JPS628087B2 - - Google Patents
Info
- Publication number
- JPS628087B2 JPS628087B2 JP55073173A JP7317380A JPS628087B2 JP S628087 B2 JPS628087 B2 JP S628087B2 JP 55073173 A JP55073173 A JP 55073173A JP 7317380 A JP7317380 A JP 7317380A JP S628087 B2 JPS628087 B2 JP S628087B2
- Authority
- JP
- Japan
- Prior art keywords
- hair
- alkyl
- quaternary ammonium
- ammonium salt
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000004209 hair Anatomy 0.000 claims description 65
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 239000002537 cosmetic Substances 0.000 claims description 16
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 10
- 125000005843 halogen group Chemical group 0.000 claims description 6
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 6
- 125000005526 alkyl sulfate group Chemical group 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- -1 alkyl quaternary ammonium salt Chemical class 0.000 description 18
- 239000000203 mixture Substances 0.000 description 10
- 230000003766 combability Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000003676 hair preparation Substances 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 5
- 230000003020 moisturizing effect Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000006071 cream Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N heptadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000003760 tallow Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000003700 hair damage Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- DGSZGZSCHSQXFV-UHFFFAOYSA-N 2,3-bis(2-ethylhexanoyloxy)propyl 2-ethylhexanoate Chemical compound CCCCC(CC)C(=O)OCC(OC(=O)C(CC)CCCC)COC(=O)C(CC)CCCC DGSZGZSCHSQXFV-UHFFFAOYSA-N 0.000 description 1
- GECRRQVLQHRVNH-MRCUWXFGSA-N 2-octyldodecyl (z)-octadec-9-enoate Chemical compound CCCCCCCCCCC(CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC GECRRQVLQHRVNH-MRCUWXFGSA-N 0.000 description 1
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 1
- HIQIXEFWDLTDED-UHFFFAOYSA-N 4-hydroxy-1-piperidin-4-ylpyrrolidin-2-one Chemical compound O=C1CC(O)CN1C1CCNCC1 HIQIXEFWDLTDED-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- CDIPRYKTRRRSEM-UHFFFAOYSA-M docosyl(trimethyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C CDIPRYKTRRRSEM-UHFFFAOYSA-M 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000000118 hair dye Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- MRAPAFWHXSJNRN-UHFFFAOYSA-M icosyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCC[N+](C)(C)C MRAPAFWHXSJNRN-UHFFFAOYSA-M 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Polymers 0.000 description 1
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 1
- 229940073665 octyldodecyl myristate Drugs 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001570 sorbitan monopalmitate Substances 0.000 description 1
