JPS61262446A - Method for forming finer crystal grains of al or al alloy - Google Patents

Method for forming finer crystal grains of al or al alloy

Info

Publication number
JPS61262446A
JPS61262446A JP10106185A JP10106185A JPS61262446A JP S61262446 A JPS61262446 A JP S61262446A JP 10106185 A JP10106185 A JP 10106185A JP 10106185 A JP10106185 A JP 10106185A JP S61262446 A JPS61262446 A JP S61262446A
Authority
JP
Japan
Prior art keywords
alloy
crystal grains
finer crystal
agent
grain
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP10106185A
Other languages
Japanese (ja)
Other versions
JPH0112821B2 (en
Inventor
Yukio Sugishita
幸男 杉下
Yoshihiro Mitsuta
美蔦 芳宏
Takao Furukawa
古川 隆夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kobe Steel Ltd
Original Assignee
Kobe Steel Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kobe Steel Ltd filed Critical Kobe Steel Ltd
Priority to JP10106185A priority Critical patent/JPS61262446A/en
Publication of JPS61262446A publication Critical patent/JPS61262446A/en
Publication of JPH0112821B2 publication Critical patent/JPH0112821B2/ja
Granted legal-status Critical Current

Links

Abstract

PURPOSE:To form efficiently the finer crystal grains of an Al or Al alloy casting by filtering the melt of the Al or Al alloy to remove inclusions, etc. therefrom then adding continuously an agent for forming the finer crystal grains to the filtered melt while filtering said agent. CONSTITUTION:The melt of the Al or Al alloy is filtered to remove Al2O3 and other impurity inclusions therefrom and thereafter the agent for forming the finer crystal grains which is made into a rod shape and contains comps. such as Al-Ti-B is added thereto by using sintered aggregate consisting of 15-30 mesh refractories as the filter for the agent for forming the finer crystal grains. The finer crystal grains of the casting of the Al and Al alloy are stably and effectively formed by adding the agent for forming the finer crystal grains while the coarse oxide and TiB2 contained therein are filtered.

Description

【発明の詳細な説明】 [産業上の利用分野1 本発明はAl*たけAl合金の結晶粒微細化方法に関し
、さらに詳しくは、アルミニウムまたはアルミニウム合
金の鋳造に際して清浄にした結晶粒微細化剤を添加する
AlまたはAl合金の結晶粒微細化方法に関する。
Detailed Description of the Invention [Industrial Application Field 1] The present invention relates to a method for refining the crystal grains of Al*Takashi Al alloy, and more specifically, the present invention relates to a method for refining grains of Al*Takashi Al alloy. The present invention relates to a method for grain refinement of added Al or Al alloy.

[従来技術] 一般に圧延遣たは押出し製品の表面の特性に要求の厳し
いAl*たはAl合金には、結晶粒微細化剤に含まれて
いる酸化物や凝集T i B 2等による表面欠陥を防
止するため、AlまたはAl合金溶湯を濾過する前の工
程において結晶粒微細化剤を添加し、また、表面特性の
要求が緩やかなAtまたはAl合金においては溶湯の濾
過後に結晶粒微細化剤を添加することが行なわれていた
[Prior Art] In general, Al* or Al alloys that have strict requirements for the surface characteristics of rolled or extruded products have surface defects caused by oxides contained in grain refiners, agglomerated TiB2, etc. In order to prevent this, a grain refining agent is added in the process before filtration of Al or Al alloy molten metal, and for At or Al alloys with mild surface property requirements, a grain refining agent is added after filtration of the molten metal. was being added.

しかして、前者においては、AlまたはAl合金溶湯の
濾過処理量に応じてAl溶湯中に含まれる介在物等によ
りフィルターに目詰りを生じ、微細化の核が濾過され結
晶粒微細化効果はAl処理量が数十〜百数十屯程度しか
維持することができず、また、後者においては、結晶粒
微細化効果は安定しているが結晶粒微細化剤に含まれる
酸化物や凝集T i B 2が鋳塊に混入することによ
り線状欠陥等を生じるという問題がある。
However, in the former case, depending on the amount of filtered Al or Al alloy molten metal, the filter is clogged with inclusions contained in the Al molten metal, and the grain refinement effect is reduced by filtering out the grain refinement nuclei. In the latter case, although the grain refining effect is stable, oxides contained in the grain refining agent and agglomerated Ti There is a problem in that linear defects and the like are caused by B2 mixed into the ingot.

[発明が解決しよ)とする問題点】 本発明は上記に説明したような従来技術における種々の
問題点を解消したものであって、AlまたはAl合金の
表面特性の厳しいもの、*た、比較的表面特性の緩いも
のの何れの場合においても、常に安定してAlまたはA
l合金溶湯の鋳造に際して結晶粒を微細化することがで
きるAlまたはAl合金の結晶粒微細化方法を堤仇する
ものである。
[Problems to be Solved by the Invention] The present invention solves the various problems in the prior art as explained above. Even in cases where the surface properties are relatively mild, Al or A remains stable.
This invention opposes a method for refining the crystal grains of Al or Al alloy, which can refine the crystal grains during casting of molten Al alloy.

