JPS62215643A - Flame-retardant resin composition - Google Patents
Flame-retardant resin compositionInfo
- Publication number
- JPS62215643A JPS62215643A JP5788486A JP5788486A JPS62215643A JP S62215643 A JPS62215643 A JP S62215643A JP 5788486 A JP5788486 A JP 5788486A JP 5788486 A JP5788486 A JP 5788486A JP S62215643 A JPS62215643 A JP S62215643A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- manufactured
- ethylene
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003063 flame retardant Substances 0.000 title claims description 23
- 239000011342 resin composition Substances 0.000 title claims description 22
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 19
- 239000000203 mixture Substances 0.000 claims abstract description 57
- 239000005038 ethylene vinyl acetate Substances 0.000 claims abstract description 29
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims abstract description 29
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims abstract description 18
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 9
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- 230000003712 anti-aging effect Effects 0.000 claims description 28
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 11
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 229920005672 polyolefin resin Polymers 0.000 claims description 7
- 150000001412 amines Chemical class 0.000 claims description 5
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- 229920003244 diene elastomer Polymers 0.000 claims 1
- -1 hydrated alumina Chemical class 0.000 abstract description 23
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 22
- 238000002156 mixing Methods 0.000 abstract description 12
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000003963 antioxidant agent Substances 0.000 abstract description 7
- 230000003078 antioxidant effect Effects 0.000 abstract description 7
- 239000007789 gas Substances 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 3
- 239000011574 phosphorus Substances 0.000 abstract description 3
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000002530 phenolic antioxidant Substances 0.000 abstract 1
- 230000000391 smoking effect Effects 0.000 abstract 1
- 229920002943 EPDM rubber Polymers 0.000 description 18
- 238000000034 method Methods 0.000 description 16
- 229920000573 polyethylene Polymers 0.000 description 16
- 239000004698 Polyethylene Substances 0.000 description 15
- 238000004132 cross linking Methods 0.000 description 15
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 13
- 239000006229 carbon black Substances 0.000 description 13
- 235000019241 carbon black Nutrition 0.000 description 13
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 13
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 10
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229910052802 copper Inorganic materials 0.000 description 8
- 239000010949 copper Substances 0.000 description 8
- 239000000945 filler Substances 0.000 description 8
- 239000003112 inhibitor Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 8
- 150000001451 organic peroxides Chemical class 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- UMHKOAYRTRADAT-UHFFFAOYSA-N [hydroxy(octoxy)phosphoryl] octyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OP(O)(=O)OCCCCCCCC UMHKOAYRTRADAT-UHFFFAOYSA-N 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 229910001868 water Inorganic materials 0.000 description 6
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 5
- 239000004014 plasticizer Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000004408 titanium dioxide Substances 0.000 description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 description 5
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 4
- 239000006087 Silane Coupling Agent Substances 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000032683 aging Effects 0.000 description 4
- 230000003679 aging effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920003051 synthetic elastomer Polymers 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- DXZMANYCMVCPIM-UHFFFAOYSA-L zinc;diethylphosphinate Chemical compound [Zn+2].CCP([O-])(=O)CC.CCP([O-])(=O)CC DXZMANYCMVCPIM-UHFFFAOYSA-L 0.000 description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 3
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 239000007983 Tris buffer Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- QBCOASQOMILNBN-UHFFFAOYSA-N didodecoxy(oxo)phosphanium Chemical compound CCCCCCCCCCCCO[P+](=O)OCCCCCCCCCCCC QBCOASQOMILNBN-UHFFFAOYSA-N 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- 239000001095 magnesium carbonate Substances 0.000 description 3
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 3
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical group CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- VETPHHXZEJAYOB-UHFFFAOYSA-N 1-n,4-n-dinaphthalen-2-ylbenzene-1,4-diamine Chemical compound C1=CC=CC2=CC(NC=3C=CC(NC=4C=C5C=CC=CC5=CC=4)=CC=3)=CC=C21 VETPHHXZEJAYOB-UHFFFAOYSA-N 0.000 description 2
- CWJHMZONBMHMEI-UHFFFAOYSA-N 1-tert-butylperoxy-3-propan-2-ylbenzene Chemical compound CC(C)C1=CC=CC(OOC(C)(C)C)=C1 CWJHMZONBMHMEI-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- VFBJXXJYHWLXRM-UHFFFAOYSA-N 2-[2-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]ethylsulfanyl]ethyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCSCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 VFBJXXJYHWLXRM-UHFFFAOYSA-N 0.000 description 2
- BIISIZOQPWZPPS-UHFFFAOYSA-N 2-tert-butylperoxypropan-2-ylbenzene Chemical compound CC(C)(C)OOC(C)(C)C1=CC=CC=C1 BIISIZOQPWZPPS-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229920005601 base polymer Polymers 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 150000004677 hydrates Chemical class 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052845 zircon Inorganic materials 0.000 description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 2
- REBKUVYQFXSVNO-NSCUHMNNSA-N (3E)-1,1-dichloropenta-1,3-diene Chemical compound C\C=C\C=C(Cl)Cl REBKUVYQFXSVNO-NSCUHMNNSA-N 0.000 description 1
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ROLAGNYPWIVYTG-UHFFFAOYSA-N 1,2-bis(4-methoxyphenyl)ethanamine;hydrochloride Chemical compound Cl.C1=CC(OC)=CC=C1CC(N)C1=CC=C(OC)C=C1 ROLAGNYPWIVYTG-UHFFFAOYSA-N 0.000 description 1
- CGHIBGNXEGJPQZ-UHFFFAOYSA-N 1-hexyne Chemical compound CCCCC#C CGHIBGNXEGJPQZ-UHFFFAOYSA-N 0.000 description 1
- PWNBRRGFUVBTQG-UHFFFAOYSA-N 1-n,4-n-di(propan-2-yl)benzene-1,4-diamine Chemical compound CC(C)NC1=CC=C(NC(C)C)C=C1 PWNBRRGFUVBTQG-UHFFFAOYSA-N 0.000 description 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- XGIDEUICZZXBFQ-UHFFFAOYSA-N 1h-benzimidazol-2-ylmethanethiol Chemical compound C1=CC=C2NC(CS)=NC2=C1 XGIDEUICZZXBFQ-UHFFFAOYSA-N 0.000 description 1
- HBMFCGVCUHLQPN-UHFFFAOYSA-N 1h-benzimidazol-2-ylmethanethiol;zinc Chemical compound [Zn].C1=CC=C2NC(CS)=NC2=C1 HBMFCGVCUHLQPN-UHFFFAOYSA-N 0.000 description 1
- JFGVTUJBHHZRAB-UHFFFAOYSA-N 2,6-Di-tert-butyl-1,4-benzenediol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1O JFGVTUJBHHZRAB-UHFFFAOYSA-N 0.000 description 1
- OLQFXOWPTQTLDP-UHFFFAOYSA-N 2-(2-hydroxyethoxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCO OLQFXOWPTQTLDP-UHFFFAOYSA-N 0.000 description 1
- BMFMTNROJASFBW-UHFFFAOYSA-N 2-(furan-2-ylmethylsulfinyl)acetic acid Chemical compound OC(=O)CS(=O)CC1=CC=CO1 BMFMTNROJASFBW-UHFFFAOYSA-N 0.000 description 1
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 1
- KRDXTHSSNCTAGY-UHFFFAOYSA-N 2-cyclohexylpyrrolidine Chemical compound C1CCNC1C1CCCCC1 KRDXTHSSNCTAGY-UHFFFAOYSA-N 0.000 description 1
- MZZYGYNZAOVRTG-UHFFFAOYSA-N 2-hydroxy-n-(1h-1,2,4-triazol-5-yl)benzamide Chemical compound OC1=CC=CC=C1C(=O)NC1=NC=NN1 MZZYGYNZAOVRTG-UHFFFAOYSA-N 0.000 description 1
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- XBWSIEWHSVIKTB-UHFFFAOYSA-N 3,5-ditert-butyl-4-[(2,6-ditert-butyl-4-hydroxyphenyl)methyl]phenol Chemical compound CC(C)(C)C1=CC(O)=CC(C(C)(C)C)=C1CC1=C(C(C)(C)C)C=C(O)C=C1C(C)(C)C XBWSIEWHSVIKTB-UHFFFAOYSA-N 0.000 description 1
- UIGULSHPWYAWSA-UHFFFAOYSA-N 3-amino-4-[(2-methylpropan-2-yl)oxy]-4-oxobutanoic acid;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)C(N)CC(O)=O UIGULSHPWYAWSA-UHFFFAOYSA-N 0.000 description 1
- 125000005917 3-methylpentyl group Chemical group 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- IELAVJDOWOPAMD-UHFFFAOYSA-N 4-n-hexylbenzene-1,4-diamine Chemical compound CCCCCCNC1=CC=C(N)C=C1 IELAVJDOWOPAMD-UHFFFAOYSA-N 0.000 description 1
- JHWGFJBTMHEZME-UHFFFAOYSA-N 4-prop-2-enoyloxybutyl prop-2-enoate Chemical compound C=CC(=O)OCCCCOC(=O)C=C JHWGFJBTMHEZME-UHFFFAOYSA-N 0.000 description 1
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- SRORDPCXIPXEAX-UHFFFAOYSA-N CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC.CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC Chemical compound CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC.CCCCCCCCCCCCCP(CCCCCCCCCCCCC)(O)(OCCCCCCCC)OCCCCCCCC SRORDPCXIPXEAX-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- 239000004641 Diallyl-phthalate Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- UTGQNNCQYDRXCH-UHFFFAOYSA-N N,N'-diphenyl-1,4-phenylenediamine Chemical compound C=1C=C(NC=2C=CC=CC=2)C=CC=1NC1=CC=CC=C1 UTGQNNCQYDRXCH-UHFFFAOYSA-N 0.000 description 1
- KUGRPPRAQNPSQD-UHFFFAOYSA-N OOOOO Chemical compound OOOOO KUGRPPRAQNPSQD-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 241000159610 Roya <green alga> Species 0.000 description 1
- 241000872198 Serjania polyphylla Species 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- LIQDVINWFSWENU-UHFFFAOYSA-K aluminum;prop-2-enoate Chemical compound [Al+3].[O-]C(=O)C=C.[O-]C(=O)C=C.[O-]C(=O)C=C LIQDVINWFSWENU-UHFFFAOYSA-K 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 description 1
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
- FQUNFJULCYSSOP-UHFFFAOYSA-N bisoctrizole Chemical compound N1=C2C=CC=CC2=NN1C1=CC(C(C)(C)CC(C)(C)C)=CC(CC=2C(=C(C=C(C=2)C(C)(C)CC(C)(C)C)N2N=C3C=CC=CC3=N2)O)=C1O FQUNFJULCYSSOP-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- OAKHANKSRIPFCE-UHFFFAOYSA-L calcium;2-methylprop-2-enoate Chemical compound [Ca+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O OAKHANKSRIPFCE-UHFFFAOYSA-L 0.000 description 1
- TXTCTCUXLQYGLA-UHFFFAOYSA-L calcium;prop-2-enoate Chemical compound [Ca+2].[O-]C(=O)C=C.[O-]C(=O)C=C TXTCTCUXLQYGLA-UHFFFAOYSA-L 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000006232 furnace black Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- DZBOAIYHPIPCBP-UHFFFAOYSA-L magnesium;2-methylprop-2-enoate Chemical compound [Mg+2].CC(=C)C([O-])=O.CC(=C)C([O-])=O DZBOAIYHPIPCBP-UHFFFAOYSA-L 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- DWLAVVBOGOXHNH-UHFFFAOYSA-L magnesium;prop-2-enoate Chemical compound [Mg+2].[O-]C(=O)C=C.[O-]C(=O)C=C DWLAVVBOGOXHNH-UHFFFAOYSA-L 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- YWFWDNVOPHGWMX-UHFFFAOYSA-N n,n-dimethyldodecan-1-amine Chemical compound CCCCCCCCCCCCN(C)C YWFWDNVOPHGWMX-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000003348 petrochemical agent Substances 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000006234 thermal black Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 125000005590 trimellitic acid group Chemical class 0.000 description 1
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- XKMZOFXGLBYJLS-UHFFFAOYSA-L zinc;prop-2-enoate Chemical compound [Zn+2].[O-]C(=O)C=C.[O-]C(=O)C=C XKMZOFXGLBYJLS-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Organic Insulating Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 り東上ｍ旦！ 本発明は、難燃性樹脂組成物に関する。[Detailed description of the invention] Tojo mdan! The present invention relates to a flame retardant resin composition.
の ｉ びその間 ぐ
従来難燃性樹脂組成物としては、ハロゲン含有ポリマー
、又は非ハロゲン系ポリマーに有機ハロゲン系難燃剤を
加えたものが知られている。しかしながら、このような
難燃性樹脂組成物を利用して得られる製品は、いずれも
焔中から遠ざけると自己消炎するものの、火災時等のよ
うに高温の焔中にあるときは最後まで燃焼が継続されて
しまい、発煙が生じたり、また熱分解によって腐食性や
毒性の強い酸性ガスが発生したり、樹脂が熱溶融して流
れる等の欠点があった。As conventional flame-retardant resin compositions, those prepared by adding an organic halogen-based flame retardant to a halogen-containing polymer or a non-halogen-based polymer are known. However, although all products obtained using such flame-retardant resin compositions self-extinguish when kept away from flames, they do not burn to the end when exposed to high-temperature flames such as during a fire. If the process is continued, there are disadvantages such as smoke generation, highly corrosive and toxic acid gas generated by thermal decomposition, and resin melting and flowing.
