EP1477319A2 - Plastic foil printable with digital printing - Google Patents

Plastic foil printable with digital printing Download PDF

Info

Publication number
EP1477319A2
EP1477319A2 EP20040011230 EP04011230A EP1477319A2 EP 1477319 A2 EP1477319 A2 EP 1477319A2 EP 20040011230 EP20040011230 EP 20040011230 EP 04011230 A EP04011230 A EP 04011230A EP 1477319 A2 EP1477319 A2 EP 1477319A2
Authority
EP
European Patent Office
Prior art keywords
film
plastic film
acrylate polymer
printing
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20040011230
Other languages
German (de)
French (fr)
Other versions
EP1477319A3 (en
Inventor
Hugh Neville Glenister
Nobert Nibbrig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
X-Film Selbstklebefolien GmbH
Original Assignee
X-Film Selbstklebefolien GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by X-Film Selbstklebefolien GmbH filed Critical X-Film Selbstklebefolien GmbH
Publication of EP1477319A2 publication Critical patent/EP1477319A2/en
Publication of EP1477319A3 publication Critical patent/EP1477319A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52Macromolecular coatings
    • B41M5/5254Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers
    • Y10T428/31931Polyene monomer-containing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31971Of carbohydrate
    • Y10T428/31993Of paper

Definitions

  • the invention relates to a plastic film which can be printed using digital printing technology, in particular self-adhesive plastic film, which on the back with a Adhesive layer and a siliconized cover is provided as well Production of the printed film from paper or plastic (film).
  • the invention has for its object a printable with digital technology
  • To create plastic film with a health-friendly ink is printable and gives a perfect print image. It is also said to be a possibility for the production of a plastic film printed in digital printing.
  • the The surface of the film is covered with a thin film of an acrylate polymer. It the result is a highly transparent and high-gloss polymer layer.
  • an acrylate polymer a copolymer of butyl acrylate and a methyl methacrylate is used.
  • the shares of the copolymer are preferably 50% by weight of butyl acrylate and 50% by weight Methyl methacrylate. It was found that such a plastic film is very good at Digital printing technology is to be printed with low solvent printing inks. A run of the Printing inks or other printing errors do not occur.
  • the acrylate polymer is used as an aqueous dispersion applied to the surface of the film and then at a temperature of Dried 90 ° to 100 ° C. Higher temperatures can damage the Lead decorative film. If the temperature is too low, the copolymer cures unsatisfactory.
  • the polymer can be applied to the film in the engraving system take place, which is followed by drying. With the engraving system, the dispersion by a rotating one with an engraved structure on its surface provided metal cylinder applied to the film web. The dried layer does not stick, so that the film can be rolled up into a roll in the usual way.
  • the film is fed to a digital printer, which is equipped with a low solvent printing ink works, and the printing process is carried out. It turned out that a very good print image can be printed and that the film also a Has a surface with high resistance.
  • Printing inks are preferred on Lactic acid base used. These printing inks can work very well on one with the Acrylic coated film can be processed. This is a Printing ink with low volatile organic solvents on an organic basis (Lactatbasis). The inks are available as low-volatile solvent ink, low-solvent ink and ecosolvent ink and called mild solvent ink.
  • a so-called decorative film which consists of a PVC film on the back provided with an adhesive layer and a siliconized paper cover is fed to an engraving device and there with a thin film from a aqueous dispersion of a copolymer of butyl acrylate and methyl methacrylate coated.
  • the PVC film is transparent or colored white during its manufacture, to form a good printing pad. It is also possible to use a different color use colored film if this is useful for later printing is.
  • the decorative film is attached to the engraving device subsequent continuous oven dried at 96 ° C. The drying time is 30 Seconds.
  • the dry decorative film is fed to a digital printer and there under Use of a low-solvent printing ink based on lactic acid derivatives printed. An excellent print image was achieved on an extremely resistant surface.
  • the process is particularly suitable for the production of photo-realistic prints.

Abstract

A polymer film (I) is printable by means of digital printing technology and has an adhesive layer and a siliconized covering on its reverse face whereby the surface of the film (I) is coated with a thin layer of an acrylate polymer. An independent claim is included for a process for the production of the film (I) by coating the surface with a thin layer of acrylate polymer prior to the printing process.

Description

Die Erfindung betrifft eine mit Digitaldrucktechnik bedruckbare Kunststoff-Folie, insbesondere selbstklebende Kunststoff-Folie, die auf ihrer Rückseite mit einer Klebemittelschicht und einer silikonisierten Abdeckung versehen ist sowie die Herstellung der bedruckten Folie aus Papier oder Kunststoff(Folie).The invention relates to a plastic film which can be printed using digital printing technology, in particular self-adhesive plastic film, which on the back with a Adhesive layer and a siliconized cover is provided as well Production of the printed film from paper or plastic (film).

