかつ電解槽本体１が陰極６である場
合の図であるが、何れの場合も第１回〜第６図に示すと
同様な考え方で、隔板１０の内側面または両面を覆うこ
とでも本発明の目的を達することが出来る。7 and 8 are views in which the partition plate 10 is provided surrounding the anode 5 and the fluororesin coating 11 covers the outer surface of the partition plate 10; is partition plate 1
0 surrounds the cathode 6 and a fluororesin coating covers the outer surface of the partition plate 10, and FIGS. 11 and 12 show that the partition plate 10 surrounds the anode 5. This figure shows a case in which the fluororesin coating 11 covers the outer surface of the partition plate 10 and the electrolytic cell body 1 is the cathode 6. The object of the present invention can also be achieved by covering the inner surface or both sides of the partition plate 10 based on the same idea as shown.
尚、隔板１０の両面をフッ素系樹脂被膜１１で覆う場合
は隔板の腐蝕を完全に防止出来るので特に好ましい。It is particularly preferable to cover both sides of the partition plate 10 with the fluororesin coating 11 because corrosion of the partition plate can be completely prevented.
また、電解槽の蓋板３の中央部が下方にＵ字形に折曲っ
ていて該折曲り部が隔板の役割を果たす形状の場合は、
第１３図及び第１４図に示すように該折曲り部の外側面
（電極と相対する面）をフッ素系樹脂で被覆すれば良い
。第１３図及び第１４図は該折曲り部の陽極５に対する
面のみを被覆しているが、これも第１図〜第６図の場合
と同様に、陰極６に対する面または両面を被覆すること
も可能なことは勿論である。本発明の電解槽は、上記説
明の通り、隔板１０の少なくともその片面がフッ素系樹
脂被膜１１で覆われているものである。In addition, if the center part of the lid plate 3 of the electrolytic cell is bent downward into a U-shape and the bent part plays the role of a partition plate,
As shown in FIGS. 13 and 14, the outer surface of the bent portion (the surface facing the electrode) may be coated with a fluororesin. In FIGS. 13 and 14, only the surface of the bent portion facing the anode 5 is coated, but as in the case of FIGS. 1 to 6, the surface facing the cathode 6 or both surfaces may be coated. Of course, this is also possible. As explained above, in the electrolytic cell of the present invention, at least one side of the partition plate 10 is covered with a fluororesin coating 11.
この種の電解槽の中には、第１図〜第１４図に示す様に
、電解槽の底板部には底板の上にフッ素系樹脂板が設け
てあって、底板の腐蝕を防止する様になっているものも
ある。また、陽極５又は陰極６に接続されている接続棒
７ａ、７ｂは、蓋板３とは絶縁材８ａ、８ｂで絶縁され
ていて、更に接続棒７ａ。In this type of electrolytic cell, as shown in Figures 1 to 14, a fluororesin plate is provided on the bottom plate of the electrolytic cell to prevent corrosion of the bottom plate. There are some that are. Furthermore, the connecting rods 7a, 7b connected to the anode 5 or the cathode 6 are insulated from the cover plate 3 by insulating materials 8a, 8b, and the connecting rods 7a.
７ｂは、例えば、接続棒固定用袋ナラ） ９ａ、 ９ｂ
で蓋板３に間接的に固定されている。7b is, for example, a connecting rod fixing nut) 9a, 9b
It is indirectly fixed to the cover plate 3.
本発明の隔板の被覆に用いるフッ素系樹脂は、例えば、
ポリテトラフルオロエチレン、ポリクロロトリフルオロ
エチレン、ポリビニリデンフルオライド、ポリビニルフ
ルオライド、テトラフルオロエチレン−ヘキサフルオロ
プロピレン共重合体、テトラフルオロエチレン−エチレ
ン共重合体、テトラフルオロエチレン−パーフルオロア
ルキルビニルエーテル共重合体、クロロトリフルオロエ
チレン−エチレン共重合体等通常公知のものが何れも好
適に使用可能である。The fluororesin used for coating the partition plate of the present invention is, for example,
Polytetrafluoroethylene, polychlorotrifluoroethylene, polyvinylidene fluoride, polyvinyl fluoride, tetrafluoroethylene-hexafluoropropylene copolymer, tetrafluoroethylene-ethylene copolymer, tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer Any of the commonly known polymers such as chlorotrifluoroethylene-ethylene copolymer and chlorotrifluoroethylene-ethylene copolymer can be suitably used.
（作用及び発明の効果）
以上、詳細に説明したように、本発明の電解槽は、隔板
の少なくともその片面がフッ素系樹脂被膜で覆われてい
るので、従来問題であった隔板の複極化を完全に防止す
ることが出来、これによって溶融塩電解の際の陽極から
発生するＮＦ３ガスやＦ２ガス中にＨ２の混入を完全に
防止することが可能となった。勿論これによって爆発の
問題も完全に解消できるので、溶融塩溶解によるＮＦＩ
やＦ２の工業的製造が可能となり、その経済的効果は極
めて大である。また、隔板の両面をフッ素系樹脂被膜で
覆うことで隔板の腐蝕も完全に防止出来る点も大いに評
価される。(Function and Effects of the Invention) As explained above in detail, in the electrolytic cell of the present invention, at least one side of the partition plate is covered with a fluororesin coating, so Polarization can be completely prevented, and as a result, it has become possible to completely prevent H2 from being mixed into the NF3 gas and F2 gas generated from the anode during molten salt electrolysis. Of course, this completely eliminates the problem of explosions, so NFI caused by molten salt dissolution
It has become possible to industrially manufacture F2 and F2, and the economic effect is extremely large. Also, the fact that corrosion of the partition plate can be completely prevented by covering both sides of the partition plate with a fluororesin coating is highly praised.