一方、オレフィン系樹脂にハロゲンフリーの難燃剤を配
合し、上記欠点を解消しようとする試みもなされている
。しかしながら、ハロゲンフリーの難燃剤を配合した樹
脂組成物の難燃性を実用上充分な程度に高めるためには
、ハロゲンフリーの難燃剤を大量に配合する必要が生じ
、そのために次のような欠点が生ずるを避は得ない。即
ち、オレフィン系樹脂にハロゲンフリーの難燃剤を大量
に配合した場合、得られる樹脂組成物の成形品はその機
械的特性、殊に機械的強度及び伸び、老化特性並びに電
気特性が著しく損われ、実用上不都合を生ずる。このよ
うにハロゲンフリーの樹脂組成物にあっては、難燃性に
優れ且つその成形品に実用上充分な機械的特性及び電気
特性を付与し得る難燃性樹脂組成物は未だ完全には開発
されていないのが現状である。On the other hand, attempts have also been made to overcome the above drawbacks by blending halogen-free flame retardants with olefin resins. However, in order to increase the flame retardance of a resin composition containing a halogen-free flame retardant to a practically sufficient degree, it is necessary to incorporate a large amount of the halogen-free flame retardant, which results in the following drawbacks: It is inevitable that this will occur. That is, when a large amount of halogen-free flame retardant is blended into an olefin resin, the mechanical properties, especially mechanical strength and elongation, aging properties, and electrical properties of the molded article of the resulting resin composition are significantly impaired. This causes practical inconvenience. As described above, in the case of halogen-free resin compositions, flame-retardant resin compositions that have excellent flame retardancy and can impart practically sufficient mechanical and electrical properties to molded products have not yet been completely developed. The current situation is that this has not been done.
４題点を解決するための 段
本発明の目的は、難燃性に優れたハロゲンフリーの樹脂
組成物を提供することにある。Steps for Solving the 4 Problems An object of the present invention is to provide a halogen-free resin composition with excellent flame retardancy.
本発明の他の目的は、その成形品に実用上充分な機械的
特性及び電気特性を付与し得る難燃性樹脂組成物を提供
することにある。Another object of the present invention is to provide a flame-retardant resin composition that can impart practically sufficient mechanical and electrical properties to molded articles.
本発明の他の特徴は、以下の記載から明らかにされるで
あろう。Other features of the invention will become apparent from the description below.
本発明の難燃性樹脂組成物は、（１）（Ａ）オレフィン
系樹脂約１００型組部、（Ｂ）金属酸化物の水和物約５
０〜約３００”１４部及び（Ｃ）含リンチタネートカッ
プリング剤約０．０５〜約５重量部からなるものである
。The flame retardant resin composition of the present invention comprises (1) (A) about 100 parts of olefin resin, (B) about 5 parts of hydrate of metal oxide.
0 to about 300'' and 14 parts by weight of (C) a phthalate-containing coupling agent.
本発明において、（１）（Ａ）成分として用いられるオ
レフィン系樹脂としては、例えばエチレン−プロピレン
ゴム（ＥＰＭ） 、エチレン−プロピレン−ジエンゴム
（ＥＰＤＭ）等のオレフィンの共重合体、インブチレン
−イソプレンゴム（ＩＩＲ）、エチレン−エチルアクリ
レート共重合体（ＥＥＡ）、エチレン−酢酸ビニル共重
合体（ＥＶＡ）等のビニル系モノマーとオレフィンとの
共重合体等を例示できる。In the present invention, the olefin resin used as component (1) (A) includes, for example, olefin copolymers such as ethylene-propylene rubber (EPM), ethylene-propylene-diene rubber (EPDM), and inbutylene-isoprene rubber. (IIR), ethylene-ethyl acrylate copolymer (EEA), ethylene-vinyl acetate copolymer (EVA), and other copolymers of vinyl monomers and olefins.
これらのオレフィン系樹脂の中でもＥＶＡ、ＥＰＭ及び
ＥＰＤＭが好適である。Among these olefin resins, EVA, EPM and EPDM are preferred.
ＥＶＡとしては、例えば酢酸ビニル含有量が約５〜約７
０重但％のエチレン−酢酸ビニル共重合体、具体的には
酢酸ビニル含有量が約５〜約２５重量％であって且つＡ
ＳＴＭ Ｄ１２３８で測定したメルトインデックス（
ＭＦＲ＞が約０．５〜約２０であるエチレン−酢酸ビニ
ル共重合体、酢酸ビニル含有量が約３０〜約７５＠伍％
であって且つ１００℃でのムーニー粘度が約５〜約６５
でおるエチレン−酢酸ビニル共重合体等を挙げることが
できる。これらの中でも特に酢酸ビニル含有量が約１０
〜約２５重量％であって且つＭＦＲが約１．０〜約１０
であるエチレン−酢酸ビニル共重合体、酢酸ビニル含有
量が約４０〜約７３重量％でおって且つ１００’Ｃでの
ムーニー粘度が約１５〜約４０であるエチレン−酢酸ビ
ニル共重合体が好適である。その具体例としては、例え
ばＭＦＲが３．０、酢酸ビニル倉口が１５重量％のエチ
レン−酢酸ビニル共重合体（エバテートＨ２Ｏ１１、住
人化学社製）、ＶＦＲが１．５、酢酸ビニル含量が２０
重量％のエチレン−酢酸ビニル共重合体〔エバテートＨ
２Ｏ３１、住人化学社製〕、ＶＦＲが２．０１酢酸ビニ
ル含量が１５重量％のエチレン−酢酸ビニル共重合体（
ＮＬＪＣ８４５０゜日本ユニカー社製）、ＭＦＲが２．
０、酢酸ビニル含量が２５重憬％のエチレン−酢酸ビニ
ル共重合体〔ユカロンＶ５０５、三菱油化社製〕、１０
０℃でのムーニー粘度が約２０、酢酸ビニル含量が４５
重口％のエチレン−酢酸ビニル共重合体〔レバプレン４
５０１バイ工ル社製）、１００℃でのムーニー粘度が約
２０、酢酸ビニル含ｍが５０重社％のエチレン−酢酸ビ
ニル共重合体〔レバプレン５００、バイエル社製〕等が
挙げられる。For example, EVA has a vinyl acetate content of about 5 to about 7.
0% by weight ethylene-vinyl acetate copolymer, specifically a vinyl acetate content of about 5 to about 25% by weight, and
Melt index measured by STM D1238 (
Ethylene-vinyl acetate copolymer with MFR> of about 0.5 to about 20, vinyl acetate content of about 30 to about 75@5%
and has a Mooney viscosity of about 5 to about 65 at 100°C.
Examples include ethylene-vinyl acetate copolymer. Among these, especially the vinyl acetate content is about 10
~25% by weight and an MFR of about 1.0 to about 10
An ethylene-vinyl acetate copolymer having a vinyl acetate content of about 40 to about 73% by weight and a Mooney viscosity of about 15 to about 40 at 100'C is preferred. It is. Specific examples include an ethylene-vinyl acetate copolymer (Evatate H2O11, manufactured by Sumima Kagaku Co., Ltd.) with an MFR of 3.0 and a vinyl acetate content of 15% by weight, a VFR of 1.5, and a vinyl acetate content of 20%.
% by weight of ethylene-vinyl acetate copolymer [evatate H
2O31, manufactured by Sumima Kagaku Co., Ltd.], an ethylene-vinyl acetate copolymer with a VFR of 2.01 and a vinyl acetate content of 15% by weight (
NLJC8450゜manufactured by Nippon Unicar), MFR is 2.
0. Ethylene-vinyl acetate copolymer with a vinyl acetate content of 25% by weight [Yukalon V505, manufactured by Mitsubishi Yuka Co., Ltd.], 10
Mooney viscosity at 0℃ is approximately 20, vinyl acetate content is 45
Weight% ethylene-vinyl acetate copolymer [levaprene 4
501 manufactured by Bayer Co., Ltd.), an ethylene-vinyl acetate copolymer having a Mooney viscosity of about 20 at 100°C and a vinyl acetate content of 50% (Levaprene 500, manufactured by Bayer Co., Ltd.), and the like.
ＥＰＭ及びＥＰＤＭとしてｔよ、従来公知のものを広く
使用できる。好ましいＥＰＭとしては、例えばエチレン
とプロピレンとの共重合体であって、プロピレン含有量
が約１５〜約７０モル％、好ましくは約２０〜約５０モ
ル％のものを挙げることができる。また、好ましいＥＰ
ＤＭとしては、例えばエチレンとプロピレンとに更に第
３成分としてジクロロペンタジェン、エチリデンノルボ
ルネン、１，４−へキサジエン等を共重合させたエチレ
ン−プロピレン−ジエン三元共重合体であって、沃素価
で示される第３成分道が約８〜約２５、好ましくは約９
〜約１５、生ゴムムーニー粘度が約３０〜約１００、好
ましくは約３０〜約６０の範囲のものを挙げることがで
きる。上記ＥＰＭ又はＥＰＤＭの例としては、ＥＰ２１
、巳Ｐ５１〔いずれも日本合成ゴム社製〕、ニスプレン
３０１、ニスプレン５０１Ａ、ニスプレン５０５〔いず
れも住人化学社製）、ＥＰ丁４０２１、ＥＰＴＩＯ４５
〔いずれも三菱油化社製〕等が挙げられる。As EPM and EPDM, a wide variety of conventionally known ones can be used. Preferred EPMs include, for example, copolymers of ethylene and propylene with a propylene content of about 15 to about 70 mol%, preferably about 20 to about 50 mol%. Also, preferred EP
DM is, for example, an ethylene-propylene-diene ternary copolymer obtained by copolymerizing ethylene and propylene with a third component such as dichloropentadiene, ethylidene norbornene, or 1,4-hexadiene, which has a high iodine value. The third component path represented by is about 8 to about 25, preferably about 9
to about 15, raw rubber Mooney viscosity is in the range of about 30 to about 100, preferably about 30 to about 60. An example of the above EPM or EPDM is EP21
, Mi P51 [all manufactured by Nippon Synthetic Rubber Co., Ltd.], Nisprene 301, Nisprene 501A, Nisprene 505 [all manufactured by Sumima Kagaku Co., Ltd.], EP-4021, EPTIO45
[All manufactured by Mitsubishi Yuka Co., Ltd.] and the like.
ＥＥＡとしては、例えばＶＦＲが約０．４〜約３５でお
り且つエチルアクリレート（ＥＡ）含有量が約５〜約３
０重量％であるものを挙げることができ、好ましくはＶ
ＦＲが約０．５〜約２８でおり且つＥＡ含有量が約５〜
約２０重ｉ％で必るものを例示できる。その具体例とし
ては、例えばＮＵＣ−６２２０ＳＤＱＤＪ−６１８２、
ＮＩＪＣ−６５７０（いずれも日本ユニカー社製）、Ａ
１７０、Ａ２７０．Ｔ４３４０−１６ （いずれも日本
石油化学社製）、ＸＣ−３００Ｅ、Ｃ−４００Ｋ（いず
れも三菱油化社製） 、Ａ−７０１、Ａ＝７０２、Ａ−
７０６、Ａ−７１０（いずれも三片・デュポンポリケミ
カル社製〕等が挙げられる。As EEA, for example, VFR is about 0.4 to about 35 and ethyl acrylate (EA) content is about 5 to about 3.
0% by weight, preferably V
FR is about 0.5 to about 28 and EA content is about 5 to about
An example of what is necessary at about 20% by weight can be given. Specific examples include NUC-6220SDQDJ-6182,
NIJC-6570 (all manufactured by Nippon Unicar), A
170, A270. T4340-16 (all manufactured by Nippon Petrochemicals), XC-300E, C-400K (all manufactured by Mitsubishi Yuka), A-701, A=702, A-
706, A-710 (all manufactured by Mikata DuPont Polychemical Company), and the like.
上記ＥＶＡ、ＥＰＭ、ＥＰＤＭ又はＥＥｌ：、架橋され
たものであるのが好ましい。この架橋ＥＶＡ、ＥＰＭ、
ＥＰＤＭ又はＥＥＡとしＴも、従来公知のものを広く使
用でき、具体的には上記ＥＶＡ、ＥＰＭＳＥＰＤＭ又は
ＥＥＡに有機過酸化物を添加し、加熱処理して架橋させ
たもの、上記ＥＶＡ、ＥＰＭ、ＥＰＤＭ又はＥＥＡに電
子線を照射シテ架橋ＥＶＡ、ＥＰＭ、ＥＰＤＭ又はＥＥ
Ａにしたものミ水架橋性ＥＶＡ、ＥＰＭ、ＥＰＤＭ又は
ＥＥＡを架橋させたもの等を例示できる。EVA, EPM, EPDM, or EEl: Preferably, it is crosslinked. This cross-linked EVA, EPM,
As EPDM or EEA, a wide variety of conventionally known ones can be used. Specifically, the above EVA, EPMS EPDM or EEA to which an organic peroxide is added and crosslinked by heat treatment, and the above EVA, EPM, EPDM Or cross-link EVA, EPM, EPDM or EE by irradiating electron beam on EEA.
Examples of A include those obtained by crosslinking water-crosslinkable EVA, EPM, EPDM, or EEA.
本発明では、（Ａ）成分として上記ＥＶＡとＥＰＭ及び
／又はＥＰＤＭとの混合物を使用することもできる。Ｅ
ＶＡとＥＰＭ及び／又はＥＰＤＭとの配合割合としては
、特に限定されず広い範囲内から適宜選択できるが、通
常重量比で前者：後者＝約９５〜５０：約５〜５０．好
ましくは前者：後者＝約９０〜７０：約１０〜３０とす
るのがよい。In the present invention, a mixture of the above EVA and EPM and/or EPDM can also be used as component (A). E
The blending ratio of VA and EPM and/or EPDM is not particularly limited and can be appropriately selected within a wide range, but the usual weight ratio is former: latter = about 95-50: about 5-50. Preferably, the former: the latter = about 90-70: about 10-30.
本発明では、（Ａ）成分として上記ＥＥＡとＥＰＭ及び
／又はＥＰＤＭとの混合物を使用することもできる。Ｅ
ＥＡとＥＰＭ及び／又はＥＰＤＭとの配合割合としては
、特に限定されず広い範囲内から適宜選択できるが、通
常型」比で前者：後者＝約９５〜５０：約５〜５０．好
ましくは前者：後者＝約９０〜７０：約１０〜３０とす
るのがよい。In the present invention, a mixture of the above EEA and EPM and/or EPDM can also be used as component (A). E
The blending ratio of EA and EPM and/or EPDM is not particularly limited and can be appropriately selected from a wide range, but the ratio of the former to the latter = about 95 to 50: about 5 to 50. Preferably, the former: the latter = about 90-70: about 10-30.
また本発明の上記（１）（Ａ）成分には、少量の直鎮状
ポリエチレンが混合されていてもよい。Further, a small amount of straight-line polyethylene may be mixed with the component (1) (A) of the present invention.
