JPS62161711A - Weakly acidic gel cosmetic - Google Patents
Weakly acidic gel cosmeticInfo
- Publication number
- JPS62161711A JPS62161711A JP279086A JP279086A JPS62161711A JP S62161711 A JPS62161711 A JP S62161711A JP 279086 A JP279086 A JP 279086A JP 279086 A JP279086 A JP 279086A JP S62161711 A JPS62161711 A JP S62161711A
- Authority
- JP
- Japan
- Prior art keywords
- cosmetic
- weakly acidic
- hydroxide
- water
- alkali metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
発明の分野
本発明は、皮膚に適用される弱酸性ゲル状化粧料ｌこ関
する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to weakly acidic gel cosmetics for application to the skin.
従来技術
人間の皮膚は酸性被膜（ａｃｉｄ ｍａｎｔｌｅ ）に
覆われており、健康な状態においては弱酸性（ｐＨ４，
５〜６．５）を呈している。したがって、皮膚に塗布す
る化粧料も弱酸性であることが皮膚の健康維持上望まし
い。そこで、従来、ゲル化剤きして水溶性、カルボキシ
ビニルポリマーを用いるゲル状化粧料を０虐いては、該
カルボキシビニルポリマーを中和し、該化粧料を所望の
弱酸性とするために、一般ニ、トリエタノールアミン、
ジェタノールアミンなどのアミン類が用いられている。Prior Art Human skin is covered with an acid mantle, and in a healthy state it has a weak acidity (pH 4,
5 to 6.5). Therefore, it is desirable for cosmetics applied to the skin to be weakly acidic in order to maintain skin health. Therefore, conventionally, gel cosmetics using a water-soluble carboxyvinyl polymer as a gelling agent are mixed to neutralize the carboxyvinyl polymer and make the cosmetic the desired weak acidity. General di, triethanolamine,
Amines such as jetanolamine are used.
しかしながら、これらのアミン類は、皮膚１こ刺激等の
望ましくない影響をおよぼすことが報告されている。そ
のため、塩基性アミノ酸、アルカリ金属水酸化物などを
中和剤として用いる試みもｔ’ｌされているが、これら
の中和剤を用いた場合、該化粧料は弱酸性では充分にゲ
ル化せず、適当な粘度のゲルを形成させるためには弱塩
基性で使用しなければならず、皮膚の健康維持上望まし
くなかった。However, these amines have been reported to have undesirable effects such as skin irritation. Therefore, attempts have been made to use basic amino acids, alkali metal hydroxides, etc. as neutralizing agents, but when these neutralizing agents are used, the cosmetics cannot be sufficiently gelled in weak acidity. First, in order to form a gel with an appropriate viscosity, it must be used in a weakly basic state, which is not desirable in terms of maintaining skin health.
本発明者は、以上の問題点を克服すべく種々検討を重ね
る間ｌこ、意外にも、塩基性アミノ酸およびアルカリ金
属水酸化物を併用して水溶性カルボキシビニルポリマー
を中和することｌこより弱酸性で適度な粘度を与えるゲ
ル状化粧料が得られることを見出し、本発明を完成する
に至った。While carrying out various studies to overcome the above problems, the present inventor unexpectedly discovered the idea of neutralizing a water-soluble carboxyvinyl polymer using a combination of a basic amino acid and an alkali metal hydroxide. The present inventors have discovered that it is possible to obtain a gel cosmetic that is weakly acidic and has an appropriate viscosity, and has completed the present invention.
発明の開示
すなわち、本発明は、水溶性カルボキシビニルポリマー
、塩基性アミノ酸およびアルカリ金属水酸化物を含有す
ることを特徴とする弱酸性ゲル状化粧料を提供するもの
である。本発明によれば、皮膚の酸性被膜を損わず、健
康維持上望ましい弱酸性（ｐＨ４，０〜６．８）のゲル
状化粧料が得られる。Disclosure of the Invention That is, the present invention provides a weakly acidic gel cosmetic characterized by containing a water-soluble carboxyvinyl polymer, a basic amino acid, and an alkali metal hydroxide. According to the present invention, it is possible to obtain a weakly acidic (pH 4.0 to 6.8) cosmetic gel that does not damage the acidic film on the skin and is desirable for maintaining health.
