JPS6080796A - Solidifying treater for radioactive waste liquor - Google Patents

Solidifying treater for radioactive waste liquor

Info

Publication number
JPS6080796A
JPS6080796A JP18770883A JP18770883A JPS6080796A JP S6080796 A JPS6080796 A JP S6080796A JP 18770883 A JP18770883 A JP 18770883A JP 18770883 A JP18770883 A JP 18770883A JP S6080796 A JPS6080796 A JP S6080796A
Authority
JP
Japan
Prior art keywords
cartridge
furnace
car
ridge
waste liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP18770883A
Other languages
Japanese (ja)
Other versions
JPH0249679B2 (en
Inventor
憲明 佐々木
永木 裕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Doryokuro Kakunenryo Kaihatsu Jigyodan
Original Assignee
Doryokuro Kakunenryo Kaihatsu Jigyodan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Doryokuro Kakunenryo Kaihatsu Jigyodan filed Critical Doryokuro Kakunenryo Kaihatsu Jigyodan
Priority to JP18770883A priority Critical patent/JPH0249679B2/en
Publication of JPS6080796A publication Critical patent/JPS6080796A/en
Publication of JPH0249679B2 publication Critical patent/JPH0249679B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Processing Of Solid Wastes (AREA)
  • Treatment Of Sludge (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。
(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.

Description

【発明の詳細な説明】 本発明LJ 、似・中・高しl\ルの)1(棒状又はス
ラリー状の敢対性廃東物を、吸水性の良好なカートリッ
ジにしみ込まけ、それをυ■熱lit IIJIづるこ
とによって放射性物質を固定化づる装ばの改良に関づる
ものであるっ 高しl\ル敢用141虻液(スラリー状液体も含む)の
同化処理法としては、現在、主にガラス固化する方法が
研究間光中である。そのプロ廿スにおいては、廃液或い
はそのi―縮凛は、ガラス原料と共に直接溶融炉内l\
供給されて溶融されるか、或いは前もって乾燥仮焼され
、粉末状にされたのら、ガラス原料と共にFfJ融炉内
炉内給さが溶融したガラス面(10,00〜1100℃
)と接触して激しく沸騰するので、ミストや微粉が多量
に発生づる。これらは水蒸気や空気と共に溶融炉から排
出され、そのときの多量の微粉が排ガス処理装置内に沈
積して閉塞を生けしめたり、放射能が高くなるという問
題が生じている。更に溶融炉へ供給される4くの蒸光に
f吊の熱か奪われ、溶融能ツノが低下するという問題も
生じている。他方後者の方法においては、[]−]クリ
ーキルン法:流動床法スプレー)ノ、等の乾燥仮焼方法
が用いられるが、何れも多量の微粉を生じ、前記と同様
の問題が生じている他、装置も少雑となるという欠点が
あった。
[Detailed description of the invention] LJ of the present invention, 1 (stick-shaped or slurry-like anti-resistance waste material) is soaked into a cartridge with good water absorption, and then υ ■Assimilation treatment methods for liquids (including slurry liquids) currently include: The main method of vitrification is currently being researched. In this process, the waste liquid or its i-condensate is directly injected into the melting furnace together with the glass raw materials.
The molten glass surface (10,00~1100℃
) and boils violently, producing a large amount of mist and fine powder. These are discharged from the melting furnace along with water vapor and air, causing problems such as a large amount of fine powder depositing in the exhaust gas treatment equipment, causing blockages and increasing radioactivity. Furthermore, there is a problem in that the heat is taken away by the steam light supplied to the melting furnace, resulting in a decrease in melting ability. On the other hand, in the latter method, dry calcining methods such as []-]Cree kiln method (fluidized bed method spray) are used, but all of them produce a large amount of fine powder and have the same problems as above. However, the disadvantage was that the equipment was complicated.

また、原子力九電所秀から死生づる中・低レベル放射性
廃液(スラリー状液体も含む)の同化処理方法としては
、現在、アスファルト、ロメント等で固定化する方法が
採用されているが、更に性11ヒの内れた則えばガラス
など高)品で製造される同化体の利用も考えられる。し
かし、これも前記高レベル成用性廃液の同化処理の場合
と同様の問題が生じるので、微粉の発生の少ない方法の
開光か課題となる。
In addition, as a method of assimilating mid- to low-level radioactive waste liquid (including slurry liquid) that is dead or dead from the nuclear power station Hide, currently, methods of fixing it with asphalt, Romento, etc. are used, but even more It is also conceivable to use assimilates made from high-quality materials such as glass. However, this also poses the same problem as the assimilation treatment of high-level synthetic waste liquid, so it is a challenge to find a method that generates less fine powder.

