JPS62200050A - Heat resistant toothed-belt - Google Patents

Heat resistant toothed-belt

Info

Publication number
JPS62200050A
JPS62200050A JP4069486A JP4069486A JPS62200050A JP S62200050 A JPS62200050 A JP S62200050A JP 4069486 A JP4069486 A JP 4069486A JP 4069486 A JP4069486 A JP 4069486A JP S62200050 A JPS62200050 A JP S62200050A
Authority
JP
Japan
Prior art keywords
belt
toothed belt
chlorosulfonated polyethylene
solid solution
aluminum oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4069486A
Other languages
Japanese (ja)
Inventor
Tomoji Mashita
真下 智司
Hajime Kakiuchi
垣内 一
Masahito Nakajima
中嶋 正仁
Kazutoshi Ishida
石田 和利
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsuboshi Belting Ltd
Original Assignee
Mitsuboshi Belting Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsuboshi Belting Ltd filed Critical Mitsuboshi Belting Ltd
Priority to JP4069486A priority Critical patent/JPS62200050A/en
Publication of JPS62200050A publication Critical patent/JPS62200050A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To improve the heat-resisting property of a rubber layer by applying to a rubber layer at the back part of a toothed belt a chlorosulfonated polyethylene rubber compound, to which a magnesium oxide-aluminum oxide solid solution is added to mix therewith. CONSTITUTION:At least the back part 6 of a toothed belt 1 is applied, as an oxidizing agent, a chlorosulfonated polyethylene rubber compound which is composed of a mixture of the above and a solid solution of magnesium oxide and aluminum oxide added thereto. The chlorosulfonated polyethylene rubber compound is a substance, in which 1-50pts.wt. of a magnesium oxide-aluminum oxide solid solution is added to 100pts.wt. of chlorosulfonated polyethylene. Thereby, the rubber compound at the back part 6, which is repeatedly subjected to at least an elastic deformation when the toothed belt 1 is in operation, can be improved so as to make its heat-resisting property better.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は耐熱性歯付ベルトに係り、詳しくは少なくとも
ベルト走行時に繰り返し伸縮変形を受ける背面部に受酸
剤として酸化マグネシウム−酸化アルミニウム固溶体を
添加したクロロスルフォン化ポリエチレンゴム組成物を
使用してなる耐熱性に優れた歯付ベルトに関するもので
ある。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a heat-resistant toothed belt, and more specifically, a magnesium oxide-aluminum oxide solid solution is added as an acid acceptor to at least the back surface of the belt, which undergoes repeated expansion and contraction deformation during belt running. The present invention relates to a toothed belt with excellent heat resistance that uses the added chlorosulfonated polyethylene rubber composition.

(従来の技術) 近年、省エネルギー化、コンパクト化の社会的要請を背
景に、自動車のエンジンルームの温度は従来に比べて上
昇して来ている。これにともない歯付ベルトの使用環境
温度も高くなってきた。従来、歯付ベルトは主としてポ
リクロロプレンゴムが使用されてきたが、高温雰囲気下
では、ゴムの硬化によりベルト背面部や歯元部で早期に
クランクを生じるという問題が発生した。
(Prior Art) In recent years, against the background of social demands for energy saving and compactness, the temperature in the engine room of automobiles has been rising compared to the past. Along with this, the environmental temperature in which toothed belts are used has also become higher. Conventionally, polychloroprene rubber has been mainly used for toothed belts, but in high-temperature atmospheres, the rubber hardens, causing problems such as early cranking of the belt back surface and tooth base.

このような歯付ベルトの早期破損現象に対し、従来より
クロロプレンゴムの耐熱性の改善が検討され、ある程度
の改良が行われてきたもののクロロプレンゴムを使用し
ている限り限界があり、現在のところ充分な効果を得る
には至っていない。
To address this phenomenon of premature failure of toothed belts, improvements in the heat resistance of chloroprene rubber have been considered and improvements have been made to some extent, but as long as chloroprene rubber is used, there is a limit. It has not yet achieved sufficient effect.