ここで直鎖状ポリエチレンとは、炭素数４〜１６のオレ
フィンとエチレンとの共重合体であって、密度が０．９
０より大きく且つ０．９６以下であり、ＭＦＲが０．１
〜２０である本質的に直鎖状のポリエチレンをいう。斯
かる直鎖状ポリエチレンは、例えば下記に示す方法によ
り製造される。Here, linear polyethylene is a copolymer of olefin having 4 to 16 carbon atoms and ethylene, and has a density of 0.9
Greater than 0 and less than or equal to 0.96, and MFR is 0.1
-20 essentially linear polyethylene. Such linear polyethylene is produced, for example, by the method shown below.
即ち、エチレンと炭素数４〜１６のオレフィンとの混合
物を触媒の存在下低圧下にて重合させることにより製造
される。エチレンとオレフィンとの混合割合としては、
通常前者１００重量部当り後者を約３〜約２０重量部、
好ましくは約５〜約１０重量部とするのがよい。使用さ
れる触媒としては、例えばシリカ、アルミナ、ジルコニ
ア、シリカ・アルミナを担体とした酸化クロムで代表さ
れる所謂フィリップス触媒、元素の周期律表第１Ｖ族〜
第■族遷移金属化合物と第工族〜第１Ｖ族の有機金属化
合物との組合せにより生成するチーグラー触媒等が挙げ
られる。チーグラー触媒の具体例としては、ＴｉＣ９ｔ
とアルキルアルミ（例えばＡＱ２ （Ｅｉａ ＞Ｃ６
０、ＡＱ ＣＥｔ’）２ＣＱ、ＡＱＥｉ３等）との組合
せを例示できる。更には、ｎ−８ＬＪ２ ＭＧ ・１／
６ ＡＱ Ｅ ’ｊ３の如き有１１ｈ’クネシウム化合
物と前記Ｔｉ化合物と有機金属ハライドとの３者の混合
物を触媒として使用してもよい。斯かる触媒の使用量と
しては、エチレンと炭素数４〜１６のオレフィンとの混
合物１００重量部当り通常的０．０’ｌ〜約５０重量部
、好ましくは約０．０５〜約２０重量部とするのがよい
。またこの重合の際の圧力は、通常的常圧〜約２０気圧
、好ましくは約３〜約２０気圧とするのがよい。これら
直鎖状ポリエチレンの好ましい゛具体的な製造法として
は、特開昭５１−１１２８９１号公報、特開昭５５−４
５７２２８公報、特開昭５５−１１３５４２号公報、米
国特許第３９５７４４８号明細書等に記載された方法を
例示できる。That is, it is produced by polymerizing a mixture of ethylene and an olefin having 4 to 16 carbon atoms under low pressure in the presence of a catalyst. The mixing ratio of ethylene and olefin is as follows:
Usually about 3 to about 20 parts by weight of the latter per 100 parts by weight of the former,
Preferably, the amount is about 5 to about 10 parts by weight. Catalysts used include, for example, silica, alumina, zirconia, so-called Phillips catalysts represented by chromium oxide using silica/alumina as carriers, and catalysts from Groups 1V to 15 of the Periodic Table of Elements.
Examples include Ziegler catalysts produced by a combination of a Group Ⅰ transition metal compound and an organometallic compound of Groups 1 to 1V. A specific example of Ziegler catalyst is TiC9t
and alkyl aluminum (e.g. AQ2 (Eia > C6
0, AQ CEt')2CQ, AQEi3, etc.) can be exemplified. Furthermore, n-8LJ2 MG ・1/
A mixture of the 11h'-cnesium compound such as 6 AQ E 'j3, the Ti compound, and an organometallic halide may be used as a catalyst. The amount of such catalyst used is usually 0.0'l to about 50 parts by weight, preferably about 0.05 to about 20 parts by weight, per 100 parts by weight of the mixture of ethylene and olefin having 4 to 16 carbon atoms. It is better to do so. The pressure during this polymerization is generally normal pressure to about 20 atm, preferably about 3 to about 20 atm. Preferred and specific manufacturing methods for these linear polyethylenes are disclosed in JP-A-51-112891 and JP-A-55-4.
Examples include methods described in JP-A-57228, JP-A-55-113542, and US Pat. No. 3,957,448.
本発明においては、上記直鎮状ポリエチレンの中でも、
該ポリエチレンを構成するエチレン連鎖に共重合される
コモノマーとしてのオレフィンが炭素数４〜１０程度の
ものが好適であり、より具体的にはコモノマーがブテン
−１、オクテン−１及び４−メチルペンテン−１が最も
好適である。In the present invention, among the above-mentioned straight-line polyethylene,
It is preferable that the olefin as a comonomer copolymerized with the ethylene chain constituting the polyethylene has about 4 to 10 carbon atoms, and more specifically, the comonomer is butene-1, octene-1, and 4-methylpentene-1. 1 is most preferred.
また上記直鎖状ポリエチレンの中でも、ＡＳＴＭＤｉ５
０５で測定した密度が約０．９１〜約０．９６のものが
好ましく、約０．９１〜約０．９４のものがより好まし
く、約０．９１’ｌ〜約０．９２５のものが最も好まし
い。更に上記直鎖状ポリエチレンの中でも、ＡＳＴＭ
Ｄ１２３８で測定したＶＦＲが約０．１〜約１０のも
のが好ましい。このような直鎖状ポリエチレンの具体例
としては、三菱ポリエチーＬＬ Ｈ２０Ｅ、Ｆ３０Ｆ
、Ｆ３０Ｈ（いずれも三菱油化社製）、ウルトゼツクス
２０２ＯＬ、３０１０Ｆ、３０２１Ｆ〔いずれも三菱油
化社製）、ＤＦＤＡ−７５４０〔ユニオンカーバイド社
製）、ＮＬＪＣＧ−５６５１、Ｇ５−６５０．ＧＲ３Ｎ
−７０４７、ＧＲ３Ｎ−７０４２（いずれも日本ユニカ
ー社製〕、出光ポリエチレン−Ｌ ０１３４ＨＳ０２
３４Ｈ〔いずれも出光石油化学社製〕等を例示できる。Also, among the above linear polyethylenes, ASTM Di5
The density measured by 05 is preferably about 0.91 to about 0.96, more preferably about 0.91 to about 0.94, and most preferably about 0.91'l to about 0.925. preferable. Furthermore, among the above linear polyethylenes, ASTM
Those having a VFR of about 0.1 to about 10 as measured by D1238 are preferred. Specific examples of such linear polyethylene include Mitsubishi Polyethylene LL H20E, F30F.
, F30H (all manufactured by Mitsubishi Yuka), Ultzex 202OL, 3010F, 3021F (all manufactured by Mitsubishi Yuka), DFDA-7540 (manufactured by Union Carbide), NLJCG-5651, G5-650. GR3N
-7047, GR3N-7042 (all manufactured by Nippon Unicar), Idemitsu polyethylene-L 0134HS02
34H [all manufactured by Idemitsu Petrochemical Co., Ltd.] and the like can be exemplified.
（１）（Ａ）成分中に混入して使用される上記直鎖状ポ
リエチレンの量としては、（１）（Ａ）成分全量中に通
常約１８重量％以下、好ましくは約１５重量％以下とす
るのがよい。(1) The amount of the linear polyethylene mixed in component (A) is usually about 18% by weight or less, preferably about 15% by weight or less based on the total amount of component (1)(A). It is better to do so.
本発明において、（Ｂ）成分として使用される金属酸化
物の水和物としては、例えば元素の周期法律表第１ａ族
、第■ａ族、第１１ｂ族、第１Ｖ ａ族及び第１Ｖ ｂ
族に属する金属元素の酸化物の水和物並びにこれらと第
１ａ族もしくは第［ａ族に属する金属元素の炭酸塩との
複塩又は化合物が挙げられ、その具体例として例えば
ＡＱ２０３・ｎＨ２Ｏ（ｎは０．５〜６、特に２．５〜
３．５の数） （以下「水和アルミナ」という）、Ｍｇ
０−ｎＨ２Ｏ（ｎは０．５〜５、特に１．５〜２．５の
数） （以下「水和マグネシア」という） 、５ａｏ６
９Ｈ２０，ＢａＯ・Ｈ２０、Ｚｒ０・２Ｈ２０，５ｎｏ
−ｎＨ２Ｏ（ｎは１〜１０の数）、３Ｍ（ＪＣＯ３・Ｍ
（Ｊ（ＯＨ）２・３日２０１６Ｍｇｏ−ＡＱ２０３ ・
Ｈ２０、Ｎ ａ ＣＯ３・ Ａ Ｑ ２０３ ・ ｎ
ト１２０ （ｎ は １〜１０の数）、Ｎａ２ｏ−８
２０３・５日２０等を挙げることができる。本発明では
、これらを１種又は２種以上混合して使用することがで
きる。これら金属酸化物の水和物の粒径としては、通常
約１０μｍ以下、特に約５μｍ以下が適当であり、実用
的には約０．１〜約５μｍが好適である。またこれら金
属酸化物の水和物の中でも特に水和アルミナ及び水和マ
グネシアが好適でおる。水和アルミナの具体例としては
、ハイシライトＨ−４２Ｍ〔昭和軽金属社製）、８１４
０３、Ｂ１４０３Ｓ〔いずれも日本軽金属社製〕等を例
示できる。In the present invention, the metal oxide hydrate used as component (B) includes, for example, Group 1a, Group Ⅰa, Group 11b, Group 1V a, and Group 1V b of the periodic table of elements.
Examples include hydrates of oxides of metal elements belonging to Group 1a or Group A, and double salts or compounds of these with carbonates of metal elements belonging to Group 1a or Group a. is 0.5 to 6, especially 2.5 to
3.5) (hereinafter referred to as "hydrated alumina"), Mg
0-nH2O (n is a number from 0.5 to 5, especially from 1.5 to 2.5) (hereinafter referred to as "hydrated magnesia"), 5ao6
9H20, BaO・H20, Zr0・2H20, 5no
-nH2O (n is a number from 1 to 10), 3M (JCO3・M
(J(OH) 2nd and 3rd 2016 Mgo-AQ203 ・
H20, N a CO3・A Q 203・n
120 (n is a number from 1 to 10), Na2o-8
203.5 days, 20, etc. can be mentioned. In the present invention, one type or a mixture of two or more types of these can be used. The particle size of these metal oxide hydrates is usually about 10 μm or less, particularly about 5 μm or less, and practically about 0.1 to about 5 μm is suitable. Among the hydrates of these metal oxides, hydrated alumina and hydrated magnesia are particularly suitable. Specific examples of hydrated alumina include Hysilite H-42M (manufactured by Showa Light Metal Co., Ltd.), 814
03, B1403S [all manufactured by Nippon Light Metal Co., Ltd.], and the like.
また水和マグネシアとしては、特にＢＥＴ法による比表
面積が３〜１５ｍ２／ｇであって、ルーゼツクス法によ
る粒度分布において５μ以上のものが０％であるものが
好適である。その具体例としては、キス７５Ｂ、キスマ
５Ａ、キスマ５Ｅ（いずれも協和化学工業社製）、ＫＸ
−４３（旭硝子社製〕等を例示できる。The hydrated magnesia preferably has a specific surface area of 3 to 15 m2/g by the BET method and 0% of particles of 5 microns or more in the particle size distribution determined by the Rouzecks method. Specific examples include Kisuma 75B, Kisuma 5A, Kisuma 5E (all manufactured by Kyowa Chemical Industry Co., Ltd.), KX
-43 (manufactured by Asahi Glass Co., Ltd.) and the like.
本発明では上記（８）成分を通常＜１）（Ａ）成分１０
０童量部に対して約５０〜約３００重量部、好ましくは
約７０〜約２５０重量部、より好ましくは約８０〜約２
００重量部配合するのがよい。In the present invention, the above component (8) is usually <1) component (A) 10
About 50 to about 300 parts by weight, preferably about 70 to about 250 parts by weight, more preferably about 80 to about 2 parts by weight
It is preferable to mix 00 parts by weight.
（Ｂ）成分の配合量が３００重量部を越えると、得られ
る樹脂組成物の機械的特性が低下するという欠点が生ず
る。また逆に（Ｂ）成分の配合量が５０重量部より少な
いと、得られる樹脂組成物の難燃性が低下するという欠
点が生ずる。If the amount of component (B) exceeds 300 parts by weight, there will be a drawback that the mechanical properties of the resulting resin composition will deteriorate. On the other hand, if the amount of component (B) is less than 50 parts by weight, the flame retardancy of the resulting resin composition will be reduced.
本発明において、（Ｃ）成分として用いられる含リンチ
タネートカップリング剤としては、例えば一般式
％式％））
〔式中、Ｒは炭素数３〜１２のアルキル基を示す。In the present invention, the nitrate-containing coupling agent used as component (C) is, for example, represented by the general formula %) [wherein R represents an alkyl group having 3 to 12 carbon atoms].
Ｒ′は炭素数１〜１８のアルキル基を示す。〕で表わさ
れる有機チタネート類を好ましく例示できる。その具体
例としてはテトライソプロビルジ（ジオクチルホスファ
イト）チタネート（ＫＲ−４１８１ケンリッチ社製〕、
テトラオクチルジ（ジトリデシルホスファイト）チタネ
ート（ＫＲ−４６Ｂ、同上社製〕、テトライソプロビル
ジ（ジラウリルホスファイト）チタネート（ＫＲ−３６
０、同上社製〕、テトラ（２，２−ジアリルオキシメチ
ル−１−ブトキシ）ジ（ジ−トリデシル）ホスファイト
チタネート（ＫＲ−５５、同上社製〕、インプロピルト
リス（ジオクチルごロホスフエート）チタネート（ＫＲ
−３８３、同上社製〕、ビス（ジオクチルピロホスフェ
ート）オキシアセテートチタネート（ＫＲ−１３８３，
同上社製〕、ビス（ジオクチルピロホスフェート）エチ
レンチタネート（ＫＲ−２３８３、同上社製〕等を例示
できる。これらの中でも特にテトライソプロビルジ（ジ
オクチルホスファイト）チタネート、テトライソプロビ
ルジ（ジラウリルホスファイト）チタネート、テトラ（
２，２−ジアリルオキシメチル−１−ブトキシ）ジ（ジ
−トリデシル）ホスファイトチタネート、イソプロピル
トリス（ジオクチルピロホスフェート）チタネート及び
ビス（ジオクチルピロホスフェート）オキシアセテート
チタネートが好適である。R' represents an alkyl group having 1 to 18 carbon atoms. Preferred examples include organic titanates represented by the following. Specific examples include tetraisoprovir di(dioctyl phosphite) titanate (KR-4181 manufactured by Kenrich);
Tetraoctyl di(ditridecyl phosphite) titanate (KR-46B, manufactured by the same company), tetraisoprovir di(dilauryl phosphite) titanate (KR-36)
0, manufactured by the same company], tetra(2,2-diallyloxymethyl-1-butoxy) di(di-tridecyl) phosphite titanate (KR-55, manufactured by the same company), inpropyltris(dioctylgolophosphate) titanate ( KR
-383, manufactured by the same company], bis(dioctylpyrophosphate) oxyacetate titanate (KR-1383,
Bis(dioctylpyrophosphate) ethylene titanate (KR-2383, manufactured by the same company), bis(dioctyl pyrophosphate) ethylene titanate (KR-2383, made by the same company), etc. Among these, especially tetraisoprovir di(dioctyl phosphite) titanate, tetraisoprovir di(dilauryl phosphite) Titanate, Tetra (
2,2-diallyloxymethyl-1-butoxy) di(di-tridecyl) phosphite titanate, isopropyl tris(dioctyl pyrophosphate) titanate and bis(dioctyl pyrophosphate) oxyacetate titanate are preferred.
