JPS62270740A - Electric discharge electrode material for ignition plug - Google Patents

Electric discharge electrode material for ignition plug

Info

Publication number
JPS62270740A
JPS62270740A JP11057786A JP11057786A JPS62270740A JP S62270740 A JPS62270740 A JP S62270740A JP 11057786 A JP11057786 A JP 11057786A JP 11057786 A JP11057786 A JP 11057786A JP S62270740 A JPS62270740 A JP S62270740A
Authority
JP
Japan
Prior art keywords
weight
discharge electrode
electrode material
electric discharge
ignition plug
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP11057786A
Other languages
Japanese (ja)
Inventor
Hisashi Higuchi
樋口 尚志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Electric Industries Ltd
Original Assignee
Sumitomo Electric Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Electric Industries Ltd filed Critical Sumitomo Electric Industries Ltd
Priority to JP11057786A priority Critical patent/JPS62270740A/en
Publication of JPS62270740A publication Critical patent/JPS62270740A/en
Pending legal-status Critical Current

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  • Spark Plugs (AREA)

Abstract

PURPOSE:To improve high temp. oxidation resistance, lead erosion resistance, and workability of electric discharge electrode material for ignition plug, by specifying the blending proportions of Cr, Fe, S, Si, Al, Ti, and C in an Ni-base alloy. CONSTITUTION:The electric discharge electrode material for ignition plug has a composition consisting of, by weight, 14-18% Cr, 6-10% Fe, <=0.015% S, 0.1-0.5% Si, 0.05-0.5% Al, <=0.3% Ti, <=0.01% C, and the balance essentially Ni. In the material of this composition, Cr improves high temp. oxidation resistance and lead erosion resistance and Al is an element improving high temp. oxidation resistance. Moreover, Si improves high temp. oxidation resistance and lead erosion resistance. Ti is incorporated in a range causing no deterioration in workability.

Description

【発明の詳細な説明】 3、発明の詳細な説明 〈産業上の利用分野〉 この発明は点火プラグ用放電電極材料の改良に関するも
のであり、比較的加工容易な点火プラグ用放電電極材料
に関する。
Detailed Description of the Invention 3. Detailed Description of the Invention <Industrial Field of Application> The present invention relates to an improvement of a discharge electrode material for a spark plug, and relates to a discharge electrode material for a spark plug that is relatively easy to process.

〈従来の技術〉 点火プラグ用放電電極材料として、従来から高Ni合金
が多く使用されており、より耐久性の優れたものとして
インコネル600の材料が用いられている。
<Prior Art> Conventionally, high Ni alloys have been widely used as discharge electrode materials for spark plugs, and Inconel 600 has been used as a material with better durability.

〈発明が解決しようとする問題点〉 しかし、インコネル600は高Ni合金に比べて加工硬
化が大きく、特に銅芯入り中心電極の加工では加工工程
に数回の熱処理が必要となり、コストを上昇させる要因
となっている。
<Problems to be solved by the invention> However, Inconel 600 suffers from greater work hardening than high-Ni alloys, and in particular, when processing a center electrode with a copper core, several heat treatments are required during the processing process, increasing costs. This is a contributing factor.

この発明は従来の点火プラグ用放電ti材料の上述の欠
点を除去するためになされたものであり、現在のインコ
ネル600程度の耐高温酸花性と、耐鉛侵食性を有し、
かつ加工性に優れた合金を提供しようとするものである
This invention was made to eliminate the above-mentioned drawbacks of conventional discharge Ti materials for spark plugs, and has high temperature acid spark resistance and lead corrosion resistance comparable to the current Inconel 600.
The purpose is to provide an alloy with excellent workability.