[問題点を解決するための手段1 本発明に係るAlまたはAl合金の結晶粒微細化方法の
特徴とするところは、 アルミニウムまたはアルミニウム合金溶湯を濾過後、こ
の濾過されたアルミニウムまたはアルミニウム合金溶湯
に結晶粒微細化剤を濾過しながら連続添加することにあ
る。
[Means for Solving the Problems 1] The method for refining grains of Al or Al alloy according to the present invention is characterized by: After filtering aluminum or aluminum alloy molten metal, the filtered aluminum or aluminum alloy molten metal is The purpose is to continuously add the grain refining agent while filtering it.

本発明に係るAlまたはAl合金の結晶粒微細化方法に
ついて以下詳細に説明する。
The method for grain refinement of Al or Al alloy according to the present invention will be described in detail below.

上記に説明したように、AlまたはAl合金(以下単に
Alということがある。)を安定に結晶粒を微細化する
ためには、AlまたはAl合金溶湯(以下単にAl溶湯
ということがある。)を濾過後に結晶粒微細化剤を連続
添加しなければならず、この場合には圧延または押し製
品の表面欠陥の原因となる結晶粒微細化剤に混入してい
る異物がAl11塊内に混入することがある。
As explained above, in order to stably refine the crystal grains of Al or Al alloy (hereinafter sometimes simply referred to as Al), it is necessary to use molten Al or Al alloy (hereinafter simply referred to as molten Al). After filtration, a grain refining agent must be added continuously, and in this case, foreign matter mixed in the grain refining agent, which causes surface defects in rolled or pressed products, may be mixed into the Al11 lump. Sometimes.

そして、本発明に係るAlまたはAl合金の結晶粒微細
化方法においては、Al溶湯を濾過した後で、このAl
1lに、例えば、15〜30メツシユの耐火物骨材を焼
結したものを結晶粒微細化剤の濾過器として設置して、
結晶粒微細化剤(通常は連続添加のためロッドとなって
いる。)の内および表面に存在している粗大酸化物およ
び凝集したTiB2を除去してから連続的に添加するも
のである。
In the method for refining grains of Al or Al alloy according to the present invention, after filtering the molten Al, the Al
For example, a sintered refractory aggregate of 15 to 30 meshes is installed in 1 liter as a filter for the grain refining agent.
The grain refiner is added continuously after removing coarse oxides and agglomerated TiB2 present in and on the surface of the grain refiner (usually in the form of a rod due to continuous addition).

この°上うに、酸化物や凝集TiBz等を濾過されて清
浄になった結晶粒微細化剤がAl溶湯に連続的に添加さ
れるので、鋳造されたAtの表面には何等の欠陥のない
優れたisが得られる。
In this way, since the crystal grain refining agent, which has been purified by filtering out oxides and agglomerated TiBz, is continuously added to the molten Al, the surface of the cast At is free from any defects. is obtained.

しかして、ロッド状の結晶粒微細化剤をAl溶湯の濾過
器の前に添加した場合、結晶粒微細化剤に含まれる表面
欠陥の原因となる異物の濾過効果はあるが、同時にAl
溶湯中に含まれる多量の介在物等も濾過されて濾過器表
面に吸着されるので、Al溶湯の処理量に応じて濾過能
力が増加し、Al溶湯において結晶粒微細化の核となる
TiB2をも濾過されてしまい、微細化効果はAl溶湯
の処理量と共に減少するが、上記に説明したように本発
明に係るAl*たはAl合金の結晶粒微細化方法におい
ては、Al溶湯を濾過した後で、結晶粒微細化剤のみを
濾過するのでこの濾過器の表面に吸着されるのは結晶粒
微細化剤のみの介在物だけで極めてWI量であるので、
結晶粒微細化剤はAl溶湯中に有効に含まれ安定した微
細化効果が得られる。
However, when a rod-shaped grain refiner is added before a filter for molten Al, it has the effect of filtering out foreign substances that cause surface defects contained in the grain refiner, but at the same time
A large amount of inclusions contained in the molten metal are also filtered and adsorbed on the filter surface, so the filtration capacity increases according to the amount of molten Al processed, and TiB2, which is the core of crystal grain refinement, is removed from the molten Al. However, as explained above, in the method for refining grains of Al* or Al alloy according to the present invention, the molten Al is filtered. Later, since only the grain refiner is filtered, what is adsorbed on the surface of this filter is only the inclusions of the grain refiner, which is a very large amount.
The grain refining agent is effectively contained in the molten Al, and a stable refining effect can be obtained.

[実施例1 本発明に係るAlまたはAl合金の結晶粒微細化方法の
実施例を説明する。
[Example 1] An example of the method for grain refinement of Al or Al alloy according to the present invention will be described.