本発明では、上記含リンチタネートカップリング剤を（
１）（Ａ）成分１００重量部当り、通常的０．０５〜約
５重量部、好ましくは約０．２〜約３重量部配合するの
がよい。該カップリング剤の配合量が５重量部を越える
と、得られる組成物の難燃性、機械的特性等の性質が低
下するという欠点が生ずる。また逆に該カップリング剤
の配合量が０．０５重量部より少ないと、得られる組成
物の加工性が低下する等の欠点が生ずる。In the present invention, the above-mentioned nitrate-containing coupling agent (
1) It is usually 0.05 to about 5 parts by weight, preferably about 0.2 to about 3 parts by weight, per 100 parts by weight of component (A). If the amount of the coupling agent exceeds 5 parts by weight, there will be a disadvantage that the properties such as flame retardance and mechanical properties of the resulting composition will be reduced. On the other hand, if the amount of the coupling agent is less than 0.05 parts by weight, disadvantages such as reduced processability of the resulting composition will occur.
本発明においては、老化防止剤を本発明組成物中に配合
するのが好ましい。老化防止剤としては、例えばヒンダ
ードフェノール系老化防止剤、アミン系老化防止剤等を
挙げることができる。ヒンダードフェノール系老化防止
剤としては、従来公知のものを広く使用でき、例えばテ
トラキス〔メチレン−５−（３，５−ジーｔｅｒｔ−ブ
チルー４−ヒドロキシフェノール）プロピオネート〔メ
タン〔イルガノックス１０１０．チバガイギー社製〕、
２．２−チオ゛〔ジエチル−ビス−３−（３，５−ジー
ｔｅｒｔ−ブチルー４−ヒドロキシフェノール）プロピ
オネート〕 〔イルガノックス１０３５、チバガイギー
社製）、４．４’ −チオビス（３−メチル−６−ｔｅ
ｒｔ−ブチルフェノール） 〔サントノックス、モンサ
ント社製）、４．４’−メチレン−ビス（３，５−ジー
ｔｅｒｔ−ブチルフェノール）〔アイオノツクス２２０
、英ＩＣＩ社製〕等を挙げることができる。またアミン
系老化防止剤としては、従来公知のものを広く使用でき
、具体例としては、例えばアンチオキシダントＤＤＡ
（ＤＤＡ、バイエル社製）、Ｎ、Ｎ’−ジ−β−ナフチ
ル−ｐ−フェニレンジアミン〔ツクランクホワイト、入
内新興社製）、Ｎ、Ｎ’−ジフェニル−ｐ−フェニレン
ジアミン〔ツクラックＤＰ、大内新興社製）、Ｎ、Ｎ’
−ジイソプロピル−ｐ−フェニレンジアミン〔アンチ
オキシダントＮｏ、２３、デュポン社製）、Ｎ、Ｎ’
−ビス（１−メチル−ヘプチル＞−ｐ−フェニレンジア
ミン（Ｅａｓｔｍａｎｃｈｅｍ、社製、Ｅａｓｔｚｏｎ
ｅ３０ ） 、フェニル、ヘキシル−ｐ−フェニレンジ
アミン（ＰｅｎｎＷａ Ｉ を社製、ＡＮＴＯ３“Ｅ”
）、Ｎ、Ｎ’ −ビス（１−エチル。In the present invention, it is preferable to incorporate an anti-aging agent into the composition of the present invention. Examples of anti-aging agents include hindered phenol-based anti-aging agents and amine-based anti-aging agents. As the hindered phenol anti-aging agent, a wide variety of conventionally known anti-aging agents can be used, such as tetrakis[methylene-5-(3,5-di-tert-butyl-4-hydroxyphenol)propionate]methane[Irganox 1010. Manufactured by Ciba Geigy],
2.2-thio゛[diethyl-bis-3-(3,5-di-tert-butyl-4-hydroxyphenol)propionate] [Irganox 1035, manufactured by Ciba Geigy), 4.4'-thiobis(3-methyl- 6-te
rt-butylphenol) [Santonox, manufactured by Monsanto Company], 4,4'-methylene-bis(3,5-di-tert-butylphenol) [Ionox 220
, manufactured by ICI, UK]. Furthermore, as the amine-based anti-aging agent, a wide variety of conventionally known anti-aging agents can be used, and specific examples include the antioxidant DDA.
(DDA, manufactured by Bayer), N,N'-di-β-naphthyl-p-phenylenediamine [Tsukrank White, manufactured by Iriuchi Shinko Co., Ltd.], N,N'-diphenyl-p-phenylenediamine [Tsukrank DP, Large (manufactured by Uchishinsha), N, N'
-diisopropyl-p-phenylenediamine [antioxidant No. 23, manufactured by DuPont), N, N'
-bis(1-methyl-heptyl>-p-phenylenediamine (manufactured by Eastmanchem, Eastzon)
e30), phenyl, hexyl-p-phenylenediamine (manufactured by PennWa I, ANTO3 “E”
), N,N'-bis(1-ethyl.
３−メチルペンチル）−ｐ−フェニレンジアミン〔υｎ
ｉ ｒｏｙａ １社製、Ｆｌｅｘｚｏｎ ８−１）
、Ｎ、 Ｎ’ −ジ−β−ナフチル−ｐ−フェニレンジ
アミン〔精工化学社製、Ｎｏｎｆｌｅｘ Ｆ ） 、２
−メルカプトメチルベンズイミダゾール〔入内新興社製
、ツクラックＭＭＢ）、２−メルカプトメチルベンズイ
ミダゾール亜鉛塩〔入内新興社製、ツクラックＭＭ８Ｚ
〕等を挙げることができる。本発明では、これら老化防
止剤を１種又は２種以上混合して使用することができる
。3-methylpentyl)-p-phenylenediamine [υn
Manufactured by i roya 1, Flexzon 8-1)
, N, N'-di-β-naphthyl-p-phenylenediamine [Nonflex F, manufactured by Seiko Kagaku Co., Ltd.], 2
-Mercaptomethylbenzimidazole [manufactured by Iruuchi Shinko Co., Ltd., Tsukurak MMB], 2-mercaptomethylbenzimidazole zinc salt [manufactured by Iruuchi Shinko Co., Ltd., Tsukurak MM8Z
] etc. In the present invention, these anti-aging agents may be used alone or in combination of two or more.
特に本発明では、特に（Ａ）成分として酢酸ビニル含有
量が約１０〜約２５重量％であって且つＭＦＲが約１．
０〜約１０であるエチレン−酢酸ビニル共重合体を使用
する場合には、老化防止剤としてヒンダードフェノール
系老化防止剤を使用するのが好ましい。また（Ａ）成分
として酢酸ビニル含有量が約４０〜約７３重最％でおっ
て且つ１００℃でのムーニー粘度が約１５〜約４０であ
るエチレン−酢酸ビニル共重合体を使用する場合には、
老化防止剤としてヒンダードフェノール系老化防止剤又
はアミン系老化防止剤を使用するのが特に好ましい。更
に（１）（Ａ）成分としてＥＰＭヤＥＰＤＭを使用する
場合には、老化防止剤としてアミン系老化防止剤を使用
するのが特に好ましい。In particular, in the present invention, the vinyl acetate content as component (A) is about 10 to about 25% by weight, and the MFR is about 1.
When using an ethylene-vinyl acetate copolymer having a molecular weight of 0 to about 10, it is preferred to use a hindered phenol antioxidant as the antioxidant. Further, when using an ethylene-vinyl acetate copolymer having a vinyl acetate content of about 40 to about 73% by weight and a Mooney viscosity of about 15 to about 40 at 100°C as component (A), ,
Particular preference is given to using hindered phenolic antiaging agents or amine antiaging agents as antiaging agents. Furthermore, when EPM or EPDM is used as component (1) (A), it is particularly preferable to use an amine-based anti-aging agent as the anti-aging agent.
上記老化防止剤の配合ｍとしては、通常上記（１）（Ａ
）成分１００重量部当り約０．１〜約５重量部、好まし
くは約０．２〜約２．５ｍｍ部、より好ましくは約０．
３〜約１．５重１部とするのがよい。老化防止剤の配合
量が５重量部を越えても、老化防止効果はそれ程向上せ
ず、経済上好ましくない。また逆に老化防止剤の配合量
が０．１重量部より少ないと、老化防止効果が発揮され
難くなり好ましくない。The formulation m of the anti-aging agent is usually (1) (A).
) per 100 parts by weight of component, from about 0.1 to about 5 parts by weight, preferably from about 0.2 to about 2.5 mm, more preferably about 0.
It is preferable to use 1 part by 3 to about 1.5 parts. Even if the amount of the anti-aging agent exceeds 5 parts by weight, the anti-aging effect will not improve significantly and this is not economically preferable. On the other hand, if the amount of anti-aging agent is less than 0.1 part by weight, the anti-aging effect will be difficult to exhibit, which is undesirable.
本発明においては、難燃助剤として赤リン、硼酸亜鉛、
二酸化チタン等を本発明組成物中に配合するのが好まし
い。ここで赤リンとしては、従来市販されているものを
広く使用でき、例えば赤リン分が約８０％以上で必って
、乾燥減債が約０．８％以下且つ７４メツシ１篩残分が
約７％以下であるものが好ましい。また、前記赤リンの
表面がフェノール−ホルマリン樹脂等の熱硬化性樹脂で
被覆されたものが好ましい。その具体例としては、ノー
バレット＃１２０．ノーバレット＃１２０ＵＦ （いず
れも燐化学工業社製）等を挙げることができる。In the present invention, red phosphorus, zinc borate,
It is preferable to incorporate titanium dioxide or the like into the composition of the present invention. Here, as the red phosphorus, a wide variety of commercially available products can be used, for example, the red phosphorus content must be about 80% or more, the drying loss is about 0.8% or less, and the sieve residue of 74 mesh is Preferably, it is about 7% or less. Moreover, it is preferable that the surface of the red phosphorus is coated with a thermosetting resin such as phenol-formalin resin. A specific example is No Bullet #120. Examples include No Bullet #120UF (both manufactured by Rin Kagaku Kogyo Co., Ltd.).
硼酸亜鉛としては、従来市販されているものを広く使用
でき、例えば化学式２ＺｎＯ・３Ｂ２０３ ・３．５Ｈ
２０で示され、粒子径が約２〜約１０μでその結晶密度
が約２．６〜約２、ｓｃｉ／ｃｒｎ３で必るものが好ま
しい。その具体例としては□、硼酸亜鉛２３３５ （英
国３０ｒａＸ社製〕等を挙げることができる。As zinc borate, conventionally commercially available ones can be widely used, for example, those with the chemical formula 2ZnO・3B203・3.5H
20 with a particle size of about 2 to about 10 microns and a crystal density of about 2.6 to about 2, sci/crn3. Specific examples include □, Zinc Borate 2335 (manufactured by 30raX, UK), and the like.
二酸化チタンとしては、従来市販されているものを広く
使用でき、例えば少なくとも約９０％以上のＴ ｔ ０
２を含み且つその粒度が１００メツシユ篩全通でおるも
の、少なくとも約９０％以上のＴｆＯ２を含み、１４９
μ篩残分が０％であって水分的０．７％以下のもの等を
好ましく例示できる。より具体的には、タイトーンＡ−
１５０、タイトーンＲ−６５０（いずれも堺化学工業社
製〕等が挙げられる。As titanium dioxide, conventionally commercially available titanium dioxide can be widely used. For example, titanium dioxide of at least about 90% or more
2 and whose particle size passes through a 100 mesh sieve, contains at least about 90% TfO2, and has a particle size of 149
Preferred examples include those in which the μ-sieve residue is 0% and the water content is 0.7% or less. More specifically, Taitone A-
150, Titone R-650 (all manufactured by Sakai Chemical Industry Co., Ltd.), and the like.
本発明では、これら難燃助剤を通常（１）（Ａ）成分１
００重量部当り約０．５〜約５０重量部、好ましくは約
２〜約２５重量部配合するのがよい。難燃助剤の配合値
が５０重量部を越えると、得られる樹脂組成物の機械的
特性が低下する傾向となるので好ましくない。また逆に
難燃助剤の配合量が０．５重置部より少ないと、難燃助
剤添加による効果が認められなくなる傾向となるので好
ましくない。In the present invention, these flame retardant aids are usually used as (1) (A) component 1
0.5 to about 50 parts by weight, preferably about 2 to about 25 parts by weight. If the blending value of the flame retardant aid exceeds 50 parts by weight, the mechanical properties of the resulting resin composition tend to deteriorate, which is not preferred. On the other hand, if the amount of the flame retardant aid is less than 0.5 parts, the effect of adding the flame retardant aid tends to be lost, which is not preferable.