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 1
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
Description
本発明は、損傷した毛髪に対して優れたヘアコ
ンデイシヨニング性を付与する毛髪化粧料に関す
る。
毛髪を傷める原因として、ブラツシングや毛髪
間の摩擦等の機械的要因、パーマネントウエーブ
液、ヘアダイおよびヘアブリーチ等の化学薬品に
よる要因、および日光や熱等の物理化学的要因等
があげられる。
機械的要因による毛髪の損傷は、近年の種々の
毛髪化粧料の技術開発に伴なつて、既に解決され
ている。しかし、化学薬品や物理的要因による損
傷毛に、優れたヘアコンデイシヨニング性を付与
することは、未だ十分には解決されていない。
本発明は、上記欠点を改善するためになされた
ものであつて、損傷した毛髪に従来より優れたヘ
アコンデイシヨニング性を付与する毛髪化粧料を
提供することを目的とする。
即ち、本発明の毛髪化粧料は、下記一般式
（）で表わされる第４級アンモニウム塩0.1ない
し３重量％と、下記一般式（）で表わされる第
４級アンモニウム塩0.1ないし３重量％と、高級
アルコールとを必須成分として含有し、かつ
（）／（）の重量比は1/3ないし1.5/1であ
り、かつ（）＋（）／高級アルコールの重量比
は1/6ないし1/3.5であることを特徴とする。
一般式（）：
（式中、R1は炭素数20〜22のアルキル基、
R2，R3およびR4は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素原子数が１又は２のアルキル硫
酸基を示す。）
一般式（）
（式中、R5およびR6は炭素数16〜18のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
以下、本発明の毛髪化粧料について更に詳細に
説明する。
本発明の毛髪化粧料の第１の必須成分は、以下
の一般式（）で表わされるモノ−Ｃ20-22アルキ
ル第４級アンモニウム塩である。
一般式（）：
（式中、R1は炭素数20〜22のアルキル基、
R2，R3およびR4は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素原子数が１又は２のアルキル硫
酸基を示す。）
第１の必須成分の配合量は、毛髪化粧料全体に
対し0.1ないし3.0重量％、好ましくは0.1ないし
2.0重量％である。0.1重量％未満では本発明の効
果は発揮されず、3.0重量％を越えると毛髪のべ
たつきおよび重みが増加し、好ましくない。
第１の必須成分の代表例として以下の物質があ
る。
エイコシルトリメチルアンモニウムクロリド、
ヘンエイコシルトリメチルアンモニウムクロリ
ド、ドコシルトリメチルアンモニウムクロリド、
ドコシルトリメチルアンモニウムブロミド、ドコ
シルトリエチルアンモニウムクロリド、ドコシル
トリメチルアンモニウムメチルサルフエート。
本発明の毛髪化粧料の第２の必須成分は、以下
の一般式（）で表わされるジ−Ｃ16-18アルキル
第４級アンモニウム塩である。
一般式（）
（式中、R5およびR6は炭素数16〜18のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）
第２の必須成分の配合量は、毛髪化粧料全体に
対し0.1ないし3.0重量％、好ましくは0.1ないし
2.0重量％である。0.1重量％未満では本発明の効
果は発揮されず、3.0重量％を越えると毛髪のべ
たつきおよび重みが増加し、好ましくない。
第２の必須成分の代表例として以下の物質があ
る。
ジバルミチルジメチルアンモニウムクロリド、
ジステアリルジメチルアンモニウムクロリド、ジ
−水素添加牛脂アルキルジメチルアンモニウムク
ロリド、ジ−水素添加牛脂アルキルジメチルアン
モニウムブロミド、ジ−水素添加牛脂アルキルジ
エチルアンモニウムメチルサルフエート。
本発明の毛髪化粧料の第３の必須成分は高級ア
ルコールであり、好ましくはＣ16-18の高級アルコ
ールである。そのような高級アルコールの具体例
として、セチルアルコール、ヘプタデカノール、
ステアリルアルコール等の飽和−価アルコール、
および脂肪族アルコールがある。更に好ましく
は、C16／C18＝1/1の重量比の高級アルコールの
混合物が良い。
本発明の毛髪化粧剤においては、上述の一般式
（）の第４級アンモニウム塩と一般式（）の
第４級アンモニウム塩との重量比（）／（）
が1/3ないし1.5／１の範囲にある必要がある。特
に好ましくは、（）／（）＝1/2.7〜1.2/1であ
る。（）／（）が1.5/1を越える場合には特に
しつとり感が劣り、1/3未満では柔軟性およびな
めらかさが劣り、好ましくない。
更に、本発明の毛髪化粧剤においては、一般式
（）の第４級アンモニウム塩と一般式（）の
第４級アンモニウム塩（）の合計量と高級アル
コールとの重量比（）＋（）／高級アルコール
は1/6ないし1/3.5の範囲内になければならない。
特に好ましい範囲は1/5.5ないし1/4である。
（）＋（）／高級アルコールが1/3.5を越えると
なめらかさが劣化し、1/6未満であると櫛通り性
およびしつとり感が劣化し、好ましくない。
本発明の毛髪化粧料中には、他の任意成分を、
本発明の効果に影響ない範囲で配合することが可
能である。そのような任意成分として以下の物質
がある。
流動パラフイン、ワセリン、固形パラフイン、
スクワランおよびオレフインオリゴマー等の炭化
水素；イソプロピルミリステート、イソプロピル
パルミテート、ステアリルステアレート、ミリス
チン酸オクチルドデシル、オレイン酸オクチルド
デシルおよび２−エチルヘキサン酸トリグリセラ
イド等のエステル；グリセリルモノステアレー
ト、ソルビタンモノパルミテート、ポリオキシエ
チレンセチルエーテル、ポリオキシエチレンステ
アリン酸エステルおよびポリオキシエチレンソル
ビタンモノラウレート等の乳化剤；メチルセルロ
ース、ヒドロキシエチルセルロース、ヒドロキシ
プロピルセルロースおよびカチオンイヒセルロー
ス等のセルロース誘導体；天然高分子類等の増粘
剤；エチレングリコール、プロピレングリコー
ル、１，３−ブチレングリコール、グリセリンお
