JPS62176059A - Lead-acid battery - Google Patents
Lead-acid batteryInfo
- Publication number
- JPS62176059A JPS62176059A JP61017309A JP1730986A JPS62176059A JP S62176059 A JPS62176059 A JP S62176059A JP 61017309 A JP61017309 A JP 61017309A JP 1730986 A JP1730986 A JP 1730986A JP S62176059 A JPS62176059 A JP S62176059A
- Authority
- JP
- Japan
- Prior art keywords
- cells
- alloy
- temperature
- lead
- electrolyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002253 acid Substances 0.000 title claims description 10
- 239000003792 electrolyte Substances 0.000 claims abstract description 9
- 229910000882 Ca alloy Inorganic materials 0.000 claims abstract description 6
- 229910001245 Sb alloy Inorganic materials 0.000 claims abstract description 5
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000010586 diagram Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000007600 charging Methods 0.000 description 1
- 238000010280 constant potential charging Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/68—Selection of materials for use in lead-acid accumulators
- H01M4/685—Lead alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Cell Electrode Carriers And Collectors (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は複数のセルを有する鉛蓄電池の改良に関し、例
えば自動車に搭載された場合のエンジンの発熱等に対し
、高温耐久性に優れたメンテナンスフリー電池（補水不
要あるいは補水頻度が小なる電池、以下ｒＭＦｔ池」と
いう）を提供するものである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to the improvement of a lead-acid battery having a plurality of cells, and is a maintenance-free battery that has excellent high-temperature durability against heat generated by an engine when installed in a car, for example. (Batteries that do not require water refilling or require low water refilling frequency, hereinafter referred to as "rMFt ponds").
従来の技術 従来、ＭＦ電池と呼ばれるものには、次の３種かある。Conventional technology Conventionally, there are three types of MF batteries:
すなわら、陽極格子体と陰極格子体の両方にＰｂ−Ｓｂ
系合金を用いた低Ｓｂ電池、陽極格子体墨ζ塁ｂ−Ｓｂ
系合金そして陰極格子体にＰｂ−Ｃａ系合金を用いた）
（１３を池（〕１イブリット電池と呼称される）、陽極
格子体と陰極格子体の両方にＰｂ−Ｃａ系合金を用いた
Ｏａ電池である。That is, Pb-Sb is used in both the anode grid and the cathode grid.
Low Sb battery using alloy, anode grid black ζ base b-Sb
Pb-Ca based alloy was used for the system alloy and cathode lattice body)
This is an Oa battery using a Pb-Ca alloy for both the anode grid and the cathode grid.
発明が解決しようとする問題点
しかし、陽極格子体にＰｂ−Ｓｂ系合金を用いる電池で
は、使用してい（うちに、陽極格子体にあったＳｂが陰
極に電析することにより、減液特性いわゆるメンテナン
スフリー特性を低下させるという欠点があった。又、陽
極格子体にＰ ｂ −Ｏａ系合金を用いる電池では、Ｐ
ｂ−Ｃａ系合金の特性から来ると思われる陽極格子体の
変形、いわゆる伸びの発生と共に、急激な性能低下を生
じるという欠点があった。そしＣ前記陽極格子体の伸び
は、電解液か高温となるセルで顕著であった。例えば鉛
蓄電池りと発熱源（エンジン等）２との関係が気２図の
ような配置の場合、各セルの電解液温度は第３図に示す
通つであり、陽極格子体の伸びは、最も高温となったＣ
！で顕著であった。Problems to be Solved by the Invention However, in batteries that use a Pb-Sb alloy for the anode grid, Sb in the anode grid is deposited on the cathode, resulting in poor liquid reduction properties. This has the disadvantage of reducing the so-called maintenance-free characteristics.Furthermore, in batteries using P b -Oa alloy for the anode grid, P
There was a drawback that deformation of the anode lattice body, so-called elongation, which was thought to result from the characteristics of the b-Ca alloy, resulted in a sudden drop in performance. The elongation of the anode grid was remarkable in cells where the electrolyte was exposed to high temperatures. For example, if the relationship between the lead-acid battery and the heat source (engine, etc.) 2 is as shown in Figure 2, the electrolyte temperature of each cell is as shown in Figure 3, and the elongation of the anode grid is The highest temperature was C
! It was noticeable.
