JPS61164267A - Manufacture of thin film transistor - Google Patents

Manufacture of thin film transistor

Info

Publication number
JPS61164267A
JPS61164267A JP608585A JP608585A JPS61164267A JP S61164267 A JPS61164267 A JP S61164267A JP 608585 A JP608585 A JP 608585A JP 608585 A JP608585 A JP 608585A JP S61164267 A JPS61164267 A JP S61164267A
Authority
JP
Japan
Prior art keywords
silicon
film
thin film
film transistor
semiconductor film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP608585A
Other languages
Japanese (ja)
Inventor
Yoshiharu Ichikawa
市川 祥治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Priority to JP608585A priority Critical patent/JPS61164267A/en
Publication of JPS61164267A publication Critical patent/JPS61164267A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/78651Silicon transistors
    • H01L29/7866Non-monocrystalline silicon transistors
    • H01L29/78663Amorphous silicon transistors
    • H01L29/78669Amorphous silicon transistors with inverted-type structure, e.g. with bottom gate

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Ceramic Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)

Abstract

PURPOSE:To make the transistor characteristics even by a method wherein the first and the second N<+> silicon films are electrically isolated by means of a phosphorus silicate glass formed by oxidizing the N<+> silicon films. CONSTITUTION:The first 5 and the second 6 N<+> silicon films are electrically isolated by means of a phosphorus silicate glass 10 formed by oxidizing the N<+> silicon films 5, 6. The interface between the glass 10 and a silicon semiconductor film 4 is subject to almost to interfacial level since the phosphorus silicate glass 10 is formed by oxidizing the N<+> silicon films 5, 6. Besides, the N<+> silicon films only may be selectively oxidized due to extremely lower electric resistance thereof than that of silicon semiconductor film 4. Resultantly, the thickness of silicon semiconductor film 4 may be made even over wide range of space causing almost no dispersion in characteristics of thin film transistor.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、液晶表示装置に用いられる薄膜トランジスタ
の製造方法に関し特に、トランジスタ特性が均一で信頼
性の高い薄膜トランジスタの製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for manufacturing a thin film transistor used in a liquid crystal display device, and particularly to a method for manufacturing a thin film transistor with uniform transistor characteristics and high reliability.

(従来技術とその問題点) 近年、オフィスオートメーションの進展に伴い、マンマ
シンインターフヱイスとしての表示テハイスの画素数の
大容量化が活発に進められている。
(Prior art and its problems) In recent years, with the progress of office automation, efforts have been made to increase the number of pixels in display technologies used as man-machine interfaces.

液晶ティスプレィにおいても液晶をスイッチングするだ
めの薄膜トランジスタの開発が盛んである。
In the field of liquid crystal displays, thin film transistors for switching liquid crystals are being actively developed.

従来の液晶表示用薄膜トランジスタの製造方法の1例と
して特公昭56−135968に示されたものが知られ
ている。第2図に前記従来の製造方法による薄膜トラン
ジスタの断面を示す模式図を示す。
As an example of a conventional method for manufacturing a thin film transistor for liquid crystal display, the method disclosed in Japanese Patent Publication No. 56-135968 is known. FIG. 2 is a schematic diagram showing a cross section of a thin film transistor manufactured by the conventional manufacturing method.

この従来の薄膜トランジスタの製造方法は、絶縁基板1
上にゲート電極2、ゲート絶縁膜3.シリコン半導体膜
4、n1シリコン膜を順次形成し、チャンネルとなるシ
リコン半導体膜4上のn“シリコン膜をフッ酸、硝酸、
酢酸の混合液にょシエッチングして除去し第1のn1シ
リコン膜5と第2のn+シリコン膜6とを電気的に分離
し、第1のn+シリコン膜5にドレイン電極7f:電気
的に接続し、第2のn’/リコン膜6にソース電極8と
液晶表示のだめの透明電極9とを電気的に接続するもの
である。従来の薄膜トランジスタの製造方法ではチャン
ネルとなる半導体膜4上のn1シリコン膜をフッ酸、硝
酸、酢酸の混合液でエツチングするため。
This conventional thin film transistor manufacturing method consists of an insulating substrate 1
A gate electrode 2, a gate insulating film 3. A silicon semiconductor film 4 and an n1 silicon film are sequentially formed, and the n" silicon film on the silicon semiconductor film 4, which will become a channel, is treated with hydrofluoric acid, nitric acid,
The first n1 silicon film 5 and the second n+ silicon film 6 are electrically separated by etching with a mixed solution of acetic acid, and the drain electrode 7f is electrically connected to the first n+ silicon film 5. The source electrode 8 and the transparent electrode 9 of the liquid crystal display are electrically connected to the second n'/recon film 6. In the conventional manufacturing method of thin film transistors, the n1 silicon film on the semiconductor film 4, which becomes the channel, is etched with a mixed solution of hydrofluoric acid, nitric acid, and acetic acid.