Neben den herkömmlichen Drucktechniken wie Hochdruck, Tiefdruck, Siebdruck und dgl. findet die Digitaldrucktechnik eine immer weitere Verbreitung. Bei der Digitaldrucktechnik werden die Druckfarben, meist als Drucktinte bezeichnet, computergesteuert in feinster Sprühtechnik direkt auf das Substrat übertragen. Sofern das Substrat ein Papier ist, entstehen dabei keine besonderen Probleme. Zu ungenügendem Druckbild kommt es jedoch, wenn als Substrat eine aus Kunststoff bestehende Folie, insbesondere PVC-Folie, verwendet werden soll. Hier behilft man sich, indem man Drucktinten verwendet, die flüchtige organische Lösungsmittel enthalten. Das hat jedoch den Nachteil, daß die Folie beschädigt werden kann und deren Oberfläche an Widerstandsfähigkeit einbüßt. Darüber hinaus sind die dafür eingesetzten Drucker mit-einer Lösungsmittelabsaugung zu versehen, was sowohl die Kosten für den Drucker als auch für das Drucken selbst erhöht.In addition to the conventional printing techniques such as letterpress, gravure, screen printing and The like. Digital printing technology is becoming increasingly widespread. In the Digital printing technology, the printing inks, usually referred to as printing ink, Computer-controlled, transferred to the substrate using the finest spray technology. Provided the substrate is a paper, there are no particular problems. To Inadequate print image occurs, however, if the substrate is one made of plastic existing film, especially PVC film, is to be used. Here you help by using printing inks, the volatile organic solvents contain. However, this has the disadvantage that the film can be damaged and their Surface loses resistance. In addition, the ones used for this To provide a printer with a solvent extraction system, which is both the cost of the Printer as well as increased for printing itself.

Der Erfindung liegt die Aufgabe zugrunde, eine mit Digitaltechnik bedruckbare Kunststoff-Folie zu schaffen, die mit einer gesundheitlich unbedenklichen Tinte bedruckbar ist und ein einwandfreies Druckbild ergibt. Außerdem soll eine Möglichkeit zur Herstellung einer im Digitaldruck bedruckten Kunststoff-Folie angegeben werden.The invention has for its object a printable with digital technology To create plastic film with a health-friendly ink is printable and gives a perfect print image. It is also said to be a possibility for the production of a plastic film printed in digital printing.

Dir Lösung der gestellten Aufgabe erfolgt gemäß den Merkmalen der Ansprüche 1 und 6. Die Unteransprüche 2 bis 5 und 7 bis 9 geben vorteilhafte Ausgestaltungen der Erfindung wieder.The solution of the task is carried out according to the features of claims 1 and 6. The subclaims 2 to 5 and 7 to 9 give advantageous refinements of Invention again.

Um ein einwandfreies Druckbild auf der Kunststoff-Folie zu erreichen, wird die Oberfläche der Folie mit einem dünnen Film aus einem Acrylatpolymer überzogen. Es entsteht eine hochtransparente und hochglänzende Polymerschicht. Als Acrylatpolymer wird ein Copolymer aus Butylacrylat und ein Methylmethacrylat eingesetzt. Die Anteile des Copolymers betragen bevorzugt 50 Gew.% Butylacrylat und 50 Gew.% Methylmethacrylat. Es zeigte sich, daß eine solche Kunststoff-Folie sehr gut in der Digitaldrucktechnik mit low-solvent Drucktinten zu bedrucken ist. Ein Verlaufen der Drucktinten oder andere Druckfehler treten nicht auf.In order to achieve a perfect print image on the plastic film, the The surface of the film is covered with a thin film of an acrylate polymer. It the result is a highly transparent and high-gloss polymer layer. As an acrylate polymer a copolymer of butyl acrylate and a methyl methacrylate is used. The shares of the copolymer are preferably 50% by weight of butyl acrylate and 50% by weight Methyl methacrylate. It was found that such a plastic film is very good at Digital printing technology is to be printed with low solvent printing inks. A run of the Printing inks or other printing errors do not occur.