一般的には、耐熱性の優れたポリマーとして、フッ素ゴ
ム、シリコンゴム、アクリルゴム、ブチルゴム、エビク
ロルヒドリゴム、エチレン−プロピレンゴム等があげら
れるが、いずれも通常の配合処方では動的疲労性、接着
性そして耐油性が悪く歯付ベルトとしての基本的機能を
満足させることは難しかった。
In general, examples of polymers with excellent heat resistance include fluororubber, silicone rubber, acrylic rubber, butyl rubber, shrimp chlorhydride rubber, and ethylene-propylene rubber. , poor adhesiveness and oil resistance, making it difficult to satisfy the basic functions of a toothed belt.

また、耐熱性の優れたポリマーのうちでは、クロロスル
フォン化ポリエチレンは動的疲労性、耐油性、接着性に
おいてはクロロプレンゴムと同等であるが、耐水性にお
いては加硫系特に受酸剤の影響が大きい。通常、クロロ
スルフォン化ポリエチレンの受酸剤としてはMgO,P
bO等の酸化物が使用されており、例えばクロロスルフ
ォン化ポリエチレンにMgOあるいはPbO等の受酸剤
を添加したゴム組成物を歯付ベルトの本体に使用して歯
付ベルトの耐熱性を向上させることが、米国特許第3,
989,868号明細書に開示されている。
Among polymers with excellent heat resistance, chlorosulfonated polyethylene is equivalent to chloroprene rubber in terms of dynamic fatigue resistance, oil resistance, and adhesion, but water resistance is affected by the vulcanization system, especially the acid acceptor. is large. Usually, MgO, P are used as acid acceptors for chlorosulfonated polyethylene.
Oxides such as bO are used. For example, a rubber composition made by adding an acid acceptor such as MgO or PbO to chlorosulfonated polyethylene is used in the main body of a toothed belt to improve the heat resistance of the toothed belt. That is, U.S. Patent No. 3,
No. 989,868.

(発明が解決しようとする問題点) しかし、pbo、pb3o4等の鉛化合物の受酸剤を使
用すれば、耐水性の良好な歯付ベルトが得られるが、公
害、衛生上の問題から鉛化合物の使用は好ましくなく、
又MgOを受酸剤として使用した場合には、架橋反応中
に生成するMgCl2により耐水性は著しく損なわれ、
歯付ベルトへの適応は不適当であった。一方、全屈酸化
物以外の受酸剤としてエポキシ系の受酸剤を使用すれば
、耐水性の良好な組成物を得ることは可能であるが、臭
気の問題等が生じて人体に不快感を与える欠点があった
(Problems to be Solved by the Invention) However, if a lead compound acid acceptor such as pbo or pb3o4 is used, a toothed belt with good water resistance can be obtained. It is not recommended to use
Furthermore, when MgO is used as an acid acceptor, water resistance is significantly impaired by MgCl2 generated during the crosslinking reaction.
Adaptation to toothed belts was inappropriate. On the other hand, if an epoxy-based acid acceptor is used as an acid acceptor other than a total oxide, it is possible to obtain a composition with good water resistance, but it may cause odor problems and cause discomfort to the human body. There was a drawback of giving.

本発明はこのような問題に対処するものであり、歯付ベ
ルトの走行時、少なくとも伸縮変形を繰り返し受けてい
る背面部のゴム組成物を改善して耐熱性を高め、高温雰
囲気下での走行時の耐クランク性を向上せしめた歯付ベ
ルトを提供することにある。
The present invention addresses these problems by improving the rubber composition of the back surface, which is subject to repeated expansion and contraction deformation at least when the toothed belt runs, to increase its heat resistance and to improve its heat resistance when running in high-temperature atmospheres. An object of the present invention is to provide a toothed belt with improved crank resistance.