ところ−(゛、カラス溶81;による固化処理の一つの
方法どして、ガラス繊維等からなる吸水性のカートリッ
ジを利用する方法が提案されている(特開昭53175
72弓参照)。ここで開示されている技1・1jは、カ
ートリッジに敢θJ l(t 176液を吸収させ、乾
燥炉においCでれにXマイクロ波を印加+、Cカー1−
リッジ上て乾燥生成物を牛成さU、次に乾燥生成物を有
づるカー1〜リツジを冶口1(炉へ)′Aって溶融させ
て故QJ性げ6棄物を組み入れた溶融カラス物質を生成
させるものである。つまり教則性廃液を同化処理づる1
、、:めには、乾燥炉のほかに溶融炉を別に設()ね+
JKzらず、装置が後陣化し、高lll1lなものとな
るという欠点があった。その上、溶ハ1:炉の前段に設
(づられるマ、イクロ波乾燥炉内においC、カー1ヘリ
ツジの供給方向どは逆の方向にIJI刀スを排出してお
り、そのため乾燥中および乾燥生成物が(=l Wした
カートリッジを溶融する際に発生J8粉塵等によってカ
ー1〜リツジの目詰りが生じ易<、排カスのスムーズな
排出ができなくなるという欠点もあった。
However, as one method of solidification treatment using glass melting, a method using a water-absorbing cartridge made of glass fiber or the like has been proposed (Japanese Patent Application Laid-Open No. 53175).
72 bow). Technique 1.1j disclosed here is to absorb the liquid θJ l (t 176) into the cartridge, apply X microwave to it in the drying oven, and apply the C car 1-
The dried product is transferred onto the ridge, and then the car 1 to the ridge containing the dried product is transferred to the furnace 1 (furnace) and melted to incorporate the waste from the QJ process. It produces a crow substance. In other words, assimilation treatment of educational waste liquid 1
,,: In addition to the drying oven, a separate melting oven should be installed ().
However, the disadvantage was that the equipment was placed in the apse, making it expensive and expensive. In addition, the supply direction of the molten metal 1: installed in the front stage of the furnace, C in the microwave drying furnace, and the car 1 helicopter is discharged in the opposite direction, so that during drying and When the dried product was melted (=lW), the cartridge was easily clogged with J8 dust, etc., and there was also a drawback that the waste residue could not be smoothly discharged.

本発明の目的は、上記のようイ1従来技術の欠点を解消
し、放射性廃液の溶融、焼結等の同化処理において、微
粉の発生(Jよる目詰りを名しく低減化して排カスを容
易にかつスムーズに排出させることができ、処理能力を
向上さけることが出来ると共に同化処理](星及び炉自
体を浩しく簡素化りることか出来るJ、うな装置を11
1供づることにある。
The purpose of the present invention is to eliminate the drawbacks of the prior art as described above, and to facilitate waste removal by reducing the generation of fine powder (nominally caused by J) in the assimilation process such as melting and sintering of radioactive waste liquid. [11] [J, eel device that can greatly simplify the star and the furnace itself]
It's about making an offering.

かかる目的を達成づることの(・さる本発明は、放射性
廃液を吸水性カー1−リッジに吸収させた被処理物を加
熱処理づる炉本体に、カー1〜リツジ供給配管や〕〕−
トリソジ押出装置、げe液供給配管や排ガス管等を(=
I 89.したものであって、排ガス管が前記炉本体の
上部に接続された構成の放射性廃液の固化処理装置であ
る。
In order to achieve such an object, the present invention provides a furnace main body in which a material to be treated in which radioactive waste liquid has been absorbed by a water-absorbing cartridge 1-ridge is heated, and a supply pipe from the car 1 to the ridge is connected to the furnace body.
Trisoji extrusion equipment, e-liquid supply piping, exhaust gas pipe, etc. (=
I 89. This solidification treatment apparatus for radioactive waste liquid is constructed in such a manner that an exhaust gas pipe is connected to the upper part of the furnace main body.

