JPS62500778A - solar control window film - Google Patents
solar control window filmInfo
- Publication number
- JPS62500778A JPS62500778A JP60504504A JP50450485A JPS62500778A JP S62500778 A JPS62500778 A JP S62500778A JP 60504504 A JP60504504 A JP 60504504A JP 50450485 A JP50450485 A JP 50450485A JP S62500778 A JPS62500778 A JP S62500778A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- dye
- metal
- item
- window
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims description 74
- 229910052751 metal Inorganic materials 0.000 claims description 40
- 239000002184 metal Substances 0.000 claims description 40
- 239000002131 composite material Substances 0.000 claims description 29
- 229920000642 polymer Polymers 0.000 claims description 28
- 239000000853 adhesive Substances 0.000 claims description 19
- 230000001070 adhesive effect Effects 0.000 claims description 19
- 238000002834 transmittance Methods 0.000 claims description 19
- 238000000576 coating method Methods 0.000 claims description 17
- 230000005540 biological transmission Effects 0.000 claims description 15
- 238000001771 vacuum deposition Methods 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 12
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000003475 lamination Methods 0.000 claims description 4
- 150000002739 metals Chemical class 0.000 claims description 4
- 238000004043 dyeing Methods 0.000 claims description 3
- 239000012939 laminating adhesive Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000006096 absorbing agent Substances 0.000 claims 3
- 239000010935 stainless steel Substances 0.000 claims 3
- 229910001220 stainless steel Inorganic materials 0.000 claims 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 2
- 229910000599 Cr alloy Inorganic materials 0.000 claims 2
- 229910000990 Ni alloy Inorganic materials 0.000 claims 2
- 239000011651 chromium Substances 0.000 claims 2
- 238000005304 joining Methods 0.000 claims 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 2
- 239000000788 chromium alloy Substances 0.000 claims 1
- 239000011247 coating layer Substances 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical group [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 239000000975 dye Substances 0.000 description 23
- -1 polyethylene terephthalate Polymers 0.000 description 10
- 238000001465 metallisation Methods 0.000 description 8
- 229920000728 polyester Polymers 0.000 description 7
- 239000012790 adhesive layer Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 230000004313 glare Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 4
- 239000005357 flat glass Substances 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- 229920006254 polymer film Polymers 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 229920006267 polyester film Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 238000010030 laminating Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000006120 scratch resistant coating Substances 0.000 description 2
- WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229920002799 BoPET Polymers 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000002310 reflectometry Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000011888 snacks Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
- B32B3/02—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10174—Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10165—Functional features of the laminated safety glass or glazing
- B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/20—Inorganic coating
- B32B2255/205—Metallic coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/402—Coloured
- B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/22—Nickel or cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2311/00—Metals, their alloys or their compounds
- B32B2311/30—Iron, e.g. steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2605/00—Vehicles
- B32B2605/006—Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
Landscapes
- Laminated Bodies (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 ソーラーaIIll紐坏フィルム 尺lと」=呈 1、几1と」二畳 本発明は窓のフィルムに係り、更に詳細にいえば、自動車の窓の改暦用に使用す るソーラー制御フィルムに係るものである。[Detailed description of the invention] Solar aIIll string film shakulto”=presentation 1, 1 and 2 tatami mats The present invention relates to a window film, and more specifically, the present invention relates to a window film, and more specifically, to a window film used for changing the calendar of automobile windows. This relates to a solar control film.
2、■迷Jと艮11gL皿 自動車の窓用フィルム、即ち、視線の上方では比較的に僅かの光しか通さないよ うビネット(vigncttc ;暗から明へ漸次変る)風に染色されかつ運転 者または乗客の視線の下方へ次第に澄むように変るフィルムとされた該自動車の 窓用フィルムが、最初の技術である積層した風防ガラスに使用された。これはリ アンの米国特許第2.609.2130号、第2、636.420号および第2 .639.687弓の主題であった。このフィルムは適当な染料中に所定の制御 i11時間だけ浸されることにJ:す■nから明までの勾配を生じ(以下にビネ ットど貯称する)、このフィルムがガラス板間にはさみ込まれて安全な風防が作 られた。2. ■ Mayu J and Tsui 11gL plate Automotive window films, i.e., allow relatively little light to pass through above the line of sight. Dyed and driven The vehicle has a film that gradually becomes clearer below the line of sight of the person or passenger. Window films were used in the first technology, laminated windshields. This is Ann U.S. Patent Nos. 2.609.2130, 2, 636.420 and 2 .. 639.687 It was the subject of the bow. This film is coated with suitable dyes during predetermined control. It was soaked for only 11 hours, resulting in a gradient from sun to light (below: This film is sandwiched between glass plates to create a safe windshield. It was done.
更にIυ近になって、既存の自動車窓の改装に有用な重合体フィルムが自動車の アフターマーケットとして紹介された。Furthermore, as Iυ approaches, polymeric films useful for retrofitting existing car windows will be available for use in automobiles. It was introduced as an aftermarket product.
