JPS62502032A - 向上した圧力スイング吸着法及びシステム - Google Patents
向上した圧力スイング吸着法及びシステムInfo
- Publication number
- JPS62502032A JPS62502032A JP61501368A JP50136886A JPS62502032A JP S62502032 A JPS62502032 A JP S62502032A JP 61501368 A JP61501368 A JP 61501368A JP 50136886 A JP50136886 A JP 50136886A JP S62502032 A JPS62502032 A JP S62502032A
- Authority
- JP
- Japan
- Prior art keywords
- pressure
- bed
- adsorption
- beds
- product
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000001179 sorption measurement Methods 0.000 title claims description 88
- 238000000034 method Methods 0.000 title claims description 74
- 239000007789 gas Substances 0.000 claims description 76
- 230000008569 process Effects 0.000 claims description 34
- 238000010926 purge Methods 0.000 claims description 27
- 239000003463 adsorbent Substances 0.000 claims description 24
- 239000011800 void material Substances 0.000 claims description 24
- 238000012546 transfer Methods 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 17
- 238000003795 desorption Methods 0.000 claims description 16
- 238000011027 product recovery Methods 0.000 claims description 14
- 238000012545 processing Methods 0.000 claims description 11
- 238000003860 storage Methods 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 5
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 230000001351 cycling effect Effects 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 238000000926 separation method Methods 0.000 description 7
- 230000008901 benefit Effects 0.000 description 6
- 230000006872 improvement Effects 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000012535 impurity Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011067 equilibration Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/50—Carbon oxides
- B01D2257/504—Carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/4003—Depressurization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40035—Equalization
- B01D2259/40041—Equalization with more than three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40064—Five
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40071—Nine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/404—Further details for adsorption processes and devices using four beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4063—Further details for adsorption processes and devices using more than four beds using seven beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4066—Further details for adsorption processes and devices using more than four beds using nine beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/406—Further details for adsorption processes and devices using more than four beds
- B01D2259/4067—Further details for adsorption processes and devices using more than four beds using ten beds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Auxiliary Devices For And Details Of Packaging Control (AREA)
- Cyclones (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Manufacture, Treatment Of Glass Fibers (AREA)
- Electrical Discharge Machining, Electrochemical Machining, And Combined Machining (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US704547 | 1985-02-22 | ||
| US06/704,547 US4650500A (en) | 1985-02-22 | 1985-02-22 | Enhanced pressure swing adsorption process and system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62502032A true JPS62502032A (ja) | 1987-08-13 |
| JPH0463726B2 JPH0463726B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-10-12 |
Family
ID=24829961
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61501368A Granted JPS62502032A (ja) | 1985-02-22 | 1986-02-21 | 向上した圧力スイング吸着法及びシステム |
Country Status (17)