本発明では、本発明組成物中に更にシランカップリング
剤を配合することができる。シランカップリング剤とし
ては、炭素−炭素二重結合もしくはエポキシ基を有する
トリアルコキシシランが好ましく、具体的にはビニル−
トリス（β−メトキシエ１〜キシシラン＞（Ａ１７２、
日本ユニカー社製）、？”−メタクリロキシプロピルト
リメトキシシラン（Ａ１７４、同上社製〕、β−（３，
４−エポキシシクロヘキシル）エチルトリメトキシシラ
ン（Ａ１８６、同上社製〕、Ｔ−グリシジルオキシプロ
ピルトリメトキシシラン（ＳＨ６０４０、トーレシリコ
ーン社製〕等を例示できる。これらの中でも特にｒ−メ
タクリロキシプロピルトリメトキシシランが好適である
。In the present invention, a silane coupling agent can be further blended into the composition of the present invention. As the silane coupling agent, trialkoxysilane having a carbon-carbon double bond or an epoxy group is preferable, specifically a vinyl-carbon double bond or a trialkoxysilane having an epoxy group.
Tris(β-methoxy 1~xysilane>(A172,
Manufactured by Nippon Unicar), ? ”-methacryloxypropyltrimethoxysilane (A174, manufactured by the same company), β-(3,
Examples include 4-epoxycyclohexyl)ethyltrimethoxysilane (A186, manufactured by the same company), T-glycidyloxypropyltrimethoxysilane (SH6040, manufactured by Toray Silicone), etc. Among these, especially r-methacryloxypropyltrimethoxysilane. is suitable.
上記シランカップリング剤の配合量としては、通常上記
（１）（Ａ）成分１００重量部当り約０．１〜約５重量
部、好ましくは約０．３〜約３重量部、より好ましくは
約０．３〜約２重量部とするのがよい。該カップリング
剤の配合量が５＠量部を越えると、得られる樹脂組成物
の難燃性、耐熱性等が低下する傾向となるので好ましく
ない。また該カンプリング剤の配合量が０．１ｆｉｆｆ
１部より少なくなると、加工性が劣る傾向となる。The amount of the silane coupling agent blended is usually about 0.1 to about 5 parts by weight, preferably about 0.3 to about 3 parts by weight, more preferably about The amount is preferably 0.3 to about 2 parts by weight. If the amount of the coupling agent exceeds 5 parts, the flame retardance, heat resistance, etc. of the resulting resin composition will tend to decrease, which is not preferable. In addition, the amount of the camping agent added is 0.1fiff.
When the amount is less than 1 part, processability tends to be poor.
本発明では、架橋のために、本発明組成物中に有機パー
オキシドを配合するのが望ましい。有機パーオキシドと
しては、従来公知のものを広く使用でき、例えばｔｅｒ
ｔ−ブチルクミルパーオキシド〔カヤブチルＣ１化薬ヌ
ーリー社製〕、α、α′−ビス（ｔｅｒｔ−ブチルパー
オキシ−ｍ−イソプロピルベンゼン） 〔バーブチルＰ
、日本油脂社製〕、２．５−ジメチル−２，５−ジーｔ
ｅｒｔ−１チルパーオキシ）ヘキシン〔バーへキサ２５
Ｂ１日本油脂社製〕、ジクミルパーオキシド（バークミ
ル０１日本油脂社製）等を挙げることができる。これら
の中でも待にｔｅｒｔ−ブチルクミルパーオキシド、α
、α′−ビス（ｔｅｒｔ−ブチルパーオキシ−ｍ−イソ
プロピルベンゼン及びジクミルパーオキシドが好適であ
る。In the present invention, it is desirable to incorporate an organic peroxide into the composition of the present invention for crosslinking. As the organic peroxide, a wide variety of conventionally known organic peroxides can be used, such as ter
t-Butyl cumyl peroxide [manufactured by Kayabutyl C1 compound Nouri Co., Ltd.], α,α'-bis(tert-butylperoxy-m-isopropylbenzene) [Barbutyl P
, manufactured by NOF Corporation], 2,5-dimethyl-2,5-di-t
ert-1 tylperoxy) hexyne [barhexa25
B1 manufactured by NOF Corporation], dicumyl peroxide (Bark Mill 01 manufactured by NOF Corporation), and the like. Among these, tert-butylcumyl peroxide, α
, α'-bis(tert-butylperoxy-m-isopropylbenzene and dicumyl peroxide) are preferred.
上記有機パーオキシドの配合量としては、通常上記（Ａ
）成分１００重量部当り、約１〜約１０重但部、好まし
くは約１．５〜約５重量部とするのがよい。有機パーオ
キシドの配合量が１０＠量部を越えると、得られる組成
物の機械的特性、老化特性等の物性が低下する傾向とな
り好ましくない。また有機パーオキシドの配合量が１重
量部より少ないと、架橋効果が認められ難くなるので好
ましくない。The amount of the organic peroxide to be blended is usually the above (A
) per 100 parts by weight of the component, from about 1 to about 10 parts by weight, preferably from about 1.5 to about 5 parts by weight. If the amount of organic peroxide added exceeds 10 parts by weight, the physical properties such as mechanical properties and aging properties of the resulting composition tend to deteriorate, which is undesirable. Further, if the amount of organic peroxide blended is less than 1 part by weight, the crosslinking effect becomes difficult to be observed, which is not preferable.
更に本発明組成物中に架橋助剤を配合するのが好ましい
。架橋助剤としては、分子内に少なくとも２個以上の反
応性炭素−炭素二重結合含有基を有する化合物である限
り、従来公知のものを広く使用でき、具体的にはジビニ
ルベンゼン、ジアリルフタレート、ジアリルイソフタレ
ート、４，４′−イソプロピリデンジフェノールビス（
ジエチレングリコールメタクリレート）エーテル、トリ
アリルトリメリテート、２．２′−ビス（４−アクリロ
キシジェトキシフェニル）プロパン等の芳香族多官能性
化合物、５ｙｎ−ｉ、２−ポリブタジェン、１，４−ブ
タンジオールジアクリレート、Ｎ、Ｎ’−メチレンビス
アクリルアミド、エチレングリコールジメタクリレート
、ネオペンチルグリコールジメタクリレート、トリメチ
ロールプロパントリメタクリレート、ペンタエリスリト
ールテトラメタクリレート、１，６−ヘキサンジオール
ジアクリレート、ジエチレングリコールジメタクリレー
ト、トリエチレングリコールジメタクリレート、１，６
−ヘキサンジオールジアクリレート、テトラヘキサンジ
オールジメタクリレート等の脂肪族多官能性化合物、ト
リアリルイソシアヌレート、トリアリルシアヌレート、
トリアクリロイルへキサヒドロ−１，３，５−トリアジ
ン、ジアクリルクロレンデート等の脂肪族多官能性環状
化合物、アルミニウムアクリレート、アルミニウムメタ
クリレート、亜鉛アクリレート、亜鉛メタクリレート、
マグネシウムアクリレート、マグネシウムメタクリレー
ト、カルシウムアクリレート、カルシウムメタクリレー
ト、ジルコンアクリレート、ジルコンメタクリレート等
の含金属多官能性化合物等を等を例示できる。この中で
もトリアリルインシアヌレート、トリアリルシアヌレー
ト、トリアクリロイルへキサヒドロ−１，３，５−トリ
アジン等が特に好適である。Furthermore, it is preferable to incorporate a crosslinking aid into the composition of the present invention. As the crosslinking aid, a wide variety of conventionally known compounds can be used as long as the compound has at least two or more reactive carbon-carbon double bond-containing groups in the molecule, and examples thereof include divinylbenzene, diallylphthalate, diallyl isophthalate, 4,4'-isopropylidene diphenol bis(
Aromatic polyfunctional compounds such as diethylene glycol methacrylate) ether, triallyl trimellitate, 2,2'-bis(4-acryloxyjethoxyphenyl)propane, 5yn-i, 2-polybutadiene, 1,4-butanediol Diacrylate, N,N'-methylenebisacrylamide, ethylene glycol dimethacrylate, neopentyl glycol dimethacrylate, trimethylolpropane trimethacrylate, pentaerythritol tetramethacrylate, 1,6-hexanediol diacrylate, diethylene glycol dimethacrylate, triethylene glycol Dimethacrylate, 1,6
- Aliphatic polyfunctional compounds such as hexanediol diacrylate and tetrahexanediol dimethacrylate, triallyl isocyanurate, triallyl cyanurate,
Aliphatic polyfunctional cyclic compounds such as triacryloylhexahydro-1,3,5-triazine and diacrylchlorendate, aluminum acrylate, aluminum methacrylate, zinc acrylate, zinc methacrylate,
Examples include metal-containing polyfunctional compounds such as magnesium acrylate, magnesium methacrylate, calcium acrylate, calcium methacrylate, zircon acrylate, and zircon methacrylate. Among these, particularly preferred are triallyl cyanurate, triallyl cyanurate, triacryloylhexahydro-1,3,5-triazine, and the like.
本発明組成物中に配合される架橋助剤の優としては、通
常上記（１）（Ａ）成分１００重ｄ部当り約０．１〜約
１０重量部、好ましくは約０．３〜約５重量部とするの
がよい。架橋助剤の配合口が１０重量部より多くなると
、得られる樹脂組成物の機械的特性及び老化特性が低下
する傾向となり好ましくない。また逆に架橋助剤の配合
量が０．１重量部より少なくなると、架橋助剤の添加効
果が認められなくなるので好ましくない本発明の組成物
には、更に充填剤を配合するのが望ましい。充填剤とし
ては、従来公知のものを広く使用でき、例えばミストロ
ンペーパータルク等のタルク、炭酸マグネシウム、炭酸
カルシウム等の金属炭酸塩、酸化亜鉛、酸化マグネシウ
ム、′酸化ベリリウム、酸化硼素、酸化アルミニウム等
の金属酸化物、クレー、無水シリカ、黒鉛、グラファイ
ト、ＷＩＬ酸バリウム、リトポン等を例示できる。この
なかでも特にクレー、ミストロシペーパータルク及び炭
酸マグネシウムが好ましい。The crosslinking aid to be incorporated into the composition of the present invention is usually about 0.1 to about 10 parts by weight, preferably about 0.3 to about 5 parts by weight, per 100 parts by weight of component (1) (A). It is preferable to use parts by weight. If the amount of crosslinking aid added exceeds 10 parts by weight, the mechanical properties and aging properties of the resulting resin composition tend to deteriorate, which is not preferable. On the other hand, if the amount of the crosslinking aid is less than 0.1 parts by weight, the effect of the addition of the crosslinking aid will not be observed, so it is desirable to further incorporate a filler into the composition of the present invention, which is undesirable. As the filler, a wide variety of conventionally known fillers can be used, such as talc such as Mistron paper talc, metal carbonates such as magnesium carbonate and calcium carbonate, zinc oxide, magnesium oxide, beryllium oxide, boron oxide, aluminum oxide, etc. Examples include metal oxides, clay, anhydrous silica, graphite, graphite, barium WIL acid, and lithopone. Among these, clay, mystrosipaper talc and magnesium carbonate are particularly preferred.
斯かる充填剤の配合量としては、通常上記（１）（Ａ）
成分１００重量部当り約５〜約２００重量部、好ましく
は約１０〜約１５０重量部、より好ましくは約５〜約５
０重量部とするのがよい。充填剤の配合量が２００重量
部を越えると、得られる樹脂組成物の機械的特性が低下
する傾向となり好ましくない。また充填剤の配合量が５
重量部より少ないと、充填剤の添加効果が認められなく
なり好ましくない。The blending amount of such filler is usually the same as (1) (A) above.
from about 5 to about 200 parts by weight, preferably from about 10 to about 150 parts by weight, more preferably from about 5 to about 5 parts by weight per 100 parts by weight of component.
It is preferable to set it to 0 parts by weight. If the amount of filler added exceeds 200 parts by weight, the mechanical properties of the resulting resin composition tend to deteriorate, which is undesirable. Also, the amount of filler added is 5
If the amount is less than 1 part by weight, the effect of adding the filler will not be observed, which is not preferable.
本発明の組成物には、加工助剤として高級脂肪酸乃至そ
の金属塩を配合するのが好ましい。高級脂肪酸としては
、例えばステアリン酸、オレイン酸等を挙げることがで
き、また金属塩としては、例えば亜鉛塩、カルシウム塩
等を挙げることができる。The composition of the present invention preferably contains higher fatty acids or metal salts thereof as processing aids. Examples of higher fatty acids include stearic acid and oleic acid, and examples of metal salts include zinc salts and calcium salts.
上記高級脂肪酸乃至その金属塩の配合層としては、上記
（１）（Ａ）成分１００重量部当り通常的０．１〜約１
０重量部、好ましくは約０．５〜約５重量部とするのが
よい。高級脂肪酸乃至その金属塩の配合量が１０重量部
を越えると、得られる樹脂組成物の機械的特性等の性質
の低下を招くという欠点が生ずる傾向となる。またその
配合層が０．１重量部より少ないと、加工助剤としての
添加効果が認められなくなる。The layer containing the above-mentioned higher fatty acid or its metal salt is usually 0.1 to about 1% per 100 parts by weight of component (1) (A).
0 parts by weight, preferably about 0.5 to about 5 parts by weight. If the amount of the higher fatty acid or its metal salt exceeds 10 parts by weight, there will be a tendency for the resulting resin composition to deteriorate in properties such as mechanical properties. Moreover, if the amount of the blended layer is less than 0.1 part by weight, the effect of addition as a processing aid will not be recognized.
本発明の組成物中には、更に銅害防止剤を配合するのが
好適である。使用される銅害防止剤としては、従来公知
のものを広く使用でき、例えばＮ。It is preferable to further include a copper damage inhibitor in the composition of the present invention. As the copper damage inhibitor used, a wide variety of conventionally known ones can be used, such as N.
Ｎ′−ビス（３−（３’ 、５’ −ジーｔｅｒｔ−７
ｆルー４′ ヒドロキシフェニル）プロピオニル）ヒド
ラジン、（３−（Ｎ−サリチルロイル）アミノ−１，２
，４−テトラゾール）、Ｎ、Ｎ’ −ジベンザルオキサ
リルヒドラジド、Ｎ、Ｎ’ −ジサリチリデンオキサリ
ルヒドラジド等を例示できる。N'-bis(3-(3',5'-tert-7
f-4' hydroxyphenyl)propionyl)hydrazine, (3-(N-salicyloyl)amino-1,2
, 4-tetrazole), N,N'-dibenzaloxalylhydrazide, N,N'-disalicylideneoxalylhydrazide, and the like.
銅害防止剤の配合層としては、通常（１）（Ａ）成分１
００重量部当り約０．０２〜約５重量部、好ましくは約
０．１〜約２重口部とするのがよい。銅害防止剤の配合
量が５重邑部を越えても、銅害防止剤添加による効果が
それほど向上せず、経済的に好ましくない。また、銅害
防止剤の配合量が０．０２重量部より少ないと、調書防
止効果が発揮され難くなる。The layer containing the copper damage inhibitor usually contains (1) (A) component 1.
