JPS62209381A - Manufacture of bimetal - Google Patents
Manufacture of bimetalInfo
- Publication number
- JPS62209381A JPS62209381A JP5315486A JP5315486A JPS62209381A JP S62209381 A JPS62209381 A JP S62209381A JP 5315486 A JP5315486 A JP 5315486A JP 5315486 A JP5315486 A JP 5315486A JP S62209381 A JPS62209381 A JP S62209381A
- Authority
- JP
- Japan
- Prior art keywords
- bimetal
- alloy
- passive film
- treatment
- expansion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 24
- 239000000956 alloy Substances 0.000 claims description 24
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 17
- 238000005530 etching Methods 0.000 claims description 12
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 230000032683 aging Effects 0.000 description 10
- 239000007864 aqueous solution Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 6
- 238000000137 annealing Methods 0.000 description 6
- 238000005097 cold rolling Methods 0.000 description 6
- 238000002845 discoloration Methods 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- PUZPDOWCWNUUKD-UHFFFAOYSA-M sodium fluoride Chemical compound [F-].[Na+] PUZPDOWCWNUUKD-UHFFFAOYSA-M 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 235000013024 sodium fluoride Nutrition 0.000 description 2
- 239000011775 sodium fluoride Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910001020 Au alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 239000003353 gold alloy Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H37/00—Thermally-actuated switches
- H01H37/02—Details
- H01H37/32—Thermally-sensitive members
- H01H37/52—Thermally-sensitive members actuated due to deflection of bimetallic element
- H01H2037/525—Details of manufacturing of the bimetals, e.g. connection to non bimetallic elements or insulating coatings
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
- H01H37/00—Thermally-actuated switches
- H01H37/02—Details
- H01H37/32—Thermally-sensitive members
- H01H37/52—Thermally-sensitive members actuated due to deflection of bimetallic element
- H01H2037/526—Materials for bimetals
Landscapes
- Details Of Measuring And Other Instruments (AREA)
- Laminated Bodies (AREA)
- Thermally Actuated Switches (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】
利用産業分野
この発明は、2枚重ねあるいは3枚重ねのバイメタルの
製造方法に係り、スタンピング加工につづいて施される
大気中での時効処理に伴ない生じる変色により、表面材
質識別用エツチングマークが不鮮明となるのを防止でき
るバイメタルの製造方法に関する。[Detailed Description of the Invention] Field of Application The present invention relates to a method for manufacturing two-ply or three-ply bimetals, and the discoloration caused by the aging treatment in the atmosphere following stamping processing causes The present invention relates to a bimetal manufacturing method that can prevent etching marks for surface material identification from becoming unclear.
、 背景技術
一般に、高膨脹側合金と低膨脹側合金とからなる2枚重
ねのバイメタルは、熱制御機器用部品等に用いられ、ま
た、高膨脹側合金と低膨脹側合金との間に中間層合金を
介在圧着した3枚重ねのバイメタルは、電流ブレーカ−
用等に用いられるが、いずれも同様の工程で製造される
。BACKGROUND TECHNOLOGY In general, a two-layer bimetal consisting of a high expansion alloy and a low expansion alloy is used for parts for thermal control equipment, etc., and an intermediate layer is used between the high expansion alloy and the low expansion alloy. A three-layer bimetal crimped with an interlayer alloy is used as a current breaker.
They are used for various purposes, but they are all manufactured using the same process.
−例として、2枚重ねのバイメタルの製造方法について
説明すると、まず、高膨脹側合金と低膨脹側合金を冷間
圧接し、拡散焼鈍、中間冷延、中間焼鈍、つづいて仕上
冷延を施す。- As an example, to explain the manufacturing method of two-ply bimetal, first, a high expansion alloy and a low expansion alloy are cold-welded, followed by diffusion annealing, intermediate cold rolling, intermediate annealing, and then finish cold rolling. .
その後、通常はバイメタルの材質の違いを識別するため
に、いずれか片面に文字等のエツチングマークを施し、
必要に応じて切断、平坦度の矯正をおこなったのち、所
要部品形状に、スタンピング加工し、さらに時効処理さ
れて製品化する。After that, in order to distinguish between the different materials of the bimetal, etching marks such as letters are usually applied to one side of the bimetal.
After cutting and straightening the flatness as necessary, stamping is performed into the required part shape, and the material is aged and manufactured into a product.
