JPS63105468A - Manufacture of nickel hydroxide electrode for alkaline storage battery - Google Patents
Manufacture of nickel hydroxide electrode for alkaline storage batteryInfo
- Publication number
- JPS63105468A JPS63105468A JP61249115A JP24911586A JPS63105468A JP S63105468 A JPS63105468 A JP S63105468A JP 61249115 A JP61249115 A JP 61249115A JP 24911586 A JP24911586 A JP 24911586A JP S63105468 A JPS63105468 A JP S63105468A
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- solution
- substrate
- nickel nitrate
- nickel hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title claims abstract description 16
- 238000003860 storage Methods 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 40
- 239000000758 substrate Substances 0.000 claims abstract description 23
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 19
- 239000007864 aqueous solution Substances 0.000 claims abstract description 16
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 7
- 238000001035 drying Methods 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- 239000003513 alkali Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 abstract description 19
- 230000007797 corrosion Effects 0.000 abstract description 8
- 238000005260 corrosion Methods 0.000 abstract description 8
- 230000005484 gravity Effects 0.000 abstract description 4
- 238000005470 impregnation Methods 0.000 abstract description 3
- 239000012670 alkaline solution Substances 0.000 abstract description 2
- 239000011149 active material Substances 0.000 description 10
- 238000000034 method Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- GPZPVAIBXPRLFD-UHFFFAOYSA-N acetic acid;azane Chemical compound N.N.CC(O)=O GPZPVAIBXPRLFD-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical compound N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000005695 Ammonium acetate Substances 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229940043376 ammonium acetate Drugs 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001493 electron microscopy Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- AOPCKOPZYFFEDA-UHFFFAOYSA-N nickel(2+);dinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O AOPCKOPZYFFEDA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/26—Processes of manufacture
- H01M4/28—Precipitating active material on the carrier
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）所業上の利用分野
この発明はアルカリ蓄電池用水重化ニッケル１（ｉ！Ｉ
＠（以下水＋ｉ＋化ニッケル電極と呼称する）の製法に
関する。DETAILED DESCRIPTION OF THE INVENTION (a) Field of industrial application This invention is directed to water-heavy nickel 1 (i!I) for alkaline storage batteries.
(hereinafter referred to as water+i+ nickel electrode).
（ロ）従来の技術と問題点
従来、水酸化ニッケル電極は、多孔性ニッケル基板例え
ば焼結式多孔性ニッケル基板を硝酸ニッケル水溶液の含
浸液中に浸漬後、アルカリ水溶液中で硝酸ニッケルを水
酸化物に変換して活物質化する工程を繰返して所要量の
活物質をブｄ塙して製造されている。そして上記工程の
１サイクｓａＤの活物′α光填計を増加させて含浸回教
を減少させるために含浸液として、硝酸ニッケル６水塩
の著：しく高濃度の水溶液を用い、その粘度を低下させ
るため６０℃以上の高温にして浸漬する方法が広く行わ
れている。しかしながら、この方法は宮浸散の硝酸ニッ
ケル水溶液中の遊離硝酸濃度が高くなり、しかも高ｌＦ
Ａであるためニッケル基板の腐蝕かおこり、極板の強度
や電極性能の低下を起こしていた。したがってこの、腐
蝕を抑制するためをこニッケル基板表面に酸化ニッケル
の皮膜を形成させる方法Ｃ特開昭５９−７８４５７号、
特開昭５９−９６６５９号など）があるがその効果は十
分なものではない。(b) Conventional technology and problems Conventionally, nickel hydroxide electrodes are produced by immersing a porous nickel substrate, such as a sintered porous nickel substrate, in an impregnating solution of an aqueous nickel nitrate solution, and then hydrating the nickel nitrate in an aqueous alkaline solution. It is manufactured by repeating the process of converting it into active material and producing the required amount of active material. In order to increase the active material 'α optical filler of one cycle saD in the above process and reduce the impregnation, a very highly concentrated aqueous solution of nickel nitrate hexahydrate is used as the impregnating liquid, and its viscosity is reduced. In order to do this, a method of immersion at a high temperature of 60° C. or higher is widely used. However, this method results in a high concentration of free nitric acid in the aqueous nickel nitrate solution and a high lF concentration.
