JPS6234355B2 - - Google Patents
Info
- Publication number
- JPS6234355B2 JPS6234355B2 JP4513682A JP4513682A JPS6234355B2 JP S6234355 B2 JPS6234355 B2 JP S6234355B2 JP 4513682 A JP4513682 A JP 4513682A JP 4513682 A JP4513682 A JP 4513682A JP S6234355 B2 JPS6234355 B2 JP S6234355B2
- Authority
- JP
- Japan
- Prior art keywords
- base
- paint
- water
- base paint
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003973 paint Substances 0.000 claims description 25
- 239000000919 ceramic Substances 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 10
- 239000002002 slurry Substances 0.000 claims description 8
- 229920001296 polysiloxane Polymers 0.000 claims description 7
- 239000002518 antifoaming agent Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims 1
- 238000010304 firing Methods 0.000 description 7
- 238000004040 coloring Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000005034 decoration Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 235000019738 Limestone Nutrition 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000010433 feldspar Substances 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- -1 glaze Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000989 no adverse effect Toxicity 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Description
【発明の詳細な説明】
本発明は陶磁器の彩飾に用いる釉下着色用の下
絵具調合液に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a base paint preparation for underglaze colors used in the decoration of ceramics.
周知のように従来では陶磁器素地に絵筆や刷毛
等で下絵具を色ムラが生じないよう均一に塗布す
ることが極めて困難であつた。これは乾燥した陶
磁器素地への絵具の吸着侵透が極めて速いことか
ら絵具を塗布している作業中の前後でもその塗布
部に濃淡の差が生じて色ムラを生じるためであ
る。この濃淡の差を無くそうと重ね塗りをした場
合にも第１図のように先に吸着した塗布部と後で
重ね塗りした塗布部とが同一に混じり合わないた
めやはり濃淡の差を解消できないものであつた。
このため施釉焼成して得られた製品の彩飾具合は
発色の濃淡を生じて不均一な着色を露呈していた
のである。そこで近時、絵具の素地面への侵透吸
着速度を遅延させ、重ね塗りを施しても先の塗布
部と後の塗布部の絵具が混じり合い均一な塗布状
態とする方法も開発されているが彩飾までの工程
に手間がかかる問題点があつた。 As is well known, in the past, it has been extremely difficult to uniformly apply base paint to a ceramic base using a paintbrush, brush, etc. without causing color unevenness. This is because the paint adsorbs and penetrates into the dried ceramic base extremely quickly, which causes a difference in shading between the parts before and after the paint is applied, resulting in color unevenness. Even if you apply multiple coats to eliminate this difference in shading, as shown in Figure 1, the applied area that was attracted first and the applied area that was overcoated later do not mix in the same way, so the difference in shading cannot be eliminated. It was hot.
For this reason, the decoration of products obtained by glazing and firing resulted in uneven coloring and uneven coloring. Therefore, a method has recently been developed that slows down the rate at which paint penetrates and adsorbs onto the base surface, so that even if multiple coats are applied, the paint in the first and second coated areas will mix and become evenly coated. However, there was a problem in that the process up to the decoration process was time-consuming.
本発明は上記した欠点をきわめて簡易且つ有効
に改良することを目的とし、これに成功したもの
であつて、本発明をまずその要旨について説明す
ると次の通りである。 The present invention aims to improve the above-mentioned drawbacks in a very simple and effective manner, and has succeeded in this purpose.First, the gist of the present invention will be explained as follows.
即ち、本発明は陶磁器素地に彩飾塗布して用
い、焼成して陶磁器を彩飾するものにおいて、水
溶性の下絵具と、水溶性シリコンエマルジヨン型
の消泡剤と、透明或いは薄着色の釉薬と、陶磁器
の素地を成形する素地用泥漿とを混合撹拌してこ
れを主成分とすることを要旨とする陶磁器彩飾に
用いる下絵具調合液である。 That is, the present invention is used to decorate a ceramic base by coating it and firing it to decorate the ceramic. This is a base paint mixture used for decorating ceramics, which is made by mixing and stirring a base slurry for molding ceramic bases and using this as the main component.
上記した本発明の要旨において水溶性シリコン
エマルジヨン型の消泡剤、釉薬、素地用泥漿を水
溶性の下絵具と混合して製品としたのは次のよう
な作用効果を生ずるからである。 In the above-mentioned gist of the present invention, the reason why a water-soluble silicone emulsion type antifoaming agent, glaze, and base slurry are mixed with a water-soluble base paint to form a product is that the following effects are produced.
(1) まず水溶性シリコンエマルジヨン型の消泡剤
を用いたのは、塗布した時に生ずる泡を消去す
ることはもちろん、下絵具の素地への吸着侵透
を遅くできて塗布し易いと共に重ね塗りができ
て均一な塗布層を形成するためであり、また焼
成により陶磁器の構成成分と同一のシリカ
（SiO2）となるため製品への悪影響がないこと
である。(1) First, we used a water-soluble silicone emulsion-type antifoaming agent, which not only eliminates the bubbles that occur when it is applied, but also slows down the adsorption and penetration of the base paint into the base, making it easier to apply and layering. This is because it can be coated to form a uniform coating layer, and because it becomes silica (SiO 2 ), which is the same component of ceramics, when fired, there is no adverse effect on the product.
