JPS621796B2 - - Google Patents
Info
- Publication number
- JPS621796B2 JPS621796B2 JP51140072A JP14007276A JPS621796B2 JP S621796 B2 JPS621796 B2 JP S621796B2 JP 51140072 A JP51140072 A JP 51140072A JP 14007276 A JP14007276 A JP 14007276A JP S621796 B2 JPS621796 B2 JP S621796B2
- Authority
- JP
- Japan
- Prior art keywords
- ammonia
- distillation
- stream
- vapor
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 244
- 229910021529 ammonia Inorganic materials 0.000 claims description 111
- 238000004821 distillation Methods 0.000 claims description 96
- 239000007789 gas Substances 0.000 claims description 79
- 239000002253 acid Substances 0.000 claims description 58
- 239000007788 liquid Substances 0.000 claims description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 37
- 239000007864 aqueous solution Substances 0.000 claims description 27
- 239000000243 solution Substances 0.000 claims description 24
- 239000000571 coke Substances 0.000 claims description 17
- 150000003839 salts Chemical class 0.000 claims description 17
- 239000003513 alkali Substances 0.000 claims description 13
- 230000002378 acidificating effect Effects 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 150000002989 phenols Chemical class 0.000 claims description 7
- 239000011269 tar Substances 0.000 claims description 7
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 5
- 238000001944 continuous distillation Methods 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000000920 calcium hydroxide Substances 0.000 claims description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 231100000614 poison Toxicity 0.000 claims description 3
- 239000003440 toxic substance Substances 0.000 claims description 3
- 150000003841 chloride salts Chemical class 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 150000004673 fluoride salts Chemical class 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000003567 thiocyanates Chemical class 0.000 claims description 2
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims 1
- 229910001868 water Inorganic materials 0.000 description 23
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 19
- 239000002351 wastewater Substances 0.000 description 19
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 17
- 235000011941 Tilia x europaea Nutrition 0.000 description 17
- 239000004571 lime Substances 0.000 description 17
- 239000000203 mixture Substances 0.000 description 17
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- 239000010802 sludge Substances 0.000 description 9
- 238000011084 recovery Methods 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 7
- 239000003245 coal Substances 0.000 description 7
- 150000002825 nitriles Chemical class 0.000 description 6
- 238000010992 reflux Methods 0.000 description 6
- 150000003863 ammonium salts Chemical class 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 230000007423 decrease Effects 0.000 description 5
- 239000002002 slurry Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 235000019270 ammonium chloride Nutrition 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 3
- 235000011130 ammonium sulphate Nutrition 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000005660 chlorination reaction Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 241000894007 species Species 0.000 description 3
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 3
- -1 Ammonium Carbonate Ammonium Chloride Ammonium Bicarbonate Ammonium Thiocyanate Ammonium Sulfide Ammonium Chemical compound 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- 238000010793 Steam injection (oil industry) Methods 0.000 description 2
- 241001148470 aerobic bacillus Species 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- MYKZLATVIJZNTH-UHFFFAOYSA-N azane;cyano thiocyanate Chemical compound N.N#CSC#N MYKZLATVIJZNTH-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000000593 degrading effect Effects 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 159000000011 group IA salts Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
- C01C1/02—Preparation, purification or separation of ammonia
- C01C1/10—Separation of ammonia from ammonia liquors, e.g. gas liquors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0068—General arrangements, e.g. flowsheets
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physical Water Treatments (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Industrial Gases (AREA)
- Treating Waste Gases (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US63352275A | 1975-11-19 | 1975-11-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5262958A JPS5262958A (en) | 1977-05-24 |
