JPS6150117B2 - - Google Patents

Info

Publication number

JPS6150117B2

JPS6150117B2 JP14676678A JP14676678A JPS6150117B2 JP S6150117 B2 JPS6150117 B2 JP S6150117B2 JP 14676678 A JP14676678 A JP 14676678A JP 14676678 A JP14676678 A JP 14676678A JP S6150117 B2 JPS6150117 B2 JP S6150117B2

Authority

JP

Japan

Prior art keywords

phosphor

zns

present

blue

amount

Prior art date

1978-11-28

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 103
• 229910052984 zinc sulfide Inorganic materials 0.000 claims description 69
• 230000004913 activation Effects 0.000 claims description 16
• 239000011159 matrix material Substances 0.000 claims description 13
• 229910052709 silver Inorganic materials 0.000 claims description 7
• 229910052693 Europium Inorganic materials 0.000 claims description 6
• 239000004332 silver Substances 0.000 claims description 6
• OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 5
• -1 silver-activated zinc sulfide phosphor Chemical class 0.000 claims description 5
• 239000005083 Zinc sulfide Substances 0.000 claims description 3
• DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 3
• BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 3
• 239000002994 raw material Substances 0.000 description 10
• 238000010304 firing Methods 0.000 description 7
• FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
• 150000001875 compounds Chemical class 0.000 description 5
• 239000000203 mixture Substances 0.000 description 5
• 239000011593 sulfur Substances 0.000 description 5
• 229910052717 sulfur Inorganic materials 0.000 description 5
• TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
• 239000012190 activator Substances 0.000 description 4
• 239000000460 chlorine Substances 0.000 description 4
• 238000010894 electron beam technology Methods 0.000 description 4
• 239000002245 particle Substances 0.000 description 4
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
• 239000003795 chemical substances by application Substances 0.000 description 3
• 229910052801 chlorine Inorganic materials 0.000 description 3
• 230000005284 excitation Effects 0.000 description 3
• 229910052736 halogen Inorganic materials 0.000 description 3
• 150000002367 halogens Chemical class 0.000 description 3
• 238000004519 manufacturing process Methods 0.000 description 3
• 239000011780 sodium chloride Substances 0.000 description 3
• 101710134784 Agnoprotein Proteins 0.000 description 2
• 229910052782 aluminium Inorganic materials 0.000 description 2
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
• 239000001055 blue pigment Substances 0.000 description 2
• 229910001629 magnesium chloride Inorganic materials 0.000 description 2
• 239000010453 quartz Substances 0.000 description 2
• VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
• SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
• 229910001508 alkali metal halide Inorganic materials 0.000 description 1
• 150000008045 alkali metal halides Chemical class 0.000 description 1
• 229910001615 alkaline earth metal halide Inorganic materials 0.000 description 1
• IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 description 1
• 239000011248 coating agent Substances 0.000 description 1
• 238000000576 coating method Methods 0.000 description 1
• 230000007423 decrease Effects 0.000 description 1
• CRHLEZORXKQUEI-UHFFFAOYSA-N dialuminum;cobalt(2+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Co+2].[Co+2] CRHLEZORXKQUEI-UHFFFAOYSA-N 0.000 description 1
• 230000000694 effects Effects 0.000 description 1
• 229910001940 europium oxide Inorganic materials 0.000 description 1
• AEBZCFFCDTZXHP-UHFFFAOYSA-N europium(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Eu+3].[Eu+3] AEBZCFFCDTZXHP-UHFFFAOYSA-N 0.000 description 1
• 238000002474 experimental method Methods 0.000 description 1
• 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
• 238000004020 luminiscence type Methods 0.000 description 1
• 239000000463 material Substances 0.000 description 1
• 238000000034 method Methods 0.000 description 1
• 239000000843 powder Substances 0.000 description 1
• 229910001961 silver nitrate Inorganic materials 0.000 description 1
• 229910052950 sphalerite Inorganic materials 0.000 description 1