(問題点を解決するための手段) 即ち、本発明の特徴とするところは、歯付ベルトの少な
くとも背面部に受酸剤として酸化マグネシウム−酸化ア
ルミニウム固溶体を添加混入してなるクロロスルフォン
化ポリエチレンゴム組成物を使用してなる歯付ベルトに
あり、上記クロロスルフォン化ポリエチレンゴム組成物
はクロロスルフォン化ポリエチレン100M量部に対し
て酸化マグネシウム−酸化アルミニウム固溶体を1〜5
0重量部、好ましくは4〜20重量部添加したものであ
る。
(Means for Solving the Problems) That is, the present invention is characterized in that a chlorosulfonated polyethylene rubber is formed by adding and mixing a magnesium oxide-aluminum oxide solid solution as an acid acceptor to at least the back surface of a toothed belt. The chlorosulfonated polyethylene rubber composition contains 1 to 5 parts of magnesium oxide-aluminum oxide solid solution per 100 M parts of chlorosulfonated polyethylene.
0 parts by weight, preferably 4 to 20 parts by weight.

図は本発明に係る歯付ベル) (1)であり、該歯付ベ
ル) (1)はベルト長手方向に一定ピッチで歯部(2
)と溝部(3)を交互に有し、ベルト伸張部(4)のベ
ルトピンチライン上にはガラス繊維、ポリエステル繊維
、アラミツド繊維からなるロープ状の抗張体(5)が埋
設し、更に抗張体(5)の上側には背面部(6)があり
、他方上記歯部(2)及び溝部(3)の表面にはゴム付
帆布からなるカバ一層(7)が貼着している。
The figure shows a toothed bell (1) according to the present invention, and the toothed bell (1) has teeth (2) at a constant pitch in the longitudinal direction of the belt.
) and grooves (3) alternately, and a rope-shaped tensile material (5) made of glass fiber, polyester fiber, or aramid fiber is buried above the belt pinch line of the belt extension part (4), and further has a There is a back surface (6) on the upper side of the upholstery (5), and a cover layer (7) made of rubberized canvas is adhered to the surfaces of the teeth (2) and grooves (3).

前記歯付ベル) (1)を高温雰囲気下で走行させると
、歯付ベルトの背面部(6)及び歯部(2)のゴム層は
化学的に熱劣化しやすい環境におかれ、しかも特に背面
部(6)はベルトがブーりと噛み合う時に伸張し、又噛
み離れる時にこれが開放されるところから繰り返し伸縮
変形を受けている。このため、ベルト本体のゴムが熱劣
化して硬度を向上し始めると、背面部(6)に位置する
ゴムは伸縮性に欠は早期にクランクを引き起こすことに
なる。
When the toothed belt (1) is run in a high-temperature atmosphere, the rubber layers of the back surface (6) and teeth (2) of the toothed belt are placed in an environment where they are susceptible to chemical thermal deterioration. The back portion (6) is repeatedly subjected to expansion and contraction deformation as it expands when the belt engages with the boob and is released when the belt disengages. For this reason, when the rubber of the belt main body deteriorates due to heat and begins to increase its hardness, the rubber located on the back surface (6) lacks elasticity and will cause cranking at an early stage.

そのため、本発明の歯付ベルトにおいては少なくとも背
面部(6)に特定の受酸体である酸化マグネシウム−酸
化アルミニウム固溶体をクロロスルフォン化ポリエチレ
ンに添加して耐熱性を向上させて熱劣化を阻止している
Therefore, in the toothed belt of the present invention, a magnesium oxide-aluminum oxide solid solution, which is a specific acid acceptor, is added to the chlorosulfonated polyethylene at least in the back surface portion (6) to improve heat resistance and prevent thermal deterioration. ing.

上記受酸体である酸化マグネシウム−酸化アルミニウム
固溶体は一般にM g6.7 A l o、30i:t
rで示され、その具体例として協和化学工業■製のKW
−2000、KW−2100等がある。
The magnesium oxide-aluminum oxide solid solution which is the acid acceptor is generally M g6.7 A lo, 30i:t
KW manufactured by Kyowa Chemical Industry ■ is a specific example.
-2000, KW-2100, etc.