よびソルビトール等の保湿剤；およびその他溶
剤、殺菌剤、香料等の少量成分である。
本発明の毛髪化粧料は、ヘアーリンス剤、スプ
レー型又はデイスペンサー型のヘアコンデイシヨ
ナーヘアーローシヨン等の各種用途に利用するこ
とができる。
次に、本発明の実施例と比較例を示し、本発明
の効果をより具体的に説明する。なお、各例の説
明に先立つて、各例で採用したヘアコンデイシヨ
ニング性の試験法について説明する。
ヘアコンデイシヨニング性は、櫛通り性、なめ
らかさ、しつとり感および毛髪柔軟性の４項目に
ついて評価した。
被処理物としての損傷毛は以下の３つのものを
使用した。
(1) ブリーチ処理毛
６％過酸化水素水にアンモニア水を加えてPH
10.2に調整して得たブリーチ液に毛束を30分間浸
漬（ブリーチ液と毛束の浴比：30倍）してブリー
チ処理したのち、流水でよくすすいだもの
(2) アルカリ損傷毛
１％水酸化ナトリウム液に毛束を30分間浸漬し
たのち流水でよくすすいだもの
(3) 熱損傷毛
毛束を80℃で５時間減圧乾燥したもの
試験法
損傷処理された毛束（５ｇ、20cm）をシヤンプ
ーしたのち、試料0.5ｇを直接塗布し、手で均一
に伸ばし、次いで25℃、65％RHの雰囲気で乾燥
させ、１昼夜放置後の毛髪の櫛通り性、なめらか
さ、しつとり感および毛髪柔軟性について官能評
価した。評価基準は、上記損傷処理毛をシヤンプ
ー処理したものを基準とする３段階評価である。
◎：非常に優れる。 〇：やや良い
△：同等
試験例 １
種々の第４級アンモニウム塩および／または高
級アルコールを含む９種の毛髪化粧料を調整し、
それらの熱損傷毛に対する性能を試験した。その
結果を表１に示す。なお、配合量は重量％である
（他の試験でも同様）。
The present invention relates to a hair cosmetic that provides excellent hair conditioning properties to damaged hair. Causes of hair damage include mechanical factors such as brushing and friction between hairs, factors caused by chemicals such as permanent wave solutions, hair dye, and hair bleach, and physicochemical factors such as sunlight and heat. Hair damage caused by mechanical factors has already been solved with the recent technological development of various hair cosmetics. However, the problem of imparting excellent hair conditioning properties to hair damaged by chemicals or physical factors has not yet been fully resolved. The present invention was made in order to improve the above-mentioned drawbacks, and an object of the present invention is to provide a hair cosmetic that provides better hair conditioning properties to damaged hair than ever before. That is, the hair cosmetic of the present invention contains 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), contains higher alcohol as an essential component, and the weight ratio of ()/() is 1/3 to 1.5/1, and the weight ratio of ()+()/higher alcohol is 1/6 to 1/3.5. It is characterized by General formula (): (In the formula, R 1 is an alkyl group having 20 to 22 carbon atoms,
R 2 , R 3 and R 4 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula () (In the formula, R 5 and R 6 are alkyl groups with 16 to 18 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. or 2.) Hereinafter, the hair cosmetic of the present invention will be explained in more detail. The first essential component of the hair cosmetic of the present invention is a mono-C 20-22 alkyl quaternary ammonium salt represented by the following general formula (). General formula (): (In the formula, R 1 is an alkyl group having 20 to 22 carbon atoms,
R 2 , R 3 and R 4 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) The blending amount of the first essential ingredient is 0.1 to 3.0% by weight, preferably 0.1 to 3.0% by weight based on the entire hair cosmetic.
