JPS6082365A - Thermal print head - Google Patents

Thermal print head

Info

Publication number
JPS6082365A
JPS6082365A JP58190136A JP19013683A JPS6082365A JP S6082365 A JPS6082365 A JP S6082365A JP 58190136 A JP58190136 A JP 58190136A JP 19013683 A JP19013683 A JP 19013683A JP S6082365 A JPS6082365 A JP S6082365A
Authority
JP
Japan
Prior art keywords
conductive layer
layer
paste
metal powder
organic vehicle
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP58190136A
Other languages
Japanese (ja)
Other versions
JPS643668B2 (en
Inventor
Hoshun Akechi
明智 方俊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm Co Ltd
Original Assignee
Rohm Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm Co Ltd filed Critical Rohm Co Ltd
Priority to JP58190136A priority Critical patent/JPS6082365A/en
Publication of JPS6082365A publication Critical patent/JPS6082365A/en
Publication of JPS643668B2 publication Critical patent/JPS643668B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N97/00Electric solid-state thin-film or thick-film devices, not otherwise provided for

Landscapes

  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Electronic Switches (AREA)

Abstract

PURPOSE:To obtain a thin conductive layer with limited deformation by printing and sintering a thick film paste comprising respective amounts of a precious metal powder, glass frit and an organic vehicle with a specified amount of a filler added thereto to form a conductive layer for energization of a resistance layer. CONSTITUTION:A thick film paste comprising 37-59wt% of a precious metal powder, 1-3wt% of glass frit and 40-60wt% of an organic vehicle to which 300-800ppm of a filler is added is printed and sintered to form a conductive layer for energization of a resistance layer. The precious metal powder herein used may be in a single or mixed form of gold, silver, platinum, vanadium and the like. The glass frit which may be used is, for example, borosilicate lead glass powder. The organic vehicle comprising a resin and a solvent is effective for improving thixotropic property as paste and such improvement can prevent the deformation during the printing and coating. This can be 2.5-3mum in the thickness and smoothes the printing of another layer on the surface of the conductive layer thereby reducing the radiation of heat.

Description

【発明の詳細な説明】 この発明はサーマルプリントヘッドに関する。[Detailed description of the invention] The present invention relates to a thermal print head.

周知のようにサーマルプリントヘッドは、第1mのよう
にアルミナのよう方セラミック製の基板lの表面に突条
状のグレーズ層2を形成し一基板1からグレーズ層2K
またがって一対の導電層3を股行−グレーズ層2の頂面
Kか込で両溝電層8にまたがって発熱用の抵抗層4を設
けて構成され。
As is well known, in a thermal print head, a protruding glaze layer 2 is formed on the surface of a ceramic substrate l made of alumina as shown in the first m, and a glaze layer 2K is formed from one substrate 1.
A pair of conductive layers 3 are straddled, and a heat generating resistance layer 4 is provided across both groove conductive layers 8 with the top surface K of the glaze layer 2 interposed therebetween.

る。抵抗層4をさ会に形成してかいてカニちその表面V
C導電層8を形成する場合もある。図では表面に設ける
保護層は省略1−である。
Ru. The resistive layer 4 is formed on the surface V of the crab chisel.
A C conductive layer 8 may also be formed. In the figure, the protective layer provided on the surface is omitted by 1-.

ところでこのような構成のサーマルプリントヘッドでは
、導電層8と【−で可及的に薄−こと75に望まれる。
Incidentally, in a thermal print head having such a configuration, it is desired that the conductive layer 8 and the conductive layer 75 be as thin as possible.

導電層8け貴金属粉末を含む厚膜ペーストラスクリーン
印刷L−エツチングによって所要のパターンに形成中る
のが普通である。そのため導電層8が厚−ときは、使用
する厚膜ペーストの量本多く、1−たがって貴金属本多
量にいるととにカリ、製造価格が上がるようになる。又
厚いと六はエツチングに長時1aJを要し、かつi% 
精1M(7) x ツチングが期待で六たくなるし、導
電層の表面に他の層を印刷成形するとき一凹凸による大
女な段差が存在するととに1って印刷精度を損なうこと
もある。
The conductive layer is typically formed into the desired pattern by screen printing and L-etching of a thick film paste containing noble metal powder. Therefore, when the conductive layer 8 is thick, a large amount of thick film paste is used, and therefore, if there is a large amount of noble metal paste, the production cost increases. Also, if it is thick, etching takes a long time of 1aJ, and i%
Precision 1M (7) .