The amount is about 0.02 to about 5 parts by weight, preferably about 0.1 to about 2 parts by weight per 00 parts by weight. Even if the amount of the copper damage inhibitor exceeds 5, the effect of adding the copper damage inhibitor does not improve much, which is economically unfavorable. Furthermore, if the amount of the copper damage inhibitor is less than 0.02 parts by weight, the effect of preventing documentation will be difficult to exhibit.
また本発明の組成物にはカーボンブラックを配合するの
が好ましい。カーボンブラックとしては、従来公知のも
のを広く使用することができるが、その中でも好ましい
ものとしては、例えばＤＢＰ吸油量が１００〜１６０Ｃ
ｍ３／１００ｇで必ッてＡＳＴＭコードがＮ５３０−Ｎ
３５１として認識されるファーネスブラック、ＤＢＰ吸
油量が３０〜５０Ｃｍ３／１００ｇのザーマルブラック
等を例示できる。斯かるカーボンブラックとしては、具
体的にはＦＥＦカーボンブラック、ＨＡＦカーボンブラ
ック、ｌ５ＡＦカーボンブラツク、ＳＲＦカーボンブラ
ック等を例示でき、より具体的には例えばダイヤブラッ
クＨ１ダイヤブラックＨ３（いずれも三菱化成社製）、
ｙｕ＋ｃａｎ−３、Ｖｕ ｌ ｃａｎ−３Ｈ（いずれも
キャボット社製）、ジーストＨ１ジースト３Ｈ（いずれ
も東海電極社製）、ケツツエンブラックＨＡＦＣケツツ
エン社製〕等が挙げられる。この中でもダイヤブラック
Ｈ及びＶｕｌＣａｎ−３が好ましい。Further, it is preferable to incorporate carbon black into the composition of the present invention. As carbon black, a wide variety of conventionally known carbon blacks can be used, but among them, preferable carbon blacks include carbon blacks with a DBP oil absorption of 100 to 160C.
ASTM code must be N530-N for m3/100g
Examples include furnace black recognized as No. 351, thermal black with a DBP oil absorption of 30 to 50 Cm3/100g, and the like. Specific examples of such carbon black include FEF carbon black, HAF carbon black, 15AF carbon black, SRF carbon black, and more specifically, for example, Dia Black H1 Dia Black H3 (all manufactured by Mitsubishi Chemical Corporation). ),
Examples include yu+can-3, Vul can-3H (all manufactured by Cabot), GEEST H1, GEIST 3H (all manufactured by Tokai Electrode), Ketsutsuen Black HAFC (manufactured by Ketsutsuen), and the like. Among these, Diamond Black H and VulCan-3 are preferred.
本発明では、上記カーボンブラックを通常（１）（Ａ）
成分１００重母型光り約０．５〜約２００重量部、好ま
しくは約０．５〜約４０重量部、より好ましくは約１〜
約２０重母部とするのがよい。カーボンブラックの配合
量が２００重量部を越えると、得られる樹脂組成物の機
械的特性が損われる傾向となるので好ましくない。また
カーボンブラックの配合量が０．５重量部より少ないと
、灰化特性が発現され難くなるので好ましくない。In the present invention, the above carbon black is usually (1) (A)
Ingredients 100 to about 200 parts by weight, preferably from about 0.5 to about 40 parts by weight, more preferably from about 1 to about 200 parts by weight
It is preferable to set it to about 20 weights. If the amount of carbon black exceeds 200 parts by weight, it is not preferable because the mechanical properties of the resulting resin composition tend to be impaired. Further, if the amount of carbon black added is less than 0.5 parts by weight, it is not preferable because the ashing property will be difficult to develop.
本発明の組成物には、上記の各種成分の他に、各種の可
塑剤、顔料等を配合することができる。In addition to the above-mentioned various components, various plasticizers, pigments, etc. can be added to the composition of the present invention.
という傾向が生ずる。This tendency arises.
可塑剤としては、例えばナフテン系、アロマ系、プロセ
ス油、フタル酸エステル類、トリメリット酸エステル類
、エポキシレジン類等を例示でき、その配合量としては
、通常（Ａ）成分１００重向部当り約０．２〜約５０重
量部、好ましくは約１〜約１０＠ｉ部とするのがよい。Examples of plasticizers include naphthenic plasticizers, aromatic plasticizers, process oils, phthalic acid esters, trimellitic acid esters, epoxy resins, etc. The amount of the plasticizer is usually per 100 parts of component (A). From about 0.2 to about 50 parts by weight, preferably from about 1 to about 10 parts by weight.
顔料としては、例えばフタロシアニンブルー、クローム
イエロー、ベンガラ等を例示でき、その配合量としては
、通常（１）（Ａ）成分１００重量部当り約０．１〜約
２０重量部、好ましくは約５〜約１０重量部とするのが
よい。Examples of pigments include phthalocyanine blue, chrome yellow, red iron oxide, etc., and the amount thereof is usually about 0.1 to about 20 parts by weight, preferably about 5 to about 20 parts by weight, per 100 parts by weight of component (1) (A). The amount is preferably about 10 parts by weight.
本発明の樹脂組成物は、架橋して用いることができる。The resin composition of the present invention can be used after being crosslinked.
斯かる場合の架橋方法は、上記有機パーオキシドを用い
る方法の他、電子線のよる架橋方法、放射線による架橋
方法、水架橋による方法等を挙げることができる。Examples of the crosslinking method in such a case include, in addition to the method using the organic peroxide described above, a crosslinking method using an electron beam, a crosslinking method using radiation, a method using water crosslinking, and the like.
本発明の組成物は、上記の各種成分の所定量を適宜配合
し、パンバリーミキサー、ヘンシェルミキサー等を使用
して従来公知の方法に従い均一に混合することにより得
ることができる。上記各成分は全てを同時に混合するこ
ともできるが、カップリング剤は充填剤投入と同時に添
加するのがよい。また、（１）（Ａ）成分として２種以
上のポリマーを使用する場合、まずポリマーを均一に混
合した後、他の成分を混合するのがよい。The composition of the present invention can be obtained by suitably blending predetermined amounts of the above-mentioned various components and uniformly mixing them according to a conventionally known method using a Panbury mixer, a Henschel mixer, or the like. Although all of the above components can be mixed at the same time, it is better to add the coupling agent at the same time as the filler is added. Moreover, when using two or more types of polymers as component (1)(A), it is preferable to mix the polymers uniformly first and then mix the other components.
本発明の組成物を使用するに際しては、従来公知の各種
成形法を広く採用することができ、例えば本発明の組成
物をロールニーダ−等の混線機を用いて混練し、次いで
これを用途に応じて種々の形状に成形すればよい。When using the composition of the present invention, various conventionally known molding methods can be widely adopted. For example, the composition of the present invention is kneaded using a mixing machine such as a roll kneader, and then this is mixed according to the purpose. It may be molded into various shapes.
Ｒ皿Ω勲呈
本発明の組成物は、本質的にハロゲンフリーのため、火
災時等のように高温の焔中に放置された場合においても
、発煙が生じたり、また熱分解によって腐食性ガスや酸
性ガスが発生したりすることはなく、しかも優れた難燃
性、機械的強度、電気特性、耐老化性等を有している。Since the composition of the present invention is essentially halogen-free, it will not emit smoke or emit corrosive gases due to thermal decomposition even if it is left in a high-temperature flame such as during a fire. It does not generate any acid gas or gas, and has excellent flame retardancy, mechanical strength, electrical properties, aging resistance, etc.
従って本発明の組成物は、建材、パイプ、ホース、シー
ト、シートカバー、壁材、電線ケーブル（内部絶縁体及
び外部シース等）等の被覆材料として好適なものである
。Therefore, the composition of the present invention is suitable as a coating material for building materials, pipes, hoses, sheets, seat covers, wall materials, electric wires and cables (internal insulators, external sheaths, etc.), and the like.
就中、本発明の組成物は、電線ケーブルの絶縁被覆又は
シース被覆用の難燃性樹脂組成物として好適に用い得る
。斯かる場合本発明の組成物は、各種の通信ケーブル、
電カケープル、制御ケーブル等の導体上、内部半導電層
上等の適当な部位に電気絶縁層として用い、またこれら
ケーブル類の絶縁層上、外部半導Ｎ層上等の適当な部位
に保護層（シース）として用いることができ、これらい
ずれの場合にも該電線ケーブルに高度の難燃性、耐炎性
を付与せしめ得る。In particular, the composition of the present invention can be suitably used as a flame-retardant resin composition for insulation coating or sheath coating of electric wire cables. In such cases, the composition of the present invention can be used for various communication cables,
It is used as an electrical insulating layer on the conductors of power cables, control cables, etc., on the internal semiconducting layer, etc., and it is also used as a protective layer on the insulating layer of these cables, on the external semiconductor N layer, etc. (sheath), and in any of these cases, high flame retardancy and flame resistance can be imparted to the electric wire cable.
釆−茄−１ 以下に実施例を掲げて本発明をより一層明らかにする。Pot-Eggplant-1 Examples are given below to further clarify the present invention.
尚、以下の実施例で得られた試料の特性は、下記の方法
により試験した。In addition, the characteristics of the samples obtained in the following examples were tested by the following method.
く難燃性試験〉
本発明組成物（Ｎｏ、 １〜１８）を、室温〜８０℃の
２本ロールで２０分間混練後、１６０℃で３０分間プレ
ス成型して厚さ３．Ｑｍｍの試料シートを作成し、この
試料シートにつき、ＪＩＳ Ｋ ７２０１（酸素指
数法）に従い酸素指数（ＬＯＩ）を求め難燃性を評価す
る。Flame retardancy test> The compositions of the present invention (Nos. 1 to 18) were kneaded for 20 minutes with two rolls at room temperature to 80°C, and then press-molded at 160°C for 30 minutes to give a thickness of 3. A sample sheet of Qmm is prepared, and the oxygen index (LOI) of this sample sheet is determined according to JIS K 7201 (oxygen index method) to evaluate flame retardancy.
本発明組成物（ＮＯ，１９〜３６）を、１６０℃の２本
ロールで２０分間混練後、１８０℃で３０分間プレス成
型して厚さ３．Ｑｍｍの試料シートを作成し、この試料
シートにつき、ＪｔＳ Ｋ ７２０１（酸素指数法
）に従い酸素指数（ＬＯＩ）を求め難燃性を評価する。The compositions of the present invention (Nos. 19 to 36) were kneaded for 20 minutes with two rolls at 160°C, and then press-molded at 180°C for 30 minutes to a thickness of 3. A sample sheet of Qmm is prepared, and the oxygen index (LOI) of this sample sheet is determined according to JtS K 7201 (oxygen index method) to evaluate flame retardancy.
本発明組成物（ＮＯ，３７〜４４）を、１６０℃の２本
ロールで２０分間混練後、１７０℃で１０分間プレス成
型して厚さ３．□ｍｍの試料シートを作成し、この試料
シートをダイヤトロンＤＰ１０００型電子線加速器によ
って空気中で１５Ｍｒａｄｓの電子線照射を行なって架
橋した後、ＪＩＳ Ｋ ７２０１（酸素指数法）に
従い酸素指数（ＬＯＩ）を求め難燃性を評価する。The compositions of the present invention (Nos. 37 to 44) were kneaded for 20 minutes with two rolls at 160°C, and then press-molded at 170°C for 10 minutes to a thickness of 3. A sample sheet of □ mm was prepared, and this sample sheet was cross-linked by irradiation with an electron beam of 15 Mrads in air using a Diatron DP1000 type electron beam accelerator, and then the oxygen index (LOI) was determined according to JIS K 7201 (oxygen index method). Evaluate flame retardancy by determining
〈機械的特性〉
上記と同様に混練、成型して厚さ１ｍｍの試料シートを
作成し、この試料シートにつき、各特性を調べる。<Mechanical Properties> A sample sheet with a thickness of 1 mm is prepared by kneading and molding in the same manner as above, and each characteristic of this sample sheet is examined.
（１）１００％モジュラス（ｋｇ／ｍｍ ” ）ＡＳＴ
Ｍ Ｄ８８２による。(1) 100% modulus (kg/mm”) AST
According to MD882.
（２）２００％モジュラス（ｋｇ／ｌｔ＋ｍ ２）ＡＳ
ＴＭ Ｄ８８２による。(2) 200% modulus (kg/lt+m2) AS
According to TM D882.
（３）抗張力（ｋｇ／ｌＴＩＩＴ１２）ＡＳＴＭ Ｄ
８８２による。(3) Tensile strength (kg/lTIIT12) ASTM D
According to 882.
（４）伸び（％）
ＡＳＴＭ Ｄ８８２による。尚、本発明組成物Ｎｏ、
１〜１８においては、Ｊｉｓ Ｋ ６３０１ハ
ロ硫ゴム試験方法に準じてオートグラフで測定した。そ
して１５０％以上のものを○及び
１５０％以下のものをＸとして評価す
る。(4) Elongation (%) According to ASTM D882. In addition, the present invention composition No.
Nos. 1 to 18 were measured using an autograph according to JIS K 6301 halosulfur rubber test method. A value of 150% or more is evaluated as ○, and a value of 150% or less is evaluated as X.
くゲル分率（％）〉
上記難燃性試験に用いたと同一の試料シートにつき、Ａ
ＳＴＭ ０２７６５に従い測定する。Gel fraction (%)> For the same sample sheet used in the above flame retardancy test,
Measured according to STM 02765.
く電気特性〉
本発明組成物（Ｎｏ、 １〜１８〉を、空温〜８０℃の
２本ロールで２０分間混練後、１６０℃で３０分間プレ
ス加硫成型して厚さ１ｍｍの試料シートを作成する。ま
た本発明組成物（ＮＯ，１９〜３６）を、１６０℃の２
本ロールで ２０分間混練後、１８０℃で３０分間プレ
ス加硫成型して厚さ１ｍｍの試料シートを作成する。ま
た本発明組成物（Ｎｏ、３７〜４４）では、難燃性試験
で用いた試料シートと同一の成型、架橋方法で作成した
厚さ１ｍｍの試料シートを用いた。これら試料シートに
つき、ＪＩＳＣ２１２３に準拠して１．Ｃ） （ｏｈｍ
−ｃｍ）を求める。Electrical properties> The compositions of the present invention (Nos. 1 to 18) were kneaded for 20 minutes with two rolls at air temperature to 80°C, and then press-vulcanized and molded at 160°C for 30 minutes to form a sample sheet with a thickness of 1 mm. In addition, the compositions of the present invention (NO, 19 to 36) were heated at 160°C at 2°C.