問題点を解決するための手段
本発明は上記の如き欠点を除去するもので、電解液温度
が高くなるセルの陽極板１こはＰｂ−８ｂ系合金の格子
体を、その他のセルの陽極板にはＰｂ−０ａ系合金の格
子体を用いることを特徴とｒるものである。Means for Solving the Problems The present invention eliminates the above-mentioned drawbacks.The present invention is intended to eliminate the above-mentioned drawbacks. It is characterized by using a lattice body of a Pb-0a alloy.
作用
゛は解液温度が高くなるセルの陽極板にＰｂ−Ｓｂ系合
金の格子体を使用すれば、当該セルの温度が高い場合に
も格子体の変形が起こらず、従って、いわゆる伸びの発
生と共に生ずる、急激な性能低下は、当該セルでは発生
しない。又、電解液温度が比較的高くならないセルの陽
極板にＰｂ−０；１系合金の格子体を使用すれば、全て
のセルの陽極板にＰｂ−ｓｈ系合金の格子体を使用した
電池に比べ、定電圧過充電時の電流が小さくなり、過充
電減液特性が向上する。The effect is that if a Pb-Sb alloy lattice is used for the anode plate of a cell where the melting temperature is high, the lattice will not deform even when the temperature of the cell is high, and therefore so-called elongation will not occur. The sudden performance deterioration that occurs with this does not occur in this cell. In addition, if a grid of Pb-0;1 alloy is used for the anode plate of a cell where the electrolyte temperature does not become relatively high, it will be possible to use a grid of Pb-sh alloy for the anode plate of all cells. In comparison, the current during constant voltage overcharging is smaller and the overcharge liquid reduction characteristics are improved.
実施例
本発明は第１図に示ｒように、発熱源２に近い側の３セ
ルをＨＢ電池３で、遠い側の３セルをＣａ電池４で構成
した。EXAMPLE In the present invention, as shown in FIG. 1, three cells near the heat generating source 2 were composed of HB batteries 3, and three cells far from the heat generating source 2 were composed of Ca batteries 4.
本発明の一実施例を説明する。An embodiment of the present invention will be described.
第４図に、ｓ ｓ ｏ ２３型鉛蓄電池につい°Ｃ１６
３°Ｃ水槽中で、２，１８Ｖ／セルの定電圧充電を行な
った時の充電期間に対する陽極板の高さ方向の伸びの変
化を示す。なお、各プロットは別々のセルに於ける測定
値である。図から判るように、低Ｓｂ電池の陽極格子体
の伸びは、Ｏａ電池のそれｌζ比べ、非常に小さい。又
、第５図に、４０“Ｃ水槽中での結果を示す。図から、
温度が比較的に低い場合には、Ｃａｉ池の陽極格子体の
伸びは小さい。次に、第１表に、同型鉛蓄電池について
２５°Ｃ水槽中で１５Ｖ／６セルの定電圧過充電を行な
った時の、１２０時間目の過充を電流を示す。Figure 4 shows the sso 23 type lead acid battery at °C16.
This figure shows the change in elongation of the anode plate in the height direction with respect to the charging period when constant voltage charging at 2.18 V/cell was performed in a 3°C water bath. Note that each plot is a measurement value in a separate cell. As can be seen from the figure, the elongation of the anode lattice of the low Sb battery is much smaller than that of the Oa battery. Also, Figure 5 shows the results in a 40"C water tank. From the figure,
When the temperature is relatively low, the elongation of the Cai pond anode grid is small. Next, Table 1 shows the overcharging current at the 120th hour when constant voltage overcharging of 15V/6 cells was performed for the same type of lead acid battery in a 25°C water bath.
第 １ 表
表から判るように、本発明による電池の過充を電流は、
（３ａＴ［池のそれより若干大であるが。As can be seen from Table 1, the current for overcharging the battery according to the present invention is:
(3aT [Although it is slightly larger than that of the pond.
１（Ｂｆｉ池、低Ｓｂ＠池のそれよりは、はるかに小さ
い。1 (much smaller than that of Bfi pond and low Sb@ pond.