これらにも増して致命的り欠陥#−1ニー導電層3が厚
膜れは厚い程熱伝導廖が太き(なるので、抵抗層4に発
生した熱雀導電層8を経由l−て放#!i、Lやすくな
ってLtうことである。抵抗層4の熱カ!感熱紙に伝導
されてプリントするのであるが、上記のように熱が他の
部分に逃げてしまうと温廣が低下してしまうので、鮮明
にプリントしようとするKFi、発熱量を高めるべ(印
加電圧を上げな叶ればならないようになる。 ′ このように導電層8としては薄すことが望ましbのであ
るが、これが薄すぎると次のよう々問題が生じる。すな
わち第2図の拡大図にも示すようにグレーズ層2の段差
部に導電層8のための導電ペースト5を印刷したときそ
のペーストが流れてパターンの形75!点線で示すよう
にくずれるようなことがある。もj〜ペーストが薄込七
きは、この形(ずれのためにペースト膜が途切れてしま
うことがある。途切れたまま焼結【−で導電層を形成す
れば、導電層と【−で使用に供1−得々bことけ明らか
である。
Even more fatal than these is the defect #-1: The thicker the knee conductive layer 3 is, the thicker the heat conduction gap. #!i, L becomes easier and Lt.Thermal power of the resistor layer 4 is conducted to the thermal paper and prints, but if the heat escapes to other parts as mentioned above, the temperature will increase. Therefore, if you want to print clearly, you will have to increase the amount of heat generated (you will have to increase the applied voltage.' In this way, it is desirable for the conductive layer 8 to be thin. However, if this is too thin, the following problem will occur. Namely, when the conductive paste 5 for the conductive layer 8 is printed on the step part of the glaze layer 2, the paste will It may flow and the pattern shape 75! It may collapse as shown by the dotted line. If the paste is thinned, the pattern may be shaped like this (the paste film may break off due to misalignment. It is clear that if the conductive layer is formed by sintering, it can be used with the conductive layer.

この発明は形くずれの少な−厚膜ペーストによる薄い導
電層を備えたサーマVプリントヘッドを提供するこ失を
目的とする。
SUMMARY OF THE INVENTION It is an object of the present invention to provide a Therma-V printhead with a thin conductive layer made of thick film paste with less deformation.

この発明は貴金属粉末87〜59重量%、ガラスフリッ
ト1〜8重量%及び有機ビークル40〜60重量%から
なる厚膜ペーストにフィラーヲ800〜sooppmf
fi加1−た本のを印刷焼結して、抵抗層通電用の導電
層と1−たと唱を特徴)ニー+る。
In this invention, a thick film paste consisting of 87 to 59% by weight of noble metal powder, 1 to 8% by weight of glass frit, and 40 to 60% by weight of organic vehicle is coated with 800 to soop pm of filler.
By printing and sintering the fi-added book, the resistive layer is characterized by a conductive layer for energizing and a conductive layer for energizing (knee +).

貴金属粉末々1−では、金、銀、白金、バナジウム等が
蛍独又は混合して使用される。ガラスフリットとしてけ
た七えはホウケイ酸鉛ガラス粉末値(使用できる。有機
ビークVけレジン及び溶剤−A、Lナル。レジンとして
はた七えはエチルセルローズ−溶剤としてはターピネオ
ール、ブチルカVビトールアセテート等が使用で^る。
In the noble metal powder 1-, gold, silver, platinum, vanadium, etc. are used alone or in combination. As a glass frit, Nanae is a lead borosilicate glass powder value (can be used.Organic beak V-ke resin and solvent - A, L Naru.As a resin, Nanae is ethyl cellulose -Solvents include terpineol, butylka V-bitol acetate, etc. is in use.

との厚膜ペーストでは有機ビークルを従来のものと比較
1−で数倍に増した点が顕著に相違する。
The difference between the thick film paste and the conventional one is that the number of organic vehicles is increased by several times compared to the conventional one.

有機ビークルはペーストとしてのチクソトロピック性の
改善に有効であり−この改善によって印刷塗布時の形(
ずれを防止することができる。1−た≠;つて薄tn膜
にL−でも問題は生じな−ようになる。
Organic vehicles are effective in improving the thixotropic properties of pastes - this improvement improves the shape during print application (
Misalignment can be prevented. If 1-ta≠; no problem will occur even if L- is applied to a thin tn film.

