JPS6393467A - Net-like filter having excellent slag removing capacity - Google Patents

Net-like filter having excellent slag removing capacity

Info

Publication number
JPS6393467A
JPS6393467A JP23855486A JP23855486A JPS6393467A JP S6393467 A JPS6393467 A JP S6393467A JP 23855486 A JP23855486 A JP 23855486A JP 23855486 A JP23855486 A JP 23855486A JP S6393467 A JPS6393467 A JP S6393467A
Authority
JP
Japan
Prior art keywords
filter
net
glass fibers
slag
woven fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23855486A
Other languages
Japanese (ja)
Other versions
JP2514006B2 (en
Inventor
Shigezo Fukuda
福田 繁三
Toshiya Amakasu
天粕 壽也
Shoichi Yoshino
吉野 彰一
Takeshi Ugata
健 宇賀田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kubota Corp filed Critical Kubota Corp
Priority to JP23855486A priority Critical patent/JP2514006B2/en
Publication of JPS6393467A publication Critical patent/JPS6393467A/en
Application granted granted Critical
Publication of JP2514006B2 publication Critical patent/JP2514006B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D43/00Mechanical cleaning, e.g. skimming of molten metals
    • B22D43/001Retaining slag during pouring molten metal
    • B22D43/004Retaining slag during pouring molten metal by using filtering means

Abstract

PURPOSE:To improve the capacity to remove scum, slag, etc. suspended and floated in a molten metal by specifying the components of glass fibers and shape retaining material of a net-like filter formed of the glass fibers. CONSTITUTION:The shape retaining agent is deposited on the net-like woven fabric formed of the glass fibers by which the net-like filter is formed. The glass fibers to be used to form such net-like filter are specified in the content of SiO2 to >=75wt%. The shape retaining material prepd. by adding natural pumice powder to a binder is used for said filter. The net-like filter which has the high slag removing capacity and is usable for filtering a molten high melting metal is obtd. in the above-mentioned manner.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、鋳鉄や鋳鋼溶湯中に懸濁浮遊しているノロ、
スラグ等の非金属介在物の除去能力に優れた綿状フィル
ターに関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention is directed to the treatment of slag suspended in cast iron or molten cast steel.
This invention relates to a cotton-like filter that has excellent ability to remove non-metallic inclusions such as slag.

(従来の技術) 従来、SiO□含有量の低いガラス繊維を網目状に織製
した網状織布にフェノール樹脂等の保形剤を被着させて
保形性を付与した網状フィルターがある。
(Prior Art) Conventionally, there is a mesh filter in which a shape retention agent such as a phenol resin is coated on a mesh woven fabric made of glass fibers with a low SiO□ content to impart shape retention properties.

この網状フィルターは、アルミやその合金等の低融点金
属溶湯濾過用フィルターとして使用され、溶湯中のノロ
等の除去作用が優れているため注目されている。
This mesh filter is used as a filter for filtering molten metals with low melting points such as aluminum and its alloys, and is attracting attention because of its excellent ability to remove slag and the like from the molten metal.

(発明が解決しようとする問題点) しかしながら、かかる綱状フィルターは、耐熱性に劣る
ので、高融点の鋳鉄や鋳鋼の溶湯濾過用フィルターとし
て使用することができない。
(Problems to be Solved by the Invention) However, such a wire filter has poor heat resistance and cannot be used as a filter for filtrating molten metal of cast iron or cast steel having a high melting point.

そこで、本発明者は、特願昭60−235032号にお
いて、高融点溶湯に対しても使用できるガラス繊維製網
状フィルターを提案した。
Therefore, in Japanese Patent Application No. 60-235032, the present inventor proposed a glass fiber mesh filter that can be used even for high melting point molten metals.

本発明者が提案した網状フィルターは、ガラス繊維中の
SiO□含有量を75重量%以上にすることで、耐熱性
を向上させ、高融点金属溶湯に対しても適用可能にした
ものである。
The reticular filter proposed by the present inventor has improved heat resistance by increasing the SiO□ content in the glass fiber to 75% by weight or more, making it applicable to high-melting-point molten metals.

