JPS6229245Y2 - - Google Patents
Info
- Publication number
- JPS6229245Y2 JPS6229245Y2 JP2942183U JP2942183U JPS6229245Y2 JP S6229245 Y2 JPS6229245 Y2 JP S6229245Y2 JP 2942183 U JP2942183 U JP 2942183U JP 2942183 U JP2942183 U JP 2942183U JP S6229245 Y2 JPS6229245 Y2 JP S6229245Y2
- Authority
- JP
- Japan
- Prior art keywords
- ink
- resin
- printed
- printing
- paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000005871 repellent Substances 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 10
- 238000007639 printing Methods 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 230000002940 repellent Effects 0.000 claims description 8
- 239000002023 wood Substances 0.000 claims description 7
- 239000000049 pigment Substances 0.000 claims description 6
- 239000004606 Fillers/Extenders Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 8
- 239000003973 paint Substances 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 229920001187 thermosetting polymer Polymers 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 229920000877 Melamine resin Polymers 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 4
- 229920000180 alkyd Polymers 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000002792 vascular Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- MZZSDCJQCLYLLL-UHFFFAOYSA-N Secalonsaeure A Natural products COC(=O)C12OC3C(CC1=C(O)CC(C)C2O)C(=CC=C3c4ccc(O)c5C(=O)C6=C(O)CC(C)C(O)C6(Oc45)C(=O)OC)O MZZSDCJQCLYLLL-UHFFFAOYSA-N 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 239000006224 matting agent Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
Description
本考案は木質感に富んだ木目凹凸模様を有し、
しかも表面性能の優れた化粧シートに関するもの
である。
従来、薄用紙等の紙を基材とした化粧シートの
印刷模様とエンボス模様を同調させる手法とし
て、特に有効なものは、例えば印刷後トツプコー
ト塗料を塗布乾燥した後に体質顔料を多量に添加
したインキにて導管部を印刷して凹凸効果を出す
マツトグロス法や、導管部インキ中にシリコン樹
脂等のトツプコート塗料を反撥させる撥液剤を添
加して、トツプコート時にその部分のみ反撥によ
り窪ませて凹凸効果を出す方法等がある。前者は
窪ませたい導管部が凸となる為に意匠的には劣
る。後者は原理的にはシリコン等の撥液剤が導管
インキ表面ににじみ出て、それがトツプコート塗
料をはじいて凹部を形成するわけであるが、撥液
剤自体は必ずしもインキ表面のみにはにじみ出
ず、印刷部周辺、そして基材が紙等の浸透性のあ
るものであれば下の方にまでにじみ出てしまう。
その為凹部がインキののつていない部分にまで広
がり不自然な感じとなる。そしてその広がりは導
管部印刷後塗料トツプコートまでの時間が長いほ
ど激しくなり、その分凹凸のシヤープさは失われ
ていく。そして更には撥液剤が紙中へ浸透してゆ
き経時で撥液効果が失われてしまう。また導管イ
ンキには塗料が付着しないために耐性が著しく劣
る為、熱硬化性インキを使用することも考えられ
るが、どうしても導管インキ部周辺はトツプコー
ト層が薄くなりがちであり、耐性がおちる傾向に
ある。また凹凸効果をさらに視覚的に高める為に
導管インキに艶消し剤を多量に添加するとインキ
自体の強度及び基材との接着然が落ち、トツプコ
ート時にトラツピングの問題が出る事が多く、ま
た製品となつた後も物性的に劣る傾向にある。
本考案は以上の様な紙を基材として撥液インキ
を使用した場合の問題点を解決する為に考案され
たものである。
以下本考案を詳細に説明する。
本考案はまず基材たる原紙1として印刷可能な
紙、通常は30〜60g/m2程度の薄用紙、又は樹脂
