JPS63116803A - Manufacture of colored decorative board - Google Patents
Manufacture of colored decorative boardInfo
- Publication number
- JPS63116803A JPS63116803A JP26441986A JP26441986A JPS63116803A JP S63116803 A JPS63116803 A JP S63116803A JP 26441986 A JP26441986 A JP 26441986A JP 26441986 A JP26441986 A JP 26441986A JP S63116803 A JPS63116803 A JP S63116803A
- Authority
- JP
- Japan
- Prior art keywords
- synthetic resin
- colored
- wood material
- decorative board
- conduit
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229920003002 synthetic resin Polymers 0.000 claims description 78
- 239000000057 synthetic resin Substances 0.000 claims description 78
- 239000000463 material Substances 0.000 claims description 41
- 239000002023 wood Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 10
- 239000003086 colorant Substances 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- 239000011120 plywood Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000009408 flooring Methods 0.000 description 3
- 238000010422 painting Methods 0.000 description 3
- 229920006305 unsaturated polyester Polymers 0.000 description 3
- KHOITXIGCFIULA-UHFFFAOYSA-N Alophen Chemical compound C1=CC(OC(=O)C)=CC=C1C(C=1N=CC=CC=1)C1=CC=C(OC(C)=O)C=C1 KHOITXIGCFIULA-UHFFFAOYSA-N 0.000 description 2
- -1 Benzene peroxide Chemical class 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000005002 finish coating Substances 0.000 description 2
- 239000011121 hardwood Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Abstract] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
〔技術分野〕
この発明は、床材、壁材、さらに土足用の床材、ヒータ
内蔵の木質形成床暖房フロア−の表層材、さらに耐熱床
材等に使用する着色化粧板の製造方法に関するものであ
る。[Detailed Description of the Invention] [Technical Field] The present invention relates to a coloring material for use in flooring materials, wall materials, flooring materials for footwear, surface materials of wooden floor heating floors with built-in heaters, and heat-resistant flooring materials. The present invention relates to a method for manufacturing a decorative board.
従来より木質材料を使用した化粧板は、木質材料に着色
合成樹脂を含浸硬化させて表面を美麗に化粧するととも
に、木質材料に高い寸法安定性、耐朽性、耐水性、耐熱
性、強度等を付与していた。Traditionally, decorative boards made of wood materials are made by impregnating the wood material with colored synthetic resin and curing it to create a beautiful surface, as well as providing the wood material with high dimensional stability, decay resistance, water resistance, heat resistance, strength, etc. It was granted.
しかしながら、かかる着色化粧板の製造方法には次のよ
うな欠点があった。However, this method of producing a colored decorative board has the following drawbacks.
fat 着色合成樹脂を貯えるタンクの数で生産でき
る着色化粧板の種類が制限され、また着色合成樹脂の貯
蔵に手間がかかった。The types of colored decorative boards that can be produced are limited by the number of tanks that store the colored synthetic resin, and it takes time and effort to store the colored synthetic resin.
(bl 着色合成樹脂の切換え時には減圧釜内や配管
等に残留した着色合成樹脂を充分に除去しておかなけれ
ば、次の着色時に色が混じるおそれがあった。(bl) When changing the colored synthetic resin, if the colored synthetic resin remaining in the vacuum pot, piping, etc. was not sufficiently removed, there was a risk of color mixing during the next coloring.
したがって、このような含浸による製造方法では、少量
多品種の生産が非常に困難であった。Therefore, with such a manufacturing method using impregnation, it is very difficult to produce a wide variety of products in small quantities.
この発明の目的は、多品種の着色化粧板の生産を可能に
した着色化粧板の製造方法を提供することである。An object of the present invention is to provide a method for manufacturing colored decorative laminates that enables the production of a wide variety of colored decorative laminates.
この発明の着色化粧板の製造方法は、木質材料に合成樹
脂を含浸させる工程と、前記木質材料を溶剤で洗浄して
木質材料の表面および導管内の合成樹脂を除去する工程
と、前記溶剤で洗浄した木質材料の導管内に着色合成樹
脂を充填する工程とを含むものである。The method for manufacturing a colored decorative board of the present invention includes a step of impregnating a wooden material with a synthetic resin, a step of cleaning the wood material with a solvent to remove the synthetic resin on the surface of the wood material and in the conduit, and a step of impregnating a wooden material with a synthetic resin, and a step of washing the wood material with a solvent to remove the synthetic resin on the surface of the wood material and in the conduit. This method includes the step of filling a colored synthetic resin into the conduit of the cleaned wood material.
このように、この発明によれば、木質材料に合成樹脂を
含浸させて木質材料の改質、すなわち寸法安定性、耐朽
性、耐水性、耐熱性、強度等の向上を図るとともに、木
質材料の表面や導管内の合成樹脂を溶剤により洗浄除去
し着色合成樹脂を前記導管内に充填するので、簡単に多
品種の着色化粧板を製造することができる。As described above, according to the present invention, a synthetic resin is impregnated into a wood material to improve the wood material, that is, to improve the dimensional stability, decay resistance, water resistance, heat resistance, strength, etc. of the wood material. Since the synthetic resin on the surface and inside the conduit is washed away with a solvent and the colored synthetic resin is filled into the conduit, it is possible to easily produce a wide variety of colored decorative boards.
この発明の方法を第1図に基づいて説明する。The method of this invention will be explained based on FIG.
第1図(A)は木質材料lに合成樹脂2を含浸させた状
態を示している0合成樹脂2としては、重合性のモノマ
ーやプレポリマー、たとえば不飽和ポリエステル等の重
合性樹脂があげられる。かかる合成樹脂の含浸方法とし
ては、常圧下で木質材料lを合成樹脂液内に浸漬する常
圧浸漬法のほか、減圧下で木質材料lを合成樹脂液に浸
漬し、ついで常圧または加圧下で浸漬する減圧常圧法ま
たは減圧加圧法などが採用可能である。これらの含浸操
作によって、合成樹脂2は木質材料1の内部に浸透する
ほか、木質材料1の全面を被覆しかつ導管3内に充填さ
れる。Figure 1 (A) shows a state in which a wooden material 1 is impregnated with a synthetic resin 2. Examples of the synthetic resin 2 include polymerizable monomers and prepolymers, such as polymerizable resins such as unsaturated polyester. . Methods for impregnating such synthetic resins include the normal pressure immersion method in which the wood material 1 is immersed in the synthetic resin liquid under normal pressure, and the immersion method in which the wood material 1 is immersed in the synthetic resin liquid under reduced pressure, and then immersed in the synthetic resin liquid under normal pressure or pressurization. It is possible to adopt a reduced pressure normal pressure method or a reduced pressure pressurization method in which the sample is immersed in water. By these impregnating operations, the synthetic resin 2 not only penetrates into the inside of the wood material 1 but also covers the entire surface of the wood material 1 and fills the inside of the conduit 3.
合成樹脂2を含浸後、木質材料1を溶剤で洗浄して、同
図(B)に示すように木質材料1の表面に付着した合成
樹脂および導管3内に充填された合成樹脂を除去する。After impregnating the synthetic resin 2, the wooden material 1 is washed with a solvent to remove the synthetic resin attached to the surface of the wooden material 1 and the synthetic resin filled in the conduit 3, as shown in FIG.
溶剤としては、合成樹脂2を溶解するものが使用され、
たとえばスチレン、アセトン、メチルエチルケトン等が
あげられる。As the solvent, one that dissolves the synthetic resin 2 is used,
Examples include styrene, acetone, methyl ethyl ketone, and the like.
溶剤による洗浄後、木質材料lを乾燥機中で加熱して硬
化、好ましくはセミ硬化させる。ついで、この木質材料
1の表面に着色合成樹脂4(クリヤーを含む)を塗布し
て、同図(C)に示すように導管3にこの着色合成樹脂
4を充填させ、この状態で着色合成樹脂4を完全硬化さ
せる。After cleaning with a solvent, the wood material 1 is heated in a dryer to harden, preferably semi-harden. Next, a colored synthetic resin 4 (including clear) is applied to the surface of this wood material 1, and the colored synthetic resin 4 is filled into the conduit 3 as shown in FIG. 4 is completely cured.
ついで1、同図(D)に示すように、木質材料1の表面
に付着した着色合成樹脂4をサンプ等により研摩して除
去し、表面塗装を施して仕上げる。1. As shown in FIG. 1D, the colored synthetic resin 4 adhering to the surface of the wood material 1 is removed by polishing with a sump or the like, and the surface is finished by painting.
このように構成したため、含浸処理する合成樹脂1がた
とえ着色されていないクリヤーなものであったとしても
、様々な色に着色した着色合成樹脂4を木質材料lに塗
布し導管3内に充填させることにより、様々な色に着色
された着色化粧板を簡単につくることができる。With this structure, even if the synthetic resin 1 to be impregnated is a clear, uncolored material, colored synthetic resins 4 colored in various colors can be applied to the wooden material 1 and filled into the conduit 3. By doing so, colored decorative boards colored in various colors can be easily produced.