たとえば、米国特許第3,775,226号および第3.8’ll 、 486 号において、“ウイルドロフが従来技(6の改造窓フィルムを詳細に論じ、又重 合体シー1−1蒸着アルミニウム彼覆、保護的重合体被覆および感圧被覆とを含 む典型的な従来技術のソーラー制御フィルムを記載している。この感圧被覆は、 貯蔵中でもフィルムを窓等に取り伺けている間でも粘着防止剤の存在により最初 tよ非作用にされる。ウイルドロフは湿気透過性重合体層、接着層、蒸着アルミ ニウム層および第2の湿気透過性重合体層の積層の順序を示す。アルミニウム層 を除いてこれらの層は光学的に明るく透明である。For example, U.S. Patent Nos. 3,775,226 and 3.8'll, 486 In the issue, “Wildloff discusses in detail the modified window film of the prior art (6) and also Coalescing Sea 1-1 includes vapor deposited aluminum overcoat, protective polymer coating and pressure sensitive coating. A typical prior art solar control film is described. This pressure sensitive coating is The presence of the anti-stick agent makes it difficult to remove the film even during storage and when it is removed from windows etc. t is rendered inactive. Wildloff has a moisture-permeable polymer layer, an adhesive layer, and a vapor-deposited aluminum layer. 3 shows the lamination order of the polymer layer and the second moisture-permeable polymer layer. aluminum layer These layers are optically bright and transparent except for
重合体層はテレフタル酸ポリエチレンの如きポリエステルで作られている。前記 した蒸着アルミニウム層は、重合体層上にジ羞度を制り11シて均一な金属1り 味を形成する。真空蒸着法により形成する。重合体層は厚味が /4〜1ミル( 6〜25μrrL)、好ましくは1/2ミル(13μm)である。The polymer layer is made of polyester such as polyethylene terephthalate. Said The vapor-deposited aluminum layer is then deposited on the polymer layer to form a uniform metal layer with a high degree of resistance. form taste. Formed by vacuum evaporation method. The polymer layer has a thickness of /4 to 1 mil ( 6 to 25 μrrL), preferably 1/2 mil (13 μm).
蒸着したアルミニウムは300オングストロ一ム単位を土よねらない厚味を有し ていて5〜60%の透光率を右することが特徴である。0.1〜0.3ミル(2 ,5〜8μ7+1)の厚味の好ましい接着剤の説明に進む。The vapor-deposited aluminum has a thickness that does not disturb 300 angstroms. It is characterized by a light transmittance of 5 to 60%. 0.1-0.3 mil (2 , 5 to 8μ7+1).
ウイルドロフはこの積層物として好ましい透明な重合体フィルムとしてポリエス テル、すなわら、2軸配向のテレフタル酸ポリエチレンを開示している。適当な フィルムに作れるその他の重合体にはフッ化ポリビニル、フッ化ポリビニリデン 、ポリカーボネート、ポリスチレン、ボリメヂル、メタクリレート、ポリアミド 、等のほかにエステルおよびヒルロースの温合エステルがあり、紫外線による劣 化防止安定剤し望むならば、含むこともできる。フィルムは」た実質的に低級ア ルキレン単m体からなる甲吊体の重合体、即らアクリロニトリル、ポリエチレン 、ポリプロピレンおよびポリアクリロニトリルから作ることもできる。ウイルド 【」フの特瀉第3,891,486 +=では、好ましくは染料である着色剤を 接着層に混入してもよいことを更に明示している。Wildroff uses polyester as the preferred transparent polymer film for this laminate. Discloses biaxially oriented polyethylene terephthalate. Appropriate Other polymers that can be made into films include polyvinyl fluoride and polyvinylidene fluoride. , polycarbonate, polystyrene, borimedyl, methacrylate, polyamide In addition to esters such as Antioxidant stabilizers can also be included, if desired. The film was essentially a low grade film. Polymers of the upper suspension body consisting of alkylene monomer, i.e. acrylonitrile, polyethylene , polypropylene and polyacrylonitrile. wild In ['F's special selection No. 3,891,486 +=, a coloring agent, preferably a dye, is used. It is further specified that it may be mixed into the adhesive layer.
ウイルド]]フの接着層は、熱硬化ft重合体またはアクリルをケトン及びまた (まアルコールに溶解した溶液から成形される。この溶液は、最終製品の成形に おいて、2つの」合体フィルムを重ね合わlる以前に澄んだフィルムに加えられ ることが好ましい。たとえば、ポリエステルはH1/larであり、アクリルは メタクリル酸メチル及び/又はエチルであり、ケ1−ンはメチルエチルであり、 アルコールはトルエンである。The adhesive layer of [Wild]] is made of thermosetting FT polymer or acrylic with ketone and (It is molded from a solution dissolved in alcohol. This solution is used to mold the final product.) was added to the clear film before overlapping the two combined films. It is preferable that For example, polyester is H1/lar, acrylic is methyl and/or ethyl methacrylate, the key is methylethyl, The alcohol is toluene.
