JPS6278278A - Synthetic fiber having abrasion resistance - Google Patents
Synthetic fiber having abrasion resistanceInfo
- Publication number
- JPS6278278A JPS6278278A JP60218865A JP21886585A JPS6278278A JP S6278278 A JPS6278278 A JP S6278278A JP 60218865 A JP60218865 A JP 60218865A JP 21886585 A JP21886585 A JP 21886585A JP S6278278 A JPS6278278 A JP S6278278A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- fiber
- fibers
- polyester resin
- silicone resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
皿１上二且朋分立
本発明は、耐摩耗性の優れた合成繊維、特に、釣糸、就
中側突糸に利用するのに適した耐摩耗性を有する合成繊
維に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention provides synthetic fibers with excellent abrasion resistance, particularly synthetic fibers with abrasion resistance suitable for use in fishing lines, especially side-seam lines. Regarding.
従来坐肢血
ポリエステル系樹脂から成る繊維は、耐久性、耐シワ性
等が優れていることから広く衣料用に用ぃられているが
、また、機械的強度が大きいことから従来、釣糸用とし
ても用い′られている。Fibers made from ischial blood polyester resin have been widely used for clothing due to their excellent durability and wrinkle resistance, but they have also traditionally been used for fishing lines due to their high mechanical strength. is also used.
しかしながら、ポリエステル系樹脂の繊維から構成され
た釣糸は、その使用時間が増大するに伴なって、釣竿に
おける糸通し部材との摩擦のために、屡々発熱して毛羽
立ちを生じ、その箇所から切断することがある。したが
って、上記釣糸の耐摩耗性を高める目的で従来、ポリエ
ステル系樹脂の繊維表面にオイリング処理を施すことが
行なわれていたが、未だその耐摩耗性を十分に改善する
に至っていない。However, as the fishing line made of polyester resin fibers is used for an extended period of time, it often generates heat due to friction with the threading member of the fishing rod and becomes fuzzed, causing it to break at that point. Sometimes. Therefore, in order to improve the abrasion resistance of the above-mentioned fishing line, oiling treatment has been conventionally carried out on the surface of polyester resin fibers, but the abrasion resistance has not yet been sufficiently improved.
■が”° しようとする口 占
本発明者は、釣糸として使用されるポリエステル系樹脂
の繊維から構成される糸の耐摩耗性の改善について検討
した結果、該繊維の表面にシリコン樹脂の被覆を形成す
ると、耐摩耗性及びその保持性の著しく向上した糸が得
られることの知見を得て、本発明をなすに至った。As a result of studying how to improve the abrasion resistance of threads made of polyester resin fibers used as fishing lines, the inventors discovered that the surface of the fibers should be coated with silicone resin. The present invention was based on the finding that by forming a yarn, a yarn with significantly improved abrasion resistance and retention ability can be obtained.
したがって、本発明の目的は、優れた耐摩耗性を有する
ポリエステル系樹脂から成る合成繊維、及び該合成繊維
から構成される釣糸を提供することにある。Therefore, an object of the present invention is to provide a synthetic fiber made of a polyester resin having excellent abrasion resistance, and a fishing line made of the synthetic fiber.
以下本発明の詳細な説明する。The present invention will be explained in detail below.
衾皿Ω旦症
本発明の特徴は、■ポリエステル系樹脂から成る繊維の
表面にシリコン樹脂の被覆を形成して成る合成繊維、及
び■該合成繊維から構成された釣糸にある。The present invention is characterized by (1) a synthetic fiber made of a polyester resin coated with a silicone resin, and (2) a fishing line made of the synthetic fiber.
なお、ここでいう“ポリエステル系樹脂”とは、テレフ
タル酸とエチレングリコールを主体とした重合体及びこ
れらの成分に少量のイソフタル酸、ポリブチレングライ
コール等を第三成分として用いた共重合体を包含する。In addition, "polyester resin" as used herein refers to a polymer mainly composed of terephthalic acid and ethylene glycol, and a copolymer containing these components with a small amount of isophthalic acid, polybutylene glycol, etc. as a third component. include.