上記の時効処理は、通常大気中にて行なわれるため、処
理品表面が濃青色に変色し、前記エツチングマークが不
鮮明になり、バイメタルの材質区別が不明確となり、商
品価値が低下する問題があった。Since the above-mentioned aging treatment is usually carried out in the atmosphere, there is a problem that the surface of the treated product turns dark blue, the etching marks become unclear, the material distinction of the bimetal becomes unclear, and the product value decreases. Ta.
発明の目的
この発明は、従来のバイメタルの製造方法における欠点
を解決し、大気中時効処理に伴なう変色によりエツチン
グマークが不鮮明となるのを防止でき、品質のすぐれた
バイメタルが得られる製造方法を目的としている。Purpose of the Invention The present invention solves the drawbacks of conventional bimetal manufacturing methods, prevents etching marks from becoming unclear due to discoloration due to atmospheric aging treatment, and provides a manufacturing method that provides bimetal with excellent quality. It is an object.
発明の梠成と効果
この発明は、大気中時効処理に伴なう変色防止及び製品
品質向上を目的に種々検討した結果、エツチングマーク
を施す前または復に、バイメタル板に不動態被膜形成液
中に浸漬する処理を施すことにより、該変色を防止する
ことができることを知見したものである。Improvements and Effects of the Invention As a result of various studies aimed at preventing discoloration due to atmospheric aging treatment and improving product quality, the present invention revealed that the bimetal plate is coated in a passive film forming solution before or after etching marks are applied. It has been discovered that this discoloration can be prevented by immersing it in water.
すなわち、この発明は、
NL 17.5Wi%〜26wt%に
Cr3.1wt%〜12wt%、 11n swt%〜
6wt%。That is, in this invention, NL 17.5 Wi% to 26 wt%, Cr 3.1 wt% to 12 wt%, and 11n swt% to
6wt%.
Mo 4wt%〜6wt%
の1種を含有するFe合金からなる高膨脹側合金板を一
面に有し、
NL35wt%〜50wt%またはCr13Wi%〜1
8wt%含有のFe合金からなる低膨脹側合金板を他面
に有する2枚重ねまたは3枚重ねのバイメタル板を圧接
して仕上げたのら、
該バイメタル板のいずれか一方面に施す識別用エツチン
グマークが、後続の大気中時効処理に伴ない変色し不鮮
明化するのを防止する処理として、不動態被膜形成液に
浸漬する処理を行なうことを特徴とするバイメタルの製
造方法である。It has a high expansion side alloy plate made of Fe alloy containing one type of Mo 4wt%~6wt% on one side, and NL35wt%~50wt% or Cr13Wi%~1
After finishing the two- or three-ply bimetal plates having a low-expansion side alloy plate made of an Fe alloy containing 8 wt% on the other side by pressure bonding, identification etching is applied to one side of the bimetal plates. This bimetal manufacturing method is characterized by performing a treatment of immersing the mark in a passive film forming liquid as a treatment to prevent the mark from discoloring and becoming unclear due to subsequent aging treatment in the atmosphere.
この発明は、例えば、該バイメタル板のいずれか一方面
に識別用エツチングマークを施した後、温度15℃〜5
0℃の不動態被膜形成液中に、1秒〜30秒浸漬する処
理を行ない、バイメタル表面に極薄不動態膜を形成させ
ることにより、スタンピング加工に続く大気中での時効
処理俊に、材料表面が濃青色に変色するのを防止し、エ
ツチングマークが鮮明で材質識別が容易となる効果が得
られる。In the present invention, for example, after forming an identification etching mark on one side of the bimetal plate, the temperature is 15°C to 5°C.
By immersing the bimetal in a passive film forming solution at 0°C for 1 to 30 seconds to form an ultra-thin passive film on the surface of the bimetal, the material can be easily aged in the atmosphere following stamping. This prevents the surface from discoloring to deep blue, making the etching marks clear and making it easy to identify the material.
この発明において、不動態被膜形成処理に用いる処理液
は、硫酸、過酸化水素及び酸性弗化アンモンまたは酸性
弗化ソーダ等の酸性弗化アルカリ、非イオン界面活性剤
及び過酸化水素安定剤を含有する水溶液が適している。In this invention, the treatment liquid used for the passive film forming treatment contains sulfuric acid, hydrogen peroxide, an acidic alkali fluoride such as acidic ammonium fluoride or acidic sodium fluoride, a nonionic surfactant, and a hydrogen peroxide stabilizer. An aqueous solution is suitable.
発明の好ましい実施態様
この発明において、高膨脹側Fe合金は、NLが17.