1クイルドロフの米国特許第3.956.559号では、ウイルドロフのフィル ムは、すぐれた可視性を右する見栄えの良いやさしい灰色を右しており、(この 色はもしフィルムを通して見るとフィルム上のアルミニウムの天然の色であり、 フィルムをながめると、印象は鏡に似ている)と述べている。他の具体例におい て、ウイルドロフはポリエステル層は色あせた抵抗アゾ染料を含浸したテレフタ ル醇ポリエチレン層で良いと述べている。1 Quildroff, U.S. Pat. No. 3,956,559, The frame has a nice-looking soft gray color for excellent visibility (this The color is the natural color of the aluminum on the film if you look through the film; When you look at the film, the impression is that it resembles a mirror). In other specific examples The polyester layer is made of terephthalate impregnated with a fade-resistant azo dye. It is stated that a polyethylene layer is sufficient.
バーガーの米国特許第4,095,013号とウイルド0フの米ロ4特訂第3, 949.134号には粘着性接着剤を使用することが示しである。Berger's U.S. Patent No. 4,095,013 and Wild 0F's U.S.-Russian Special Edition No. 3, No. 949.134 indicates the use of a tacky adhesive.
重合体フィルム上に金属を被覆する従来技術の方法は真空被覆であったが、これ はその方法が敏速で信頼できまた安価であるためである。ある特定種の金属被覆 では一層安価であるスパッタリング方法を用いる。本出願の目的のため、スパッ タリング以外の真空被覆を従来の真空被覆と呼称する。The prior art method of coating metals onto polymeric films was vacuum coating; This is because the method is quick, reliable, and inexpensive. certain types of metal coatings In this case, a less expensive sputtering method is used. For the purpose of this application, Vacuum coating other than taring is referred to as conventional vacuum coating.
本出願人は本発明以前に本発明が公然と使用されたか、知られたか文献に記載さ れていIこかは知らない。その本発明とは、第2の重合体部を従来の真空被覆に よりFi′Q度にビネット金属化することにより重合体フィルムを染める段階と 、2つの氾合体箔を、自動車内部及び染料層に対し相対的に外方に位置決めした 金属層に積層してまぶしくない高濃度の金属化された複合体を形成する段階とよ り得られる効果を窓への使用のため教示するものである。Applicants do not believe that the invention has been used in the public domain, known or described in the literature prior to the present invention. I don't know about that. The present invention is to apply a second polymer portion to a conventional vacuum coating. dyeing the polymer film by vignette metallization to a higher Fi'Q degree; , the two flood foils were positioned outwardly relative to the interior of the vehicle and the dye layer. The step of laminating the metal layer to form a highly concentrated metallized composite that does not glare The purpose of this paper is to teach the effects that can be obtained for use in windows.
改造自動車フィルム産業においては、従来の考えでは従来の真空被覆方法により 金属化して得た複合フィルムは自動車には使用できなかった。その理由は金属化 した表面を外側に向けると自動車の外部にいる人には好ましくないまぶしさを生 じまた金属化した表面を自動車の内部に向けると車内の人に取って危険なまばゆ さすなわち鏡の効果を生じるからである。従って、まぶしさの要因を考慮して、 フィルム上の金属層の濃度を非常に低くυ1限することが必要であると考えられ た。そこで、従来技術では、自動車の内方に向いた内側には金属を非常に低い濃 度で被覆していた。In the modified automotive film industry, traditional thinking has been that traditional vacuum coating methods Composite films obtained by metallization could not be used in automobiles. The reason is metallization Surfaces facing outward can create undesirable glare for people outside the vehicle. Also, pointing a metalized surface toward the interior of a car can create a dangerous glare for people inside the car. This is because it produces a mirror effect. Therefore, considering the glare factor, It is considered necessary to limit the concentration of the metal layer on the film to a very low υ1. Ta. Therefore, in the conventional technology, metal is placed on the inside of the car at a very low concentration. It was covered with water.
従来技術の考えと構造とでは、従来重合体フィルムを効果的に真空金属化すると 、その可視光の透過に対する不透明度により金属層は許容できない程に高い反Q lll率となる。The idea and structure of conventional technology is that it is difficult to effectively vacuum metalize a conventional polymer film. , the metal layer has an unacceptably high anti-Q due to its opacity to the transmission of visible light. 1ll rate.
1981年以来、反)1率の許容値に更に制約が課せられ[v[5c20 Jに より35%以上の可視光反射率は禁止された。Since 1981, further constraints have been imposed on the permissible value of the anti)1 rate [v[5c20] Visible light reflectance of 35% or more is prohibited.
VESCは州の安全機関と会n格がハイウェイの安全にゆだねられている産業と の自発的団体である。この団体の会員はアメリカ合衆国の全州を包含しこの団体 の基準が多くの州で通常法律になっている。複合フィルムは従来の真空am技術 を使用した場合には45%以下の透過率の反射抑制面に対応するよう作ることは できない。しかしながらある場合には、外来金属をスパッタリングして成功した 。しかしながら、スパッタリングはずっと高価な方法である。VESC is a state safety agency and industry whose association is dedicated to highway safety. It is a voluntary organization of The members of this organization include all states in the United States. standards have become regular law in many states. Composite film is made using traditional vacuum AM technology When using , it is not possible to make it compatible with a reflection suppressing surface with a transmittance of 45% or less. Can not. However, in some cases, foreign metals have been successfully sputtered. . However, sputtering is a much more expensive method.