。 占を１するための一
本発明では、ポリエチレンテレフタレートのようなポリ
エステル系樹脂から成る繊維の表面に、シリコン樹脂の
被覆を形成するものであって、ここで用いる繊維はモノ
フィラメント又はマルチフィラメントの適数本を適当な
デニールの繊維素線にしたものでもよく、更には、この
繊維素線を組紐に組みあげたものでもよい。. In the present invention, a coating of silicone resin is formed on the surface of a fiber made of a polyester resin such as polyethylene terephthalate, and the fiber used here is a monofilament or multifilament of an appropriate number. The book may be made into fiber strands of a suitable denier, or the fiber strands may be braided into a braid.
なお、繊維としてモノフィラメントを用いる場合は、１
００〜１０００デニールのものが好ましく、繊維素線を
用いる場合には３〜５０デニールの単糸を１５０〜８０
０デニールの集合糸にしたものが好ましい。In addition, when using monofilament as the fiber, 1
00 to 1000 denier is preferable, and when using fiber filaments, 3 to 50 denier single yarn is preferably 150 to 80 denier.
Preferably, it is made into a 0 denier bundled yarn.
これらの繊維の表面にシリコン樹脂の被覆を形成するに
は、シリコン樹脂を溶剤に溶解した溶液に繊維を浸漬な
どにより接触させて行なう。In order to form a silicone resin coating on the surface of these fibers, the fibers are brought into contact with a solution in which the silicone resin is dissolved in a solvent by immersion or the like.
ここで用いるシリコン樹脂としては、ジメチルシリコン
樹脂、高級脂肪酸変性シリコン樹脂、メチルハイドロジ
エンシリコン樹脂、メチルフェニルシリコン樹脂等を例
示し得、これらは各シリコーンオイルとして市販されて
いる。Examples of the silicone resin used here include dimethyl silicone resin, higher fatty acid-modified silicone resin, methylhydrogen silicone resin, and methylphenyl silicone resin, which are commercially available as various silicone oils.
因に、これらのシリコーンオイルは、耐寒性、耐熱性、
潤滑性、電気絶縁性、撥水性などが優れているので、主
として、電気絶縁油、潤滑油等に利用されているが、繊
維用としては撥水処理に用いられている程度である。Incidentally, these silicone oils have cold resistance, heat resistance,
Since it has excellent lubricity, electrical insulation, and water repellency, it is mainly used as electrical insulating oil, lubricating oil, etc., but it is only used for water repellent treatment for textiles.
また、上記シリコン樹脂の溶剤としては、二塩化エタン
、四塩化炭素、アセトン、メチルエチルケトン、１．１
．１−トリクロルエタン、パークロルエチレン等を例示
できる。Further, as the solvent for the silicone resin, ethane dichloride, carbon tetrachloride, acetone, methyl ethyl ketone, 1.1
．． Examples include 1-trichloroethane and perchlorethylene.
上述したようにして、シリコン樹脂の溶液に繊維を浸漬
した後、風乾すると１〜１０重量％のシリコン樹脂の被
覆が形成される。After immersing the fibers in a solution of silicone resin as described above, the fibers are air-dried to form a coating of 1-10% by weight silicone resin.
本発明では、上記シリコン樹脂の？！！！覆を形成する
に際して、繊維に予め下塗りを施してもよく、下塗りに
用いる樹脂としては、ポリエチレンテレフタレート樹脂
のようなポリエステル系樹脂、ナイロン、アクリル系樹
脂、もしくは弗化ビニリデン系樹脂を用い、二塩化エタ
ン、四塩化炭素、ア七トン、メチルエチルケトン、１．
ＬＬ）リクロルエタン、パークロルエチレン等の溶剤に
熔解したものを適用するとよい。In the present invention, the above-mentioned silicone resin ? ! ! ! When forming the cover, the fibers may be undercoated in advance, and the resin used for the undercoat is polyester resin such as polyethylene terephthalate resin, nylon, acrylic resin, or vinylidene fluoride resin, and Ethane, carbon tetrachloride, a7ton, methyl ethyl ketone, 1.