該受酸体の添加量はクロロスルフォン化ポリエチレン1
00重量部に対して1〜50重量部、好ましくは4〜2
0重量部であり、この場合酸化マグネシウム−酸化アル
ミニウム固溶体が1重量部以下では、架橋中に発生する
塩化水素を充分に除去することができないため、クロロ
スルフォン化ポリエチレンの架橋点が少なくなって所定
の加硫物が得られず、耐熱性に欠けて早期にクラックの
発生しやすい歯付ベルトになる。一方、50重量部以上
になるとムーニー粘度が著しく高くなり加工上の問題が
生じる。従って、本発明の歯付ベルトに使用するゴム組
成物は、ベルトライフを改良せしめ且つ加工性を満足せ
しめるためにも、クロロスルフォン化ポリエチレンに酸
化マグネシウム−酸化アルミニウム固溶体を前記範囲内
において添加するものが最も好適であり、且つ必要であ
る。
The amount of the acid acceptor added is chlorosulfonated polyethylene 1
1 to 50 parts by weight, preferably 4 to 2 parts by weight per 00 parts by weight
In this case, if the magnesium oxide-aluminum oxide solid solution is 1 part by weight or less, hydrogen chloride generated during crosslinking cannot be sufficiently removed, so the number of crosslinking points in the chlorosulfonated polyethylene decreases and This results in a toothed belt that lacks heat resistance and is prone to early cracking. On the other hand, if the amount exceeds 50 parts by weight, the Mooney viscosity becomes extremely high, causing processing problems. Therefore, the rubber composition used in the toothed belt of the present invention is one in which a magnesium oxide-aluminum oxide solid solution is added to chlorosulfonated polyethylene within the above range in order to improve belt life and satisfy processability. is the most preferred and necessary.

この酸化マグネシウム−酸化アルミニウム固溶体はその
まま混練時に添加してもさしつかえないが、より分散性
を改善するために前もってステアリン酸ソーダ等のアニ
オン系界面活性剤やシランカップリング剤等により処理
し使用することも可能である。
This magnesium oxide-aluminum oxide solid solution can be added as is during kneading, but in order to further improve dispersibility, it should be treated with an anionic surfactant such as sodium stearate or a silane coupling agent before use. is also possible.

尚、前記本発明の歯付ベルトに用いられる組成物には通
常用いられるカーボンブラック、軟化剤、老化防止剤、
加工助剤、粘着剤、加硫促進剤等を配合することができ
る。
The composition used in the toothed belt of the present invention contains commonly used carbon black, a softener, an anti-aging agent,
Processing aids, adhesives, vulcanization accelerators, etc. can be added.

前記各成分を混合する方法としては特に制限はなく、例
えばバンバリーミキサ−、ニーダ−等を用い、適宜公知
の手段、方法によって混練することができる。
There are no particular restrictions on the method of mixing the components, and they may be kneaded by appropriate known means and methods using, for example, a Banbury mixer, a kneader, or the like.

また、前記酸化マグネシウム−酸化アルミニウム固溶体
を添加したクロロスルフォン化ポリエチレン組成物を用
いた歯付ベルトの成形方法は、従来適用されている種々
の公知の方法を適宜使用することができ、同等制限され
るものではないことを云うまでもまい。
In addition, as a method for forming a toothed belt using the chlorosulfonated polyethylene composition to which the magnesium oxide-aluminum oxide solid solution is added, various conventionally applied known methods can be used as appropriate, and there are no equivalent restrictions. Needless to say, it is not something that can be done.

以下、本発明を実施例により更に説明する。しかし、本
発明は係る実施例に限定されるものではなく、前記目的
を逸脱しない範囲において適宜改変可能である。
The present invention will be further explained below with reference to Examples. However, the present invention is not limited to these embodiments, and can be modified as appropriate without departing from the above objectives.

