JPS628404B2 - - Google Patents
Info
- Publication number
- JPS628404B2 JPS628404B2 JP56083616A JP8361681A JPS628404B2 JP S628404 B2 JPS628404 B2 JP S628404B2 JP 56083616 A JP56083616 A JP 56083616A JP 8361681 A JP8361681 A JP 8361681A JP S628404 B2 JPS628404 B2 JP S628404B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- fatty acid
- carbon atoms
- polyoxyethylene
- acid ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000004209 hair Anatomy 0.000 claims description 53
- -1 polyoxyethylene Polymers 0.000 claims description 24
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 23
- 229930195729 fatty acid Natural products 0.000 claims description 23
- 239000000194 fatty acid Substances 0.000 claims description 23
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- 239000002537 cosmetic Substances 0.000 claims description 12
- 150000004665 fatty acids Chemical class 0.000 claims description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 10
- 150000001298 alcohols Chemical class 0.000 claims description 10
- 108090000765 processed proteins & peptides Proteins 0.000 claims description 10
- 229920001184 polypeptide Polymers 0.000 claims description 9
- 102000004196 processed proteins & peptides Human genes 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 239000003995 emulsifying agent Substances 0.000 claims description 7
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 4
- 235000019438 castor oil Nutrition 0.000 claims description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 125000004429 atom Chemical group 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 125000005843 halogen group Chemical group 0.000 claims description 2
- 125000005526 alkyl sulfate group Chemical group 0.000 claims 1
- 239000003676 hair preparation Substances 0.000 description 15
- 230000000694 effects Effects 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 235000019441 ethanol Nutrition 0.000 description 9
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 230000001914 calming effect Effects 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- LQIAZOCLNBBZQK-UHFFFAOYSA-N 1-(1,2-Diphosphanylethyl)pyrrolidin-2-one Chemical compound PCC(P)N1CCCC1=O LQIAZOCLNBBZQK-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 206010019049 Hair texture abnormal Diseases 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 230000003700 hair damage Effects 0.000 description 1
- 230000003699 hair surface Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Description
本発明は、毛髪化粧料に係り、特に、毛髪をし
つとりと落ちつかせ、毛髪に光沢を付与し、べた
つきがなく、髪をまとめ易くすると同時に、毛髪
のブラツシング性をも改善したゲル状毛髪化粧料
に関する。
近年、毛髪はブラツシング、パーマ、ヘアカラ
ー等の普及により、非常に傷み易い環境におかれ
ている。消費者の声も、毛髪がパサパサして落ち
つかないとか、つやがないとか、ブラツシング性
が悪いという悩みが実に多い。
従つて、毛髪化粧料としては、毛髪をしつとり
