JPS6128732B2 - - Google Patents
Info
- Publication number
- JPS6128732B2 JPS6128732B2 JP54001417A JP141779A JPS6128732B2 JP S6128732 B2 JPS6128732 B2 JP S6128732B2 JP 54001417 A JP54001417 A JP 54001417A JP 141779 A JP141779 A JP 141779A JP S6128732 B2 JPS6128732 B2 JP S6128732B2
- Authority
- JP
- Japan
- Prior art keywords
- molybdenum
- uranium
- solution
- activated carbon
- ammonia
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 84
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 70
- 229910052750 molybdenum Inorganic materials 0.000 claims description 70
- 239000011733 molybdenum Substances 0.000 claims description 70
- 229910052770 Uranium Inorganic materials 0.000 claims description 51
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 51
- 239000000243 solution Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 34
- 239000012670 alkaline solution Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 9
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 21
- 235000011114 ammonium hydroxide Nutrition 0.000 description 20
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 18
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 18
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 238000002386 leaching Methods 0.000 description 12
- 239000002253 acid Substances 0.000 description 9
- 229910021529 ammonia Inorganic materials 0.000 description 9
- 238000000926 separation method Methods 0.000 description 9
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 239000001099 ammonium carbonate Substances 0.000 description 8
- 230000002378 acidificating effect Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 description 4
- 235000012501 ammonium carbonate Nutrition 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- 238000011109 contamination Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000007800 oxidant agent Substances 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000011609 ammonium molybdate Substances 0.000 description 2
- 235000018660 ammonium molybdate Nutrition 0.000 description 2
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 2
- 229940010552 ammonium molybdate Drugs 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000005554 pickling Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 description 2
- 229910000442 triuranium octoxide Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910000169 coffinite Inorganic materials 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 229910000439 uranium oxide Inorganic materials 0.000 description 1
- 229910000189 uranophane Inorganic materials 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Carbon And Carbon Compounds (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/869,338 US4199551A (en) | 1978-01-13 | 1978-01-13 | Recovery of molybdenum and uranium from activated charcoal containing molybdenum and residual uranium |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54101707A JPS54101707A (en) | 1979-08-10 |
| JPS6128732B2 true JPS6128732B2 (US20020095090A1-20020718-M00002.png) | 1986-07-02 |
Family
ID=25353366
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP141779A Granted JPS54101707A (en) | 1978-01-13 | 1979-01-12 | Recovery of molybdenum from uranium containing solution |
Country Status (10)
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4273745A (en) * | 1979-10-03 | 1981-06-16 | Amax Inc. | Production of molybdenum oxide from ammonium molybdate solutions |
| IT1127300B (it) * | 1979-12-19 | 1986-05-21 | Euteco Impianto Spa | Procedimento per il recupero di composti del molibdeno |
| FR2531060B1 (fr) * | 1982-07-28 | 1986-07-04 | Cogema | Procede de recuperation du molybdene sur charbon actif, a partir d'une solution uranifere acide contenant plus de molybdene que d'uranium |
| US4584184A (en) * | 1984-05-21 | 1986-04-22 | Allied Corporation | Separation and recovery of molybdenum values from uranium process waste |
| ES2004072A6 (es) * | 1986-01-23 | 1988-12-01 | France Mokta Comp | Procedimiento para la separacion de molibdeno por via resina |
| US20100084327A1 (en) * | 2008-09-16 | 2010-04-08 | Paul Goranson | Recovery and precipitation of various elements and compounds |
| US9567237B2 (en) | 2012-11-16 | 2017-02-14 | Honeywell International Inc. | Separation and recovery of molybdenum values from uranium process distillate |
| CN116240374B (zh) * | 2023-05-06 | 2023-07-25 | 中核沽源铀业有限责任公司 | 一种低成本高收率的铀钼矿尾渣工业化冶炼方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2901314A (en) * | 1950-03-22 | 1959-08-25 | Spears P Vavalides | Removal of uranium from organic liquids |
| US2819944A (en) * | 1954-01-26 | 1958-01-14 | Howard L Wibbles | Purification process |
| US3288570A (en) * | 1963-08-16 | 1966-11-29 | Susquehanna Western Inc | Process for the selective recovery of uranium, zirconium and molybdenum |
| US3307938A (en) * | 1964-04-27 | 1967-03-07 | American Metal Climax Inc | Process for extracting metal values |
| US3790658A (en) * | 1970-05-15 | 1974-02-05 | Union Carbide Corp | Purification process for recovering uranium from an acidic aqueous solution by ph control |
| US3940318A (en) * | 1970-12-23 | 1976-02-24 | Union Carbide Corporation | Preparation of a primary target for the production of fission products in a nuclear reactor |
| US3799883A (en) * | 1971-06-30 | 1974-03-26 | Union Carbide Corp | Production of high purity fission product molybdenum-99 |
| US4092399A (en) * | 1976-12-01 | 1978-05-30 | Atlantic Richfield Company | Recovery of uranium from carbonate leach solutions |
-
1978
- 1978-01-13 US US05/869,338 patent/US4199551A/en not_active Expired - Lifetime
- 1978-12-19 AU AU42673/78A patent/AU509367B2/en not_active Expired
-
1979
- 1979-01-04 DE DE19792900257 patent/DE2900257A1/de not_active Ceased
- 1979-01-10 ZA ZA79104A patent/ZA79104B/xx unknown
- 1979-01-10 CA CA319,379A patent/CA1104830A/en not_active Expired
- 1979-01-10 FR FR7900551A patent/FR2414478A1/fr active Granted
- 1979-01-10 BR BR7900138A patent/BR7900138A/pt unknown
- 1979-01-11 GB GB791098A patent/GB2012253B/en not_active Expired
- 1979-01-12 JP JP141779A patent/JPS54101707A/ja active Granted
- 1979-01-12 OA OA56706A patent/OA06147A/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU4267378A (en) | 1979-07-19 |
| GB2012253B (en) | 1982-06-30 |
| US4199551A (en) | 1980-04-22 |
| JPS54101707A (en) | 1979-08-10 |
| ZA79104B (en) | 1980-01-30 |
| CA1104830A (en) | 1981-07-14 |
| FR2414478A1 (fr) | 1979-08-10 |
| OA06147A (fr) | 1981-06-30 |
| AU509367B2 (en) | 1980-05-08 |
| DE2900257A1 (de) | 1979-07-19 |
| GB2012253A (en) | 1979-07-25 |
| FR2414478B1 (US20020095090A1-20020718-M00002.png) | 1984-06-22 |
| BR7900138A (pt) | 1979-08-14 |
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