nシリコン膜とシリコン半導体膜とのエツチングスピー
ドがほぼ等しくn+シリコン膜のみを選択的にエツチン
グすることができない。したがって液晶ディスプレイに
用いるような大面積の基板を均一にエツチングするのが
困難である。薄膜トランジスタ特性はシリコン半導体膜
の膜厚に対して影響を受けるためTPT特性は不均一と
なシこのため液晶ディスプレイの表示特性は劣化すると
いう欠点があったコまたシリコン半導体上部は、エツチ
ングしたため多数の欠陥が生じ、この欠陥のためTPT
特性の信頼性は低下するという欠点があった。この欠陥
はエツチング後にパッシベーション膜を形成することに
よジ減少できるが、シリコン半導体膜とパッシベーショ
ン膜との界面には多数の界面準位が生じ薄膜トランジス
タの特性はばらつくという欠点があった。
Since the etching speed of the n silicon film and the silicon semiconductor film are almost equal, it is not possible to selectively etch only the n+ silicon film. Therefore, it is difficult to uniformly etch large-area substrates such as those used in liquid crystal displays. Since the thin film transistor characteristics are affected by the thickness of the silicon semiconductor film, the TPT characteristics are not uniform, which has the disadvantage of deteriorating the display characteristics of the liquid crystal display.Also, the upper part of the silicon semiconductor has been etched, resulting in a large number of defects. A defect occurs and due to this defect TPT
There was a drawback that the reliability of the characteristics decreased. Although this defect can be reduced by forming a passivation film after etching, there is a drawback that a large number of interface states are generated at the interface between the silicon semiconductor film and the passivation film, resulting in variations in the characteristics of the thin film transistor.

(発明の目的) 本発明は、このような従来の欠点を除去し、トランジス
タ特性が均一で信頼性の高い薄膜トランジスタの製造方
法を提供することにある。
(Object of the Invention) An object of the present invention is to provide a method for manufacturing a thin film transistor having uniform transistor characteristics and high reliability by eliminating such conventional drawbacks.

(発明の構成) 本発明は、絶縁基板上にゲート電極を形成する工程と、
ゲート絶縁膜を形成する工程と、シリコン半導体膜を形
成する工程と、該シリコン半導体膜上にn+シリコン膜
を形成し、該n1シリコン膜を第1のn+シリコン膜と
第2のn“シリコン膜に電気的に分離する工程と、前記
第1のn”シリコン膜に、(3) ドレイン電極を前記第2のn+シリコン膜にソース電極
をそれぞれ電気的に接続する工程とから少なくともなる
薄膜トランジスタの製造方法において、n゛シリコン膜
酸化させて形成したリンシリケイトガラスを用いて前記
第1および第2のn1シリコン膜を電気的に分離する方
法を用いることを特徴とする薄膜トランジスタの製造方
法である。
(Structure of the Invention) The present invention includes a step of forming a gate electrode on an insulating substrate;
a step of forming a gate insulating film; a step of forming a silicon semiconductor film; forming an n+ silicon film on the silicon semiconductor film; and (3) electrically connecting a drain electrode and a source electrode to the second n+ silicon film, respectively. The method of manufacturing a thin film transistor is characterized in that the first and second n1 silicon films are electrically isolated using phosphosilicate glass formed by oxidizing an n1 silicon film.

さらに前記n1シリコン膜を酸化させてリンシリケイト
ガラスを形成する方法として陽極酸化法を用いるとよい
Further, it is preferable to use an anodic oxidation method as a method for oxidizing the n1 silicon film to form phosphosilicate glass.

