JPS62258788A - Preparation of detoxifying agent for heavy metal contained in dust and sludge - Google Patents
Preparation of detoxifying agent for heavy metal contained in dust and sludgeInfo
- Publication number
- JPS62258788A JPS62258788A JP60222601A JP22260185A JPS62258788A JP S62258788 A JPS62258788 A JP S62258788A JP 60222601 A JP60222601 A JP 60222601A JP 22260185 A JP22260185 A JP 22260185A JP S62258788 A JPS62258788 A JP S62258788A
- Authority
- JP
- Japan
- Prior art keywords
- sludge
- dust
- heavy metal
- sodium
- added
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010802 sludge Substances 0.000 title claims abstract description 16
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 13
- 239000000428 dust Substances 0.000 title claims abstract description 12
- 239000003795 chemical substances by application Substances 0.000 title claims description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052979 sodium sulfide Inorganic materials 0.000 claims abstract description 3
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract 2
- 150000002500 ions Chemical class 0.000 claims abstract 2
- 238000003756 stirring Methods 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 231100000331 toxic Toxicity 0.000 claims description 2
- 230000002588 toxic effect Effects 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 claims 1
- 229910052938 sodium sulfate Inorganic materials 0.000 claims 1
- 235000011152 sodium sulphate Nutrition 0.000 claims 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 7
- 238000010828 elution Methods 0.000 abstract description 3
- 239000007788 liquid Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 3
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 abstract description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 abstract description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 abstract description 2
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 abstract 6
- LMBWSYZSUOEYSN-UHFFFAOYSA-N diethyldithiocarbamic acid Chemical compound CCN(CC)C(S)=S LMBWSYZSUOEYSN-UHFFFAOYSA-N 0.000 abstract 2
- 229950004394 ditiocarb Drugs 0.000 abstract 2
- 230000001473 noxious effect Effects 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Landscapes
- Processing Of Solid Wastes (AREA)
- Treatment Of Sludge (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、有毒な重金属を含有する各種ダスト汚泥、ス
ラッヂよりの重金属溶出を固定化する薬剤の製造法に関
するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing a drug that immobilizes heavy metals eluted from various types of dust sludge and sludge containing toxic heavy metals.
上記ダスト、汚泥、スラッヂ中には総水銀、鉛、カドニ
ュウム、砒素、亜鉛５マンガン、銅などの重金属が含ま
れている。そのためこれ等の梗棄にはセメント系固化材
による固化処理が行われているのが現状である。しかし
ながらこれらの重金属を「有害な産業廃棄物に係る判定
基亭を定める総理府令Ｊによって基準値以下に固定させ
ることは費用手数は無視出来ないものがあり特に容積の
増大は今後の埋立地の確保等にますます厳しい対処が求
められてくる。スセメント固化による最大の欠点として
再溶出の問題が生じている。The dust, sludge, and sludge contain heavy metals such as total mercury, lead, cadmium, arsenic, zinc, manganese, and copper. Therefore, at present, these wastes are solidified using a cement-based solidifying agent. However, fixing these heavy metals below the standard value according to the Prime Minister's Office Ordinance J, which stipulates the standards for determining standards for hazardous industrial waste, involves costs that cannot be ignored, and the increase in volume in particular means securing future landfill sites. Increasingly strict measures are required to deal with these problems.The biggest drawback of cement solidification is the problem of re-elution.
そこで本発明は処理物の容積を最小限圧縮させ含有重金
属を科学的に封鎖し再溶出を防止するものである。以下
具体的に説明する。Therefore, the present invention aims to minimize the volume of the treated material, scientifically sequester the heavy metals contained therein, and prevent re-elution. This will be explained in detail below.
先ずエチレンイミンＣＩＩ 、 −〇 Ｈに−４化炭素
を加え混練を行い次いで苛性ソーダ−、ジエチルジチル
カルバミンソーダー、硫化ソーダー、水を加え攪拌し最
後にチオ硫酸ソーダー加え１時間攪拌する上記の各組成
の配合率は下記の通り
Ｅｔｈｙｌｏｎａｉｍｉｎ（Ｐｏｌｙ＋ｍａｒ） ３
０％ｉｎ ｗａｔｅｒ Ｏ，４２％Ｃａｒｂｏｎ Ｄｅ
ｓｕｌｆｌｄｅ Ｏ，６３％Ｓｏ
ｄｉｕｍ ｌ１ｙｄｒｏｘｉｄａ
１０．２１％Ｓｏｄｉｕｍ Ｄ１
ｅｔｈｙｌｄｉｔｈｏｃａｒｂａ＠ａｔａ Ｏ
，７５％Ｓｏｄｉｕｍ 丁ｈｌｏｓｕｌｆａｔａ
０．０６％Ｓｏ
ｄｉｕｍ ５ｕｌｆｉｄｅ ｌｓ
、ｏｏ％Ｄｉｓｔｉｌｌｅｄ リａｔｅｒ
７２．９２％上記
組成液を該ダスト、汚泥、スラッヂに対し重ス比で１％
〜１０％の範囲で添加し充分（約１ｏ分間）混練するこ
とにより目的は達せられる。First, -carbon tetracide is added to ethyleneimine CII, -〇H and kneaded. Then, caustic soda, diethyldithylcarbamine soda, sodium sulfide and water are added and stirred. Finally, sodium thiosulfate is added and stirred for 1 hour. The blending ratio is as follows: Ethylonaimin (Poly+mar) 3
0% in water O, 42% Carbon De
sulflde O,63%So
dium l1ydroxida
10.21% Sodium D1
ethyldithocarba@ata O
,75% Sodium dihlosulfata
0.06% So
dium 5 ulfide ls
,oo%Distilled retar
72.92% The above composition liquid is 1% by weight of the dust, sludge, and sludge.