従来技術においては、たとえば、20〜30%程度の光透過10%といった。I tE常に低い光透過率と35%以下の反射率とをイエする複合フィルムを、従来 の真空金属被覆にJ:り形成することである。本発明は如何にしてこの目的を果 すかに関するものである。In the prior art, for example, the light transmission is 10%, which is about 20 to 30%. I Traditionally, composite films with consistently low light transmittance and reflectance of 35% or less The method is to form a vacuum metal coating on the surface of the metal. How does the invention achieve this objective? It is about watermelon.
−−L 使用される用語は次の如く定?iする、すなわら、「高金属濃度1は約45%以 下の光透過率と容認できないまぶしさとを意味する。--L Are the terms used defined as follows? i, that is, ``high metal concentration 1 is about 45% or more.'' Means low light transmission and unacceptable glare.
「低金属濃度」は約45%以上の光透過率を意味する。"Low metal concentration" means a light transmission of about 45% or greater.
[従来の金属の真空被覆」は抵抗および誘導真空金属化を含みスパッタリングを 除く。[Conventional Vacuum Coating of Metals] includes resistive and inductive vacuum metallization and sputtering. except.
「容認できない反射率」は約35%以上を意味する。"Unacceptable reflectance" means greater than or equal to about 35%.
[PETJはテレフタル酸ボリエブレンを意味する。[PETJ means polyethylene terephthalate.
「染料」は情況が要求しない限り一般の染料、顔料および透明な金属酸化物を含 む。"Dye" includes common dyes, pigments and transparent metal oxides unless the circumstances require. nothing.
「ビネッ1−」は厚さが大から小に漸減するか又は任意の物質の層であり、これ により昭から明までの可視効果を生IL立Ju かつ可視光の約35%以下を反射する金属を、重合体の第1の層に対し従来の真 空被覆方法により被覆し、重合体の第1の層を次いで35%以上の光透過率を右 づる第2の染色処理済重合体層に接合することにより、運転古の視線の上方個所 に35%以下の光透過値と約35%以下の反射率とをもする複合フィルムがle tられるということである。1つの好ましい具体例では、最大濃度の個所は窓の 頂部にありその濃度は視線の下方の低濃度部分までビネット風に漸減している。"Vinet 1-" is a layer of any substance whose thickness decreases from large to small; The visual effect from the Showa era to the Ming era was created by and a metal that reflects less than about 35% of visible light is added to the first layer of the polymer in a conventional manner. Coated by blank coating method, the first layer of polymer is then coated with a light transmittance of more than 35%. By bonding to the second dyed polymer layer, the upper part of the line of sight of the driver A composite film having a light transmission value of about 35% or less and a reflectance of about 35% or less is available. It means being beaten. In one preferred embodiment, the point of maximum concentration is at the window. It is located at the top and its concentration gradually decreases in a vignette style to the low concentration area below the line of sight.
更に1つの予期できない利点は、染料のきわめて有用な個所の外方に金属を位置 決めできるということであり、その個所では金属がプラスチックフィルム感光染 料の色あ、せを生じないよう保護する役目を果す。A further unexpected advantage is that the metal is located outside of the most useful areas of the dye. This means that the metal can be exposed to the plastic film at that location. It serves to protect the material from fading and fading.
従って、プラスナックフィルムを自動車の窓に改造的に応用するにおいての大き な前進が達成される。乗客の視線の上方の窓の頂部部分を通しての光の透過のビ ネットは金属層を組み込/υだ複合物を使用することにより大きく減少できる。Therefore, it is important to apply plastic snack film to automobile windows as a modification. progress is achieved. A view of the transmission of light through the top part of the window above the passenger's line of sight. The net can be greatly reduced by incorporating metal layers/using composites.
この金属層は従来の真空被覆により加えられるものでぞの複合物にしなければ許 容しデ1い反01を生じる。This metal layer is added by conventional vacuum coating and is not acceptable unless it is made into a composite material. If the value is 1, the result will be 01.
簡単にいえば、本発明はその最も広い面において、111度が高いが反射度が低 い金属の層を含む第1の!■合体フィルム層と、第1の表面に染料の被覆を有す るか染料をフィルムに含浸させた第2の重合体層と、フィルム層を積層する手段 とを提供することを意図している。染料は被覆、浸漬、スプレィおよび印刷の如 き当業界に知られた手段により付着できるが現在のところ被覆が好ましい。金属 層は従来の真空金属被覆により行なう。Simply put, the present invention has a high 111 degree angle on its widest surface, but a low reflectivity. The first one contains a layer of metal! ■Has a combined film layer and a coating of dye on the first surface means for laminating the film layer with a second polymer layer in which the film is impregnated with a dye; It is intended to provide. Dyes can be applied by coating, dipping, spraying and printing. Although it can be applied by any means known in the art, coatings are currently preferred. metal The layering is done by conventional vacuum metallization.
更に特定の1つの具体例では、本発明は染料を含浸した重合体、好ましいのはプ レフタル酸ポリエチレンの第2のシートに従来の真空被覆により接着積層した高 濃度の個所を41する金属のビネット層を支持している配向した第1のシートに 係る。In a more particular embodiment, the present invention provides dye-impregnated polymers, preferably polymers. High-quality polyethylene phthalate adhesive laminated to a second sheet of polyethylene phthalate using conventional vacuum coating. an oriented first sheet supporting a vignette layer of metal with 41 concentration points; It depends.