と落ちつかせ、つやおよびブラツシング性を向上
させるものが望まれている。
また、毛髪は首筋等の肌に直接触れるものであ
り、また手入れの際は必ず手で触れられる部分で
あるから、べたべたした重い感触は徹底的に嫌わ
れる。
従つて、べたつきの無い安定した乳化系である
ことも、好ましい毛髪化粧料の条件である。
市販されている毛髪化粧料の中には、毛髪に関
する消費者の悩みを解決し、毛髪を美しく健康に
保つと謳つたものが多いが、実際に前記条件を円
満に備えた毛髪化粧料は殆ど見当らない。即ち、
従来の毛髪化粧料は多量の油分を含むため、仕上
りが重く、いつまでもべたべたしている。
一方、毛髪化粧料中の油分の配合量を少なくす
ることによつて、軽くてサラツとした毛髪の仕上
り効果を得ることが試みられているが、いくら油
分を少なくしても、べたつきは若干減少するだけ
でさしたる効果は無く、つやおよびブラツシング
性に至つては著しく低下してしまう。
また、表面張力、粘度および融点の低い油分を
使用する方法も試みられており、例えば、ジオー
ル誘導体または分枝脂肪族アルコールにメチルポ
リシロキサンを混合溶解したものを使用する特許
が知られている。この方法は、毛髪化粧料の有効
成分を毛髪の表面に均一に付着せしめ、毛髪同
士、および毛髪とブラシや櫛との間の摩擦を減ら
して、毛髪を機械的な刺激から保護することを主
眼としたものである。
しかし、そのようなべたつきの無い表面張力の
低い油分は、極めて疎水性に富むものであるた
め、毛髪がばさつく（しつとりと落ちつかない）
うえに、被洗浄能力（シヤンプー洗浄性）も劣る
という欠点がある。
本発明の目的は、毛髪をしつとりと落ちつか
せ、ブラツシング性を向上させ、べたつきを少な
くし、かつ髪をまとめ易くすることの可能な毛髪
化粧料を提供することにある。
本発明の毛髪化粧料は、
一般式
（式中、R1，R2，R3およびR4のうち１つ又は
２つは炭素数８〜24の長鎖アルキル基、残りは炭
素数１又は２のアルキル基であり、Ｘはハロゲン
原子又は炭素数が１又は２のアルキル基を有する
アルキル硫酸である。
で表わされる第４級アンモニウム塩の１種又は２
種以上を0.5〜4.0重量％、炭素数が14〜22の直鎖
飽和アルコールを0.7〜5.0重量％、炭素数８〜20
の脂肪酸とポリペプチドとの縮合物を0.1〜3.0重
量％、およびポリオキシエチレンが付加された多
分子鎖状の乳化剤の１種又は２種以上を0.2〜7.0
重量％含有することを特徴とする。
前記一般式で表わされる第４級アンモニウム塩
は、モノ長鎖アルキル又はジ長鎖アルキルのタイ
プのもの、もしくはそれらの混合物であり、陽イ
オン性を示すことから、本発明の組成物が毛髪に
効果的に吸着するために本質的に重要な成分であ
る。この第４級アンモニウム塩の長鎖アルキル基
の炭素数が７以下の場合には、水溶性が高くなつ
て、水系では毛髪への吸着より水への分散が強く
なり、即ち毛髪への吸着率が非常に低くなつてし
まう。また、毛髪に吸着しても、アルキル基の鎖
長が短かいため、毛髪の柔軟効果が著しく低い。
一方、第４級アンモニウム塩の長鎖アルキル基の
炭素数が24を越えると、陽イオン性が小さくなつ
て、毛髪への吸着率が減少し、また吸着してもア
ルキル基の鎖長が長いため毛髪の滑沃性が著しく
低下してしまう。また、長鎖アルキル基の数が３
個または４個の場合、陽イオン性が劣り、上述と
同様の難点が生じて好ましくない。
炭素数14〜22の飽和アルコールは、上述の第４
級アンモニウム塩と一対となつて毛髪に吸着し、
特に毛髪の保水性を増大して毛髪を落ちつかせ
る。この飽和アルコールの炭素数が13以下では、
毛髪を落ちつかせる効果が劣り、炭素数が22を越
えても毛髪を落ちつかせる効果が弱い。また、不
飽和アルコールは、第４級アンモニウム塩と効率
よく対を作らず、毛髪に上述の性能を与えない。
脂肪酸ポリペプチド縮合物は、炭素数８〜20の
脂肪酸と、例えば分子量が200〜2000の蛋白質分
解物（ポリペプチド）との縮合物であり、末端の
カルボン酸基は、酸のまま、リチウム塩、ナトリ
ウム塩、カリウム塩、アルコールアミン塩の形で
ある。この脂肪酸ポリペプチド縮合物は、ブラツ
シング、パーマ、ヘアカラー等で傷んだ毛髪表面
に吸着し、毛髪の損傷を修復する効果を与えるも
のである。脂肪酸の炭素数が７以下の場合には毛
髪への吸着量が少なく、またたとえ吸着しても毛
髪のつやを出す効果が弱い。また、脂肪酸の炭素
数が20を越えると毛髪のパサツキを抑える効果が
劣る。一方、ポリペプチドの分子量は、200未満
では傷んだ毛髪の修復効果が弱く、2000を越える
と毛髪が硬くなるので、好ましくない。
以上説明した第４級アンモニウム塩、飽和アル
コールおよび脂肪酸ポリペプチドの毛髪化粧料中
の含有量は、それぞれ0.5〜4.0重量％、0.7〜5.0
重量％、および0.1〜3.0重量％であり、これらの
範囲内において特異的な効果を発揮する。
本発明の毛髪化粧料が毛髪表面に均一に吸着
し、かつ安定な分散組成物として存在して商品価
値を保持するためには、上述の成分に加え、更に
ポリオキシエチレンが付加された多分子鎖状の乳
化剤を含有することが必要である。この乳化剤と
しては、例えばポリオキシエチレン硬化ヒマシ油
エーテル、ポリオキシエチレン硬化ヒマシ油エー
テルの脂肪酸エステル、ポリオキシエチレングリ
セリル脂肪酸エステル、ポリオキシエチレンソル
ビタン脂肪酸エステル、ポリオキシエチレンソル
ビツト脂肪酸エステル、およびポリオキシエチレ
ンソルビトール脂肪酸エステルのうちの１種又は
２種以上であり、含有量は0.2〜7.0重量％であ
る。
本発明の毛髪化粧料中には、他の任意成分を本
発明の効果に影響のない範囲で配合することが可
能である。そのような任意成分として、天然又は
合成の各種油分；アミノ酸；生薬；高分子物質；
プロピレングリコール、１，３−ブチレングリコ
ール、グリセリン、ソルビトール、エタノール等
の保湿剤；溶剤；および殺菌剤、香料、色素等の
少量成分がある。
本発明の毛髪化粧料は、ヘアローシヨン、ヘア
コンデイシヨナー、ヘアリンス等の各種用途に適
用することができる。
次に、本発明の毛髪化粧料の効果を更に具体的
に示す実施例を示す。なお、各実施例の説明に先