A, the nickel substrate was corroded and the strength of the electrode plate and electrode performance were reduced. Therefore, in order to suppress this corrosion, a method of forming a nickel oxide film on the surface of a nickel substrate is disclosed in Japanese Patent Application Laid-Open No. 59-78457.
(Japanese Unexamined Patent Publication No. 59-96659, etc.), but their effects are not sufficient.
この発明は上記問題点を改善するためになされたもので
ある。This invention has been made to improve the above problems.
（／ｉ 問題点を解決するための手段と作用一般に、
金属ニッケルや水酸化ニッケルを、高温、高温度の酸性
硝酸ニッケル水溶液に浸漬すると、遊離の硝酸が消費さ
れるまで溶解して水溶液のｐＩＩは上昇する。しかしこ
の発明の発明者はこの現象を詳細に研究した結果次のよ
うな現象を見出した。(/i In general, means and actions for solving problems,
When metallic nickel or nickel hydroxide is immersed in a high-temperature acidic nickel nitrate aqueous solution, free nitric acid is dissolved until it is consumed, and the pII of the aqueous solution increases. However, as a result of detailed research into this phenomenon, the inventor of the present invention discovered the following phenomenon.
すなわち、上記水溶液のｐＨを１〜２に調整しておくと
高温にしても前記溶解現象は大きく進行せず逆に沈澱が
生じ、この沈澱をＸ光回折分析に付したところ、Ｎ１２
（ＯＨ）２（ＮＯ３）２・２Ｈ２０であることが分かり
、しかも、この生成物は６０℃以上の高温瘉こおいても
ＰＨが１以上であれば非常に安定であることが見出され
たのである。That is, when the pH of the aqueous solution is adjusted to 1 to 2, the dissolution phenomenon does not proceed significantly even at high temperatures, and on the contrary, a precipitate is formed.When this precipitate was subjected to X-ray diffraction analysis, it was found that N12
(OH)2(NO3)2.2H20, and it was also found that this product is very stable even at high temperatures of 60℃ or higher as long as the pH is 1 or higher. It is.
この発明は、上記の知見に基づいてなされたもさせ、洗
浄乾燥する工程を繰返して、所要量の水酸化ニッケルを
前記ニッケル基板に充填するアルカリ蓄電池用水酸化ニ
ッケル電極の製法において、前記硝酸ニッケル水溶液の
温度が約６０〜１００℃で、ＰＨが約１〜２であること
を特徴とするアルカリ蓄電池用水酸化ニッケル電極の製
法を提供するものである。The present invention was made based on the above findings, and includes a method for manufacturing a nickel hydroxide electrode for an alkaline storage battery, in which the nickel hydroxide electrode is filled into the nickel substrate in a required amount by repeating the washing and drying process. The present invention provides a method for producing a nickel hydroxide electrode for an alkaline storage battery, characterized in that the temperature is about 60 to 100°C and the pH is about 1 to 2.
この発明に用いられる多孔性ニッケル基板としては、通
常アルカリ蓄電池の電極用に利用されているものでよく
、例えば、カーボニルニッケル粉末に、水、メチルセル
ロースなどの結合剤、および増孔剤などからなるスラリ
ーをニッケルメッキ鋼板などの両面に塗布して乾燥し還
元性雰囲気下で焼結して製造するものなどがあげられる
。The porous nickel substrate used in this invention may be one that is normally used for electrodes of alkaline storage batteries, such as a slurry consisting of carbonyl nickel powder, water, a binder such as methylcellulose, and a pore-forming agent. Examples include those manufactured by coating both sides of a nickel-plated steel plate, drying, and sintering in a reducing atmosphere.