After kneading with this roll for 20 minutes, press vulcanization molding was performed at 180° C. for 30 minutes to prepare a sample sheet with a thickness of 1 mm. Further, for the compositions of the present invention (Nos. 37 to 44), sample sheets with a thickness of 1 mm were used, which were created by the same molding and crosslinking method as the sample sheets used in the flame retardancy test. Regarding these sample sheets, 1. C) (ohm
-cm).
〈老化特性〉
本発明組成物Ｎｏ、 ’ｌ〜１８においては、上記電
気試験で用いたと同一の試料シートにつき、ＡＳＴＭ
Ｄ５７３に従い１３５℃×７日後の伸び残率（％）を
求める。伸び残率６０％以上を○、３０〜６０％をΔ及
び３０％以下を×として評価する。<Aging characteristics> In the compositions No. 1 to 18 of the present invention, the ASTM
The remaining elongation rate (%) after 7 days at 135°C is determined according to D573. A residual elongation rate of 60% or more is evaluated as ◯, 30 to 60% as Δ, and 30% or less as ×.
本発明組成物Ｎｏ、’１９〜４４においては、上記電気
特性試験で用いたと同一の試料シートにつき、ＡＳＴＭ
Ｄ５７３に従い１５０’ＣＸ４日後の抗張力残率（
％）及び伸び残率（％）を求める。For composition Nos. '19 to 44 of the present invention, the same sample sheets used in the above electrical property test were tested using ASTM
According to D573, tensile strength remaining after 150'CX4 days (
%) and remaining elongation rate (%).
また下記各実施例における各成分の記号は、次のものを
示す。In addition, the symbols of each component in each example below indicate the following.
〈ベースポリマー〉
Ａ−１・・・ＥＰＤＭ（日本合成ゴム社製、ＥＰ２’ｌ
、プロピレン含は＝３３％〕
Ａ−２・・・ＥＰＤＭ（日本合成ゴム社製、ＥＰ５’！
、プロピレン含徂＝２６％〕
Ａ−３・−ＥＰＭ（日本合成ゴム社製、ＥＰＯ２Ｐ）Ａ
−４・・・ＥＶＡｆ’バイエル社製、レバプレン４５０
、ＶＡ含有量＝４５重重置〕
Ａ−５・・・ＥＶＡ （バイエル社製、レバプレン５０
０、ＶＡ含有伍＝５０重伍％〕
Ａ−６・・・ＥＶＡ（住人化学社製、エバテートＨ２Ｏ
３１、ＭＦＲ＝１．５、■△含有框＝２０重量％〕
Ａ−７−ＥＶＡ（日本ユニカー社製、ＮＵＣ−８４５０
、ＶＦＲ＝２、ＶＡ含含有−１５重量％〕
Ａ−８・・・ＥＶＡ（三菱油化社製、ユカロンＶ５０５
、ＶＦＲ＝２．０、ＶＡ含有量＝２０重量％） ゛
Ａ−９・・・ＥＶＡ（住人化学社製、エバテートＨ２Ｏ
１Ｌ ＭＦＲ＝３．０１ＶＡ含有量＝１５重量％〕
Ａ−１０・・・ＥＥＡ（日本ユニカー社製、ＮＵＣ−６
５７０ＳＭＦＲ＝２０．ＥＡ含有量＝２５重量％）
Ａ−１１・・・ＥＥＡ（日本ユニカー社製、ＮＵＣ−６
２２０ＳＶＦＲ−４、ＥＡ含有量＝７重量％〕
Ａ−１２・・・ＥＥＡ（三片・デュポンポリケミカル社
製、Ａ７０１、ＶＦＲ＝５、ＥＡ含有最＝９重量％〕
Ａ−１３・・・ＥＥＡ（日本石油化学社製、Ａ１７０゜
ＶＦＲ＝０．７１、ＥＡ含有量＝
１５．６重量％）
Ａ−１４・・・ＥＥＡ（三菱油化社製、ＸＣ−３００Ｅ
、ＭＦＲ＝０．４、ＥＡ含有量＝１２重量％〕
Ａ−１５・・・直鎖状ポリエチレン〔三菱油化社製、ウ
ルトゼツクス２０２ＯＬ、ＭＦＲ＝
２．１、密度＝０．９２０）
Ａ−１６・・・直鎖状ポリエチレン〔三菱油化社製、三
菱ポリエチ−ＬＬＨ２０Ｅ、ＭＦＲ＝
０．５、密度＝０．９１８）
Ａ−１７・・・直鎖状ポリエチレン〔三菱油化社製、三
菱ポリエチーＬＬＦ３０Ｆ、ＭＦＲ＝
１．０、密度＝０．９２０）
く難燃剤〉
Ｂ−１・・・ＡＱ （ＯＨ）ａ （昭和軽金属社製、
ハイジライトト１４２Ｍ）
Ｂ−２・・・Ｍｑ（ＯＨ）２ （協和化学社製、キスマ
５Ｂ）
Ｂ−３・・・ｌ’ｖｌＱ （ＯＨ）２ （旭硝子社製、
ＫＸ−４〈カップリング剤〉
Ｃ−１・・・イソプロピルトリス（ジオクチルごロホス
フエート）チタネート〔ケンリッチ社製、ＫＲ３８Ｓ）
Ｃ−２・・・ビス（ジオクチルピロホスフェート）オキ
シアセテートチタネート〔ケンリッチ社製、ＫＲ１３８
Ｓ）
Ｃ−３・・・テトライソプロピルビス（ジラウリルホス
ファイト）チタネート〔ケンリッチ社製、ＫＲ−３６Ｇ
）
Ｃ−４・・・テトラ（２，２−ジアリルオキシメチル−
１−ブトキシ）ジ（ジ−トリデシル）ホスファイトチタ
ネート〔ケンリッチ社製、ＫＲ−５５）
Ｃ−５・・・ビス（ジオクチルごロホスフエート）エチ
レンヂタネート〔ケンリッチ社製、ＫＲ−２３８３）
〈添加剤〉
Ｄ−１・・・老化防止剤〔入内新興社製、ＭＢ）０−２
・・・老化防止剤〔チバガイギー社製、イルガノックス
１０１０．テトラキス〔メチレン−５−（３，５−ジー
ｔｅｒｔ−ブチルー４−ヒドロキシフェニル）プロピオ
ネートコメタン〕
Ｄ−３・・・老化防止剤〔入内新興社製、ツクラック３
００．４，４′−ジヒドロキシ−３゜３′−ジーｔｅｒ
ｔ−ブチルー５，５′−ジメチルジフェニルサルファイ
ド〕
Ｄ−４・・・老化防止剤〔チバガイギー社製、イルガノ
ックス１０３５、（３，５−ジーｔｅｒｔ−ブチルー４
−ヒドロキシフェノール）プロピオネート〕
Ｄ−５・・・老化防止剤（バイエル社製、アンチオキシ
ダントＯＤＡ）
Ｄ−６・・・老化防止剤〔入内新興社製、ツクランクＮ
５−６．２，２′−メチレンビス（４−メチル−５−ｔ
ｅｒｔ−ブチルフェノール）Ｄ−７・・・赤リン・・・
〔燐化学社製、ツバレッド＃１２０〕
Ｄ−８・・・硼酸亜鉛（Ｂｏｒａｘ社製、硼酸亜鉛＃Ｄ
−９・・・二酸化チタン〔堺化学工業社製、タイトーン
Ａ１５０）
Ｄ−１０・・・シランカップリング剤〔日本ユニカー社
製、Ａ１７４、〔γ−メタクリロキシプロピルトリメト
キシシラン〕〕
Ｄ−１１・・・ジクミルパーオキサイド〔三片石油化学
社製、ＤＣＰ）
Ｄ−１２・・・パーブチルＰ〔日本油脂社製〕Ｄ−１３
・・・カヤブチルＣ（化薬ヌーリー社製〕Ｄ−１４・・
・架橋助剤〔大束化学社製、ＴＡＦ、トリアクリロイル
へキサヒドロ−１，３，５−トリアジン〕
Ｄ−１５・・・トリアリルイソシアヌレート〔日本水素
工業社製、ＴＡＩＣ）
Ｄ−１６・・・酸化亜鉛
Ｄ−１１・・・炭酸マグネシウム
Ｄ−１８・・・ステアリン酸
Ｄ−１９・・・ステアリン酸亜鉛
Ｄ−２０・・・銅害防止剤〔アデカアーガス社製、ＭＡ
ＲＫ ＣＤＡ−１）
Ｄ−２１・・・銅害防止剤（チバガイギー社製、チヌビ
ン３２０〕
Ｄ−２２・・・ＨＡＦカーボン〔三菱化成社製、ダイヤ
ブランクＨ〕
Ｄ−２３・・・ＨＡＦカーボン〔キャボット社製、ｙａ
ｌｃａｎ−３）
Ｄ−２４・・・プロセス油〔ナフテン系、日本サン石油
社製、サンセン４２４０．粘度＝１５〜２Ｑｃｓｔ、比
重＝０．９２０）
Ｄ−２５・・・アエロジル
Ｄ−２６・・・シーノックス４１２Ｓ（白石カルシウム
社製〕
実施例
下記第１表に示すベースポリマー、難燃剤、含リンチタ
ネートカップリング剤及びその他の添加剤の所定量（重
量部）を混合して本発明組成物を得た。<Base polymer> A-1...EPDM (manufactured by Japan Synthetic Rubber Co., Ltd., EP2'l
, propylene content = 33%] A-2... EPDM (manufactured by Japan Synthetic Rubber Co., Ltd., EP5'!
, propylene content = 26%] A-3・-EPM (manufactured by Japan Synthetic Rubber Co., Ltd., EPO2P) A
-4...EVAf' Bayer, Levaprene 450
, VA content = 45 layers] A-5...EVA (manufactured by Bayer, Levaprene 50
0, VA content 50% by weight A-6...EVA (manufactured by Sumitomo Chemical Co., Ltd., Evatate H2O
31, MFR = 1.5, ■△ containing frame = 20% by weight] A-7-EVA (manufactured by Nippon Unicar Co., Ltd., NUC-8450
, VFR=2, VA content -15% by weight] A-8...EVA (manufactured by Mitsubishi Yuka Co., Ltd., Yucalon V505
, VFR = 2.0, VA content = 20% by weight) ゛A-9...EVA (manufactured by Sumitomo Chemical Co., Ltd., Evatate H2O
1L MFR = 3.01 VA content = 15% by weight] A-10... EEA (manufactured by Nippon Unicar Co., Ltd., NUC-6
570SMFR=20. EA content = 25% by weight) A-11... EEA (manufactured by Nippon Unicar Co., Ltd., NUC-6
220SVFR-4, EA content = 7% by weight] A-12...EEA (manufactured by Mikata DuPont Polychemical Co., Ltd., A701, VFR = 5, EA content = 9% by weight) A-13...EEA (Manufactured by Nippon Petrochemical Co., Ltd., A170° VFR = 0.71, EA content = 15.6% by weight) A-14... EEA (manufactured by Mitsubishi Yuka Co., Ltd., XC-300E
, MFR = 0.4, EA content = 12% by weight] A-15...Linear polyethylene [Mitsubishi Yuka Co., Ltd., Ultzex 202OL, MFR = 2.1, density = 0.920) A-16 ... Linear polyethylene [manufactured by Mitsubishi Yuka Co., Ltd., Mitsubishi Polyethylene-LLH20E, MFR = 0.5, density = 0.918] A-17... Linear polyethylene [manufactured by Mitsubishi Yuka Co., Ltd., Mitsubishi Polyethylene Co., Ltd.] LLF30F, MFR=1.0, density=0.920) Flame retardant> B-1...AQ (OH)a (manufactured by Showa Light Metal Co., Ltd.,
Hygilite 142M) B-2...Mq(OH)2 (manufactured by Kyowa Chemical Co., Ltd., Kisuma 5B) B-3...l'vlQ (OH)2 (manufactured by Asahi Glass Co., Ltd.,
KX-4 <Coupling agent> C-1...Isopropyl tris(dioctyl golophosphate) titanate [manufactured by Kenrich, KR38S] C-2...Bis(dioctylpyrophosphate) oxyacetate titanate [manufactured by Kenrich, KR138]
S) C-3...Tetraisopropyl bis(dilauryl phosphite) titanate [manufactured by Kenrich, KR-36G
) C-4...tetra(2,2-diallyloxymethyl-
1-Butoxy) di(di-tridecyl) phosphite titanate [manufactured by Kenrich, KR-55] C-5...Bis(dioctyl golophosphate) ethylene ditanate [manufactured by Kenrich, KR-2383] <Additive > D-1... Anti-aging agent [manufactured by Iriuchi Shinkosha, MB) 0-2
...Anti-aging agent [manufactured by Ciba Geigy, Irganox 1010. Tetrakis [methylene-5-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate comethane] D-3...Anti-aging agent [Manufactured by Irinai Shinko Co., Ltd., Tsukrak 3
00.4,4'-dihydroxy-3゜3'-diter
t-Butyl-5,5'-dimethyldiphenyl sulfide] D-4... Anti-aging agent [manufactured by Ciba Geigy, Irganox 1035, (3,5-di-tert-butyl-4
-Hydroxyphenol) propionate] D-5...Antioxidant (manufactured by Bayer AG, antioxidant ODA) D-6...Antioxidant [manufactured by Iriuchi Shinko Co., Ltd., Tsurank N
5-6.2,2'-methylenebis(4-methyl-5-t
ert-butylphenol) D-7...Red phosphorus...
[Manufactured by Rin Kagaku Co., Ltd., Tsubared #120] D-8... Zinc borate (manufactured by Borax Co., Ltd., Zinc borate #D
-9... Titanium dioxide [manufactured by Sakai Chemical Industry Co., Ltd., Titone A150] D-10... Silane coupling agent [manufactured by Nippon Unicar Co., Ltd., A174, [γ-methacryloxypropyltrimethoxysilane]] D-11. ... Dicumyl peroxide [manufactured by Mikata Petrochemical Co., Ltd., DCP] D-12 ... Perbutyl P [manufactured by NOF Corporation] D-13
... Kayabutyl C (manufactured by Kayaku Nouri Co., Ltd.) D-14...