LL) It is preferable to apply a solution dissolved in a solvent such as lychloroethane or perchlorethylene.
なお、この下塗りを施すことにより、繊維とシリコン樹
脂との相互の接着性が強固となり、また、繊維を組紐と
して用いた場合には、組紐素線相互のずれが防止できる
ようになる。By applying this undercoat, the mutual adhesion between the fibers and the silicone resin becomes strong, and when the fibers are used as a braid, it becomes possible to prevent the braid strands from shifting from each other.
叙上のようにして、ポリエステル系樹脂から成る繊維の
表面にシリコン樹脂の被覆を形成すると、該繊維の耐摩
耗性が著しく向上すると共に、上記繊維もしくは下塗り
を施した繊維をシリコン樹脂の溶液に接触させた場合、
繊維又は下塗り樹脂を一部膨潤もしくは僅かに熔解させ
ることによりシリコン樹脂を強固に接着し得るので、そ
の被覆が摩擦により剥離することもなく、したがって長
時間に亘って耐摩耗性を安定に保持し得る。When a silicone resin coating is formed on the surface of a fiber made of polyester resin as described above, the abrasion resistance of the fiber is significantly improved. If you come into contact with
By partially swelling or slightly melting the fibers or undercoat resin, the silicone resin can be firmly bonded, so the coating will not peel off due to friction, and therefore its wear resistance will be stably maintained over a long period of time. obtain.
したがって、本発明による合成繊維は釣糸、特に胴突糸
の釣糸の作成に適しているのみならず、耐摩耗性が要求
されるその他の用途に供することが可能となる。Therefore, the synthetic fibers according to the present invention are not only suitable for making fishing lines, especially fishing lines such as body line, but also can be used for other uses that require wear resistance.
以下に実施例を示して本発明の効果を具体的に説明する
。EXAMPLES The effects of the present invention will be specifically explained below with reference to Examples.
発■■の−１−１とプＪ果
実施例１
市販の１０デニールのポリエチレンテレフタレートモノ
フィラメント３０本より成る繊維素線を組紐機にかけて
８打の組紐を加熱しながら２４００デニールの組紐を得
た。この組紐をメチルフェニルシリコーン樹脂（メチル
フェニルシリコーンオイル、東芝シリコーン社製ＴＳＦ
４３３）の四塩化炭素５％（−ｔ）溶液中に浸漬した
後、８０℃で２分間通風下に乾燥して溶剤を揮発させた
。Example 1 A fiber wire consisting of 30 commercially available 10-denier polyethylene terephthalate monofilaments was heated in a braiding machine to obtain an 8-stroke braid to obtain a 2400-denier braid. This braid is made of methylphenyl silicone resin (methylphenyl silicone oil, TSF manufactured by Toshiba Silicone Co., Ltd.).
433) in a 5% (-t) solution of carbon tetrachloride, and then dried at 80° C. for 2 minutes under ventilation to evaporate the solvent.
得られた組紐の表面にはメチルフェニルシリコン樹脂の
被覆が１．５％形成された。A 1.5% coating of methylphenyl silicone resin was formed on the surface of the obtained braid.
この組紐糸の耐摩耗性を試験した結果を後記表１に示す
。The results of testing the abrasion resistance of this braided thread are shown in Table 1 below.
実施例２
実施例１に記載したと同様の手順で作成した２４００デ
ニールの組紐を静止水中に３０日間浸漬した後、風乾し
た。次いで得られた組紐をポリエチレンテレフタレート
の二塩化エタンの８％（ｗｔ）溶液中に浸漬した後、８
０℃で３〜５分間熱風下に乾燥した下塗りを施した。Example 2 A 2400 denier braid made in the same manner as described in Example 1 was immersed in still water for 30 days and then air dried. The resulting braid was then immersed in an 8% (wt) solution of polyethylene terephthalate in ethane dichloride.