混抄紙を使用し、導管部以外の木目柄を印刷2形
成した後に、熱硬化性の樹脂よりなる透明なベタ
層3を設ける。熱硬化性樹脂としては、アクリル
ウレタン、ウレタン、アミノアルキド、メラミン
等、基材又は下地の印刷2のインキとの接着性を
有していれば任意であるがトツプコートとの密着
性からウレタン系アミノアルキツド樹脂が望まし
い。次に熱硬化性層が半硬化の状態のうちにアク
リルウレタン、ウレタン、自己架橋アクリルメラ
ミン、アミノアルキド等の熱硬化型のビヒクルに
シリコン樹脂、フツ素樹脂等の撥液剤を2〜5%
添加し、さらにシリカ系体質顔料を樹脂に対し、
70〜200PHR添加し、着色顔料で色付けした硬化
性インキにて導管部を印刷4する。しかる後にト
ツプコート樹脂5を塗布し、導管部のみトツプコ
ートの塗料を反撥させて凹部6を形成させる。ト
ツプコート樹脂はウレタン、アクリルウレタン、
アクリル、メラミン、アクリルメラミン、アミノ
アルキド等硬化性のものであり、特に透明ベタ層
との密着が悪くなければ任意である。
本構成により得られた凹部よりなるエンボス模
様は以下の要因でシヤープ性を有し、しかも安定
性があり、表面物性的にも優れたものが得られ
る。
まず硬化性インキの印刷の下側に熱硬化性の透
明なベタ層が設けられているので、硬化性インキ
の基材への浸透が防がれ、撥液剤の導管部以外へ
のにじみ出しを押えることが出来、撥液剤を有効
に作用されてエンボス樹脂がシヤープになる。ま
た導管部周辺の物性も、トツプコート樹脂が薄く
なつているにもかかわらず、透明なベタ層に補助
されて十分な物性を有しており、硬化性インキに
よる導管部の印刷自体も硬化性でかつベタ層が印
刷されている事により、密着が強因となり、又、
若干でもベタ層へ根をはるかたちにもなるので、
物性面でもかなり向上している。また硬化性イン
キ中へ撥液剤を保持する役割としてのシリカ系体
質顔料が多量に添加されているので艶消し効果を
も有する。
次に本考案の実施例について説明する。
実施例
原紙1として30g/m2の薄用紙を用い、これに
通常のグラビア印刷法で木目柄の印刷2を行い、
次いで版深60μのベタ版でアクリルウレタン系の
塗料を3gdry/m2程度の塗布量で全面にのせ、
乾燥させてベタ層3を形成する。しかる後に凹に
したい導管部を下記組成の硬化性インキにて通常
のグラビア印刷法で印刷4する。
次いで該木目模様紙上にグラビア印刷機により
トツプコート樹脂としてアミノアルキド系塗料を
8gdry/m2塗布して乾燥させ、天然木に類似し
たリアル感に富む化粧シートを得た。
導管インキに組成=
ポリオール;20重量部
シリカ系体積顔料;20重量部
溶剤;60重量部
イソシアネート(トリレン・ジ・イソシアネー
ト);20重量部
シリコン;3重量部
着色顔料;少々
比較例として本案以外の条件にて化粧シートを
作成し、各項目について実施例との比較を行つ
た。
This invention has a wood grain pattern that gives it a rich wood feel,
Moreover, it relates to a decorative sheet with excellent surface performance. Conventionally, particularly effective methods for harmonizing the printed pattern and embossed pattern of a decorative sheet based on paper such as thin paper include, for example, the matt gloss method, in which a top coat paint is applied and dried after printing, and then the duct parts are printed with ink containing a large amount of extender pigment to create a rough effect, and a method in which a liquid repellent agent such as silicone resin that repels the top coat paint is added to the ink for the duct parts, and only that part is recessed by the repulsion during top coating to create a rough effect. The former is inferior in terms of design because the duct parts to be recessed become convex. The latter is a method in which, in principle, the liquid repellent agent such as silicone seeps onto the surface of the duct ink, which repels the top coat paint to form recesses, but the liquid repellent agent itself does not necessarily seep only onto the ink surface, but seeps out around the printed part, and even downward if the substrate is permeable such as paper.