(実施例) 歯付ベルトの背面部及び歯部に第1表の如き配合ゴムを
使用した。表中、比較例−1は従来のクロロプレンゴム
組成物を使用した例であり、比較例−2はクロロスルフ
ォン化ポリエチレンに受酸剤として通常用いられている
MgOを使用した例である。
(Example) Compounded rubbers as shown in Table 1 were used for the back surface and teeth of a toothed belt. In the table, Comparative Example 1 is an example in which a conventional chloroprene rubber composition was used, and Comparative Example 2 is an example in which MgO, which is commonly used as an acid acceptor, is used in chlorosulfonated polyethylene.

以   下   余   白 第  1  表 第1表に示した配合にもとづき、バンバリーミキサ−で
混練しその配合物を通常加硫条件150℃、30分プレ
ス加硫した。加硫物の物性は第2表に示される。
Table 1: Based on the formulation shown in Table 1, the mixture was kneaded in a Banbury mixer, and the mixture was press-vulcanized at 150° C. for 30 minutes under normal vulcanization conditions. The physical properties of the vulcanizate are shown in Table 2.

以   下   余   白 第2表 注)、()内は変化率を示す。below below remaining white Table 2 Note) The numbers in parentheses indicate the rate of change.

第2表より明らかな如く、本発明歯付ベルトに使用され
るゴム組成物は、従来のクロロプレンゴム組成物に比べ
、硬さ、モジュラスの上昇及び伸びの低下が小さく耐熱
性がはるかに良好であり、耐水性においても従来のクロ
ロプレンゴム組成物よりやや良好である。一方、クロロ
スルフォン化ポリエチレンに受酸剤としてMgOを使用
したゴム組成物は、耐水性において従来のクロロプレン
ゴム組成物に比べ著しく劣っていることが分る。
As is clear from Table 2, the rubber composition used in the toothed belt of the present invention shows less increase in hardness, less modulus, and less decrease in elongation than the conventional chloroprene rubber composition, and has much better heat resistance. It also has slightly better water resistance than conventional chloroprene rubber compositions. On the other hand, it can be seen that a rubber composition using MgO as an acid acceptor in chlorosulfonated polyethylene is significantly inferior in water resistance to a conventional chloroprene rubber composition.

次に、前記第1表に示す各配合ゴムを使用した歯付ベル
トL型(歯のピンチ9,525鰭、長さ31.5インチ
、巾0.75インチ、ガラスコード抗張体使用)を製造
し耐熱性走行試験及びベルト背面駆動における背面ゴム
の貼着試験を行った。
Next, a toothed belt L type (9,525 tooth pinch fins, length 31.5 inches, width 0.75 inches, glass cord tensile material used) was made using each compounded rubber shown in Table 1 above. After manufacturing, we conducted a heat resistance running test and a back rubber adhesion test in belt back drive.

その結果は第3表及び第4表の通りであった。The results were as shown in Tables 3 and 4.

第3表 第4表 上記第3表及び第4表から明らかなように、酸化マグネ
シウム−酸化アルミニウム固溶体を添加配合したクロロ
スルフォン化ポリエチレンゴム組成物を使用した本発明
の歯付ベルトは、従来の歯付ベルトに比べ高温雰囲気下
でのベルトライフを向上せしめ、ベルト背面の貼着も生
じない。
Table 3 Table 4 As is clear from Tables 3 and 4 above, the toothed belt of the present invention using the chlorosulfonated polyethylene rubber composition containing a magnesium oxide-aluminum oxide solid solution is different from the conventional toothed belt. Compared to toothed belts, the belt life is improved in high-temperature atmospheres, and the back side of the belt does not stick.