この発明において、硝酸ニッケル水溶液としては比重が
約１．７〜１．８程度の高湿度のものが適切である。そ
して含浸は約６０〜１００℃でかつｐＨは約１〜２で行
われる。In this invention, a high humidity solution having a specific gravity of approximately 1.7 to 1.8 is suitable as the nickel nitrate aqueous solution. The impregnation is then carried out at a temperature of about 60-100°C and a pH of about 1-2.
含浸液の温度は約６０℃以上でないと粘度が高く、また
１００℃を超えると含浸液の蒸発量が多く、ＰＨの調整
が［０１である。またｐＨは約１〜２の範囲以外では、
極板のニッケルおよび活物質の水酸化ニッケルの硝酸ニ
ッケル水溶液の含浸液への溶出液が急激に上昇するので
好ましくない。If the temperature of the impregnating liquid is not about 60°C or higher, the viscosity will be high, and if it exceeds 100°C, the amount of evaporation of the impregnating liquid will be large, and the pH will be adjusted to [01]. In addition, outside the pH range of about 1 to 2,
This is not preferable because the elution of nickel from the electrode plate and nickel hydroxide from the active material into the impregnating solution of the nickel nitrate aqueous solution rises rapidly.
これは含浸液のｐＨを１〜２に調整しておくと、極板の
表面にＮ１２（ＯＨ）２（Ｎ０８）２・２Ｈ２０の皮膜
が形成され含浸液に対して不働態化して耐腐蝕性を示す
ものと考えられる。This is because when the pH of the impregnating liquid is adjusted to 1 to 2, a film of N12(OH)2(N08)2.2H20 is formed on the surface of the electrode plate, which becomes passivated to the impregnating liquid and becomes corrosion resistant. This is considered to indicate that
また含浸液のＰＨの調整には通常の酸とアルカリで行う
ことができるが、液濃度などの含浸液の管理を容易に行
うために、ＰＨの調整は硝酸と水酸化ニッケルとを添加
することによって行うのが好ましい。In addition, the pH of the impregnating solution can be adjusted using ordinary acids and alkalis, but in order to easily manage the impregnating solution, such as the concentration of the solution, the pH can be adjusted by adding nitric acid and nickel hydroxide. It is preferable to carry out by.
に））実施例
この発明を実施例によって説明するがこの発明を限定す
るものではない。B)) Examples This invention will be explained by examples, but the invention is not limited thereto.
多孔度約８５％の焼結式ニッケル基板を、比重が１．７
５の硝酸ニッケル水溶液を約８０℃に昇温し、硝酸を添
加してそのｐＨを１〜２に調整したものに浸漬し、次い
でこれを常温の水ｉＷ イＦ、ｌｙ ！Ｊウム水溶液に
浸漬して基板中の硝酸ニッケルを水ｔｅ化物に変換して
活物質化し、次いで水洗乾燥する工程を６回繰返して！
４４（Ａｌを製作した。次に上記含浸液のｐＥ［を０〜
１と２〜８とに調整すること以外、前記電極（４）と同
様にして、電極（Ｂ）と（Ｃ）をそれぞれ作製した。こ
のようにして作製した電極（Ａ）、（Ｂ）および（Ｑを
酢酸アンモニウム−アンモニア水溶液中１６時間浸漬し
て活物質を抽出した後の基板表面の粒子形状を表わす定
食型″１に子顕微鏡写真（Ｘ２５００）を第１ａ〜ＩＣ
図に示した。これらの写真からみて電極（４）は電極（
Ｂ）と（Ｃ）と比べて孔蝕などの腐蝕が抑制されている
ことは明らかであり、電極（４）の強度低下などによる
電（仇性能の低下は最も少ないと考えられる。A sintered nickel substrate with a porosity of approximately 85% and a specific gravity of 1.7.
The aqueous nickel nitrate solution of No. 5 was heated to about 80°C and immersed in the solution, the pH of which was adjusted to 1 to 2 by adding nitric acid, and then immersed in water at room temperature. The process of immersing the substrate in an aqueous Jium solution to convert the nickel nitrate in the substrate into telphide hydrate to form an active material, then washing and drying with water was repeated six times!