上記網状フィルターによって、鋳鉄や鋳鋼?8湯の′濾
過が可能になったが、除滓能力のより一層の向上が要望
されている。
Is it cast iron or cast steel depending on the above mesh filter? Although it has become possible to filter 8 hot water, there is a need for further improvement in the slag removal ability.

本発明はかかる要望に鑑みなされたもので、除滓能力に
優れた高融点金属溶湯濾過用の綿状フィルターを提供す
ることを目的とする。
The present invention was made in view of such a need, and an object of the present invention is to provide a cotton-like filter for filtration of high melting point metal molten metal that has excellent sludge removal ability.

(問題点を解決するだめの手段) 斜上の目的を達成するために講じられた本発明の手段は
、網状織布を形成するガラス繊維として、SiO□含有
量が75重量%以上のものを用い、該ガラス繊維で形成
された綱状織布に保形性を与えるための保形剤として、
粘結剤に天然軽石粉末が添加されたものを用いる点にあ
る。
(Another Means to Solve the Problem) The means of the present invention taken to achieve the purpose of slanting is to use glass fibers containing 75% by weight or more of SiO□ as the glass fibers forming the reticulated woven fabric. As a shape-retaining agent for imparting shape-retaining properties to the rope-like woven fabric formed from the glass fibers,
The key point is that natural pumice powder is used as a binder.

(作用および実施例) 本発明の網状フィルターの素材として用いられる網状織
布は、直径3〜9μmでSiO□組成が75重量%以上
のガラス長繊維を束ねたものを織製して形成される。
(Operations and Examples) The reticulated woven fabric used as the material for the reticulated filter of the present invention is formed by weaving a bundle of long glass fibers with a diameter of 3 to 9 μm and an SiO□ composition of 75% by weight or more. .

Sin2組成を75重量%以上にするのは、1450℃
以下のあらゆる種類の鋳鉄溶湯に適合させるためである
。5102が高純度のものでは、1500℃以上の鋳鋼
付溶湯に対しても適合可能になる。ここに、適合とは溶
湯中に20秒間浸漬しても繊維がスラグ化しないことを
いう。前記20秒間は、通常、注湯時間はこの程度以下
であるところから設定されたものである。
Setting the Sin2 composition to 75% by weight or more is at 1450°C.
This is to make it compatible with all types of molten cast iron. If 5102 is of high purity, it can be applied to molten metal with cast steel of 1500°C or higher. Here, compatibility means that the fibers do not turn into slag even when immersed in molten metal for 20 seconds. The above-mentioned 20 seconds was set because the pouring time is usually within this range.

尚、ガラス繊維のSin、含有量を上げるには、ガラス
繊維に酸性処理を施せばよい。ずなわら、塩酸、硝酸、
硫酸などの酸性溶液に反応促進のだめの触媒を加えた溶
液中に、シリカを主成分としたガラス繊維を浸漬し、温
度、時間、酸性溶液の濃度をコントロールしながら不純
物であるCab、 MgO。
Incidentally, in order to increase the Sin content of the glass fibers, the glass fibers may be subjected to acid treatment. Zunawara, hydrochloric acid, nitric acid,
Glass fibers mainly composed of silica are immersed in an acidic solution such as sulfuric acid and a catalyst to accelerate the reaction, and impurities such as Cab and MgO are removed while controlling the temperature, time, and concentration of the acidic solution.

Fe201+ Cr20s+ Na2021 K2O1
Ti0z、  B20sなどの含有率を下げ、その結果
として5i02の含有量を上げるのである。
Fe201+ Cr20s+ Na2021 K2O1
The content of Ti0z, B20s, etc. is lowered, and as a result, the content of 5i02 is increased.

網状織布の目開きサイズは、溶湯中のノロやスラグ等の
大きさにもよるが、通常、0.4〜4iで充分である。
The opening size of the reticulated woven fabric depends on the size of slag, slag, etc. in the molten metal, but 0.4 to 4i is usually sufficient.