It is 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky and heavy, which is not preferable. The following substances are representative examples of the first essential component. eicosyltrimethylammonium chloride,
Heneicosyltrimethylammonium chloride, docosyltrimethylammonium chloride,
Docosyltrimethylammonium bromide, docosyltriethylammonium chloride, docosyltrimethylammonium methyl sulfate. The second essential component of the hair cosmetic of the present invention is a di-C 16-18 alkyl quaternary ammonium salt represented by the following general formula (). General formula () (In the formula, R 5 and R 6 are alkyl groups with 16 to 18 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. (or 2 alkyl sulfate group)) The amount of the second essential component is 0.1 to 3.0% by weight, preferably 0.1 to 3.0% by weight, based on the total hair cosmetic.
It is 2.0% by weight. If it is less than 0.1% by weight, the effect of the present invention will not be exhibited, and if it exceeds 3.0% by weight, the hair will become sticky and heavy, which is not preferable. Representative examples of the second essential component include the following substances. dibalmityldimethylammonium chloride,
Distearyldimethylammonium chloride, di-hydrogenated tallow alkyldimethylammonium chloride, di-hydrogenated tallow alkyldimethylammonium bromide, di-hydrogenated tallow alkyldiethylammonium methylsulfate. The third essential component of the hair cosmetic of the present invention is a higher alcohol, preferably a C 16-18 higher alcohol. Specific examples of such higher alcohols include cetyl alcohol, heptadecanol,
Saturated-hydric alcohols such as stearyl alcohol,
and aliphatic alcohols. More preferably, a mixture of higher alcohols with a weight ratio of C 16 /C 18 = 1/1 is preferred. In the hair cosmetic of the present invention, the weight ratio ()/() of the quaternary ammonium salt of the above general formula () to the quaternary ammonium salt of the general formula () is
must be in the range of 1/3 to 1.5/1. Particularly preferably, ()/()=1/2.7 to 1.2/1. When ()/() exceeds 1.5/1, the moisturizing feeling is particularly poor, and when it is less than 1/3, flexibility and smoothness are poor, which is not preferable. Furthermore, in the hair cosmetic composition of the present invention, the weight ratio of the total amount of the quaternary ammonium salt of the general formula () and the quaternary ammonium salt () of the general formula () to the higher alcohol is ()+()/ Higher alcohol must be within the range of 1/6 to 1/3.5.
A particularly preferred range is 1/5.5 to 1/4.
If the content of ()+()/higher alcohol exceeds 1/3.5, the smoothness will deteriorate, and if it is less than 1/6, the combability and moist feeling will deteriorate, which is not preferable. The hair cosmetic of the present invention contains other optional ingredients,
It is possible to mix them within a range that does not affect the effects of the present invention. Such optional ingredients include the following substances. liquid paraffin, vaseline, solid paraffin,
Hydrocarbons such as squalane and olefin oligomers; esters such as isopropyl myristate, isopropyl palmitate, stearyl stearate, octyldodecyl myristate, octyldodecyl oleate and 2-ethylhexanoic acid triglyceride; glyceryl monostearate, sorbitan monopalmitate Emulsifiers such as , polyoxyethylene cetyl ether, polyoxyethylene stearate, and polyoxyethylene sorbitan monolaurate; Cellulose derivatives such as methyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, and cationic cellulose; Thickeners of natural polymers, etc. moisturizers such as ethylene glycol, propylene glycol, 1,3-butylene glycol, glycerin and sorbitol; and other small amounts of ingredients such as solvents, disinfectants, and fragrances. The hair cosmetic composition of the present invention can be used in various applications such as a hair rinse, a spray-type or dispenser-type hair conditioner, and a hair lotion. Next, Examples and Comparative Examples of the present invention will be shown to explain the effects of the present invention more specifically. Before explaining each example, the hair conditioning test method used in each example will be explained. Hair conditioning properties were evaluated in four categories: combability, smoothness, moisturizing feel, and hair flexibility. The following three types of damaged hair were used as objects to be treated. (1) Bleached hair: Add ammonia water to 6% hydrogen peroxide solution to pH