立つて、各実施例で採用した試験法について説明
する。
(1) 性能
毛髪化粧料を毛髪10ｇに対し0.5ｇの割合で
毛髪に塗布もしくは散布したのちの毛髪のしつ
とり感、まとまり性、つや、ブラツシング性お
よびパサツキ性を次のように評価する。
評価基準は、１重量％の塩化ステアリルトリ
メチルアンモニウム、３重量％のセチルアルコ
ール、10重量％のプロピレングリコール、およ
び86重量％の水からなる、従来から良く知られ
た代表的な汎用リンス組成物の性能を基準とし
た５段階評価である。
◎ ： 良い
○ ： やや良い
△ ： 同等
× ： やや劣る
×× ： 劣る
(2) 性状
毛髪化粧料を100c.c.のガラス容器に密封し、−
５℃〜40℃に６ケ月保存した後の外観を観察し
て、その分散安定性を評価した。
○ ： 変化なし
△ ： 液相と水相がやや分離
× ： 油相と水相が明らかに分離
実施例 １
下記の表−１に示す配合組成の５種の毛髪化粧
料を調製し、それらの性能及び性状を試験した。
その結果を同表に示す。同表から明らかなよう
に、第４級アンモニウム塩、飽和アルコール、脂
肪酸ポリペプチドおよび多分子鎖乳化剤のいずれ
か１つが欠けても（試料No.１〜４）本発明の効果
を達成できないことがわかる。
The present invention relates to hair cosmetics, and in particular, gel-like hair that moisturizes and soothes hair, imparts luster to the hair, is non-sticky, makes hair easier to comb, and at the same time improves hair brushability. Regarding cosmetics. In recent years, due to the spread of brushing, perming, hair coloring, etc., hair is placed in an environment where it is extremely susceptible to damage. Consumers often complain that their hair is dry and unsmooth, lacks shine, and has poor brushability. Therefore, there is a desire for hair cosmetics that moisturize and soothe hair and improve shine and brushability. In addition, since hair comes into direct contact with the skin of the nape of the neck and is always touched by hands when caring for it, a sticky and heavy feel is completely disliked. Therefore, a stable emulsion system without stickiness is also a desirable condition for hair cosmetics. Among the hair cosmetics on the market, many claim to solve consumers' hair-related concerns and keep hair beautiful and healthy, but in reality, very few hair cosmetics fully meet the above conditions. I can't find it. That is,
Conventional hair cosmetics contain a large amount of oil, resulting in a heavy, sticky finish. On the other hand, attempts have been made to achieve a light and silky finish by reducing the amount of oil in hair cosmetics, but no matter how much oil is reduced, the stickiness is slightly reduced. There is no significant effect just by applying it, and the shine and brushability are significantly reduced. Additionally, attempts have been made to use oils with low surface tension, viscosity, and melting point; for example, patents are known in which methylpolysiloxane is mixed and dissolved in diol derivatives or branched aliphatic alcohols. The main purpose of this method is to uniformly adhere the active ingredients of hair cosmetics to the surface of the hair, reduce friction between the hairs and between the hair and the brush or comb, and protect the hair from mechanical stimulation. That is. However, such non-sticky oils with low surface tension are extremely hydrophobic, making the hair frizzy (not moist and calm).