Um zu einer im Digitaldruck einwandfrei bedruckten Kunststoff-Folie zu gelangen, wird die Oberfläche der Folie vor dem Druckvorgang mit einem dünnen Film aus einem Acrylatpolymer beschichtet. Hierfür wird das Acrylatpolymer als wässrige Dispersion auf die Oberfläche der Folie aufgetragen und anschließend bei einer Temperatur von 90° bis 100°C getrocknet. Höhere Temperaturen können zu einer Beschädigung der Dekorfolie führen. Bei zu niedrigen Temperaturen ist die Aushärtung des Copolymers nicht ausreichend. Der Auftrag des Polymers auf die Folie kann im Gravursystem erfolgen, an das sich die Trocknung anschließt. Beim Gravursystem wird die Dispersion durch einen rotierenden mit einer eingravierten Struktur auf seiner Oberfläche versehenen Metallzylinder auf die Folienbahn aufgetragen. Die getrocknete Schicht klebt nicht, so daß die Folie in üblicher Weise zu einer Rolle aufgerollt werden kann. Für den Druckvorgang wird die Folie einem Digitaldrucker zugeführt, der mit einer low-solvent Drucktinte arbeitet, und der Druckvorgang ausgeführt. Es zeigte sich, daß ein sehr gutes Druckbild gedruckt werden kann und daß die Folie außerdem eine Oberfläche mit hoher Beständigkeit hat. Bevorzugt werden Drucktinten auf Milchsäurebasis eingesetzt. Diese Drucktinten können sehr gut auf einer mit der Acrylatschicht versehenen Folie verarbeitet werden. Es handelt sich hier um eine Drucktinte mit schwerflüchtigen organischen Lösenmitteln auf organischer Basis (Lactatbasis). Die Tinten werden als low-volatile solvent ink, low-solvent ink, ecosolvent ink und als mild-solvent ink bezeichnet. In order to obtain a plastic film that is perfectly printed in digital printing, cover the surface of the film with a thin film from a Acrylic polymer coated. For this, the acrylate polymer is used as an aqueous dispersion applied to the surface of the film and then at a temperature of Dried 90 ° to 100 ° C. Higher temperatures can damage the Lead decorative film. If the temperature is too low, the copolymer cures unsatisfactory. The polymer can be applied to the film in the engraving system take place, which is followed by drying. With the engraving system, the dispersion by a rotating one with an engraved structure on its surface provided metal cylinder applied to the film web. The dried layer does not stick, so that the film can be rolled up into a roll in the usual way. For the printing process, the film is fed to a digital printer, which is equipped with a low solvent printing ink works, and the printing process is carried out. It turned out that a very good print image can be printed and that the film also a Has a surface with high resistance. Printing inks are preferred on Lactic acid base used. These printing inks can work very well on one with the Acrylic coated film can be processed. This is a Printing ink with low volatile organic solvents on an organic basis (Lactatbasis). The inks are available as low-volatile solvent ink, low-solvent ink and ecosolvent ink and called mild solvent ink.

Anhand eines Ausführungsbeispiels wird die Erfindung nachstehend näher erläutert.The invention is explained in more detail below using an exemplary embodiment.

Eine sogenannte Dekorfolie, die aus einer PVC-Folie besteht, die auf ihrer Rückseite mit einer Klebemittelschicht und einer silikonisierten Abdeckung aus Papier versehen ist, wird einer Gravureinrichtung zugeführt und dort mit einem dünnen Film aus einer wässrigen Dispersion aus einem Copolymer aus Butylacrylat und Methylmethacrylat beschichtet. Die PVC-Folie ist bei ihrer Herstellung transparent oder weiß eingefärbt, um eine gute Druckunterlage zu bilden. Möglich ist auch, eine mit einer anderen Farbe eingefärbte Folie zu verwenden, wenn dieses für den späteren Druckvorgang nützlich ist. Nach der Beschichtung wird die Dekorfolie in einem an die Gravureinrichtung sich anschließenden Durchlaufofen bei 96°C getrocknet. Die Trockenzeit beträgt 30 Sekunden. Die trockene Dekorfolie wird einem Digitaldrucker zugeführt und dort unter Verwendung einer low-solvent Drucktinte auf der Basis von Milchsäurederivaten bedruckt. Es wurde eine ausgezeichnetes Druckbild erreicht auf einer äußerst beständigen Oberfläche.A so-called decorative film, which consists of a PVC film on the back provided with an adhesive layer and a siliconized paper cover is fed to an engraving device and there with a thin film from a aqueous dispersion of a copolymer of butyl acrylate and methyl methacrylate coated. The PVC film is transparent or colored white during its manufacture, to form a good printing pad. It is also possible to use a different color use colored film if this is useful for later printing is. After coating, the decorative film is attached to the engraving device subsequent continuous oven dried at 96 ° C. The drying time is 30 Seconds. The dry decorative film is fed to a digital printer and there under Use of a low-solvent printing ink based on lactic acid derivatives printed. An excellent print image was achieved on an extremely resistant surface.

Das Verfahren eignet sich besonders für die Herstellung von fotorealistischen Drucken.The process is particularly suitable for the production of photo-realistic prints.