しかも更に特定の具体例においては、たとえば、85対15のニッケル・クロム 合金の層を従来の真空被覆により被覆したP[Tの第1のシートを染料を被覆し たPUTのフィルムに′vA層する。あるいはまたポリエステルに染料か顔料も しくはその組合わけを含浸した積層接着剤を被覆できる。接着剤には任、Q適当 な染料または顔料を使用できる。染料の例は当業界で知られ市販されている。好 ましいの【41使用時には灰色に見える非7;、に微細に粉砕したカーボンブラ ックが含浸されているポリニスデル接着剤である。Yet in even more specific embodiments, e.g. 85:15 nickel chromium A first sheet of P[T coated with a layer of alloy by conventional vacuum coating is coated with a dye. A layer of 'vA' is applied to the PUT film. Or dyes or pigments in polyester Alternatively, a lamination adhesive impregnated with the combination can be coated. Good for adhesive, Q suitable Any dye or pigment can be used. Examples of dyes are known in the art and commercially available. good Finely pulverized carbon bran (non-7), which appears gray when using [41]. The glue is impregnated with polynisdel adhesive.
積層物は、硬い被覆、すなわ)う、当業界に既に知られている種類のいづれの引 っ掻き抵抗被覆を被覆することにより仕上げられる。積層物はあらゆる周知の接 着的装着手段により自動車の窓に装着するよう準備される。The laminate may have a hard coating, i.e., any of the types already known in the art. Finished by applying a scratch resistant coating. Laminates can be used with all known connections. It is prepared to be attached to the window of a motor vehicle by means of an attached attachment means.
前記したフィルムの具体例のリベては前記に明記した数値の限界内に入り、自動 車の窓の内面に接着され、更に(自動車の内側に対し相対的に)外側の金属層と 共に染料へ位置決めされて自動車のソーラー制御窓構造体を作る。The reversal of the specific example of film described above falls within the numerical limits specified above and is automatic. Glued to the inside surface of the car window and further bonded to the outer metal layer (relative to the inside of the car) Together they are positioned to dye to create an automotive solar control window structure.
掲[lましい・、の7 な「 現在好ましい具体例の理解に役立つ図面を参照して説明する。7. The presently preferred embodiments will now be described with reference to the drawings which will be helpful in understanding them.
第1図は本発明の原理に基き作った複合物の断面図。FIG. 1 is a cross-sectional view of a composite made based on the principles of the present invention.
第2図はソーラー制御構造体を作るため自動車の窓に当てた第1図の積層物の断 面図。Figure 2 shows a section of the laminate of Figure 1 applied to a car window to create a solar control structure. Surface diagram.
第3図は第2図の構造体の変形具体例である。FIG. 3 shows a modified example of the structure shown in FIG. 2.
第1図は現在のところ好ましい本発明の1つの具体例を断面で示す。符号10は 配向したテレフタル酸ポリエチレンで作った染料含浸フィルム12に被覆した引 っ掻き抵抗被覆11を含む積層物を総体的に示す。フィルム12はこの目的に適 するよう産業界に知られたいくつかの染料のうち所望の色のものに浸ンへして作 った基体である。そのようにして染4色したフィルムはヴアージニア州マーチン スヴイルの7−ブン・ブ[]ロシング・インコーホレイテッドからUV安定化7 0%光透過グレイとして販売している。このマーチンフィルムは染料を全体に含 浸した浸漬フィルムである。FIG. 1 shows, in cross-section, one presently preferred embodiment of the invention. The code 10 is A dye-impregnated film 12 made of oriented polyethylene terephthalate is coated with a dye-impregnated film 12. A laminate including a scratch resistant coating 11 is generally shown. Film 12 is suitable for this purpose. It is made by soaking it in the desired color of several dyes known to the industry to It is a basic body. The film, which was dyed in four colors in this way, was produced in Martin, Virginia. UV Stabilized 7 from Svir's 7-Bun Bu[] Losing Incoholated It is sold as 0% light transmission gray. This Martin film contains dye throughout. It is a soaked film.
[−1−シフ6R36積接着層層14の 01ミル(2,5μm)の層が染色し たポリエステルフィルム層12を48ゲージテレフタル酎の層18に接合し、こ の層には従来の真空被覆により±20オングストローム変化できる約140オン ゲス1−ロームの当初の厚味がHli減するニッケル・クロム合金のビネッ1一 層16が被覆されている。、驚いたことに、安定化層16の好ましくない可視光 に対するバリヤどしての効果は金属の1度とIIン味とに対し予想される好まし くない高い可視光反射もなく保持される。[-1-01 mil (2.5 μm) layer of Schiff 6R36 laminated adhesive layer 14 is dyed. The polyester film layer 12 is bonded to the 48 gauge terephthalate layer 18. The layer contains about 140 Å, which can vary by ±20 Å using conventional vacuum coating. Guess 1 - Vinet 11 of a nickel-chromium alloy whose initial thickness of ROHM is reduced by Hli Layer 16 is coated. , surprisingly, the undesirable visible light of the stabilizing layer 16 The effect as a barrier on metallic No high visible light reflection and no retention.