5wt%未満では熱膨張係数が小さくなりすぎ、また、
26wt%を越えると同様に熱膨張係数が小さくなりす
ぎて好ましくない。Preferred Embodiment of the Invention In this invention, the high expansion Fe alloy has an NL of 17.
If it is less than 5 wt%, the coefficient of thermal expansion becomes too small, and
If it exceeds 26 wt%, the coefficient of thermal expansion becomes too small, which is not preferable.
また、Mnが5wt%未満、Crが3.1wt%未満、
Mo4wt%未満では、高膨張特性の安定性の点で好ま
しくなく、rlnが6wt%を越えると耐食性が悪くな
り、また、Crが12wt%を越えたり、鶴が6wt%
を越えると加工性が悪くなるため好ましくない。Further, Mn is less than 5 wt%, Cr is less than 3.1 wt%,
If Mo is less than 4wt%, it is unfavorable in terms of stability of high expansion properties, if rln exceeds 6wt%, corrosion resistance will deteriorate, and if Cr exceeds 12wt% or Tsuru is 6wt%.
Exceeding this is not preferable because workability deteriorates.
従って、高膨脹側合金は、
Ni17.5wt%〜26wt%に11++ 5wt%
〜6wt%またはCr3.1wt%〜12wt%
めるいはMo 4*t%〜6wt%の1種を含有するF
e合金とし、特に、
N;19.5〜20.5 Cr 5.5〜6.5
Fe合金(wt%)、Ni21.5〜22.5−Cr
3.1〜3.6−Fe合金(wt%)、hL17.5〜
18.5=Cr 11.0〜12.0−Fe合金(wt
%)、NL24〜26 Mo 4〜6 Fe合金(
wt%)、Ni22.5〜23.5 Inn 5.0
〜6.0 Fe合金(wt%)が好ましい。Therefore, the high expansion side alloy contains 17.5wt% to 26wt% Ni and 11++5wt%
-6 wt% or Cr3.1 wt% - 12 wt% F containing one of Mo 4*t% - 6 wt%
e alloy, especially N: 19.5-20.5 Cr 5.5-6.5
Fe alloy (wt%), Ni21.5-22.5-Cr
3.1-3.6-Fe alloy (wt%), hL17.5~
18.5=Cr 11.0-12.0-Fe alloy (wt
%), NL24-26 Mo 4-6 Fe alloy (
wt%), Ni22.5-23.5 Inn 5.0
~6.0 Fe alloy (wt%) is preferred.
また、低膨脹側Fe合金は、NLが35wt%未満、C
rが13wt%未満では熱膨張係数が太き(なりすぎ、
また、NLが50111%を越え、またCrが18wt
%を越えると同様に熱膨張係数が大きくなりすぎて好ま
しくないため、
NL 35Wj%〜50wt%、またはCr13W[%
〜18wt%含有のFe合金とし、
アンバー合金、 NL38wt%−Fe合金、NL42
Wj%−Fe合金、Cr13〜18wt%−Fe合金が
好ましい。In addition, the low expansion side Fe alloy has a NL of less than 35 wt% and a C
If r is less than 13 wt%, the coefficient of thermal expansion becomes too large (too much,
In addition, NL exceeds 50111% and Cr is 18wt.
If it exceeds 35Wj% to 50wt%, or Cr13W[%
~18wt% Fe alloy, Amber alloy, NL38wt%-Fe alloy, NL42
Wj%-Fe alloy and Cr13-18wt%-Fe alloy are preferred.
中間層合金は、用途等に応じて適宜選定すればよい。The intermediate layer alloy may be appropriately selected depending on the application and the like.
この発明の特徴である不動態被膜形成処理は、硫酸、過
酸化水素及び酸性弗化アンモンまたは酸性弗化ソーダ等
の酸性弗化アルカリ、非イオン界面活性剤及び過酸化水
素安定剤を含有する水溶液を用い、該水溶液温度は、1
5°C未満では、バイメタル表面に形成される不動態被
膜の厚みのばらつきが多く、大気中時効処理に伴なう製
品表面の変色防止効果が少なく、また、該水溶液温度が
50℃を越えると、水溶液の劣化が激しく、処理温度は
15°C〜50℃とする。The passive film forming treatment, which is a feature of this invention, consists of an aqueous solution containing sulfuric acid, hydrogen peroxide, an acidic alkali fluoride such as acidic ammonium fluoride or acidic sodium fluoride, a nonionic surfactant, and a hydrogen peroxide stabilizer. is used, and the temperature of the aqueous solution is 1
If the temperature is less than 5°C, there will be many variations in the thickness of the passive film formed on the bimetal surface, and the effect of preventing discoloration of the product surface due to atmospheric aging treatment will be small. , the aqueous solution deteriorates rapidly, and the treatment temperature is set at 15°C to 50°C.