(構成の詳細な説明) 本発明は、上述の方法を用いることにより従来技術の問
題点を解決した。本発明の製造方法による薄膜トランジ
スタの断面を示す模式図を第1図に示す口車発明のトラ
ンジスタの製造方法によればn9シリコン膜を酸化させ
てリンシリケイトガラス10を形成するため、シリコン
半導体膜4との界面にはほとんど界面準位が発生しない
。またn+シリコン膜はシリコン半導体膜よりも電気抵
抗が極めて低いため選択的にn+シリコン膜のみを酸化
できる。このためシリコン半導体膜の厚みは大面積にわ
たシ均一となシ薄膜トランジスタの特性のバラツキはほ
とんどない。
(Detailed Description of Configuration) The present invention solves the problems of the prior art by using the above method. A schematic diagram showing a cross section of a thin film transistor according to the manufacturing method of the present invention is shown in FIG. Almost no interface states are generated at the interface with. Furthermore, since the n+ silicon film has an extremely lower electrical resistance than the silicon semiconductor film, only the n+ silicon film can be selectively oxidized. Therefore, the thickness of the silicon semiconductor film is uniform over a large area, and there is almost no variation in the characteristics of the thin film transistor.

(実施例) 以下本発明の実施例について第1図を参照して詳細に説
明する。ガラス基板1上にクロムvioo。
(Example) Hereinafter, an example of the present invention will be described in detail with reference to FIG. Chrome vioo on glass substrate 1.

^蒸着し、フォトレジスト法により所定パターンにエツ
チングしてゲート電極2を形成した後、ゲート絶縁膜3
として窒化シリコンを30001.半導体膜4としてア
モルファスシリコンを3000X%♂シリコン膜として
リンドープアモルファスシリコン5001eプラズマC
VD法により連続形成した。
After forming the gate electrode 2 by vapor depositing and etching into a predetermined pattern using a photoresist method, a gate insulating film 3 is formed.
Silicon nitride as 30001. Amorphous silicon is used as the semiconductor film 4, and phosphorus-doped amorphous silicon 5001e is used as the 3000X%♂♂ silicon film, plasma C.
Continuous formation was performed by the VD method.

ノンドープアモA/7アスシリコンの比抵抗は10麺程
度、リンドープアモルファスシリコンの比抵抗は103
rLcrn程度であった。その後n1シリコン膜。
The specific resistance of non-doped amorphous silicon is about 10, and the specific resistance of phosphorus-doped amorphous silicon is 103.
It was about rLcrn. Then n1 silicon film.

半導体膜4を液晶ディスプレイを透過型とするためおよ
び寄生薄膜トランジスタが生じないように所定パターン
に加工しその上面にクロムe2000^蒸着しバター二
′ングしてドレイン電極7、ソース電極8を形成した後
、I T O1000itl−Arスバッタしパターニ
ングして透明電極9を形成した。
After processing the semiconductor film 4 into a predetermined pattern in order to make the liquid crystal display transparent and to prevent the generation of parasitic thin film transistors, chromium e2000^ is deposited on the upper surface and buttered to form a drain electrode 7 and a source electrode 8. , I TO 1000 itl-Ar sputtering and patterning to form a transparent electrode 9.

その後チャンネルとなるノンドープアモルファスシリコ
ン上のリンドープアモルファスシリコン全陽極酸化し、
第1のn+シリコン膜5と第2のn+シリコン膜6と全
電気的に分離形成した。陽極酸化は、エチレングリコー
ル11!中に硝酸カリウム10gを溶かした溶液中でド
レイン電極に電圧100〜200i−印加し、AMIの
白色光音り/ドープアモルファスシリコンに照射して行
なった。このようにして製造した薄膜トランジスタと従
来の薄膜トランジスタを比較するためチャンネルとなる
ノンドープアモルファスシリコン上のリンドープアモル
ファスシリコン全フッ酸、硝酸、酢酸の混合液を用いて
エツチング除去したものも同様のプロセスで製造した。
After that, the phosphorus-doped amorphous silicon is fully anodized on the non-doped amorphous silicon that will become the channel.
The first n+ silicon film 5 and the second n+ silicon film 6 were formed to be completely electrically separated. Anodic oxidation is ethylene glycol 11! A voltage of 100 to 200 i was applied to the drain electrode in a solution containing 10 g of potassium nitrate, and the white light of the AMI/doped amorphous silicon was irradiated. In order to compare thin film transistors manufactured in this way with conventional thin film transistors, phosphorus-doped amorphous silicon on non-doped amorphous silicon that will serve as a channel was etched away using a mixture of hydrofluoric acid, nitric acid, and acetic acid, and was also manufactured using the same process. did.

