JPS6131856B2 - - Google Patents
Info
- Publication number
- JPS6131856B2 JPS6131856B2 JP12499178A JP12499178A JPS6131856B2 JP S6131856 B2 JPS6131856 B2 JP S6131856B2 JP 12499178 A JP12499178 A JP 12499178A JP 12499178 A JP12499178 A JP 12499178A JP S6131856 B2 JPS6131856 B2 JP S6131856B2
- Authority
- JP
- Japan
- Prior art keywords
- mordant
- dye
- poly
- chloride
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011347 resin Substances 0.000 claims description 60
- 229920005989 resin Polymers 0.000 claims description 60
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 42
- 239000000203 mixture Substances 0.000 claims description 41
- 125000000129 anionic group Chemical group 0.000 claims description 16
- 125000002091 cationic group Chemical group 0.000 claims description 13
- 230000000717 retained effect Effects 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 77
- -1 chloride Chemical class 0.000 description 29
- 239000000243 solution Substances 0.000 description 29
- 238000012546 transfer Methods 0.000 description 29
- 238000000576 coating method Methods 0.000 description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000011248 coating agent Substances 0.000 description 23
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 18
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- IOLCXVTUBQKXJR-UHFFFAOYSA-M potassium bromide Chemical compound [K+].[Br-] IOLCXVTUBQKXJR-UHFFFAOYSA-M 0.000 description 16
- 238000000034 method Methods 0.000 description 13
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 12
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 10
- 239000002253 acid Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 239000000178 monomer Substances 0.000 description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 108010010803 Gelatin Proteins 0.000 description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 8
- 125000000217 alkyl group Chemical group 0.000 description 8
- 229920000159 gelatin Polymers 0.000 description 8
- 239000008273 gelatin Substances 0.000 description 8
- 235000019322 gelatine Nutrition 0.000 description 8
- 235000011852 gelatine desserts Nutrition 0.000 description 8
- 239000011230 binding agent Substances 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical group C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 229910052739 hydrogen Inorganic materials 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 5
- 125000004429 atom Chemical group 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 239000004848 polyfunctional curative Substances 0.000 description 5
- 239000001103 potassium chloride Substances 0.000 description 5
- 235000011164 potassium chloride Nutrition 0.000 description 5
- 238000002791 soaking Methods 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- KAMCBFNNGGVPPW-UHFFFAOYSA-N 1-(ethenylsulfonylmethoxymethylsulfonyl)ethene Chemical compound C=CS(=O)(=O)COCS(=O)(=O)C=C KAMCBFNNGGVPPW-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 4
- 230000002401 inhibitory effect Effects 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 125000003710 aryl alkyl group Chemical group 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000007859 condensation product Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000012954 diazonium Substances 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 125000000623 heterocyclic group Chemical group 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 238000000016 photochemical curing Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 229920003082 Povidone K 90 Polymers 0.000 description 2
- ABBQHOQBGMUPJH-UHFFFAOYSA-M Sodium salicylate Chemical compound [Na+].OC1=CC=CC=C1C([O-])=O ABBQHOQBGMUPJH-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical class C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RZUBARUFLYGOGC-MTHOTQAESA-L acid fuchsin Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=C(N)C(C)=CC(C(=C\2C=C(C(=[NH2+])C=C/2)S([O-])(=O)=O)\C=2C=C(C(N)=CC=2)S([O-])(=O)=O)=C1 RZUBARUFLYGOGC-MTHOTQAESA-L 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 125000004397 aminosulfonyl group Chemical group NS(=O)(=O)* 0.000 description 2
- 125000000732 arylene group Chemical group 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000295 complement effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- UMBBGOALZMAJSF-UHFFFAOYSA-N n-benzylethenamine;hydrochloride Chemical compound [Cl-].C=C[NH2+]CC1=CC=CC=C1 UMBBGOALZMAJSF-UHFFFAOYSA-N 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229910000160 potassium phosphate Inorganic materials 0.000 description 2
- 235000011009 potassium phosphates Nutrition 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 2
- 239000012266 salt solution Substances 0.000 description 2
- 229960004025 sodium salicylate Drugs 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000001043 yellow dye Substances 0.000 description 2
- QLAJNZSPVITUCQ-UHFFFAOYSA-N 1,3,2-dioxathietane 2,2-dioxide Chemical group O=S1(=O)OCO1 QLAJNZSPVITUCQ-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- KSOWMDCLEHRQPH-UHFFFAOYSA-N 4-diazocyclohexa-1,5-dien-1-amine Chemical compound NC1=CCC(=[N+]=[N-])C=C1 KSOWMDCLEHRQPH-UHFFFAOYSA-N 0.000 description 1
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical group [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229910006074 SO2NH2 Inorganic materials 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- OPBHFMXWRRFKIY-UHFFFAOYSA-N [Cl-].CC(=CC(=O)NCCC[NH3+])C Chemical compound [Cl-].CC(=CC(=O)NCCC[NH3+])C OPBHFMXWRRFKIY-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical class 0.000 description 1
- 125000000304 alkynyl group Chemical group 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 229940092714 benzenesulfonic acid Drugs 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 125000003917 carbamoyl group Chemical group [H]N([H])C(*)=O 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 125000005521 carbonamide group Chemical group 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 150000008049 diazo compounds Chemical class 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-O diazynium Chemical group [NH+]#N IJGRMHOSHXDMSA-UHFFFAOYSA-O 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 1
- 238000007606 doctor blade method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000006575 electron-withdrawing group Chemical group 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229940098779 methanesulfonic acid Drugs 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- KVBGVZZKJNLNJU-UHFFFAOYSA-N naphthalene-2-sulfonic acid Chemical compound C1=CC=CC2=CC(S(=O)(=O)O)=CC=C21 KVBGVZZKJNLNJU-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- 125000004437 phosphorous atom Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- ZNNZYHKDIALBAK-UHFFFAOYSA-M potassium thiocyanate Chemical compound [K+].[S-]C#N ZNNZYHKDIALBAK-UHFFFAOYSA-M 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229920003176 water-insoluble polymer Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F3/00—Colour separation; Correction of tonal value
- G03F3/10—Checking the colour or tonal value of separation negatives or positives
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/016—Diazonium salts or compounds
- G03F7/021—Macromolecular diazonium compounds; Macromolecular additives, e.g. binders
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Description
æ¬çºæã¯ãäŸãã°ã«ã©ãŒãã«ãŒãã€ã³ã°
ïŒcolorâproofingïŒçšã®é£ç¶é調è²çŽ ç»åãã€ã
ãã®ã«æçšãªå 硬åæ§ç»å圢æçµæç©åã³èŠçŽ ã«
é¢ããã åŸæ¥ã®ã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ã¯ãã«ããªã³
ç³»è²çŽ ãšã§é£ç¶é調ç»åã圢æããã¢ããªã³ç³»åª
æå€ãäžããããã«ããžã¢ãŸæš¹èãäžæŽ»æ§éåäœ
ãã€ã³ããŒãšã®æ··åç©ã®åœ¢ã§å¡åžç©äžã«å«ãŸããŠ
ããããšããã»ãã¯ã°ããã³ïŒH.McGuckinïŒã®
ã«ããç¹èš±ç¬¬998278å·ã«ã¯ããã®äŸã瀺ãããŠã
ããããããã·ã»ã«ããŒãºãéåäœãã€ã³ããŒãš
ããŠçšããããŠãããããããªããããã®ç³»ã§ã¯
ãã®å¡åžç©äžã®ãã€ã³ããŒã¯é²å ãããŠããªãéš
åãå®å šãªå±€ãšããŠåç¶ã®ãŸãŸã§ãã€ãããã®ã
ãšã¯å 硬åæ§ãžã¢ãŸæš¹èãçšããé²å ãããªãã€
ãéšåã®å¡åžç©ããŠãªã·ãŠïŒwashïŒå·¥çšã§å šéš
åãé€ãããåŸæ¥ã®ç³»ãšã¯ç°ãªããã®ã§ãããåŸ
è ã®ç³»ãããŠãªã·ãŠã»ãªããç³»ïŒwashâoff
systemïŒãšåŒã³ãäžèšã®ã«ããç¹èš±ã«èšèŒãã
ãŠãããããªãŠãªã·ãŠã»ã¢ãŠãç³»ïŒwashâout
systemïŒãšã¯åºå¥ããŠããã åŸæ¥ããŠãªã·ãŠã»ãªã ãžã¢ãŸæš¹èã¯å€ãã®ç
ç±ããã«ã©ãŒãã«ãŒãã€ã³ã°ç³»ã«ãããæçšæ§ã
éãããŠããããããã®çç±ã®ãã¡ã®ç¬¬ïŒã®çç±
ã¯ããã®ãããªæš¹èã®èªåã«ããã¹ããŒããè¥å¹²
é ããšããããšã§ããã第ïŒã®çç±ã¯ãŠãªã·ãŠã»
ãªãç³»ã§ã®ãã®æš¹èããåŸãããã³ã³ãã©ã¹ãã
é£ç¶é調ç»åãã€ããã«ã¯ãããããã»ã©ã®ãã®
ã§ãããšããããšã§ããã1967幎ïŒæå·ã®ã°ã©ã
ã€ãã¯ã»ã¢ãŒãã»ãã³ã¹ãªãŒïŒGraphic Arts
MonthlyïŒã«ã¯æ¬¡ã®ããšãèšèŒãããŠããããçŸ
åšã§ã¯âŠâŠâŠâŠé£ç¶é調å解ãã¬ãè©Šéšããæºè¶³
ãªæ¹æ³ã¯ãªããçŸåšåŸãããã«ã©ãŒãã€ã«ã ã¯ã
ã®äœ¿çšã«ã¯ããŸãã«ãã³ã³ãã©ã¹ããé«ãããâŠ
âŠâŠâŠããšãããã¢ããªã³ç³»è²çŽ ã®ç³»ãéçºãã
ããªãã°ãè²çŽ ã®é©çšç¯å²ã¯ä»ããããã€ãšåºã
ãªãããŸãä»ã®æå æ§ææãäŸãã°äžè¿°ããã«ã
ãç¹èš±ã«èšèŒãããŠãããããªãžã¢ãŸå¡©ãã¢ããª
ã³ç³»è²çŽ ãšå ±ã«çšããããŠãããããžã¢ãŸæš¹èªã¯
ã¹ããŒããé«ããããžã¢ãŸå¡©ããã奜ãŸããã æ¬çºæã®ããããç¹åŸŽã¯ãŠãªã·ãŠã»ãªãæå æ§
ãžã¢ãŸæš¹èçµæç©åã³ãããå«æãããã«ãŒãã€
ã³ã°èŠçŽ ã«ããã æŽã«è©³ããã¯ãå 硬åæ§ç©è³ªãšããŠæå æ§ãžã¢
ãŸæš¹èãã«ããªã³ç³»éåäœåªæå€ãšäžç·ã«æ··åç©
ã®ç¶æ ã§å«ãŸããŠãããŠãªã·ãŠã»ãªãæå æ§çµæ
ç©ã®æäŸã«ãããããã«ãããŠäžèšåªæå€ã¯äžèš
æš¹èãšäœµçšããããã®ã§ããïŒçžå®¹æ§ãããïŒã
ããããã®çµæç©ã®å ã«ãã硬åãããéšåã«ä¿
æãããããšãã§ãããã®ã§ããã ãã®ãããªçµæç©ãçšããŠè²çŽ ç»åã圢æãã
ã«ã¯ããã®çµæç©ã®å¡åžå±€ãæ åé²å ãããã®å±€
ãæ°Žã§ãããã§çŸåããã¢ããªã³ç³»è²çŽ ããã®å±€
ã«å ããããã§ãã®è²çŽ ãåªæå€ã«ããäžååã
ãŠè²çŽ ç»åã«ããã°ããããã®è²çŽ ç»åã¯ãæŽ
ã«ããã®çµæç©ã®åªæå€ããã匷ãã«ããªã³ç³»åª
æå€ãå«ãååå±€ã«è»¢åããããšãã§ããããã®
転åã¯ããçš®ã®å¡©ã®æº¶æ¶²åã¯ã¢ã«ã³ãŒã«ãšæ°Žã®æ··
å溶液ã®ååšäžã§ãäžèšè²çŽ ãçµæç©ã®åªæå€ã
ãååå±€äžã®åªæå€ã«ç§»è¡ãããã®ã«ã¡ããã©å
åãªæéäžèšååå±€ãçµæç©ã®å±€ã«æ¥è§Šãããã
ãšã«ããè¡ãªãããã æ¬çºæã¯é£ç¶é調åçç»åãã€ããã®ã«æçšãª
çµæç©åã³ãã«ãŒãã€ã³ã°èŠçŽ ã«éå®ããããã®
ã§ã¯ãªãããæ¬çºæã¯ãã®ç®çã®ããã«ç¹ã«æçš
ã§ãããäŸãã°ãé£ç¶é調ç»å圢æã¯åŸã§åŒ·èª¿ã
ãã奜ãŸããå ·äœäŸã®ãã¬ã»ãã¬ã¹ã«ã©ãŒãã«ãŒ