A dry base coat was applied under hot air for 3-5 minutes at 0°C.
この下塗りによりポリエチレンテレフタレートの２．６
Ｍ量％が被覆された。With this undercoat, 2.6% of polyethylene terephthalate
M amount% was coated.
次いで、上記下塗りを行なった組紐を、ジメチルフェニ
ルシリコーンオイルの二塩化エタンの５％（讐ｔ）溶液
中に浸漬した後、６０℃で２分間風乾して上記シリコン
樹脂の被覆を形成した。該シリコン樹脂の３，０重量％
が被覆された。Next, the undercoated braid was immersed in a 5% solution of dichloroethane in dimethylphenyl silicone oil, and then air-dried at 60° C. for 2 minutes to form a coating of the silicone resin. 3.0% by weight of the silicone resin
was coated.
次に、本発明によるポリエステル系樹脂から成る繊維の
耐摩耗性向上の効果を確認するために下記の試験を行な
った。Next, the following test was conducted to confirm the effect of improving the abrasion resistance of the fibers made of polyester resin according to the present invention.
試験方法：
試料として市販のポリエチレンテレフタレートから成る
糸を用い、ついで１ケ月間水洗処理したものの表面に、
シリコン樹脂の被覆を形成した糸を試験に供した。なお
、この水洗処理は、線糸の水中での耐久性を調べるため
と、及び市販品ではオイリング等の何かの表面処理を施
したものが少くないので、表面処理物を完全に除去する
ために行なった。Test method: A commercially available thread made of polyethylene terephthalate was used as a sample, and the surface of the thread was washed with water for one month.
The yarn coated with silicone resin was tested. This water washing treatment was carried out to check the durability of the thread in water, and to completely remove any surface treatment as many commercially available products have been subjected to some kind of surface treatment such as oiling. I went to
ついで、上記水洗処理を行なった糸の表面に実施例１に
記載したと同様の手順により、メチルフェニルシリコン
樹脂の被覆１．５％を形成して得られた糸について下記
条件での耐摩耗性試験を行ない、更に、静止水中に浸漬
し、１０日毎に６０日迄耐摩耗性試験により切断するに
至る迄の回数を測定した。Next, a 1.5% coating of methylphenyl silicone resin was formed on the surface of the thread that had been washed with water in the same manner as described in Example 1, and the abrasion resistance of the obtained thread was measured under the following conditions. The test was carried out, and the test piece was further immersed in still water, and the number of times until cutting was measured by an abrasion resistance test every 10 days up to 60 days.
また、対照として、上記シリコン樹脂の被覆を形成しな
い糸についても同様にして測定した。In addition, as a control, a yarn not coated with the silicone resin was also measured in the same manner.
結果は表１に示すとおりである。The results are shown in Table 1.
表１にみられるとおり、本発明によるシリコン樹脂の被
覆を形成したポリエステル系樹脂の繊維から成る糸の耐
摩耗性は著しく向上する。As shown in Table 1, the abrasion resistance of the yarn made of polyester resin fibers coated with silicone resin according to the present invention is significantly improved.
Claims (8)
ン樹脂の被覆を形成して成る耐摩耗性を有する合成繊維
。(1) A synthetic fiber with wear resistance, which is made by forming a coating of silicone resin on the surface of a fiber made of polyester resin.
ント又はマルチフィラメントである特許請求の範囲第（
１）項記載の合成繊維。(2) The fiber made of polyester resin is a monofilament or a multifilament.
Synthetic fibers described in section 1).
る特許請求の範囲第（１）項記載の合成繊維。(3) The synthetic fiber according to claim (1), wherein the fiber made of polyester resin is in the form of thread.
構成されたものである特許請求の範囲第（１）項記載の
合成繊維。(4) The synthetic fiber according to claim (1), wherein the fiber made of polyester resin is configured in the form of a braid.