・Crosslinking aid [manufactured by Ohtsuka Kagaku Co., Ltd., TAF, triacryloylhexahydro-1,3,5-triazine] D-15... Triallylisocyanurate [manufactured by Nippon Hydrogen Industry Co., Ltd., TAIC] D-16... Zinc oxide D-11...Magnesium carbonate D-18...Stearic acid D-19...Zinc stearate D-20...Copper damage inhibitor [Manufactured by Adeka Argus, MA
RK CDA-1) D-21...Copper damage inhibitor (manufactured by Ciba Geigy, Tinuvin 320) D-22...HAF carbon [manufactured by Mitsubishi Chemical Corporation, Diamond Blank H] D-23...HAF carbon [ Manufactured by Cabot, ya
lcan-3) D-24... Process oil [naphthenic, manufactured by Nippon Sun Oil Co., Ltd., Sansen 4240. Viscosity = 15-2Qcst, specific gravity = 0.920) D-25... Aerosil D-26... Seenox 412S (manufactured by Shiroishi Calcium Co., Ltd.) Example Base polymer shown in Table 1 below, flame retardant, phosphorus-containing A composition of the present invention was obtained by mixing predetermined amounts (parts by weight) of a titanate coupling agent and other additives.
第 １ 表
第 １ 表 （続 き）
第 １ 表 （続き）
第 １ 表 （続 き）
第 １ 表 （続き）
第 １ 表 （続 き）
第 １ 表 （続き）
へ−１１
第 １ 表 （続 き）
第 １ 表 （続 き）
第 １ 表 （続き）
第 １ 表 （続 き）
第 １ 表 （続 き）
第 １ 表 （続き）
第 １ 表 （続 き）
第 １ 表 （続 き）
上記で得られた本発明組成物の各物性を下記第２表に示
す。Table 1 Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Go to -11 Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Table 1 (continued) Above The physical properties of the composition of the present invention obtained in the above are shown in Table 2 below.
第 ２ 表 特 性 組 成 物 Ｎｏ。Table 2 Characteristics Group composition No.
（４） ＯＯＯＯＯ○
ゲル分率
（％）
老化特性
１３５℃、７日 ０００ ０ ０ ０第 ２
表 （続 き）
（４） ○ ○ ○ ○ ○ Ｏグル分率
（％）
１３５℃、７日 ０ ０ ０ ０００第 ２
表 （続き）
特 性 組 成 物 Ｎｏ。(4) OOOOO○ Gel fraction (%) Aging characteristics 135℃, 7 days 000 0 0 0 2nd
Table (continued) (4) ○ ○ ○ ○ ○ O-glue fraction (%) 135℃, 7 days 0 0 0 000 2nd
Table (continued) Properties Composition No.
難燃性 ３１．４３６．０３４．５３０．３ ２８３
０．３（ＬＯＩ）
（４） ○○ｏｏｏ。Flame retardant 31.436.034.530.3 283
0.3 (LOI) (4) ○○ooo.
ゲル分率
（％）
（ＸＩＯ’ ５ ）
老化特性
１３５°Ｃ，７日 ○ ○ ○ Ｑ Ｏ
○第 ２ 表 （続 き）
ゲル分率
（％）
１５０℃、４日
第 ２ 表 （続 き）
特 性 組 成 物 Ｎｏ。Gel fraction (%) (XIO' 5) Aging characteristics 135°C, 7 days ○ ○ ○ Q O
○Table 2 (continued) Gel fraction (%) 150°C, 4 days Table 2 (continued) Characteristics Composition No.
ゲル分率 （％） １５０℃、４日 第 ２ 表 （続 き） 特 性 組 成 物 Ｎｏ。Gel fraction (%) 150℃, 4 days Table 2 (Continued) Characteristics Group composition No.
難燃性 ２７．８３２．１３３．２３１．４３２．１
２８．４（ＬＯＩ）
（２＞ ０．８１０．７６０．６００．６４０．６
００．７６（３） １．８４１．７９１．４０１．
５６１．６６１．２９（％）
、ｃ＞ｏｈｍ−ｃｍ ３．６０．８０．９６４．３０
．９１ｊ（ＸＩＯＩ ５ ）
１５０℃、４日
抗張力残率（％） ９２ ９４ ９４ ９０
９２ ９０伸び残率（％） ８４ ９２
９０ ’Ｊ３ ９０ ８１第 ２ 表
（続き）
特 性 組 成 物 Ｎｏ。Flame retardant 27.832.133.231.432.1
28.4 (LOI) (2> 0.810.760.600.640.6
00.76(3) 1.841.791.401.
561.661.29 (%), c>ohm-cm 3.60.80.964.30
．． 91j (XIOI 5 ) 150°C, 4-day tensile strength retention (%) 92 94 94 90
92 90 Remaining elongation rate (%) 84 92
90 'J3 90 81 Table 2
(continued) Characteristics Composition No.
難燃性 ２９．８３１．２３１．９３１．２３２，２
３０．３（ＬＯＩ）
（１） ０．６１０．５５０．４９０．３９０．４
２０．７２（３） ０．７６０．７１０．７２０．
７２０．８１１．４０ゲル分率
８７（％）
ｏ ｏｈｍ−ｃｍ ０．０８ Ｇ、０４ ０
．０７ ０．１１ ０．１２ ２．３（ＸＩＯ’ ５
）
１５０℃、４日
抗張力残率（％） ８０ ８２ ８４ ８１
８０ ９４伸び残率（％） ９６ ７２
７３ ７２ ７０ ９２第 ２ 表 〈
続 き）
特性 組成物Ｎｏ。Flame retardant 29.831.231.931.232,2
30.3 (LOI) (1) 0.610.550.490.390.4
20.72(3) 0.760.710.720.
720.811.40 gel fraction
87 (%) o ohm-cm 0.08 G, 04 0
．． 07 0.11 0.12 2.3(XIO' 5
) 150℃, 4-day tensile strength retention (%) 80 82 84 81
80 94 Remaining elongation rate (%) 96 72
73 72 70 92 Table 2
Continued) Characteristics Composition No.
難燃性 ３２．９３３．４
（ＬＯＩ）
（１） ０．７９０．８０
（３＞ １．４３１．３８
ゲル分率 ８８８９
（％）
ρｏｈｍ−ｃｔ＋＋ ２．９ ３．１（Ｘ
ＩＯＩ ５ ）
老化特性
１５０℃、４日
抗張力残率（％）９８９７
伸び残率（％）９４９０
上記第２表より本発明組成物を利用して得られるシート
は、優れた特性を有することがわかる。Flame retardancy 32.933.4 (LOI) (1) 0.790.80 (3> 1.431.38 Gel fraction 8889 (%) ρohm-ct++ 2.9 3.1 (X
IOI 5) Aging properties 150°C, 4 days Tensile strength retention (%) 9897 Elongation retention (%) 9490 From Table 2 above, it can be seen that the sheet obtained using the composition of the present invention has excellent properties. .
（以 上）(that's all)
Claims (8)
び （Ｃ）含リンチタネートカップリング剤約０．０５〜約
５重量部 からなる難燃性樹脂組成物。(1) (A) about 100 parts by weight of an olefin resin, (B) about 50 to about 300 parts by weight of a metal oxide hydrate, and (C) about 0.05 to about 5 parts by weight of a nitrate-containing coupling agent. A flame retardant resin composition consisting of parts.
体、エチレン−プロピレンゴム及びエチレン、プロピレ
ン−ジエンゴムからなる群から選ばれた少なくとも１種
である特許請求の範囲第１項に記載の組成物。(2) The composition according to claim 1, wherein the olefin resin is at least one selected from the group consisting of ethylene-vinyl acetate copolymer, ethylene-propylene rubber, and ethylene, propylene-diene rubber.
ネシアからなる群から選ばれた少なくとも１種である特
許請求の範囲第１項又は第２項に記載の組成物。(3) The composition according to claim 1 or 2, wherein the metal oxide hydrate is at least one selected from the group consisting of hydrated alumina and hydrated magnesia.
、化学式、表等があります▼ 又は▲数式、化学式、表等があります▼ 〔式中、Ｒは炭素数３〜１２のアルキル基を示す。Ｒ’
は炭素数１〜１８のアルキル基を示す。〕で表わされる
有機チタネート類である特許請求の範囲第１項乃至第３
項のいずれかに記載の組成物。(4) Phincitanate-containing coupling agent has the general formula ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ or ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼ [In the formula, R represents an alkyl group having 3 to 12 carbon atoms. R'
represents an alkyl group having 1 to 18 carbon atoms. ] Claims 1 to 3 are organic titanates represented by
The composition according to any of paragraphs.
範囲第１項乃至第４項のいずれかに記載の組成物。(5) About 70 to about 250 parts by weight of component (B) and about 0.2 to about 3 parts by weight of component (C) are blended with respect to 100 parts by weight of component (A). The composition according to any of paragraph 4.
至第５項のいずれかに記載の組成物。(6) The composition according to any one of claims 1 to 5, which contains an anti-aging agent.
及びアミン系老化防止剤からなる群から選ばれた少なく
とも１種である特許請求の範囲第６項に記載の組成物。(7) The composition according to claim 6, wherein the anti-aging agent is at least one selected from the group consisting of hindered phenolic anti-aging agents and amine anti-aging agents.
する特許請求の範囲第６項又は第７項に記載の組成物。(8) The composition according to claim 6 or 7, which contains about 0.1 to about 5 parts by weight of an anti-aging agent per 100 parts by weight of component (A).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61057884A JPH0627225B2 (en) | 1986-03-14 | 1986-03-14 | Flame-retardant resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61057884A JPH0627225B2 (en) | 1986-03-14 | 1986-03-14 | Flame-retardant resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62215643A true JPS62215643A (en) | 1987-09-22 |
| JPH0627225B2 JPH0627225B2 (en) | 1994-04-13 |
Family
ID=13068416
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61057884A Expired - Lifetime JPH0627225B2 (en) | 1986-03-14 | 1986-03-14 | Flame-retardant resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0627225B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008246752A (en) * | 2007-03-29 | 2008-10-16 | Tokai Rubber Ind Ltd | Heat-resistant rubber hose for diesel |
| JP2011528724A (en) * | 2008-07-18 | 2011-11-24 | ティコナ・エルエルシー | Flame retardant polymer composition |
| JP2013148608A (en) * | 2012-01-17 | 2013-08-01 | Furukawa Electric Co Ltd:The | Optical fiber cable |
| WO2018193665A1 (en) * | 2017-04-20 | 2018-10-25 | 住友電気工業株式会社 | Resin composition and electric wire |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5363452A (en) * | 1976-11-18 | 1978-06-06 | Furukawa Electric Co Ltd:The | Crystalline polyolefin resin composite materials having flexibility |
| JPS5531871A (en) * | 1978-08-29 | 1980-03-06 | Furukawa Electric Co Ltd:The | Polyethylene resin composition filled with large amount of inorganic material |
| JPS59179538A (en) * | 1983-03-30 | 1984-10-12 | Maruki Kagaku Kogyo Kk | Thermoplastic resin composition having high specific gravity |
| JPS6131446A (en) * | 1984-07-24 | 1986-02-13 | Hitachi Cable Ltd | Ethylene-propylene rubber composition having tracking resistance |
| JPS61106646A (en) * | 1984-10-30 | 1986-05-24 | Karupu Kogyo Kk | Resin composition for engraving by cutting |
| JPS61213245A (en) * | 1985-03-20 | 1986-09-22 | Dainichi Nippon Cables Ltd | Flame-retardant resin composition |
| JPS61293243A (en) * | 1981-06-09 | 1986-12-24 | ロバ−ト アンデイ | Fire retardant high strength polyolefin containing surface coated alumina hydrate and organotitanate and its production |
| JPS6418098A (en) * | 1987-07-13 | 1989-01-20 | Japan Aviation Electron | Multilayer film reflecting mirror |
| JPH0517934A (en) * | 1991-07-11 | 1993-01-26 | Kotoo:Kk | Solidifying agent spraying machine |
-
1986
- 1986-03-14 JP JP61057884A patent/JPH0627225B2/en not_active Expired - Lifetime
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5363452A (en) * | 1976-11-18 | 1978-06-06 | Furukawa Electric Co Ltd:The | Crystalline polyolefin resin composite materials having flexibility |
| JPS5531871A (en) * | 1978-08-29 | 1980-03-06 | Furukawa Electric Co Ltd:The | Polyethylene resin composition filled with large amount of inorganic material |
| JPS61293243A (en) * | 1981-06-09 | 1986-12-24 | ロバ−ト アンデイ | Fire retardant high strength polyolefin containing surface coated alumina hydrate and organotitanate and its production |
| JPS59179538A (en) * | 1983-03-30 | 1984-10-12 | Maruki Kagaku Kogyo Kk | Thermoplastic resin composition having high specific gravity |
| JPS6131446A (en) * | 1984-07-24 | 1986-02-13 | Hitachi Cable Ltd | Ethylene-propylene rubber composition having tracking resistance |
| JPS61106646A (en) * | 1984-10-30 | 1986-05-24 | Karupu Kogyo Kk | Resin composition for engraving by cutting |
| JPS61213245A (en) * | 1985-03-20 | 1986-09-22 | Dainichi Nippon Cables Ltd | Flame-retardant resin composition |
| JPS6418098A (en) * | 1987-07-13 | 1989-01-20 | Japan Aviation Electron | Multilayer film reflecting mirror |
| JPH0517934A (en) * | 1991-07-11 | 1993-01-26 | Kotoo:Kk | Solidifying agent spraying machine |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008246752A (en) * | 2007-03-29 | 2008-10-16 | Tokai Rubber Ind Ltd | Heat-resistant rubber hose for diesel |
| JP2011528724A (en) * | 2008-07-18 | 2011-11-24 | ティコナ・エルエルシー | Flame retardant polymer composition |
| JP2013148608A (en) * | 2012-01-17 | 2013-08-01 | Furukawa Electric Co Ltd:The | Optical fiber cable |
| WO2018193665A1 (en) * | 2017-04-20 | 2018-10-25 | 住友電気工業株式会社 | Resin composition and electric wire |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0627225B2 (en) | 1994-04-13 |
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