ãã€ã³ã°èŠçŽ ïŒpreâpress colorâproorfing
elementïŒã®åéã«æçšã§ãããããŸãæ¬çºæã®
çµæç©ãšèŠçŽ ã®ä»ã®å¯èœãªäœ¿çšããªãã¡ãã°ã©ã
ã€ãã¯ã¢ãŒãã»ããªã³ãã»ãã€ã«ã ããã€ã¯ãã
ã¢ã€ã«ã»ããªã³ãã»ãã€ã«ã ããããªã»ãã¹ã¯çš
äžéäœåã¯ãªãªãŒã¹ã»ããªã³ãã«ãéèŠã§ããã
ãããå¯èœã«ããæ¬çºæã®çµæç©ã¯ãžã¢ãŸæš¹èãš
ãã®æš¹èãšçžå®¹æ§ã®ã«ããªã³ç³»éåäœåªæå€ãã
ãªãããã®çµæç©ã¯ã¢ããªã³ç³»è²çŽ ãå ã«ãã硬
åããéšåã«åŒãã€ãããã«ä¿æããããšãã§ã
ãæ§è³ªãæããŠãããé©åœãªç»å圢ææ§ãã«ãŒã
ã€ã³ã°èŠçŽ ã¯æ¯æäœäžã«ãã®æå æ§çµæç©ãå¡åž
ããããã®ãããªãã ãã®çµæç©ã¯ãå 硬åæ§ãžã¢ãŸæš¹èå«æãŠãªã·
ãŠã»ãªãçµæç©ãé£ç¶é調ç»å圢æã«äžé©ã§ãã
ãšèããŠãããã®ã以äžã«èšèŒãããã¢ããªã³ç³»
è²çŽ ã®éåäœåªæå€ãå ããããšã«ããéåžžã«æ
çšãªãã®ã«ããããšãã§ãããšããçºèŠã«åºã¥ã
ãã®ã§ããã 氎溶æ§ã®æå æ§ãžã¢ãŸæš¹èãªãã©ã®ãããªãã®
ã§ãçšããããšãã§ãããç¹ã«æå¹ãªãã®ã¯æ¬¡åŒ
ã§è¡šããããç¹°è¿åäœãæããäœååéã®æš¹èã§
ããïŒ åŒäžã®ïŒªã¯J1åã¯J2ã§ä»¥äžã«å®çŸ©ãããã
ã¯ã¯ãã©ã€ãçã®ã¢ããªã³ã§ãããïœã¯ïŒåã¯ïŒ
ã§ãããæ®éãããã¯æŽ»æ§ãªã«ã«ããã«ååç©ã
äŸãã°ãã«ã ã¢ã«ãããåã¯ãã©ãã«ã ã¢ã«ãã
ãã次åŒã§ç€ºããããžã¢ãŸååç©ãšçž®åãããŠã€
ããããïŒ åŒïŒïŒåã¯ïŒïŒã®Xâ²ã¯ãã©ã€ãããã¹ã
ãšãŒããã¹ã«ããšãŒããã«ãªããã¬ãŒãçã®ã¢ã
ãªã³ã§ããïŒ åŒïŒïŒåã¯ïŒïŒã®ïŒã¯ãžã¢ãŸããŠã åºãå®
å®ã«ããå ¬ç¥ã®ïŒäŸ¡åã¯ïŒäŸ¡ã®éå±ãäŸãã°ã«ã
ããŠã ãäºéããã¹ãã¹ãç çŽ ãã¢ã³ãã¢ã³ãã¹
ãºãéãçœéãæ°Žéã§ããïŒ åŒïŒïŒåã¯ïŒïŒã®ïŒžã¯ãã©ã€ãåã¯ã¹ã«
ããšãŒãã®ã¢ããªã³åã¯ã¢ããªã³ã®æ··åç©ã§ã
ãïŒ J2ã¯æš¹èãïœâãžã¢ãŸãžããšãã«ã¢ãã³å¡©ã®ã¢
ã«ãããçž®åçæç©ã®å Žåã¯ãããšãã«åã¯çœ®æ
ããšãã«ã§ããããŸãJ1ã¯æ°ŽçŽ ã§ããã ç¹ã«å¥œãŸãããžã¢ãŸæš¹èã¯ïŒâã¢ããâïŒã»
1â²âãžããšãã«ã¢ãã³ã®ãžã¢ãŸããŠã å¡©ãäŸãã°
ïŒã»1â²âãžããšãã«ã¢ãã³âïŒâãžã¢ãŸããŠã ã
ã©ã€ãåã¯ïŒã»1â²âãžããšãã«ã¢ãã³âïŒâãžã¢
ãŸããŠã ãã¹ããšãŒãããé žäžã§ãã¢ã«ãããäŸ
ãã°ãã©ãã«ã ã¢ã«ãããåã¯ãã«ã ã¢ã«ããã
ãšçž®åãããã€ãã§è€éå±å¡©ãäŸãã°ã¯ãããžã³
ã±ãŒãåã¯ãã«ãªããã¬ãŒãã«å€ããé žçž®åçæ
ç©ã§ããããã®ãããªæš¹èã¯åŸæ¥ããç¥ãããŠã
ãããã®è£œé æ³ãæŽã«è©³ããããšã¯äŸãã°ã³ã¶ãŒ
ã«ãïŒKosarïŒã®æå æ§ç³»ïŒLightâSensitive
SystemsïŒ323â324é ïŒ1965ïŒãç±³åœç¹èš±ç¬¬
323584å·ã«èšèŒãããŠããã æå æ§ãžã¢ãŸæš¹èã«å ãåœãŠããšãã¬äœçšã®æš¹
èåãã§ãããããªãã¡ãæ åçã«é²å ãããã
ã®ãããªæš¹èã®å¡åžç©ã¯æ¶æ©ããŠæ°Žã«æº¶ããªãã
ãªããŒãã€ããããã®å¡åžç©ã®é²å ãããªãã€ã
éšåã¯å¥œãŸããã¯ãã®ãŸãŸæ°Žã«æº¶ããç¶æ ã«ãšã©
ãŸãããã®ããé©åœãªæº¶å€ã§åŠçãããšæŽé€
ïŒwash offïŒãããã ãã®å¡åžç©ã®ä¿åæ§ãããããããã«ãéåžžé ž
æ§ã®ä¿åå€ãäžèšã®ãžã¢ãŸæš¹èã«å ãããããã
ã®ç®çã®ããã«åŸæ¥ããçšããããŠããé žãšããŠ
ã¯ãªã³é žãã¯ãšã³é žãïœâãã«ãšã³ã¹ã«ãã³é žã
ã¡ã¿ã³ã¹ã«ãã³é žããã³ãŒã³ã¹ã«ãã³é žãåã³ã
ãã®çœ®æèªå°äœãïŒâããã¿ã¬ã³ã¹ã«ãã³é žçã
ããããŸãããããã®å¡åžç©ããã䜿çšããå Žå
ã¯ãã®ãããªé žå®å®åå€ãå ¥ããªããŠããããã
ãé žå®å®åå€ãçšããå Žåã¯ããã®éãçŽ0.1mg/
ïœm2ãšçŽ1.0mg/dm2ã®éã§å€ããããšãã§ããã ã«ããªã³ç³»éåäœåªæå€ã¯ãæ åçã«ç¡¬åãã
çµæç©ããã€ããããæ¬çºæã®èŠçŽ ãé©åœãªè²çŽ
溶液ã«æµžãããšãã«ã¢ããªã³ç³»è²çŽ ãåªæããäœ
çšãè¡ãªãã è²å解ãã¬ïŒãããéããŠçµæç©ã®é²å ãè¡ãª
ãããïŒã®è²ã«å¯ŸããŠè£è²ã®æžè²è²çŽ ãé©åœã«éž
ã¶ããšã«ãããã«ã©ãŒãã«ãŒãïŒcolorâdroofïŒ
ãïŒè²å解ããžãããªããªãŒãã¬ã€ïŒoverlayïŒ
ã®åœ¢ã§åŸãããšãã§ããããã®ããžã¯æ¬çºæã«åŸ
ã€ãŠã€ããããïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ãšïŒçš®
é¡ã®æžè²è²çŽ 溶液ããåŸãããããã®ããã«ããŠ
çããç»åã¯ãã®ã³ã³ãã©ã¹ããæ¯èŒçäœãã
ãããã®ãããªã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ã¯é£ç¶
é調ç»åã«çšããã®ã«ããããŠé©ããŠããããã
è©Šéšã®çµæã«ã©ãŒãã¬ã®ãã¡äžã€åã¯ãã以äžã
ä¿®æ£ããå¿ èŠãããå Žåã¯ä¿®æ£ããè²å解ãã¬ã
ã€ãããã®ãã¬ã®æ°ãããã«ãŒãã€ã³ã°èŠçŽ ãé²
å ããåŠçãã次ãã§ãã®æ§æç©ïŒã³ã³ããžã
ãïŒãåè©Šéšããããšãã§ããããã®ããå°å·ç
ãã€ãããå°å·æ©ã«çµã¿å®éã«åçãå°å·ããã
ã¬ã®æ£ãããè©Šéšããå¿ èŠããªãã ã«ããªã³ç³»éåäœåªæå€ã¯ãã®å šéšããžã¢ãŸæš¹
èãšæå¹ã«äœçšããããã§ã¯ãªããäŸãã°ãåªæ
å€ã®ãã¡ã®ãããã®ã¯ããããã溶åªäžã§æš¹èã
æ²æŸ±ãããçµæç©ãå¡åžããããšãã§ããªãã®ã§
æš¹èãšäžç·ã«çšããããšãã§ããªãïŒããªãã¡çž
容æ§ããªãïŒããŸããåªæå€ã®ãã¡ã®ä»ã®ãã®ã¯
å ã«ãã硬åãããžã¢ãŸæš¹èãæ¯æäœã«å¯ŸããŠæ
ããŠããéåžžã®æ¥çæ§ãç¢ãªãããããããã«æš¹
èã®å 硬åãé»å®³ãããåŸã€ãŠãéåäœåªæå€ã¯
æš¹èãšäžç·ã«çšããããšã®ã§ãããã®ïŒããªã
ã¡ãçžå®¹æ§ã®ãããã®ïŒã§ãªããã°ãªããªããã
ãªãã¡ããã®åªæå€ã¯ãžã¢ãŸæš¹èã®éåžžã®å 硬å
ãããæ©èœãé»å®³âãã®é»å®³ãå¡åžã«å¿ èŠãªæº¶æ¶²
æ§ãå 硬åããæš¹èã®æ¥çæ§ãå 硬åã®éçšèªäœ
åã¯å 硬åã«é¢ããæš¹èã®ä»ã®æ§è³ªã®ãã®ã§ãã
âãããã®ã§ãã€ãŠã¯ãªããªãã ãžã¢ãŸæš¹èãšãããšçžå®¹æ§ã®ããåªæå€ãšã®é
ã®çžäºäœçšã®ã¡ã«ããºã ã¯ãŸã å®å šã«ã¯å€ã€ãŠã
ãªããå æ¶æ©ããžã¢ãŸæš¹èå ã§èµ·ããããã«åªæ
å€ãæç²ãããã®ãããããšãéåäœåªæå€ãæš¹
èãšæ¶æ©ããã®ãæããã§ãªããã©ã®ãããªå Žå
ã§ãããã®åªæå€ã¯ãã¡ã«ããºã ãã©ãã§ããã
çµæç©ã®å ã«ãã硬åãããéšåã«ä¿æãããã
ãšãã§ãããšå ±ã«ããžã¢ãŸæš¹èãšäž¡ç«ããããã®
ã§ãªããã°ãªããªãã æçšãªéåäœã«ããªã³ç³»åªæå€ã¯åçš®ã®åçã
ã€ã«ã ãåççŽåã³ãã®ä»ã®çšéã«ãããŠãã§ã«
çšããããŠãããé»è·ã垯æããã«ããªã³åºãæ
ããç¹°è¿åéäœåäœãå«ãçµæç©ïŒäŸãã°ç±³åœç¹
蚱第3758445å·åã³å第3958995å·ã«èšèŒãããŠã
ãïŒã®ãããã€ãåªæå€ã®ãã¡ã®äžéšãå«ãŸã
ããå¿è«ãäžèšã®æ§è³ªãšååŠçµæãæãããã®ä»
ã®éåäœææã§ãä»ãŸã§åçåéã«ãããŠæçšãª
åççšåªæå€ãšããŠèªããããŠããªãã€ããã®ã
æ¬çºæã®ç¯å²å ã§çšããããšãã§ããã ç¹ã«æçšãªéåäœåªæå€çµæç©ã§æ¬çºæã«çšã
ãããšã®ã§ãããã®ã¯ããªããŒéã«æ¬¡åŒïŒïŒå
ã¯ïŒïŒã®åéäœåäœãæããç©è³ªã§ããïŒ ããã«ãããŠïŒ ã¯æ°ŽçŽ ååãïŒããïŒåã®ççŽ ååãæãã
ã¢ã«ãã«åºãå°ãªããšãïŒåã®è³éŠææ žãå«æã
ãåºäŸãã°ããšãã«ãããªã«ããããã«çã§ã
ãïŒ ïŒ±ã¯ååŠçµååã¯ã¢ã«ãã¬ã³ãã¢ãªãŒã¬ã³ãã¢
ãªãŒã¬ã³ã¢ã«ãã¬ã³ãã¢ã«ãã¬ã³ã¢ãªãŒã¬ã³ãã¢
ãªãŒã¬ã³ãã¹ã¢ã«ãã¬ã³ãåã¯âCOâR4âãâ
COâOR1âãââCOâR4âãâCOâNHR4âåº
ïŒäœããR4ã¯ïŒããïŒåã®ççŽ ååãæããã¢ã«
ãã¬ã³ã§ããïŒãããªäºäŸ¡ã®åºãè¡šããããŸãã¯
ããšãã«âNHâCOâCH2âïŒåªæå€ïŒâ36ãã
ã®åºïŒã§ããããã®ïŒ±ã¯ïŒ€ãšäžç·ã«ãªã€ãŠãã¢ã«
ãã¬ã³åºãïŒããïŒåã®ççŽ ååãæããâã¢
ã«ãã¬ã³çœ®æãã¬ã€ã³ã€ãããã€ããã®ã«å¿ èŠãª
ååãè¡šããïŒ Mâ²ã¯çªçŽ åã¯ãªã³ã®ååãè¡šããããã®
Mâ²ã¯R1ãR2åã³R3ãšäžç·ã«ãªã€ãŠç¬¬ïŒçŽã¢ã³
ã¢ããŠã åºåã¯ç¬¬ïŒçŽãã¹ããŠã åºã圢æãïŒ Xâ³ã¯ãã©ã€ãã€ãªã³ïŒäŸãã°ã¯ãã©ã€ãå
ã¯ãããã€ãïŒãã€ãã¬ãŒããã¡ãœã¹ã«ããšãŒ
ããïœâãã«ãšã³ã¹ã«ãããŒãçã®é žã¢ããªã³ã
è¡šããïŒ R1ãR2åã³R3ã¯ãåäžåã¯ç°çš®ã®ãã®ã§ã
ãããããã¯ããããïŒãã20åã®ççŽ ååãæ
ããã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«åã¯ã¢ã«ã«ãªãŒã«
åºãåã¯ïŒãã10åã®ççŽ ååãæããã¢ã«ã
ã«ãã¢ã«ã±ãã«åã¯ã¢ã«ããã«åºãè¡šããããŸã
Mâ²ãšäžç·ã«ãªã€ãŠãR1ãR2åã³R3ã¯æ¬¡åŒãæ
ããè€çŽ ç°ãã€ããã®ã«å¿ èŠãªååãè¡šããïŒ äœããã¯æ°ŽçŽ ååãïŒããïŒåã®ççŽ ååã
æããã¢ã«ã¢ã«ãã«ãè¥ããã¯ã¢ã«ãã«ã§ããã
å㯠äœããã¯äžé£œåè€çŽ ç°ãã€ããã®ã«å¿ èŠãªé
éå±ååã§ãããã¯äžèšã§å®çŸ©ãããã®ã§ã
ãã 奜ãŸããã¯ãR1ãR2ããã³R3ã¯ãMâ²ãšäžç·
ã«ãªã€ãŠããåºãè¡šããå Žåã¯ãïŒâã€ãããŸãŒ
ã«ãïŒâããªãžã³ãïŒâããªãžã³ãïŒâããªãž
ã³ãïŒâããªãžã³ãïŒâã¡ãã«âïŒâããªãžã³ã
ãããªãžã³ããããŒã«ããŸãã¯ïŒâã¢ã«ããªã³åº
ãå®æããããã«å¿ èŠãªååãè¡šããã ç¹ã«æçšãªæåªå€ã¯æ¬¡åŒã§è¡šããããç¹°è¿åäœ
ãæããåªæå€ã§ããïŒ ããã«ãããŠã R5ãR6åã³R7ã¯åäžåã¯ç°çš®ã®ãã®ã§ããã
ããããïŒãã20å奜ãŸããã¯ïŒã10åã®ççŽ å
åãæããã¢ã«ãã«ãã·ã¯ãã¢ã«ãã«åã¯çœ®æã¢
ã«ãã«åºåã¯ïŒã20ã®ççŽ ååãæããã¢ãªãŒ
ã«ãã¢ã«ã«ãªãŒã«è¥ããã¯ã¢ã«ã¢ã«ãã«åºäŸãã°
ããšãã«ããã³ãžã«ãïœâã¡ãã«ãã³ãžã«çãè¡š
ããããŸãR5ãšR6åã¯R5ãR6åã³R7ã¯ããš
äžç·ã«ãªã€ãŠã€ãããŸãŒã«ãïŒâããªãžã³ãïŒâ
ããªãžã³ãïŒâããªãžã³ãïŒâããªãžã³ãïŒâã¡
ãã«âïŒâããªãžã³ããããªãžã³ããããŒã«ãŸã
ã¯ïŒâã¢ã«ããªã³åºã®ãããªè€çŽ ç°ãã€ããã®ã«
å¿ èŠãªååãè¡šããïŒ ïŒžã¯ãã©ã€ãã€ãªã³ïŒããšãã°ãã¯ãã©ã€
ãããããã€ãïŒããã€ãã¬ãŒããã¡ããµã«ããš
ãŒããïœâãã«ãšã³ã¹ã«ãããŒãã®ãããªé žã¢ã
ãªã³ã§ããã æ¬çºæã«æçšã§ããããšãããã€ãéåäœåªæ
å€çµæç©ã¯ãã¢ããªããŒåã¯ã³ããªããŒã§ããã
ãªãã§ãã³ããªããŒã¯ç¹ã«æå¹ã§ããããšããã
ã€ãã代衚çãªã³ããªããŒäžã«ã¯ãäžèšã®ïŒïŒ
åã¯ïŒïŒåŒã§è¡šããããç¹°è¿åäœãæããæŽã«
éé»å®³æ§ã¢ãããŒã®æ®åºãããªãå¥ã®ç¹°è¿åäœã
75ééïŒ ãŸã§å«ãéåäœåªæå€çµæç©ãå«ãŸã
ãããªãããéé»å®³æ§ãã¢ãããŒåã¯ç¹°è¿åäœã¯
ã¢ããªã³ç³»è²çŽ ã®åªæãååŠçã«ãåã¯ç©ççã«
é»å®³ããªãååŠåäœãããããã®ãããªéé»å®³æ§
ç¹°è¿åäœãäžããã¢ãããŒã«ã¯ãèèªæåã³è³éŠ
æã®çåæ°ŽçŽ ãäŸãã°ãªã¬ãã€ã³ã眮æãªã¬ãã€
ã³ãã¹ãã¬ã³åã³çœ®æã¹ãã¬ã³ïŒã¢ã«ãã«ã¢ã¯ãª
ã¬ãŒãåã³ã¡ã¿ã¯ãªã¬ãŒãåã³ãããã®èªå°äœïŒ
åã³ãã®ãããªã¢ãããŒãšå®è³ªäžåäžã®å ¬ç¥ç©è³ª
ããããæŽã«ãããå¿ èŠãªãã°ãæ¬çºæã«æçšãª
éåäœæåªå€çµæç©ã¯ããããæ¶æ©ãããããšã
ã§ããã®ã§ãåã ã®éåäœã®éã¯ãžããã«ãã³ãŒ
ã³ããžã¡ã¿ã¯ãªã¬ãŒãã®ãããªïŒå®èœæ¶æ©æ§åºã
æŽã«åçš®ã®å ¬ç¥ã®ïŒå®èœæ¶æ©æ§åºã«ããæ¶æ©åã
ããã代衚çã«ã¯ããããã®ãããªïŒå®èœæ¶æ©æ§
åºãååšãããšããã°ããããã®åºã¯ããã®ãã
ãªæ¶æ©ã³ããªããŒãã€ããã®ã«çšããããã¢ãã
ãŒã®å ±éåå¯èœãªãã¬ã³ãã«ååšããã¢ãããŒã®
å šééã«åºã¥ããŠãæ¬çºæã®éåäœåªæå€çµæç©
äžã«ïŒééïŒ ãŸã§ã®ç¯å²ã奜ãŸããã¯0.1ããïŒ
ééïŒ å«ãŸãããæ¬çºæã«ãããŠåªæå€çµæç©ãš
ããŠæçšãªä»£è¡šçãªã³ããªããŒã¯(a) äžèšïŒïŒ
åã¯ïŒïŒåŒãæããç¹°è¿åäœã®ã¢ãããŒã25ã
ã99ééïŒ ã(b) éé»å®³ç¹°è¿åäœã®ã¢ãããŒãïŒ
ãã75ééïŒ åã³(c) ããååšãããšããã°ãïŒ
å®èœæ¶æ©æ§å€ãïŒãã10ééïŒ å«æããåéäœã®
ãã¬ã³ãããå ±éåãããã æ¬çºæã«æçšãªéåäœã«ããªã³ç³»åªæå€çµæç©
ã®ä»£è¡šçãªãã®ã第ïŒè¡šã«ç€ºãããªãã«ãã³å ã¯
ã¢ã«æ¯ã§ããã 第 ïŒ è¡š M1 ããªïŒã¹ãã¬ã³âã³âïŒâãã¬ã€ãããã
ãã«âã»ïŒ®âãžã¡ãã«ââãã³ãžã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M2 ããªââã¢ãªã«âã»ïŒ®âãžã¡ãã«âã
ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M3 ããªââããã«ã€ãããŸãŒã«ïŒé žæµŽã§ã
ããã³åããããšã«ããªã³ã«ãªãïŒ M4 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«ã®
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M5 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M6 ããªïŒããã«ã¢ã»ããŒãããªãžããŠã ã¯
ãã©ã€ãïŒ M7 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«â
ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M8 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªãšãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M9 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«ã®
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M10 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãšãã¬
ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒïŒ93ïŒïŒïŒïœ M11 ããªïŒïŒ®âã¢ãªã«âã»ïŒ®âãžã¡ãã«âã
ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãâã³â
ãžããã«ãã³ãŒã³ïŒïŒ95ïŒïŒïŒïœ M12 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«âãã³ãžã«ã¢ã³ã¢ããŠã
ãããã€ãâã³âãžããã«ãã³ãŒã³ïŒïŒ49ïŒ
49ïŒïŒïŒïœ M13 ããªïŒïŒ®âïŒâãããã«âã»ïŒ®âãžã¡ã
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M14 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M15 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããã«
ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒ
ïŒïŒïœ M16 ããªïŒã¹ãã¬ã³âã³ââãã³ãžã«âã»
âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããããã«ã¢ã³ã¢ã
ãŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒ M17 ããªïŒïŒ®âãã³ãžã«âã»ïŒ®âãžã¡ãã«â
ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M18 ããªïŒã¹ãã¬ã³âã³ââããã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M19 ããªïŒïŒâããã«ã€ãããŸãŒã«âã³âïŒâ
ããã«âïŒâãã³ãžã«âã€ãããŸãªãŠã ã¯ã
ã©ã€ãïŒïŒïŒïŒïŒïŒïœ M20 ããªïŒïŒã»ïŒâãžã¡ãã«âïŒâããã«ããª
ãžãŠã âïœâãã«ãšã³ã¹ã«ãããŒãïŒ M21 ããªïŒïŒâãã³ãžã«âïŒâããã«ããªãžã
ãŠã ã¯ãã©ã€ãïŒ M22 ããªïŒïŒâãã³ãžã«âïŒâã¡ãã«âïŒâã
ãã«ããªãžããŠã ã¯ãã©ã€ãïŒ M23 ããªïŒïŒ®âã«ã«ãã¢ã€ã«ã¡ãã«âã»ïŒ®â
ãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ã
ã©ã€ãïŒ M24 ããªïŒïŒ®âã·ã¯ãããã·ã«âã»ïŒ®âãžã¡
ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M25 ããªãã»ïŒ®âãžã¡ãã«ââïŒïŒâã¡ã
ã«âïŒâãããã«ïŒâããã«ãã³ãžã«ã¢ã³ã¢ã
ãŠã ã¯ãã©ã€ãã M26 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã¡
ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒïŒïŒïŒïŒïŒïœ M27 ããªïŒïŒ®âã€ãœããã«âã»ïŒ®âãžã¡ãã«
âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M28 ããªãâãã³ãžã«âã»ïŒ®âãžã¡ãã«â
ïŒïŒâã¢ã¯ãªã«ã¢ããâïŒã»ïŒâãžã¡ãã«âã
ããã«ïŒâã¢ã³ã¢ããŠã ã¯ãã©ã€ãã M29 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M30 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®âãã³ãžã«â
ã»ïŒ®âãžã¡ãã«âïŒâããã«ãã³ãžã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M31 ããªïŒïŒ°ã»ïŒ°ã»ïŒ°âããªãªã¯ãã«ããã«ã
ã³ãžã«ãã¹ãã㊠ã¯ãã©ã€ãïŒ M32 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã
ãã·ã« ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©
ã€ãïŒïŒïŒïŒïŒïŒïœ M33 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã¡
ãã« ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒïŒïŒïŒïŒïŒïœ M34 ããªïŒã¹ãã¬ã³âã³ââãã³ãžã«âã»
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã â
ã³âãžããã«ãã³ãŒã³ïŒïŒ49.5ïŒ49.5ïŒïŒïŒïœ M35 ããªïŒïŒ®âããã«ãã³ãžã«ãããªãžããŠã
ã¯ãã©ã€ãïŒ M36 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âïŒâãã
ã«ããšãã«ã«ã«ãã¢ã€ã«ã¡ãã«ã¢ã³ã¢ããŠã
ã¯ãã©ã€ãïŒ M37 ããªïŒïŒ®âã¢ã»ããã«âã»ïŒ®âãžã¡ãã«
âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M38 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââã¡ããã·ã«
ã«ããã«ã¡ãã«âããã«ãã³ãžã«âã¢ã³ã¢ããŠ
ã ã¯ãã©ã€ãïŒ M39 ããªïŒããã«ãã³ãžã«âïŒâããªãžããŠã
ã¯ãã©ã€ãïŒ M40 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã
ããªãžããŠã ã¯ãã©ã€ãïŒ M41 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã
ããªãžããŠã ã¯ãã©ã€ãïŒ M42 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã¢
ã«ããªããŠã ã¯ãã©ã€ãïŒ M43 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââããã«ãã³
ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M44 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââã·ã¯ããã
ã·ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ æ¬çºæã«æçšãªåªæå€çµæç©ã¯ããç¥ãããŠã
ãååŠåå¿ãçšããŠã€ããããšãã§ããããã®ã
ããªååŠåå¿ã¯åçåéã«ãããŠãããšåãç©è³ª
åã¯ããã«äŒŒãç©è³ªã®äœ¿çšã«çµã³ã€ããŠæ¢ã«è©³çŽ°
ã«èšèŒãããŠãããåŸã€ãŠãæ¬çºæã«çšããåçš®
ã®åªæå€ç©è³ªã補é ãã詳现ãªèª¬æã¯å¿ èŠã§ãª
ããããããªããããããã®ãããªç©è³ªãã€ãã
詳现ãªèª¬æãç¥ããããšãã«ã¯æ¬¡ã®ç¹èš±ãåç §ã
ãããïŒè±åœç¹èš±ç¬¬1261925å·ïŒç±³åœç¹èš±ç¬¬
3488706å·ïŒå第3557066å·ïŒå第3625694å·ïŒå
第3709690å·ïŒå第3770439å·ïŒå第3758445å·ïŒ
å第3773509å·ïŒå第3859096å·ïŒå第3898088
å·ïŒå第3944424å·ïŒåã³å第3958995å·ã åªæå€ãšãžã¢ãŸæš¹èã®çžå¯Ÿéã¯æå®ã®ç®çãšã
ãçšéãšåæ§ååéãšåªæå€ã®åªæåã«ããç°ãª
ããåªæå€ã®ååéãããŸãåªæåã倧ãããª
ãã°ãªãã»ã©ãã®éãå°ãªãçšããããšãã§ã
ããããã«ãã»ãšãã©ãã¹ãŠã®ãžã¢ãŸæš¹èã¯çŒåº
ããæ±ããçè²ãããã®ã§ãçšããããæš¹èã®é
ã¯äœ¿çšçšéã«èš±ãããäžé£œå床ã®éã«ããçšäŸå
ããã ã«ã©ãŒãã«ãŒãã€ã³ã°ã«çšããã«ã¯ããžã¢ãŸæš¹
èã¯0.16ã0.10mg/dm2ã®å¡åžéã奜ãŸããããŸã
åªæå€ã¯0.5ã5.0mg/dm2ã奜ãŸãããç¹ã«å¥œãŸã
ãåªæå€ã®éã¯1.0ã1.5mg/dm2ã§ããã æ¬çºæã®çµæç©ã®å¡åžç©ãèªå·±æ¯ææ§ã§ãªãå Ž
åã«ã¯æ¯æäœãçšãããããã®æ¯æäœäžã«çµæç©
ãå¡åžãããã åŸæ¥ããçšããããŠããåççšæ¯æäœãæ¬çºæ
ã®å®æœã®éã«çšããããã代衚çãªæ¯æäœã«ã¯äž
éæãªæ¯æäœãäŸãã°éå±ãåççšçŽæ¯æäœãšå
æ§éæãªæ¯æäœãäŸãã°ãã€ã«ã æ¯æäœãã¬ã©ã¹
æ¯æäœãå«ãŸããããã®æ¯æäœã¯ç¡¬è³ªã®ãã®ã§
ãããŸãè»è³ªã®ãã®ã§ããããããæ®éã«çšãã
ããŠããæãäžè¬çãªåççšæ¯æäœã¯çŽæ¯æäœ
ïŒäœããã€ãæ¶ãä»äžãããããã®ãå«ãïŒãšé
æãªãã€ã«ã æ¯æäœãäŸãã°ããªïŒãšãã¬ã³ãã¬
ãã¿ã¬ãŒãïŒãã€ã«ã ãã§ãããé©åœãªæ¯æäœã®
代衚çãªãã®ã¯è±åœã®ããŒãã³ãã»ãã³ãã·ã€ãŒ
ããŒ091ã€ãŒãšãã»ããŒã ãŠãšã«ïŒHavant
Hampsnire  091 EF HomwellïŒã®ã€ã³ãã¹
ããªã¢ã«ã»ãªãããŠããã€ãŒãºã»ãªãããã
ïŒIndnstrial Opportunwities LimiteolïŒããçºè¡
ãããŠãããããã¯ãã»ã©ã€ã»ã³ã·ã³ã°ã»ã€ã³ã
ãã¯ã¹ïŒProduct Licensing IndexïŒã92å·»ã
1971幎12æå·ã9232å·ã«èšèŒãããŠããããã®æ¯
æäœã¯ããã«å¯Ÿããæå æ§å¡åžç©ã®æ¥çæ§ããã
ããããã«ãã®æ¯æäœã®è¡šé¢ã®æ§è³ªãå€ããç®ç
ã§ïŒå±€åã¯æ°å±€ã®äžå¡å±€ãä»åšãããããšãã§ã
ãã代衚çã«ã¯ãå転å¡åžæ³ããã©ã·å¡åžæ³ãã
ã¯ã¿ãŒãã¬ãŒãå¡åžæ³ãåã¯ããããŒå¡åžæ³çã®
æ段ãçšããŠæ°Žæº¶æ¶²ãæ¯æäœäžã«å¡åžããŠããã
ã®å¡åžç©ã也ç¥ããã代衚çãªå¡åžæ³ã®ä»ã®äŸã«
ã€ããŠã¯ãäžèšã®ãããã¯ãã»ã©ã€ã»ã³ã·ã³ã°ã»
ã€ã³ããã¯ã¹ïŒProduct Licensing IndexïŒ92
å·»ã1971幎12æã9232å·ã®109é ã«èšèŒãããŠã
ãããŸãå¡åžå©å€ããã®å¡åžçµæç©ã«å ¥ããããš
ãã§ããã è²çŽ ã®æ·»å äžã«èŠçŽ ãæ¿ããæ¹æããªããã°ãª
ããªãå Žåã¯èŠçŽ ãããã«ç¡¬ãããããšãæãŸã
ãããã®ãããªç¡¬ãã¯ãžã¢ãŸæš¹èäžãäžå¡å±€ã«ä»¥
äžã«èšèŒãããããã«ããªïŒããã«ãããªãã³ïŒ
ã®ãããªããã«ããªããŒãå ¥ããããšã«ããåŸã
ããã äžèšã®ããã«ããŠã€ããããèŠçŽ ã¯ããŸãåã
ã«æ åçã«é²å ãããã€ãã§ã¢ããªã³è²çŽ ãå«ãŸ
ããŠããè²çŽ 济ã«æµžãåã«çŸåãããããžã¢ãŸæš¹
èãæå ãã掻æ§èŒ»å°ç·ã«å¯Ÿããé²å ã¯ã©ã®ãã
ãªåœ¢åŒã®ãã®ã§ãçšããããšãã§ããããã®ãã
ãªæš¹èã¯çŽ«å€ç·ã«äž»ãšããŠæå ããã®ã§ã玫å€ç·
ã«å¯ãå æºã奜ãŸããããã®ãããªç¹æ§ãæãã
åŸæ¥ããçšããããŠããå æºã¯å®¹æã«å©çšããã
ãšãã§ããã é²å æ¹åŒã¯çšããããèŠçŽ ã«ããç°ãªãããã«
ã©ãŒãã«ãŒãã€ã³ã°ãªãŒãã¬ã€èŠçŽ ã«ã¯éåžžã®å¯
çé²å ãããããŠäŸ¿å©ã§ããã é²å ãçµã€ããããã®èŠçŽ ã®å¡åžç©ã®é²å ãã
ãªãã€ãéšåãæŽãèœãšãããããèœããŠãã®èŠ
çŽ ãçŸåãããæš¹èå¡åžç©ã®å ã«ãã硬åããéš
åã ããé²å éã«æ¯äŸããŠæ®ããåŸã€ãŠãæ®ã€ãŠ
ããåªæå€ã®éã¯é²å éã«æ£æ¯äŸããŠååšããã
æŽæ¶²ã¯éåžžã®æ°Žéæ°ŽãããªãããããŠãã®ãã®ã
éããªåŽé§ç¶ã«ããŠãåã¯èå£ããã®æµæ°Žã«ãŠæŽ
ãèœãšãããšãã§ããããŸãããã®æ°ŽæŽã¯æ°Žäžã«
ã²ãããããçš®ã®ææãšæ©æ¢°çã«ããã€ãŠè¡ãªã
ããšãã§ãããæ°ŽæŽæéã«ã¯äœãå¶éããªããã
ïŒç§ããïŒåã®ç¯å²ã®æéãå¹æçã§ããã 次ã«ããã®çŸåãããèŠçŽ ç¹ã«å ã«ãã硬åã
ãåªæå€æš¹èå¡åžç©ã¯ãã®èŠçŽ ãé©åœãªè²çŽ 济ã«
浞ããŠã¢ããªã³ç³»è²çŽ ãå ããããããã®è²çŽ ã¯
äžèšå¡åžç©å ã§äžååããããè²çŽ 济ã¯ä»¥äžã«è©³
现ã«èšèŒãããåã®è²çŽ ã®æ°Žæº¶æ¶²ãç·©è¡æ°Žæº¶æ¶²ã§
ããã浞挬æéãšæµŽã®æž©åºŠã¯åºç¯å²ã«å€æŽå¯èœã§
ãããã10ã100ç§ã奜ãŸããããŸã枩床ã¯10ã
40âã奜ãŸããã次ã«ãã®èŠçŽ ãååºããå¿ èŠã«
ããéå°ã®è²çŽ ãé€ãããã«ãããã次ãã§å ç±
ããŠåã¯å ç±ããã«ä¹Ÿç¥ããããªãããããå·¥çš
ã¯çŸåå·¥çšãšå šãåãã«åãæéã®ç¯å²ã§è¡ãªã
ããšãã§ããããŸããæ°Žã«ããåŠçå·¥çšã®ãã¹ãŠ
ãè²çŽ 济ã«ã€ããŠäžè¿°ããã®ãšåã枩床ç¯å²ã§è¡
ãªãããšãã§ããã ã€ã³ããã·ãšã³ïŒimbibitionïŒã«ããèŠçŽ ã«å¯
èŠåãã€ããããã«ã©ã®ãããªã¢ããªã³ç³»è²çŽ ã
çšããããšãã§ããããã®è²çŽ ã®éžæã¯ããã¡ã
ããæå®ã®è²ãæçµçšéã«ããå·Šå³ããããäŸã
ã°ããã©ãã¯ã»ããªã³ã¿ãŒã»ãªãŒãã¬ã€ã«ã¯ãã©
ãã¯è²çŽ ãçšãããããè€åã«ã©ãŒã»ãã«ãŒãã€
ã³ã°ã»ãªãŒãã¬ã€ã圢æããéã®è²å解ããžã«ã¯
åè²ã®ã·ã¢ã³ãããŒã³ã¿åã³ã€ãšããŒãéžã°ã
ããæ¬çºæã«çšããç¹ã«å¥œãŸããçš®é¡ã®ããŒã³ã¿
è²çŽ ã¯æ¬¡åŒã§ç€ºãããæ§é åŒããã€ããã®ãããª
ãïŒ ããã«ãããŠãR8ãšR9ã¯äžèšã«ç€ºããããã
ãªé»ååžåŒæ§ã®åºã§ããïŒ SO2CH2CH2CO2H4ã¹ã«ãã¢ã¢ã€ã«ãã«ã«ãã
ã·ã«ãSO3HãSO2CH3ãïŒãïŒåã®ççŽ ååã®
ã¢ã«ãã«ã
ïŒcolorâproofingïŒçšã®é£ç¶é調è²çŽ ç»åãã€ã
ãã®ã«æçšãªå 硬åæ§ç»å圢æçµæç©åã³èŠçŽ ã«
é¢ããã åŸæ¥ã®ã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ã¯ãã«ããªã³
ç³»è²çŽ ãšã§é£ç¶é調ç»åã圢æããã¢ããªã³ç³»åª
æå€ãäžããããã«ããžã¢ãŸæš¹èãäžæŽ»æ§éåäœ
ãã€ã³ããŒãšã®æ··åç©ã®åœ¢ã§å¡åžç©äžã«å«ãŸããŠ
ããããšããã»ãã¯ã°ããã³ïŒH.McGuckinïŒã®
ã«ããç¹èš±ç¬¬998278å·ã«ã¯ããã®äŸã瀺ãããŠã
ããããããã·ã»ã«ããŒãºãéåäœãã€ã³ããŒãš
ããŠçšããããŠãããããããªããããã®ç³»ã§ã¯
ãã®å¡åžç©äžã®ãã€ã³ããŒã¯é²å ãããŠããªãéš
åãå®å šãªå±€ãšããŠåç¶ã®ãŸãŸã§ãã€ãããã®ã
ãšã¯å 硬åæ§ãžã¢ãŸæš¹èãçšããé²å ãããªãã€
ãéšåã®å¡åžç©ããŠãªã·ãŠïŒwashïŒå·¥çšã§å šéš
åãé€ãããåŸæ¥ã®ç³»ãšã¯ç°ãªããã®ã§ãããåŸ
è ã®ç³»ãããŠãªã·ãŠã»ãªããç³»ïŒwashâoff
systemïŒãšåŒã³ãäžèšã®ã«ããç¹èš±ã«èšèŒãã
ãŠãããããªãŠãªã·ãŠã»ã¢ãŠãç³»ïŒwashâout
systemïŒãšã¯åºå¥ããŠããã åŸæ¥ããŠãªã·ãŠã»ãªã ãžã¢ãŸæš¹èã¯å€ãã®ç
ç±ããã«ã©ãŒãã«ãŒãã€ã³ã°ç³»ã«ãããæçšæ§ã
éãããŠããããããã®çç±ã®ãã¡ã®ç¬¬ïŒã®çç±
ã¯ããã®ãããªæš¹èã®èªåã«ããã¹ããŒããè¥å¹²
é ããšããããšã§ããã第ïŒã®çç±ã¯ãŠãªã·ãŠã»
ãªãç³»ã§ã®ãã®æš¹èããåŸãããã³ã³ãã©ã¹ãã
é£ç¶é調ç»åãã€ããã«ã¯ãããããã»ã©ã®ãã®
ã§ãããšããããšã§ããã1967幎ïŒæå·ã®ã°ã©ã
ã€ãã¯ã»ã¢ãŒãã»ãã³ã¹ãªãŒïŒGraphic Arts
MonthlyïŒã«ã¯æ¬¡ã®ããšãèšèŒãããŠããããçŸ
åšã§ã¯âŠâŠâŠâŠé£ç¶é調å解ãã¬ãè©Šéšããæºè¶³
ãªæ¹æ³ã¯ãªããçŸåšåŸãããã«ã©ãŒãã€ã«ã ã¯ã
ã®äœ¿çšã«ã¯ããŸãã«ãã³ã³ãã©ã¹ããé«ãããâŠ
âŠâŠâŠããšãããã¢ããªã³ç³»è²çŽ ã®ç³»ãéçºãã
ããªãã°ãè²çŽ ã®é©çšç¯å²ã¯ä»ããããã€ãšåºã
ãªãããŸãä»ã®æå æ§ææãäŸãã°äžè¿°ããã«ã
ãç¹èš±ã«èšèŒãããŠãããããªãžã¢ãŸå¡©ãã¢ããª
ã³ç³»è²çŽ ãšå ±ã«çšããããŠãããããžã¢ãŸæš¹èªã¯
ã¹ããŒããé«ããããžã¢ãŸå¡©ããã奜ãŸããã æ¬çºæã®ããããç¹åŸŽã¯ãŠãªã·ãŠã»ãªãæå æ§
ãžã¢ãŸæš¹èçµæç©åã³ãããå«æãããã«ãŒãã€
ã³ã°èŠçŽ ã«ããã æŽã«è©³ããã¯ãå 硬åæ§ç©è³ªãšããŠæå æ§ãžã¢
ãŸæš¹èãã«ããªã³ç³»éåäœåªæå€ãšäžç·ã«æ··åç©
ã®ç¶æ ã§å«ãŸããŠãããŠãªã·ãŠã»ãªãæå æ§çµæ
ç©ã®æäŸã«ãããããã«ãããŠäžèšåªæå€ã¯äžèš
æš¹èãšäœµçšããããã®ã§ããïŒçžå®¹æ§ãããïŒã
ããããã®çµæç©ã®å ã«ãã硬åãããéšåã«ä¿
æãããããšãã§ãããã®ã§ããã ãã®ãããªçµæç©ãçšããŠè²çŽ ç»åã圢æãã
ã«ã¯ããã®çµæç©ã®å¡åžå±€ãæ åé²å ãããã®å±€
ãæ°Žã§ãããã§çŸåããã¢ããªã³ç³»è²çŽ ããã®å±€
ã«å ããããã§ãã®è²çŽ ãåªæå€ã«ããäžååã
ãŠè²çŽ ç»åã«ããã°ããããã®è²çŽ ç»åã¯ãæŽ
ã«ããã®çµæç©ã®åªæå€ããã匷ãã«ããªã³ç³»åª
æå€ãå«ãååå±€ã«è»¢åããããšãã§ããããã®
転åã¯ããçš®ã®å¡©ã®æº¶æ¶²åã¯ã¢ã«ã³ãŒã«ãšæ°Žã®æ··
å溶液ã®ååšäžã§ãäžèšè²çŽ ãçµæç©ã®åªæå€ã
ãååå±€äžã®åªæå€ã«ç§»è¡ãããã®ã«ã¡ããã©å
åãªæéäžèšååå±€ãçµæç©ã®å±€ã«æ¥è§Šãããã
ãšã«ããè¡ãªãããã æ¬çºæã¯é£ç¶é調åçç»åãã€ããã®ã«æçšãª
çµæç©åã³ãã«ãŒãã€ã³ã°èŠçŽ ã«éå®ããããã®
ã§ã¯ãªãããæ¬çºæã¯ãã®ç®çã®ããã«ç¹ã«æçš
ã§ãããäŸãã°ãé£ç¶é調ç»å圢æã¯åŸã§åŒ·èª¿ã
ãã奜ãŸããå ·äœäŸã®ãã¬ã»ãã¬ã¹ã«ã©ãŒãã«ãŒ
ãã€ã³ã°èŠçŽ ïŒpreâpress colorâproorfing
elementïŒã®åéã«æçšã§ãããããŸãæ¬çºæã®
çµæç©ãšèŠçŽ ã®ä»ã®å¯èœãªäœ¿çšããªãã¡ãã°ã©ã
ã€ãã¯ã¢ãŒãã»ããªã³ãã»ãã€ã«ã ããã€ã¯ãã
ã¢ã€ã«ã»ããªã³ãã»ãã€ã«ã ããããªã»ãã¹ã¯çš
äžéäœåã¯ãªãªãŒã¹ã»ããªã³ãã«ãéèŠã§ããã
ãããå¯èœã«ããæ¬çºæã®çµæç©ã¯ãžã¢ãŸæš¹èãš
ãã®æš¹èãšçžå®¹æ§ã®ã«ããªã³ç³»éåäœåªæå€ãã
ãªãããã®çµæç©ã¯ã¢ããªã³ç³»è²çŽ ãå ã«ãã硬
åããéšåã«åŒãã€ãããã«ä¿æããããšãã§ã
ãæ§è³ªãæããŠãããé©åœãªç»å圢ææ§ãã«ãŒã
ã€ã³ã°èŠçŽ ã¯æ¯æäœäžã«ãã®æå æ§çµæç©ãå¡åž
ããããã®ãããªãã ãã®çµæç©ã¯ãå 硬åæ§ãžã¢ãŸæš¹èå«æãŠãªã·
ãŠã»ãªãçµæç©ãé£ç¶é調ç»å圢æã«äžé©ã§ãã
ãšèããŠãããã®ã以äžã«èšèŒãããã¢ããªã³ç³»
è²çŽ ã®éåäœåªæå€ãå ããããšã«ããéåžžã«æ
çšãªãã®ã«ããããšãã§ãããšããçºèŠã«åºã¥ã
ãã®ã§ããã 氎溶æ§ã®æå æ§ãžã¢ãŸæš¹èãªãã©ã®ãããªãã®
ã§ãçšããããšãã§ãããç¹ã«æå¹ãªãã®ã¯æ¬¡åŒ
ã§è¡šããããç¹°è¿åäœãæããäœååéã®æš¹èã§
ããïŒ åŒäžã®ïŒªã¯J1åã¯J2ã§ä»¥äžã«å®çŸ©ãããã
ã¯ã¯ãã©ã€ãçã®ã¢ããªã³ã§ãããïœã¯ïŒåã¯ïŒ
ã§ãããæ®éãããã¯æŽ»æ§ãªã«ã«ããã«ååç©ã
äŸãã°ãã«ã ã¢ã«ãããåã¯ãã©ãã«ã ã¢ã«ãã
ãã次åŒã§ç€ºããããžã¢ãŸååç©ãšçž®åãããŠã€
ããããïŒ åŒïŒïŒåã¯ïŒïŒã®Xâ²ã¯ãã©ã€ãããã¹ã
ãšãŒããã¹ã«ããšãŒããã«ãªããã¬ãŒãçã®ã¢ã
ãªã³ã§ããïŒ åŒïŒïŒåã¯ïŒïŒã®ïŒã¯ãžã¢ãŸããŠã åºãå®
å®ã«ããå ¬ç¥ã®ïŒäŸ¡åã¯ïŒäŸ¡ã®éå±ãäŸãã°ã«ã
ããŠã ãäºéããã¹ãã¹ãç çŽ ãã¢ã³ãã¢ã³ãã¹
ãºãéãçœéãæ°Žéã§ããïŒ åŒïŒïŒåã¯ïŒïŒã®ïŒžã¯ãã©ã€ãåã¯ã¹ã«
ããšãŒãã®ã¢ããªã³åã¯ã¢ããªã³ã®æ··åç©ã§ã
ãïŒ J2ã¯æš¹èãïœâãžã¢ãŸãžããšãã«ã¢ãã³å¡©ã®ã¢
ã«ãããçž®åçæç©ã®å Žåã¯ãããšãã«åã¯çœ®æ
ããšãã«ã§ããããŸãJ1ã¯æ°ŽçŽ ã§ããã ç¹ã«å¥œãŸãããžã¢ãŸæš¹èã¯ïŒâã¢ããâïŒã»
1â²âãžããšãã«ã¢ãã³ã®ãžã¢ãŸããŠã å¡©ãäŸãã°
ïŒã»1â²âãžããšãã«ã¢ãã³âïŒâãžã¢ãŸããŠã ã
ã©ã€ãåã¯ïŒã»1â²âãžããšãã«ã¢ãã³âïŒâãžã¢