網状織布は、下記の保形剤を被着させて保形性を付与す
る前に、焼成により予め収縮させておくのがよい。その
理由は、酸性処理されたシリカ繊維中には多くの気孔が
存在しており、この気孔のため濾過中に綱状織布が収縮
する。この収縮が太きいと、溶湯流路にセントされ、上
型と下型とによって鋳型見切り面に挟持された網状フィ
ルターは、フィルターの押え部の鋳物砂を溶湯中にかき
落して砂かみなどの鋳造欠陥を誘発させたり、鋳型の砂
硬度が高い場合はフィルターを損傷させたりするからで
ある。
It is preferable that the net-like woven fabric is previously shrunk by firing before being coated with the following shape-retaining agent to impart shape-retaining properties. The reason for this is that there are many pores in the acid-treated silica fibers, and these pores cause the rope-like woven fabric to shrink during filtration. If this contraction is large, the mesh filter, which is inserted into the molten metal flow path and sandwiched between the upper mold and the lower mold parting surface, will scrape the molding sand from the filter holding part into the molten metal, causing the sand filter to drain into the molten metal. This is because it may induce casting defects or damage the filter if the sand hardness of the mold is high.

焼成温度が高くかつ焼成時間が長いほど加熱収縮率は大
きくなり、網状フィルターの収縮は小さくなって好都合
であるが、通常、加熱収縮率は2゜5〜15%で充分で
ある。尚、加熱収縮率とは、焼成前の繊維束(糸)の長
さを2、焼成後の長さをl′としたとき、100 X 
(1−7!°)/*で表わされる。
The higher the firing temperature and the longer the firing time, the higher the heat shrinkage rate and the smaller the shrinkage of the mesh filter, which is advantageous, but usually a heat shrinkage rate of 2.5 to 15% is sufficient. The heat shrinkage rate is 100 X, where the length of the fiber bundle (thread) before firing is 2 and the length after firing is l'.
It is expressed as (1-7!°)/*.

尚、上記加熱収縮率は800℃X30分乃至1)00℃
×5〜10分程度の焼成により得られる。1)00℃を
越えるとシリカ繊維がクリストバライト変態を起こし脆
化するので、焼成温度は1)00’C以下で行うことが
必要である。
In addition, the above heating shrinkage rate is 800℃ x 30 minutes to 1) 00℃
* Obtained by firing for about 5 to 10 minutes. 1) If the temperature exceeds 00°C, the silica fiber undergoes cristobalite transformation and becomes brittle, so the firing temperature must be 1) 00'C or lower.

網状織布に保形性を与えるための保形剤は、粘結剤と天
然軽石粉末との混合物が用いられる。
A mixture of a binder and natural pumice powder is used as a shape retaining agent to impart shape retaining properties to the reticulated woven fabric.

粘結剤としては、酸性ノボラック系フェノールレジン、
中性フェノールレジン、澱粉糊、酸性シリカゾル溶液等
を例示できる。
As a binder, acidic novolak phenol resin,
Examples include neutral phenol resin, starch paste, and acidic silica sol solution.

粘結剤に添加される天然軽石は、網状フィルター構成の
シリカ長繊維と同一のSiO□分を約70%、A I2
. Chを約17%含有しており、スラグ吸着表面積を
大きくする為に粒状に粉砕したものを用いる。
The natural pumice added to the binder contains about 70% SiO□, which is the same as the silica long fibers in the network filter structure, and A I2
.. It contains approximately 17% Ch, and is used in pulverized form to increase the slag adsorption surface area.

天然軽石の成分が酸性のSiO□より成ることから吸着
されるスラグはCaO、MgOの塩基性スラグが主であ
る。
Since the component of natural pumice is acidic SiO□, the slag that is adsorbed is mainly basic slag of CaO and MgO.

天然軽石の粒度は、60メツシュ以上の微粉がよい。6
0メソシユ以下の粗粉では、使用粘結剤中に充分攪拌混
合されず、網状織布に均一に塗布されにくい。
The particle size of natural pumice is preferably 60 mesh or more. 6
If the coarse powder is less than 0 mesosinus, it will not be sufficiently stirred and mixed into the binder used, and it will be difficult to uniformly apply it to the reticulated woven fabric.

