JPS61197406A - Oxygen-generation material - Google Patents
Oxygen-generation materialInfo
- Publication number
- JPS61197406A JPS61197406A JP3401085A JP3401085A JPS61197406A JP S61197406 A JPS61197406 A JP S61197406A JP 3401085 A JP3401085 A JP 3401085A JP 3401085 A JP3401085 A JP 3401085A JP S61197406 A JPS61197406 A JP S61197406A
- Authority
- JP
- Japan
- Prior art keywords
- water
- oxygen
- exchange resin
- anion exchange
- peroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は酸素発生体に関し、とくに魚類水槽に用いるに
適している酸素発生体に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to an oxygen generator, and particularly to an oxygen generator suitable for use in fish tanks.
（従来の技術）
水と反応して酸素を発生する材料を用いて炭坑や軍事的
に緊急に酸素を発生させることが海外において実績とし
て存在する。(Prior Art) There is evidence overseas that oxygen can be generated in coal mines or in the military in emergencies using materials that generate oxygen by reacting with water.
この材料は、過酸化マグネ／ラム等の過酸化物と、クエ
ン酸等の有機酸を主剤とするものである。The main ingredients of this material are peroxides such as magne/rum peroxide and organic acids such as citric acid.
ところでこの材料を魚類水槽中で使用すると、有機酸が
水中にＭ出してしまうという問題点があった。However, when this material is used in a fish tank, there is a problem in that the organic acid releases M into the water.
（発明の目的）
本発明は魚類水槽中でこの材料を使用する場合、有機酸
が水中に溶出してしまうことを防止することを目的とし
たものである。(Object of the Invention) The object of the present invention is to prevent organic acids from leaching into water when this material is used in a fish tank.
（発明の解決しようとする問題点）
上記の目的を達成するために有機酸が水中に溶出しない
ように陰イオン交換樹脂層によってこれを防止するよう
にした。(Problems to be Solved by the Invention) In order to achieve the above object, an anion exchange resin layer is used to prevent organic acids from dissolving into water.
（問題点を解決するだめの手段）
上記の問題点を解決するため過酸化物と有機酸を主剤と
する、水と反応して酸素を発生する材料を陰イオン交換
樹脂を含有する透水性シート材料を少くとも１部に用い
た包装材料で包装して成り、包装材料の透水性を有する
部分が前記シート材料のみであることを要点とした。(Means to Solve the Problem) In order to solve the above problem, a water-permeable sheet containing an anion exchange resin is a material whose main ingredients are peroxide and organic acid, and which reacts with water to generate oxygen. The main point is that the sheet material is packaged with a packaging material in which at least a portion of the packaging material is made of the same material, and that the only part of the packaging material that has water permeability is the sheet material.
水と反応して酸素を発生する材料は過酸化物であって主
として過酸マンガンや過酸化カルシウムを使用する。主
剤としてこれと併用する有機酸としてはアスコルビン酸
、クエン酸、リンゴ酸、酒石酸等である。また触媒とし
て活性炭が使用され、ｐＨ調整剤としてＭｇＯ、Ｍｇ（
Ｓｉｎ３）２を、パイングーとして石膏を用い必要に応
じて吸水性樹脂としてデングンーアクリル酸グラフト重
合体、アクリル酸−ビニルアルコール共重合体やポリア
クリル酸ノーダ等が使用される。The material that reacts with water to generate oxygen is a peroxide, and mainly manganese peroxide and calcium peroxide are used. Organic acids used in conjunction with this as a main ingredient include ascorbic acid, citric acid, malic acid, and tartaric acid. In addition, activated carbon is used as a catalyst, and MgO, Mg(
Sin 3) 2 is used, gypsum is used as the pineapple, and if necessary, a dendritic acid-acrylic acid graft polymer, an acrylic acid-vinyl alcohol copolymer, a polyacrylic acid nodium, etc. are used as the water-absorbing resin.
これらの主剤の包装材料は袋状としても容器状でもよい
。The packaging material for these base ingredients may be in the form of a bag or a container.
陰イオン交換樹脂としてはＤ工Ａ工０Ｎ−ＷＡ ３Ｑ
（三菱化成社製、スチレン系弱塩基性陰イオン交換樹脂
）を使用するのがよい。As anion exchange resin, D Engineering A Engineering 0N-WA 3Q
(manufactured by Mitsubishi Kasei Corporation, styrene-based weakly basic anion exchange resin) is preferably used.