ãŸããŠã ãã¹ããšãŒãããé žäžã§ãã¢ã«ãããäŸ
ãã°ãã©ãã«ã ã¢ã«ãããåã¯ãã«ã ã¢ã«ããã
ãšçž®åãããã€ãã§è€éå±å¡©ãäŸãã°ã¯ãããžã³
ã±ãŒãåã¯ãã«ãªããã¬ãŒãã«å€ããé žçž®åçæ
ç©ã§ããããã®ãããªæš¹èã¯åŸæ¥ããç¥ãããŠã
ãããã®è£œé æ³ãæŽã«è©³ããããšã¯äŸãã°ã³ã¶ãŒ
ã«ãïŒKosarïŒã®æå æ§ç³»ïŒLightâSensitive
SystemsïŒ323â324é ïŒ1965ïŒãç±³åœç¹èš±ç¬¬
323584å·ã«èšèŒãããŠããã æå æ§ãžã¢ãŸæš¹èã«å ãåœãŠããšãã¬äœçšã®æš¹
èåãã§ãããããªãã¡ãæ åçã«é²å ãããã
ã®ãããªæš¹èã®å¡åžç©ã¯æ¶æ©ããŠæ°Žã«æº¶ããªãã
ãªããŒãã€ããããã®å¡åžç©ã®é²å ãããªãã€ã
éšåã¯å¥œãŸããã¯ãã®ãŸãŸæ°Žã«æº¶ããç¶æ ã«ãšã©
ãŸãããã®ããé©åœãªæº¶å€ã§åŠçãããšæŽé€
ïŒwash offïŒãããã ãã®å¡åžç©ã®ä¿åæ§ãããããããã«ãéåžžé ž
æ§ã®ä¿åå€ãäžèšã®ãžã¢ãŸæš¹èã«å ãããããã
ã®ç®çã®ããã«åŸæ¥ããçšããããŠããé žãšããŠ
ã¯ãªã³é žãã¯ãšã³é žãïœâãã«ãšã³ã¹ã«ãã³é žã
ã¡ã¿ã³ã¹ã«ãã³é žããã³ãŒã³ã¹ã«ãã³é žãåã³ã
ãã®çœ®æèªå°äœãïŒâããã¿ã¬ã³ã¹ã«ãã³é žçã
ããããŸãããããã®å¡åžç©ããã䜿çšããå Žå
ã¯ãã®ãããªé žå®å®åå€ãå ¥ããªããŠããããã
ãé žå®å®åå€ãçšããå Žåã¯ããã®éãçŽ0.1mg/
ïœm2ãšçŽ1.0mg/dm2ã®éã§å€ããããšãã§ããã ã«ããªã³ç³»éåäœåªæå€ã¯ãæ åçã«ç¡¬åãã
çµæç©ããã€ããããæ¬çºæã®èŠçŽ ãé©åœãªè²çŽ
溶液ã«æµžãããšãã«ã¢ããªã³ç³»è²çŽ ãåªæããäœ
çšãè¡ãªãã è²å解ãã¬ïŒãããéããŠçµæç©ã®é²å ãè¡ãª
ãããïŒã®è²ã«å¯ŸããŠè£è²ã®æžè²è²çŽ ãé©åœã«éž
ã¶ããšã«ãããã«ã©ãŒãã«ãŒãïŒcolorâdroofïŒ
ãïŒè²å解ããžãããªããªãŒãã¬ã€ïŒoverlayïŒ
ã®åœ¢ã§åŸãããšãã§ããããã®ããžã¯æ¬çºæã«åŸ
ã€ãŠã€ããããïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ãšïŒçš®
é¡ã®æžè²è²çŽ 溶液ããåŸãããããã®ããã«ããŠ
çããç»åã¯ãã®ã³ã³ãã©ã¹ããæ¯èŒçäœãã
ãããã®ãããªã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ã¯é£ç¶
é調ç»åã«çšããã®ã«ããããŠé©ããŠããããã
è©Šéšã®çµæã«ã©ãŒãã¬ã®ãã¡äžã€åã¯ãã以äžã
ä¿®æ£ããå¿ èŠãããå Žåã¯ä¿®æ£ããè²å解ãã¬ã
ã€ãããã®ãã¬ã®æ°ãããã«ãŒãã€ã³ã°èŠçŽ ãé²
å ããåŠçãã次ãã§ãã®æ§æç©ïŒã³ã³ããžã
ãïŒãåè©Šéšããããšãã§ããããã®ããå°å·ç
ãã€ãããå°å·æ©ã«çµã¿å®éã«åçãå°å·ããã
ã¬ã®æ£ãããè©Šéšããå¿ èŠããªãã ã«ããªã³ç³»éåäœåªæå€ã¯ãã®å šéšããžã¢ãŸæš¹
èãšæå¹ã«äœçšããããã§ã¯ãªããäŸãã°ãåªæ
å€ã®ãã¡ã®ãããã®ã¯ããããã溶åªäžã§æš¹èã
æ²æŸ±ãããçµæç©ãå¡åžããããšãã§ããªãã®ã§
æš¹èãšäžç·ã«çšããããšãã§ããªãïŒããªãã¡çž
容æ§ããªãïŒããŸããåªæå€ã®ãã¡ã®ä»ã®ãã®ã¯
å ã«ãã硬åãããžã¢ãŸæš¹èãæ¯æäœã«å¯ŸããŠæ
ããŠããéåžžã®æ¥çæ§ãç¢ãªãããããããã«æš¹
èã®å 硬åãé»å®³ãããåŸã€ãŠãéåäœåªæå€ã¯
æš¹èãšäžç·ã«çšããããšã®ã§ãããã®ïŒããªã
ã¡ãçžå®¹æ§ã®ãããã®ïŒã§ãªããã°ãªããªããã
ãªãã¡ããã®åªæå€ã¯ãžã¢ãŸæš¹èã®éåžžã®å 硬å
ãããæ©èœãé»å®³âãã®é»å®³ãå¡åžã«å¿ èŠãªæº¶æ¶²
æ§ãå 硬åããæš¹èã®æ¥çæ§ãå 硬åã®éçšèªäœ
åã¯å 硬åã«é¢ããæš¹èã®ä»ã®æ§è³ªã®ãã®ã§ãã
âãããã®ã§ãã€ãŠã¯ãªããªãã ãžã¢ãŸæš¹èãšãããšçžå®¹æ§ã®ããåªæå€ãšã®é
ã®çžäºäœçšã®ã¡ã«ããºã ã¯ãŸã å®å šã«ã¯å€ã€ãŠã
ãªããå æ¶æ©ããžã¢ãŸæš¹èå ã§èµ·ããããã«åªæ
å€ãæç²ãããã®ãããããšãéåäœåªæå€ãæš¹
èãšæ¶æ©ããã®ãæããã§ãªããã©ã®ãããªå Žå
ã§ãããã®åªæå€ã¯ãã¡ã«ããºã ãã©ãã§ããã
çµæç©ã®å ã«ãã硬åãããéšåã«ä¿æãããã
ãšãã§ãããšå ±ã«ããžã¢ãŸæš¹èãšäž¡ç«ããããã®
ã§ãªããã°ãªããªãã æçšãªéåäœã«ããªã³ç³»åªæå€ã¯åçš®ã®åçã
ã€ã«ã ãåççŽåã³ãã®ä»ã®çšéã«ãããŠãã§ã«
çšããããŠãããé»è·ã垯æããã«ããªã³åºãæ
ããç¹°è¿åéäœåäœãå«ãçµæç©ïŒäŸãã°ç±³åœç¹
蚱第3758445å·åã³å第3958995å·ã«èšèŒãããŠã
ãïŒã®ãããã€ãåªæå€ã®ãã¡ã®äžéšãå«ãŸã
ããå¿è«ãäžèšã®æ§è³ªãšååŠçµæãæãããã®ä»
ã®éåäœææã§ãä»ãŸã§åçåéã«ãããŠæçšãª
åççšåªæå€ãšããŠèªããããŠããªãã€ããã®ã
æ¬çºæã®ç¯å²å ã§çšããããšãã§ããã ç¹ã«æçšãªéåäœåªæå€çµæç©ã§æ¬çºæã«çšã
ãããšã®ã§ãããã®ã¯ããªããŒéã«æ¬¡åŒïŒïŒå
ã¯ïŒïŒã®åéäœåäœãæããç©è³ªã§ããïŒ ããã«ãããŠïŒ ã¯æ°ŽçŽ ååãïŒããïŒåã®ççŽ ååãæãã
ã¢ã«ãã«åºãå°ãªããšãïŒåã®è³éŠææ žãå«æã
ãåºäŸãã°ããšãã«ãããªã«ããããã«çã§ã
ãïŒ ïŒ±ã¯ååŠçµååã¯ã¢ã«ãã¬ã³ãã¢ãªãŒã¬ã³ãã¢
ãªãŒã¬ã³ã¢ã«ãã¬ã³ãã¢ã«ãã¬ã³ã¢ãªãŒã¬ã³ãã¢
ãªãŒã¬ã³ãã¹ã¢ã«ãã¬ã³ãåã¯âCOâR4âãâ
COâOR1âãââCOâR4âãâCOâNHR4âåº
ïŒäœããR4ã¯ïŒããïŒåã®ççŽ ååãæããã¢ã«
ãã¬ã³ã§ããïŒãããªäºäŸ¡ã®åºãè¡šããããŸãã¯
ããšãã«âNHâCOâCH2âïŒåªæå€ïŒâ36ãã
ã®åºïŒã§ããããã®ïŒ±ã¯ïŒ€ãšäžç·ã«ãªã€ãŠãã¢ã«
ãã¬ã³åºãïŒããïŒåã®ççŽ ååãæããâã¢
ã«ãã¬ã³çœ®æãã¬ã€ã³ã€ãããã€ããã®ã«å¿ èŠãª
ååãè¡šããïŒ Mâ²ã¯çªçŽ åã¯ãªã³ã®ååãè¡šããããã®
Mâ²ã¯R1ãR2åã³R3ãšäžç·ã«ãªã€ãŠç¬¬ïŒçŽã¢ã³
ã¢ããŠã åºåã¯ç¬¬ïŒçŽãã¹ããŠã åºã圢æãïŒ Xâ³ã¯ãã©ã€ãã€ãªã³ïŒäŸãã°ã¯ãã©ã€ãå
ã¯ãããã€ãïŒãã€ãã¬ãŒããã¡ãœã¹ã«ããšãŒ
ããïœâãã«ãšã³ã¹ã«ãããŒãçã®é žã¢ããªã³ã
è¡šããïŒ R1ãR2åã³R3ã¯ãåäžåã¯ç°çš®ã®ãã®ã§ã
ãããããã¯ããããïŒãã20åã®ççŽ ååãæ
ããã¢ãªãŒã«ãã¢ã«ã¢ã«ãã«åã¯ã¢ã«ã«ãªãŒã«
åºãåã¯ïŒãã10åã®ççŽ ååãæããã¢ã«ã
ã«ãã¢ã«ã±ãã«åã¯ã¢ã«ããã«åºãè¡šããããŸã
Mâ²ãšäžç·ã«ãªã€ãŠãR1ãR2åã³R3ã¯æ¬¡åŒãæ
ããè€çŽ ç°ãã€ããã®ã«å¿ èŠãªååãè¡šããïŒ äœããã¯æ°ŽçŽ ååãïŒããïŒåã®ççŽ ååã
æããã¢ã«ã¢ã«ãã«ãè¥ããã¯ã¢ã«ãã«ã§ããã
å㯠äœããã¯äžé£œåè€çŽ ç°ãã€ããã®ã«å¿ èŠãªé
éå±ååã§ãããã¯äžèšã§å®çŸ©ãããã®ã§ã
ãã 奜ãŸããã¯ãR1ãR2ããã³R3ã¯ãMâ²ãšäžç·
ã«ãªã€ãŠããåºãè¡šããå Žåã¯ãïŒâã€ãããŸãŒ
ã«ãïŒâããªãžã³ãïŒâããªãžã³ãïŒâããªãž
ã³ãïŒâããªãžã³ãïŒâã¡ãã«âïŒâããªãžã³ã
ãããªãžã³ããããŒã«ããŸãã¯ïŒâã¢ã«ããªã³åº
ãå®æããããã«å¿ èŠãªååãè¡šããã ç¹ã«æçšãªæåªå€ã¯æ¬¡åŒã§è¡šããããç¹°è¿åäœ
ãæããåªæå€ã§ããïŒ ããã«ãããŠã R5ãR6åã³R7ã¯åäžåã¯ç°çš®ã®ãã®ã§ããã
ããããïŒãã20å奜ãŸããã¯ïŒã10åã®ççŽ å
åãæããã¢ã«ãã«ãã·ã¯ãã¢ã«ãã«åã¯çœ®æã¢
ã«ãã«åºåã¯ïŒã20ã®ççŽ ååãæããã¢ãªãŒ
ã«ãã¢ã«ã«ãªãŒã«è¥ããã¯ã¢ã«ã¢ã«ãã«åºäŸãã°
ããšãã«ããã³ãžã«ãïœâã¡ãã«ãã³ãžã«çãè¡š
ããããŸãR5ãšR6åã¯R5ãR6åã³R7ã¯ããš
äžç·ã«ãªã€ãŠã€ãããŸãŒã«ãïŒâããªãžã³ãïŒâ
ããªãžã³ãïŒâããªãžã³ãïŒâããªãžã³ãïŒâã¡
ãã«âïŒâããªãžã³ããããªãžã³ããããŒã«ãŸã
ã¯ïŒâã¢ã«ããªã³åºã®ãããªè€çŽ ç°ãã€ããã®ã«
å¿ èŠãªååãè¡šããïŒ ïŒžã¯ãã©ã€ãã€ãªã³ïŒããšãã°ãã¯ãã©ã€
ãããããã€ãïŒããã€ãã¬ãŒããã¡ããµã«ããš
ãŒããïœâãã«ãšã³ã¹ã«ãããŒãã®ãããªé žã¢ã
ãªã³ã§ããã æ¬çºæã«æçšã§ããããšãããã€ãéåäœåªæ
å€çµæç©ã¯ãã¢ããªããŒåã¯ã³ããªããŒã§ããã
ãªãã§ãã³ããªããŒã¯ç¹ã«æå¹ã§ããããšããã
ã€ãã代衚çãªã³ããªããŒäžã«ã¯ãäžèšã®ïŒïŒ
åã¯ïŒïŒåŒã§è¡šããããç¹°è¿åäœãæããæŽã«
éé»å®³æ§ã¢ãããŒã®æ®åºãããªãå¥ã®ç¹°è¿åäœã
75ééïŒ ãŸã§å«ãéåäœåªæå€çµæç©ãå«ãŸã
ãããªãããéé»å®³æ§ãã¢ãããŒåã¯ç¹°è¿åäœã¯
ã¢ããªã³ç³»è²çŽ ã®åªæãååŠçã«ãåã¯ç©ççã«
é»å®³ããªãååŠåäœãããããã®ãããªéé»å®³æ§
ç¹°è¿åäœãäžããã¢ãããŒã«ã¯ãèèªæåã³è³éŠ
æã®çåæ°ŽçŽ ãäŸãã°ãªã¬ãã€ã³ã眮æãªã¬ãã€
ã³ãã¹ãã¬ã³åã³çœ®æã¹ãã¬ã³ïŒã¢ã«ãã«ã¢ã¯ãª
ã¬ãŒãåã³ã¡ã¿ã¯ãªã¬ãŒãåã³ãããã®èªå°äœïŒ
åã³ãã®ãããªã¢ãããŒãšå®è³ªäžåäžã®å ¬ç¥ç©è³ª
ããããæŽã«ãããå¿ èŠãªãã°ãæ¬çºæã«æçšãª
éåäœæåªå€çµæç©ã¯ããããæ¶æ©ãããããšã
ã§ããã®ã§ãåã ã®éåäœã®éã¯ãžããã«ãã³ãŒ
ã³ããžã¡ã¿ã¯ãªã¬ãŒãã®ãããªïŒå®èœæ¶æ©æ§åºã
æŽã«åçš®ã®å ¬ç¥ã®ïŒå®èœæ¶æ©æ§åºã«ããæ¶æ©åã
ããã代衚çã«ã¯ããããã®ãããªïŒå®èœæ¶æ©æ§
åºãååšãããšããã°ããããã®åºã¯ããã®ãã
ãªæ¶æ©ã³ããªããŒãã€ããã®ã«çšããããã¢ãã
ãŒã®å ±éåå¯èœãªãã¬ã³ãã«ååšããã¢ãããŒã®
å šééã«åºã¥ããŠãæ¬çºæã®éåäœåªæå€çµæç©
äžã«ïŒééïŒ ãŸã§ã®ç¯å²ã奜ãŸããã¯0.1ããïŒ
ééïŒ å«ãŸãããæ¬çºæã«ãããŠåªæå€çµæç©ãš
ããŠæçšãªä»£è¡šçãªã³ããªããŒã¯(a) äžèšïŒïŒ
åã¯ïŒïŒåŒãæããç¹°è¿åäœã®ã¢ãããŒã25ã
ã99ééïŒ ã(b) éé»å®³ç¹°è¿åäœã®ã¢ãããŒãïŒ
ãã75ééïŒ åã³(c) ããååšãããšããã°ãïŒ
å®èœæ¶æ©æ§å€ãïŒãã10ééïŒ å«æããåéäœã®
ãã¬ã³ãããå ±éåãããã æ¬çºæã«æçšãªéåäœã«ããªã³ç³»åªæå€çµæç©
ã®ä»£è¡šçãªãã®ã第ïŒè¡šã«ç€ºãããªãã«ãã³å ã¯
ã¢ã«æ¯ã§ããã 第 ïŒ è¡š M1 ããªïŒã¹ãã¬ã³âã³âïŒâãã¬ã€ãããã
ãã«âã»ïŒ®âãžã¡ãã«ââãã³ãžã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M2 ããªââã¢ãªã«âã»ïŒ®âãžã¡ãã«âã
ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M3 ããªââããã«ã€ãããŸãŒã«ïŒé žæµŽã§ã
ããã³åããããšã«ããªã³ã«ãªãïŒ M4 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«ã®
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M5 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M6 ããªïŒããã«ã¢ã»ããŒãããªãžããŠã ã¯
ãã©ã€ãïŒ M7 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«â
ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M8 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªãšãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M9 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââãããã«ã®
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M10 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãšãã¬
ã³ã°ãªã³ãŒã«ãžã¡ã¿ã¯ãªã¬ãŒãïŒïŒ93ïŒïŒïŒïœ M11 ããªïŒïŒ®âã¢ãªã«âã»ïŒ®âãžã¡ãã«âã
ãã«ãã³ãžã«ã¢ã³ã¢ããŠã ãããã€ãâã³â
ãžããã«ãã³ãŒã³ïŒïŒ95ïŒïŒïŒïœ M12 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«âãã³ãžã«ã¢ã³ã¢ããŠã
ãããã€ãâã³âãžããã«ãã³ãŒã³ïŒïŒ49ïŒ
49ïŒïŒïŒïœ M13 ããªïŒïŒ®âïŒâãããã«âã»ïŒ®âãžã¡ã
ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M14 ããªïŒã¹ãã¬ã³âã³ââã¢ãªã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M15 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããã«
ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒ
ïŒïŒïœ M16 ããªïŒã¹ãã¬ã³âã³ââãã³ãžã«âã»
âãžã¡ãã«ã¢ã¯ãªã«ã¢ãããããã«ã¢ã³ã¢ã
ãŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒ M17 ããªïŒïŒ®âãã³ãžã«âã»ïŒ®âãžã¡ãã«â
ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M18 ããªïŒã¹ãã¬ã³âã³ââããã«âã»ïŒ®
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M19 ããªïŒïŒâããã«ã€ãããŸãŒã«âã³âïŒâ
ããã«âïŒâãã³ãžã«âã€ãããŸãªãŠã ã¯ã
ã©ã€ãïŒïŒïŒïŒïŒïŒïœ M20 ããªïŒïŒã»ïŒâãžã¡ãã«âïŒâããã«ããª
ãžãŠã âïœâãã«ãšã³ã¹ã«ãããŒãïŒ M21 ããªïŒïŒâãã³ãžã«âïŒâããã«ããªãžã
ãŠã ã¯ãã©ã€ãïŒ M22 ããªïŒïŒâãã³ãžã«âïŒâã¡ãã«âïŒâã
ãã«ããªãžããŠã ã¯ãã©ã€ãïŒ M23 ããªïŒïŒ®âã«ã«ãã¢ã€ã«ã¡ãã«âã»ïŒ®â
ãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ã
ã©ã€ãïŒ M24 ããªïŒïŒ®âã·ã¯ãããã·ã«âã»ïŒ®âãžã¡
ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ M25 ããªãã»ïŒ®âãžã¡ãã«ââïŒïŒâã¡ã
ã«âïŒâãããã«ïŒâããã«ãã³ãžã«ã¢ã³ã¢ã
ãŠã ã¯ãã©ã€ãã M26 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã¡
ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒïŒïŒïŒïŒïŒïœ M27 ããªïŒïŒ®âã€ãœããã«âã»ïŒ®âãžã¡ãã«
âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M28 ããªãâãã³ãžã«âã»ïŒ®âãžã¡ãã«â
ïŒïŒâã¢ã¯ãªã«ã¢ããâïŒã»ïŒâãžã¡ãã«âã
ããã«ïŒâã¢ã³ã¢ããŠã ã¯ãã©ã€ãã M29 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âããã«ã
ã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M30 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®âãã³ãžã«â
ã»ïŒ®âãžã¡ãã«âïŒâããã«ãã³ãžã«ã¢ã³ã¢
ããŠã ã¯ãã©ã€ãïŒïŒïŒïŒïŒïŒïœ M31 ããªïŒïŒ°ã»ïŒ°ã»ïŒ°âããªãªã¯ãã«ããã«ã
ã³ãžã«ãã¹ãã㊠ã¯ãã©ã€ãïŒ M32 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã
ãã·ã« ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©
ã€ãïŒïŒïŒïŒïŒïŒïœ M33 ããªïŒã¹ãã¬ã³âã³âã»ïŒ®ã»ïŒ®âããªã¡
ãã« ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒïŒïŒïŒïŒïŒïœ M34 ããªïŒã¹ãã¬ã³âã³ââãã³ãžã«âã»
âãžã¡ãã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã â
ã³âãžããã«ãã³ãŒã³ïŒïŒ49.5ïŒ49.5ïŒïŒïŒïœ M35 ããªïŒïŒ®âããã«ãã³ãžã«ãããªãžããŠã
ã¯ãã©ã€ãïŒ M36 ããªïŒïŒ®ã»ïŒ®ã»ïŒ®âããªã¡ãã«âïŒâãã
ã«ããšãã«ã«ã«ãã¢ã€ã«ã¡ãã«ã¢ã³ã¢ããŠã
ã¯ãã©ã€ãïŒ M37 ããªïŒïŒ®âã¢ã»ããã«âã»ïŒ®âãžã¡ãã«
âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M38 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââã¡ããã·ã«
ã«ããã«ã¡ãã«âããã«ãã³ãžã«âã¢ã³ã¢ããŠ
ã ã¯ãã©ã€ãïŒ M39 ããªïŒããã«ãã³ãžã«âïŒâããªãžããŠã
ã¯ãã©ã€ãïŒ M40 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã
ããªãžããŠã ã¯ãã©ã€ãïŒ M41 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã
ããªãžããŠã ã¯ãã©ã€ãïŒ M42 ããªïŒïŒ®âã¡ãã«ââããã«ãã³ãžã«ã¢
ã«ããªããŠã ã¯ãã©ã€ãïŒ M43 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââããã«ãã³
ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ M44 ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«ââã·ã¯ããã
ã·ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€
ãïŒ æ¬çºæã«æçšãªåªæå€çµæç©ã¯ããç¥ãããŠã
ãååŠåå¿ãçšããŠã€ããããšãã§ããããã®ã
ããªååŠåå¿ã¯åçåéã«ãããŠãããšåãç©è³ª
åã¯ããã«äŒŒãç©è³ªã®äœ¿çšã«çµã³ã€ããŠæ¢ã«è©³çŽ°
ã«èšèŒãããŠãããåŸã€ãŠãæ¬çºæã«çšããåçš®
ã®åªæå€ç©è³ªã補é ãã詳现ãªèª¬æã¯å¿ èŠã§ãª
ããããããªããããããã®ãããªç©è³ªãã€ãã
詳现ãªèª¬æãç¥ããããšãã«ã¯æ¬¡ã®ç¹èš±ãåç §ã
ãããïŒè±åœç¹èš±ç¬¬1261925å·ïŒç±³åœç¹èš±ç¬¬
3488706å·ïŒå第3557066å·ïŒå第3625694å·ïŒå
第3709690å·ïŒå第3770439å·ïŒå第3758445å·ïŒ
å第3773509å·ïŒå第3859096å·ïŒå第3898088
å·ïŒå第3944424å·ïŒåã³å第3958995å·ã åªæå€ãšãžã¢ãŸæš¹èã®çžå¯Ÿéã¯æå®ã®ç®çãšã
ãçšéãšåæ§ååéãšåªæå€ã®åªæåã«ããç°ãª
ããåªæå€ã®ååéãããŸãåªæåã倧ãããª
ãã°ãªãã»ã©ãã®éãå°ãªãçšããããšãã§ã
ããããã«ãã»ãšãã©ãã¹ãŠã®ãžã¢ãŸæš¹èã¯çŒåº
ããæ±ããçè²ãããã®ã§ãçšããããæš¹èã®é
ã¯äœ¿çšçšéã«èš±ãããäžé£œå床ã®éã«ããçšäŸå
ããã ã«ã©ãŒãã«ãŒãã€ã³ã°ã«çšããã«ã¯ããžã¢ãŸæš¹
èã¯0.16ã0.10mg/dm2ã®å¡åžéã奜ãŸããããŸã
åªæå€ã¯0.5ã5.0mg/dm2ã奜ãŸãããç¹ã«å¥œãŸã
ãåªæå€ã®éã¯1.0ã1.5mg/dm2ã§ããã æ¬çºæã®çµæç©ã®å¡åžç©ãèªå·±æ¯ææ§ã§ãªãå Ž
åã«ã¯æ¯æäœãçšãããããã®æ¯æäœäžã«çµæç©
ãå¡åžãããã åŸæ¥ããçšããããŠããåççšæ¯æäœãæ¬çºæ
ã®å®æœã®éã«çšããããã代衚çãªæ¯æäœã«ã¯äž
éæãªæ¯æäœãäŸãã°éå±ãåççšçŽæ¯æäœãšå
æ§éæãªæ¯æäœãäŸãã°ãã€ã«ã æ¯æäœãã¬ã©ã¹
æ¯æäœãå«ãŸããããã®æ¯æäœã¯ç¡¬è³ªã®ãã®ã§
ãããŸãè»è³ªã®ãã®ã§ããããããæ®éã«çšãã
ããŠããæãäžè¬çãªåççšæ¯æäœã¯çŽæ¯æäœ
ïŒäœããã€ãæ¶ãä»äžãããããã®ãå«ãïŒãšé
æãªãã€ã«ã æ¯æäœãäŸãã°ããªïŒãšãã¬ã³ãã¬
ãã¿ã¬ãŒãïŒãã€ã«ã ãã§ãããé©åœãªæ¯æäœã®
代衚çãªãã®ã¯è±åœã®ããŒãã³ãã»ãã³ãã·ã€ãŒ
ããŒ091ã€ãŒãšãã»ããŒã ãŠãšã«ïŒHavant
Hampsnire  091 EF HomwellïŒã®ã€ã³ãã¹
ããªã¢ã«ã»ãªãããŠããã€ãŒãºã»ãªãããã
ïŒIndnstrial Opportunwities LimiteolïŒããçºè¡
ãããŠãããããã¯ãã»ã©ã€ã»ã³ã·ã³ã°ã»ã€ã³ã
ãã¯ã¹ïŒProduct Licensing IndexïŒã92å·»ã
1971幎12æå·ã9232å·ã«èšèŒãããŠããããã®æ¯
æäœã¯ããã«å¯Ÿããæå æ§å¡åžç©ã®æ¥çæ§ããã
ããããã«ãã®æ¯æäœã®è¡šé¢ã®æ§è³ªãå€ããç®ç
ã§ïŒå±€åã¯æ°å±€ã®äžå¡å±€ãä»åšãããããšãã§ã
ãã代衚çã«ã¯ãå転å¡åžæ³ããã©ã·å¡åžæ³ãã
ã¯ã¿ãŒãã¬ãŒãå¡åžæ³ãåã¯ããããŒå¡åžæ³çã®
æ段ãçšããŠæ°Žæº¶æ¶²ãæ¯æäœäžã«å¡åžããŠããã
ã®å¡åžç©ã也ç¥ããã代衚çãªå¡åžæ³ã®ä»ã®äŸã«
ã€ããŠã¯ãäžèšã®ãããã¯ãã»ã©ã€ã»ã³ã·ã³ã°ã»
ã€ã³ããã¯ã¹ïŒProduct Licensing IndexïŒ92
å·»ã1971幎12æã9232å·ã®109é ã«èšèŒãããŠã
ãããŸãå¡åžå©å€ããã®å¡åžçµæç©ã«å ¥ããããš
ãã§ããã è²çŽ ã®æ·»å äžã«èŠçŽ ãæ¿ããæ¹æããªããã°ãª
ããªãå Žåã¯èŠçŽ ãããã«ç¡¬ãããããšãæãŸã
ãããã®ãããªç¡¬ãã¯ãžã¢ãŸæš¹èäžãäžå¡å±€ã«ä»¥
äžã«èšèŒãããããã«ããªïŒããã«ãããªãã³ïŒ
ã®ãããªããã«ããªããŒãå ¥ããããšã«ããåŸã
ããã äžèšã®ããã«ããŠã€ããããèŠçŽ ã¯ããŸãåã
ã«æ åçã«é²å ãããã€ãã§ã¢ããªã³è²çŽ ãå«ãŸ
ããŠããè²çŽ 济ã«æµžãåã«çŸåãããããžã¢ãŸæš¹
èãæå ãã掻æ§èŒ»å°ç·ã«å¯Ÿããé²å ã¯ã©ã®ãã
ãªåœ¢åŒã®ãã®ã§ãçšããããšãã§ããããã®ãã
ãªæš¹èã¯çŽ«å€ç·ã«äž»ãšããŠæå ããã®ã§ã玫å€ç·
ã«å¯ãå æºã奜ãŸããããã®ãããªç¹æ§ãæãã
åŸæ¥ããçšããããŠããå æºã¯å®¹æã«å©çšããã
ãšãã§ããã é²å æ¹åŒã¯çšããããèŠçŽ ã«ããç°ãªãããã«
ã©ãŒãã«ãŒãã€ã³ã°ãªãŒãã¬ã€èŠçŽ ã«ã¯éåžžã®å¯
çé²å ãããããŠäŸ¿å©ã§ããã é²å ãçµã€ããããã®èŠçŽ ã®å¡åžç©ã®é²å ãã
ãªãã€ãéšåãæŽãèœãšãããããèœããŠãã®èŠ
çŽ ãçŸåãããæš¹èå¡åžç©ã®å ã«ãã硬åããéš
åã ããé²å éã«æ¯äŸããŠæ®ããåŸã€ãŠãæ®ã€ãŠ
ããåªæå€ã®éã¯é²å éã«æ£æ¯äŸããŠååšããã
æŽæ¶²ã¯éåžžã®æ°Žéæ°ŽãããªãããããŠãã®ãã®ã
éããªåŽé§ç¶ã«ããŠãåã¯èå£ããã®æµæ°Žã«ãŠæŽ
ãèœãšãããšãã§ããããŸãããã®æ°ŽæŽã¯æ°Žäžã«
ã²ãããããçš®ã®ææãšæ©æ¢°çã«ããã€ãŠè¡ãªã
ããšãã§ãããæ°ŽæŽæéã«ã¯äœãå¶éããªããã
ïŒç§ããïŒåã®ç¯å²ã®æéãå¹æçã§ããã 次ã«ããã®çŸåãããèŠçŽ ç¹ã«å ã«ãã硬åã
ãåªæå€æš¹èå¡åžç©ã¯ãã®èŠçŽ ãé©åœãªè²çŽ 济ã«
浞ããŠã¢ããªã³ç³»è²çŽ ãå ããããããã®è²çŽ ã¯
äžèšå¡åžç©å ã§äžååããããè²çŽ 济ã¯ä»¥äžã«è©³
现ã«èšèŒãããåã®è²çŽ ã®æ°Žæº¶æ¶²ãç·©è¡æ°Žæº¶æ¶²ã§
ããã浞挬æéãšæµŽã®æž©åºŠã¯åºç¯å²ã«å€æŽå¯èœã§
ãããã10ã100ç§ã奜ãŸããããŸã枩床ã¯10ã
40âã奜ãŸããã次ã«ãã®èŠçŽ ãååºããå¿ èŠã«
ããéå°ã®è²çŽ ãé€ãããã«ãããã次ãã§å ç±
ããŠåã¯å ç±ããã«ä¹Ÿç¥ããããªãããããå·¥çš
ã¯çŸåå·¥çšãšå šãåãã«åãæéã®ç¯å²ã§è¡ãªã
ããšãã§ããããŸããæ°Žã«ããåŠçå·¥çšã®ãã¹ãŠ
ãè²çŽ 济ã«ã€ããŠäžè¿°ããã®ãšåã枩床ç¯å²ã§è¡
ãªãããšãã§ããã ã€ã³ããã·ãšã³ïŒimbibitionïŒã«ããèŠçŽ ã«å¯
èŠåãã€ããããã«ã©ã®ãããªã¢ããªã³ç³»è²çŽ ã
çšããããšãã§ããããã®è²çŽ ã®éžæã¯ããã¡ã
ããæå®ã®è²ãæçµçšéã«ããå·Šå³ããããäŸã
ã°ããã©ãã¯ã»ããªã³ã¿ãŒã»ãªãŒãã¬ã€ã«ã¯ãã©
ãã¯è²çŽ ãçšãããããè€åã«ã©ãŒã»ãã«ãŒãã€
ã³ã°ã»ãªãŒãã¬ã€ã圢æããéã®è²å解ããžã«ã¯
åè²ã®ã·ã¢ã³ãããŒã³ã¿åã³ã€ãšããŒãéžã°ã
ããæ¬çºæã«çšããç¹ã«å¥œãŸããçš®é¡ã®ããŒã³ã¿
è²çŽ ã¯æ¬¡åŒã§ç€ºãããæ§é åŒããã€ããã®ãããª
ãïŒ ããã«ãããŠãR8ãšR9ã¯äžèšã«ç€ºããããã
ãªé»ååžåŒæ§ã®åºã§ããïŒ SO2CH2CH2CO2H4ã¹ã«ãã¢ã¢ã€ã«ãã«ã«ãã
ã·ã«ãSO3HãSO2CH3ãïŒãïŒåã®ççŽ ååã®
ã¢ã«ãã«ã
ãåŒãâSO2CH
ïŒCH3ïŒ2ãâSO2CF3SO2NHCH2CO2Hãããã²ã³ã
SO2NHCïŒCH3ïŒ3ãSO2NHCH3ãSO2N
ïŒC2H5ïŒ2ãSO2NïŒCH3ïŒ2ã
SO2NHCïŒCH3ïŒ3ãSO2NHCH3ãSO2N
ïŒC2H5ïŒ2ãSO2NïŒCH3ïŒ2ã
ãåŒãå
ã³
ãåŒã
R10ã¯ïŒãïŒåã®ççŽ ååã®ã¢ã«ãã«ã
ãåŒã
ãåŒãåã¯
ãåŒã
ã§ãããåã³
R11ã¯ããããæ°ŽçŽ åã¯ãã©ã€ãã§ããã
ã·ã¢ã³è²çŽ ã®ãã¡ã§ç¹ã«å¥œãŸããçš®é¡ã®ãã®
ã¯ãR11ãïœâãããã§ãR8ãR9åã³R10ãäžèš
ã«ç€ºãããã®ã§ããè²çŽ ã§ããã ããã«æçšãªããŒã³ã¿è²çŽ ã¯ã¢ã·ããã¯ã·ã³ã
ã«ã©ãŒã€ã³ããã¯ã¹1740ã§ãããç¹ã«æçšãªé»è²
è²çŽ ã¯æ¬¡åŒïŒïŒåã¯ïŒïŒã§ç€ºãããæ§é åŒã
æããè²çŽ ã§ããïŒ ããã«ãããŠã R12ã¯SO2âNHCH2CO2HãSO3HãSO2NH2ã
ããã²ã³ãã«ã«ããã·ã«ãSO2Hã CONHCH2COOHã§ããïŒ R13ã¯ïŒãïŒåã®ççŽ ååãæããã¢ã«ã³ã
ã·ãæ°ŽçŽ ãããã²ã³åã¯ã«ã«ããã·ã§ããïŒ R14ã¯æ°ŽçŽ ãããããã·ãïŒãïŒåã®ççŽ åå
ãæããã¢ã«ãã«ïŒäŸãã°ã¡ãã«ããšãã«ãã€ãœ
ãããã«åã³ïœâãããã«ïŒãã·ã¢ããã«ã«ãã
ã·ã«ãã«ã«ãã³ã¢ãããåã¯ã«ã«ãã¢ã€ã«ã§ã
ãã R15ã¯
ã¯ãR11ãïœâãããã§ãR8ãR9åã³R10ãäžèš
ã«ç€ºãããã®ã§ããè²çŽ ã§ããã ããã«æçšãªããŒã³ã¿è²çŽ ã¯ã¢ã·ããã¯ã·ã³ã
ã«ã©ãŒã€ã³ããã¯ã¹1740ã§ãããç¹ã«æçšãªé»è²
è²çŽ ã¯æ¬¡åŒïŒïŒåã¯ïŒïŒã§ç€ºãããæ§é åŒã
æããè²çŽ ã§ããïŒ ããã«ãããŠã R12ã¯SO2âNHCH2CO2HãSO3HãSO2NH2ã
ããã²ã³ãã«ã«ããã·ã«ãSO2Hã CONHCH2COOHã§ããïŒ R13ã¯ïŒãïŒåã®ççŽ ååãæããã¢ã«ã³ã
ã·ãæ°ŽçŽ ãããã²ã³åã¯ã«ã«ããã·ã§ããïŒ R14ã¯æ°ŽçŽ ãããããã·ãïŒãïŒåã®ççŽ åå
ãæããã¢ã«ãã«ïŒäŸãã°ã¡ãã«ããšãã«ãã€ãœ
ãããã«åã³ïœâãããã«ïŒãã·ã¢ããã«ã«ãã
ã·ã«ãã«ã«ãã³ã¢ãããåã¯ã«ã«ãã¢ã€ã«ã§ã
ãã R15ã¯
ãåŒãïŒäœããR16ã¯SO3Hã
CO2Hãã¯ãã©ã€ãåã¯æ°ŽçŽ ã§ããïŒã§ããïŒ
ããã«ãããŠã
R17ã¯ïŒããçŽïŒåã®ççŽ ååãæããã¢ã«ã
ã«ã§ããã R18ã¯C2H4SO3HãïŒããçŽïŒåã®ççŽ ååã
æããã¢ã«ãã«åã¯C2H4NHSO2CH3ã§ããã 第ïŒè¡šã«äžèšã®çš®é¡ã«å±ããè²çŽ ã®ä»£è¡šçãªã
ã®ã瀺ãã
ã«ã§ããã R18ã¯C2H4SO3HãïŒããçŽïŒåã®ççŽ ååã
æããã¢ã«ãã«åã¯C2H4NHSO2CH3ã§ããã 第ïŒè¡šã«äžèšã®çš®é¡ã«å±ããè²çŽ ã®ä»£è¡šçãªã
ã®ã瀺ãã
ãè¡šã
ãè¡šã
äžèšã®è²çŽ ã¯ãã¹ãŠéåžžè¡ãªãããŠããåææ³
ã«ããã€ããããšãã§ããã è²çŽ 济ã®æ¿åºŠã¯åºãç¯å²ã«ããã€ãŠå€ããããš
ãã§ããè²çŽ ã®åžå ä¿æ°ã«ããçšåºŠäŸåããã奜
ãŸããæ¿åºŠã¯æº¶æ¶²ã®0.1ééããŒã»ã³ããã2.0é
éããŒã»ã³ãã§ãããæ¢ã«è¿°ã¹ãããã«ããã®æº¶
å€ã¯æ°Žããåã¯åé¡ã®è²çŽ ã«é©ããPHã«ç·©è¡ãã
æ°ŽïŒäŸãã°ã·ã¢ã³ãããŒã³ã¿åã¯é»è²è²çŽ ã®ãã
ãã®ã«ã¯PHãçŽ8.0ã«ããããã«ååãªãªã³é žã«
ãªãŠã âæ°Žé žåãããªãŠã ãçšããããããŸãåª
æå€ã第ïŒè¡šã®M3ã ãšPHãïŒã«ããããã«é žã
çšãããããïŒã§ããã ãã®ããã«ããŠã€ãã€ãèŠçŽ ã¯æçµç»åãå«ã
ã§ãããç¹ã«è£è²ã®ïŒè²å解ããžãéæãªæ¯æäœ
äžã«ãã®ããã«åœ¢æããããšãã¯ããã®èŠçŽ ã¯ã«
ã©ãŒãã«ãŒããã€ããåºãçœè²ããã¯ã°ã©ãŠã³ã
äžã«éããããã 次ã«è»¢åæ³ã«ã€ããŠè¿°ã¹ãã è²çŽ ç»åãäžèšã®ãã«ãŒãã€ã³ã°èŠçŽ ïŒãã®èŠ
çŽ ã¯ã»ã³ããŒå±€ãšããŠåãïŒããååèŠçŽ ã«è»¢å
ãããããšãã§ããããªãããã®ååèŠçŽ ã¯å¥œãŸ
ããã¯æ¯æäœãšååå±€ãããªããååå±€ã«ã¯ã»ã³
ããŒå±€ã®åªæå€ã®åªæåããã倧ããªåªæåãæ
ããã«ããªã³ç³»åªæå€ãå«ãŸããŠããããã®ãã
ãªçžå¯Ÿçãªåªæåã¯éåžžã®ç«¶äºåªæå€è©ŠéšïŒäŸã
ã°1976幎ïŒæ25æ¥çºè¡ã®ç±³åœç¹èš±ç¬¬3958995å·ã«
èšèŒãããŠããïŒã«ãã容æã«æ±ãããããäžèš
ã®ããã«ããŠã€ãã€ãã·ã¢ã³ãããŒã³ã¿åã³ã€ãš
ããŒã®å解ããžãããããæ£ç¢ºã«äžèŽãããŠåäž
ååèŠçŽ ã«è»¢åãããããšã«ããå®å šãªã«ã©ãŒã
ã«ãŒããåŸãããšãã§ããã ååå±€ã¯ç¬¬ïŒè¡šã®éåäœåªæå€ã®ãã¡ã®äžã€ã
å«ã¿ããã®åªæå€ã¯ã»ã³ããŒå±€ã®åªæå€ããåªæ
æ§ã倧ãããæŽã«ãã®ååå±€ã¯ãå¿ èŠã«ãããŒã©
ãã³ã®ãããªãã€ã³ããŒãå«ãã§ããããŸããã«
ã ã¢ã«ããããšããã¹ïŒããã«ã¹ã«ããã«ã¡ã
ã«ïŒãšãŒãã«ã®ãããªéåžžã®ç¡¬èå€ããã®ãŒã©ã
ã³ãšäžç·ã«çšããããšãã§ãããååå±€ã«çšãã
ããåªæå€ãšãã€ã³ããŒã®éã«ã¯å¶éããªãåªæ
å€ã«ã€ããŠã¯5.0ãš50mg/dm2ã®éããŸããã€ã³ã
ãŒã«ã€ããŠã¯ïŒãš60mg/dm2ã®éã§çšããããšã
ã§ããããããã€ã³ããŒã䜿ããªããªãã°ããå€
éã®åªæå€ãçšããŠããããç¹ã«å¥œãŸããååå±€
ã¯åªæå€ã10ã30mg/dm2ããŒã©ãã³ã30ã50mg/
ïœm2ãããªããããã«ãã«ã ã¢ã«ããã硬èå€ã
å«ãååå±€ã§ããã ããååå±€ãããèªäœæ¯æäœãšãªããªãå Žåã¯
ã»ã³ããŒå±€ã«ã€ããŠäžè¿°ããæ¯æäœã®ãã¡ã®ã©ã
ã§ãçšããããšãã§ããã ãã®è²çŽ ã®è»¢åã¯å¡©æº¶æ¶²ããã¢ã«ã³ãŒã«ãšæ°Žã®
æ··å溶液ã®ååšäžã§æãããèµ·ããã®ã§ããã®è»¢
åãããããããã«ã»ã³ããŒå±€ãšååå±€ã®ãã¡ã®
ããããäžæ¹åã¯åæ¹ãåãã€ãŠãã®ãããªæº¶æ¶²
ã«äžå®ã®æéïŒãã®æéã«ã¯å¶éããªãã10ãã
100ç§ã®ç¯å²ã§ããïŒæµžããŠããã®ã奜ãŸããã
ãšãå€ã€ããã€ãã§ãã®ïŒã€ã®å±€ããäŸãã°ã©ã
ããŒãã®ç¶æ ã«ããŠå§åããŒã«éã«ïŒç§ãã100
ç§ééããŠæŒå§ããããªããã®å§åããŒã©éã«é
ãæéã¯çžå¯Ÿçãªåªæåã«ããç°ãªããåªæå€å
å¿ã®åªæåã極端ã«éãå Žååã¯éåžžã«äŒŒãŠãã
å Žåã«ã¯ããã®ç¯å²å€ã®ç§»éæéãé©ããŠããã
次ãã§ïŒå±€ãåé¢ããã ãŸããã®ååå±€ã¯ãã®äžã«ç§»åæ§ã®å¡©ãå ¥ããŠ
ã€ããããšãã§ããããŸãã»ã³ããŒå±€ã¯ãããæ°Ž
ã«çæé浞ããŠããçšããããã 転åã®ç®çã§éžã°ãã塩溶液ã¯äž»ã«åªæããã
è²çŽ ã®æº¶è§£åºŠã«äŸåããããã®æº¶æ¶²ã«çšãããã
ç¹ã«å¥œãŸããå¡©ã«å¡©åã«ãªãŠã ãèåã«ãªãŠã ã
æ²åã«ãªãŠã ããµãªãã«é žãããªãŠã åã³ããªã·
ã¢ããŒãã§ããããã®ãããªæº¶æ¶²äžã®å¡©ã®æ¿åºŠã¯
çŽ0.1MããçŽ1.0Mã®ç¯å²ã«ããããã®ãã¡KIå
ã¯KBrã¯ãäžèšæ¿åºŠã®ç¯å²å ã§äœæ¿åºŠã§çšããŠã
é®®æãªç»åãçããããšã泚ç®ãããã 転åæ³ã«æçšãªã¢ã«ã³ãŒã«ãšæ°Žãšã®æº¶æ¶²ã¯ã¢ã«
ã³ãŒã«ãæ°Žã®äœç©ã®ïŒããïŒåã®äœç©ã§ååšãã
æ··å液ãããªããæçšãªã¢ã«ã³ãŒã«ã®ä»£è¡šçãªã
ã®ã¯ã¡ã¿ããŒã«ããšã¿ããŒã«åã³ã€ãœãããããŒ
ã«ã§ããã ãã®ãããªè»¢ååŸã«ã»ã³ããŒå±€ãè²çŽ 济ã«åã³
浞ããŠãã®å±€ãåã³æè²ããããšããŸãå¯èœã§ã
ãã å®æœäŸ 次ã«ä»£è¡šçãªå®æœäŸãèšèŒããŠæ¬çºæãæŽã«è©³
现ã«èª¬æããã å®æœäŸ ïŒ æ¬¡ã®ããã«ããŠã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ãã€
ãã€ãã 100ãã¯ãã³ã®åã¿ã®äžå¡ããªãšã¹ãã«æ¯æäœ
ã«ã0.8mg/dm2ã®ãžã¢ãŸæš¹èãNo.4ã¿ã€ãââã
ãã«ã ã¢ã«ããããšïœâãžã¢ãŸããšãã«ã¢ãã³ãš
ã®çž®åã«ãã€ãŠã€ããããã¯ãããžã³ã±ãŒãå¡©ã
ãšã¢ããŠã³ãNo.4ãã¿ã€ããããšã¢ããŠã³ã
ã±ãã«ã«ç€ŸïŒFairmount Chemical Co.ïŒãã
äŸçµŠããããïŒ0.2mg/dm2ã®ãªã³é žïŒå®å®å
å€ïŒïŒ3.5mg/dm2ã®éåäœåªæå€ãM1ããªã¹ãã¬
ã³âã³âïŒâãã¬ã€ãããããã«âã»ïŒ®âãžã¡
ãã«ââãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ
ïŒïŒïŒïŒïŒïœïŒåã³0.3mg/dm2ã®ãªãªã³ã»ãµãã¢ã¯
ã¿ã³ãïŒOlin SurfactantïŒ10Gããªãªã³ã»ã±ãã«
ã«ç€ŸïŒOlin Chemical Co.ïŒãã補é ãããŠãã
ããã«ããšããã·ããªã°ãªã»ããŒã«ããããªãå±€
ãå¡åžããã äžèšã®å¡åžç©ã®ãµã³ãã«ãã¡ããœã¿å·ãããã¢
ããªã¹ã®ã³ã©ã€ãã»ã€ã³ã³ãŒãã¬ã€ããã
ïŒColight IncorporatedïŒã«ãã補é ãããã³ã©
ã€ãïŒColightïŒã¢ãã«ïŒâ99æ°Žéèžæ°ã©ã³ãã
ãã®å ã«ã30ç§éã0.15ãã€æ¿åºŠãå¢å ããã¹ã
ããã»ã¿ãã¬ãããéããŠå¯çé²å ããã ãã®ãµã³ãã«ã21âã®æ°Žãçšã10ç§éåŽé§æŽé€
ïŒã¹ãã¬ã€ã»ãŠãªã·ãŠïŒããŠãããã¢ãããã¯ã·
ã³ïŒAcid FuchsinïŒè²çŽ ã®0.4ïŒ æ°Žæº¶æ¶²ã«30ç§é
浞ããã€ãã§21âã®æ°Žã§20ç§éãããã ããã®èŠ
çŽ ãçœè²ã®ããªã³ãçŽã®ã·ãŒãã®äžã«çœ®ãããšã
