JPS62215517A - Composition for washing hair - Google Patents
Composition for washing hairInfo
- Publication number
- JPS62215517A JPS62215517A JP5774386A JP5774386A JPS62215517A JP S62215517 A JPS62215517 A JP S62215517A JP 5774386 A JP5774386 A JP 5774386A JP 5774386 A JP5774386 A JP 5774386A JP S62215517 A JPS62215517 A JP S62215517A
- Authority
- JP
- Japan
- Prior art keywords
- formula
- composition
- specific
- menthol
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 238000005406 washing Methods 0.000 title abstract description 6
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 14
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 claims abstract description 10
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 3
- 150000001768 cations Chemical group 0.000 claims abstract description 3
- NOOLISFMXDJSKH-KXUCPTDWSA-N (-)-Menthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@H]1O NOOLISFMXDJSKH-KXUCPTDWSA-N 0.000 claims abstract 5
- NFLGAXVYCFJBMK-UHFFFAOYSA-N isomenthone Natural products CC(C)C1CCC(C)CC1=O NFLGAXVYCFJBMK-UHFFFAOYSA-N 0.000 claims abstract 2
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 238000004040 coloring Methods 0.000 abstract description 19
- 229940041616 menthol Drugs 0.000 abstract description 11
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 abstract description 7
- 239000002453 shampoo Substances 0.000 abstract description 7
- 239000004615 ingredient Substances 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 230000006866 deterioration Effects 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 8
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 7
- 230000002265 prevention Effects 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 238000002845 discoloration Methods 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000003352 sequestering agent Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013068 control sample Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000004649 discoloration prevention Methods 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- ALOVPZWOOLXQEU-UHFFFAOYSA-N 2-[2-dodecoxyethyl(2-hydroxyethyl)amino]ethanol;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCOCCN(CCO)CCO ALOVPZWOOLXQEU-UHFFFAOYSA-N 0.000 description 1
- LIFHMKCDDVTICL-UHFFFAOYSA-N 6-(chloromethyl)phenanthridine Chemical compound C1=CC=C2C(CCl)=NC3=CC=CC=C3C2=C1 LIFHMKCDDVTICL-UHFFFAOYSA-N 0.000 description 1
- KUVIULQEHSCUHY-XYWKZLDCSA-N Beclometasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(Cl)[C@@H]1[C@@H]1C[C@H](C)[C@@](C(=O)COC(=O)CC)(OC(=O)CC)[C@@]1(C)C[C@@H]2O KUVIULQEHSCUHY-XYWKZLDCSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000035597 cooling sensation Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
帆泉五恋且且分髭
本発明はシャンプーのような毛髪洗浄用組成物、さらに
詳しくは、アンモニアやアルカノールアミンを対イオン
とするある種のアニオン界面活性剤とメントールを配合
した毛髪洗浄用組成物において、経時により生じろ着色
を防止した毛髪洗浄用組成物に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to hair cleaning compositions such as shampoos, and more particularly to certain anionic surfactants having ammonia or alkanolamines as counterions and menthol. The present invention relates to a hair cleansing composition that prevents coloring that occurs over time in a hair cleansing composition containing the following.
従来の技術
アンモニアやアルカノールアミンを対イオンとする式二
ｒｊ＋−０−（（ｊｌｔｃＨｔｏ）ｎ−ＳＯ，−Ｍ
［Ｉ］［式中、Ｒ８は炭素数８〜２０のアルキルまたは
アルケニル；ｎは０〜５；ＭはＮＨ，またはアルカノー
ルアミン、例えば、トリエタノールアミンから誘導され
るカチオンを意味する］
で示されるアニオン界面活性剤が経時により着色を生じ
ることがよく知られており、この界面活性剤を用いるシ
ャンプーなどの毛髪洗浄用組成物では、金属封鎖剤、尿
素、還元剤、酸化防止剤、紫外線吸収剤などを添加して
この着色を防止している。しかしながら。この着色は毛
髪洗浄用組成物に配合される香料、特に、メントールに
より促進され、従来の方法では防止できず、該界面活性
剤とメントールを含有する毛髪洗浄用組成物においては
、経時着色およびそれに伴う香りと清涼感の減少による
商品価値の低下を防ぐことは困難である。Conventional technology The formula 2rj+-0-((jltcHto)n-SO,-M with ammonia or alkanolamine as a counterion)
[I] [wherein R8 is alkyl or alkenyl having 8 to 20 carbon atoms; n is 0 to 5; M means NH or a cation derived from alkanolamine, such as triethanolamine] It is well known that anionic surfactants cause coloration over time, and in hair cleaning compositions such as shampoos that use these surfactants, sequestering agents, urea, reducing agents, antioxidants, and ultraviolet absorbers are often used. This coloring is prevented by adding ingredients such as. however. This coloration is promoted by fragrances, especially menthol, contained in the hair washing composition, and cannot be prevented by conventional methods. It is difficult to prevent a decrease in product value due to the accompanying decrease in fragrance and refreshing sensation.