Hair strands were bleached by immersing them in a bleach solution adjusted to 10.2 for 30 minutes (bath ratio of bleach solution and hair strands: 30 times), and then rinsed thoroughly with running water (2) Alkali-damaged hair 1% Hair bundles soaked in sodium hydroxide solution for 30 minutes and then rinsed thoroughly with running water (3) Heat-damaged hair Hair bundles dried under reduced pressure at 80°C for 5 hours Test method Damaged hair bundles (5 g, 20 cm) After shampooing, apply 0.5g of the sample directly, spread it evenly by hand, and then dry it in an atmosphere of 25℃ and 65%RH. After leaving it for one day and night, check the combability, smoothness, and moisture of the hair. and hair flexibility was sensory evaluated. The evaluation criteria is a three-level evaluation based on the shampoo-treated damaged hair. ◎: Very excellent. 〇: Fairly good △: Equivalent test example 1 Nine types of hair cosmetics containing various quaternary ammonium salts and/or higher alcohols were prepared,
Their performance on heat-damaged hair was tested. The results are shown in Table 1. Note that the blending amount is expressed in weight % (the same applies to other tests).
【表】【table】
【表】
表１から明らかなように、モノＣ20-22アルキル
第４級アンモニウム塩、ジ−Ｃ16-18アルキル第４
級アンモニウム塩および高級アルコールの組合せ
（実施例１）以外の化粧料（比較例１−８）は、
櫛通り性、なめらかさ、しつとり感および毛髪柔
軟性が不充分である。
試験例 ２
モノ−Ｃ20-22アルキル第４級アンモニウム塩と
ジ−Ｃ16-18アルキル第４級アンモニウム塩との重
量比を変えた５種の毛髪化粧料を調整し、それら
の熱損傷毛に対する性能について試験した。その
結果を以下の表２に示す。[Table] As is clear from Table 1, monoC 20-22 alkyl quaternary ammonium salt, di-C 16-18 alkyl quaternary ammonium salt,
Cosmetics (Comparative Examples 1-8) other than the combination of grade ammonium salt and higher alcohol (Example 1),
The combability, smoothness, moisturizing feeling and hair flexibility are insufficient. Test Example 2 Five types of hair cosmetics with different weight ratios of mono-C 20-22 alkyl quaternary ammonium salt and di-C 16-18 alkyl quaternary ammonium salt were prepared, and their heat-damaged hair was evaluated. The performance against was tested. The results are shown in Table 2 below.
【表】
表２から明らかなように、モノ−Ｃ20-22アルキ
ル第４級アンモニウム塩とジ−Ｃ16-18アルキル第
４級アンモニウム塩との重量比が1/3ないし1.5/1
のときにいずれも優れた性能を示すことがわか
る。
試験例 ３
高級アルコールの量を変化させた５種類の毛髪
化粧料を調整し、それらの熱損傷毛に対する性能
について試験した。その結果を以下の表３に示
す。[Table] As is clear from Table 2, the weight ratio of mono-C 20-22 alkyl quaternary ammonium salt to di-C 16-18 alkyl quaternary ammonium salt is 1/3 to 1.5/1.
It can be seen that both exhibit excellent performance when . Test Example 3 Five types of hair cosmetics with varying amounts of higher alcohol were prepared and tested for their performance on heat-damaged hair. The results are shown in Table 3 below.
【表】
表３から明らかなように、モノ−Ｃ20-22アルキ
ル第４級アンモニウム塩とジ−Ｃ16-18アルキル第
４級アンモニウム塩との合計量と高級アルコール
との重量比が1/6ないし1/3.5のときにいずれも優
れた性能を示すことがわかる。
試験例 ４
モノ−Ｃ20-22アルキル第４級アンモニウム塩と
ジ−Ｃ16-18アルキル第４級アンモニウム塩の重量
を変えた６種類の毛髪化粧料を調整し、それらの
熱損傷毛に対する性能について試験した。その結
果を以下の表４に示す。[Table] As is clear from Table 3, the weight ratio of the total amount of mono-C 20-22 alkyl quaternary ammonium salt and di-C 16-18 alkyl quaternary ammonium salt to the higher alcohol is 1/ It can be seen that all cases show excellent performance when the ratio is 6 to 1/3.5. Test Example 4 Six types of hair cosmetics with different weights of mono-C 20-22 alkyl quaternary ammonium salt and di-C 16-18 alkyl quaternary ammonium salt were prepared, and their performance on heat-damaged hair was evaluated. was tested. The results are shown in Table 4 below.