ã«è¯å¥œãªæ¿åºŠã®é£ç¶é調ããŒã³ã¿ç»åãçããã
ç·è²ãã€ã«ã¿ãŒãéããŠæž¬å®ãããæ¿åºŠãšã¬ã³ã
ãŒã¯æ¬¡ã®éãã§ãã€ãïŒïŒ€naxïŒ2.10ãnioïŒ
0.18ãγïŒ2.40ãåŽé§æŽé€ïŒã¹ãã¬ã€ã»ãŠãªã·
ãŠïŒã浞挬åã³ãããã®ä»å·¥çšã«ãããæéãšæž©
床ã®æ¡ä»¶ãå€ããŠåæ§ã®å¡åžç©ãåŠçãããšãã
ããããåŠçå¯å®¹åºŠã芳å¯ããããäŸãã°è²çŽ 济
ã®æµžæŒ¬æéã15ç§ãã90ç§ã«å€ããŠãã»ã³ã·ãã¡
ããªãŒã«å®è³ªçãªå·®ãçããªãã€ãããã®ããšã¯
è²çŽ 济ã®æž©åºŠã16âãã32âã«å€ããŠãåãã§ã
ã€ãã å®æœäŸ ïŒ åªæå€ã第ïŒè¡šã®M2ã®ããªïŒïŒ®ã»ïŒ®âãžã¡ã
ã«ââã¢ãªã«ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒã§ãã€ã以å€ã¯å®æœäŸïŒãšåãã«ã©ãŒ
ãã«ãŒãã€ã³ã°èŠçŽ ã®ãµã³ãã«ãã€ãã€ããããŒ
ãããŒã³ã®èµ€è²ãç·è²åã³éè²ã®å解ãã¬ã«é²å
åŸããããã®ãµã³ãã«ãå®æœäŸïŒã«èšèŒããæ¡ä»¶
äžã§åŠçãããçšããããããããã®è²çŽ 溶液ã¯
次ã®éãã§ãã€ãã
ã«ããã€ããããšãã§ããã è²çŽ 济ã®æ¿åºŠã¯åºãç¯å²ã«ããã€ãŠå€ããããš
ãã§ããè²çŽ ã®åžå ä¿æ°ã«ããçšåºŠäŸåããã奜
ãŸããæ¿åºŠã¯æº¶æ¶²ã®0.1ééããŒã»ã³ããã2.0é
éããŒã»ã³ãã§ãããæ¢ã«è¿°ã¹ãããã«ããã®æº¶
å€ã¯æ°Žããåã¯åé¡ã®è²çŽ ã«é©ããPHã«ç·©è¡ãã
æ°ŽïŒäŸãã°ã·ã¢ã³ãããŒã³ã¿åã¯é»è²è²çŽ ã®ãã
ãã®ã«ã¯PHãçŽ8.0ã«ããããã«ååãªãªã³é žã«
ãªãŠã âæ°Žé žåãããªãŠã ãçšããããããŸãåª
æå€ã第ïŒè¡šã®M3ã ãšPHãïŒã«ããããã«é žã
çšãããããïŒã§ããã ãã®ããã«ããŠã€ãã€ãèŠçŽ ã¯æçµç»åãå«ã
ã§ãããç¹ã«è£è²ã®ïŒè²å解ããžãéæãªæ¯æäœ
äžã«ãã®ããã«åœ¢æããããšãã¯ããã®èŠçŽ ã¯ã«
ã©ãŒãã«ãŒããã€ããåºãçœè²ããã¯ã°ã©ãŠã³ã
äžã«éããããã 次ã«è»¢åæ³ã«ã€ããŠè¿°ã¹ãã è²çŽ ç»åãäžèšã®ãã«ãŒãã€ã³ã°èŠçŽ ïŒãã®èŠ
çŽ ã¯ã»ã³ããŒå±€ãšããŠåãïŒããååèŠçŽ ã«è»¢å
ãããããšãã§ããããªãããã®ååèŠçŽ ã¯å¥œãŸ
ããã¯æ¯æäœãšååå±€ãããªããååå±€ã«ã¯ã»ã³
ããŒå±€ã®åªæå€ã®åªæåããã倧ããªåªæåãæ
ããã«ããªã³ç³»åªæå€ãå«ãŸããŠããããã®ãã
ãªçžå¯Ÿçãªåªæåã¯éåžžã®ç«¶äºåªæå€è©ŠéšïŒäŸã
ã°1976幎ïŒæ25æ¥çºè¡ã®ç±³åœç¹èš±ç¬¬3958995å·ã«
èšèŒãããŠããïŒã«ãã容æã«æ±ãããããäžèš
ã®ããã«ããŠã€ãã€ãã·ã¢ã³ãããŒã³ã¿åã³ã€ãš
ããŒã®å解ããžãããããæ£ç¢ºã«äžèŽãããŠåäž
ååèŠçŽ ã«è»¢åãããããšã«ããå®å šãªã«ã©ãŒã
ã«ãŒããåŸãããšãã§ããã ååå±€ã¯ç¬¬ïŒè¡šã®éåäœåªæå€ã®ãã¡ã®äžã€ã
å«ã¿ããã®åªæå€ã¯ã»ã³ããŒå±€ã®åªæå€ããåªæ
æ§ã倧ãããæŽã«ãã®ååå±€ã¯ãå¿ èŠã«ãããŒã©
ãã³ã®ãããªãã€ã³ããŒãå«ãã§ããããŸããã«
ã ã¢ã«ããããšããã¹ïŒããã«ã¹ã«ããã«ã¡ã
ã«ïŒãšãŒãã«ã®ãããªéåžžã®ç¡¬èå€ããã®ãŒã©ã
ã³ãšäžç·ã«çšããããšãã§ãããååå±€ã«çšãã
ããåªæå€ãšãã€ã³ããŒã®éã«ã¯å¶éããªãåªæ
å€ã«ã€ããŠã¯5.0ãš50mg/dm2ã®éããŸããã€ã³ã
ãŒã«ã€ããŠã¯ïŒãš60mg/dm2ã®éã§çšããããšã
ã§ããããããã€ã³ããŒã䜿ããªããªãã°ããå€
éã®åªæå€ãçšããŠããããç¹ã«å¥œãŸããååå±€
ã¯åªæå€ã10ã30mg/dm2ããŒã©ãã³ã30ã50mg/
ïœm2ãããªããããã«ãã«ã ã¢ã«ããã硬èå€ã
å«ãååå±€ã§ããã ããååå±€ãããèªäœæ¯æäœãšãªããªãå Žåã¯
ã»ã³ããŒå±€ã«ã€ããŠäžè¿°ããæ¯æäœã®ãã¡ã®ã©ã
ã§ãçšããããšãã§ããã ãã®è²çŽ ã®è»¢åã¯å¡©æº¶æ¶²ããã¢ã«ã³ãŒã«ãšæ°Žã®
æ··å溶液ã®ååšäžã§æãããèµ·ããã®ã§ããã®è»¢
åãããããããã«ã»ã³ããŒå±€ãšååå±€ã®ãã¡ã®
ããããäžæ¹åã¯åæ¹ãåãã€ãŠãã®ãããªæº¶æ¶²
ã«äžå®ã®æéïŒãã®æéã«ã¯å¶éããªãã10ãã
100ç§ã®ç¯å²ã§ããïŒæµžããŠããã®ã奜ãŸããã
ãšãå€ã€ããã€ãã§ãã®ïŒã€ã®å±€ããäŸãã°ã©ã
ããŒãã®ç¶æ ã«ããŠå§åããŒã«éã«ïŒç§ãã100
ç§ééããŠæŒå§ããããªããã®å§åããŒã©éã«é
ãæéã¯çžå¯Ÿçãªåªæåã«ããç°ãªããåªæå€å
å¿ã®åªæåã極端ã«éãå Žååã¯éåžžã«äŒŒãŠãã
å Žåã«ã¯ããã®ç¯å²å€ã®ç§»éæéãé©ããŠããã
次ãã§ïŒå±€ãåé¢ããã ãŸããã®ååå±€ã¯ãã®äžã«ç§»åæ§ã®å¡©ãå ¥ããŠ
ã€ããããšãã§ããããŸãã»ã³ããŒå±€ã¯ãããæ°Ž
ã«çæé浞ããŠããçšããããã 転åã®ç®çã§éžã°ãã塩溶液ã¯äž»ã«åªæããã
è²çŽ ã®æº¶è§£åºŠã«äŸåããããã®æº¶æ¶²ã«çšãããã
ç¹ã«å¥œãŸããå¡©ã«å¡©åã«ãªãŠã ãèåã«ãªãŠã ã
æ²åã«ãªãŠã ããµãªãã«é žãããªãŠã åã³ããªã·
ã¢ããŒãã§ããããã®ãããªæº¶æ¶²äžã®å¡©ã®æ¿åºŠã¯
çŽ0.1MããçŽ1.0Mã®ç¯å²ã«ããããã®ãã¡KIå
ã¯KBrã¯ãäžèšæ¿åºŠã®ç¯å²å ã§äœæ¿åºŠã§çšããŠã
é®®æãªç»åãçããããšã泚ç®ãããã 転åæ³ã«æçšãªã¢ã«ã³ãŒã«ãšæ°Žãšã®æº¶æ¶²ã¯ã¢ã«
ã³ãŒã«ãæ°Žã®äœç©ã®ïŒããïŒåã®äœç©ã§ååšãã
æ··å液ãããªããæçšãªã¢ã«ã³ãŒã«ã®ä»£è¡šçãªã
ã®ã¯ã¡ã¿ããŒã«ããšã¿ããŒã«åã³ã€ãœãããããŒ
ã«ã§ããã ãã®ãããªè»¢ååŸã«ã»ã³ããŒå±€ãè²çŽ 济ã«åã³
浞ããŠãã®å±€ãåã³æè²ããããšããŸãå¯èœã§ã
ãã å®æœäŸ 次ã«ä»£è¡šçãªå®æœäŸãèšèŒããŠæ¬çºæãæŽã«è©³
现ã«èª¬æããã å®æœäŸ ïŒ æ¬¡ã®ããã«ããŠã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ ãã€
ãã€ãã 100ãã¯ãã³ã®åã¿ã®äžå¡ããªãšã¹ãã«æ¯æäœ
ã«ã0.8mg/dm2ã®ãžã¢ãŸæš¹èãNo.4ã¿ã€ãââã
ãã«ã ã¢ã«ããããšïœâãžã¢ãŸããšãã«ã¢ãã³ãš
ã®çž®åã«ãã€ãŠã€ããããã¯ãããžã³ã±ãŒãå¡©ã
ãšã¢ããŠã³ãNo.4ãã¿ã€ããããšã¢ããŠã³ã
ã±ãã«ã«ç€ŸïŒFairmount Chemical Co.ïŒãã
äŸçµŠããããïŒ0.2mg/dm2ã®ãªã³é žïŒå®å®å
å€ïŒïŒ3.5mg/dm2ã®éåäœåªæå€ãM1ããªã¹ãã¬
ã³âã³âïŒâãã¬ã€ãããããã«âã»ïŒ®âãžã¡
ãã«ââãã³ãžã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãïŒ
ïŒïŒïŒïŒïŒïœïŒåã³0.3mg/dm2ã®ãªãªã³ã»ãµãã¢ã¯
ã¿ã³ãïŒOlin SurfactantïŒ10Gããªãªã³ã»ã±ãã«
ã«ç€ŸïŒOlin Chemical Co.ïŒãã補é ãããŠãã
ããã«ããšããã·ããªã°ãªã»ããŒã«ããããªãå±€
ãå¡åžããã äžèšã®å¡åžç©ã®ãµã³ãã«ãã¡ããœã¿å·ãããã¢
ããªã¹ã®ã³ã©ã€ãã»ã€ã³ã³ãŒãã¬ã€ããã
ïŒColight IncorporatedïŒã«ãã補é ãããã³ã©
ã€ãïŒColightïŒã¢ãã«ïŒâ99æ°Žéèžæ°ã©ã³ãã
ãã®å ã«ã30ç§éã0.15ãã€æ¿åºŠãå¢å ããã¹ã
ããã»ã¿ãã¬ãããéããŠå¯çé²å ããã ãã®ãµã³ãã«ã21âã®æ°Žãçšã10ç§éåŽé§æŽé€
ïŒã¹ãã¬ã€ã»ãŠãªã·ãŠïŒããŠãããã¢ãããã¯ã·
ã³ïŒAcid FuchsinïŒè²çŽ ã®0.4ïŒ æ°Žæº¶æ¶²ã«30ç§é
浞ããã€ãã§21âã®æ°Žã§20ç§éãããã ããã®èŠ
çŽ ãçœè²ã®ããªã³ãçŽã®ã·ãŒãã®äžã«çœ®ãããšã
ã«è¯å¥œãªæ¿åºŠã®é£ç¶é調ããŒã³ã¿ç»åãçããã
ç·è²ãã€ã«ã¿ãŒãéããŠæž¬å®ãããæ¿åºŠãšã¬ã³ã
ãŒã¯æ¬¡ã®éãã§ãã€ãïŒïŒ€naxïŒ2.10ãnioïŒ
0.18ãγïŒ2.40ãåŽé§æŽé€ïŒã¹ãã¬ã€ã»ãŠãªã·
ãŠïŒã浞挬åã³ãããã®ä»å·¥çšã«ãããæéãšæž©
床ã®æ¡ä»¶ãå€ããŠåæ§ã®å¡åžç©ãåŠçãããšãã
ããããåŠçå¯å®¹åºŠã芳å¯ããããäŸãã°è²çŽ 济
ã®æµžæŒ¬æéã15ç§ãã90ç§ã«å€ããŠãã»ã³ã·ãã¡
ããªãŒã«å®è³ªçãªå·®ãçããªãã€ãããã®ããšã¯
è²çŽ 济ã®æž©åºŠã16âãã32âã«å€ããŠãåãã§ã
ã€ãã å®æœäŸ ïŒ åªæå€ã第ïŒè¡šã®M2ã®ããªïŒïŒ®ã»ïŒ®âãžã¡ã
ã«ââã¢ãªã«ããã«ãã³ãžã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ãïŒã§ãã€ã以å€ã¯å®æœäŸïŒãšåãã«ã©ãŒ
ãã«ãŒãã€ã³ã°èŠçŽ ã®ãµã³ãã«ãã€ãã€ããããŒ
ãããŒã³ã®èµ€è²ãç·è²åã³éè²ã®å解ãã¬ã«é²å
åŸããããã®ãµã³ãã«ãå®æœäŸïŒã«èšèŒããæ¡ä»¶
äžã§åŠçãããçšããããããããã®è²çŽ 溶液ã¯
次ã®éãã§ãã€ãã
ãè¡šã
ãªãŠã ã§ç·©
è¡ïŒ
åå Žåãšãè¯å¥œãªæ¿åºŠã®ããžãåŸãããã è¡šé¢ãã€ãæ¶ãããããªãšãã¬ã³è¢«èŠçŽã®æ¯æ
äœäžã«ã21mg/dm2ã®åªæå€ããªïŒã¹ãã¬ã³âã³
ââãã³ãžã«âã»ïŒ®âãžã¡ãã«ããã«ãã³ãž
ã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãžããã«ãã³
ãŒã³ïŒïŒ49.5ïŒ49.5ïŒïŒïŒã¢ã«æ¯ïŒM34ã第ïŒ
è¡šïŒïŒ42mg/dm2ã®é žåŠçãããã°ã¹ãã³ãŒã©ã
ã³ïŒ0.4mg/dm2ã®ãã«ã ã¢ã«ããã硬èå€ïŒåã³
0.7mg/dm2ã®å®æœäŸïŒã«èšèŒããçé¢æŽ»æ§å€ãã
ãªãçµæç©ã®å±€ãå¡åžããŠååèŠçŽ ãã€ãã€ãã
ãã®ååèŠçŽ ãå¡©åã«ãªãŠã ã®0.5M氎溶液ïŒ21
âïŒã«30ç§é浞ããŠåãã€ãŠã¬ãããŠãããããŒ
ã³ã¿ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãšäžç·ã«å
ããŠè»ããŽã 補ã®å§åããŒã©ã®éã«ã¯ãã¿é¢æ¥è§Š
ããŠããŒã©ãŒåŒãããã21âã§30ç§éæ¥è§ŠããŠã
ããïŒåã®ææãã¯ããããååèŠçŽ ã«è¯è³ªã®è»¢
åç»åãåŸãããããã®ååèŠçŽ ã也ãããŠã
ããäžèšã®æ¹æ³ãã€ãšããŒãšã·ã¢ã³ã§æè²ããã
ãã«ãŒãã€ã³ã°èŠçŽ ãããããçšããŠé 次繰è¿ã
ããã€ãšããŒç»åãããŒã³ã¿è»¢åç»åã«ç®ã§èŠãª
ããæ£ç¢ºã«åãããããã®ã€ãšããŒãã«ãŒãã€ã³
ã°èŠçŽ ã®äžç«¯çžãããŒã³ã¿è»¢åç»åãšæŽåããç¶
æ ã«ä¿ã¡ãªããããŒãã§ãã°ã€ããååèŠçŽ ãå
ãã€ãŠãã¿ããŸããŠããéããã®ããŒãã§ãã°ã€
ããã«ãŒãã€ã³ã°èŠçŽ ããã€ãã§ãã±ãã±ããšå
ãããã転ååŸããã®ååèŠçŽ ãåã³ä¹Ÿãããã·
ã¢ã³ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãçšããŠã
ã®æ¹æ³ãç¹°è¿ãããïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ã
ã¹ãŠããã®ç»å転åãçµã€ãããšã«è¯å¥œãªãå®å š
ãªè²åçç»åãåŸãããã å®æœäŸ ïŒâ28 å®æœäŸïŒã®èŠçŽ ãšæ¹æ³ãç¹°è¿ããããªããçšã
ãåªæå€ã¯ç¬¬ïŒè¡šã®M3ããM28ã§ãã€ãããŸã
é žå®å®åå€ã¯0.4mg/dm2ã®éã§çšãããåå Žå
å ±ãåŸãããè²çŽ ç»åã¯æºè¶³ãªæ¿åºŠã®é£ç¶é調ã§
ãã€ãã å®æœäŸ 29â34 åªæå€ã®æ¿åºŠã調ç¯ããŠè²çŽ ç»åã®ïŒ€naxã調
ç¯ããèœåã調ã¹ããåªæå€ã®æ¿åºŠã3.5ã3.0ã
2.5ã2.0ã1.5åã³1.0mg/dm2ã«ããŠå®æœäŸã«èšèŒ
ãããšåãããã«äžé£ã®ãã«ãŒãã€ã³ã°èŠçŽ ãã€
ãã€ãã åå¡åžç©ã®ãµã³ãã«ãé²å ããã¢ãããã¯ã·ã³
è²çŽ ïŒAcid Fuchsin dyeïŒã®0.5氎溶液ãçšã
ãŠãå®æœäŸïŒã«èšèŒãããšåãããã«åŠçããã
第ïŒè¡šã«ç·è²ã®ãã€ã«ã ãéããŠæž¬å®ããããã
ããã®åªæå€ã®æ¿åºŠã«å¯Ÿããæ倧æ¿åºŠã瀺ããã
ãªãåå°æ¿åºŠã¯ãã«ãŒãã€ã³ã°èŠçŽ ãçœè²ããªã³
ãçŽã®ã·ãŒãäžã«çœ®ããŠåŸããã®ã§ããã
è¡ïŒ
åå Žåãšãè¯å¥œãªæ¿åºŠã®ããžãåŸãããã è¡šé¢ãã€ãæ¶ãããããªãšãã¬ã³è¢«èŠçŽã®æ¯æ
äœäžã«ã21mg/dm2ã®åªæå€ããªïŒã¹ãã¬ã³âã³
ââãã³ãžã«âã»ïŒ®âãžã¡ãã«ããã«ãã³ãž
ã«ã¢ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãžããã«ãã³
ãŒã³ïŒïŒ49.5ïŒ49.5ïŒïŒïŒã¢ã«æ¯ïŒM34ã第ïŒ
è¡šïŒïŒ42mg/dm2ã®é žåŠçãããã°ã¹ãã³ãŒã©ã
ã³ïŒ0.4mg/dm2ã®ãã«ã ã¢ã«ããã硬èå€ïŒåã³
0.7mg/dm2ã®å®æœäŸïŒã«èšèŒããçé¢æŽ»æ§å€ãã
ãªãçµæç©ã®å±€ãå¡åžããŠååèŠçŽ ãã€ãã€ãã
ãã®ååèŠçŽ ãå¡©åã«ãªãŠã ã®0.5M氎溶液ïŒ21
âïŒã«30ç§é浞ããŠåãã€ãŠã¬ãããŠãããããŒ
ã³ã¿ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãšäžç·ã«å
ããŠè»ããŽã 補ã®å§åããŒã©ã®éã«ã¯ãã¿é¢æ¥è§Š
ããŠããŒã©ãŒåŒãããã21âã§30ç§éæ¥è§ŠããŠã
ããïŒåã®ææãã¯ããããååèŠçŽ ã«è¯è³ªã®è»¢
åç»åãåŸãããããã®ååèŠçŽ ã也ãããŠã
ããäžèšã®æ¹æ³ãã€ãšããŒãšã·ã¢ã³ã§æè²ããã
ãã«ãŒãã€ã³ã°èŠçŽ ãããããçšããŠé 次繰è¿ã
ããã€ãšããŒç»åãããŒã³ã¿è»¢åç»åã«ç®ã§èŠãª
ããæ£ç¢ºã«åãããããã®ã€ãšããŒãã«ãŒãã€ã³
ã°èŠçŽ ã®äžç«¯çžãããŒã³ã¿è»¢åç»åãšæŽåããç¶
æ ã«ä¿ã¡ãªããããŒãã§ãã°ã€ããååèŠçŽ ãå
ãã€ãŠãã¿ããŸããŠããéããã®ããŒãã§ãã°ã€
ããã«ãŒãã€ã³ã°èŠçŽ ããã€ãã§ãã±ãã±ããšå
ãããã転ååŸããã®ååèŠçŽ ãåã³ä¹Ÿãããã·
ã¢ã³ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãçšããŠã
ã®æ¹æ³ãç¹°è¿ãããïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ã
ã¹ãŠããã®ç»å転åãçµã€ãããšã«è¯å¥œãªãå®å š
ãªè²åçç»åãåŸãããã å®æœäŸ ïŒâ28 å®æœäŸïŒã®èŠçŽ ãšæ¹æ³ãç¹°è¿ããããªããçšã
ãåªæå€ã¯ç¬¬ïŒè¡šã®M3ããM28ã§ãã€ãããŸã
é žå®å®åå€ã¯0.4mg/dm2ã®éã§çšãããåå Žå
å ±ãåŸãããè²çŽ ç»åã¯æºè¶³ãªæ¿åºŠã®é£ç¶é調ã§
ãã€ãã å®æœäŸ 29â34 åªæå€ã®æ¿åºŠã調ç¯ããŠè²çŽ ç»åã®ïŒ€naxã調
ç¯ããèœåã調ã¹ããåªæå€ã®æ¿åºŠã3.5ã3.0ã
2.5ã2.0ã1.5åã³1.0mg/dm2ã«ããŠå®æœäŸã«èšèŒ
ãããšåãããã«äžé£ã®ãã«ãŒãã€ã³ã°èŠçŽ ãã€
ãã€ãã åå¡åžç©ã®ãµã³ãã«ãé²å ããã¢ãããã¯ã·ã³
è²çŽ ïŒAcid Fuchsin dyeïŒã®0.5氎溶液ãçšã
ãŠãå®æœäŸïŒã«èšèŒãããšåãããã«åŠçããã
第ïŒè¡šã«ç·è²ã®ãã€ã«ã ãéããŠæž¬å®ããããã
ããã®åªæå€ã®æ¿åºŠã«å¯Ÿããæ倧æ¿åºŠã瀺ããã
ãªãåå°æ¿åºŠã¯ãã«ãŒãã€ã³ã°èŠçŽ ãçœè²ããªã³
ãçŽã®ã·ãŒãäžã«çœ®ããŠåŸããã®ã§ããã
ãè¡šã
åªæå€ã®æ¿åºŠãæžå°ããã«ã€ããŠãæ倧æ¿åºŠã
æžå°ãããæ倧æ¿åºŠå¯Ÿåªæå€ã®æ¿åºŠã®ã°ã©ãã¯çŽ
ç·é¢ä¿ã瀺ããããã®ã°ã©ãã«åºã¥ããŠãåªæå€
ã®æ¿åºŠã倧äœ1.2mg/dm2ã§1.30ã®æå¹ãªåå°ïŒ€nax
ãåŸãããããšãããã€ãã倧äœ0.15 logEã®å š
ã¹ããŒãå€åã¯åªæå€ã®æ¿åºŠã3.5ãš1.0mg/dm2ã®
éã§ããããšã瀺ããã³ã³ãã©ã¹ããšïŒ€nioã¯å š
äœãéããŠã»ãšãã©äžå€ã§ãã€ãã å®æœäŸ 35 å®æœäŸïŒã«èšèŒããã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ
ã®ãµã³ãã«ãã³ã©ã€ãã¢ãã«ïŒColight modelïŒ
ïŒâ99æ°Žéèžæ°ç¯ããã®å ã«30ç§éã³ã³ãã©ã¹
ãã»ããŒãããŒã³ãã¬ãéããŠå¯çé²å ãããã
ã®èŠçŽ ãå®æœäŸïŒãšåãããã«åŠçãã也ãã
ãã 21mg/dm2ã®åªæå€ãããªïŒã¹ãã¬ã³âã³â
âãã³ãžã«ïŒ®ã»ïŒ®âãžã¡ãã«âããã«ãã³ãžã«ã¢
ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãžããã«ãã³ãŒ
ã³ïŒïŒç¬¬ïŒè¡šã®M34ïŒã21mg/dm2ã®ãŒã©ãã³åã³
0.2mg/dm2ã®ãã¹ïŒããã«ã¹ã«ããã«ã¡ãã«ïŒãš
ãŒãã«ç¡¬èå€ãããªãååææã21âã®èžçæ°Žã«
30ç§éåãã€ãŠããããŠãããæè²ãããã«ãŒã
ã€ã³ã°èŠçŽ ãšé¢æ¥è§ŠãããŠ21âã§30ç§éè»ãããŽ
ã 補ã®å§åããŒã©ãŒã«éããŠã©ãããŒããããé
åžžã«äœæ¿åºŠã®è»¢åç»åïŒïŒ€nax0.30ïŒãåŸãã
ãã転å溶液ã«ã¡ã¿ããŒã«ãšèžçæ°Žã®æ··å液
ïŒïŒïŒïŒïŒãçšããŠäžèšã®æ¹æ³ãç¹°è¿ãããæ¹è¯
ããã転åæ¿åºŠãåŸãããïŒïŒ€nax0.68ïŒããã®å®
æœäŸã¯è»¢åå·¥çšã«ã¢ã«ã³ãŒã«ãšæ°Žã®æº¶æ¶²ãçšãã