44 (Al) was produced. Next, the pE of the impregnating solution was adjusted to 0 to
Electrodes (B) and (C) were prepared in the same manner as electrode (4) except that the electrodes were adjusted to 1 and 2 to 8, respectively. Electrodes (A), (B), and (Q) prepared in this way are immersed in an ammonium acetate-ammonia aqueous solution for 16 hours to extract the active material. Photo (X2500) from 1a to IC
Shown in the figure. From these photos, electrode (4) is electrode (
It is clear that corrosion such as pitting is suppressed compared to B) and (C), and it is thought that the deterioration in electrical performance due to a decrease in the strength of the electrode (4) is the least.
また比重１．７５の硝ｒｔＪニッケル水溶液を８０″Ｃ
に保持し、そのｐＨを硝酸もしくは水酸化ニッケルを添
加することによってθ〜３の櫨々のｐＨ値に保持し、こ
れに多孔度約８５％の焼結式ニッケル基板（ａｊｉｌ
）を６０分浸漬後直ちに水洗乾燥した後、重量を測定し
くｂｆ）、次いでこれを酢酸アンモニウム−アンモニア
水溶液中に１６時１汗１浸潰して活物質を抽出後、水洗
乾燥した後に重量（を測定した（ ｃ９ ）。上記の重
量測定値から、下記の１（改を算出した。In addition, a nitric rtJ nickel aqueous solution with a specific gravity of 1.75 was heated at 80"C.
By adding nitric acid or nickel hydroxide, the pH is maintained at a constant pH value of θ~3, and a sintered nickel substrate (ajil
) was immersed for 60 minutes, immediately washed with water and dried, then weighed bf), then soaked in an ammonium acetate-ammonia aqueous solution at 16:1 per sweat to extract the active material, washed with water and dried, and then weighed (bf). It was measured (c9). From the above weight measurement value, the following 1 (change) was calculated.
上記活物・詮充填中、含浸液に溶解し
た基板のニッケルの６分率
（溶解ニッケルｕ分率：α）
＝（ａ−Ｃ）／ａＸ１００％
上記方法で充填された活物質の酢酸
アンモニウム−アンモニア水溶６処
理による抽出量の百分率
（抽出活物質百分率：β）
＝（ｂ−ｃ）／ａＸ１００％
上記のαとβの算出イ直それぞれと硝酸ニッケル水溶液
のｐＨとの関係を示すグラフ図を第２図に示す（α−Ｐ
Ｈの関係は〇−〇、β−ＰＨの関係は△・・・△で示し
た）。このグラフによればＰＨが約１〜２の範囲ではα
とβの値はいずれも最も小さいことから基板の腐蝕を最
小をこおさえることができるので、ＰＨの範囲としては
約１〜２が好ましいことは明らかである。6 fraction of nickel in the substrate dissolved in the impregnating solution during filling with the above active material (dissolved nickel u fraction: α) = (a-C)/aX100% Ammonium acetate of the active material filled in the above method Percentage of extraction amount by ammonia aqueous 6 treatment (extracted active material percentage: β) = (b-c)/aX100% A graph showing the relationship between the above calculations of α and β and the pH of the nickel nitrate aqueous solution. As shown in Figure 2 (α-P
The H relationship is shown as 〇-〇, and the β-PH relationship is shown as △...△). According to this graph, in the pH range of approximately 1 to 2, α
Since both the values of and β are the smallest, corrosion of the substrate can be kept to a minimum, so it is clear that the pH range is preferably about 1 to 2.
（力 発明の効果
この発明によれば、高温、高濃暦の硝酸ニッケル水溶液
に基板を浸漬しても基板の腐）偵が抑［ｉｌＪされ、安
定した性能の水酸化ニッケル電極を１（トることができ
る。Effects of the Invention According to the present invention, corrosion of the substrate is suppressed even when the substrate is immersed in a high-temperature, highly concentrated nickel nitrate aqueous solution, and a nickel hydroxide electrode with stable performance can be used. can be done.