Therefore, the recesses spread to the areas where there is no ink, making it look unnatural. The longer the time between printing the ducts and topcoating the paint, the more severe the spread becomes, and the sharpness of the unevenness is lost. Furthermore, the liquid-repellent agent penetrates into the paper, and the liquid-repellent effect is lost over time. In addition, since the paint does not adhere to the duct ink, its resistance is significantly inferior, so it is possible to use a thermosetting ink, but the topcoat layer tends to be thin around the duct ink, and its resistance tends to decrease. In addition, if a large amount of matting agent is added to the duct ink to further visually enhance the unevenness effect, the strength of the ink itself and its adhesion to the substrate decrease, and trapping problems often occur during topcoating, and the physical properties tend to be inferior even after the product is made. This device was devised to solve the problems when using liquid-repellent ink on paper as described above. The device will be explained in detail below. In this device, first, a printable paper, usually a thin paper of about 30-60g/m2 or a resin-mixed paper, is used as the base paper 1 , and after printing 2 of the wood grain pattern other than the vascular area, a transparent solid layer 3 made of a thermosetting resin is provided. Any thermosetting resin can be used, such as acrylic urethane, urethane, amino alkyd, melamine, etc., as long as it has adhesive properties with the ink of the base material or undercoat printing 2, but urethane-based amino alkyd resin is preferable in terms of adhesion with the top coat. Next, while the thermosetting layer is in a semi-cured state, 2-5% of a liquid repellent agent such as silicone resin or fluororesin is added to a thermosetting vehicle such as acrylic urethane, urethane, self-crosslinking acrylic melamine, amino alkyd, etc.
Addition of silica-based extender pigment to resin.
The ducts are printed 4 with a hardening ink colored with a coloring pigment. Then, a top coat resin 5 is applied, and the ducts are repelled by the top coat paint only, forming recesses 6. The top coat resin is urethane, acrylic urethane,
The material may be a hardening material such as acrylic, melamine, acrylic melamine, or aminoalkyd, and may be any material as long as it does not have poor adhesion to the transparent solid layer. The embossed pattern consisting of recesses obtained by this configuration has sharpness, stability, and excellent surface properties due to the following factors. First, a thermosetting transparent solid layer is provided under the printing of the hardening ink, which prevents the hardening ink from penetrating the substrate and prevents the liquid repellent from bleeding out to areas other than the ducts, and the embossed resin becomes sharp due to the effective action of the liquid repellent. Furthermore, even though the top coat resin is thin, the physical properties around the ducts are sufficient due to the support of the transparent solid layer, and the printing of the ducts with the hardening ink itself is hardening and has a solid layer printed, which provides strong adhesion, and
This will help the plant to take root in the solid layer even a little,
The physical properties have also been improved considerably. In addition, a large amount of silica-based extender pigment is added to the hardening ink to retain the liquid repellent, which also provides a matte effect. Next, an example of the present invention will be described. Example: A thin paper of 30 g/ m2 was used as the base paper 1, and a wood grain pattern was printed 2 on it using the usual gravure printing method.
Next, apply an acrylic urethane paint to the entire surface with a 60μ solid plate at a coating weight of about 3g dry/m2.
It is dried to form a solid layer 3. The vascular areas to be concave are then printed 4 by normal gravure printing with a curable ink of the following composition. Next, 8 g dry/ m2 of aminoalkyd paint is applied as a topcoat resin onto the wood grain paper using a gravure printer and dried to obtain a decorative sheet with a realistic feel similar to natural wood. Composition of vascular ink: Polyol 20 parts by weight Silica-based volume pigment 20 parts by weight Solvent 60 parts by weight Isocyanate (tolylene diisocyanate) 20 parts by weight Silicone 3 parts by weight Coloring pigment A small amount A decorative sheet was prepared under conditions other than those of this example as a comparative example, and each item was compared with the examples.