Moreover, it has the disadvantage of being inferior in cleaning ability (shampoo cleaning performance). An object of the present invention is to provide a hair cosmetic that makes hair moist and calm, improves brushability, reduces stickiness, and makes hair easier to comb. The hair cosmetic of the present invention has the general formula: (In the formula, one or two of R 1 , R 2 , R 3 and R 4 are long-chain alkyl groups with 8 to 24 carbon atoms, the rest are alkyl groups with 1 or 2 carbon atoms, and X is a halogen It is an alkyl sulfuric acid having an alkyl group having 1 or 2 atoms or carbon atoms.One or two quaternary ammonium salts represented by
0.5 to 4.0% by weight of species or higher, 0.7 to 5.0% by weight of linear saturated alcohols with 14 to 22 carbon atoms, 8 to 20 carbon atoms
0.1 to 3.0% by weight of a condensate of fatty acid and polypeptide, and 0.2 to 7.0% of one or more polymolecular chain emulsifiers to which polyoxyethylene is added.
It is characterized by containing % by weight. The quaternary ammonium salt represented by the above general formula is of the mono-long chain alkyl type or di-long chain alkyl type, or a mixture thereof, and exhibits cationic properties, so that the composition of the present invention may be applied to the hair. It is an essential component for effective adsorption. When the long chain alkyl group of this quaternary ammonium salt has 7 or less carbon atoms, its water solubility becomes high, and in an aqueous system, its dispersion in water becomes stronger than its adsorption to hair, that is, the adsorption rate to hair increases. becomes very low. Furthermore, even if adsorbed to hair, the hair softening effect is extremely low because the chain length of the alkyl group is short.
On the other hand, when the number of carbon atoms in the long chain alkyl group of the quaternary ammonium salt exceeds 24, the cationicity becomes small and the adsorption rate to hair decreases, and even if adsorbed, the chain length of the alkyl group is long. As a result, the smoothness of the hair is significantly reduced. In addition, the number of long chain alkyl groups is 3
If the number is 1 or 4, the cationic property will be poor and the same problems as mentioned above will occur, which is not preferable. Saturated alcohols having 14 to 22 carbon atoms are
It forms a pair with grade ammonium salt and adsorbs to the hair.
In particular, it increases the water retention capacity of the hair and soothes the hair. When the number of carbon atoms in this saturated alcohol is 13 or less,
It is less effective in calming hair, and even if the number of carbon atoms exceeds 22, the effect in calming hair is weak. Also, unsaturated alcohols do not pair efficiently with quaternary ammonium salts and do not provide the above-mentioned properties to the hair. A fatty acid polypeptide condensate is a condensate of a fatty acid having 8 to 20 carbon atoms and, for example, a protein decomposition product (polypeptide) having a molecular weight of 200 to 2,000. , in the form of sodium salts, potassium salts, and alcohol amine salts. This fatty acid polypeptide condensate adsorbs to the surface of hair that has been damaged by brushing, perming, hair coloring, etc., and has the effect of repairing hair damage. When the number of carbon atoms in the fatty acid is 7 or less, the amount of fatty acid adsorbed to the hair is small, and even if it is adsorbed, the effect of making the hair glossy is weak. Furthermore, if the number of carbon atoms in the fatty acid exceeds 20, the effect of suppressing dry hair will be poor. On the other hand, when the molecular weight of the polypeptide is less than 200, the effect of restoring damaged hair is weak, and when it exceeds 2000, the hair becomes hard, which is not preferable. The contents of the quaternary ammonium salt, saturated alcohol, and fatty acid polypeptide described above in the hair cosmetic are 0.5 to 4.0% by weight and 0.7 to 5.0% by weight, respectively.