第１図、第３図、第５図は隔板が平板上である場合の、
第７図は隔板が陽極を取り巻く形状である場合の、第９
図は隔板が陰極を取り巻く形状である場合の、第１１図
は隔板が陽極を取り巻く形状でありかつ電解槽本体が陰
極である場合の、第１３図は蓋板の中央部が下方にＵ字
形に折曲っていて該折曲り部が隔板の役割を果たす形状
の場合の、夫々の電解槽の縦断面図であり、第２図は第
１図の、第４図は第３図の、第６図は第５図の、第８図
は第７図の、第１０図は第９図の、第１２図は第１１図
の、第１４図は第１３図の、Ａ −Ａ”矢視図を示す。
図において、
１−ｍ−電解槽本体、２−ｍ−フッ素系樹脂板、３−−
一 蓋板、 ４−−一電解浴、５−ｍ−陽極、
６−−−陰極、？ａ、７ｂ−−− 接続棒、８ａ
、８ｂ−−一絶縁材、９ａ、９ｂ−−一 接続棒固定用
袋ナツト、１０−ｍ−隔板、 １１−一−フッ素系樹
脂被膜、１２−−一陽極発生ガス出口管、
１３−ｍ−陰極発生ガス出口管、
１４−−−バッキング、１５−−−ボルトナツト、を示
す。Figures 1, 3, and 5 show the case where the diaphragm is on a flat plate.
Figure 7 shows the ninth case where the diaphragm is shaped to surround the anode.
Figure 11 shows the case where the partition plate is shaped to surround the cathode, Figure 11 shows the case where the partition plate is shaped to surround the anode and the electrolytic cell body is the cathode, and Figure 13 shows the case where the center part of the lid plate is downward. FIG. 2 is a longitudinal cross-sectional view of each electrolytic cell in a U-shaped case where the bent portion serves as a partition plate, and FIG. 2 is the same as FIG. 1, and FIG. 4 is the same as FIG. , Fig. 6 is Fig. 5, Fig. 8 is Fig. 7, Fig. 10 is Fig. 9, Fig. 12 is Fig. 11, Fig. 14 is Fig. 13, A-A. "The arrow view is shown. In the figure, 1-m-electrolytic cell main body, 2-m-fluorine resin plate, 3--
1-cover plate, 4--electrolytic bath, 5-m-anode,
6---Cathode, ? a, 7b--- Connection rod, 8a
, 8b--1 insulation material, 9a, 9b--1 connection rod fixing cap nut, 10-m-diaphragm, 11-1-fluorine resin coating, 12--1 anode generated gas outlet pipe, 13-m -Cathode generated gas outlet pipe, 14--backing, 15--bolt nuts are shown.
Claims (1)
離するための隔板の少なくともその片面がフッ素系樹脂
被膜で覆われてなることを特徴とする改良された電解槽
。 ２）隔板の両面がフッ素系樹脂被膜で覆われてなる特許
請求の範囲第１項記載の改良された電解槽。[Claims] 1) An improved electrolytic cell characterized in that at least one side of a partition plate for separating gas generated from the anode and gas generated from the cathode is covered with a fluororesin coating. . 2) The improved electrolytic cell according to claim 1, wherein both sides of the partition plate are covered with a fluororesin coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61276794A JPH0757914B2 (en) | 1986-11-21 | 1986-11-21 | Improved electrolyzer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61276794A JPH0757914B2 (en) | 1986-11-21 | 1986-11-21 | Improved electrolyzer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS63130789A true JPS63130789A (en) | 1988-06-02 |
| JPH0757914B2 JPH0757914B2 (en) | 1995-06-21 |
Family
ID=17574467
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61276794A Expired - Lifetime JPH0757914B2 (en) | 1986-11-21 | 1986-11-21 | Improved electrolyzer |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0757914B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001077412A1 (en) | 2000-04-07 | 2001-10-18 | Toyo Tanso Co., Ltd. | Apparatus for generating fluorine gas |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5436152A (en) * | 1977-08-26 | 1979-03-16 | Nec Corp | Clock synchronization circuit between central processors |
| JPS58100688A (en) * | 1981-12-11 | 1983-06-15 | Asahi Glass Co Ltd | Electrolytic cell for generating fluorine |
| JPS60155502A (en) * | 1983-12-22 | 1985-08-15 | アライド・コーポレーシヨン | Fluorine electrolytic manufacture and novel electrolytic cell |
-
1986
- 1986-11-21 JP JP61276794A patent/JPH0757914B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5436152A (en) * | 1977-08-26 | 1979-03-16 | Nec Corp | Clock synchronization circuit between central processors |
| JPS58100688A (en) * | 1981-12-11 | 1983-06-15 | Asahi Glass Co Ltd | Electrolytic cell for generating fluorine |
| JPS60155502A (en) * | 1983-12-22 | 1985-08-15 | アライド・コーポレーシヨン | Fluorine electrolytic manufacture and novel electrolytic cell |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001077412A1 (en) | 2000-04-07 | 2001-10-18 | Toyo Tanso Co., Ltd. | Apparatus for generating fluorine gas |
| US6818105B2 (en) | 2000-04-07 | 2004-11-16 | Toyo Tanso Co., Ltd. | Apparatus for generating fluorine gas |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0757914B2 (en) | 1995-06-21 |
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| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |