JPS63107717A - Filter medium - Google Patents
Filter mediumInfo
- Publication number
- JPS63107717A JPS63107717A JP25305686A JP25305686A JPS63107717A JP S63107717 A JPS63107717 A JP S63107717A JP 25305686 A JP25305686 A JP 25305686A JP 25305686 A JP25305686 A JP 25305686A JP S63107717 A JPS63107717 A JP S63107717A
- Authority
- JP
- Japan
- Prior art keywords
- filter medium
- sepiolite
- zeolite
- filter
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 claims abstract description 28
- 238000001179 sorption measurement Methods 0.000 claims abstract description 10
- 239000004113 Sepiolite Substances 0.000 claims abstract description 9
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 9
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 9
- 239000010457 zeolite Substances 0.000 claims abstract description 9
- 241000209094 Oryza Species 0.000 claims description 8
- 235000007164 Oryza sativa Nutrition 0.000 claims description 8
- 235000009566 rice Nutrition 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 3
- 239000013078 crystal Substances 0.000 claims description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
- 239000011707 mineral Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 32
- 238000001914 filtration Methods 0.000 abstract description 16
- 230000000694 effects Effects 0.000 abstract description 6
- 239000011148 porous material Substances 0.000 abstract description 5
- 230000005484 gravity Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 239000004568 cement Substances 0.000 abstract description 2
- 239000004927 clay Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000002956 ash Substances 0.000 abstract 3
- 235000019738 Limestone Nutrition 0.000 abstract 1
- 239000006028 limestone Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 5
- 239000010903 husk Substances 0.000 description 5
- 231100000719 pollutant Toxicity 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 241000894006 Bacteria Species 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 241000251468 Actinopterygii Species 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 235000015170 shellfish Nutrition 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000008400 supply water Substances 0.000 description 1
- 230000009182 swimming Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
各種の貯水施設のうち、例えば水泳用プール等の場合に
は人体からの垢や病原菌等によって水質が汚染され、更
にこれを殺菌処理するために散布した塩素ガス等の余剰
遊離塩素が人体に好ましくないので、その水質を浄化さ
せる必要がある。また、水族館や養魚池等の場合には魚
介類の排泄物や餌料の残滓等によって水質が汚染され、
更にこれらが腐敗して有毒ガスを発生すると魚介類の成
育に好ましくないので、その水質を浄化させる必要があ
る。そこで本発明は、これらの貯水施設の水質を浄化さ
せるためのろ過装置に用いるろ過材に関するものである
。[Detailed Description of the Invention] (Industrial Application Field) Among various water storage facilities, for example, in the case of swimming pools, the water quality is contaminated with dirt and pathogenic bacteria from human bodies, and it is necessary to sterilize the water. Excess free chlorine such as chlorine gas sprayed on water is not good for the human body, so it is necessary to purify the water quality. In addition, in the case of aquariums and fish ponds, the water quality is contaminated by fish and shellfish excrement and feed residue, etc.
Furthermore, if these decompose and produce toxic gases, it is not favorable for the growth of seafood, so it is necessary to purify the water quality. Therefore, the present invention relates to a filter material used in a filtration device for purifying the water quality of these water storage facilities.
(従来の技術)
前記した貯水施設の水質を浄化させる手段としては、例
えば活性炭等のろ過材を充填したカートリッジ式のろ過
装置を貯水tM股の給水口および廃水口に設けたり、一
定期間毎に貯水II全全体水を取り替えたり、貯水中に
化学物質による殺菌剤や浄化剤を散布すること等が行な
われていた。(Prior Art) As means for purifying the water quality of the water storage facility described above, for example, a cartridge-type filtration device filled with a filter material such as activated carbon is installed at the water supply and waste water ports of the water storage tM, and Water storage II The entire water was replaced, and chemical disinfectants and purification agents were sprayed into the storage water.
(発明が解決しようとする問題点)
しかしながら、これらの水質浄化手段において、前記活
性炭によるろ過材では細菌等を含む各種の汚染物質に対
する浄化が不十分であり、また貯水の取り替え作業は資
源および労力の上で負担が大きく、更に化学物質による
殺菌や浄化は安全性の上で各種の制約を受ける等の問題
点があった。(Problems to be Solved by the Invention) However, in these water purification means, the activated carbon filtration medium is insufficient in purifying various pollutants including bacteria, and replacing the stored water requires resources and labor. In addition, sterilization and purification using chemical substances are subject to various safety restrictions.
そこで、本発明では浄化作用に優れ、簡単且つ安全に使
用できるろ過材の提供を目的とするものである。Therefore, an object of the present invention is to provide a filter medium that has excellent purification effect and is easy and safe to use.
(実施例) 以下に本発明の実施例を図面により説明する。(Example) Embodiments of the present invention will be described below with reference to the drawings.
浄化材の主成分となるモミガラ灰は多孔質構造の硅化物
であり、吸着効果のある活性シリカを主成分とすると共
に、粉砕の程度によって0.2〜2゜0の範囲に分布す
る比重を備えている。また、浄化材の吸着補助材の一つ
として使用するゼオライト(沸石)は、天然あるいは合
成による多孔質の鉱物結晶体であって、主としてアンモ
ニアガスや窒素ガス等の気体に対する吸着効果を有し、
一般的には比重が2.0〜2.4である。また、他の吸
着補助材として使用するセピオライト(海泡石)は、前
記ゼオライトより更に微細な多孔質構造による鉱物結晶
体であって、前記アンモニアガスや窒素ガス等の気体は
もちろん、細菌に対する吸着効果をも有するものである
。Rice husk ash, which is the main component of the purification material, is a porous silicide and contains activated silica, which has an adsorption effect, as its main component, and has a specific gravity that ranges from 0.2 to 2.0 degrees depending on the degree of pulverization. We are prepared. In addition, zeolite, which is used as an adsorption aid for purification materials, is a natural or synthetic porous mineral crystal that has an adsorption effect mainly on gases such as ammonia gas and nitrogen gas.
Generally, the specific gravity is 2.0 to 2.4. In addition, sepiolite (seiolite), which is used as another adsorption auxiliary material, is a mineral crystal with a porous structure that is even finer than the zeolite, and it adsorbs not only gases such as ammonia gas and nitrogen gas but also bacteria. It also has some effects.
前記したモミガラ灰に、粉状又は粒状化させたゼオライ
トとセピオライトの少なくともいずれか一方を、少なく
とも5%以上で望ましくは10〜30%の比率で配合し
、これに粘土、セメント、石灰等のうちから選ばれた少
量の結着材を添加する。これらは混合され、また使用さ
れる結着材の 。At least one of powdered or granulated zeolite and sepiolite is blended into the above-mentioned rice husk ash in a ratio of at least 5% or more, preferably 10 to 30%, and added with clay, cement, lime, etc. Add a small amount of a binder selected from These are mixed and also used as a binder.
性状やろ過材の用途によっては焼結させ、比重が1.0
〜2.0に調整すると共に、粒度が数mm−数10mm
の粒状体あるいは所望の厚みを有する板状体にしてろ過
材を成形させる。このろ過材1は、第1図で示すように
多数の気孔2を有する多孔質構造を有し、主成分である
モミガラ灰は、その気孔中に貯えていた空気を除々に放
出しながら水中に酸素を供給すると共に、当該モミガラ
灰が含有する活性シリカの吸着力によって比較的大きな
水中の汚染粒子を、放出した空気と入れ換りに気孔2中
に取り込んで水質の浄化を計る。また、ろ過材1に配合
されているゼオライトやセピオライトによる吸着補助材
は、前記モミガラ灰では吸着しにくいアンモニアや窒素
あるいは塩素ガス等の有害ガスを効果的に吸着し、前記
モミガラ灰と協働して水質の浄化を促進すると共に、特
に微細な多孔質構造を有するセピオライトは細菌をも吸
着拘束して除去しうるちのである。Depending on the properties and purpose of the filter material, it may be sintered to have a specific gravity of 1.0.
~2.0, and the particle size is several mm to several tens of mm.
The filter material is formed into a granular material or a plate-like material having a desired thickness. As shown in Fig. 1, this filter material 1 has a porous structure with a large number of pores 2, and rice hull ash, which is the main component, gradually releases the air stored in the pores while being absorbed into the water. In addition to supplying oxygen, the adsorption power of the activated silica contained in the rice husk ash takes relatively large pollutant particles in the water into the pores 2 to replace the released air, thereby purifying the water quality. In addition, the adsorption aids such as zeolite and sepiolite contained in the filter material 1 effectively adsorb harmful gases such as ammonia, nitrogen, or chlorine gas that are difficult to adsorb with the rice husk ash, and work together with the rice husk ash. In addition to promoting water purification, sepiolite, which has a particularly fine porous structure, can also absorb and remove bacteria.
次に、第2乃至第4図は前記したろ過材をろ過装置に使
用した実施例であり、第2図および第3図の実施例は、
回流形式の貯水施設の給水口や排水口に取付けられるカ
ートリッジ式のろ過装置に適用したものである。円筒状
で矢視の如く流路の前後端部にろ布あるいは金網等によ
る透通材3を張設したろ過バック4内は、前記した粒状
のろ過材5を充填すると共に、当該ろ過バック4内の一
方端部側に円板状のろ過材6を挿着させている。Next, Figures 2 to 4 show examples in which the above-described filter media are used in a filter device, and the examples shown in Figures 2 and 3 are as follows:
It is applied to a cartridge-type filtration device that is installed at the water inlet or outlet of a recirculation type water storage facility. The inside of the filtration bag 4, which is cylindrical and has a transparent material 3 such as filter cloth or wire mesh stretched at the front and rear ends of the flow path as shown by the arrow, is filled with the granular filter material 5 described above, and the filter bag 4 is A disk-shaped filter material 6 is inserted into one end of the filter.
これによって、前記ろ過材のもつ優れた浄化作用による
ろ過装置が得られる。As a result, a filtration device can be obtained that utilizes the excellent purifying action of the filter medium.
また第4図の実施例は、貯水施設の水底7と水中8に各
々ろ過装置9,10を設置したものである。水底7に設
置されたろ過装置9は、ろ布や金網あるいは無数の透孔
を備えたプラスチックシート等によってケーシング11
が形成され、該ケーシング内に前記した粒状のろ過材1
2を充填させたものである。一方、水中8に設置された
ろ過装置10は、前記と同様のケーシング13を有し、
該ケーシング13内には方形板状のろ過材14が収容さ
れており、当該ろ過装置10は上端に緊着された浮具1
5によって浮遊されると共に、下端に緊着された錘16
によって直立状に安定されている。また前記したろ過装
置9は、沈澱した堆積汚染物質17に対して酸素を供給
すると共に、ヘドロ状の微粒子や有害ガスあるいは細菌
等を吸着する。更に前記したろ過装置10は、水中8に
浮遊する汚染物質に対しても前記同様の作用によって水
質の改善と浄化を計ることができるものであり、所定期
間使用された後は新しいものと交換して使用する。In the embodiment shown in FIG. 4, filtration devices 9 and 10 are installed at the bottom 7 and underwater 8 of the water storage facility, respectively. A filtration device 9 installed at the bottom of the water 7 has a casing 11 made of a filter cloth, a wire mesh, a plastic sheet with numerous through holes, etc.
is formed, and the above-mentioned granular filter material 1 is formed in the casing.
2 is filled. On the other hand, the filtration device 10 installed in the water 8 has a casing 13 similar to the above,
A rectangular plate-shaped filter medium 14 is accommodated in the casing 13, and the filter device 10 has a floating device 1 tightly attached to the upper end thereof.
A weight 16 is floated by 5 and is tightly attached to the lower end.
It is stabilized in an upright position by Further, the above-described filtering device 9 supplies oxygen to the precipitated contaminant 17, and also adsorbs sludge-like fine particles, harmful gases, bacteria, and the like. Furthermore, the above-described filtration device 10 can improve and purify the water quality by the same action as described above for pollutants floating in the water 8, and after being used for a predetermined period of time, it can be replaced with a new one. and use it.
尚、前記したろ過材は淡水はもちろんのこと、塩分濃度
の高い海水に対しても有効である。Incidentally, the above-mentioned filter medium is effective not only for freshwater but also for seawater with a high salt concentration.
(発明の効果)
前記した実施例でも明らかなとおり、本発明によるろ過
材は、主成分であるモラガラ灰と、ゼオ −ライ
トあるいはセピオライトによる吸着補助材とが協働し、
各種の汚染物質による水質を改善して浄化させることが
可能であると共に、当該ろ過材は化学物質ではないので
、長期使用されても水質に悪影響を与える恐れもない。(Effects of the Invention) As is clear from the examples described above, in the filter medium according to the present invention, mora ash, which is the main component, and an adsorption auxiliary material made of zeolite or sepiolite work together,
It is possible to improve and purify water quality caused by various pollutants, and since the filter medium is not a chemical substance, there is no risk of adversely affecting water quality even if it is used for a long period of time.
図面は本発明の実施例を示し、第1図はろ過材の構造を
示す正面図、第2図は同ろ過材を使用したカートリッジ
式のろ過バックの正面図、第3図は同縦断面図、第4図
は同ろ過材を使用した他のろ過装置の実施例図である。
[符号の説明]
1・・・ろ過材 2・・・気孔3・・・透通
材 4・・・ろ過バック5.12・・・粒状
ろ過材 6・・・円板状ろ過材7・・・水底
8・・・水中9.10・・・ろ過装置 11.1
3・・・ケーシング14・・・方形板状ろ過材 15・
・・浮具16・・・錘 17・・・堆積汚
染物質N曽The drawings show embodiments of the present invention, with Fig. 1 being a front view showing the structure of the filter material, Fig. 2 being a front view of a cartridge type filtration bag using the same filter material, and Fig. 3 being a longitudinal sectional view of the same. , FIG. 4 is an example diagram of another filtration device using the same filter material. [Explanation of symbols] 1... Filter material 2... Pore 3... Permeable material 4... Filtration bag 5.12... Granular filter material 6... Disc-shaped filter material 7...・Underwater
8... Underwater 9.10... Filtration device 11.1
3...Casing 14...Square plate filter material 15.
...Floating device 16... Weight 17... Accumulated pollutant Nso
Claims (1)
結晶体であるゼオライトとセピオライトの両方又は何れ
か一方を吸着補助材として配合すると共に、これらに結
着材を添加して粒状あるいは板状に成形して成るろ過材
。Rice hull ash is the main component, and porous mineral crystals such as zeolite and/or sepiolite are blended into the rice hull ash as adsorption aids, and a binder is added to these to form particles or plates. A filter material made by molding.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25305686A JPS63107717A (en) | 1986-10-24 | 1986-10-24 | Filter medium |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25305686A JPS63107717A (en) | 1986-10-24 | 1986-10-24 | Filter medium |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63107717A true JPS63107717A (en) | 1988-05-12 |
Family
ID=17245869
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25305686A Pending JPS63107717A (en) | 1986-10-24 | 1986-10-24 | Filter medium |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63107717A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04256490A (en) * | 1990-12-26 | 1992-09-11 | Hiroyoshi Machii | Water purifying device |
JPH08218403A (en) * | 1995-02-20 | 1996-08-27 | Yukihiro Funai | Block for purified water for vegetation and foundation bed material for purified water for vegetation and greening method for civil engineering structure in which the block for purified water for vegetation is used and water purification method in river |
WO2010023740A1 (en) * | 2008-08-28 | 2010-03-04 | Tanabe Seisuke | Method of desalinating seawater |
JP2010234190A (en) * | 2009-03-30 | 2010-10-21 | Kobelco Eco-Solutions Co Ltd | Retainer for bag filter |
JP2015124564A (en) * | 2013-12-27 | 2015-07-06 | 前田建設工業株式会社 | Wall structure for preventing contaminant diffusion using zeolite-based concrete panel |
CN109529453A (en) * | 2018-11-07 | 2019-03-29 | 福建滤冠新型材料科技有限公司 | A kind of carbon nano-particle diaphragm |
JP2020048447A (en) * | 2018-09-26 | 2020-04-02 | 信濃建設株式会社 | Water quality purification agent for aquarium fish |
-
1986
- 1986-10-24 JP JP25305686A patent/JPS63107717A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04256490A (en) * | 1990-12-26 | 1992-09-11 | Hiroyoshi Machii | Water purifying device |
JPH08218403A (en) * | 1995-02-20 | 1996-08-27 | Yukihiro Funai | Block for purified water for vegetation and foundation bed material for purified water for vegetation and greening method for civil engineering structure in which the block for purified water for vegetation is used and water purification method in river |
WO2010023740A1 (en) * | 2008-08-28 | 2010-03-04 | Tanabe Seisuke | Method of desalinating seawater |
JP2010234190A (en) * | 2009-03-30 | 2010-10-21 | Kobelco Eco-Solutions Co Ltd | Retainer for bag filter |
JP2015124564A (en) * | 2013-12-27 | 2015-07-06 | 前田建設工業株式会社 | Wall structure for preventing contaminant diffusion using zeolite-based concrete panel |
JP2020048447A (en) * | 2018-09-26 | 2020-04-02 | 信濃建設株式会社 | Water quality purification agent for aquarium fish |
CN109529453A (en) * | 2018-11-07 | 2019-03-29 | 福建滤冠新型材料科技有限公司 | A kind of carbon nano-particle diaphragm |
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