く問題点を解決するための手段〉 以上の目的を達成するための、この発明にかかる点火プ
ラグ用放電を極材料はCrが14〜18重量%、Feが
6〜10重量%、Sが0、 O15重量%以下、Siが
0.1〜0.5重量%、Alが0.05〜0.5重量%
、Tiが0.3重量%以下、Cが0.01重量%以下で
、残部が基本的にNiからなることを特徴とするもので
ある。
Means for Solving the Problems> In order to achieve the above objects, the electrode material for the spark plug discharge according to the present invention contains 14 to 18% by weight of Cr, 6 to 10% by weight of Fe, and 0% of S. , O 15% by weight or less, Si 0.1-0.5% by weight, Al 0.05-0.5% by weight
, Ti is 0.3% by weight or less, C is 0.01% by weight or less, and the balance basically consists of Ni.

本発明で使用する点火プラグ用放電電極材料中、Crは
耐高温酸化性および耐鉛侵食性を向上させる元素であり
、含有量を14重量%以下のときは効果が少く、18重
量%以上にすると加工性が悪(なる、また、本発明にお
いてA7は高温耐酸化性を向上させる元素であり、0.
05重量%以下では効果が少く、0.5重量%以上では
加工性を悪化させるため、O,OS〜0.5重量%の範
囲に限定される。SはNi基合金の高温強度を著しく劣
化させるため、含有量は0.015重量%以下に限定さ
れる。 s+は本発明の合金では耐高温酸化性および耐
鉛侵食性を向上させる元素であり、0.1重量%以下の
含有量のときは効果が少く、0.5重量%以上添加する
と加工性を悪化させるから、0.1〜0.5重量%の範
囲内に限定される。
In the spark plug discharge electrode material used in the present invention, Cr is an element that improves high-temperature oxidation resistance and lead corrosion resistance, and the effect is small when the content is less than 14% by weight, and when the content is less than 18% by weight. This results in poor workability (in addition, in the present invention, A7 is an element that improves high-temperature oxidation resistance, and 0.
If it is less than 0.05% by weight, the effect will be small, and if it is more than 0.5% by weight, the processability will deteriorate, so it is limited to a range of O,OS to 0.5% by weight. Since S significantly deteriorates the high temperature strength of the Ni-based alloy, the content is limited to 0.015% by weight or less. S+ is an element that improves high-temperature oxidation resistance and lead corrosion resistance in the alloy of the present invention, and when the content is less than 0.1% by weight, the effect is small, and when it is added more than 0.5% by weight, it improves workability. Since it causes deterioration, it is limited to a range of 0.1 to 0.5% by weight.

また、本発明合金においては、TiはCやNと反応し、
粒界や粒内に析出して加工性を悪化させるため、0.3
重量%以下に限定される。
Furthermore, in the alloy of the present invention, Ti reacts with C and N,
0.3 because it precipitates at grain boundaries and inside grains and deteriorates workability.
Limited to % by weight or less.

く実 施 例〉 つぎに、本発明の実施例および比較例に基づいて、発明
内容をより具体的に説明する。
EXAMPLES Next, the content of the invention will be explained in more detail based on examples and comparative examples of the present invention.

実施例および比較例は、それぞれ下記の表−1に示すC
r、 Fe、  S、 Si、 Al、 Ti、  C
の各元素を表記の重量比で混合して得られた点火プラグ
用放電電極材料について加工荷重、高温テストおよび高
鉛テストを行った。
Examples and comparative examples are shown in Table 1 below.
r, Fe, S, Si, Al, Ti, C
Machining load, high temperature tests, and high lead tests were conducted on the discharge electrode material for spark plugs obtained by mixing each element in the indicated weight ratio.

ただし、表−1中、試料光1は実施例のものを、試料N
12,3.4はそれぞれ上記各元素を表中に示す混合比
で配合した比較例の点火プラグ用放電電極材料であり、
試料光5は従来の点火プラグ用放電電極材料である。
However, in Table 1, sample light 1 is that of the example, sample light N
12 and 3.4 are comparative examples of discharge electrode materials for spark plugs in which each of the above elements was blended at the mixing ratio shown in the table,
The sample light 5 is a conventional discharge electrode material for a spark plug.