【表】【table】
図面は本考案の一実施例を示すもので、第1図
は本化粧シートの断面図である。
1……原紙、2……(絵柄の)印刷、3……
(透明な)ベタ層、4……(硬化性インキによ
る)印刷、5……トツプコート樹脂、6……凹
部。
The drawings show one embodiment of the present invention, and FIG. 1 is a sectional view of the present decorative sheet. 1... Base paper, 2... (design) printing, 3...
(Transparent) solid layer, 4... Printing (using curable ink), 5... Top coat resin, 6... Concave portion.
Claims (1)
性樹脂による透明なベタ層3が設けられ、さらに
その上にシリカ系体質顔料を70〜200PHRおよび
撥液剤を含む硬化性インキによる導管部が印刷4
され、さらにその上にトツプコート樹脂が導管部
の印刷4に転移することなく形成され、導管部が
凹になるように表現されたことを特色とする化粧
シート。 A wood grain pattern 2 is printed on the base paper, a transparent solid layer 3 made of a curable resin is provided on top of it, and a conduit section is coated with a curable ink containing a silica-based extender pigment of 70 to 200 PHR and a liquid repellent. is printed 4
The decorative sheet is further characterized in that a top coat resin is formed on the printing 4 of the conduit part without being transferred, and the conduit part is expressed to be concave.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2942183U JPS59137031U (en) | 1983-03-01 | 1983-03-01 | makeup sheet |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2942183U JPS59137031U (en) | 1983-03-01 | 1983-03-01 | makeup sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS59137031U JPS59137031U (en) | 1984-09-12 |
JPS6229245Y2 true JPS6229245Y2 (en) | 1987-07-27 |
Family
ID=30160277
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2942183U Granted JPS59137031U (en) | 1983-03-01 | 1983-03-01 | makeup sheet |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS59137031U (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2598904B2 (en) * | 1987-02-09 | 1997-04-09 | 大日本印刷株式会社 | Decorative sheet |
-
1983
- 1983-03-01 JP JP2942183U patent/JPS59137031U/en active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS59137031U (en) | 1984-09-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS6229245Y2 (en) | ||
KR20000070060A (en) | Release sheet and process for preparation of synthetic leather | |
JPS59160570A (en) | Manufacture of decorative sheet | |
JPS5843271B2 (en) | Decorative material manufacturing method | |
JP3269538B2 (en) | Manufacturing method of three-dimensional patterned decorative paper | |
JP2006328285A (en) | Sublimation transfer print-coated leather product and method for producing the same | |
JPS5941793B2 (en) | Decorative board manufacturing method | |
JPS62134256A (en) | Product made of synthetic resin to which genuine japanese lacuer is executed | |
JPS6229110B2 (en) | ||
JPH10128902A (en) | Inorganic decorative board having excellent anti-fouling property and production method thereof | |
JPS59155087A (en) | Manufacture of synchronously embossed decorative material | |
JP2668591B2 (en) | Manufacturing method of decorative sheet | |
JPS6014583Y2 (en) | Painted decorative board | |
EP1477319A2 (en) | Plastic foil printable with digital printing | |
JPS6113040B2 (en) | ||
JPH0120065B2 (en) | ||
JP3807832B2 (en) | Decorative plate manufacturing method | |
JPS59216662A (en) | Preparation of embossed decorative material | |
JPH06270370A (en) | Decorative laminated sheet | |
JPS6310289Y2 (en) | ||
JP2582303Y2 (en) | Decorative paper | |
JPS6012105B2 (en) | Manufacturing method for decorative floorboards | |
JPH08174770A (en) | Decorative paper and its manufacture | |
JP3120893B2 (en) | Decorative paper | |
JPH054305A (en) | Manufacture of decorative sheet |