本発明ｌこ用いられる塩基性アミノ酸としては、アルギ
ニン、リジン、ヒドロキシリジン、ヒスチジンなどが挙
げられ、これらの１種または２種以上が化粧料全量に対
して０．０１〜５．０重量％、好ましくは０．１〜２．
０重量％の範囲で配合され、アルカリ金属水酸化物とし
ては、水酸化カリウム、水酸化ナトリウム、水酸化リチ
ウムなどが挙げられ、これらの１種または２種以上が化
粧料全量に対して０．０１〜５．０重量％、好ましくは
、０．０５〜２．０重量％の範囲で配合される。塩基性
アミノ酸およびアルカリ金属水酸化物のいずれか一方の
配合量が０．０１重量％未満であると弱酸性ｌこおいて
良好なゲルが形成されず、また、両者の配合量の合計が
８．０重量％を超えると該化粧料が塩基性になってしま
い、所望する弱酸性ゲル状化粧料が得られなくなる。The basic amino acids used in the present invention include arginine, lysine, hydroxylysine, histidine, etc., and one or more of these may be present in an amount of 0.01 to 5.0% by weight based on the total amount of the cosmetic. Preferably 0.1-2.
The alkali metal hydroxides include potassium hydroxide, sodium hydroxide, lithium hydroxide, etc., and one or more of these are blended in an amount of 0.0% by weight based on the total amount of the cosmetic. 01 to 5.0% by weight, preferably 0.05 to 2.0% by weight. If the amount of either the basic amino acid or the alkali metal hydroxide is less than 0.01% by weight, a good gel will not be formed in a weakly acidic environment, and the total amount of both will be less than 8% by weight. If it exceeds 0.0% by weight, the cosmetic becomes basic, making it impossible to obtain the desired weakly acidic gel-like cosmetic.
本発明の化粧料ｌこゲル化剤として用いられている水溶
性カルボキシビニルポリマーは、化粧料全量ｌこ対して
０．０１〜５．０重量％、好ましくは０．２〜２．５重
量％の範囲で配合される。配合量が０．０１重量％より
少ないと充分なゲル性を呈さず、また、５．０重置％よ
り多いと粘度が高くなり過ぎて、ともに化粧料として使
用するのに適さなくなる。The water-soluble carboxyvinyl polymer used as a gelling agent in the cosmetic of the present invention is 0.01 to 5.0% by weight, preferably 0.2 to 2.5% by weight based on the total amount of the cosmetic. It is blended within the range of. If the amount is less than 0.01% by weight, sufficient gelling properties will not be exhibited, and if the amount is more than 5.0% by weight, the viscosity will become too high, making both of them unsuitable for use as cosmetics.
つぎｌこ、トリエタノールアミン、Ｌ−アルギニンおよ
び水酸化°カリウムを中和剤として用いた化粧料におい
て形成したゲルの評価を行なった結果を示す。Next, the results of evaluating gels formed in cosmetics using triethanolamine, L-arginine, and potassium hydroxide as neutralizing agents are shown.
試料として用いた化粧料はつぎの処方に従い、常法によ
り製造した。The cosmetic used as a sample was manufactured by a conventional method according to the following recipe.
成 分 配合量（重量％）水溶
性カルボキシビニルポリマー １．０ソルビト
ール ３．０ヤシ油脂肪酸
アミドプロピルジメ
チルアミノ酢酸ベタイン ０．５メツ
キンスＭＯ・３
メツキンスＰＯ６２
１，３−ブチレングリコール ４．０ポ
リオキシエチレン（１５Ｅ、０．）
グリセリルモノステアレート ５．０ポリオ
キシエチレン硬化ヒマシ油
（４０Ｅ、０．） ４．
０香料 ０．６中
和剤 第１表に表示精
製水 １００１こ調整形
成したゲルは、瓶中におけるゲルの流動性をもとに、つ
ぎの基準に従って評価した。Ingredients Amount (wt%) Water-soluble carboxyvinyl polymer 1.0 Sorbitol 3.0 Coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine 0.5 Metkins MO・3 Metkins PO62 1,3-butylene glycol 4.0 Polyoxyethylene (15E, 0.) Glyceryl monostearate 5.0 Polyoxyethylene hydrogenated castor oil (40E, 0.) 4.