% by weight, and 0.1 to 3.0% by weight, and exhibits specific effects within these ranges. In order for the hair cosmetic composition of the present invention to uniformly adsorb onto the hair surface and exist as a stable dispersion composition to maintain its commercial value, in addition to the above-mentioned components, it is necessary to add polyoxyethylene to the hair cosmetic composition. It is necessary to contain a chain emulsifier. Examples of the emulsifier include polyoxyethylene hydrogenated castor oil ether, fatty acid ester of polyoxyethylene hydrogenated castor oil ether, polyoxyethylene glyceryl fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, and polyoxyethylene sorbitan fatty acid ester. It is one or more kinds of ethylene sorbitol fatty acid esters, and the content is 0.2 to 7.0% by weight. It is possible to incorporate other optional ingredients into the hair cosmetic of the present invention within a range that does not affect the effects of the present invention. Such optional ingredients include various natural or synthetic oils; amino acids; crude drugs; polymeric substances;
Moisturizers such as propylene glycol, 1,3-butylene glycol, glycerin, sorbitol, and ethanol; solvents; and minor components such as bactericides, fragrances, and pigments. The hair cosmetic composition of the present invention can be applied to various uses such as hair lotion, hair conditioner, and hair rinse. Next, Examples will be shown that more specifically demonstrate the effects of the hair cosmetic of the present invention. In addition, before explaining each example, the test method adopted in each example will be explained. (1) Performance After the hair cosmetic is applied or sprayed on the hair at a ratio of 0.5 g to 10 g of hair, the moisturizing feeling, manageability, shine, brushability, and dryness of the hair are evaluated as follows. The evaluation criteria were based on a typical well-known general purpose rinse composition consisting of 1% by weight stearyltrimethylammonium chloride, 3% by weight cetyl alcohol, 10% by weight propylene glycol, and 86% by weight water. It is a five-level evaluation based on performance. ◎: Good ○: Slightly good △: Same ×: Slightly inferior ××: Inferior (2) Properties Hair cosmetics were sealed in a 100 c.c. glass container and -
The dispersion stability was evaluated by observing the appearance after being stored at 5°C to 40°C for 6 months. ○: No change △: Liquid phase and aqueous phase are slightly separated ×: Oil phase and aqueous phase are clearly separated Example 1 Five types of hair cosmetics having the formulation shown in Table 1 below were prepared, and their Performance and properties were tested.
The results are shown in the same table. As is clear from the same table, even if any one of the quaternary ammonium salt, saturated alcohol, fatty acid polypeptide, and multimolecular chain emulsifier is missing (sample Nos. 1 to 4), the effects of the present invention cannot be achieved. Recognize.
【表】【table】
【表】
実施例 ２
下記の表−２に示す配合組成の４種の毛髪化粧
料を調製し、それらの性能および性状を試験し
た。その結果を同表に示す。同表から明らかなよ
うに、炭素数８〜24の長鎖アルキル基を有するモ
ノ長鎖アルキル型又はジ直鎖アルキル型の第４級
アンモニウム塩を用いたときに、本発明の効果を
達成できることがわかる。[Table] Example 2 Four types of hair cosmetics having the formulation shown in Table 2 below were prepared and their performance and properties were tested. The results are shown in the same table. As is clear from the table, the effects of the present invention can be achieved when using a mono-long chain alkyl type or di-linear alkyl type quaternary ammonium salt having a long chain alkyl group having 8 to 24 carbon atoms. I understand.
【表】
実施例 ３
下記の表−３に示す配合組成の４種の毛髪化粧
料を調製し、それらの性能および性状を試験し
た。その結果を同表に示す。同表から明らかなよ
うに、炭素数14〜22の直鎖飽和アルコールを用い
たときに、いずれも本発明の効果を達成できるこ
とがわかる。なお、炭素数が13以下および23以上
のアルコール、または不飽和アルコールを用いた
場合には、本発明の効果は認められない。[Table] Example 3 Four types of hair cosmetics having the formulation shown in Table 3 below were prepared and their performance and properties were tested. The results are shown in the same table. As is clear from the same table, it can be seen that the effects of the present invention can be achieved when linear saturated alcohols having 14 to 22 carbon atoms are used. Note that the effects of the present invention are not observed when alcohols having 13 or less carbon atoms or 23 or more carbon atoms or unsaturated alcohols are used.
【表】
実施例 ４
下記の表−４に示す配合組成の７種の毛髪化粧
料を調製し、それらの性能および性状を試験し
た。その結果を同表に示す。同表から明らかなよ
うに、炭素数８〜20の脂肪酸と分子量200〜2000
のポリペプチドの脂肪酸ペプチドを用いた時に、
好ましい本発明の効果が得られることがわかる。[Table] Example 4 Seven types of hair cosmetics having the formulation shown in Table 4 below were prepared and their performance and properties were tested. The results are shown in the same table. As is clear from the same table, fatty acids with a carbon number of 8 to 20 and molecular weights of 200 to 2000
When using the fatty acid peptide of the polypeptide,
It can be seen that favorable effects of the present invention can be obtained.