この際、全ての導管3に着色合成樹脂4が充填されない
と木質材料1の表面に凹部が残り、表面塗装を施しても
凹部が残って目立つという問題がある場合は、着色合成
樹脂を塗布し硬化させる作業を複数回行うとよい。At this time, if all the conduits 3 are not filled with the colored synthetic resin 4, recesses will remain on the surface of the wood material 1, and if there is a problem that the recesses will remain and stand out even after surface painting, apply the colored synthetic resin. It is best to perform the curing process multiple times.
すなわち、前述のようにして合成樹脂2を木質材料1に
含浸させ、余分な合成樹脂2を溶剤で洗浄除去し、セミ
硬化させたのち、複数回にわたって着色合成樹脂4を塗
布(オーバーコート)シ硬化させて化粧板の表面を平滑
にするのである。その方法の一例を示すと以下のとおり
である。That is, the wooden material 1 is impregnated with the synthetic resin 2 as described above, the excess synthetic resin 2 is washed away with a solvent, and after semi-curing, the colored synthetic resin 4 is applied (overcoated) several times. It is cured to smooth the surface of the decorative board. An example of the method is as follows.
fal 合成樹脂のセミ硬化−着色合成樹脂の塗布−
熱圧プレス−着色合成樹脂の塗布−熱圧プレス−研磨−
仕上げ塗装
(bl 合成樹脂のセミ硬化−着色合成樹脂の塗布−
熱圧プレス−研摩→着色合成樹脂の塗布−熱圧プレス−
研磨−仕上げ塗装
(C1合成樹脂のセミ硬化−着色合成樹脂の塗布−セミ
硬化−着色合成樹脂の塗布−熱圧プレス−研磨−仕上げ
塗装
次に実施例をあげてこの発明の方法を詳細に説明する。fal Semi-curing of synthetic resin - Application of colored synthetic resin -
Hot press - Coating of colored synthetic resin - Hot press - Polishing -
Finish painting (bl Semi-curing of synthetic resin - Application of colored synthetic resin -
Hot Press - Polishing → Application of colored synthetic resin - Hot Press -
Polishing - Finish coating (Semi-curing of C1 synthetic resin - Application of colored synthetic resin - Semi-curing - Application of colored synthetic resin - Hot press - Polishing - Finish coating Next, the method of this invention will be explained in detail with reference to Examples. do.
実施例1: 木質材料として広葉樹のなら単板(厚さ0
.5 mm )を用い、これに常法に従って合成樹脂を
含浸させた。ついで、単板をスチレン浴中に30分間浸
漬して洗浄し、導管内に充填さた合成樹脂および表面に
付着した合成樹脂を除去した。Example 1: If the wood material is hardwood, veneer (thickness 0
.. 5 mm), and was impregnated with a synthetic resin according to a conventional method. Next, the veneer was washed by immersing it in a styrene bath for 30 minutes to remove the synthetic resin filled in the conduit and the synthetic resin adhering to the surface.
洗浄後、単板を100〜120℃の乾燥機中で10〜1
5分間加熱し、単板中の合成樹脂をセミ硬化させた。こ
のセミ硬化単板を接着剤が塗布された合板上に載置し、
さらに単板の上面にフローコータにより着色合成樹脂を
0.55〜0.73g/m”(6〜8g/尺2)で塗布
し、熱圧プレスを行い、合成樹脂を完全硬化させた。さ
らに、サンプにより表面を研磨し、仕上げ塗装して着色
化粧板を得た。After washing, place the veneer in a dryer at 100-120°C for 10-1
It was heated for 5 minutes to semi-cure the synthetic resin in the veneer. Place this semi-cured veneer on plywood coated with adhesive,
Furthermore, a colored synthetic resin was applied to the top surface of the veneer at 0.55 to 0.73 g/m'' (6 to 8 g/scale 2) using a flow coater, and heat-pressing was performed to completely cure the synthetic resin. Then, the surface was polished with a sump and a finish coat was applied to obtain a colored decorative board.
