JPS6191103A - Acaricide - Google Patents
AcaricideInfo
- Publication number
- JPS6191103A JPS6191103A JP59213764A JP21376484A JPS6191103A JP S6191103 A JPS6191103 A JP S6191103A JP 59213764 A JP59213764 A JP 59213764A JP 21376484 A JP21376484 A JP 21376484A JP S6191103 A JPS6191103 A JP S6191103A
- Authority
- JP
- Japan
- Prior art keywords
- benzyl benzoate
- mites
- acaricide
- main chain
- aliphatic hydrocarbon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000000895 acaricidal effect Effects 0.000 title claims abstract description 14
- 239000000642 acaricide Substances 0.000 title claims abstract description 13
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 150000001338 aliphatic hydrocarbons Chemical group 0.000 claims abstract description 8
- 239000000443 aerosol Substances 0.000 claims abstract description 7
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 claims abstract 14
- 229960002903 benzyl benzoate Drugs 0.000 claims abstract 7
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract 2
- 229930195733 hydrocarbon Natural products 0.000 claims abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract 2
- 239000002917 insecticide Substances 0.000 claims description 6
- 239000002728 pyrethroid Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 5
- 241001465754 Metazoa Species 0.000 abstract description 4
- 239000007921 spray Substances 0.000 abstract description 3
- 239000004480 active ingredient Substances 0.000 abstract description 2
- 239000000839 emulsion Substances 0.000 abstract description 2
- 235000013305 food Nutrition 0.000 abstract description 2
- 239000003350 kerosene Substances 0.000 abstract description 2
- 239000012188 paraffin wax Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 1
- 241000238876 Acari Species 0.000 description 25
- 239000000428 dust Substances 0.000 description 9
- 239000002253 acid Substances 0.000 description 7
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000417 fungicide Substances 0.000 description 4
- 241000238710 Dermatophagoides Species 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- -1 fatty acid esters Chemical class 0.000 description 3
- 239000005871 repellent Substances 0.000 description 3
- 230000002940 repellent Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 241000238711 Pyroglyphidae Species 0.000 description 2
- 241000283984 Rodentia Species 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- 210000000078 claw Anatomy 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000003623 enhancer Substances 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 229940046533 house dust mites Drugs 0.000 description 2
- 239000003915 liquefied petroleum gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229940108410 resmethrin Drugs 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- SBNFWQZLDJGRLK-RTWAWAEBSA-N (1R)-trans-phenothrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 SBNFWQZLDJGRLK-RTWAWAEBSA-N 0.000 description 1
- WAITXWGCJQLPGH-UHFFFAOYSA-N 1-ethylsulfanyloctane Chemical compound CCCCCCCCSCC WAITXWGCJQLPGH-UHFFFAOYSA-N 0.000 description 1
- PIVQQUNOTICCSA-UHFFFAOYSA-N ANTU Chemical compound C1=CC=C2C(NC(=S)N)=CC=CC2=C1 PIVQQUNOTICCSA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000488563 Eotetranychus carpini Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- 208000006877 Insect Bites and Stings Diseases 0.000 description 1
- 241000273338 Macronyssidae Species 0.000 description 1
- YBHQCJILTOVLHD-YVMONPNESA-N Mirin Chemical compound S1C(N)=NC(=O)\C1=C\C1=CC=C(O)C=C1 YBHQCJILTOVLHD-YVMONPNESA-N 0.000 description 1
- 241000916145 Tarsonemidae Species 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000000073 carbamate insecticide Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- FODTZLFLDFKIQH-FSVGXZBPSA-N gamma-Oryzanol (TN) Chemical compound C1=C(O)C(OC)=CC(\C=C\C(=O)O[C@@H]2C([C@@H]3CC[C@H]4[C@]5(C)CC[C@@H]([C@@]5(C)CC[C@@]54C[C@@]53CC2)[C@H](C)CCC=C(C)C)(C)C)=C1 FODTZLFLDFKIQH-FSVGXZBPSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000000749 insecticidal effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 229960000490 permethrin Drugs 0.000 description 1
- RLLPVAHGXHCWKJ-UHFFFAOYSA-N permethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OCC1=CC=CC(OC=2C=CC=CC=2)=C1 RLLPVAHGXHCWKJ-UHFFFAOYSA-N 0.000 description 1
- 229960003536 phenothrin Drugs 0.000 description 1
- 238000005375 photometry Methods 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
江業上の卯四−分」ｍ
本発明は段ダニ削、特に長ル］ｌこイつたる浸透二散汀
に雪・−た安９谷酸へ／ノル系殺ダニ剤に関”ｔろ。[Detailed Description of the Invention] The present invention is based on step-wise cutting, especially long-cutting. Regarding acaricides.