(2) 次に釉薬を添加する効果は下絵具の発色を良
好にすることであり、これにより陶磁器本体と
後で施釉焼成して得られる表面の透明釉との間
に下絵具の発色層を形成して雅趣豊かな色彩を
露呈できることになるのである。(2) Next, the effect of adding a glaze is to improve the coloring of the underpainting, which creates a coloring layer of the underpainting between the ceramic body and the transparent glaze on the surface obtained by applying the glaze and firing it later. As a result, it can be formed to reveal elegant colors.
(3) さらに陶磁器の素地用泥漿を添加したのは塗
布乾燥後の素焼きによりその下絵具の塗布層を
陶磁器素地に安定接着させる効果があり、これ
により該塗布層が素地表面から剥落することが
ないのである。このため該素焼き品の取扱い及
び次の施釉焼成の工程が円滑にできる利点も生
ずる。なおこの素地用泥漿は陶磁器本体を構成
するものと同質なものであり焼成後の製品につ
き何ら支障がないものである。(3) Furthermore, the addition of slurry for ceramic bases has the effect of stably adhering the coated layer of the base paint to the ceramic base by unglazing after coating and drying, thereby preventing the coated layer from peeling off from the base surface. There isn't. Therefore, there is an advantage that the handling of the unglazed product and the subsequent glazing and firing process can be carried out smoothly. It should be noted that this slurry for the base material is of the same quality as that constituting the main body of the ceramic, and will not cause any problems with the product after firing.
上記した本発明の要旨を更に明白にすると共に
本発明の構成と効果を具体的に説明するため、本
発明の実施例を次に詳述する。 EXAMPLES In order to further clarify the gist of the present invention described above and specifically explain the configuration and effects of the present invention, examples of the present invention will be described in detail below.
実施例
(イ) 600c.c.の水溶性に下絵具としての塩化コバル
ト（CoCl2）22gを溶いた下絵具溶液
(ロ) シリコンエマルジヨン型の消泡剤として有効
成分16％の塗装用の水溶性シリコンエマルジヨ
ン型白色乳濁液（会社商品名、信越化学工業株
式会社、信越シリコーンKM85）
(ハ) 透明釉として、重量割合で長石44.5％、珪石
26.8％、石灰石17.5％、蛙目11.2％を混合して
湿式粉砕し、水分62％に調整し180メツシユを
通した混合液
(ニ) 素地用泥漿として、重量割合で天草陶石40
％、長石28％、粘土25％、カオリン７％を湿式
粉砕し水分33％に調整し180節目を通した泥漿
そして上記の下絵具溶液100c.c.、消泡剤溶液100
c.c.、釉薬80c.c.、素地用泥漿20c.c.の割合で混合撹拌
して本例の下絵具調合液を得るのである。Example (a) A base paint solution prepared by dissolving 22 g of cobalt chloride (CoCl 2 ) as a base paint in 600 c.c. water-soluble base paint (b) A silicone emulsion type antifoaming agent for painting with an active ingredient of 16%. Water-soluble silicone emulsion type white emulsion (company product name, Shin-Etsu Chemical Co., Ltd., Shin-Etsu Silicone KM85) (c) As a transparent glaze, feldspar 44.5% by weight, silica stone
26.8% of limestone, 17.5% of limestone, and 11.2% of Frogmite were wet-pulverized, the moisture content was adjusted to 62%, and the mixture was passed through a 180 mesh (d) Amakusa pottery stone 40% by weight as slurry for the base material.
%, 28% feldspar, 25% clay, and 7% kaolin are wet-milled and adjusted to a moisture content of 33%, and the slurry is passed through 180 knots, and the above base color solution is 100 c.c., and the antifoaming agent solution is 100 ml.
cc., 80 c.c. of glaze, and 20 c.c. of base slurry are mixed and stirred to obtain the base paint mixture of this example.
本例の下絵具調合液Ｓを用いて乾燥した陶磁器
素地１の表面に刷毛等で塗布すると、その吸着侵
透速度が遅延し泡を生ずることなく色ムラの発生
もなく均一に塗布できる（第２図参照）ことが確
認され、その塗布作業が円滑にできたのである。
そしてこれを塗布後、乾燥し800℃で素焼きを行
ない、ついで透明釉２を施釉して1280℃で本焼成
を行なつて陶磁器製品を得た（第３図参照）。以
上のようにすると該陶磁器製品の下絵具による彩
飾が濃淡の色ムラを生ずることなく雅趣豊かなコ
バルトブルーの色彩となつたのである。 When the base paint mixture S of this example is applied with a brush or the like to the surface of the dried ceramic base 1, the rate of adsorption and penetration is delayed, and the paint can be applied uniformly without forming bubbles or uneven coloring. (See Figure 2), and the application process was completed smoothly.