第１ａ〜ＩＣ図はこの発明の実廁例と比軸例の水酸化ニ
ッケル１Ｊ！、極の基板の腐蝕状態を示す、基板表面の
粒子形状を表わす定食型電子顕倣鏡写真（Ｘ２５００）
、第２図は基板を硝酸ニッケル水溶液中に含浸時の溶解
ニッケルと袖出活物賀の百分率のそれぞれとＩ）Ｈとの
関係を示すグラフ図である。
しだ・、こ１）
第１ａ図
第１ｂ図
第１０（４
第２図
Ｈ−Figures 1a to IC are actual examples and ratio examples of nickel hydroxide 1J! , a set-type electron microscopy photograph (X2500) showing the particle shape of the substrate surface, showing the corrosion state of the electrode substrate.
FIG. 2 is a graph showing the relationship between I)H and each of the percentages of dissolved nickel and nickel when the substrate is impregnated in an aqueous nickel nitrate solution. 1) Figure 1a Figure 1b Figure 10 (4 Figure 2H-
Claims (1)
、アルカリ処理して水酸化ニッケルに変換させ、洗浄乾
燥する工程を繰返して、所要量の水酸化ニッケルを前記
ニッケル基板に充填するアルカリ蓄電池用水酸化ニッケ
ル電極の製法において、前記硝酸ニッケル水溶液の温度
が約６０〜１００℃で、ＰＨが約１〜２であることを特
徴とするアルカリ蓄電池用水酸化ニッケル電極の製法。 ２、硝酸ニッケル水溶液のＰＨの調整を、硝酸および／
または水酸化ニッケルを添加することによつて行う特許
請求の範囲第１項の製法。[Claims] 1. A porous nickel substrate is immersed in a nickel nitrate aqueous solution, treated with alkali to convert it into nickel hydroxide, and the steps of washing and drying are repeated to add the required amount of nickel hydroxide to the nickel substrate. A method for producing a nickel hydroxide electrode for an alkaline storage battery to be filled, wherein the temperature of the nickel nitrate aqueous solution is about 60 to 100°C, and the pH is about 1 to 2. 2.Adjust the pH of the nickel nitrate aqueous solution using nitric acid and/or
Alternatively, the manufacturing method according to claim 1, which is carried out by adding nickel hydroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61249115A JPS63105468A (en) | 1986-10-20 | 1986-10-20 | Manufacture of nickel hydroxide electrode for alkaline storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61249115A JPS63105468A (en) | 1986-10-20 | 1986-10-20 | Manufacture of nickel hydroxide electrode for alkaline storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS63105468A true JPS63105468A (en) | 1988-05-10 |
Family
ID=17188171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61249115A Pending JPS63105468A (en) | 1986-10-20 | 1986-10-20 | Manufacture of nickel hydroxide electrode for alkaline storage battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS63105468A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5788669A (en) * | 1980-11-20 | 1982-06-02 | Matsushita Electric Ind Co Ltd | Manufacture of electrode for alkaline storage battery |
| JPS5834566A (en) * | 1981-08-14 | 1983-03-01 | ウエスチングハウス・エレクトリツク・コ−ポレ−シヨン | Method of filling active substance in porous and flexible expansible metal storage battery plate |
| JPS6074262A (en) * | 1983-09-30 | 1985-04-26 | Furukawa Battery Co Ltd:The | Manufacture of nickel electrode |
-
1986
- 1986-10-20 JP JP61249115A patent/JPS63105468A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5788669A (en) * | 1980-11-20 | 1982-06-02 | Matsushita Electric Ind Co Ltd | Manufacture of electrode for alkaline storage battery |
| JPS5834566A (en) * | 1981-08-14 | 1983-03-01 | ウエスチングハウス・エレクトリツク・コ−ポレ−シヨン | Method of filling active substance in porous and flexible expansible metal storage battery plate |
| JPS6074262A (en) * | 1983-09-30 | 1985-04-26 | Furukawa Battery Co Ltd:The | Manufacture of nickel electrode |
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