従゛」′：技Ｉｆｉ
従来から屋内性のダニで人間に対して重要な被害をした
らすしのにイエダニかよく知られていた。゛'': Techniques Ifi Traditionally, indoor dust mites that cause serious damage to humans have been known to be dust mites.
しかし近年前や家屋四から発生するコナダニ類やチリダ
ニ題（ヒヨウヒダニ類）更にこれらを捕食するツメダニ
類のアレルギー、虫咬症などが問題となり、これらのダ
ニ類の防除に従来から害虫類の防除に使用されていたＨ
ａミリン虫剤、カーバメート系殺虫剤、ピレスロイド系
段虫昂（などか試みられているか、いずれも防除の決め
手にはならず、又長期にわたって浸透拡散性を発揮する
ものがなく安全性の面からピレスロイド系殺虫剤の使用
か多くなっている。However, in recent years, problems such as dust mites and house dust mites that appear in houses, as well as allergies and insect bites from the claw mites that prey on these mites, have become a problem, and it has been used to control pests to control these mites. H that was being
(a) Mirin insecticides, carbamate insecticides, pyrethroid insecticides, etc. have been tried, but none of them are decisive for control, and there are no long-term permeation-diffusion properties, so there are concerns about safety. The use of pyrethroid insecticides is increasing.
一方、安Ｑ香酸ベノノルは段ダニ剤として広く使用され
ているか、浸透に散性に乏しく、従〜て、十分なｉぐ虫
効果か（’Ｅられないという欠点かあった。On the other hand, Benonol benzoate is widely used as a mite agent, but it has poor penetration and dispersibility, so it may not have sufficient insecticidal effect (it also has the drawback of not being able to be absorbed).
この欠点を改良するため脂肪酸エステル類をＦｌ’散抑
ｉ、ｌＩ剤として用いる提案かなさイーでいろ（特開昭
５５−１２２７０２Ｊゴー公報）、、シかしｔから、指
１「ノ醒エステル■１は、／−ソやノユウクノμｊの汚
染や黴の堅固となるため二ζらのらのを吋象とする使用
に：ｉ必ずしし適していない。In order to improve this drawback, it is proposed to use fatty acid esters as Fl' dispersion inhibitors (Japanese Patent Application Laid-open No. 55-122702J). ■1 is not necessarily suitable for use with 2ζ et al. as it causes contamination of /-so and noyukuno μj and hardening of mold.
含狐左ｙ迭１−ようζＪ’％腓差尭
安口す酸へ７ノルを有効成分とする殺ダニ剤の浸６拡散
性を汚染性物質を用いろことなく向上さＵることを目的
とする。The purpose is to improve the dispersibility of acaricides containing 7nol as an active ingredient by soaking them in acid without using any contaminants. shall be.
問題；＼を解決するための手段
本発明者らは、指Ａｂ枚炭化水素を主鎖として存する化
合物（特にパラフィン系炭化水素）を安１香酸ヘノノル
と併用すると、安θ呑酸ベンノルの骨中への拡散性かｘ
Ｌ＜高くなることを究明しに。Means for Solving Problem; Is it diffusible inside?
To find out why L< is high.
即ち、本発明は安つ呑酸ベノノルと脂肪族炭化水素を主
鎖として存する化合物を含有する殺ダニ剤に関する。That is, the present invention relates to an acaricide containing benonol acetate and a compound having an aliphatic hydrocarbon as its main chain.
本発明に用いろ脂肪族炭化水素を主鎖として有する化合
物は沸Ａ１５０〜３００°Ｃ１より好ましくは１８０〜
２１１１０℃のらのであり（このＥａＭＪをはずれろ場
合は骨内に広く安９香酸べ／ノルが広がることはない）
、直鎖パラフィン類、側鎖を有するパラフィン類、ナフ
テン類およびそれらの混合物であってしよい。溶解性の
くで側鎖を汀するベラライフ類（パラフィン系炭化−１
？素類）か好ましい。最し一般的ζものとして、ケロノ
ノかめる。The compound having an aliphatic hydrocarbon as the main chain used in the present invention has a boiling point of 150 to 300°C, preferably 180 to 300°C.