一方、式［！］のアニオン界面活性剤および式＝［式中
、Ｒｔは炭素数８〜２０のアルキルまたはアルケニルを
意味する］
で示されるアルカノールアミドと、メントールを組合せ
た毛髪洗浄用組成物は、すぐれた清涼感および洗髪性能
を示すことが実証されているか、この組成物においても
、式［Ｉ］の界面活性剤とメント−ルによる経時着色が
生じ、その防止が非常に困難である。On the other hand, the expression [! ] An anionic surfactant of the formula = [where Rt means an alkyl or alkenyl having 8 to 20 carbon atoms] A hair cleansing composition that combines menthol with an anionic surfactant of the formula = [where Rt means an alkyl or alkenyl having 8 to 20 carbon atoms] Even in this composition, coloring occurs over time due to the surfactant of formula [I] and menthol, and it is very difficult to prevent this.
発明が解決しようとする問題点
本発明者は、式［Ｉ］のアニオン界面活性剤、式［■］
のアルカノールアミドおよびメントールを含有する毛髪
洗浄用組成物における経時着色を防止するために鋭意研
究を重ねた。その結果、ある種のジホスホン酸を共存さ
せることにより、経時着色が効果的に防止することを見
出した。Problems to be Solved by the Invention The present inventor has proposed an anionic surfactant of formula [I], an anionic surfactant of formula [■]
In order to prevent hair washing compositions containing alkanolamide and menthol from coloring over time, we have conducted extensive research. As a result, it was found that discoloration over time can be effectively prevented by coexisting with a certain type of diphosphonic acid.
問題点を解決するための手段
本発明は、
（ａ）式［Ｉ］のアニオン界面活性剤１〜２０重量％、
（ｂ）式［■］のアルカノールアミド０．１〜１０重量
％、
（ｃ） Ｑ−またはｄＱ−メントール０．０１〜５重量
％
および
（ｄ）式：
［式中、Ｍ７、Ｍ２、Ｍ、およびＭ４は、各々、独立し
て水素または、ナトリウム、カリウムなどのアルカリ金
属を意味する］
で示されるジホスホン酸０．００１−１重量％を配合し
てなる毛髪洗浄用組成物を提供するものである。Means for Solving the Problems The present invention comprises (a) 1 to 20% by weight of an anionic surfactant of formula [I], (b) 0.1 to 10% by weight of alkanolamide of formula [■], (c ) Q- or dQ-menthol 0.01 to 5% by weight and formula (d): [wherein M7, M2, M, and M4 each independently represent hydrogen or an alkali metal such as sodium or potassium; This invention provides a hair cleansing composition containing 0.001-1% by weight of diphosphonic acid represented by the following formula.
前記のごとく、毛髪洗浄用組成物の経時による着色防止
のため、従来より、ＥＤＴＡなどの金属封鎖剤が用いら
れ、一方、式［Ｉ［Ｉ］の化合物も金属封鎖作用を有す
るものであるが、式［Ｉ］のアニオン界面活性剤、式［
Ｉ１］のアルカノールアミドおよびメントールを含有す
る毛髪洗浄用組成物の経時による着色防止においては、
従来の金属封鎖剤はほとんどその効果を示さず、式［Ｉ
［Ｉ］の化合物が特異的に着色防止効果を発揮する。か
くして、本発明の毛髪洗浄用組成物においては、式［ｆ
ｆｌ］のジホスホン酸を配合することにより、特異的に
経時による着色およびそれによる商品価値の低下が防止
される。As mentioned above, in order to prevent coloring of hair cleansing compositions over time, metal sequestering agents such as EDTA have been conventionally used, and on the other hand, compounds of formula [I[I] also have metal sequestering effects. , an anionic surfactant of formula [I], an anionic surfactant of formula [I], an anionic surfactant of formula [I],
In preventing discoloration over time of a hair cleansing composition containing an alkanolamide and menthol in [I1],
Conventional sequestering agents show little effect and have the formula [I
The compound [I] specifically exhibits a discoloration prevention effect. Thus, in the hair cleansing composition of the present invention, the formula [f
By incorporating diphosphonic acid [fl], discoloration over time and the resulting decrease in commercial value are specifically prevented.