ããšãã§ããããšã瀺ããã®ã§ããã å®æœäŸ 36â38 æ²åã«ãªãŠã åã³å¡©åã«ãªãŠã ã®è»¢åä¿é²å€ãš
ããŠã®æ§èœãæ¯èŒãããããªãã¡ããã®ååç©
ã¯ããããå浞济ïŒpresoalc bathïŒã«å ãããš
ãã¯ãè²çŽ ã®è»¢ç§»é床ãå¢å ãããã21mg/dm2ã®
åªæå€ã第ïŒè¡šã®M34ïŒ40mg/dm2ã®ãã°ã¹ãã³
ïŒpigskinïŒãŒã©ãã³ïŒåã³0.2mg/dm2ã®ãã¹ïŒã
ãã«ã¹ã«ããã«ã¡ãã«ïŒãšãŒãã«ç¡¬èå€ãããªã
å±€ãããªãšãã¬ã³è¢«èŠçŽã®æ¯æäœäžã«å¡åžãããŠ
ããåå°ååèŠçŽ ã®ãµã³ãã«ãå浞挬ããããã«
ãããã®å¡©ã®æº¶æ¶²ïŒ0.5nïŒãçšããããã®ãµã³ã
ã«ããããã®æº¶æ¶²äžã§21âã§30ç§éå浞挬ããŠã
ããå®æœäŸïŒã«åŸã€ãŠã€ããããåŠçãããè²çŽ
ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ïŒãªããããã®
èŠçŽ ã¯ããŒãããŒã³ã¹ã¯ãªãŒã³ãéããŠé²å ãã
ãïŒã«21âã§30ç§éã©ãããŒããããåŸãããæ
倧æ¿åºŠããããŒãšããŒã³ç»åã®é®®æ床ã®è©äŸ¡ãšäž
ç·ã«ç¬¬ïŒè¡šã«ç€ºãã
æžå°ãããæ倧æ¿åºŠå¯Ÿåªæå€ã®æ¿åºŠã®ã°ã©ãã¯çŽ
ç·é¢ä¿ã瀺ããããã®ã°ã©ãã«åºã¥ããŠãåªæå€
ã®æ¿åºŠã倧äœ1.2mg/dm2ã§1.30ã®æå¹ãªåå°ïŒ€nax
ãåŸãããããšãããã€ãã倧äœ0.15 logEã®å š
ã¹ããŒãå€åã¯åªæå€ã®æ¿åºŠã3.5ãš1.0mg/dm2ã®
éã§ããããšã瀺ããã³ã³ãã©ã¹ããšïŒ€nioã¯å š
äœãéããŠã»ãšãã©äžå€ã§ãã€ãã å®æœäŸ 35 å®æœäŸïŒã«èšèŒããã«ã©ãŒãã«ãŒãã€ã³ã°èŠçŽ
ã®ãµã³ãã«ãã³ã©ã€ãã¢ãã«ïŒColight modelïŒ
ïŒâ99æ°Žéèžæ°ç¯ããã®å ã«30ç§éã³ã³ãã©ã¹
ãã»ããŒãããŒã³ãã¬ãéããŠå¯çé²å ãããã
ã®èŠçŽ ãå®æœäŸïŒãšåãããã«åŠçãã也ãã
ãã 21mg/dm2ã®åªæå€ãããªïŒã¹ãã¬ã³âã³â
âãã³ãžã«ïŒ®ã»ïŒ®âãžã¡ãã«âããã«ãã³ãžã«ã¢
ã³ã¢ããŠã ã¯ãã©ã€ãâã³âãžããã«ãã³ãŒ
ã³ïŒïŒç¬¬ïŒè¡šã®M34ïŒã21mg/dm2ã®ãŒã©ãã³åã³
0.2mg/dm2ã®ãã¹ïŒããã«ã¹ã«ããã«ã¡ãã«ïŒãš
ãŒãã«ç¡¬èå€ãããªãååææã21âã®èžçæ°Žã«
30ç§éåãã€ãŠããããŠãããæè²ãããã«ãŒã
ã€ã³ã°èŠçŽ ãšé¢æ¥è§ŠãããŠ21âã§30ç§éè»ãããŽ
ã 補ã®å§åããŒã©ãŒã«éããŠã©ãããŒããããé
åžžã«äœæ¿åºŠã®è»¢åç»åïŒïŒ€nax0.30ïŒãåŸãã
ãã転å溶液ã«ã¡ã¿ããŒã«ãšèžçæ°Žã®æ··å液
ïŒïŒïŒïŒïŒãçšããŠäžèšã®æ¹æ³ãç¹°è¿ãããæ¹è¯
ããã転åæ¿åºŠãåŸãããïŒïŒ€nax0.68ïŒããã®å®
æœäŸã¯è»¢åå·¥çšã«ã¢ã«ã³ãŒã«ãšæ°Žã®æº¶æ¶²ãçšãã
ããšãã§ããããšã瀺ããã®ã§ããã å®æœäŸ 36â38 æ²åã«ãªãŠã åã³å¡©åã«ãªãŠã ã®è»¢åä¿é²å€ãš
ããŠã®æ§èœãæ¯èŒãããããªãã¡ããã®ååç©
ã¯ããããå浞济ïŒpresoalc bathïŒã«å ãããš
ãã¯ãè²çŽ ã®è»¢ç§»é床ãå¢å ãããã21mg/dm2ã®
åªæå€ã第ïŒè¡šã®M34ïŒ40mg/dm2ã®ãã°ã¹ãã³
ïŒpigskinïŒãŒã©ãã³ïŒåã³0.2mg/dm2ã®ãã¹ïŒã
ãã«ã¹ã«ããã«ã¡ãã«ïŒãšãŒãã«ç¡¬èå€ãããªã
å±€ãããªãšãã¬ã³è¢«èŠçŽã®æ¯æäœäžã«å¡åžãããŠ
ããåå°ååèŠçŽ ã®ãµã³ãã«ãå浞挬ããããã«
ãããã®å¡©ã®æº¶æ¶²ïŒ0.5nïŒãçšããããã®ãµã³ã
ã«ããããã®æº¶æ¶²äžã§21âã§30ç§éå浞挬ããŠã
ããå®æœäŸïŒã«åŸã€ãŠã€ããããåŠçãããè²çŽ
ã§æè²ããããã«ãŒãã€ã³ã°èŠçŽ ïŒãªããããã®
èŠçŽ ã¯ããŒãããŒã³ã¹ã¯ãªãŒã³ãéããŠé²å ãã
ãïŒã«21âã§30ç§éã©ãããŒããããåŸãããæ
倧æ¿åºŠããããŒãšããŒã³ç»åã®é®®æ床ã®è©äŸ¡ãšäž
ç·ã«ç¬¬ïŒè¡šã«ç€ºãã
ãè¡šã
第ïŒè¡šããå€ãããã«ãæ倧æ¿åºŠã¯æ°Žãã
KClãKBrãKI溶液ã«è¡ãã«ã€ããŠåŸã ã«å¢å ã
ãåŸåããã€ããããããªãããç»åã®é®®æ床ã¯
éæ¹åã«ãã€ããè²çŽ ã®è»¢åãå¢å ããã«ã€ããŠ
ç»åã®è³ªãæªããªãåŸåã«ããã®ã¯ãè²çŽ ã®æº¶è§£
床ãå¢å ããã®ããåŽé¢ãžã®è²çŽ ã®æ¡æ£ãå¢å ã
ããããšèãããããå転åç»åã®æ°ŽæŽããªããµ
ã³ãã«ãïŒãã€ãŒãé¢ããïŒåã®15ã¯ããè¢å ç¯
ããã®å ã®äžã§èŠ³å¯ãããæ²åã«ãªãŠã ã§è»¢åã
ããè²çŽ ç»åã«ã€ããŠã¯ããªãã²ã©ãé»è²ã®æ±ã
ãèæ¯åã«èŠããããèåã«ãªãŠã ãšå¡©åã«ãªãŠ
ã ã§è»¢åãããç»åã¯èæ¯åã«äœãã®æ±ããèŠã
ããªãã€ããããã¯KIã®æ¿åºŠãäœããšïŒäŸãã°
0.25MïŒKBrã®é®®æ床ã«å¹æµãããçšåºŠã®æ¹è¯ã
ãã転åè²çŽ ç»åãåŸãããããšãäºæž¬ãããã å®æœäŸ 39 èŠçŽ ã«éåäœåªæå€ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«â
âã·ã¯ãããã·ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠ
ã ã¯ãã©ã€ãïŒãš0.4mg/dm2ã®ãªã³é žãå«ãã§ã
ããã«ãŒãã€ã³ã°èŠçŽ ãå®æœäŸïŒãšåæ§ã«ã€ãã€
ããé²å ãšåŠçãå®æœäŸïŒãšåãããã«è¡ãªã€
ãããªãè²çŽ 济ã¯68.1ïœ/ã®ãªã³é žã«ãªãŠã ãš
1.87ïœ/ã®æ°Žé žåãããªãŠã ã§ãã€ãŠPH8.0ç·©è¡
ããã 4.2mg/dm2ã®åªæå€M34ã42mg/dm2ã®ãŒã©ãã³
åã³0.2mg/dm2ã®ãã¹ïŒããã«ã¹ã«ããã«ã¡ã
ã«ïŒãšãŒãã«ç¡¬èå€ãããªãå±€ãå¡åžããååèŠ
çŽ ã®ãµã³ãã«ã1Mã®KBr溶液ã«21âã§30ç§é浞
ããããã®ããã«ããŠåãã€ãŠæµžããååèŠçŽ ã
æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãšé¢æ¥è§ŠãããŠ21
âã§30ç§éããŒã©ãŒã§åŒããããã®ïŒåã®èŠçŽ ã
å¥ã ã«ã¯ããããšãããè¯å¥œãªæ¿åºŠã®è²çŽ 転åç»
åãåŸãããã å®æœäŸ 40 è²çŽ 転åä¿é²å€æº¶æ¶²ãšããŠKBrãšKCNSã®0.5M
溶液ãçšããå®æœäŸ39ãç¹°è¿ããã 転åå¡©ãšããŠããªã·ã¢ã³åã«ãªãŠã ãçšãããš
転åæ¿åºŠãååã«æ¹è¯ããããã®ãåŸãããã
KCNSãçšããå Žåã®è»¢ååã¯KBr溶液ãçšããŠ
åŸãããå Žåã®è»¢ååã«æ¯ã¹ãŠå€§äœïŒåå¢å ãã
ïŒ2.55察0.79ïŒãåããããªæ¿åºŠã®å¢å ã¯ãµãªãã«
é žã®ãããªãŠã å¡©ã§ãåŸãããã å®æœäŸ 41 ã¢ã³ããªãŠãŒã¹ïŒAndrewsïŒãžã¢ãŸæš¹èP1001
âBFããã«ã ã¢ã«ããããšïœâãžã¢ãŸãžããšã
ã«ã¢ãã³ã®çž®åçæç©ã®ãã«ãªããã¬ãŒãå¡©ãå®
æœäŸ39ã®ãã«ãŒãã€ã³ã°èŠçŽ ã«çšããããã®æš¹è
ã¯å®æœäŸïŒã®ããšã¢ã¢ã³ãïŒFairmountïŒãžã¢ãŸ
æš¹èãããããããããæ°Žã«å¯Ÿãã溶解床ãå°ã
ãããšãå€ã€ãããå¡åžã«å¿ èŠãšãããæ¿åºŠã§ã¯
ååã«æ°Žæº¶æ§ã§ãã€ããåªæå€ãå®å®å€ãšã®çžå®¹
æ§ãè¯ãããšã泚ç®ããããå¡åžããå Žåã®åäž
æ§ãè¯å¥œã§ãã€ããã»ã³ã·ãã¡ããªãŒçã«ãçæ¿
床ã§ã®ã¢ã³ããªãŠãŒã¹ãžã¢ãŸæš¹èã¯è¥å¹²ãã³ã³
ãã©ã¹ãã瀺ããããŸãããšã¢ã¢ã³ãæš¹èããã
ã¹ããŒãã0.15 logEéãã€ããããã«ïŒ€naxã
nioããããããã®å·®ã¯ããå°ããã€ãã ã¢ãããã¯ã·ã³è²çŽ ã®0.5ïŒ æº¶æ¶²ãçšããŠå®æœ
äŸïŒã«èšèŒãšåãããã«é²å ãšåŠçãè¡ãªã€ããš
ããæºè¶³ãªçµæãåŸãããã å®æœäŸ 42 ããã§ã¯å¥ã®è»¢åæ³ãæ¢ããã ååèŠçŽ ãã©ãããŒãããåã«30ç§é転å溶液
ã«æµžã代ãã«ããã®ãã«ãŒãã€ã³ã°èŠçŽ ãèžçæ°Ž
ã«ïŒç§é浞ããŠããã転åå¡©ãå«ãã§ããååèŠ
çŽ ãããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒæ¯æäœãçš
ããããšã©ãããŒããããïŒç§éæ¥è§ŠãããŠã
ããïŒåã®èŠçŽ ãã¯ããããšãããã»ãšãã©å šéš
ã®è²çŽ ã転åããã ãã®å®éšããããªãšãã¬ã³è¢«èŠçŽã«å¡åžããå
åèŠçŽ ãçšãåäžã®æ¡ä»¶äžã§ç¹°è¿ãããè¯å¥œãªæ¿
床ã®è»¢åãåŸãããïŒïŒ€naxïŒ1.52ïŒãããããã
ã®ååèŠçŽ ã¯ãã®åé¢ã®éã«å±€ãã¯ãããåŸåã
ã¿ãããã ååå±€ã«è»¢åå¡©ãå ¥ããã«ã¯ããã®å±€ã0.5M
ã®KCNS氎溶液ã«30ç§é浞ããŠãã也ç¥ãããã°
ããã åæ§ã®çµæã¯0.5Mã®ãµãªãã«é žãããªãŠã 溶
液ã«ååèŠçŽ ã30ç§é浞ããŠãåŸãããã å®æœäŸ 43 硬å床ã倧ããããèŠçŽ ã蚌æããããã«ãæ¯
æäœã«æ¬¡ã®çµæç©ãå¡åžããããšã«ããå®æœäŸ24
ãç¹°è¿ããã 第ïŒè¡šã®éåäœåªæå€ 10.0 ïœ å®æœäŸïŒã®æš¹è 3.75ïœ ãªã³é žïŒ85ïŒ ïŒ 1.5 ïœ çé¢æŽ»æ§å€ïŒ50ïŒ æº¶æ¶²ïŒ 0.90ïœ èžçæ°Ž 923 ml ãã®æº¶æ¶²ããåªæå€ã®ä¹Ÿç¥æã®å¡åžéã2.0mg/
ïœm2åã³ãžã¢ãŸæš¹èã®å¡åžéã0.75mg/dm2ã«ãªã
ããã«å¡åžããã ãã®ç¬¬ïŒå¡åžç©ã®äžã«æ¬¡ã®çµæãæãã第ïŒå¡
åžç©ãå¡åžããïŒ âPVPâK90âããªããã«ãããªãã³ïŒååé
360000ïŒ âGAF ã³ãŒãã¬ãŒã·ãšã³ãã販売ãããŠãã
â ïŒ ïœ çé¢æŽ»æ§å€10G 1.0ïœ èžçæ°Ž 1000 ml ãã®æº¶æ¶²ãPVPâK90ã®å¡åžéã1.0mg/dm2ã«
ãªãããã«å¡åžãããå®æœäŸïŒãšåãããã«é²å
ãšçŸåãè¡ãªã€ãããã®èŠçŽ ãè²çŽ 溶液ã«ã²ãã
ãã¹ãã³ãžã§æãè²çŽ ãé©çšãããããã€ãå Žå
ã®æµææ§ã¯å®æœäŸïŒã®ããã«æ¯ã¹ãŠæ¹åãããã å®æœäŸ 44 ããªïŒããã«ãããªãã³ïŒããžã¢ãŸæš¹èãšå ±ã«
第ïŒå¡åžç©ã«å ¥ããå Žåããããã«å¯Ÿããæµææ§
ãæ¹åãããã æ¯èŒäŸ ïŒ äžé©åœãªåªæå€ åªæå€ã«ãžã¡ãã«âβâããããã·ãšãã«Î³â
ã¹ãã¢ã«ã¢ãããããã«ã¢ã³ã¢ããŠã ïŒæ°ŽçŽ ãã¹
ããšãŒãïŒåéäœååç©ã§ïŒ²åºã第ïŒçŽã¢ã³ã¢ã
ãŠã ã«çµåããŠãããååéã324ã§ããïŒãçš
ãããããçéã®ãŒã©ãã³ã«å ãã以å€ã¯å®æœäŸ
ïŒãšåãããã«èŠçŽ ãã€ãããããåŠçããããŸ
ãè²çŽ ã®æº¶æ¶²ã¯0.5ïŒ æ¿åºŠã§ãã€ããè²çŽ ã«æµžã
ãããšã®çµæã¯äžæºè¶³ãªã»ã©ç»åæ¿åºŠãäœãã€
ãã æ¯èŒäŸ ïŒåã³ïŒ ãžã¢ãŸæš¹èã®æ¬ åŠããŠããåªæå€ å®æœäŸïŒãšåæ§ã«ïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ã
ã€ãããããåŠçãããäœãããããã®ãã«ãŒã
ã€ã³ã°èŠçŽ ã¯åªæå€ãããããå«ãã§ãããããŸ
ãçŽæ¯æäœãçšããïŒé žåãã¿ã³ã§çè²ããå æ°Ž
å解ããã©ãšãã«ãªã«ãœã·ãªã±ãŒããšæ¶æ©çµåã
ãå æ°Žå解ããªïŒããã«ã¢ã»ããŒãïŒã§äžå¡ã
ãããã®ïŒåã®èŠçŽ ãå®æœäŸïŒãšåæ§ã«é²å ãã
èžçæ°Žã§10ç§éæŽãã氎济ïŒæ¯èŒäŸïŒïŒåã¯è²çŽ
济ïŒæ¯èŒäŸïŒïŒã§30ç§é浞ããã€ãã§20ç§éãã
ãçŸåããããªããçŸå枩床ã¯21âã§ãã€ããåŠ
çåŸãäž¡æ¹å ±åãããã«ç°è²ã®ç»åãæããŠã
ããæ¶æ©ãžã¢ãŸæš¹èåç¬ã«ããã¢ããªã³ç³»è²çŽ ã®
åªæå€ã¯äœãèŠãããªãã€ãã æ¯èŒäŸ ïŒ çžå¯Ÿã¹ããŒãïŒã«ããªã³ç³»è²çŽ ãæããåŸæ¥ã®
ãã«ãŒãã€ã³ã°èŠçŽ ãšã¢ããªã³ç³»è²çŽ ãæãã
æ¬çºæã®èŠçŽ å®æœäŸïŒãšåæ§ã«èŠçŽ ãã€ãã€ããäœããæå
æ§å±€ã«ã¯åªæå€ãå ¥ããªãã€ããã³ã³ãããŒã«ãš
ããŠãæ¬çºæãšåãèŠçŽ ãã€ãã€ãããã®èŠçŽ ã¯
第ïŒè¡šã®åªæå€M19ã1.5mg/dm2æå æ§å±€ã«å«ãŸ
ããŠãããåŸæ¥ã®èŠçŽ ãå®æœäŸïŒãšåãããã«é²
å ããåŠçããããããã«ããªã³ç³»è²çŽ ã¡ãã¬ã³
ãã«ãŒãçšãããã³ã³ãããŒã«èŠçŽ ããŸãå®æœäŸ
ïŒã«åŸã€ãŠé²å ãåŠçãããããã®å Žåã«ã¯PH
8.0ã®ãããã¢ãŒæº¶æ¶²äžã§ç¬¬ïŒè¡šã®ã¢ããªã³ç³»è²
çŽ D1ãçšãããåªæå€ã®ãªãåŸæ¥ã®èŠçŽ ã¯ã
ã³ã³ãã©ã¹ããæããŠããïŒã¬ã³ããŒ3.0察2.0ïŒ
ã«ããããããæ¬çºæã®ããããã0.75 logEã¹
ããŒããé ãã€ãã åŸã€ãŠãåŸæ¥ããç¥ãããŠãããžã¢ãŸæš¹èã«ã
ã€ãŠåªæãããã«ããªã³ç³»è²çŽ ã¯ã«ããªã³ç³»åªæ
å€ãå«ã¿ã¢ããªã³ç³»ã®è²çŽ ãçšããããšã®ã§ãã
æ¬çºæã®èŠçŽ ããåŸããããããªã¹ããŒããäžã
ãããšãã§ããªãã æ¯èŒäŸ ïŒ çžå¯Ÿã¹ããŒãããžã¢ãŸæš¹è察ãžã¢ãŸå¡© äžå¡ãã100ãã¯ãã³ã®åãã®ããªãšã¹ãã«æ¯
æäœäžã«æ¬¡ã®æº¶æ¶²ïŒ¢ã湿最æã®åãã25ãã¯ãã³
ã«ãªãããã«å¡åžããŠãã«ãŒãã€ã³ã°èŠçŽ ãã€ã
ã€ãïŒ
KClãKBrãKI溶液ã«è¡ãã«ã€ããŠåŸã ã«å¢å ã
ãåŸåããã€ããããããªãããç»åã®é®®æ床ã¯
éæ¹åã«ãã€ããè²çŽ ã®è»¢åãå¢å ããã«ã€ããŠ
ç»åã®è³ªãæªããªãåŸåã«ããã®ã¯ãè²çŽ ã®æº¶è§£
床ãå¢å ããã®ããåŽé¢ãžã®è²çŽ ã®æ¡æ£ãå¢å ã
ããããšèãããããå転åç»åã®æ°ŽæŽããªããµ
ã³ãã«ãïŒãã€ãŒãé¢ããïŒåã®15ã¯ããè¢å ç¯
ããã®å ã®äžã§èŠ³å¯ãããæ²åã«ãªãŠã ã§è»¢åã
ããè²çŽ ç»åã«ã€ããŠã¯ããªãã²ã©ãé»è²ã®æ±ã
ãèæ¯åã«èŠããããèåã«ãªãŠã ãšå¡©åã«ãªãŠ
ã ã§è»¢åãããç»åã¯èæ¯åã«äœãã®æ±ããèŠã
ããªãã€ããããã¯KIã®æ¿åºŠãäœããšïŒäŸãã°
0.25MïŒKBrã®é®®æ床ã«å¹æµãããçšåºŠã®æ¹è¯ã
ãã転åè²çŽ ç»åãåŸãããããšãäºæž¬ãããã å®æœäŸ 39 èŠçŽ ã«éåäœåªæå€ããªïŒïŒ®ã»ïŒ®âãžã¡ãã«â
âã·ã¯ãããã·ã«âããã«ãã³ãžã«ã¢ã³ã¢ããŠ
ã ã¯ãã©ã€ãïŒãš0.4mg/dm2ã®ãªã³é žãå«ãã§ã
ããã«ãŒãã€ã³ã°èŠçŽ ãå®æœäŸïŒãšåæ§ã«ã€ãã€
ããé²å ãšåŠçãå®æœäŸïŒãšåãããã«è¡ãªã€
ãããªãè²çŽ 济ã¯68.1ïœ/ã®ãªã³é žã«ãªãŠã ãš
1.87ïœ/ã®æ°Žé žåãããªãŠã ã§ãã€ãŠPH8.0ç·©è¡
ããã 4.2mg/dm2ã®åªæå€M34ã42mg/dm2ã®ãŒã©ãã³
åã³0.2mg/dm2ã®ãã¹ïŒããã«ã¹ã«ããã«ã¡ã
ã«ïŒãšãŒãã«ç¡¬èå€ãããªãå±€ãå¡åžããååèŠ
çŽ ã®ãµã³ãã«ã1Mã®KBr溶液ã«21âã§30ç§é浞
ããããã®ããã«ããŠåãã€ãŠæµžããååèŠçŽ ã
æè²ããããã«ãŒãã€ã³ã°èŠçŽ ãšé¢æ¥è§ŠãããŠ21
âã§30ç§éããŒã©ãŒã§åŒããããã®ïŒåã®èŠçŽ ã
å¥ã ã«ã¯ããããšãããè¯å¥œãªæ¿åºŠã®è²çŽ 転åç»
åãåŸãããã å®æœäŸ 40 è²çŽ 転åä¿é²å€æº¶æ¶²ãšããŠKBrãšKCNSã®0.5M
溶液ãçšããå®æœäŸ39ãç¹°è¿ããã 転åå¡©ãšããŠããªã·ã¢ã³åã«ãªãŠã ãçšãããš
転åæ¿åºŠãååã«æ¹è¯ããããã®ãåŸãããã
KCNSãçšããå Žåã®è»¢ååã¯KBr溶液ãçšããŠ
åŸãããå Žåã®è»¢ååã«æ¯ã¹ãŠå€§äœïŒåå¢å ãã
ïŒ2.55察0.79ïŒãåããããªæ¿åºŠã®å¢å ã¯ãµãªãã«
é žã®ãããªãŠã å¡©ã§ãåŸãããã å®æœäŸ 41 ã¢ã³ããªãŠãŒã¹ïŒAndrewsïŒãžã¢ãŸæš¹èP1001
âBFããã«ã ã¢ã«ããããšïœâãžã¢ãŸãžããšã
ã«ã¢ãã³ã®çž®åçæç©ã®ãã«ãªããã¬ãŒãå¡©ãå®
æœäŸ39ã®ãã«ãŒãã€ã³ã°èŠçŽ ã«çšããããã®æš¹è
ã¯å®æœäŸïŒã®ããšã¢ã¢ã³ãïŒFairmountïŒãžã¢ãŸ
æš¹èãããããããããæ°Žã«å¯Ÿãã溶解床ãå°ã
ãããšãå€ã€ãããå¡åžã«å¿ èŠãšãããæ¿åºŠã§ã¯
ååã«æ°Žæº¶æ§ã§ãã€ããåªæå€ãå®å®å€ãšã®çžå®¹
æ§ãè¯ãããšã泚ç®ããããå¡åžããå Žåã®åäž
æ§ãè¯å¥œã§ãã€ããã»ã³ã·ãã¡ããªãŒçã«ãçæ¿
床ã§ã®ã¢ã³ããªãŠãŒã¹ãžã¢ãŸæš¹èã¯è¥å¹²ãã³ã³
ãã©ã¹ãã瀺ããããŸãããšã¢ã¢ã³ãæš¹èããã
ã¹ããŒãã0.15 logEéãã€ããããã«ïŒ€naxã
nioããããããã®å·®ã¯ããå°ããã€ãã ã¢ãããã¯ã·ã³è²çŽ ã®0.5ïŒ æº¶æ¶²ãçšããŠå®æœ
äŸïŒã«èšèŒãšåãããã«é²å ãšåŠçãè¡ãªã€ããš
ããæºè¶³ãªçµæãåŸãããã å®æœäŸ 42 ããã§ã¯å¥ã®è»¢åæ³ãæ¢ããã ååèŠçŽ ãã©ãããŒãããåã«30ç§é転å溶液
ã«æµžã代ãã«ããã®ãã«ãŒãã€ã³ã°èŠçŽ ãèžçæ°Ž
ã«ïŒç§é浞ããŠããã転åå¡©ãå«ãã§ããååèŠ
çŽ ãããªïŒãšãã¬ã³ãã¬ãã¿ã¬ãŒãïŒæ¯æäœãçš
ããããšã©ãããŒããããïŒç§éæ¥è§ŠãããŠã
ããïŒåã®èŠçŽ ãã¯ããããšãããã»ãšãã©å šéš
ã®è²çŽ ã転åããã ãã®å®éšããããªãšãã¬ã³è¢«èŠçŽã«å¡åžããå
åèŠçŽ ãçšãåäžã®æ¡ä»¶äžã§ç¹°è¿ãããè¯å¥œãªæ¿
床ã®è»¢åãåŸãããïŒïŒ€naxïŒ1.52ïŒãããããã
ã®ååèŠçŽ ã¯ãã®åé¢ã®éã«å±€ãã¯ãããåŸåã