0 Flavor 0.6 Neutralizing agent Shown in Table 1 Purified water 1001 The gel thus prepared was evaluated according to the following criteria based on the fluidity of the gel in the bottle.
Ｏ・・・・・・瓶傾倒後も流動性を示さない。O: Shows no fluidity even after the bottle is tilted.
△・・・・・・瓶傾倒後徐々ｆこ流動性を示す。Δ: Gradually shows fluidity after the bottle is tilted.
Ｘ・・・・・・瓶傾倒と同時【こ流動性を示す。X...At the same time as the bottle is tilted [This shows fluidity.
結果は第１表に示すとおりである。なお、稠度は不動工
業（株）製しオメータＮＲＭ−２００２Ｊ型を用いて、
サンプルを２５℃に恒温化し、直径１０ ｍｍのアダプ
ターを用いて、エレベータ−の上昇温度を２ ＣＨＩ
／ ｒｒｌ １ ｎ とした条件下で測定した値であ
る。The results are shown in Table 1. The consistency was measured using Ometer NRM-2002J model manufactured by Fudo Kogyo Co., Ltd.
The sample was incubated at 25°C and the elevator temperature was increased to 2 CHI using a 10 mm diameter adapter.
/rrl 1 n .
第１表１こ示すごとく、Ｌ−アルギニンおよび水酸化カ
リウムを併用した場合ｌこのみ、弱酸性の良好なゲルが
得られる。As shown in Table 1, when L-arginine and potassium hydroxide are used together, a gel with good weak acidity can be obtained.
さらに、本発明の弱酸性ゲル状化粧料１こは、必要に応
じて適当な非イオン界面活性剤、アニオン界面活性剤、
カチオン界面活性剤、両性界面活性剤、油分、ワックス
、防腐剤、酸化防止剤、薬剤、紫外線吸収剤、色素、香
料、水等を弱酸性およびゲル形成を損わない範囲で添加
することができる。Furthermore, the weakly acidic gel cosmetic of the present invention 1 may contain a suitable nonionic surfactant, anionic surfactant,
Cationic surfactants, amphoteric surfactants, oils, waxes, preservatives, antioxidants, drugs, ultraviolet absorbers, pigments, fragrances, water, etc. can be added to the extent that they do not impair weak acidity or gel formation. .
本発明化粧料は常法Ｅこ従って製造することができ、洗
顔料、整肌料、整髪、料等の通常の剤型とすることがで
きる。The cosmetic composition of the present invention can be manufactured according to the conventional method E, and can be made into a usual dosage form such as a face wash, a skin conditioner, a hair conditioner, etc.
このようにして得られた本発明の弱酸性ゲル状化粧料は
、皮膚を覆っている酸性被膜を損わず、皮膚の健康維持
ζこ好ましいものである。The weakly acidic gel-like cosmetic of the present invention thus obtained does not damage the acidic film covering the skin and is preferable for maintaining the health of the skin.
実施例 つぎに実施例を挙げて本発明をさらに詳しく説明する。Example Next, the present invention will be explained in more detail with reference to Examples.
実施例１
つぎの処方ｌこより常法に従って弱酸性ゲル状洗顔料（
ＰＨ６，０）を調製した。Example 1 A weakly acidic gel facial cleanser (
PH6,0) was prepared.
成 分 配合量（重量％）水溶性カ
ルボキシビニルポリマー １．０ソルビトール
３．０ヤシ油脂肪酸アミドプロピ
ルジメ
チルアミ／酢酸ベタイン ０．５メツキン
スＭ Ｏ，３メツキンスＰ
Ｏ，２１，３−ブチレングリ
コール ４．０ポリオキシエチレン（１５Ｅ
、０．）
グリセリルモノステアレート ５．０ポリオキ
シエチレン硬化ヒマシ油
（４０Ｅ、０． ’） ４．
０香料 ０．６ＫＯ
ＨＯ，４
精製水 残部実施例２
つぎの処方により常法ｌこ従って弱酸性ゲル状化粧水（
ＰＨ６，２）を調製した。Ingredients Amount (wt%) Water-soluble carboxyvinyl polymer 1.0 Sorbitol
3.0 Coconut oil fatty acid amidopropyldimethylamine/betaine acetate 0.5 Metzkins M O, 3 Metzkins P
O,21,3-butylene glycol 4.0 polyoxyethylene (15E
, 0. ) Glyceryl monostearate 5.0 Polyoxyethylene hydrogenated castor oil (40E, 0.') 4.