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2599274B1 (fr) * | 1986-06-02 | 1988-08-26 | Air Liquide | Procede et installation de separation d'un melange gazeux par adsorption. |
| FR2633847B1 (fr) * | 1988-07-08 | 1991-04-19 | Air Liquide | Procede de traitement d'un melange gazeux par adsorption |
| US5203888A (en) * | 1990-11-23 | 1993-04-20 | Uop | Pressure swing adsorption process with multiple desorption steps |
| US5133785A (en) * | 1991-02-26 | 1992-07-28 | Air Products And Chemicals, Inc. | Separation of multicomponent gas mixtures by selective adsorption |
| US5330561A (en) * | 1992-11-16 | 1994-07-19 | Air Products And Chemicals, Inc. | Extended vacuum swing adsorption process |
| US5429664A (en) * | 1993-02-22 | 1995-07-04 | Air Products And Chemicals, Inc. | Pressure swing absorption with recycle of void space gas |
| US5370728A (en) * | 1993-09-07 | 1994-12-06 | Praxair Technology, Inc. | Single bed pressure swing adsorption system and process |
| US5433770A (en) * | 1993-12-27 | 1995-07-18 | Uop | PSA process employing a rapid depressurization step to create a disequilibrium effect |
| US5540758A (en) * | 1994-02-03 | 1996-07-30 | Air Products And Chemicals, Inc. | VSA adsorption process with feed/vacuum advance and provide purge |
| JP3309197B2 (ja) * | 1995-03-02 | 2002-07-29 | 住友精化株式会社 | 濃縮酸素の回収方法 |
| US5656065A (en) * | 1995-10-04 | 1997-08-12 | Air Products And Chemicals, Inc. | Multibed pressure swing adsorption apparatus and method for the operation thereof |
| US6210466B1 (en) * | 1999-08-10 | 2001-04-03 | Uop Llc | Very large-scale pressure swing adsorption processes |
| US6379431B1 (en) * | 2000-01-20 | 2002-04-30 | Air Products And Chemicals, Inc. | Pressure swing adsorption process with multiple beds on purge and/or with ten beds and four pressure equalization steps |
| US6565628B2 (en) | 2001-07-23 | 2003-05-20 | Air Products And Chemicals, Inc. | Pressure swing adsorption process with reduced pressure equalization time |
| US7390350B2 (en) * | 2005-04-26 | 2008-06-24 | Air Products And Chemicals, Inc. | Design and operation methods for pressure swing adsorption systems |
| US8491704B2 (en) | 2011-01-11 | 2013-07-23 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
| US8435328B2 (en) | 2011-01-11 | 2013-05-07 | Praxair Technology, Inc. | Ten bed pressure swing adsorption process operating in normal and turndown modes |
| US8496733B2 (en) | 2011-01-11 | 2013-07-30 | Praxair Technology, Inc. | Large scale pressure swing adsorption systems having process cycles operating in normal and turndown modes |
| US8551217B2 (en) | 2011-01-11 | 2013-10-08 | Praxair Technology, Inc. | Six bed pressure swing adsorption process operating in normal and turndown modes |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5259073A (en) * | 1975-11-07 | 1977-05-16 | Union Carbide Corp | Selective adsorption |
| JPS5513192A (en) * | 1978-05-27 | 1980-01-30 | Bayer Antwerpen Nv | Pressure swing adsorption method |
| JPS58146419A (ja) * | 1982-02-16 | 1983-09-01 | リンデ・アクチエンゲゼルシヤフト | サイクル作動する圧力推移式吸着装置の稼動方法 |
| JPS6011202A (ja) * | 1983-06-27 | 1985-01-21 | Nippon Denshi Zairyo Kk | 水素ガスの選択的濃縮方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3430418A (en) * | 1967-08-09 | 1969-03-04 | Union Carbide Corp | Selective adsorption process |
| US3717974A (en) * | 1968-12-30 | 1973-02-27 | Union Carbide Corp | Selective adsorption process for air separation |
| AU462688B2 (en) * | 1971-02-25 | 1975-06-01 | Union Carbide Corporation | Selective adsorption process |
| IL41351A (en) * | 1972-01-24 | 1976-01-30 | Union Carbide Corp | Selective adsorption process for air separation |