又焼結時有機ビークルは飛散して1.まり本のであるか
ち、これが多量に含まれてbる程、焼結後に卦すて薄−
導電膜づI形成されるよりに々る。有機ビークルの添加
量が40重量%未満ではチクソトロビツク性の改善には
不十分であるし、60重量%をこえると、貴金属の添加
量が少な(なりすぎて導電性が損なわれるようになって
都合が悪b0フィラーとしてはアルミナ(A/?s+O
a )セラミック、酸化チタン(T1.0+ )等ガ使
用できる。このようなフィラーを添加しておくと一焼結
時基板の表面或すはペースト内のガスがフィラーとペー
ストの境面を通って外部に放散しやすぐなる。本しガス
が放散せずに内部にとぢこめちれたとすると慨泡が発生
1〜、そのため膜にフクレや亀裂を生ずるととガある。
Also, during sintering, the organic vehicle is scattered and causes 1. The more this is contained in a book, the thinner it becomes after sintering.
The more the conductive film is formed, the more it becomes active. If the amount of organic vehicle added is less than 40% by weight, it will not be sufficient to improve the thixotropic properties, and if it exceeds 60% by weight, the amount of precious metal added will be too small (too much, and the conductivity will be impaired). However, as a bad b0 filler, alumina (A/?s+O
a) Ceramics, titanium oxide (T1.0+), etc. can be used. Adding such a filler makes it easier for gas on the surface of the substrate or in the paste to dissipate to the outside through the interface between the filler and the paste during sintering. If the gas does not dissipate and instead collapses inside, bubbles will form, which can cause blisters and cracks in the film.

1−かしフィラーを混在してお叶は膜のフクレ、亀裂の
発生を確実に防止できるようになる。kか添加量がao
oppm未満ではガス抜去のためには不十分であり一又
sooppmをこえると−フィラー自体が絶縁体である
かち一導電層と[−での導電性が損なわかれるようにな
って都合カgtxt、−又エッチング時に邪魔な存在ト
ナッて高精度のエツφングが期待できなりようになる。
1-By mixing the oak filler, it becomes possible to reliably prevent blistering and cracking of the leaf film. k or the amount added is ao
If it is less than soopm, it is insufficient for gas removal, and if it exceeds soopm, the filler itself is an insulator, and the conductivity between the conductive layer and [- is impaired, which may cause problems. In addition, high-precision etching cannot be expected due to the existence of obstacles during etching.

フィラーの粒径は0.1〜0.85μm3を適当である
The particle size of the filler is suitably 0.1 to 0.85 μm3.

貴金属と1.では他の添加物の添加#シの関係かc−5
9〜87重度%でよ−。従来ではこの添加量が80〜9
0重f!−%であるかムー これからして本使用貴金腐
量75工少方(てすみ、それだけ製造価格ゴ低廉とガっ
て都合がより0 次にこの発明の実施例を謄明する。金51電量%に鉛ガ
ラス2重量%を添加し、これを有機ビークル(エチルセ
ルロースとターピネオールとの混合体)47重重景に分
散させて厚膜ペーストを得た。これにアルミナ500p
pmを添加したものをスクリーン印刷して焼結1.た。
Precious metals and 1. So, is it related to the addition of other additives?c-5
The severity is 9-87%. Conventionally, this addition amount was 80 to 9
0 weight f! Is it -%? From now on, the amount of precious metal used in this invention is 75 units less (I'm sorry, but it's convenient that the manufacturing price is that low. Next, I will explain the embodiments of this invention. Gold 51 A thick film paste was obtained by adding 2% by weight of lead glass to the amount of electricity and dispersing it in an organic vehicle (mixture of ethyl cellulose and terpineol) of 47% by weight.To this, 500p of alumina was added.
Screen printing and sintering of pm-added material 1. Ta.

得た導N層のシート抵抗FiggmΩ/口であり、その
厚みを8μ(8回塗り)と1.た。この形成にあたり、
図に示すよう々段差部での形(ずれは皆無であった。又
膜の7クレ、亀裂は何ち生じたかった。々シ導電層の厚
みとしては25μでも形くずれは生じなかった。
The sheet resistance of the obtained conductive N layer is FigmΩ/hole, and its thickness is 8 μ (8 coats) and 1. Ta. In this formation,
As shown in the figure, there was no deviation of the shape at the stepped portion. There were no cracks or cracks in the film. Even when the thickness of the conductive layer was 25 μm, no deformation occurred.

