JPS6128726B2 - - Google Patents
Info
- Publication number
- JPS6128726B2 JPS6128726B2 JP55092499A JP9249980A JPS6128726B2 JP S6128726 B2 JPS6128726 B2 JP S6128726B2 JP 55092499 A JP55092499 A JP 55092499A JP 9249980 A JP9249980 A JP 9249980A JP S6128726 B2 JPS6128726 B2 JP S6128726B2
- Authority
- JP
- Japan
- Prior art keywords
- extraction
- organic solvent
- ethylhexyl
- phosphoric acid
- extractant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000605 extraction Methods 0.000 claims description 78
- 239000003960 organic solvent Substances 0.000 claims description 47
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims description 27
- 239000010941 cobalt Substances 0.000 claims description 22
- 229910017052 cobalt Inorganic materials 0.000 claims description 22
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 22
- 150000002148 esters Chemical class 0.000 claims description 22
- 229910052751 metal Inorganic materials 0.000 claims description 22
- 239000002184 metal Substances 0.000 claims description 22
- 239000002253 acid Substances 0.000 claims description 20
- -1 2-ethylhexyl group Chemical group 0.000 claims description 10
- 239000003085 diluting agent Substances 0.000 claims description 9
- 239000003701 inert diluent Substances 0.000 claims description 5
- 239000003350 kerosene Substances 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- 230000002401 inhibitory effect Effects 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 8
- 150000002739 metals Chemical class 0.000 description 8
- 238000000638 solvent extraction Methods 0.000 description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 7
- 238000002474 experimental method Methods 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 229910052738 indium Inorganic materials 0.000 description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000012074 organic phase Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- ZDFBXXSHBTVQMB-UHFFFAOYSA-N 2-ethylhexoxy(2-ethylhexyl)phosphinic acid Chemical compound CCCCC(CC)COP(O)(=O)CC(CC)CCCC ZDFBXXSHBTVQMB-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- QJJHQIDBFYJADS-UHFFFAOYSA-N 8-methylnonylphosphonic acid Chemical compound CC(C)CCCCCCCP(O)(O)=O QJJHQIDBFYJADS-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OOAOQKBSQVZVET-UHFFFAOYSA-N 2-ethylhexyl(8-methylnonoxy)phosphinic acid Chemical compound CCCCC(CC)CP(O)(=O)OCCCCCCCC(C)C OOAOQKBSQVZVET-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- JJJOZVFVARQUJV-UHFFFAOYSA-N 2-ethylhexylphosphonic acid Chemical compound CCCCC(CC)CP(O)(O)=O JJJOZVFVARQUJV-UHFFFAOYSA-N 0.000 description 1
- RPMDUPHXLGPJKL-UHFFFAOYSA-N 3,5,5-trimethylhexylphosphonic acid Chemical compound CC(C)(C)CC(C)CCP(O)(O)=O RPMDUPHXLGPJKL-UHFFFAOYSA-N 0.000 description 1
- JLCLWEMPUJATFG-UHFFFAOYSA-N 8-methylnonoxy(8-methylnonyl)phosphinic acid Chemical compound CC(C)CCCCCCCOP(O)(=O)CCCCCCCC(C)C JLCLWEMPUJATFG-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 125000004122 cyclic group Chemical class 0.000 description 1
- HCIQUGMKXQZZMG-UHFFFAOYSA-N ethyl hexyl hydrogen phosphate Chemical compound CCCCCCOP(O)(=O)OCC HCIQUGMKXQZZMG-UHFFFAOYSA-N 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Extraction Or Liquid Replacement (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Detergent Compositions (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9249980A JPS5719340A (en) | 1980-07-07 | 1980-07-07 | Organic solvent for extracting metal |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9249980A JPS5719340A (en) | 1980-07-07 | 1980-07-07 | Organic solvent for extracting metal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5719340A JPS5719340A (en) | 1982-02-01 |
| JPS6128726B2 true JPS6128726B2 (enrdf_load_stackoverflow) | 1986-07-02 |
Family
ID=14055988
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9249980A Granted JPS5719340A (en) | 1980-07-07 | 1980-07-07 | Organic solvent for extracting metal |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5719340A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6418031U (enrdf_load_stackoverflow) * | 1987-07-21 | 1989-01-30 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055972C (zh) * | 1995-12-30 | 2000-08-30 | 内蒙古包钢稀土高科技股份有限公司 | 生产低镁低锌混合稀土金属的方法 |
| JP7156491B1 (ja) * | 2021-04-22 | 2022-10-19 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| JP7099592B1 (ja) * | 2021-06-25 | 2022-07-12 | 住友金属鉱山株式会社 | 硫酸コバルトの製造方法 |
| CN118127325B (zh) * | 2024-02-23 | 2024-11-05 | 湖南金源新材料循环利用有限公司 | 一种分离钴镁的萃取工艺 |
-
1980
- 1980-07-07 JP JP9249980A patent/JPS5719340A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6418031U (enrdf_load_stackoverflow) * | 1987-07-21 | 1989-01-30 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5719340A (en) | 1982-02-01 |
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