トランジスタ特性測定は500×500素子のマトリク
スアレイについて行った。
The transistor characteristics were measured on a matrix array of 500×500 elements.

従来の薄膜トランジスタの特性は、  Ion、  I
offとも±20%程度のばらつきが見られたが、本発
明の薄膜トランジスタでは±2%以内であった。これは
、フッ酸、硝酸、酢酸の混合液を用いてリンドープアモ
ルファスシリコンをエツチングする場合ノンドープ膜と
のエツチング選択比がとれずノンドープ膜もエツチング
されてしまうため、エツチング速度のばらつきがえのま
まトランジスタ特性に影響を与えるためである。一方直
流電圧をゲートおよびドレイン・ソース間にそれぞれ1
5V印加した場合のドレイン・ソース間電流の変化を初
期値’il+oo%ととし90%となる時間を測定した
The characteristics of conventional thin film transistors are Ion, I
Although a variation of about ±20% was observed for both off and off, the variation was within ±2% in the thin film transistor of the present invention. This is because when etching phosphorous-doped amorphous silicon using a mixed solution of hydrofluoric acid, nitric acid, and acetic acid, the etching selectivity with the non-doped film cannot be maintained and the non-doped film is also etched, resulting in variations in the etching rate. This is because it affects transistor characteristics. On the other hand, a DC voltage of 1 is applied between the gate and the drain and source.
The change in the drain-source current when 5V was applied was set to the initial value 'il+oo%, and the time to reach 90% was measured.

従来の薄膜トランジスタでは10時間程度でありたが本
発明の薄膜トランジスタでは1000時間程度と大幅に
信頼性が向上した。これは ’h、y リコンを酸化さ
せてチャンネルとなるアモルファスシリコン上にリンシ
リケイトガラスを形成したため界面準位が大巾に減少し
たためである。
The reliability of the conventional thin film transistor was approximately 10 hours, but the reliability of the thin film transistor of the present invention was significantly improved to approximately 1000 hours. This is because 'h,y silicon is oxidized to form phosphosilicate glass on the amorphous silicon that serves as the channel, and the interface level is greatly reduced.

(発明の効果) 本発明による薄膜トランジスタの製造方法を用いれば薄
膜トランジスタ特性が均一で信頼性の高い薄膜トランジ
スタを製造できる。これはnシリコン膜を酸化させてリ
ンシリケイトガラスを製造するためチャンネル層上の半
導体膜の膜厚が均一となシまた半導体膜とリンシリケイ
トガラスとの界面準位も非常に少なくなるためである。
(Effects of the Invention) By using the method for manufacturing a thin film transistor according to the present invention, a thin film transistor with uniform thin film transistor characteristics and high reliability can be manufactured. This is because phosphosilicate glass is manufactured by oxidizing the n-silicon film, so the thickness of the semiconductor film on the channel layer is not uniform, and the interface states between the semiconductor film and the phosphosilicate glass are also very small. .

以上詳細に述べた通り、本発明による薄膜トランジスタ
の製造方法を用いれば特性が均一で信頼性の高い薄膜ト
ランジスタを提供できる。
As described above in detail, by using the method for manufacturing a thin film transistor according to the present invention, a thin film transistor with uniform characteristics and high reliability can be provided.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の製造方法による薄膜トランジスタの断
面を示す模式図、第2図は従来の製造方法による薄膜ト
ランジスタの断面を示す模式図である。 図において、1・・・絶縁基板、2・・・ゲート電極、
3・・・ゲート絶縁膜、4・・・シリコン半導体膜、訃
・・第1のnシリコン膜、6・・・第2のn/リコン膜
、7・・・ドレイン電極、8・・・ソニス電極、9・・
・透明電極、10・・・nシリコン膜を酸化させて形成
したリンシリケイトガラスをそれぞれ示す。 第1図 第2図
FIG. 1 is a schematic diagram showing a cross section of a thin film transistor manufactured by the manufacturing method of the present invention, and FIG. 2 is a schematic diagram showing a cross section of a thin film transistor manufactured by a conventional manufacturing method. In the figure, 1... insulating substrate, 2... gate electrode,
3... Gate insulating film, 4... Silicon semiconductor film, D... First n silicon film, 6... Second n/recon film, 7... Drain electrode, 8... Sonis Electrode, 9...
・Transparent electrode, phosphosilicate glass formed by oxidizing a 10...n silicon film is shown. Figure 1 Figure 2