After applying this, it was dried and bisque fired at 800°C, then transparent glaze 2 was applied and main firing was performed at 1280°C to obtain a ceramic product (see Figure 3). By doing the above, the decoration of the ceramic product with the underpainting paint became an elegant cobalt blue color without causing any unevenness in shading.
なお本発明は上記の実施例に限定されるもので
はなく、上記した作用効果の達成される範囲内に
おいて夫々適当に定められてよいものである。例
えば水溶性の下絵具としてはニツケル、マンガ
ン、クローム等の塩化物又は硝酸物等適宜に用い
ることができる。また下絵具調合液の夫々の混合
割合も任意に調合できるのである。 It should be noted that the present invention is not limited to the above-mentioned embodiments, but may be appropriately determined within the range in which the above-mentioned effects can be achieved. For example, as the water-soluble base paint, chlorides or nitrates of nickel, manganese, chrome, etc. can be used as appropriate. Furthermore, the mixing ratio of each of the base paint preparations can be adjusted as desired.
上述の説明によつて明白となるように、本発明
によれば素地への塗布が極めて容易にできると共
に塗布層を安全配置できしかも色ムラのないよう
発色彩飾できるのでこれによりもたらされる実益
は大きいといえる。 As will become clear from the above description, the present invention makes it possible to apply the coating to the substrate extremely easily, safely arrange the coated layer, and to decorate with color without unevenness, so that the practical benefits brought about by this are: It can be said that it is large.
第１図は従来の下絵具を素地面に塗布した後施
釉焼成した陶磁器製品の縦断面図、第２図は本発
明の下絵具調合液を素地に塗布した状態の縦断面
図、第３図はそれに施釉焼成した陶磁器製品の縦
断面図である。
１：素地、２：透明釉、Ｓ：下絵具調合液。
Figure 1 is a vertical cross-sectional view of a ceramic product prepared by applying a conventional base paint to the base surface and then glazing and firing it. Figure 2 is a vertical cross-sectional view of a ceramic product with the base paint mixture of the present invention applied to the base surface. Figure 3 is a vertical cross-sectional view of a ceramic product that has been glazed and fired. 1: Base, 2: Transparent glaze, S: Base paint mixture.
Claims (1)
磁器を彩飾するものにおいて、水溶性の下絵具
と、水溶性シリコンエマルジヨン型の消泡剤と、
透明或いは薄着色の釉薬と、陶磁器の素地を成形
する素地用泥漿とを混合撹拌してこれを主成分と
することを特徴とする陶磁器彩飾に用いる下絵具
調合液。1. A water-soluble base paint, a water-soluble silicone emulsion-type antifoaming agent, and a water-soluble base paint, a water-soluble silicone emulsion-type antifoaming agent, and the like.
A base paint mixture for use in decorating ceramics characterized by mixing and stirring a transparent or lightly colored glaze and a base slurry for shaping the base of ceramics, and using the mixture as a main component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4513682A JPS58162679A (en) | 1982-03-20 | 1982-03-20 | Blended solution for underglaze color useful for illuminating ceramic ware |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4513682A JPS58162679A (en) | 1982-03-20 | 1982-03-20 | Blended solution for underglaze color useful for illuminating ceramic ware |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58162679A JPS58162679A (en) | 1983-09-27 |
| JPS6234355B2 true JPS6234355B2 (en) | 1987-07-27 |
Family
ID=12710858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4513682A Granted JPS58162679A (en) | 1982-03-20 | 1982-03-20 | Blended solution for underglaze color useful for illuminating ceramic ware |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58162679A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0564751U (en) * | 1992-02-04 | 1993-08-27 | 帝人製機株式会社 | Indicator plug |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMO20060245A1 (en) * | 2006-07-31 | 2008-02-01 | Iniziativa Otto S R L | PROCEDURE FOR THE CONSTRUCTION OF CONSTRUCTION LINING MANUFACTURERS, IN PARTICULAR TILES AND / OR SIMILAR, AND A MANUFACTURED BY MEANS OF THIS PROCEDURE. |
| KR101306586B1 (en) * | 2012-02-29 | 2013-09-10 | 한국세라믹기술원 | Manufacturing method of underglaze pigment |
| CN111268910A (en) * | 2018-12-05 | 2020-06-12 | 福建省佳圣轩工艺品有限公司 | Zinc-free transparent glaze for porcelain tableware and manufacturing method thereof |
-
1982
- 1982-03-20 JP JP4513682A patent/JPS58162679A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0564751U (en) * | 1992-02-04 | 1993-08-27 | 帝人製機株式会社 | Indicator plug |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58162679A (en) | 1983-09-27 |
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