The purpose can be achieved by adding in the range of ~10% and kneading thoroughly (about 10 minutes).
尚含有重金属が多量に含有されＥる場合は上記組成液に
対し数％のポルトランドセメントを添加すれば組成液の
添加量を増やす事なく処理できる。If a large amount of heavy metals are contained, it can be treated by adding several percent of Portland cement to the above composition solution without increasing the amount of the composition solution.
上記組成液を使用し電気ダストを処理した実施例を示す
。An example in which electrical dust was treated using the above composition liquid will be shown.
未処理ダスト 組成液による処】！！
ＩＰ ｂ １７．！＋ｖ／ｉ
０．３４ｍ／ｌＣｄ ２５．Ｏｑ／ｌ
０．０２１１に／ｌＡ ｓ Ｑ、
Ｏ１ａｇ／を以下 ０．０１ Ｎ
／ を以下Ｚｎ ６００ｑ八
０．１１．八Ｍｎ ２４．８ｑ八
ｏ、ｏｔｑ八昭へ６０年６月２４日
岡山工業技術センターＮα５８３
手続補正書（方式）
昭和６２年５月２６日
１、事件の表示 昭和６０年特許願第２２２６０１号２
、発明の名称 ダスト、汚泥、スラッヂ中に含有される
重金属の無毒性化剤の製造法
３、補正をする者
事件との関係 特許出願人Treatment with untreated dust composition solution]! !
IP b 17. ! +v/i
0.34m/lCd 25. Oq/l
0.0211/lA s Q,
O1ag/ or less 0.01 N
/ below Zn 600q8
0.11. 8Mn 24.8q8
o, otq to Yasaki June 24, 1960 Okayama Industrial Technology Center Nα583 Procedural amendment (method) May 26, 1988 1, Indication of case Patent Application No. 222601 of 1985 2
, Title of the invention Method for manufacturing a detoxifying agent for heavy metals contained in dust, sludge, and sludge 3 Relationship with the case of the person making the amendment Patent applicant
Claims (1)
ている人体に有毒な重金属イオンを無毒性化するに当り
ポリエチレンイミンと二流化炭素と水酸化ナトリウムを
反応させこれにジエチルジチルカルバミンソーダ、チオ
硫酸ナトリウム、硫化ソーダを加え適量の水を加え混合
攪拌してなるダスト、汚泥、スラッヂ中に含まれる有害
重金属の無毒性化剤の製造方法For the purpose of environmental conservation, in order to detoxify heavy metal ions that are toxic to the human body contained in dust, sludge, sludge, etc., polyethyleneimine, carbon disulfide, and sodium hydroxide are reacted, and diethyldithylcarbamine soda and thio A method for producing a detoxifying agent for harmful heavy metals contained in dust, sludge, and sludge by adding sodium sulfate and sodium sulfide, adding an appropriate amount of water, and mixing and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60222601A JPS62258788A (en) | 1985-10-05 | 1985-10-05 | Preparation of detoxifying agent for heavy metal contained in dust and sludge |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60222601A JPS62258788A (en) | 1985-10-05 | 1985-10-05 | Preparation of detoxifying agent for heavy metal contained in dust and sludge |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62258788A true JPS62258788A (en) | 1987-11-11 |
Family
ID=16785024
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60222601A Pending JPS62258788A (en) | 1985-10-05 | 1985-10-05 | Preparation of detoxifying agent for heavy metal contained in dust and sludge |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62258788A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01218672A (en) * | 1988-02-29 | 1989-08-31 | Nkk Corp | Method for treating alkali-containing fly ash |
| JPH06166862A (en) * | 1992-08-19 | 1994-06-14 | Nippon Soda Co Ltd | Fixative for heavy metal of fly ash and detoxication method |
-
1985
- 1985-10-05 JP JP60222601A patent/JPS62258788A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01218672A (en) * | 1988-02-29 | 1989-08-31 | Nkk Corp | Method for treating alkali-containing fly ash |
| JPH06166862A (en) * | 1992-08-19 | 1994-06-14 | Nippon Soda Co Ltd | Fixative for heavy metal of fly ash and detoxication method |
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