また、該水溶液への浸漬時間が1秒未満では、生成する
不動態被膜厚みにばらつきを生じ、大気中時効処理に伴
なう製品表面の変色防止効果が少なく、また、浸漬時間
が30秒を越えると、エツチングマークの施工俊に処理
した場合、該マークが薄くなるため好ましくない。In addition, if the immersion time in the aqueous solution is less than 1 second, the thickness of the generated passive film will vary, and the effect of preventing discoloration of the product surface due to aging treatment in the atmosphere will be small. If it exceeds this, it is not preferable because the mark will become thinner if the etching mark is processed quickly.
実施例
餞酊
高膨脹側合金板に、2ONL 6Cr Fe合金(
vt%〉を使用し、低膨脹側合金板に、36NL F
e合金(wt%)を使用し、
冷間圧接し、拡散焼鈍、中間冷延、中間焼鈍、つづいて
仕上冷延して、板厚0.4mmX板幅30mmのバイメ
タル帯板を製造し、片面にエツチングマークを施した。Example: 2ONL 6Cr Fe alloy (
vt%> and 36NL F on the low expansion side alloy plate.
Using e-alloy (wt%), cold welding, diffusion annealing, intermediate cold rolling, intermediate annealing, and final cold rolling were performed to produce a bimetal strip with a thickness of 0.4 mm and a width of 30 mm. An etching mark was applied to the.
ざらに、0.4mmX 25mmX 50mm寸法に打
ち汰き加工及び曲げ加工の成形加工した。It was then roughly stamped and bent to a size of 0.4 mm x 25 mm x 50 mm.
その後、不動態被膜形成液として、CPE (商品名、
三菱化成社製)の50%水溶液を用い、成形加工材を液
温20℃の該水溶液に5秒間の浸漬処理した。After that, CPE (trade name,
Using a 50% aqueous solution (manufactured by Mitsubishi Kasei Corporation), the molded material was immersed in the aqueous solution at a temperature of 20° C. for 5 seconds.
ざらに大気中で、350℃、1時間の時効処理を行ない
、得られたこの発明によるバイメタルの外観状況を観察
し、その結果を第1′表に示す。The appearance of the obtained bimetal according to the present invention was observed after aging at 350° C. for 1 hour in the air, and the results are shown in Table 1'.
また、比較のため、同一の高膨脹側合金及び低膨脹側合
金を使用し、不動態被膜形成の浸漬処理を施さない以外
は、同一工程1条件で製造した2枚重ねのバイメタルの
時効処理後の外観状況を観察し、その結果を第1表に示
す。For comparison, we also used the same high-expansion side alloy and low-expansion side alloy, and after the aging treatment of two-ply bimetals manufactured under the same process conditions except that the immersion treatment for forming a passive film was not performed. The appearance was observed and the results are shown in Table 1.
以下余白
第1表
高膨脹側合金板に、23NL 5Mn Fe合金(
wt%)を使用し、低膨脹側合金板に、36NL F
e合金(wt%)を使用し、さらに両者間の中間層合金
に、0.5Co NL金合金用いて、冷間圧接し、拡
散焼鈍、中間冷延、中間焼鈍、つづいて仕上冷延して、
板厚0.2mmX板幅20mmのバイメタル帯板を製造
した。23NL 5Mn Fe alloy (
wt%), and 36NL F was used for the low expansion side alloy plate.
e alloy (wt%), and 0.5Co NL gold alloy as an intermediate layer alloy between the two, cold welding, diffusion annealing, intermediate cold rolling, intermediate annealing, and then finish cold rolling. ,
A bimetal strip plate with a thickness of 0.2 mm and a width of 20 mm was manufactured.
不動態被膜形成液として、CPE (商品名、三菱化成
社製)の30%水溶液を用い、成形加工材を液温30℃
の該水溶液に3秒間の浸漬処理し、その1多、片面にエ
ツチングマークを施した。A 30% aqueous solution of CPE (trade name, manufactured by Mitsubishi Kasei Corporation) was used as the passive film forming liquid, and the molded material was heated to a liquid temperature of 30°C.
The sample was immersed in the aqueous solution for 3 seconds, and etching marks were made on one side of the sample.