| DE2916585A1 (de) * | 1979-04-24 | 1980-11-06 | Linde Ag | Druckwechsel-adsorptionsverfahren |
| US4340398A (en) * | 1981-05-20 | 1982-07-20 | Union Carbide Corporation | Pressure swing adsorption recovery |
| US4381189A (en) * | 1981-10-27 | 1983-04-26 | Union Carbide Corporation | Pressure swing adsorption process and system |
| US4461630A (en) * | 1982-09-30 | 1984-07-24 | Union Carbide Corporation | Product recovery in pressure swing adsorption process and system |
| US4468237A (en) * | 1982-10-19 | 1984-08-28 | Union Carbide Corporation | Pressure swing adsorption with direct and indirect pressure equalizations |
| FR2534827A1 (fr) * | 1982-10-22 | 1984-04-27 | Air Liquide | Procede de traitement de gaz par adsorption comportant plusieurs adsorbeurs en phase de production simultanee |
| US4482361A (en) * | 1983-01-14 | 1984-11-13 | Union Carbide Corporation | Pressure swing adsorption process |
| US4512780A (en) * | 1983-11-08 | 1985-04-23 | Union Carbide Corporation | Pressure swing adsorption with intermediate product recovery |
-
1985
- 1985-02-22 US US06/704,547 patent/US4650500A/en not_active Expired - Lifetime
-
1986
- 1986-02-17 CA CA000502045A patent/CA1268716A/en not_active Expired - Lifetime
- 1986-02-20 EG EG85/86A patent/EG18067A/xx active
- 1986-02-21 AU AU54560/86A patent/AU578807B2/en not_active Ceased
- 1986-02-21 KR KR1019860700732A patent/KR930006398B1/ko not_active Expired - Fee Related
- 1986-02-21 CN CN86101847.8A patent/CN1004788B/zh not_active Expired
- 1986-02-21 BR BR8605491A patent/BR8605491A/pt not_active IP Right Cessation
- 1986-02-21 WO PCT/US1986/000335 patent/WO1986004831A1/en active IP Right Grant
- 1986-02-21 GR GR860499A patent/GR860499B/el unknown
- 1986-02-21 DE DE8686901648T patent/DE3676767D1/de not_active Expired - Fee Related
- 1986-02-21 IN IN148/DEL/86A patent/IN166413B/en unknown
- 1986-02-21 EP EP86901648A patent/EP0215843B1/en not_active Expired - Lifetime
- 1986-02-21 AT AT86901648T patent/ATE59793T1/de not_active IP Right Cessation
- 1986-02-21 ZA ZA861321A patent/ZA861321B/xx unknown
- 1986-02-21 JP JP61501368A patent/JPS62502032A/ja active Granted
- 1986-10-22 DK DK507086A patent/DK165223C/da not_active IP Right Cessation
-
1987
- 1987-10-08 MY MYPI87002879A patent/MY102034A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5259073A (en) * | 1975-11-07 | 1977-05-16 | Union Carbide Corp | Selective adsorption |
| JPS5513192A (en) * | 1978-05-27 | 1980-01-30 | Bayer Antwerpen Nv | Pressure swing adsorption method |
| JPS58146419A (ja) * | 1982-02-16 | 1983-09-01 | リンデ・アクチエンゲゼルシヤフト | サイクル作動する圧力推移式吸着装置の稼動方法 |
| JPS6011202A (ja) * | 1983-06-27 | 1985-01-21 | Nippon Denshi Zairyo Kk | 水素ガスの選択的濃縮方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0215843A1 (en) | 1987-04-01 |
| WO1986004831A1 (en) | 1986-08-28 |
| CN1004788B (zh) | 1989-07-19 |
| CA1268716A (en) | 1990-05-08 |
| JPH0463726B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-10-12 |
| DK507086A (da) | 1986-10-22 |
| BR8605491A (pt) | 1987-04-22 |
| DE3676767D1 (de) | 1991-02-14 |
| ZA861321B (en) | 1986-10-29 |
| ATE59793T1 (de) | 1991-01-15 |
| EP0215843B1 (en) | 1991-01-09 |
| KR930006398B1 (ko) | 1993-07-14 |
| DK165223C (da) | 1993-03-22 |
| DK507086D0 (da) | 1986-10-22 |
| MY102034A (en) | 1992-02-29 |
| GR860499B (en) | 1986-06-18 |
| IN166413B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1990-05-05 |
| EG18067A (en) | 1991-08-30 |
| AU5456086A (en) | 1986-09-10 |
| DK165223B (da) | 1992-10-26 |
| KR870700392A (ko) | 1987-12-28 |
| CN86101847A (zh) | 1986-08-20 |
| AU578807B2 (en) | 1988-11-03 |
| US4650500A (en) | 1987-03-17 |
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