また、天然軽石の保形剤に占める含有量は、体積%で5
〜30%がよい。5%未満では、粘結剤に混合して網状
織布に塗布後、フィルターとして使用した時、顕著なス
ラグ吸着効果の向上が認められず、30%を越えると網
状織布に塗布の際、目づまりを起こしやすい。
In addition, the content of natural pumice as a shape retainer is 5% by volume.
~30% is good. If it is less than 5%, no significant improvement in slag adsorption effect will be observed when it is mixed with a binder and applied to a reticulated woven fabric and used as a filter; if it exceeds 30%, when applied to a reticulated woven fabric, Easy to cause clogging.

保形剤が被着された網状織布は、適宜乾燥されてサイジ
ングされ、製品とされる。
The reticulated woven fabric coated with the shape retaining agent is appropriately dried and sized to produce a product.

次に具体的実施例について説明する。Next, specific examples will be described.

(1)  SiO□含有量が75重量%のガラス繊維に
よって形成された網状織布が、フェノールレジン溶液の
みによって保形された網状フィルター(比較例)と、天
然軽石粉末がフェノールレジン溶液中に添加された保形
剤によって保形された網状フィルター(実施例)を製作
した。尚、実施例における天然軽石粉末の粒径は120
メツシユスルー、添加量は全量に対して15体積%であ
る。
(1) A mesh filter (comparative example) in which a mesh woven fabric made of glass fiber with a SiO□ content of 75% by weight was maintained in shape only by a phenol resin solution, and a mesh filter in which natural pumice powder was added to the phenol resin solution. A reticular filter (Example) whose shape was retained using the above-mentioned shape retention agent was manufactured. In addition, the particle size of the natural pumice powder in the examples is 120
The amount added is 15% by volume based on the total amount.

又、フィルターの目開きサイズはIXl、51■、開口
率は22.5%である。
Further, the opening size of the filter is IXl, 51 cm, and the aperture ratio is 22.5%.

(2)実施例、比較例のフィルターを100 X100
 wmにサイジングした後、1400〜1450℃の鋳
S1容を易表面に30秒間載置した後取出して、フィル
ターのスラグによる目づまり面積を調べた。
(2) Filters of Examples and Comparative Examples 100 x 100
After sizing to wm, a cast S1 volume heated at 1400 to 1450°C was placed on an easy surface for 30 seconds and then taken out, and the area of the filter clogged with slag was examined.

(3)  スラグ除滓効果を下記式で表わして、実施例
と比較例とを計算した結果、次の値が得られた。
(3) The slag removal effect was expressed by the following formula, and as a result of calculations for Examples and Comparative Examples, the following values were obtained.

載直面開口血槓 実施例 ・・・・・・ 40〜70% 比較例 ・・・・・・ 10〜30% (4)  スラグ除滓効果は、フィルターのスラグ吸着
効果の良否を表わしており、高い値はど除滓能力が優れ
ている。(3)の結果より、実施例は従来例に比べて、
スラグ除滓効果が掻めて大きいことが確かめられた。尚
、実施例、比較例とも、フィルターのスラグ化は生じな
かった。
Examples of blood sludge with openings on the mounting surface: 40 to 70% Comparative examples: 10 to 30% (4) The slag removal effect indicates the quality of the slag adsorption effect of the filter. The higher the value, the better the slag removal ability. From the results of (3), compared to the conventional example, the example
It was confirmed that the slag removal effect was significant. Incidentally, in both Examples and Comparative Examples, slagging of the filter did not occur.

(発明の効果) 以上説明した通り、本発明の網状フィルターは所定量の
5in2を含有したガラス繊維によって、網状織布を形
成したものであるから、耐熱性に優れ、鋳鉄や鋳鋼等高
融点金属溶湯中の非金属介在物を濾過除去することがで
きる。
(Effects of the Invention) As explained above, the reticular filter of the present invention has a reticular woven fabric made of glass fibers containing a predetermined amount of 5in2, so it has excellent heat resistance and can be used with high melting point metals such as cast iron and cast steel. Non-metallic inclusions in the molten metal can be filtered out.