また酸素発生体主剤の包装材料としては不織布が適描で
、例えばＰＰ−パルプ混合の湿式不織布やＰＰ−ＰＥと
セルローズの混合不織布などがよい。A suitable packaging material for the oxygen generating agent is a non-woven fabric, such as a wet-laid non-woven fabric mixed with PP-pulp or a non-woven fabric mixed with PP-PE and cellulose.
（作 用）
酸素発生剤主剤を上記陰イオン交換樹脂を含む不織布で
包装したり、また水不透過性の剛性容器（例工ばプラス
チック容器）中に入れ、蓋の部分に陰イオン交換樹脂層
を有する水透過性の不織布とし、酸素発生体主剤は単な
る不織布で強圧的に包装しであるから水中に入れて不織
布を通して浸透する水と反応して酸素発生主剤は酸素を
発生するが主剤中の有機酸は陰イオン交換樹脂層により
水中に有機酸を放出（溶出）することがなく、魚類に無
害である。(Function) The main oxygen generating agent is packaged with a nonwoven fabric containing the above-mentioned anion exchange resin, or placed in a water-impermeable rigid container (for example, a plastic container), and the lid is covered with an anion exchange resin layer. It is a water-permeable non-woven fabric with a water-permeable non-woven fabric, and the oxygen-generating main ingredient is simply a non-woven fabric that is wrapped under pressure.The oxygen-generating main ingredient reacts with the water that permeates through the non-woven fabric by putting it in water, but the oxygen generating agent generates oxygen. The organic acid is not released (eluted) into water due to the anion exchange resin layer, and is harmless to fish.
（実施例） 本発明の酸素発生体を図示の実施例によって説明する。(Example) The oxygen generating body of the present invention will be explained with reference to illustrated embodiments.
第１図は酸素発生材料Ｂをイオン交換樹脂層を有する不
織布Ａ中に強制包装したものの説明図であり、第２図は
他の実施例の説明図で水不透過性の（例えばプラスチッ
ク製）容器Ｃ中に、酸素発生材料Ｂを単なる不織布Ａ′
に強制包装し、蓋りが陰イオン交換樹脂層を有する不織
布Ａで密封したものである。FIG. 1 is an explanatory diagram of an oxygen generating material B forcibly wrapped in a nonwoven fabric A having an ion-exchange resin layer, and FIG. 2 is an explanatory diagram of another example, which is made of water-impermeable material (for example, made of plastic). Oxygen generating material B is placed in a container C using a simple non-woven fabric A'.
The container was forcibly packaged and the lid was sealed with nonwoven fabric A having an anion exchange resin layer.
陰イオン交換樹脂を含有する不織布シート材料は粉末陰
イオン交換樹脂を不織布上に散布し、他の不織布をその
上に重さね、熱融着することによって得られる。A nonwoven sheet material containing an anion exchange resin is obtained by scattering a powdered anion exchange resin onto a nonwoven fabric, placing another nonwoven fabric thereon, and heat-sealing the nonwoven fabric.
イオン交換樹脂は５〜５０ｆ／Ｍ２程度を使用し、不織
布は２０〜１００ Ｐ／Ｍ２のものを上下枚を合せるよ
うにする。The ion exchange resin used is about 5 to 50 f/M2, and the nonwoven fabric is 20 to 100 P/M2, and the upper and lower sheets are matched.
酸素発生材の組成の１例は下記の通りである。An example of the composition of the oxygen generating material is as follows.
過酸化カルシウム（主剤）１５重量部
クエン酸粉末 （主剤） １５ 〃活
性炭（触媒）１５〃
石膏（固化重量剤）５０〃
ｐＨ調整剤（協和化学社製 ５ 〃キ
ヨーワード １００゜
酸化マグネシウム生体）
上記酸素発生材５０２を上述のイオン交換樹脂含有不織
布に加圧状態で封入し、水中に入れると直ちに酸素の細
かい泡が連続的に発生しその発生量は１００ ｃｃ ／
Ｈで全部で約ＩＬ程度の発生を見た。Calcium peroxide (base ingredient) 15 parts by weight Citric acid powder (base ingredient) 15 〃Activated carbon (catalyst) 15〃 Gypsum (solidification weight agent) 50〃 pH adjuster (manufactured by Kyowa Kagaku Co., Ltd. 5 〃Kyoward 100゜magnesium oxide living body) Above oxygen When the generating material 502 is encapsulated under pressure in the above-mentioned ion-exchange resin-containing nonwoven fabric and placed in water, fine oxygen bubbles are immediately generated continuously and the amount of generation is 100 cc/
A total of about IL was observed in H.