実施例2: なら単板を厚さ3.0鰭の合板に貼着した
ものに実施例1と同様に合成樹脂を含浸させ、スチレン
により洗浄した。これを60±10℃の乾燥機中で3時
間加熱し、合成樹脂をセミ硬化させた。ついで、単板の
表面に着色合成樹脂をロールコータで0.55〜0.7
3 g/m” (6〜8g/尺t)で塗布し、熱圧プ
レスを行い、合成樹脂を完全硬化させた。さらに、サン
プにより表面を研磨し、仕上げ塗装して着色化粧板を得
た。Example 2: A veneer was attached to a plywood board having a thickness of 3.0 fins and impregnated with a synthetic resin in the same manner as in Example 1, and then washed with styrene. This was heated in a dryer at 60±10° C. for 3 hours to semi-cure the synthetic resin. Next, the surface of the veneer is coated with a colored synthetic resin of 0.55 to 0.7 using a roll coater.
3 g/m" (6 to 8 g/t) and heat-pressed to completely cure the synthetic resin.Furthermore, the surface was polished with a sump and a final coat was applied to obtain a colored decorative board. .
実施例3: スチレンによる洗浄に代えてアセトン浴中
に30秒間浸漬して洗浄したほかは実施例1と同様にし
て着色化粧板を得た。Example 3: A colored decorative board was obtained in the same manner as in Example 1, except that washing was performed by immersing the board in an acetone bath for 30 seconds instead of washing with styrene.
参考例1 (化粧板の表面の平滑化): 広葉樹のなら
単板(厚さ0.50)に常法に従って合成樹脂を含浸さ
せた。この単板を110〜120℃の乾燥機中で10〜
15分間加熱し、合成樹脂をセミ硬化させた。ついで、
接着剤を塗布した合板上にこのセミ硬化単板を積載し、
この表面にフローコータにより着色合成樹脂を0.46
〜0.55g/m2 (5〜6g/尺りで塗布し、熱圧
プレスを行い、合成樹脂を完全硬化させた。さらに、再
度、同様にして着色合成樹脂を塗布し、熱圧ブレスで完
全硬化させた。その後、#150のサンドペーパーによ
り表面を研磨し、余分な合成樹脂を除去し、下塗り、上
塗りを行った。Reference Example 1 (Smoothing of surface of decorative board): A hardwood veneer (thickness: 0.50) was impregnated with a synthetic resin according to a conventional method. This veneer is placed in a dryer at 110-120°C for 10~
It was heated for 15 minutes to semi-cure the synthetic resin. Then,
This semi-hardened veneer is placed on top of plywood coated with adhesive,
Colored synthetic resin is applied to this surface using a flow coater.
〜0.55g/m2 (applied at 5 to 6g/measure and heat-pressed to completely cure the synthetic resin.Furthermore, colored synthetic resin was applied again in the same manner and completely cured with heat-pressure press. After that, the surface was polished with #150 sandpaper to remove excess synthetic resin, and an undercoat and topcoat were applied.
使用した着色合成樹脂液の配合は以下の通りである。The composition of the colored synthetic resin liquid used is as follows.
(成分) (重量部)不飽和ポリエス
テル 100スチレンモノマー
10ベンゼンペルオキシド 2
着色剤 1ここで、着色
剤は以下の組成を有するものを使用した。(Ingredients) (Parts by weight) Unsaturated polyester 100 Styrene monomer
10 Benzene peroxide 2
Colorant 1 Here, the colorant having the following composition was used.
(成分) (重量部)パーマネントブ
ラウン 100パーマネントブラツク
5また、前記各熱圧プレスは温度140℃、
圧力10〜12kg/c+s” 、時間3〜4分間の条
件で行った。(Ingredients) (Parts by weight) Permanent Brown 100 Permanent Black
5 In addition, each of the above-mentioned hot presses has a temperature of 140°C,
The test was carried out under conditions of a pressure of 10 to 12 kg/c+s'' and a time of 3 to 4 minutes.
参考例2: 参考例1と同様にして単板に合成樹脂を含
浸させ、セミ硬化後、着色合成樹脂を塗布し、熱圧プレ
スした。これを#150のサンドペーパーにより表面を
研磨したのち、再度、着色合成樹脂を塗布して熱圧プレ
スし、さらに研磨して表面塗装を行った。なお、着色合
成樹脂、熱圧ブレス条件は参考例1と同じである。Reference Example 2: A veneer was impregnated with a synthetic resin in the same manner as in Reference Example 1, and after semi-curing, a colored synthetic resin was applied and hot pressure pressed. After the surface of this was polished with #150 sandpaper, a colored synthetic resin was applied again, hot-press pressed, and the surface was further polished and painted. Note that the colored synthetic resin and the heat-pressing conditions are the same as in Reference Example 1.