| JPS621796B2 true JPS621796B2 (enrdf_load_stackoverflow) | 1987-01-16 |
Family
ID=24539969
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51140072A Granted JPS5262958A (en) | 1975-11-19 | 1976-11-19 | Method of separating acidic gas and ammonia from dilute water solution containing these |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS5262958A (enrdf_load_stackoverflow) |
| AU (1) | AU513320B2 (enrdf_load_stackoverflow) |
| BR (1) | BR7607656A (enrdf_load_stackoverflow) |
| CA (1) | CA1090281A (enrdf_load_stackoverflow) |
| DE (1) | DE2652524C2 (enrdf_load_stackoverflow) |
| GB (1) | GB1563512A (enrdf_load_stackoverflow) |
| SE (1) | SE426162B (enrdf_load_stackoverflow) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4140586A (en) * | 1976-06-14 | 1979-02-20 | Bethlehem Steel Corporation | Method and apparatus for distillation |
| NL7803765A (nl) * | 1978-04-10 | 1979-10-12 | Hoogovens Ijmuiden Bv | Werkwijze voor het verwijderen van ammoniak en ammo- niumzouten uit industrieel afvalwater. |
| CA1135653A (en) * | 1978-09-12 | 1982-11-16 | Yutaka Ota | Apparatus for treatment of ammoniacal waste liquid |
| US4323430A (en) * | 1981-03-16 | 1982-04-06 | United States Steel Corporation | Process for separating ammonia and acid gases from streams containing fixed ammonia salts |
| DE3707446A1 (de) * | 1987-03-07 | 1988-09-29 | Steinmueller Gmbh L & C | Verfahren zum entfernen von ammoniak aus einem abwasser eines rauchgasreinigungsprozesses |
| DE4041569A1 (de) * | 1990-12-22 | 1992-06-25 | Hoechst Ag | Verfahren zur aufarbeitung schwefelwasserstoff, cyanwasserstoff und ammoniak enthaltender waessriger loesungen |
| DE4330569C1 (de) * | 1992-11-23 | 1994-07-21 | Preussag Noell Wassertech | Verfahren und Vorrichtung zur Entfernung von ammoniumhaltigen Verbindungen aus Abwässern |
| JP2008185310A (ja) * | 2007-01-31 | 2008-08-14 | Mitsubishi Heavy Ind Ltd | 空気調和装置 |
| FR2945287B1 (fr) * | 2009-05-06 | 2012-07-13 | Alcion Environnement | Procede de recuperation et de recyclage d'ammoniac, installation |
| MX2012004975A (es) | 2009-10-28 | 2012-07-20 | Oasys Water Inc | Sistemas y metodos de separacion osmotica. |
| KR101292545B1 (ko) | 2009-12-28 | 2013-08-12 | 주식회사 엘지화학 | 트리클로로실란의 정제 방법 및 정제 장치 |
| AU2011305488B2 (en) * | 2010-09-22 | 2015-09-10 | Oasys Water LLC | Osmotically driven membrane processes and systems and methods for draw solute recovery |
| FR2988304B1 (fr) * | 2012-03-23 | 2014-11-28 | Suez Environnement | Procede d'extraction de l'ammoniac dissous dans un effluent liquide, et installation pour la mise en oeuvre de ce procede |
| JP5954101B2 (ja) * | 2012-10-16 | 2016-07-20 | Ｊｆｅスチール株式会社 | 安水処理システム |
| CN105555379B (zh) * | 2013-07-18 | 2018-02-27 | Lg化学株式会社 | 分隔壁蒸馏塔 |
| RU2640533C2 (ru) * | 2016-01-19 | 2018-01-09 | Рустем Руждиевич Везиров | Способ выделения из технологического конденсата сероводорода и аммиака |
| CN107754368B (zh) * | 2017-10-17 | 2022-12-02 | 杭州富如德科技有限公司 | 一种酸性水汽提塔的防腐方法及其防腐装置 |
| JP7092530B2 (ja) * | 2018-03-23 | 2022-06-28 | 月島環境エンジニアリング株式会社 | 酸性成分及びアンモニアを含有する廃水のアンモニアストリッピング処理装置及びその方法 |
| CN113292094A (zh) * | 2021-06-02 | 2021-08-24 | 江西思远再生资源有限公司 | 一种去除次氧化锌原料中氯根、硫酸根的方法 |
| CN114873669A (zh) * | 2022-01-26 | 2022-08-09 | 锦益创典(天津)科技有限责任公司 | 一种沼液脱碳脱氨方法及系统 |
| PL73709Y1 (pl) * | 2023-01-23 | 2024-12-09 | Biuro Projektów Koksoprojekt Spółka Z Ograniczoną Odpowiedzialnością | Urządzenie do oddestylowania z wód procesowych składników kwaśnych i amoniaku zaabsorbowanych z gazów przemysłowych |
| CN116216830B (zh) * | 2023-01-28 | 2025-01-07 | 中冶焦耐(大连)工程技术有限公司 | 一种节能脱酸蒸氨工艺及装置 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE975759C (de) * | 1943-03-28 | 1962-09-27 | Otto & Co Gmbh Dr C | Verfahren zum Aufarbeiten der bei der Gasreinigung mittels ammoniakalischer Waesser anfallenden Fluessigkeit |
-
1976
- 1976-11-01 AU AU19178/76A patent/AU513320B2/en not_active Expired
- 1976-11-16 SE SE7612804A patent/SE426162B/xx unknown
- 1976-11-17 BR BR7607656A patent/BR7607656A/pt unknown
- 1976-11-18 DE DE2652524A patent/DE2652524C2/de not_active Expired
- 1976-11-18 CA CA266,017A patent/CA1090281A/en not_active Expired
- 1976-11-18 GB GB48152/76A patent/GB1563512A/en not_active Expired
- 1976-11-19 JP JP51140072A patent/JPS5262958A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| GB1563512A (en) | 1980-03-26 |
| SE7612804L (sv) | 1977-05-20 |
| AU513320B2 (en) | 1980-11-27 |
| BR7607656A (pt) | 1977-09-27 |
| CA1090281A (en) | 1980-11-25 |
| DE2652524C2 (de) | 1986-12-04 |
| DE2652524A1 (de) | 1977-05-26 |
| AU1917876A (en) | 1978-05-11 |
| JPS5262958A (en) | 1977-05-24 |
| SE426162B (sv) | 1982-12-13 |
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