ã¿ãããã ååå±€ã«è»¢åå¡©ãå ¥ããã«ã¯ããã®å±€ã0.5M
ã®KCNS氎溶液ã«30ç§é浞ããŠãã也ç¥ãããã°
ããã åæ§ã®çµæã¯0.5Mã®ãµãªãã«é žãããªãŠã 溶
液ã«ååèŠçŽ ã30ç§é浞ããŠãåŸãããã å®æœäŸ 43 硬å床ã倧ããããèŠçŽ ã蚌æããããã«ãæ¯
æäœã«æ¬¡ã®çµæç©ãå¡åžããããšã«ããå®æœäŸ24
ãç¹°è¿ããã 第ïŒè¡šã®éåäœåªæå€ 10.0 ïœ å®æœäŸïŒã®æš¹è 3.75ïœ ãªã³é žïŒ85ïŒ ïŒ 1.5 ïœ çé¢æŽ»æ§å€ïŒ50ïŒ æº¶æ¶²ïŒ 0.90ïœ èžçæ°Ž 923 ml ãã®æº¶æ¶²ããåªæå€ã®ä¹Ÿç¥æã®å¡åžéã2.0mg/
ïœm2åã³ãžã¢ãŸæš¹èã®å¡åžéã0.75mg/dm2ã«ãªã
ããã«å¡åžããã ãã®ç¬¬ïŒå¡åžç©ã®äžã«æ¬¡ã®çµæãæãã第ïŒå¡
åžç©ãå¡åžããïŒ âPVPâK90âããªããã«ãããªãã³ïŒååé
360000ïŒ âGAF ã³ãŒãã¬ãŒã·ãšã³ãã販売ãããŠãã
â ïŒ ïœ çé¢æŽ»æ§å€10G 1.0ïœ èžçæ°Ž 1000 ml ãã®æº¶æ¶²ãPVPâK90ã®å¡åžéã1.0mg/dm2ã«
ãªãããã«å¡åžãããå®æœäŸïŒãšåãããã«é²å
ãšçŸåãè¡ãªã€ãããã®èŠçŽ ãè²çŽ 溶液ã«ã²ãã
ãã¹ãã³ãžã§æãè²çŽ ãé©çšãããããã€ãå Žå
ã®æµææ§ã¯å®æœäŸïŒã®ããã«æ¯ã¹ãŠæ¹åãããã å®æœäŸ 44 ããªïŒããã«ãããªãã³ïŒããžã¢ãŸæš¹èãšå ±ã«
第ïŒå¡åžç©ã«å ¥ããå Žåããããã«å¯Ÿããæµææ§
ãæ¹åãããã æ¯èŒäŸ ïŒ äžé©åœãªåªæå€ åªæå€ã«ãžã¡ãã«âβâããããã·ãšãã«Î³â
ã¹ãã¢ã«ã¢ãããããã«ã¢ã³ã¢ããŠã ïŒæ°ŽçŽ ãã¹
ããšãŒãïŒåéäœååç©ã§ïŒ²åºã第ïŒçŽã¢ã³ã¢ã
ãŠã ã«çµåããŠãããååéã324ã§ããïŒãçš
ãããããçéã®ãŒã©ãã³ã«å ãã以å€ã¯å®æœäŸ
ïŒãšåãããã«èŠçŽ ãã€ãããããåŠçããããŸ
ãè²çŽ ã®æº¶æ¶²ã¯0.5ïŒ æ¿åºŠã§ãã€ããè²çŽ ã«æµžã
ãããšã®çµæã¯äžæºè¶³ãªã»ã©ç»åæ¿åºŠãäœãã€
ãã æ¯èŒäŸ ïŒåã³ïŒ ãžã¢ãŸæš¹èã®æ¬ åŠããŠããåªæå€ å®æœäŸïŒãšåæ§ã«ïŒåã®ãã«ãŒãã€ã³ã°èŠçŽ ã
ã€ãããããåŠçãããäœãããããã®ãã«ãŒã
ã€ã³ã°èŠçŽ ã¯åªæå€ãããããå«ãã§ãããããŸ
ãçŽæ¯æäœãçšããïŒé žåãã¿ã³ã§çè²ããå æ°Ž
å解ããã©ãšãã«ãªã«ãœã·ãªã±ãŒããšæ¶æ©çµåã
ãå æ°Žå解ããªïŒããã«ã¢ã»ããŒãïŒã§äžå¡ã
ãããã®ïŒåã®èŠçŽ ãå®æœäŸïŒãšåæ§ã«é²å ãã
èžçæ°Žã§10ç§éæŽãã氎济ïŒæ¯èŒäŸïŒïŒåã¯è²çŽ
济ïŒæ¯èŒäŸïŒïŒã§30ç§é浞ããã€ãã§20ç§éãã
ãçŸåããããªããçŸå枩床ã¯21âã§ãã€ããåŠ
çåŸãäž¡æ¹å ±åãããã«ç°è²ã®ç»åãæããŠã
ããæ¶æ©ãžã¢ãŸæš¹èåç¬ã«ããã¢ããªã³ç³»è²çŽ ã®
åªæå€ã¯äœãèŠãããªãã€ãã æ¯èŒäŸ ïŒ çžå¯Ÿã¹ããŒãïŒã«ããªã³ç³»è²çŽ ãæããåŸæ¥ã®
ãã«ãŒãã€ã³ã°èŠçŽ ãšã¢ããªã³ç³»è²çŽ ãæãã
æ¬çºæã®èŠçŽ å®æœäŸïŒãšåæ§ã«èŠçŽ ãã€ãã€ããäœããæå
æ§å±€ã«ã¯åªæå€ãå ¥ããªãã€ããã³ã³ãããŒã«ãš
ããŠãæ¬çºæãšåãèŠçŽ ãã€ãã€ãããã®èŠçŽ ã¯
第ïŒè¡šã®åªæå€M19ã1.5mg/dm2æå æ§å±€ã«å«ãŸ
ããŠãããåŸæ¥ã®èŠçŽ ãå®æœäŸïŒãšåãããã«é²
å ããåŠçããããããã«ããªã³ç³»è²çŽ ã¡ãã¬ã³
ãã«ãŒãçšãããã³ã³ãããŒã«èŠçŽ ããŸãå®æœäŸ
ïŒã«åŸã€ãŠé²å ãåŠçãããããã®å Žåã«ã¯PH
8.0ã®ãããã¢ãŒæº¶æ¶²äžã§ç¬¬ïŒè¡šã®ã¢ããªã³ç³»è²
çŽ D1ãçšãããåªæå€ã®ãªãåŸæ¥ã®èŠçŽ ã¯ã
ã³ã³ãã©ã¹ããæããŠããïŒã¬ã³ããŒ3.0察2.0ïŒ
ã«ããããããæ¬çºæã®ããããã0.75 logEã¹
ããŒããé ãã€ãã åŸã€ãŠãåŸæ¥ããç¥ãããŠãããžã¢ãŸæš¹èã«ã
ã€ãŠåªæãããã«ããªã³ç³»è²çŽ ã¯ã«ããªã³ç³»åªæ
å€ãå«ã¿ã¢ããªã³ç³»ã®è²çŽ ãçšããããšã®ã§ãã
æ¬çºæã®èŠçŽ ããåŸããããããªã¹ããŒããäžã
ãããšãã§ããªãã æ¯èŒäŸ ïŒ çžå¯Ÿã¹ããŒãããžã¢ãŸæš¹è察ãžã¢ãŸå¡© äžå¡ãã100ãã¯ãã³ã®åãã®ããªãšã¹ãã«æ¯
æäœäžã«æ¬¡ã®æº¶æ¶²ïŒ¢ã湿最æã®åãã25ãã¯ãã³
ã«ãªãããã«å¡åžããŠãã«ãŒãã€ã³ã°èŠçŽ ãã€ã
ã€ãïŒ
ãè¡šã
也ç¥åŸãå®æœäŸïŒã®é²å
ãåŠçæ³ãçšãããè¯
奜ãªç»åãåŸãããã«ã¯ãã®èŠçŽ ã¯é²å ã«ïŒåé
èŠãããå®æœäŸïŒã®èŠçŽ ã®é²å æéã«ããã¹ãã®
ããã«éåžžã«é·ãã®ã¯ããã®ãžã¢ãŸå¡©ãæ¬çºæã®
ãžã¢ãŸæš¹èãçšããå Žåã«åŸããã代衚çãªé²å
æé30ç§ã«ããã¹é ãããšãç«èšŒãããã®ã§ã
ãã æ¯èŒäŸ ïŒ äœ¿çšã§ããªãéåäœåªæå€ å®æœäŸïŒãšåæ§ã«ãã«ãŒãã€ã³ã°èŠçŽ ãã€ãã
åŠçãããäœããçšããåªæå€ã¯ããªãã¹ãã¬ã³
âã³âããã«ãã³ãžã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ããïŒïŒïŒïŒïŒã§ãã€ãããŸãè²çŽ 溶液ã¯
0.5ïŒ æ¿åºŠã§ãã€ãã ãã®å¡åžæº¶æ¶²ã®åºäœã¯å¡åžããåã«æ²æŸ±ããåª
æå€ã¯ãžã¢ãŸæš¹èãäžæº¶æ§ã«ããããã®åªæå€ã¯
çžå®¹æ§ããªããã®ã§ãã€ãã
奜ãªç»åãåŸãããã«ã¯ãã®èŠçŽ ã¯é²å ã«ïŒåé
èŠãããå®æœäŸïŒã®èŠçŽ ã®é²å æéã«ããã¹ãã®
ããã«éåžžã«é·ãã®ã¯ããã®ãžã¢ãŸå¡©ãæ¬çºæã®
ãžã¢ãŸæš¹èãçšããå Žåã«åŸããã代衚çãªé²å
æé30ç§ã«ããã¹é ãããšãç«èšŒãããã®ã§ã
ãã æ¯èŒäŸ ïŒ äœ¿çšã§ããªãéåäœåªæå€ å®æœäŸïŒãšåæ§ã«ãã«ãŒãã€ã³ã°èŠçŽ ãã€ãã
åŠçãããäœããçšããåªæå€ã¯ããªãã¹ãã¬ã³
âã³âããã«ãã³ãžã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯
ãã©ã€ããïŒïŒïŒïŒïŒã§ãã€ãããŸãè²çŽ 溶液ã¯
0.5ïŒ æ¿åºŠã§ãã€ãã ãã®å¡åžæº¶æ¶²ã®åºäœã¯å¡åžããåã«æ²æŸ±ããåª
æå€ã¯ãžã¢ãŸæš¹èãäžæº¶æ§ã«ããããã®åªæå€ã¯
çžå®¹æ§ããªããã®ã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (a) æå æ§ãå 硬åæ§ãžã¢ãŸæš¹èããã³ã (b) ãžã¢ãŸæš¹èãšçžå®¹æ§ã§ããããã€æš¹èãå 硬
åããããšãã«ãã¢ããªã³æ§ææãåŒãã€ãã
ãµã€ããšããŠããžã¢ãŸæš¹èãšå ±ã«ä¿çãããé
åäœã«ããªã³æ§åªæå€ãã®æ··åç©ãããªããŠãª
ã·ãŠã»ãªãæå æ§çµæç©ã
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US84087977A | 1977-10-11 | 1977-10-11 | |
| US05/874,970 US4220700A (en) | 1978-02-03 | 1978-02-03 | Continuous-tone dyed diazo imaging elements |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5465027A JPS5465027A (en) | 1979-05-25 |
| JPS6131856B2 true JPS6131856B2 (ja) | 1986-07-23 |
Family
ID=27126216
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12499178A Granted JPS5465027A (en) | 1977-10-11 | 1978-10-11 | Washhoff photosensitive composition and proofing element |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JPS5465027A (ja) |
| DE (1) | DE2844314A1 (ja) |
| FR (1) | FR2406230A1 (ja) |
| GB (1) | GB2007379B (ja) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5562274A (en) * | 1978-11-01 | 1980-05-10 | Morohoshi Printing Ink | Photosensitive dyeing composition |
| US4315978A (en) * | 1980-03-06 | 1982-02-16 | Eastman Kodak Company | Solid-state color imaging device having a color filter array using a photocrosslinkable barrier |
| CA1164707A (en) * | 1980-12-08 | 1984-04-03 | Hugh G. Mcguckin | Dye imbibition imaging material including cationic mordant layer and photosensitive polyesterionomer layer |
| JPS57147629A (en) * | 1981-03-07 | 1982-09-11 | Konishiroku Photo Ind Co Ltd | Image forming material |
| JPS57197537A (en) * | 1981-05-29 | 1982-12-03 | Konishiroku Photo Ind Co Ltd | Photosensitive composition |
| DE3328019A1 (de) * | 1982-09-21 | 1984-03-22 | Polychrome Corp., 10702 Yonkers, N.Y. | Mit wasser entwickelbare druckplatte |
| JPS59107345A (ja) * | 1982-12-10 | 1984-06-21 | Kuraray Co Ltd | çè²ç»å圢æçšææ |
| JPS59111639A (ja) * | 1982-12-17 | 1984-06-27 | Kuraray Co Ltd | çè²ç»å圢æçšææ |
| JPS59222842A (ja) * | 1983-06-01 | 1984-12-14 | Fuji Photo Film Co Ltd | å¹³çå°å·ççšæå æ§çµæç© |
| JPS61203449A (ja) * | 1985-03-06 | 1986-09-09 | Somar Corp | æå æ§çµæç© |
| JPH06103391B2 (ja) * | 1985-09-20 | 1994-12-14 | å¯å£«åçãã€ã«ã æ ªåŒäŒç€Ÿ | æå æ§èšé²ææ |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB341454A (en) * | 1929-07-15 | 1931-01-15 | Michele Luigi Martinez | Colour photography |
| US2349819A (en) * | 1941-06-12 | 1944-05-30 | Economy Oil Trucking Corp | Multicolor printing |
| BE543031A (ja) * | 1954-12-29 | |||
| US3486450A (en) * | 1964-02-27 | 1969-12-30 | Eastman Kodak Co | Color proofing system |
| BE713299A (ja) * | 1967-04-06 | 1968-08-16 | ||
| CA943694A (en) * | 1968-03-01 | 1974-03-12 | Hyman L. Cohen | Polymers and photographic elements containing same |
| NL174835C (nl) * | 1969-05-20 | 1984-08-16 | Hoechst Ag | Werkwijze voor het bereiden van een lichtgevoelig condensatieprodukt van een aromatische diazoniumverbinding. |
| DE2163883A1 (de) * | 1971-12-22 | 1973-06-28 | Klaus Schuengel | Kopierschichten fuer den flach- und offsetdruck |
| JPS516563B2 (ja) * | 1972-03-05 | 1976-02-28 | ||
| IT982883B (it) * | 1972-03-13 | 1974-10-21 | Somar Mfg | Elemento fotosensibile e procedi mento per fabbricare negative a finestra aperta |
| US3859096A (en) * | 1973-11-05 | 1975-01-07 | Eastman Kodak Co | Crosslinking polymeric dye mordants |
| US3958995A (en) * | 1974-11-19 | 1976-05-25 | Eastman Kodak Company | Photographic elements containing cross-linked mordants and processes of preparing said elements |
-
1978
- 1978-10-10 FR FR7828821A patent/FR2406230A1/fr active Granted
- 1978-10-11 DE DE19782844314 patent/DE2844314A1/de not_active Ceased
- 1978-10-11 JP JP12499178A patent/JPS5465027A/ja active Granted
- 1978-10-11 GB GB7840090A patent/GB2007379B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| FR2406230A1 (fr) | 1979-05-11 |
| JPS5465027A (en) | 1979-05-25 |
| GB2007379A (en) | 1979-05-16 |
| GB2007379B (en) | 1982-02-24 |
| DE2844314A1 (de) | 1979-04-12 |
| FR2406230B1 (ja) | 1980-07-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4808508A (en) | Negative working color proofing process comprising diazo compound and polyvinyl acetal/polyvinyl alcohol/polyvinyl acetate resin | |
| JPS61100748A (ja) | å€è²ç»åã®åœ¢ææ³ | |
| US4245031A (en) | Photopolymerizable compositions based on salt-forming polymers and polyhydroxy polyethers | |
| CA1111697A (en) | Light sensitive copying material containing a diazonium salt polycondensation product in a fish glue binder | |
| US2993788A (en) | Multicolor reproduction using light sensitive diazo oxides | |
| JPS6131856B2 (ja) | ||
| US4948693A (en) | Positive working color proofing system comprising polyvinyl acetal/polyvinyl alcohol/polyvinyl acetate resin | |
| US4220700A (en) | Continuous-tone dyed diazo imaging elements | |
| US3642474A (en) | Method for producing halftone multicolor images | |
| US5246818A (en) | Developer composition for positive working color proofing films | |
| US4291115A (en) | Elements and method which use photopolymerizable compositions based on salt-forming polymers and polyhydroxy polyethers | |
| JPS58219546A (ja) | æå äœ | |
| US4247615A (en) | Continuous-tone dyed diazo imaging process | |
| US5246812A (en) | Partially translucent white film having a metallized surface | |
| US5053310A (en) | Negative working diazo resin color proofing material comprising polyvinyl acetal/polyvinyl, alcohol/polyvinyl acetate resin | |
| JPS5965840A (ja) | çè²ç»åã®åœ¢ææ¹æ³ããã³ããã«äœ¿çšããããã®çè²ç»å圢æçšæå ææ | |
| JPS63101843A (ja) | ã«ã©ãŒç»åã圢æããæ¹æ³åã³æå æ§çŽ å | |
| EP0048160B1 (en) | Photosensitive recording material, and method of half-tone etching | |
| US4374194A (en) | Dye imbibition photohardenable imaging material and process for forming positive dye images | |
| CA1100806A (en) | Continuous-tone dyed diazo imaging elements | |
| US5360688A (en) | Composite black and white substrate for color proofing films | |
| US5288570A (en) | Composite black and white substrate for color proofing films | |
| EP0291537B1 (en) | Colored image-forming material and process for forming colored image | |
| JPH023063A (ja) | å€è²ç»åã®è£œæ³ | |
| US3793026A (en) | Photochemical reproduction process |