【表】【table】
【表】
表４から明らかなように、モノ−Ｃ20-22アルキ
ル第４級アンモニウム塩とジ−Ｃ16-18アルキル第
４級アンモニウム塩の重量がいずれも0.1ないし
３重量％の範囲内にあるときに、優れた性能を示
すことがわかる。
試験例 ５
他種類の第４級アンモニウム塩を用いて３種類
の化粧料を調整し、それらの熱損傷毛に対する性
能について試験した。その結果を表５に示す。[Table] As is clear from Table 4, the weight of the mono-C 20-22 alkyl quaternary ammonium salt and the di-C 16-18 alkyl quaternary ammonium salt is within the range of 0.1 to 3% by weight. At certain times, it can be seen that it shows excellent performance. Test Example 5 Three types of cosmetics were prepared using other types of quaternary ammonium salts, and their performance on heat-damaged hair was tested. The results are shown in Table 5.
【表】
表５から明らかなように、本発明の範囲内の毛
髪化粧料はいずれも優れた性能を示すことがわか
る。
試験例 ６
下記の表６に示す配合組成のヘアーリンス組成
物を製造し、３種類の損傷毛（ブリーチ処理毛、
アルカリ処理毛、熱損傷毛）に対する性能を試験
した。性能評価は、40℃のヘアーリンス組成物の
20％希釈液200mlに毛束（8.5ｇ、20cm）を５秒間
浸漬し、40℃の温水200mlで３秒間づつ２回すす
いで乾燥した後のものについて行なつた。[Table] As is clear from Table 5, all hair cosmetics within the scope of the present invention exhibit excellent performance. Test Example 6 A hair rinse composition having the composition shown in Table 6 below was manufactured and tested on three types of damaged hair (bleached hair,
Performance on alkali-treated hair and heat-damaged hair was tested. Performance evaluation of hair rinse composition at 40℃
A hair bundle (8.5 g, 20 cm) was immersed in 200 ml of the 20% diluted solution for 5 seconds, rinsed twice with 200 ml of 40°C warm water for 3 seconds each, and dried.
【表】
表６から明らかなように、本発明のヘアーリン
ス組成物は、従来のものよりも、損傷毛に対し優
れた櫛通り性、なめらかさ、しつとり感および毛
髪柔軟性効果を有することがわかる。
試験例 ７
下記の表７に示す配合組成のヘアークリーム組
成物を製造し、試験例６と同様の３種類の損傷毛
に対する性能を試験した。[Table] As is clear from Table 6, the hair rinse composition of the present invention has superior combability, smoothness, moisturizing feeling, and hair flexibility effects on damaged hair compared to conventional ones. I understand that. Test Example 7 A hair cream composition having the formulation shown in Table 7 below was manufactured, and its performance on three types of damaged hair similar to Test Example 6 was tested.
【表】【table】
【表】
本発明のヘアークリーム組成物は、ブリーチ処
理毛、アルカリ処理毛および熱損傷毛に対し、従
来のヘアークリームにない優れた櫛通り性、なめ
らかさ、しつとり感および毛髪柔軟性を付与する
効果を有していた。[Table] The hair cream composition of the present invention provides excellent combability, smoothness, moisturizing feeling, and hair flexibility for bleach-treated hair, alkali-treated hair, and heat-damaged hair, which are not found in conventional hair creams. It had the effect of imparting.