Claims (2)

【特許請求の範囲】[Claims] (1)絶縁基板上にゲート電極を形成する工程と、ゲー
ト絶縁膜を形成する工程と、シリコン半導体膜を形成す
る工程と、該シリコン半導体膜上にn^+シリコン膜を
形成し該n^+シリコン膜を第1のn^+シリコン膜と
第2のn^+シリコン膜に電気的に分離する工程と、前
記第1のn^+シリコン膜にドレイン電極を前記第2の
n^+シリコン膜にソース電極をそれぞれ電気的に接続
する工程とから少なくともなる薄膜トランジスタの製造
方法において、n^+シリコン膜を酸化させて形成した
リンシリケイトガラスを用いて前記第1および第2のn
^+シリコン膜を電気的に分離する方法を用いることを
特徴とする薄膜トランジスタの製造方法。
(1) A step of forming a gate electrode on an insulating substrate, a step of forming a gate insulating film, a step of forming a silicon semiconductor film, a step of forming an n^+ silicon film on the silicon semiconductor film, and a step of forming the n^+ silicon film on the silicon semiconductor film. + electrically separating the silicon film into a first n^+ silicon film and a second n^+ silicon film, and connecting a drain electrode to the first n^+ silicon film to the second n^+ silicon film; In the method for manufacturing a thin film transistor, which comprises at least the step of electrically connecting a source electrode to a silicon film, the first and second n
^+ A method for manufacturing a thin film transistor characterized by using a method of electrically isolating a silicon film.
(2)前記n^+シリコン膜を酸化させてリンシリケイ
トガラスを形成する方法として陽極酸化法を用いること
を特徴とする前記第1項記載の薄膜トランジスタの製造
方法。
(2) The method for manufacturing a thin film transistor according to item 1, wherein an anodic oxidation method is used as a method for oxidizing the n^+ silicon film to form phosphosilicate glass.
JP608585A 1985-01-17 1985-01-17 Manufacture of thin film transistor Pending JPS61164267A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP608585A JPS61164267A (en) 1985-01-17 1985-01-17 Manufacture of thin film transistor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP608585A JPS61164267A (en) 1985-01-17 1985-01-17 Manufacture of thin film transistor

Publications (1)

Publication Number Publication Date
JPS61164267A true JPS61164267A (en) 1986-07-24

Family

ID=11628703

Family Applications (1)

Application Number Title Priority Date Filing Date
JP608585A Pending JPS61164267A (en) 1985-01-17 1985-01-17 Manufacture of thin film transistor

Country Status (1)

Country Link
JP (1) JPS61164267A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0361609A2 (en) * 1988-09-30 1990-04-04 Philips Electronics Uk Limited Thin-film transistors, their method of manufacture, and display device using such transistors
JPH0669233A (en) * 1991-12-03 1994-03-11 Samsung Electron Co Ltd Manufacture of semiconductor device
US5334859A (en) * 1991-09-05 1994-08-02 Casio Computer Co., Ltd. Thin-film transistor having source and drain electrodes insulated by an anodically oxidized film
FR2718885A1 (en) * 1994-04-15 1995-10-20 Thomson Lcd Method for manufacturing a reverse stage TFT.

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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JPS57128382A (en) * 1981-02-02 1982-08-09 Canon Kk Electrooptical display device
JPS587873A (en) * 1981-07-07 1983-01-17 Matsushita Electric Ind Co Ltd Diode and manufacture thereof
JPS58112365A (en) * 1981-12-26 1983-07-04 Fujitsu Ltd Manufacture of thin film transistor
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