式［Ｉ１のアニオン界面活性剤の代表的なものとしては
、ラウリル硫酸トリエタノールアミン、ポリオキシエチ
レン（３）ラウリルエーテル硫酸トリエタノールアミン
、ラウリル硫酸アンモニウムなどが挙げられる。これら
は実際に用いる個々の活性剤の特性、所望の性能および
経済的観点から、一般に、組成物全量に基づいて１〜２
０重量％配合する。Representative examples of the anionic surfactant of formula [I1 include triethanolamine lauryl sulfate, triethanolamine lauryl ether sulfate, and ammonium lauryl sulfate. These will generally vary from 1 to 2, based on the total amount of the composition, depending on the characteristics of the particular active agent actually used, the desired performance, and economical considerations.
Add 0% by weight.
式［■］のアルカノールアミドの代表的なものとしては
、ヤシ油脂肪酸ジェタノールアミドが挙げられ、これも
所望の性能および経済的観点から一般に、組成物全量に
基づいて０．１〜ｌＯ重量％配合する。Typical alkanolamides of formula [■] include coconut oil fatty acid jetanolamide, which is also generally used in amounts ranging from 0.1 to 10% by weight based on the total amount of the composition from a desired performance and economic point of view. Blend.
σ−またはｄ１２−メントールは、単独で乙、香料の−
成分として配合してもよく、清涼感、溶解性、経済的観
点から、組成物全量に基づいて０．０１〜５重量％、好
ましくは、０．１〜５重量％配合する。σ- or d12-menthol can be used alone or as a fragrance.
It may be blended as a component, and from the viewpoint of cooling sensation, solubility, and economy, it is blended in an amount of 0.01 to 5% by weight, preferably 0.1 to 5% by weight, based on the total amount of the composition.
式［Ｉ］のジホスホン酸の代表的なものとしては、キレ
スクリンＨＥＰ（キレスト化学社製）、タービナルＳＬ
、ターピナル４ＮＬ（ヘンケル白水社製）が挙げられ、
所望の性能および経済的観点から、一般に、組成物全量
に基づいて０．００１〜１重量％、好ましくは０．０１
〜０．５重量％配合する。Typical diphosphonic acids of formula [I] include Killesculin HEP (manufactured by Killest Chemical Co., Ltd.) and Turbinal SL.
, Terpinal 4NL (manufactured by Henkel Hakusuisha),
From the desired performance and economic point of view, generally 0.001 to 1% by weight, preferably 0.01% by weight, based on the total composition.
~0.5% by weight is blended.
本発明の毛髪洗浄用組成物は各成分を混合、溶解するよ
うな常法により、シャンプーとすることができ、所望に
より、さらに、他の香料、着色料、防腐剤、コンディシ
ョニング剤などを配合とてもよい。なお、前記のごとく
、通常、シャンプーの着色防止剤として使用されている
金属封鎖剤の配合は、本発明においては、あまり有効で
はなく、かえって、着色を促進する場合もあり、避ける
事が好ましい。The hair cleansing composition of the present invention can be made into a shampoo by mixing and dissolving each component, and if desired, other fragrances, colorants, preservatives, conditioning agents, etc. can be added. good. As mentioned above, the inclusion of a metal sequestering agent, which is usually used as a coloring prevention agent in shampoos, is not very effective in the present invention and may even accelerate coloring, so it is preferable to avoid it.
及嵐鰺
っぎに実施例および比較例を挙げて、本発明をさらに詳
しく説明する。EXAMPLES The present invention will be explained in more detail by giving examples and comparative examples.
実施例１
次の処方に従い、種々の着色防止剤を用いて、常法によ
りンヤンプーを調製し、５０°Ｃに１ケ月放置して着色
防止剤無添加の対照試料と目視により比較し、着色防止
効果を評価した。結果を第１表に示す。Example 1 Nyanpu was prepared according to the following recipe using various anti-coloring agents in a conventional manner, left at 50°C for one month, and visually compared with a control sample with no anti-coloring agent added. The effectiveness was evaluated. The results are shown in Table 1.