It is 21110℃ (if this EaMJ is removed, ben9zoic acid ben/nol will not spread widely within the bone)
, normal paraffins, paraffins with side chains, naphthenes and mixtures thereof. Veralife (paraffinic carbonization-1
? elemental class) is preferred. The most common ζ is keronononokameru.
安ρｆｆ酸ベノジルに対するＩＨ脂肪族炭化水素主鎖と
して有する化合物の量は前者０１〜５重！け部に対して
後背５０〜２００重Φ部、より好ましくは前者０５〜２
重’ｉｔ部に対して後者８０〜１７０重指部である。The amount of the compound possessed as the IH aliphatic hydrocarbon main chain for benodyl anodic acid is 01 to 5 times the former! The back part has a diameter of 50 to 200, more preferably the former part is 05 to 2.
The latter is 80 to 170 times larger than the ``it'' portion.
更に本発明のダニ防除組成物には、公知の害虫忌避剤、
効力増強剤、酸化防止剤、殺虫剤、げっ歯動物駆除及び
忌避剤、殺菌剤、防黴剤、除草剤、肥料、着香料、着色
料等を配合することができろ。Furthermore, the mite control composition of the present invention contains known pest repellents,
Potency enhancers, antioxidants, insecticides, rodent control and repellents, fungicides, fungicides, herbicides, fertilizers, flavorings, colorants, etc. can be added.
配合可能な他の害虫忌避剤としては、Ｎ、Ｎ ノエチル
ーメタートルアミド、２．３．４．５−ヒス（Δ。Other pest repellents that can be blended include N,N noethyl-methertoluamide, 2.3.4.5-His (Δ.
ブチレノ）−テトラヒドロフルフラール、ノーｎプート
ルイソノンコンロ不一ト、ジーｎ−プチルサクノネート
、２−ヒトクキ／エチルオクチルサルファイド等を、効
力増強剤としてはＮ−（２−エチルヘキノル）ヒノクロ
−（２，２，Ｉ Ｌ５−へブテノ−２゜３−ンカルホキ
ノイミト、６−（プロピルピベａニル）−ブチルカルヒ
チルエーテル等を、酸化防止剤と乙ではブチ！レヒドロ
キ／アニノール、ジブチルヒドロキノトルエン、トフフ
エロール、γ オリザノール等を、殺虫剤としては一般
名アレスリ／及びその幾何及び（又は）光学異性体、フ
ェノバレレート、ペルメトリン、フェノトリン、Ｄ−レ
スメトリン、ＤＬ−レスメトリン等の少なくとし１種以
上のピレスロイド類を、げっ歯動物駆除及び弘１１とし
てはα−ナフチルチオウレア、ノクロへキノミド等を、
殺菌剤としてはサリチル酸、ｐクロロ・ｍ−キルノール
、２−（＝１’−チアゾイル）ベノズイミダゾール等を
、防黴剤としてはα ブロモノンナミソクアルデヒト、
Ｎ ツメチル−Ｎ−フェニルＮ′・（フルオロジクロロ
メチル）チオスルファミド等を夫々例示できるか、これ
らに限定されるしのではない。N-(2-ethylhexynol)-tetrahydrofurfural, non-n-butyl isonone, di-n-butyl sacnonate, 2-hytonocyl/ethyl octylsulfide, etc., and the potency enhancers include N-(2-ethylhexynol)-tetrahydrofurfural, di-n-butyl sacnonate, ,2,I L5-hebuteno-2゜3-enecarphoquinoid, 6-(propylpibenyl)-butylcarhythyl ether, etc., and antioxidant and buty!rehydroky/aninol, dibutylhydrokinotoluene. , tofuferol, γ-oryzanol, etc., and at least one or more insecticides such as common name Arethri/and its geometric and/or optical isomers, phenovalerate, permethrin, phenothrin, D-resmethrin, DL-resmethrin, etc. Pyrethroids, α-naphthylthiourea, nokurohequinoid, etc. for rodent extermination and Hiro 11,
As a fungicide, salicylic acid, pchlorom-kylnol, 2-(=1'-thiazoyl)benozimidazole, etc. are used, and as a fungicide, α-bromononamisoqualdehyde,
Examples include, but are not limited to, N-methyl-N-phenylN'.(fluorodichloromethyl)thiosulfamide and the like.