ｐＨの状態は不織布中にイオン交換樹脂を含有させない
もので包装したものでは水のｐＨは５程度に下がるが本
考案の上記のものではｐＨ７が維持された。これは包装
体中での水に浴けた有機酸が不織布中の陰イオン交換樹
脂によって吸着されたためである。Regarding the pH condition, when the nonwoven fabric is packaged without containing an ion exchange resin, the pH of water drops to about 5, but in the above-mentioned product of the present invention, the pH of the water was maintained at 7. This is because the organic acid exposed to water in the package was adsorbed by the anion exchange resin in the nonwoven fabric.
（効 果）
上述のように本発明の酸素発生体を水中に入れても外部
の水中のｐＨに影響がなく、包装体中に余分のスペース
がなく水中に入れても酸素の発生で包装体が浮上するこ
とがなく、酸素の泡は極めて細かく連続発生し、水中に
入れただけで容易に酸素が発生するので取扱いが極めて
簡単で作業工程も少なくコストは低廉である等の利点が
ある。(Effects) As mentioned above, even if the oxygen generator of the present invention is placed in water, there is no effect on the pH of the water outside, and there is no extra space in the package, so even if it is placed in water, oxygen generation causes the package to be damaged. does not float to the surface, extremely fine oxygen bubbles are continuously generated, and oxygen is easily generated just by placing it in water, so it has the advantages of being extremely easy to handle, requiring few work steps, and being inexpensive.
第１図は本発明の酸素発生体の１実施例の説明図、第２
図は同じく他の実施例を示す説明図である。
Ａ・・・・・・陰イオン交換樹脂を含有する不織布Ｂ・
・・・・・酸素発生材
Ｃ・・・・・・グラスチック容器
Ａ′・・・・・・単なる不織布FIG. 1 is an explanatory diagram of one embodiment of the oxygen generating body of the present invention, and FIG.
The figure is an explanatory diagram showing another embodiment as well. A... Nonwoven fabric containing anion exchange resin B.
...Oxygen generating material C...Glassic container A'...Mere non-woven fabric
Claims (1)
生する材料を、陰イオン交換樹脂を含有する透水性シー
ト材料を少くとも１部に使用した包装材料で包装してな
り、包装材料の透水性を有する部分が前記シート材料の
みであることを特徴とする酸素発生体。A material containing a peroxide and an organic acid as main ingredients and which generates oxygen by reacting with water is packaged with a packaging material containing at least a portion of a water-permeable sheet material containing an anion exchange resin, An oxygen generator characterized in that the only part of the packaging material that has water permeability is the sheet material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3401085A JPS61197406A (en) | 1985-02-22 | 1985-02-22 | Oxygen-generation material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3401085A JPS61197406A (en) | 1985-02-22 | 1985-02-22 | Oxygen-generation material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61197406A true JPS61197406A (en) | 1986-09-01 |
| JPH0341402B2 JPH0341402B2 (en) | 1991-06-24 |
Family
ID=12402450
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3401085A Granted JPS61197406A (en) | 1985-02-22 | 1985-02-22 | Oxygen-generation material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61197406A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63156001A (en) * | 1986-08-07 | 1988-06-29 | Meiwa Kouyu Kk | Oxygen generating member |
| JPH01144373U (en) * | 1988-03-28 | 1989-10-04 | ||
| WO1998025456A1 (en) * | 1996-12-13 | 1998-06-18 | Chemoxal S.A. | Use of peracetic acid in fish farming |
| WO2001014259A1 (en) * | 1999-08-19 | 2001-03-01 | Aea Technology Plc | A method and apparatus for reducing pollution from run-off water from highways |
| EP0905086A3 (en) * | 1997-09-26 | 2003-12-03 | Mitsubishi Gas Chemical Company, Inc. | Oxygen generating materials, carbon dioxide absorbing materials, and transport method of live fishery products |
-
1985
- 1985-02-22 JP JP3401085A patent/JPS61197406A/en active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63156001A (en) * | 1986-08-07 | 1988-06-29 | Meiwa Kouyu Kk | Oxygen generating member |
| JPH01144373U (en) * | 1988-03-28 | 1989-10-04 | ||
| WO1998025456A1 (en) * | 1996-12-13 | 1998-06-18 | Chemoxal S.A. | Use of peracetic acid in fish farming |
| EP0905086A3 (en) * | 1997-09-26 | 2003-12-03 | Mitsubishi Gas Chemical Company, Inc. | Oxygen generating materials, carbon dioxide absorbing materials, and transport method of live fishery products |
| WO2001014259A1 (en) * | 1999-08-19 | 2001-03-01 | Aea Technology Plc | A method and apparatus for reducing pollution from run-off water from highways |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0341402B2 (en) | 1991-06-24 |
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