金属化に現在のところ好ましい■合体フィルムはイムベリアル・ケミカル・カン バニイが商1 [1cI−4221の下にまたアメリカン・ホイヂエスが商45 「l1ostaphan 5000Jの下に販売している。重合体フィルムを 染色し金属化する方法と、それに適した染F1および金属と、フィルムをフィル ムに接合する接着剤その他の手段と、フィルムを窓ガラスにHfflりることと はすべて当業界に周知であり、それら要素自体は本発明として権利を要求するも のでない。しかし、それら要素と本出願に記載し権利を要求した他の要素と組み 合わせた6のが本発明を構成づるものであり、従って本発明はその全体として考 察されるものである。The currently preferred coalescing film for metallization is Imbellial Chemical Can. Bunny is quotient 1 [under 1cI-4221, American Hoygies is quotient 45 "l1ostaphan" is sold under 5000J.Polymer film Dyeing and metallizing method, suitable dye F1 and metal, and film filter Adhesive or other means of bonding the film to the window glass and are all well known in the art, and the elements themselves may not be claimed as invention. It's not. However, the combination of those elements with other elements described and claimed in this application The six elements in total constitute the present invention, and therefore the present invention should not be considered as a whole. It is something that can be observed.
層12.48を接合するのに現在のところ好ましい積層接着剤はデュポン社が商 標rEDlam jの下にまたモートン・ケミカル・カンパニイが商品番号r 7611−3GJの下に製造しているポリエステル樹脂である。The currently preferred laminating adhesive for bonding layers 12.48 is commercially available from DuPont. Under the mark rEDlam, there is also the product number r of Morton Chemical Company. It is a polyester resin manufactured under the trade name 7611-3GJ.
フィルム18は積層物10が自動車の窓ガラス24に8着する用意ができるまで は解放ライナー22により保護される。積層物10を窓ガラスに装着する際に解 放ライナー22をはがし積層物10を0.25ミル(6μmrL)厚味の接着層 20によりガラス24に装着する。アクリルまたはポリエステル樹IIFi系の いづれかを装着接着剤として使用できる。現在のところ好ましい樹脂は[Na口 ona180−1057Jである。別の有用な接着剤は■ンリ“ントの[R^− 11591である。The film 18 is applied until the laminate 10 is ready to be applied to the automobile window glass 24. is protected by a release liner 22. When attaching the laminate 10 to the window glass, Peel off the release liner 22 and attach the laminate 10 to a 0.25 mil (6 μm rL) thick adhesive layer. 20 is attached to the glass 24. Acrylic or polyester wood IIFi type Either can be used as a mounting adhesive. At present, the preferred resin is [Na- ona180-1057J. Another useful adhesive is the adhesive [R^- It is 11591.
第2図を見れば、この図には解放ライナー22が取り除かれ積層物10が接着ト 1η20により窓ガラス24に接着して示しである。Turning to FIG. 2, this figure shows that the release liner 22 has been removed and the laminate 10 has been removed from the adhesive tape. It is shown bonded to the window glass 24 by 1η20.
1つの変形具体例では、使用する接着剤に適当でそれに融和づる油に溶解する任 意の染料を接着剤14に混入できる。In one alternative embodiment, an oil-soluble agent suitable for and compatible with the adhesive used is used. Any dye can be mixed into the adhesive 14.
この変形具体例では、染色した接着剤が染色石化を行うのでフィルム自体を染色 する必要tまない。第3図を見れば、小合体フィルム12の層に染料を含浸させ ずに染v1が積層接着剤i48に分散されていることが判る。第3図の変形具体 例では、染料を含浸した接着層14aを重合体層12にHayer捧のグラビア シリンダにより被覆する。In this modified example, the dyed adhesive performs dye petrification, so the film itself is dyed. There's no need to. Referring to FIG. It can be seen that the dye v1 is dispersed in the lamination adhesive i48. Modification of Figure 3 In the example, a dye-impregnated adhesive layer 14a is attached to the polymer layer 12 using a gravure film dedicated to Hayer. Cover with cylinder.
すべての複合フィルムに対する金属層の好ましい具体例が第3図に示しである。A preferred embodiment of the metal layer for all composite films is shown in FIG.
金属層[a 1.を高濃度の個所113bから低濃度の個所に向【)薄くなって いてビネツ1〜効果を生じ第2図と第3図とにおいて共に、矢印は自動車の外側 に向いている。フィルムを内側にHfiし、また図面から判るように、金属を染 色したフィルム12に相対的に外側に8着する 現在のところ好ましい具体例を装造づる際に、ヴアージニア州マーナンスヴイル のマーチン・ブ]]セシング・インコーホレイテッド製の92ないし48ゲージ の染色したP[170%光透過率フィルムのロールである染色処理した層12を 硬化し/、=Aルガノボリシロキリン化合物の如き引っ掻きおよび摩耗抵抗プラ スチック材の被覆Jイ【わら居11を約4ミク[1ン(μm)厚味にして硬く被 覆した。Metal layer [a1. becomes thinner from the high concentration area 113b to the low concentration area. In both Figures 2 and 3, the arrow points to the outside of the car. suitable for Hfi the film inside and dye the metal as you can see from the drawing. 8 pieces on the outside relative to the colored film 12 In constructing the presently preferred embodiment, [Martin Bu]] 92 or 48 gauge manufactured by Sessing Incorporated The dyed layer 12, which is a roll of dyed P [170% light transmittance film] harden/,=A scratch and abrasion resistant plastics such as Luganoborisiloquiline compounds. Covering of stick material Overturned.