参考例3: なら単板を厚さ3.0鶴の合板に貼着した
ものに常法に従って合成樹脂を含浸させた。Reference Example 3: A veneer was adhered to a 3.0 mm thick plywood board and impregnated with a synthetic resin according to a conventional method.
これを60±5℃の乾燥機中で5時間以上加熱し、合成
樹脂をセミ硬化させた。ついで、単板の表面に着色合成
樹脂をロールコータにより0.46〜0.55g/m”
(5〜6g/尺りで塗布(オーバーコート)シ、再
度、60±5℃の乾燥機中で2時間以上加熱し、合成樹
脂をセミ硬化させた。This was heated in a dryer at 60±5° C. for 5 hours or more to semi-cure the synthetic resin. Next, a colored synthetic resin is applied to the surface of the veneer using a roll coater at 0.46 to 0.55 g/m.
(Applyed (overcoated) at 5 to 6 g/measure) and heated again in a dryer at 60±5° C. for 2 hours or more to semi-cure the synthetic resin.
セミ硬化終了後、再度、着色合成樹脂を塗布(オーバー
コート)し、熱圧プレスし、硬化させた。After semi-curing, a colored synthetic resin was again applied (overcoated), hot-pressed, and cured.
その後、単板表面を研磨し、塗装した。The surface of the veneer was then polished and painted.
使用した着色合成樹脂の組成は以下の通りである。The composition of the colored synthetic resin used is as follows.
(成分) (重量部)不飽和ポリエス
テル 100スチレンモノマー
20ベンゼンペルオキシド 2
着色剤 5ここで、着色
剤は以下の組成を有するものを使用した。(Ingredients) (Parts by weight) Unsaturated polyester 100 Styrene monomer
20 Benzene peroxide 2
Colorant 5 Here, the colorant having the following composition was used.
(成分) (重量部)ビコールステイ
ンブラウン 100ビコールステインブラツク
3また、熱圧プレスは参考例1と同じ条件
で行った。(Ingredients) (Parts by weight) Bicol Stain Brown 100 Bicol Stain Black
3 In addition, hot press was performed under the same conditions as in Reference Example 1.
この発明によれば、木質材料に合成樹脂を含浸させて木
質材料の改質、すなわち寸法安定性、耐朽性、耐水性、
耐熱性、強度等の向上を図るとともに、木質材料の表面
や導管内の合成樹脂を溶剤により洗浄除去し着色合成樹
脂を前記風管内に充填するので、簡単に多品種の着色化
粧板を製造することができるという効果がある。According to this invention, the wooden material is impregnated with a synthetic resin to improve the dimensional stability, decay resistance, water resistance, etc.
In addition to improving heat resistance, strength, etc., the synthetic resin on the surface of the wood material and inside the conduit is washed away with a solvent, and the colored synthetic resin is filled into the wind conduit, so it is easy to manufacture a wide variety of colored decorative boards. It has the effect of being able to
第1図はこの発明の方法を示す工程説明図である。
1・・・木質材料、2・・・合成樹脂、3・・・導管、
4・・・着色合成樹脂
第1図
手続補正口(膀FIG. 1 is a process explanatory diagram showing the method of this invention. 1... Wooden material, 2... Synthetic resin, 3... Conduit,
4...Colored synthetic resin Figure 1 Procedure correction port (bladder)
Claims (1)
を溶剤で洗浄して木質材料の表面および導管内の合成樹
脂を除去する工程と、前記溶剤で洗浄した木質材料の導
管内に着色合成樹脂を充填する工程とを含む着色化粧板
の製造方法。a step of impregnating a wooden material with a synthetic resin; a step of washing the wood material with a solvent to remove the synthetic resin on the surface of the wood material and inside the conduit; and a step of impregnating the wooden material with a colored synthetic resin in the conduit after washing with the solvent. A method for manufacturing a colored decorative board, comprising the step of filling.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26441986A JPS63116803A (en) | 1986-11-05 | 1986-11-05 | Manufacture of colored decorative board |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP26441986A JPS63116803A (en) | 1986-11-05 | 1986-11-05 | Manufacture of colored decorative board |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63116803A true JPS63116803A (en) | 1988-05-21 |
Family
ID=17402910
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP26441986A Pending JPS63116803A (en) | 1986-11-05 | 1986-11-05 | Manufacture of colored decorative board |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63116803A (en) |
-
1986
- 1986-11-05 JP JP26441986A patent/JPS63116803A/en active Pending
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