なお、「成形荷重」は、点火プラグの中心電極加工時の
成形加重値を示し、「高温テスト」は試料を1000℃
から300℃間を3.000回ヒートサイクルした後の
残存率を示シ、「耐Pb7−スト」は、PbO: Pb
S −1:1混合浴中に900℃×2時間浸漬後の残存
率を示したものである。
In addition, "forming load" indicates the molding load value during processing of the center electrode of the spark plug, and "high temperature test" refers to the value of the molding load when processing the center electrode of the spark plug.
"Pb7-resistant" indicates the residual rate after 3,000 heat cycles between 300°C and 300°C.
This figure shows the residual rate after being immersed in a S-1:1 mixed bath at 900°C for 2 hours.

〈発明の効果〉 表−1からも明らかな通り、成形荷重は試料光1〜4に
ついてはいずれも患5よりも小さく、磁2では高温テス
ト、ll&13および隘4では耐pbテストで阻5より
も劣り、本発明の点火プラグ用放電電極材料であるNi
lは耐pbテストが−5に比べ若干劣るものの高温テス
トでは隘5に比べて優れており、成形荷重も含めて総合
的に比較すれば、本発明の点火プラグ用放電電極材料と
して阻5と同等であり、加工性の優れた合金であること
が判る。
<Effects of the Invention> As is clear from Table 1, the molding loads for Sample Lights 1 to 4 are all smaller than that of Sample 5, and that of Magnetic 2 in the high temperature test, and 1 & 13 and 4 in the PB test. Ni, which is the discharge electrode material for spark plugs of the present invention, is also inferior.
Although the PB test of 1 is slightly inferior to 5, it is superior to 5 in the high temperature test, and when compared comprehensively including the molding load, it is the best discharge electrode material for spark plugs of the present invention. It can be seen that the alloy is equivalent and has excellent workability.

Claims (1)

【特許請求の範囲】 Crが14〜18重量%、 Feが6〜10重量%、 Sが0.015重量%以下、 Siが0.1〜0.5重量%、 Alが0.05〜0.5重量%、 Tiが0.3重量%以下、 Cが0.01重量%以下で、残部が基本的にNiからな
ることを特徴とする点火プラグ用放電電極材料。
[Claims] Cr: 14-18% by weight, Fe: 6-10% by weight, S: 0.015% by weight or less, Si: 0.1-0.5% by weight, Al: 0.05-0. A discharge electrode material for a spark plug, characterized in that Ti is 0.3% by weight or less, C is 0.01% by weight or less, and the balance basically consists of Ni.
JP11057786A 1986-05-16 1986-05-16 Electric discharge electrode material for ignition plug Pending JPS62270740A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP11057786A JPS62270740A (en) 1986-05-16 1986-05-16 Electric discharge electrode material for ignition plug

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP11057786A JPS62270740A (en) 1986-05-16 1986-05-16 Electric discharge electrode material for ignition plug

Publications (1)

Publication Number Publication Date
JPS62270740A true JPS62270740A (en) 1987-11-25

Family

ID=14539361

Family Applications (1)

Application Number Title Priority Date Filing Date
JP11057786A Pending JPS62270740A (en) 1986-05-16 1986-05-16 Electric discharge electrode material for ignition plug

Country Status (1)

Country Link
JP (1) JPS62270740A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6759795B2 (en) 2002-02-27 2004-07-06 Ngk Spark Plug Co., Ltd. Spark plug
JP2007165291A (en) * 2005-11-16 2007-06-28 Ngk Spark Plug Co Ltd Spark plug for internal combustion engine

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6759795B2 (en) 2002-02-27 2004-07-06 Ngk Spark Plug Co., Ltd. Spark plug
JP2007165291A (en) * 2005-11-16 2007-06-28 Ngk Spark Plug Co Ltd Spark plug for internal combustion engine

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