吸−分 重量％ラウリル硫
酸トリエタノールアミン １５．０ヤシ油脂肪酸ジ
エタノールアミド ５０Ｑ−メントール
２．０呑料（メントール含有せ
ず）０．５
第１表に示す着色防止剤 第１表に表示精製水
残 部なお、着色防止
効果は、次の基準で評価した。Absorption content Weight % Lauryl sulfate triethanolamine 15.0 Coconut oil fatty acid diethanolamide 50Q-menthol
2.0 Drinks (not containing menthol) 0.5 Discoloration inhibitor shown in Table 1 Purified water shown in Table 1 Balance The discoloration prevention effect was evaluated according to the following criteria.
１：著しい着色防止効果が認められる。1: Significant coloring prevention effect is observed.
２：着色防止効果が認められる。2: Coloring prevention effect is observed.
３：対照試料と同程度の着色が認められる。3: Coloring to the same extent as the control sample is observed.
４：着色の促進が認められる。4: Promotion of coloring is observed.
第１表
注〕
＊： １−ヒドロキシエタン−１，１−ジホスホン酸・
・・キレスクリンＨＥＰ（キレスト化学社製）またはタ
ーピナルＳＬ（ヘンケル白水社製）＊＊； ｌ−ヒドロ
キシエタン−１，１−ジホスホン酸ナトリウム・・・タ
ーピナル４ＮＬ（ヘンケル白水社製）
第１表に示すごとく、種々の着色防止剤のうちで、式［
Ｉ■］のジホスホン酸が特異的に着色防止効果を示す。Note to Table 1] *: 1-Hydroxyethane-1,1-diphosphonic acid
... Killesculin HEP (manufactured by Killest Chemical Co., Ltd.) or Terpinal SL (manufactured by Henkel Hakusui Co., Ltd.) **; Sodium l-hydroxyethane-1,1-diphosphonate ... Terpinal 4NL (manufactured by Henkel Hakusui Co., Ltd.) Shown in Table 1 Among various coloring inhibitors, the formula [
The diphosphonic acid shown in I■] exhibits a specific coloring prevention effect.
実施例２〜７および比較例１〜４
第２表に示す処方に従い、常法により種々のシャンプー
を調製した。各シャンプーの試料を５０℃で３ケ月放置
または日光に２ケ月暴露後の着色度を０℃に保持した試
料と比較して次の基準により評価した。Examples 2 to 7 and Comparative Examples 1 to 4 Various shampoos were prepared by conventional methods according to the formulations shown in Table 2. After each shampoo sample was left at 50°C for 3 months or exposed to sunlight for 2 months, the degree of coloration was compared with a sample maintained at 0°C and evaluated according to the following criteria.
○：着色が著しく防止されている。○: Coloring is significantly prevented.
△：着色が防止される。Δ: Coloring is prevented.
Ｘ：着色防止効果が認められない。X: No coloring prevention effect observed.
また、放置または暴露後の臭気および清涼感、総合評価
を次の基準て評価した。In addition, the odor, refreshing feeling, and overall evaluation after being left or exposed were evaluated based on the following criteria.
○：非常に良い。○: Very good.
△：良好。△: Good.
Ｘ：不良。X: Defective.
結果を第２表に示す。The results are shown in Table 2.
第２表から明らかなごとく、式［Ｉ１１］のジホスホン
酸の添加により、特異的な着色が防止でき、商品価値の
低下を有効に防ぐことができる。As is clear from Table 2, the addition of the diphosphonic acid of formula [I11] can prevent specific coloring and effectively prevent a decrease in commercial value.
特許出廓人サンスター株式会社Patent distributor Sunstar Co., Ltd.