Claims (1)
ニウム塩0.1ないし３重量％と、下記一般式
（）で表わされる第４級アンモニウム塩0.1ない
し３重量％と、高級アルコールとを必須成分とし
て含有し、かつ（）／（）の重量比は1/8な
いし1.5/1であり、かつ（）＋（）／高級アル
コールの重量比は1/6ないし1/3.5であることを特
徴とする毛髪化粧料。 一般式（）： （式中、R1は炭素数20〜22のアルキル基、
R2，R3およびR4は炭素数１〜３のアルキル基又
はヒドロキシアルキル基、Ｘはハロゲン原子又は
アルキル基の炭素原子数が１又は２のアルキル硫
酸基を示す。） 一般式（） （式中、R5およびR6は炭素数16〜18のアルキ
ル基、R7およびR8は炭素数１〜３のアルキル基
又はヒドロキシアルキル基、Ｘはハロゲン原子又
はアルキル基の炭素数が１又は２のアルキル硫酸
基を示す。）[Scope of Claims] 1 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), 0.1 to 3% by weight of a quaternary ammonium salt represented by the following general formula (), and a higher alcohol. contains as an essential component, and the weight ratio of ()/() is 1/8 to 1.5/1, and the weight ratio of () + ()/higher alcohol is 1/6 to 1/3.5. A hair cosmetic product featuring: General formula (): (In the formula, R 1 is an alkyl group having 20 to 22 carbon atoms,
R 2 , R 3 and R 4 represent an alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms, and X represents a halogen atom or an alkyl sulfate group having 1 or 2 carbon atoms in the alkyl group. ) General formula () (In the formula, R 5 and R 6 are alkyl groups with 16 to 18 carbon atoms, R 7 and R 8 are alkyl groups with 1 to 3 carbon atoms or hydroxyalkyl groups, and X is a halogen atom or an alkyl group with 1 carbon number. or 2 alkyl sulfate group)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7317380A JPS56169614A (en) | 1980-05-31 | 1980-05-31 | Hair cosmetic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7317380A JPS56169614A (en) | 1980-05-31 | 1980-05-31 | Hair cosmetic |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56169614A JPS56169614A (en) | 1981-12-26 |
| JPS628087B2 true JPS628087B2 (en) | 1987-02-20 |
Family
ID=13510479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7317380A Granted JPS56169614A (en) | 1980-05-31 | 1980-05-31 | Hair cosmetic |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS56169614A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59110611A (en) * | 1982-12-15 | 1984-06-26 | Lion Corp | Hair cosmetic |
| JPS6019711A (en) * | 1983-07-12 | 1985-01-31 | Kao Corp | Hair rinse agent composition |
| ATE60219T1 (en) * | 1984-03-15 | 1991-02-15 | Procter & Gamble | HAIR TREATMENT AGENTS WITH CONDITIONING PROPERTIES. |
| JPH0615454B2 (en) * | 1985-06-13 | 1994-03-02 | 株式会社資生堂 | Hair cosmetics |
| JP2820329B2 (en) * | 1991-04-01 | 1998-11-05 | 株式会社資生堂 | Hair cosmetics |
| US5693317A (en) * | 1991-09-30 | 1997-12-02 | Colgate-Palmolive Company | Conditioning rinse compositions which facilitates setting of hair |
| US6149899A (en) * | 1998-08-07 | 2000-11-21 | Helene Curtis, Inc. | Opaque conditioning composition |
| JP6466678B2 (en) | 2014-10-01 | 2019-02-06 | ルネサスエレクトロニクス株式会社 | Semiconductor integrated circuit, variable gain amplifier, and sensor system |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS53118531A (en) * | 1977-03-24 | 1978-10-17 | Lion Corp | Liquid hair conditioning composition |
| US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
-
1980
- 1980-05-31 JP JP7317380A patent/JPS56169614A/en active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4144326A (en) * | 1975-05-19 | 1979-03-13 | American Cyanamid Company | Oil free, water-soluble, clear creme rinse for hair |
| JPS53118531A (en) * | 1977-03-24 | 1978-10-17 | Lion Corp | Liquid hair conditioning composition |
| JPS55108811A (en) * | 1979-02-10 | 1980-08-21 | Lion Corp | Hair-treating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS56169614A (en) | 1981-12-26 |
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