特にピレスロイド系化合物を配合すると殺ダニり１里は
一層向上し、ｔＴＪ垂り１１里を示す。この場合、ピレ
スロイド系化合物１に対して″に口り酸へノノル０５以
上、＃ｌＩＬ＜！ｌｌツノ上合−４るのかよし＋一
本発明殺ダニ組成物は液剤、乳剤いずれにし使用し得る
が特に好ましくはアエブールで、５５る。アエゾールに
することにより、汚染性成分の配合を極力少なくする二
とができる。アエゾール用噴霧削としてはフロ７、ジメ
チルエーテル、液化石油ガス等を例示しうる。中でも、
ジメチルエーテル、液化石油ガスが好ましい。原液に対
する噴霧剤の配合割合は、通常１ｍ部で前者１０〜３５
Ｑに対し後者２３０〜２０、好ましくは前者７０〜１７
０に対しｉＵδ１００〜６０配合さシする。In particular, when a pyrethroid compound is added, the acaricidal rate of 1 ri is further improved, and the tTJ drop rate is 11 ri. In this case, the miticide composition of the present invention can be used in the form of either a liquid or an emulsion. Particularly preferred is Aeboul, which has a 55% rating. By making it into an aerosol, the amount of contaminating components can be minimized. Examples of aerosol sprays include Flo 7, dimethyl ether, and liquefied petroleum gas. Among them,
Dimethyl ether and liquefied petroleum gas are preferred. The mixing ratio of the spray agent to the stock solution is usually 10 to 35 parts per 1 m of the former.
The latter 230-20 for Q, preferably the former 70-17
0, iUδ100-60 is blended.
かくして卵１製される各種影響を有する本発明のダニ防
除組成物は、その使用゛に当り防除効果を要求されろダ
ニの棲Ｑ１区域例えば一般家庭、行物含庫、食堂の厨房
、家具、押入れ、玄関、洗面所等に噴霧により、また動
物体自体に噴霧等により通用できる。Thus, the mite control composition of the present invention, which has various effects, can be used in areas where mites live, such as general homes, storage areas, cafeteria kitchens, furniture, etc. It can be applied to closets, entrances, washrooms, etc. by spraying, or by spraying onto the animal itself.
発明の効果
本発明段ダニ削は、長期にわ、ｔっで浸透拡散効謁に１
１１ら極めて宝Ｊ′Ｌｆこ段ダニク１４里を１１続する
。Effects of the invention The step mite removal of the present invention has a long-term penetration and diffusion effect.
11 and the very treasure J'Lf This stage Danik 14 ri is continued 11 times.
本発明の段タニクＩノ果は、ケーガコ＋ダニ、コナヒヨ
ウヒダニ、コふチリダニ、ヤケチリダニ、チリニクダニ
、ツソガムノ、ヒヨウヒダニ、コナダニ、ヒゼンダニ、
ニキヒダニ、イエダニ、ワクモ、トリサノダニ、ツメダ
ニ、ノラミダニ、ハリクチダニ、ナコリグニ、ササラダ
ニ、ニクダニに対し強力ｔらのてめろ。特にケナガコナ
ダニ、コナヒクウヒｙ二、フナチリダニ、ヤケチリダニ
、チリニクダニ等に対する効果は本発明で初めて見出１
こされｆこ乙のである。The fruits of the present invention include Kigako + mites, Kona erectus mites, Kofutida mites, Burnt erect mites, Chiriniku mites, Tsusogamuno, Dermatophagoides nigricans, Dermatophagoides nigricans, Dermatophagoides nigricans,
Powerful against dust mites, house dust mites, red mites, bird mites, claw mites, wild mites, yellow mites, white mites, sasara mites, and mites. In particular, the effect on woolly dust mites, brown dust mites, brown dust mites, yellow dust mites, dust mites, etc. was discovered for the first time in the present invention1.
This is what happened.