Claims (1)
［ I ］［式中、Ｒ＿１は炭素数８〜２０のアルキルま
たはアルケニル；ｎは０〜５；ＭはＮＨ＿４またはアル
カノールアミンから誘導されるカチオンを意味する］で
示されるアニオン界面活性剤１〜２０重量％、（ｂ）式 ▲数式、化学式、表等があります▼［II］ ［式中、Ｒ＿２は炭素数８〜２０のアルキルまたはアル
ケニルを意味する］ で示されるアルカノールアミド０．１〜１０重量％、 （ｃ）ｌ−またはｄｌ−メントール０．０１〜５重量％
、 および （Ｄ）式： ▲数式、化学式、表等があります▼［III］ ［式中、Ｍ＿１、Ｍ＿２、Ｍ＿３およびＭ＿４は、各々
、独立して水素またはアルカリ金属を意味する］ で示されるジホスホン酸０．００１〜１重量％を配合し
てなることを特徴とする毛髪洗浄用組成物。(1) Formula (a): R_1-O-(CH_2CH_2O)n-SO_3・M
[I] Anionic surfactants 1 to 20 represented by [wherein R_1 is alkyl or alkenyl having 8 to 20 carbon atoms; n is 0 to 5; M means a cation derived from NH_4 or alkanolamine] Weight%, formula (b) ▲ Numerical formulas, chemical formulas, tables, etc. are available ▼ [II] [In the formula, R_2 means alkyl or alkenyl having 8 to 20 carbon atoms] 0.1 to 10% by weight of alkanolamide represented by %, (c) l- or dl-menthol 0.01-5% by weight
, and (D) formula: ▲There are mathematical formulas, chemical formulas, tables, etc.▼ [III] [In the formula, M_1, M_2, M_3 and M_4 each independently mean hydrogen or an alkali metal] Diphosphophone represented by A hair cleansing composition comprising 0.001 to 1% by weight of an acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5774386A JPS62215517A (en) | 1986-03-14 | 1986-03-14 | Composition for washing hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5774386A JPS62215517A (en) | 1986-03-14 | 1986-03-14 | Composition for washing hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62215517A true JPS62215517A (en) | 1987-09-22 |
| JPH0327526B2 JPH0327526B2 (en) | 1991-04-16 |
Family
ID=13064387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5774386A Granted JPS62215517A (en) | 1986-03-14 | 1986-03-14 | Composition for washing hair |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62215517A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997031659A1 (en) * | 1996-02-28 | 1997-09-04 | Bausch & Lomb Incorporated | Treatment of contact lenses with aqueous solution including phosphonic compounds |
| US5858937A (en) * | 1996-02-28 | 1999-01-12 | Bausch & Lomb Incorporated | Treatment of contact lenses with aqueous solution including phosphonic compounds |
| JP2008143817A (en) * | 2006-12-08 | 2008-06-26 | Milbon Co Ltd | Emulsion-type cosmetic composition |
-
1986
- 1986-03-14 JP JP5774386A patent/JPS62215517A/en active Granted
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997031659A1 (en) * | 1996-02-28 | 1997-09-04 | Bausch & Lomb Incorporated | Treatment of contact lenses with aqueous solution including phosphonic compounds |
| US5858937A (en) * | 1996-02-28 | 1999-01-12 | Bausch & Lomb Incorporated | Treatment of contact lenses with aqueous solution including phosphonic compounds |
| JP2008143817A (en) * | 2006-12-08 | 2008-06-26 | Milbon Co Ltd | Emulsion-type cosmetic composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0327526B2 (en) | 1991-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1047932A (en) | Shampoo compositions which impart high luster and manageability to hair | |
| US5922659A (en) | Cleanser composition | |
| JPS5851991B2 (en) | Hypoallergenic shampoo composition | |
| JP2001107079A (en) | Detergent composition | |
| JPS62138594A (en) | Detergent composition | |
| JPS62215517A (en) | Composition for washing hair | |
| JPH02218797A (en) | Detergent composition having low irritation | |
| US5075042A (en) | Surfactant blend containing an alkyl poly(ethyleneoxy)sulfonate to reduce dermal irritation | |
| JPH0529002B2 (en) | ||
| JPH0559889B2 (en) | ||
| JP3630186B2 (en) | Soap composition | |
| JPS62260900A (en) | Detergent composition | |
| JP3400142B2 (en) | Detergent composition | |
| JPH06104617B2 (en) | Shampoo composition | |
| JPH01180815A (en) | Cleaning agent composition | |
| JPH01149710A (en) | Detergent composition | |
| JPH06157292A (en) | Face washing agent composition having pearly luster | |
| JP3423809B2 (en) | Detergent composition | |
| JPH0692826A (en) | Composition for washing hair | |
| JP2003231896A (en) | Cleanser composition | |
| JPS5918440B2 (en) | cleaning composition | |
| JPH0633403B2 (en) | Surfactant composition | |
| JPS62112696A (en) | Detergent composition | |
| JPH10237488A (en) | Detergent composition | |
| JPH06293629A (en) | Cleansing agent composition having pearly luster |