実施例I Al溶湯を濾過した後に、結晶粒微細化剤(ロッド状の
Al−Ti−B)のみの濾過器<15〜30/ツシユの
耐火物を焼結した濾過器)により濾過してAl溶湯に連
続的に添加して鋳造する。
Example I After filtering Al molten metal, it is filtered using a filter containing only a crystal grain refining agent (rod-shaped Al-Ti-B <15 to 30/filter made of sintered refractory) to remove Al. It is continuously added to molten metal and cast.

その結果、製品表面には線状欠陥は認められず、結晶粒
3III11以下の安定した結晶粒微細化効果が得られ
た。
As a result, no linear defects were observed on the product surface, and a stable crystal grain refinement effect of 3III11 or less crystal grains was obtained.

比較例I Al溶湯の濾過器の前でA I−T i −Bの結晶粒
微細化剤を添加した場合、この微細化剤の添加初期にお
いては微細化効果は認められるが、100〜200屯程
度のAl溶湯の処理を行なうとAl溶湯中に含まれてい
る介在物によって濾過器が目詰りして、微細化剤のTi
B2も共に濾過されてしまい、次第に結晶粒微細化効果
は少なくなってくる。
Comparative Example I When A I-T i -B crystal grain refiner is added in front of the filtration device for molten Al, the grain refiner effect is observed in the initial stage of addition of this refiner, but after 100 to 200 tons. If molten Al is processed to a certain extent, the filter will be clogged with inclusions contained in the molten Al, and the Ti finer will be removed.
B2 is also filtered out, and the crystal grain refinement effect gradually decreases.

従って、結晶粒が3■以下となる微細化効果はAl溶湯
処理量が50〜150屯程度までしか得られない。
Therefore, the refinement effect of reducing the crystal grain size to 3 cm or less can only be obtained when the amount of molten Al processed is about 50 to 150 tons.

比較例2 Al溶湯の濾過後において、結晶粒微細化剤ロッドのA
l−Ti  Bを連続添加すると、この結晶粒微細化剤
に含まれている粗大酸化物および凝集T ! B 2が
Al1)塊中に混入することになって、表面欠陥が発生
する。この表面欠陥は線状欠陥である。
Comparative Example 2 After filtering molten Al, A of the grain refiner rod
When l-TiB is continuously added, the coarse oxides contained in this grain refiner and the agglomeration T! B2 is mixed into the Al1) lump, causing surface defects. This surface defect is a linear defect.

[発明の効果1 以上説明した五うに、本発明に係るAlまたはAl合金
の結晶粒微細化方法は上記の構成を有しているものであ
るから、従来法においてはAlまたはAl合金鋳塊の結
晶粒の微細化には制約力fあったが、殆んど全べてのA
lまたはAl合金に適用することが可能であり、さらに
、安定した結晶粒微細化効果を得ることができるという
優れた方法である。
[Effect of the invention 1 As explained above, the method for grain refining of Al or Al alloy according to the present invention has the above configuration, so in the conventional method, the method for refining the grains of Al or Al alloy ingot is Although there was a constraining force f on grain refinement, almost all A
This is an excellent method that can be applied to L or Al alloys, and can also provide a stable grain refinement effect.

Claims (1)

【特許請求の範囲】[Claims] アルミニウムまたはアルミニウム合金溶湯を濾過後、こ
の濾過されたアルミニウムまたはアルミニウム合金溶湯
に結晶粒微細化剤を濾過しながら連続添加することを特
徴とするAlまたはAl合金の結晶粒微細化方法。
A method for refining grains of Al or Al alloy, which comprises filtering aluminum or molten aluminum alloy, and then continuously adding a grain refining agent to the filtered molten aluminum or aluminum alloy while filtering.
JP10106185A 1985-05-13 1985-05-13 Method for forming finer crystal grains of al or al alloy Granted JPS61262446A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10106185A JPS61262446A (en) 1985-05-13 1985-05-13 Method for forming finer crystal grains of al or al alloy

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10106185A JPS61262446A (en) 1985-05-13 1985-05-13 Method for forming finer crystal grains of al or al alloy

Publications (2)

Publication Number Publication Date
JPS61262446A true JPS61262446A (en) 1986-11-20
JPH0112821B2 JPH0112821B2 (en) 1989-03-02

Family

ID=14290596

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10106185A Granted JPS61262446A (en) 1985-05-13 1985-05-13 Method for forming finer crystal grains of al or al alloy

Country Status (1)

Country Link
JP (1) JPS61262446A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0666329A1 (en) * 1994-02-08 1995-08-09 VAW Aluminium AG Aluminium strip for offset printing plates
EP1217084A3 (en) * 2000-11-09 2003-05-21 VAW Aluminium AG Apparatus for the filtration and addition of grain refining agent to melts

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0666329A1 (en) * 1994-02-08 1995-08-09 VAW Aluminium AG Aluminium strip for offset printing plates
EP1217084A3 (en) * 2000-11-09 2003-05-21 VAW Aluminium AG Apparatus for the filtration and addition of grain refining agent to melts

Also Published As

Publication number Publication date
JPH0112821B2 (en) 1989-03-02

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