0 fragrance 0.6KO
HO,4 Purified water Remainder Example 2 A weakly acidic gel lotion (
PH6,2) was prepared.
成 分 配合量（重量％）水溶
性カルボキシビニルポリマー ０．４エタノール
３０６０Ｌ−アルギニン
０．３ＫＯＨＯ，１
１，３−ブチレングリコール ２．０ポリ
オキシエチレン硬化ヒマシ浦
（６０Ｅ、０． ） ０．
７香料 ０．２精
製水 残部実施例３
つぎの処方により常法に従って弱酸性ゼリー状ふきとり
型パック（ＰＨ５，９） を調製した。Ingredients Amount (wt%) Water-soluble carboxyvinyl polymer 0.4 Ethanol 3060L-arginine 0.3 KOHO, 1 1,3-butylene glycol 2.0 Polyoxyethylene hardened castor ura (60E, 0.) 0.
7 Fragrance 0.2 Purified Water Remaining Example 3 A weakly acidic jelly-like wipe-off type pack (PH 5,9) was prepared according to the following recipe according to a conventional method.
成 分 配合量（重量％）ヒドロ
キシエチルセルロース ３．０水溶性カルボ
キシビニルポリマー １．０ポリオキシエチレン
オレイルエー
ゲル（１５Ｅ、０． ） １．０
ＫＯＩ（０，３
Ｌ−アルギニン ０．６エタノ
ール ５・０香料
０．３メツキンス
ＭＯ１２
精製水 残部実施例
４
つぎの処方ｌこより常法に従って弱酸性ゲル状ヘアコン
ディショナー（ｐＨ５，８）を調整した。Component Amount (wt%) Hydroxyethyl cellulose 3.0 Water-soluble carboxyvinyl polymer 1.0 Polyoxyethylene oleyl agel (15E, 0.) 1.0
KOI (0.3 L-Arginine 0.6 Ethanol 5.0 Fragrance
0.3 Metzkins MO12 Purified water Remainder Example 4 A weakly acidic gel hair conditioner (pH 5.8) was prepared using the following formulation according to a conventional method.
成 分
水溶性カルボキシビニルポリマー ０．８プロ
ピレングリコール ５，０ポリオ
キシエチレラノリン ５．０流動パラフ
イン ２５．０ミリスチン酸イ
ソプロピル １２．０ワセリン
６．０ポリオキシエチレン
ステアリルエーテル（３０Ｅ、０．） ４．ＯＬ
−アルギニン ０．４ＮａＯ
ＨＯ，１Ingredients Water-soluble carboxyvinyl polymer 0.8 Propylene glycol 5.0 Polyoxyethylene lanoline 5.0 Liquid paraffin 25.0 Isopropyl myristate 12.0 Vaseline
6.0 Polyoxyethylene stearyl ether (30E, 0.) 4. OL
-Arginine 0.4NaO
HO,1
Claims (4)
酸およびアルカリ金属水酸化物を含有することを特徴と
する弱酸性ゲル状化粧料。(1) A weakly acidic gel cosmetic containing a water-soluble carboxyvinyl polymer, a basic amino acid, and an alkali metal hydroxide.
キシリジンおよびヒスチジンからなる群から選ばれる前
記第（１）項の化粧料。(2) The cosmetic according to item (1) above, wherein the basic amino acid is selected from the group consisting of arginine, lysine, hydroxylysine, and histidine.
化ナトリウムおよび水酸化リチウムからなる群から選ば
れる前記第（１）項の化粧料。(3) The cosmetic according to item (1) above, wherein the alkali metal hydroxide is selected from the group consisting of potassium hydroxide, sodium hydroxide, and lithium hydroxide.