発明の効果
上述のように本発明ｔζよれば、度数のセルを有する鉛
蓄電池において、電解液温度か高（なり易い一部のセル
の急激な性能低下を防止し。Effects of the Invention As described above, according to the present invention tζ, in a lead-acid battery having cells of 100 to 300 Hz, the electrolyte temperature can be prevented from rapidly deteriorating in some cells, which is likely to occur.
減液特性をほとんど低下させずに、Ｗｌ池のＩＦ命延長
を図ることかできる点極めて有用である。It is extremely useful in that it is possible to extend the IF life of the Wl pond without substantially reducing the liquid reduction characteristics.
第り図は本発明の一実施例を示゛ｒ説明図、第２図（を
鉛蓄電池と発熱源との位置１カ係を示す説明図、第３図
は第２図における鉛蓄電池各セルの電解液温度を示す曲
線図、第４図は６３°Ｃ水槽中で定電圧充電した時の陽
極板の伸びを示す曲線図−１１１５図は４０°Ｃ水槽中
で定電圧充電した時の陽極板の伸びを示す曲線図。Figure 2 is an explanatory diagram showing one embodiment of the present invention, Figure 2 is an explanatory diagram showing the positional relationship between the lead-acid battery and the heat source, and Figure 3 is an explanatory diagram showing each cell of the lead-acid battery in Figure 2. Figure 4 is a curve diagram showing the elongation of the anode plate when charged at constant voltage in a 63°C water tank - Figure 1115 is a curve diagram showing the elongation of the anode plate when charged at constant voltage in a 40°C water tank. A curve diagram showing the elongation of the plate.
Claims (1)
くなり易いセルの陽極板にはＰｂ−Ｓｂ系合金の格子体
を、他のセルの陽極板にはＰｂ−Ｃａ系合金の格子体を
使用したことを特徴とする鉛蓄電池。In a lead-acid battery consisting of multiple cells, a Pb-Sb alloy lattice is used for the anode plate of the cell where the electrolyte temperature tends to rise, and a Pb-Ca alloy lattice is used for the anode plates of other cells. A lead-acid battery that is characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61017309A JPS62176059A (en) | 1986-01-29 | 1986-01-29 | Lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61017309A JPS62176059A (en) | 1986-01-29 | 1986-01-29 | Lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS62176059A true JPS62176059A (en) | 1987-08-01 |
Family
ID=11940407
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61017309A Pending JPS62176059A (en) | 1986-01-29 | 1986-01-29 | Lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62176059A (en) |
-
1986
- 1986-01-29 JP JP61017309A patent/JPS62176059A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP4501330B2 (en) | Lead acid battery | |
| CN113258032B (en) | Negative electrode material, negative electrode slurry, battery cell, low-temperature-resistant battery and preparation method of battery | |
| JPS62176059A (en) | Lead-acid battery | |
| JPS5931836B2 (en) | lead acid battery | |
| JP3094423B2 (en) | Lead storage battery | |
| JP4827452B2 (en) | Method for producing lead-acid battery | |
| JP3030143B2 (en) | Non-aqueous electrolyte secondary battery | |
| Burrows et al. | Low maintenance lead-acid batteries for energy storage | |
| JPH10294113A (en) | Positive electrode plate for sealed lead-acid battery | |
| JPS607061A (en) | Manufacture of plate for sealed lead storage battery | |
| JP2964555B2 (en) | Battery storage method for lead-acid batteries | |
| JPH0869813A (en) | Sealed lead-acid battery | |
| JP2553858B2 (en) | Lead acid battery | |
| JPH0294369A (en) | Sealed lead-acid battery | |
| JPH0770321B2 (en) | Sealed lead acid battery | |
| JPH08236101A (en) | Lead-acid battery | |
| JPH03147262A (en) | Collector for lead-acid battery | |
| JP3496241B2 (en) | How to charge lead storage batteries | |
| JPS62208568A (en) | Paste type lead-acid battery | |
| JP2002367668A (en) | Control valve type lead acid storage battery | |
| JPH0193058A (en) | Lead-acid battery | |
| JP2004071224A (en) | Storage battery | |
| JPS62188169A (en) | Sealed lead-acid battery | |
| JPS61153958A (en) | Maintenance-free lead acid battery | |
| JPH02160374A (en) | Sealed type lead-acid battery |