未処理の48ゲージP[Tの第2のロールをイムベリアル・グミカル・カンパニ イから入手す゛る。このフィルムは製造業名はrlci 4424と名称をイ] シである。この48ゲージロールを次いで当業界に知られている従来の真空被覆 、ずなわら、通常の方法による誘導および抵抗金属化により片面をニックルーク ロムのビネットを設けて準備する。A second roll of untreated 48 gauge P [T Get it from here. The manufacturing name of this film is RLCI 4424. It is shi. This 48 gauge roll was then coated using conventional vacuum coating techniques known in the art. , Zunawara, one side nick-lucked by inductive and resistive metallization by conventional methods Prepare by setting up a vignette of the ROM.
ポリエステルフィルムを13から明に変化するバンドに金属化し、このバンドを 後に切断して所望のビネットにする。The polyester film is metallized into a band that changes from 13 to light, and this band is It is then cut to create the desired vignette.
たとえば、中心の最も暗い部分を5インf(127tywt>の領域にわたり約 35%の光透過率にしていづれかの側を100%光透過率になるよう薄くしてビ ネットにする。バンドを合わせた幅はほぼ10インチ(254am)である。金 属化したフィルムを次に均一に70%の透過率を有する染料を含浸したテレフタ ル酸ポリエチレンフィルムに積層する。種々の光透過濃度にケるため同じ濃度の 種々の型組の被覆を行うため可変の蝕刻したグラビアシリンダを使用して顔料の 濃度を一定に保ちつつ顔料入り接着剤の厚味を変えることができる。For example, the darkest part of the center is approximately Make it 35% light transmittance and thin one side to 100% light transmittance. Make it online. The combined width of the bands is approximately 10 inches (254 am). Money The coated film is then uniformly impregnated with a dye with a transmittance of 70%. laminated to polyethylene film. To accommodate various light transmission densities, Pigment coating using variable etched gravure cylinders for coating various molds. The thickness of the pigmented adhesive can be varied while keeping the concentration constant.
着色した接着剤の値は最ら0nいバンドでの50%の光透過率から約10インチ (254gm)のバンド幅における70%の光透過率にまで瀬滅する。Colored adhesive values are approximately 10 inches from 50% light transmission in the narrowest band. The light transmission decreases to 70% at a bandwidth of (254 gm).
積層接着剤が変形具体例では色を含むかもしれないことを理解してその結果とし て得られた金属化し染色したフィルムが積層される。次に解放ライナーを有する 装着接着剤を被覆り−る。次に、仕上げた複合物を中心で切断して旧都から底部 にまで(切断時に中心から側部に)所定の所望の光透過勾配の2本のロールを形 成する。典型的には40インチ(1016m+)幅の重合体複合シートを5イン チ(127g+)の中心にお【プる平均光透過率が許容幅が10%〜30%の節 回で望ましくは約22%であるバンドで金属化し、しかも両側の1/2インチ( 1,3aa )において中心から外側にまで約20〜70%で勾配を有しかつこ の外側を越えて約70%であるバンドで金属化する。ロールは、フィルムが視線 上方の窓の暗部を覆う部分に位置決め′Cきるよう自動車の窓から切取られVJ 所される。運転者の視線の下方のフィルム個所は10%の光透過率を有する。ロ ールから余分の幅部分を捨てる。As a result, it is understood that the laminating adhesive may contain color in modified embodiments. The resulting metallized and dyed films are then laminated. then has a release liner Cover with mounting adhesive. Next, cut the finished composite down the center and remove the bottom part from the old capital. Shape the two rolls with a given desired light transmission gradient (from the center to the sides when cutting) until to be accomplished. Typically 5 inches of 40 inch (1016 m+) wide polymer composite sheet (127g+) A node with an allowable range of average light transmittance of 10% to 30% metallized with a band that is preferably about 22% thick and 1/2 inch ( 1.3aa) has a slope of about 20 to 70% from the center to the outside. metallize with a band that is about 70% beyond the outside of the metallization. roll, film is line of sight VJ is cut out from a car window so that it can be positioned in the part that covers the dark part of the upper window. be placed. The area of the film below the driver's line of sight has a light transmission of 10%. B Discard the extra width from the roll.