【表】【table】
【表】
実施例 ５
下記の表−５に示す配合組成の５種の毛髪化粧
料を調製し、それらの性能および性状を試験し
た。その結果を同表に示す。同表から明らかなよ
うに、多分子鎖乳化剤を含む本発明の毛髪化粧料
は、いずれも優れた性能を示すことがわかる。[Table] Example 5 Five types of hair cosmetics having the formulation shown in Table 5 below were prepared and their performance and properties were tested. The results are shown in the same table. As is clear from the same table, it can be seen that all the hair cosmetics of the present invention containing a multi-molecular chain emulsifier exhibit excellent performance.
Claims (1)
２つは炭素数８〜24の長鎖アルキル基、残りは炭
素数１又は２のアルキル基であり、Ｘはハロゲン
原子又は炭素数が１又は２のアルキル基を有する
アルキル硫酸基である。） で表される第４級アンモニウム塩の１種又は２種
以上を0.5〜4.0重量％、炭素数が14〜22の直鎖飽
和アルコールを0.7〜5.0重量％、炭素数８〜20の
脂肪酸とポリペプチドとの縮合物を0.1〜3.0重量
％、およびポリオキシエチレンが付加された多分
子鎖状の乳化剤の１種又は２種以上を0.2〜7.0重
量％含有することを特徴とする毛髪化粧料。 ２ 前記多分子鎖状の乳化剤は、ポリオキシエチ
レン硬化ヒマシ油エーテル、ポリオキシエチレン
硬化ヒマシ油エーテルの脂肪酸エステル、ポリオ
キシエチレングリセリル脂肪酸エステル、ポリオ
キシエチレンソルビタン脂肪酸エステル、ポリオ
キシエチレンソルビツト脂肪酸エステル、および
ポリオキシエチレンソルビトール脂肪酸エステル
からなる群から選択された少なくとも１種である
特許請求の範囲第１項記載の毛髪化粧料。[Claims] 1. General formula (In the formula, one or two of R 1 , R 2 , R 3 and R 4 are long-chain alkyl groups with 8 to 24 carbon atoms, the rest are alkyl groups with 1 or 2 carbon atoms, and X is a halogen It is an alkyl sulfate group having an alkyl group having 1 or 2 atoms or carbon atoms. 0.7 to 5.0% by weight of a linear saturated alcohol, 0.1 to 3.0% by weight of a condensate of a fatty acid having 8 to 20 carbon atoms and a polypeptide, and one or more polymolecular chain emulsifiers to which polyoxyethylene is added. A hair cosmetic containing 0.2 to 7.0% by weight of two or more types. 2 The polymolecular chain emulsifier is polyoxyethylene hydrogenated castor oil ether, fatty acid ester of polyoxyethylene hydrogenated castor oil ether, polyoxyethylene glyceryl fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester. The hair cosmetic according to claim 1, which is at least one selected from the group consisting of , and polyoxyethylene sorbitol fatty acid ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56083616A JPS57200307A (en) | 1981-05-30 | 1981-05-30 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56083616A JPS57200307A (en) | 1981-05-30 | 1981-05-30 | Hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57200307A JPS57200307A (en) | 1982-12-08 |
| JPS628404B2 true JPS628404B2 (en) | 1987-02-23 |
Family
ID=13807415
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56083616A Granted JPS57200307A (en) | 1981-05-30 | 1981-05-30 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57200307A (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59196809A (en) * | 1983-04-22 | 1984-11-08 | Lion Corp | Hair cosmetic composition |
| JPS6019710A (en) * | 1983-07-12 | 1985-01-31 | Lion Corp | Hair cosmetic |
| JPS62132812A (en) * | 1985-12-03 | 1987-06-16 | Sunstar Inc | Hair rinse agent composition |
| JP2878287B2 (en) * | 1988-08-12 | 1999-04-05 | 株式会社成和化成 | Cosmetic base material |
| JPH0655657B2 (en) * | 1989-03-06 | 1994-07-27 | ホーユー株式会社 | Hair treatment agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5326333A (en) * | 1976-08-24 | 1978-03-11 | Lion Corp | Hair rinsing composition |
| JPS5386044A (en) * | 1976-12-30 | 1978-07-29 | Kanebo Ltd | Self-spraying foamed aerosol cosmetic composition |
-
1981
- 1981-05-30 JP JP56083616A patent/JPS57200307A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5326333A (en) * | 1976-08-24 | 1978-03-11 | Lion Corp | Hair rinsing composition |
| JPS5386044A (en) * | 1976-12-30 | 1978-07-29 | Kanebo Ltd | Self-spraying foamed aerosol cosmetic composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57200307A (en) | 1982-12-08 |
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