ル系樹脂、アクリル系樹脂、ナイロン及び弗化ビニリデ
ン系樹脂から成る群から選択されるもので予め下塗りさ
れたものである特許請求の範囲第（１）項記載の合成繊
維。(5) The fibers made of polyester resin are pre-primed with a material selected from the group consisting of polyester resin, acrylic resin, nylon, and vinylidene fluoride resin. Synthetic fibers as described in section.
剤溶液と接触させることにより形成される特許請求の範
囲第（１）項記載の合成繊維。(6) The synthetic fiber according to claim (1), wherein the silicone resin coating is formed by bringing the fiber into contact with a silicone resin solvent solution.
ン樹脂の被覆を形成した合成繊維から構成された釣糸。(7) A fishing line made of synthetic fibers with a silicone resin coating formed on the surface of the fibers made of polyester resin.
の釣糸。(8) The fishing line according to claim (7), wherein the line is a body line.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60218865A JPS6278278A (en) | 1985-10-01 | 1985-10-01 | Synthetic fiber having abrasion resistance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60218865A JPS6278278A (en) | 1985-10-01 | 1985-10-01 | Synthetic fiber having abrasion resistance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6278278A true JPS6278278A (en) | 1987-04-10 |
| JPH0121272B2 JPH0121272B2 (en) | 1989-04-20 |
Family
ID=16726521
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60218865A Granted JPS6278278A (en) | 1985-10-01 | 1985-10-01 | Synthetic fiber having abrasion resistance |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6278278A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03244334A (en) * | 1990-02-21 | 1991-10-31 | Toyobo Co Ltd | Fishing-line |
| JPH0475549A (en) * | 1990-07-17 | 1992-03-10 | Toyobo Co Ltd | Fishing line for deep-sea fishing |
-
1985
- 1985-10-01 JP JP60218865A patent/JPS6278278A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03244334A (en) * | 1990-02-21 | 1991-10-31 | Toyobo Co Ltd | Fishing-line |
| JPH0475549A (en) * | 1990-07-17 | 1992-03-10 | Toyobo Co Ltd | Fishing line for deep-sea fishing |
| JP2527082B2 (en) * | 1990-07-17 | 1996-08-21 | 東洋紡績株式会社 | Deep sea fishing line |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0121272B2 (en) | 1989-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS62100968A (en) | String heater element and manufacture of the same | |
| JPH0665886A (en) | Anti-staining treatment agent for fabric for paper manufacturing | |
| CN102469838A (en) | Work glove | |
| JPS6278278A (en) | Synthetic fiber having abrasion resistance | |
| JP5536002B2 (en) | Fabric, thread or floc surface treatment method | |
| US2728692A (en) | Method of preventing shrinkage of wool | |
| US3807273A (en) | Method of making pliable, dyed and braided polyester sutures | |
| US2376813A (en) | Rope | |
| JP4614306B2 (en) | Method for producing hydrophobic finished aramid fabric and use thereof | |
| US2715616A (en) | Organic coating for wire | |
| JPS61275479A (en) | Synthetic fiber having abrasion resistance | |
| US2184600A (en) | Method of producing waterproof air transmissive fabrics for garments | |
| JP3972127B2 (en) | Metal-coated fiber body and method for producing the same | |
| US2382081A (en) | Method of treating wire for belt manufacture | |
| JPS5976983A (en) | Production of highly color developable fiber | |
| JP4258681B2 (en) | Composite spun yarn and woven / knitted fabric comprising the same | |
| JPS61100223A (en) | Production of mop code yarn prevented from fray | |
| JP2009001941A (en) | Method for shrink-proof treatment of animal fiber by hydrophobization treatment | |
| JPH0314676A (en) | Production of waterproof cloth | |
| US1856713A (en) | Lubrication of textile fibers | |
| US461272A (en) | Frank a | |
| JPH0473267A (en) | Method for water repellent treatment of synthetic fiber fabric | |
| JP2021180607A (en) | Wiring protective sleeve | |
| JP2652691B2 (en) | Durable soft finish | |
| JP2886946B2 (en) | Insulation material composed of melt anisotropic aromatic polyester fiber |