火−一五一−3 48番ゲージのIcI 442ポリエステルフイルムを、中心における最も暗い 部分を35%の光透過率としかつ5インチ(127,M)の領域にわたり両側が 100%の透過率となるよう両側り向へごネットにした昭いバンドにおいて、8 5対15の組成比のニッケル・り1コム合金により金属化した。仝体幅はほぼ1 0インチであった。マーチン・プロはシンク・インコーホレイテッドから入手し た70%透過率を右する均一に染料を含浸した48ゲージのテレフタル酸ポリエ チレンフィルムにグラビヤ被覆により4ミクロン(μ仇)厚味の硬い被覆を施し た。Tue-151-3 48 gauge IcI 442 polyester film at the darkest point in the center The section has a light transmission of 35% and covers an area of 5 inches (127, M) on both sides. In a thin band with nets on both sides to achieve 100% transmittance, 8 It was metallized with a nickel-RI1com alloy with a composition ratio of 5:15. Body width is approximately 1 It was 0 inches. Martin Pro is available from Think Incorporated. Uniformly dye impregnated 48 gauge terephthalate polyester with 70% transmittance A 4 micron (μ) thick hard coating is applied to the tyrene film using gravure coating. Ta.
次にこれら2つのフィルムを豆いに積層して外面の1つに硬いフィルムを位置さ せて150ゲージの複合物を形成した。硬くなく被覆した表面を次に珪素被覆し た側を接着剤に向けて保護的珪素ライナーに組み合わU゛た感圧的装着1に着剤 で被覆した。These two films are then laminated into a bean, with the hard film placed on one of the outer surfaces. A 150 gauge composite was formed. The non-hard coated surface is then silicon coated. Attach pressure sensitive attachment 1 to the protective silicone liner with the opposite side facing the adhesive. coated with.
次に、複合物全体を半分に削りそれによりバンドの中心でつ1ブを分前した。同 時に両縁部を切りそろえて1つの縁部にビネットを右する20インチ(510I l!R)の仕上げ製品をとが予想される。The entire composite was then cut in half, thereby cutting off one piece in the center of the band. same 20 inches (510I) with both edges trimmed and vignette right on one edge. l! R) is expected to produce a finished product.
国際調査報告international search report
Claims (23)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US65533684A | 1984-09-27 | 1984-09-27 | |
US655336 | 1984-09-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS62500778A true JPS62500778A (en) | 1987-04-02 |
Family
ID=24628480
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60504504A Pending JPS62500778A (en) | 1984-09-27 | 1985-09-25 | solar control window film |
Country Status (4)
Country | Link |
---|---|
JP (1) | JPS62500778A (en) |
KR (1) | KR870700503A (en) |
GB (1) | GB2176148B (en) |
WO (1) | WO1986002038A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0353677B1 (en) * | 1988-08-04 | 1995-04-05 | LINTEC Corporation | A plastics plate and an adhesive film therefor |
US5189551A (en) * | 1989-07-27 | 1993-02-23 | Monsanto Company | Solar screening film for a vehicle windshield |
KR100310163B1 (en) * | 1995-06-15 | 2001-12-28 | 구광시 | Control film for sun light |
US5693415A (en) * | 1995-06-21 | 1997-12-02 | Hanita Coatings | Composite film for windows comprising a non-stoichiometric aluminum oxide layer |
AUPN871296A0 (en) * | 1996-03-15 | 1996-04-18 | Sola International Holdings Ltd | Multicoat for light transmitting articles |
KR100419781B1 (en) * | 2001-03-09 | 2004-02-21 | 주식회사 엘지화학 | Shading Film for the Roll-Type Shading Screen to Be Hung at Indoor Windows and the Method of Manufacturing thereof |
FR2897694B1 (en) * | 2006-02-23 | 2008-05-16 | Essilor Int | METHOD FOR PRODUCING A POLARIZING OPTICAL ELEMENT |
US7550193B2 (en) | 2006-05-05 | 2009-06-23 | Nanofilm Ltd | Infrared radiation blocking laminate |
US20080020201A1 (en) * | 2006-07-20 | 2008-01-24 | Lisa Yvonne Winckler | Composite, Color Corrected Films Comprising an Aluminum Oxide Coating |
WO2008011546A2 (en) * | 2006-07-20 | 2008-01-24 | Cpfilms Inc. | Solar control polymer films comprising an aluminum oxide coating |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3499697A (en) * | 1965-01-04 | 1970-03-10 | Monsanto Co | Pellucid laminate with interference filter multilayer and monolayer |
US3956559A (en) * | 1972-03-16 | 1976-05-11 | Material Distributors Corporation | Solar control safety window |
US3949134A (en) * | 1973-07-18 | 1976-04-06 | Material Distributors Corporation | Solar control film for use by consumers and the like |
US4247599A (en) * | 1978-12-26 | 1981-01-27 | Insulating Shade | Composite sheet material having low emittance characteristics |
US4226910A (en) * | 1979-07-12 | 1980-10-07 | Minnesota Mining And Manufacturing Company | Energy control sheet having insulative properties |
-
1985
- 1985-09-25 GB GB08612139A patent/GB2176148B/en not_active Expired
- 1985-09-25 WO PCT/US1985/001844 patent/WO1986002038A1/en active Application Filing
- 1985-09-25 JP JP60504504A patent/JPS62500778A/en active Pending
-
1986
- 1986-05-27 KR KR1019860700307A patent/KR870700503A/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO1986002038A1 (en) | 1986-04-10 |
KR870700503A (en) | 1987-12-29 |
GB8612139D0 (en) | 1986-06-25 |
GB2176148B (en) | 1988-10-26 |
GB2176148A (en) | 1986-12-17 |
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