従って、本発明のダニ防除剤はこれを家庭内のタタミ、
カーペット等や食物収納庫および人体、動物体、植物体
に適用することによって、これ等の場所て棲９．又は寄
生している種々のダニに対して確実な殺ダニ効果を発揮
し、ひいては、動物体、）ダニによろ刺咬、吠面、アレ
ルギー性疾患をも的確に回避できる乙のである。Therefore, the tick control agent of the present invention can prevent ticks in the home.
By applying it to carpets, food storage areas, and human, animal, and plant bodies, it can be used in these places.9. It also exhibits a reliable acaricidal effect against various parasitic mites, and can also accurately prevent animal bodies, mite bites, barking, and allergic diseases.
Ｘ光測１〜５
下記表−Ｉに記載の配合割合で安８？５酸ベノノル、ケ
ロノノを温合溶解する。これをエアゾール容器に充４１
シ、バルブ部分を取付けると同時にガスを充填して本発
明殺ダニエアゾールをｉすｆ二。畳床に液を注入４−７
１時は、ホタノＮｉ１口に長い′Ｐｃ瑞穴あきステンレ
スバイブ（先端口径０ 、５ ＭＩ＋）を取り付け、畳
床に注入しｊ−０
畳床に製品として５πＱを注入し、２６１時間後に安い
、呑酸ヘノノルのＩｆＬ散状態を常法によりガスクロマ
トグラフィーによって確認した。X-photometry 1 to 5 Benonol and keronono ammonium 8-5 acids are heated and dissolved in the proportions shown in Table I below. Fill this into an aerosol container41
At the same time as installing the valve part, fill it with gas and use the mite-killing aerosol of the present invention. Inject liquid into the tatami floor 4-7
At 1 o'clock, a long 'Pc perforated stainless steel vibrator (tip diameter 0, 5 MI+) was attached to the Hotano Ni 1 mouth, and injected into the tatami floor. The IfL dispersion state of henonolanosulfate was confirmed by gas chromatography using a conventional method.
？２−１
確之の結果、明らかにケロ／ンにより安い谷酸ベノノル
が広範囲に拡散したことを確認した。? 2-1 As a result of the investigation, it was confirmed that benonol, a cheap acid, was clearly diffused over a wide area by kerosene.
Ｘ皇！１６〜１２
ポタノ噴口に長いステンレスパイプを付けた本発明殺ダ
ニエアゾールをろ紙に富貴させ、＋ＸＱ噴射して５分後
に拡散した安、０．８酸ベンジルの状態を確認した。結
果を表−２に示す。Emperor X! 16-12 A filter paper was enriched with the acaricidal aerosol of the present invention using a long stainless steel pipe attached to the potano nozzle, +XQ was sprayed, and 5 minutes later, the state of the diffused benzyl 0.8 acid was confirmed. The results are shown in Table-2.
表−２
ケロノンと混ｒ７することにより、明らかに安巳香酸ヘ
ノノルの拡散かよりｒｊろ。Table 2 By mixing r7 with keronone, the diffusion of henonol ammizoate was clearly increased.
実施例１３〜３７
ピレスロイド系化合物および安り、香酸ヘンノルの所定
虫をノルマルノ（ラフイン１こ溶解し、下工己の表−３
に示したようにそれぞれクラフト紙（５Ｃ！＋ｘ５ｃｍ
）に処理し、風乾してノルマルＩくラフイノを除去し、
それぞれのンート形筈の本発明段グ二剤を得た。Examples 13 to 37 Specified insects of pyrethroid compounds and alcoholic acid were dissolved in 1 portion of roughin and prepared in Table 3 below.
As shown in kraft paper (5C!+x5cm)
), air-dried to remove the normal I.
The second agent of the present invention, which was supposed to be in the form of a tube, was obtained.