(発明の効果) 以上のように本発明の歯付ベルトは、少なくともベルト
走行時、伸縮変形を繰り返す背面部のゴム層に酸化マグ
ネシウム−酸化アルミニウム固溶体を添加混入したクロ
ロスルフォン化ポリエチレンゴム組成物を使用すること
により該ゴム層の耐熱性を高め、これにより高温雰囲気
下での硬度上昇によるクランクの発生及びベルト背面の
貼着性をおさえ、高温雰囲気下での走行条件下にあって
もベルトライフを大きく向上させることができる優れた
効果を有している。
(Effects of the Invention) As described above, the toothed belt of the present invention includes a chlorosulfonated polyethylene rubber composition in which a magnesium oxide-aluminum oxide solid solution is added to the rubber layer on the back surface, which repeatedly expands and contracts at least when the belt runs. By using this, the heat resistance of the rubber layer is increased, which suppresses the occurrence of cranks due to increased hardness in high-temperature atmospheres and the adhesion of the back of the belt, and extends the belt life even under running conditions in high-temperature atmospheres. It has an excellent effect that can greatly improve the

【図面の簡単な説明】[Brief explanation of drawings]

図は本発明に係る歯付ベルトの部分側面図である。 (1)・・・歯付ベルト(2)・・・歯部(5)・・・
抗張体     (6)・・・背画部特許出願人 三ツ
星ベルト株式会社 手続補正書(自発) 昭和62年 5月lJ日
The figure is a partial side view of a toothed belt according to the present invention. (1)...Toothed belt (2)...Toothed part (5)...
Tensile body (6)... Back part patent applicant Mitsuboshi Belting Co., Ltd. Procedural amendment (voluntary) May 1, 1986

Claims (1)

【特許請求の範囲】 1、歯付ベルトの少なくとも背面部に、クロロスルフォ
ン化ポリエチレン100重量部に対し、酸化マグネシウ
ム−酸化アルミニウム固溶体(Mg_0_._7Al_
0_._3O_1_._1_5)を1〜50重量部添加
混入したゴム組成物を用いたことを特徴とする歯付ベル
ト。 2、前記ゴム組成物をベルト背面部のみに使用した特許
請求の範囲第1項記載の耐熱性歯付ベルト。 3、前記ゴム組成物をベルトの歯部ならびに背面部に使
用した特許請求の範囲第1項記載の歯付ベルト。
[Claims] 1. At least on the back side of the toothed belt, a magnesium oxide-aluminum oxide solid solution (Mg_0_._7Al_
0__. _3O_1_. A toothed belt characterized by using a rubber composition containing _1_5) in an amount of 1 to 50 parts by weight. 2. The heat-resistant toothed belt according to claim 1, wherein the rubber composition is used only on the back side of the belt. 3. The toothed belt according to claim 1, wherein the rubber composition is used for the teeth and the back surface of the belt.
JP4069486A 1986-02-25 1986-02-25 Heat resistant toothed-belt Pending JPS62200050A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4069486A JPS62200050A (en) 1986-02-25 1986-02-25 Heat resistant toothed-belt

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4069486A JPS62200050A (en) 1986-02-25 1986-02-25 Heat resistant toothed-belt

Publications (1)

Publication Number Publication Date
JPS62200050A true JPS62200050A (en) 1987-09-03

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ID=12587661

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4069486A Pending JPS62200050A (en) 1986-02-25 1986-02-25 Heat resistant toothed-belt

Country Status (1)

Country Link
JP (1) JPS62200050A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0451983A2 (en) * 1990-03-29 1991-10-16 Mitsuboshi Belting Ltd. Power transmission belt

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5136247A (en) * 1974-05-31 1976-03-27 Uniroyal Inc
JPS58222128A (en) * 1982-06-18 1983-12-23 Kyowa Chem Ind Co Ltd Method for improving water resistance of halogen- containing rubber

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5136247A (en) * 1974-05-31 1976-03-27 Uniroyal Inc
JPS58222128A (en) * 1982-06-18 1983-12-23 Kyowa Chem Ind Co Ltd Method for improving water resistance of halogen- containing rubber

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0451983A2 (en) * 1990-03-29 1991-10-16 Mitsuboshi Belting Ltd. Power transmission belt
US5254050A (en) * 1990-03-29 1993-10-19 Mitsuboshi Belting Ltd. Power transmission belt

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