ボキシビニルポリマーを０．０１〜５．０重量％、塩基
性アミノ酸を０．０１〜５．０重量％およびアルカリ金
属水酸化物を０．０１〜５．０重量％含有することを特
徴とする前記第（１）項の化粧料。(4) 0.01 to 5.0% by weight of water-soluble carboxyvinyl polymer, 0.01 to 5.0% by weight of basic amino acid, and alkali metal hydroxide based on the total weight of the weakly acidic gel cosmetic. The cosmetic composition according to item (1) above, characterized in that it contains 0.01 to 5.0% by weight of.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61002790A JPH0745393B2 (en) | 1986-01-08 | 1986-01-08 | Weakly acidic gel cosmetics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61002790A JPH0745393B2 (en) | 1986-01-08 | 1986-01-08 | Weakly acidic gel cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62161711A true JPS62161711A (en) | 1987-07-17 |
| JPH0745393B2 JPH0745393B2 (en) | 1995-05-17 |
Family
ID=11539152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61002790A Expired - Lifetime JPH0745393B2 (en) | 1986-01-08 | 1986-01-08 | Weakly acidic gel cosmetics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0745393B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63174924A (en) * | 1987-01-14 | 1988-07-19 | Toko Yakuhin Kogyo Kk | Ointment base and ointment |
| JPH03178913A (en) * | 1989-12-06 | 1991-08-02 | Shiseido Co Ltd | Skin external agent |
| WO1994026236A1 (en) * | 1993-05-14 | 1994-11-24 | Henkel Kommanditgesellschaft Auf Aktien | Hair-treatment agents |
| JP2002212049A (en) * | 2001-01-18 | 2002-07-31 | Noevir Co Ltd | Skin cosmetic |
| EP1657263A4 (en) * | 2003-07-18 | 2007-02-14 | Japan Exlan Co Ltd | Polymer sustainedly releasing amino acid derivative, cosmetic and fiber construct containing the polymer, method of producing the same and method of regenerating the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5748904A (en) * | 1980-09-05 | 1982-03-20 | Kanebo Ltd | Transparent cosmetic |
| JPS5939814A (en) * | 1982-08-27 | 1984-03-05 | Shiseido Co Ltd | Cosmetic |
| JPS59161308A (en) * | 1983-03-01 | 1984-09-12 | Shiseido Co Ltd | External preparation for skin |
| JPS6081119A (en) * | 1983-10-13 | 1985-05-09 | Shiseido Co Ltd | Cosmetic containing metal lame agent |
-
1986
- 1986-01-08 JP JP61002790A patent/JPH0745393B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5748904A (en) * | 1980-09-05 | 1982-03-20 | Kanebo Ltd | Transparent cosmetic |
| JPS5939814A (en) * | 1982-08-27 | 1984-03-05 | Shiseido Co Ltd | Cosmetic |
| JPS59161308A (en) * | 1983-03-01 | 1984-09-12 | Shiseido Co Ltd | External preparation for skin |
| JPS6081119A (en) * | 1983-10-13 | 1985-05-09 | Shiseido Co Ltd | Cosmetic containing metal lame agent |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63174924A (en) * | 1987-01-14 | 1988-07-19 | Toko Yakuhin Kogyo Kk | Ointment base and ointment |
| JPH0555483B2 (en) * | 1987-01-14 | 1993-08-17 | Toko Yakuhin Kogyo Kk | |
| JPH03178913A (en) * | 1989-12-06 | 1991-08-02 | Shiseido Co Ltd | Skin external agent |
| WO1994026236A1 (en) * | 1993-05-14 | 1994-11-24 | Henkel Kommanditgesellschaft Auf Aktien | Hair-treatment agents |
| JP2002212049A (en) * | 2001-01-18 | 2002-07-31 | Noevir Co Ltd | Skin cosmetic |
| JP4577996B2 (en) * | 2001-01-18 | 2010-11-10 | 株式会社ノエビア | Skin cosmetics |
| EP1657263A4 (en) * | 2003-07-18 | 2007-02-14 | Japan Exlan Co Ltd | Polymer sustainedly releasing amino acid derivative, cosmetic and fiber construct containing the polymer, method of producing the same and method of regenerating the same |
| CN100424104C (en) * | 2003-07-18 | 2008-10-08 | 日本爱克兰工业株式会社 | Polymer sustainedly releasing amino acid derivative, cosmetic and fiber construct containing the polymer, method of producing the same and method of regenerating the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0745393B2 (en) | 1995-05-17 |
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