ノ、３No, 3
Claims (1)
有する化合物を含有する殺ダニ剤。 ２、エアゾール用である第１項記載の殺ダニ剤。 ３、安息香酸ベンジル１重量部に対し脂肪族炭化水素を
主鎖として有する化合物を５００〜２０００重量部配合
した第１項記載の殺ダニ剤。 ４、脂肪族系炭化水素を主鎖として有する化合物がパラ
フィン系炭化水素である第１項記載の殺ダニ剤。 ５、ピレスロイド系殺虫剤をさらに加えた第１項記載の
殺ダニ剤。[Scope of Claims] 1. A miticide containing a compound having benzyl benzoate and an aliphatic hydrocarbon as a main chain. 2. The acaricide according to item 1, which is for aerosol use. 3. The acaricide according to item 1, wherein 500 to 2000 parts by weight of a compound having an aliphatic hydrocarbon as a main chain is blended with 1 part by weight of benzyl benzoate. 4. The acaricide according to item 1, wherein the compound having an aliphatic hydrocarbon as a main chain is a paraffinic hydrocarbon. 5. The acaricide according to item 1, further comprising a pyrethroid insecticide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59213764A JPH0621041B2 (en) | 1984-10-11 | 1984-10-11 | Acaricide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59213764A JPH0621041B2 (en) | 1984-10-11 | 1984-10-11 | Acaricide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6191103A true JPS6191103A (en) | 1986-05-09 |
| JPH0621041B2 JPH0621041B2 (en) | 1994-03-23 |
Family
ID=16644636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59213764A Expired - Lifetime JPH0621041B2 (en) | 1984-10-11 | 1984-10-11 | Acaricide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0621041B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0583774A1 (en) * | 1992-08-18 | 1994-02-23 | The State Of Israel-Ministry Of Agriculture | An arthropod control composition for plant protection |
| US5916917A (en) * | 1997-02-20 | 1999-06-29 | Reckitt & Colman Inc. | Dust mite control compositions containing benzyl benzoate and alcohol |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5170826A (en) * | 1974-12-16 | 1976-06-18 | Taisho Pharmaceutical Co Ltd | Eazoorusatsuchuzai |
| JPS5325284A (en) * | 1976-08-19 | 1978-03-08 | Daikin Ind Ltd | Aerosol composition |
| JPS5331583A (en) * | 1976-09-06 | 1978-03-24 | Daikin Ind Ltd | Aerosol composition |
| JPS55122702A (en) * | 1979-02-07 | 1980-09-20 | Morgan Ward Critchley Co Ltd | Miticidal composition |
| JPS5973502A (en) * | 1982-10-21 | 1984-04-25 | Fumakiraa Kk | Aerosol insecticide |
| JPS59167501A (en) * | 1983-03-14 | 1984-09-21 | Dainippon Jiyochiyuugiku Kk | Aerosol injection agent |
| JPS60142906A (en) * | 1983-12-28 | 1985-07-29 | Katsuta Yoshio | Acaricide for indoor use |
| JPS60163805A (en) * | 1984-02-04 | 1985-08-26 | Katsuta Yoshio | Acaricide for indoor use |
-
1984
- 1984-10-11 JP JP59213764A patent/JPH0621041B2/en not_active Expired - Lifetime
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5170826A (en) * | 1974-12-16 | 1976-06-18 | Taisho Pharmaceutical Co Ltd | Eazoorusatsuchuzai |
| JPS5325284A (en) * | 1976-08-19 | 1978-03-08 | Daikin Ind Ltd | Aerosol composition |
| JPS5331583A (en) * | 1976-09-06 | 1978-03-24 | Daikin Ind Ltd | Aerosol composition |
| JPS55122702A (en) * | 1979-02-07 | 1980-09-20 | Morgan Ward Critchley Co Ltd | Miticidal composition |
| JPS5973502A (en) * | 1982-10-21 | 1984-04-25 | Fumakiraa Kk | Aerosol insecticide |
| JPS59167501A (en) * | 1983-03-14 | 1984-09-21 | Dainippon Jiyochiyuugiku Kk | Aerosol injection agent |
| JPS60142906A (en) * | 1983-12-28 | 1985-07-29 | Katsuta Yoshio | Acaricide for indoor use |
| JPS60163805A (en) * | 1984-02-04 | 1985-08-26 | Katsuta Yoshio | Acaricide for indoor use |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0583774A1 (en) * | 1992-08-18 | 1994-02-23 | The State Of Israel-Ministry Of Agriculture | An arthropod control composition for plant protection |
| US5916917A (en) * | 1997-02-20 | 1999-06-29 | Reckitt & Colman Inc. | Dust mite control compositions containing benzyl benzoate and alcohol |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0621041B2 (en) | 1994-03-23 |
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