つづいて、平坦度矯正を行なったバイメタル板を、厚み
0.2mmX 1Bmmφ寸法に打ち扱き加工の成形加
工を行ない、ざらに大気中で、350℃、1時間の時効
処理を行ない、得られたこの発明による3枚重ねのバイ
メタルの外観状況を観察し、その結果を第2表に示す。Next, the flattened bimetal plate was punched and formed into a size of 0.2mm thick x 1Bmmφ, and roughly aged in the atmosphere at 350°C for 1 hour. The appearance of the three-layer bimetal according to the invention was observed, and the results are shown in Table 2.
また、比較のため、同一の高膨脹側合金及び低膨脹側合
金を使用し、不動態被膜形成処理を施さない以外は、同
一工程1条件で製造したバイメタルの時効処理後の外観
状況を観察し、その結果を第2表に示す。In addition, for comparison, we observed the appearance after aging treatment of a bimetal manufactured under the same process conditions except that the same high expansion alloy and low expansion alloy were used and no passive film formation treatment was performed. , the results are shown in Table 2.
第2表Table 2
Claims (1)
12wt%、Mn5wt%〜6wt%、Mo4wt%〜
6wt%の1種を含有するFe合金からなる高膨脹側合
金板を一面に有し、 Ni35wt%〜50wt%またはCr13wt%〜1
8wt%含有のFe合金からなる低膨脹側合金板を他面
に有する2枚重ねまたは3枚重ねのバイメタル板を圧接
して仕上げたのち、 該バイメタル板のいずれか一方面に識別用エッチングマ
ークを施す前または後に、 不動態被膜形成液中に浸漬することを特徴とするバイメ
タルの製造方法。[Claims] 1 17.5wt% to 26wt% Ni and 3.1wt% to Cr
12wt%, Mn5wt%~6wt%, Mo4wt%~
It has a high expansion side alloy plate made of an Fe alloy containing 6 wt% of one kind on one side, Ni35wt%~50wt% or Cr13wt%~1
After pressing and finishing two or three bimetal plates having a low expansion side alloy plate made of an Fe alloy containing 8wt% on the other side, an identification etching mark is made on one side of the bimetal plates. A method for producing a bimetal, which comprises immersing the bimetal in a passive film forming solution before or after applying the bimetal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5315486A JPS62209381A (en) | 1986-03-11 | 1986-03-11 | Manufacture of bimetal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5315486A JPS62209381A (en) | 1986-03-11 | 1986-03-11 | Manufacture of bimetal |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS62209381A true JPS62209381A (en) | 1987-09-14 |
JPH0357438B2 JPH0357438B2 (en) | 1991-09-02 |
Family
ID=12934922
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP5315486A Granted JPS62209381A (en) | 1986-03-11 | 1986-03-11 | Manufacture of bimetal |
Country Status (1)
Country | Link |
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JP (1) | JPS62209381A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0317594U (en) * | 1989-07-03 | 1991-02-21 | ||
WO2014171515A1 (en) * | 2013-04-19 | 2014-10-23 | タイコエレクトロニクスジャパン合同会社 | Protective device |
EP3564028A1 (en) * | 2018-05-02 | 2019-11-06 | Hitachi Metals, Ltd. | Dissimilar metal joined material and method of manufacturing same |
-
1986
- 1986-03-11 JP JP5315486A patent/JPS62209381A/en active Granted
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0317594U (en) * | 1989-07-03 | 1991-02-21 | ||
WO2014171515A1 (en) * | 2013-04-19 | 2014-10-23 | タイコエレクトロニクスジャパン合同会社 | Protective device |
CN105308710A (en) * | 2013-04-19 | 2016-02-03 | 泰科电子日本合同会社 | Protective device |
JPWO2014171515A1 (en) * | 2013-04-19 | 2017-02-23 | Littelfuseジャパン合同会社 | Protective device |
US10283295B2 (en) | 2013-04-19 | 2019-05-07 | Littelfuse Japan G.K. | Protection device |
EP2988313B1 (en) | 2013-04-19 | 2020-05-20 | Littelfuse Japan G.K. | Protective device |
EP2988313B2 (en) † | 2013-04-19 | 2023-03-29 | Littelfuse Japan G.K. | Protective device |
EP3564028A1 (en) * | 2018-05-02 | 2019-11-06 | Hitachi Metals, Ltd. | Dissimilar metal joined material and method of manufacturing same |
Also Published As
Publication number | Publication date |
---|---|
JPH0357438B2 (en) | 1991-09-02 |
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