【、たがってこの厚みとしては2.5〜8μであればよ
−ととり里理解で去る。
[Therefore, I understand that the thickness should be 2.5 to 8μ.

ちなみに従来では、金85gt%、鉛ガラス8重量%、
有機ピークfv12重量%によってペーストを得、これ
をスクリーン印刷してかII−,85(1で焼結した。
By the way, conventionally, gold is 85gt%, lead glass is 8wt%,
A paste was obtained with an organic peak fv of 12% by weight, which was screen printed and sintered with II-,85 (1).

得た導電層のシート抵抗は8mΩ/口の程度の圧入をも
って形成する七たけ段差部での形(ずれによっても途切
れは回避で去る。fx卦このように1−で得た導電層で
は180d当りに8〜6個のフクレ及び亀裂の発生力n
」れた。
The sheet resistance of the conductive layer obtained is the shape of the seven-step step formed by press-fitting of about 8 mΩ/hole (discontinuity is avoided even if there is a shift. The force of generating 8 to 6 blisters and cracks n

以上詳述1.たよりIFこの発明によれば、発熱用の抵
抗層への通NK使用する導電層と)−で従来より本充分
薄(すること−h;で六、1.≠1本このように薄に一
でも、導電層の段差部にかはる途切れを皆無と11.1
−かも膜の7タレ、亀裂の発生を防止でき、そして何^
支障な(導N層を薄(Fるこ七がで4゜ア1、M、ワ、
ヵヘ。別。9゜印刷、8、骨となり、かつ抵抗層から導
電層を経由して放散する熱量をも減少させることづ(で
き、本って熱の浪費を防止することがでi、P#明なプ
リン) 、5g可能となるといった効果を奏する。
Detailed explanation above 1. According to this invention, the conductive layer used in the resistance layer for heat generation is thinner than the conventional one (6, 1.≠1). However, there is no discontinuity in the step part of the conductive layer.11.1
-It can prevent the occurrence of sagging and cracking of the seaweed film, and what ^^
Thin conductive N layer (4゜A1, M, Wa,
Kahe. another. 9゜Printing, 8. It is possible to reduce the amount of heat dissipated from the resistive layer via the conductive layer. ), 5g is possible.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はサーマルプリンタヘッドの断面囮、第2図は一
部の拡大断面mである。
FIG. 1 is a cross-sectional decoy of a thermal printer head, and FIG. 2 is a partially enlarged cross-section m.

Claims (1)

【特許請求の範囲】[Claims] 貴金属粉末87〜59重量%、ガラスフリット1〜8重
量%及び有機ビークル40〜60重量%かちなる厚膜ペ
ーストにフィラー800〜800ppmを添加したもの
をもって−厚みが8μ以下の発熱用の抵抗体の通電用の
導電層シして々るサーマルプリントヘッド。
A thick film paste consisting of 87-59% by weight of noble metal powder, 1-8% by weight of glass frit, and 40-60% by weight of organic vehicle, with 800-800 ppm of filler added - for use in heat-generating resistors with a thickness of 8μ or less. A thermal print head with a conductive layer for electricity.
JP58190136A 1983-10-12 1983-10-12 Thermal print head Granted JPS6082365A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58190136A JPS6082365A (en) 1983-10-12 1983-10-12 Thermal print head

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58190136A JPS6082365A (en) 1983-10-12 1983-10-12 Thermal print head

Publications (2)

Publication Number Publication Date
JPS6082365A true JPS6082365A (en) 1985-05-10
JPS643668B2 JPS643668B2 (en) 1989-01-23

Family

ID=16252989

Family Applications (1)

Application Number Title Priority Date Filing Date
JP58190136A Granted JPS6082365A (en) 1983-10-12 1983-10-12 Thermal print head

Country Status (1)

Country Link
JP (1) JPS6082365A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0386559A (en) * 1989-08-30 1991-04-11 Matsushita Electric Ind Co Ltd Thermal head and production thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0386559A (en) * 1989-08-30 1991-04-11 Matsushita Electric Ind Co Ltd Thermal head and production thereof

Also Published As

Publication number Publication date
JPS643668B2 (en) 1989-01-23

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