Claims (9)

Mit Digitaldrucktechnik bedruckbare Kunststoff-Folie, insbesondere selbstklebende Kunststoff-Folie, die auf ihrer Rückseite mit einer Klebeschicht und einer silikonisierten Abdeckung versehen ist, dadurch gekennzeichnet, daß die Oberfläche der Folie mit einem dünnen Film aus einem Acrylatpolymer beschichtet ist.Plastic film which can be printed with digital printing technology, in particular self-adhesive plastic film which is provided on the back with an adhesive layer and a siliconized cover, characterized in that the surface of the film is coated with a thin film of an acrylate polymer. Kunststoff-Folie nach Anspruch 1, dadurch gekennzeichnet, daß das Acrylatpolymer ein Copolymer aus Butulacrylat und Methylmethacrylat ist.Plastic film according to claim 1, characterized in that the acrylate polymer is a copolymer of butulacrylate and methyl methacrylate. Kunststoff-Folie nach Anspruch 1 oder 2, dadurch gekennzeichnet, daß das Copolymer aus 50 Gew.% Butylacrylat und 50 Gew.% Methylmethacrylat besteht. Plastic film according to claim 1 or 2, characterized in that the copolymer consists of 50% by weight of butyl acrylate and 50% by weight of methyl methacrylate. Kunststoff-Folie nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß die Polymerschicht hochtransparent ist.Plastic film according to one of claims 1 to 3, characterized in that the polymer layer is highly transparent. Kunststoff-Folie nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, daß die Kunststoff-Folie eine hochglänzende Folie ist.Plastic film according to one of claims 1 to 4, characterized in that the plastic film is a high-gloss film. Herstellung einer im Digitaldruck bedruckten Kunststoff-Folie, insbesondere einer selbstklebenden Kunststoff-Folie, die auf ihrer Rückseite mit einem Klebemittel und einer silikonisierten Abdeckung versehen ist nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, daß die Oberfläche der Folie vor dem Druckvorgang mit einem dünnen Film aus einem Acrylatpolymer beschichtet wird.Production of a plastic film printed in digital printing, in particular a self-adhesive plastic film, which is provided on the back with an adhesive and a siliconized cover according to one of claims 1 to 5, characterized in that the surface of the film before the printing process with a thin film is coated from an acrylate polymer. Herstellung einer Kunststoff-Folie nach Anspruch 6, dadurch gekennzeichnet, daß das Acrylatpolymer als wässrige Dispersion auf die Oberfläche der Folie aufgetragen wird.Production of a plastic film according to claim 6, characterized in that the acrylate polymer is applied as an aqueous dispersion to the surface of the film. Herstellung einer Kunststoff-Folie nach einem der Ansprüche 6 oder 7, dadurch gekennzeichnet, daß die Folie nach dem Auftrag des Acrylatpolymers einer Trocknung bei 90 - 100°C unterworfen wird. Production of a plastic film according to one of claims 6 or 7, characterized in that the film is subjected to drying at 90-100 ° C after the acrylate polymer has been applied. Herstellung einer Kunststoff-Folie nach einem der Ansprüche 6 bis 8, dadurch gekennzeichnet, daß der Druckvorgang unter Verwendung von Pigmenttinte auf der Basis von Milchsäurederivaten erfolgt.Production of a plastic film according to one of claims 6 to 8, characterized in that the printing process is carried out using pigment ink based on lactic acid derivatives.
EP20040011230 2003-05-13 2004-05-12 Plastic foil printable with digital printing Withdrawn EP1477319A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10321365 2003-05-13
DE2003121365 DE10321365A1 (en) 2003-05-13 2003-05-13 Plastic film printable with digital printing technology and production of a printed plastic film

Publications (2)

Publication Number Publication Date
EP1477319A2 true EP1477319A2 (en) 2004-11-17
EP1477319A3 EP1477319A3 (en) 2004-12-01

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EP20040011230 Withdrawn EP1477319A3 (en) 2003-05-13 2004-05-12 Plastic foil printable with digital printing

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US (1) US20040258942A1 (en)
EP (1) EP1477319A3 (en)
DE (1) DE10321365A1 (en)

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DE202010008172U1 (en) 2010-07-28 2011-11-30 Westag & Getalit Ag Male mold for producing a female mold, with which a three-dimensional original positive structure can be pressed into high-pressure lamites (HPL)
EP2412516A2 (en) 2010-07-28 2012-02-01 Westag & Getalit AG Male component for producing a female component which can be used to press a three dimensional original positive structure in high pressure laminate panels or high pressure laminates

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Also Published As

Publication number Publication date
EP1477319A3 (en) 2004-12-01
US20040258942A1 (en) 2004-12-23
DE10321365A1 (en) 2004-12-16

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