また、網状織布は天然軽石粉末が添加された保形剤によ
って保形されているので、除滓能力に極めて優れる。
Furthermore, since the reticulated woven fabric is retained in shape by a shape retaining agent to which natural pumice powder is added, it has extremely excellent sludge removal ability.

Claims (1)

【特許請求の範囲】[Claims] (1)ガラス繊維で形成された網状織布に保形剤が被着
されて保形された網状フィルターにおいて、ガラス繊維
はSiO_2含有量が75重量%以上であり、保形剤は
粘結剤に天然軽石粉末が添加されていることを特徴とす
る除滓能力に優れた網状フィルター。
(1) In a mesh filter whose shape is maintained by adhering a shape preservation agent to a mesh fabric made of glass fibers, the glass fiber has an SiO_2 content of 75% by weight or more, and the shape preservation agent is a binder. A mesh filter with excellent sludge removal ability, characterized by the addition of natural pumice powder.
JP23855486A 1986-10-06 1986-10-06 A mesh filter with excellent slag removal performance Expired - Lifetime JP2514006B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23855486A JP2514006B2 (en) 1986-10-06 1986-10-06 A mesh filter with excellent slag removal performance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23855486A JP2514006B2 (en) 1986-10-06 1986-10-06 A mesh filter with excellent slag removal performance

Publications (2)

Publication Number Publication Date
JPS6393467A true JPS6393467A (en) 1988-04-23
JP2514006B2 JP2514006B2 (en) 1996-07-10

Family

ID=17031966

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23855486A Expired - Lifetime JP2514006B2 (en) 1986-10-06 1986-10-06 A mesh filter with excellent slag removal performance

Country Status (1)

Country Link
JP (1) JP2514006B2 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011045925A (en) * 2009-07-29 2011-03-10 Tokyo Kogyo Boyeki Shokai Ltd Method for manufacturing filtering medium for molten metal, and filtering medium for molten metal
JP2017518616A (en) * 2014-06-12 2017-07-06 ダイムラー・アクチェンゲゼルシャフトDaimler AG Separator for electrochemical storage device, method for manufacturing electrode material, and electrochemical energy storage device
FR3068261A1 (en) * 2017-06-29 2019-01-04 Equipement Industriel Pinet METHOD FOR MANUFACTURING A GEOPOLYMER-BASED FILTER AND GEOPOLYMER-BASED FILTER THUS OBTAINED
CN111533582A (en) * 2020-04-26 2020-08-14 上海伊索热能技术股份有限公司 Preparation method for removing slag of ceramic fiber

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011045925A (en) * 2009-07-29 2011-03-10 Tokyo Kogyo Boyeki Shokai Ltd Method for manufacturing filtering medium for molten metal, and filtering medium for molten metal
JP2013006219A (en) * 2009-07-29 2013-01-10 Tokyo Kogyo Boyeki Shokai Ltd Filter medium for molten metal
JP2017518616A (en) * 2014-06-12 2017-07-06 ダイムラー・アクチェンゲゼルシャフトDaimler AG Separator for electrochemical storage device, method for manufacturing electrode material, and electrochemical energy storage device
US10290846B2 (en) 2014-06-12 2019-05-14 Daimler Ag Separator for an electrochemical storage system, method for the production of an electrode material and electrochemical energy storage system
FR3068261A1 (en) * 2017-06-29 2019-01-04 Equipement Industriel Pinet METHOD FOR MANUFACTURING A GEOPOLYMER-BASED FILTER AND GEOPOLYMER-BASED FILTER THUS OBTAINED
CN111533582A (en) * 2020-04-26 2020-08-14 上海伊索热能技术股份有限公司 Preparation method for removing slag of ceramic fiber

Also Published As

Publication number Publication date
JP2514006B2 (en) 1996-07-10

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