以下、図面に部づさ本発明についC更に51シく説明す
る。第1図は本発明の一実随例を示す説明図である。こ
の装置は、敢qJ性I5°e)1々をガラス原料製の吸
水性カー1〜リツジに吸収させた被処理物を1Jl熱溶
融Jる炉本体1と、該炉本体1の上側部ど連通し略水平
に延U’る被処理物供給路2ど、該被処理物供給路2の
基端側に(、!2置でるカー1〜リツジllt給自己管
3並びにカー1−リッジ押出装置4と、被処理物供給路
2の中間部に接続される廃液供給配色5と、炉水1ホ1
の上部に接続されt、:Jl)ガス管6及びマイク[l
波導波τ(・7とl)r +らなる。カートリッジ供給
装置(図示せ?1′)から送られてくるカー1〜リツジ
8(J、I’ilJえばカラス繊維等のシー1〜状物を
I (−Jけ円t1状とした吸水性の良lfな81.’
■II集合体であり、処理づ゛ぺさ廃液組成と最終ガラ
ス組成とから決められた組成を持つ。このノノートリツ
ジ8は、カー1〜リツジ供給配管3を通って被処理物供
給路2に送られ、カー1−リッジ押出装置4により水平
方向に被処理物供給路2に)ばって)スリ出さt)る。
The present invention will be further explained below with reference to the drawings. FIG. 1 is an explanatory diagram showing an example of the present invention. This equipment consists of a furnace body 1 in which 1Jl of the workpiece is heated and melted, and the upper part of the furnace body A workpiece supply path 2 which communicates and extends substantially horizontally, and a car 1 to ridge llt supply pipe 3 and a car 1 to ridge extrusion which are located on the proximal end side of the workpiece supply path 2 (,!2) are connected and extend substantially horizontally. A device 4, a waste liquid supply color scheme 5 connected to the intermediate part of the material supply path 2, and a reactor water 1 hole 1.
connected to the upper part of the gas pipe 6 and the microphone [l
The waveguide consists of τ(・7 and l)r +. Cartridges 1 to 8 (J, I'ilJ, for example, glass fibers etc. Good LF 81.'
■It is a II aggregate and has a composition determined from the treated waste liquid composition and the final glass composition. This no-no cartridge 8 is sent to the workpiece supply path 2 through the car 1 to the cartridge supply piping 3, and is horizontally pushed out into the workpiece supply path 2 by the car 1-ridge extrusion device 4 and then slipped out. ).

廃液イバ給配管5の真下に到達したカートリッジ8には
、軽液供給系から廃液供給配色5を通って送lうれてく
る教則性廃液く微粒子等を多量に含むスラリー状液体も
含j、れる)がしみ出さない程度にまでしみ込まぜられ
被処理物9となる。(−の後、カー1−リッジ押出装置
1にj、っ゛C炉本体1内に送込まれ、マイクロ波光1
に器(図示せず)からマイク[)波導波琶・7を通−J
て印加されたマイクロ波によっt’ J)■熱溶融さ4
′シることになる。
The cartridge 8 that has reached just below the waste liquid supply pipe 5 also contains a slurry-like liquid containing a large amount of particulates, etc. ) is impregnated to such an extent that it does not seep out, forming the object to be treated 9. (After -, the car 1 is fed into the ridge extrusion device 1,
From the microphone (not shown) to the waveguide 7-J
t' J) ■ Thermal melting due to microwaves applied
'I'm going to have a hard time.

その除重じる1ノ1刀スは、排ガス管6を通−) −j
、 Jjlガス処理系(図示lず)に(l給され、−て
こで処理されることになる。炉本体1内で1−成された
溶融物は、その下部に形成されているカラス抜き出しノ
ズル10を通って)T1本体1の外に取出される。この
様な装置によって、廃液中に含まれる核分裂生成物、ア
クチニド元素或いは重金属元素等の不揮発性成分を固定
化することが出来る。尚、水蒸気や発生カス等の気体は
jIIすものの(紋杓は通さないというカー1〜リツジ
白体の濾過作用を利用しでいるため、炉本体内での扮塵
の光![は極めて少なく、また微粉の飛1Jf(や排ガ
スへの同伴を極めて低く抑えることが出来るし、甲−の
炉水1本内で被処理物4乾燥し、溶n1!づることがで
きるため、敢に(・1性廃HQの処理1稈及び炉自体を
Oi1索化でさ、排カス処理庖(勇め−C容易にするこ
とが出来る。また、本実施例のように廃液をしみ込J′
せだ1灸のカー1−リ・Iシ(被処理物)の加熱にマイ
クロ波を利用づると、カートリッジの内部からカ[」熱
でさ゛るので、溶融に要づる時間が人さく短縮ηきるの
JJな1うづ、装置を極めて単純化りることがCさる。
The 1 no 1 sword to be removed is passed through the exhaust gas pipe 6 -) -j
The molten material formed in the furnace main body 1 is fed to the Jjl gas processing system (not shown) and processed using a lever. 10) and is taken out of the T1 main body 1. With such a device, nonvolatile components such as nuclear fission products, actinide elements, and heavy metal elements contained in the waste liquid can be immobilized. In addition, although gases such as water vapor and generated dregs are absorbed (because the filtration effect of the Kerr 1-Rizji white body is used, which does not pass through the ladle, the amount of light from the dust inside the furnace body is extremely small). In addition, it is possible to keep the amount of fine powder flying (1Jf) and entrainment into the exhaust gas extremely low, and it is possible to dry and melt 44 pieces of material in one bottle of reactor water. Processing of single waste HQ By converting one culm and the furnace itself into an Oi1 cable, it is possible to easily process the waste slag.
When microwaves are used to heat the object to be treated during moxibustion, the heat is released from the inside of the cartridge, so the time required for melting can be significantly shortened. The main point of JJ is that the device can be extremely simplified.

カー1−リッジの(呂j古・・」)去(1、基本l生1
止どしC必要イ1条イ1、!lなわら吸水11ど濾過性
能の(ユかIR扱い[生等を1!1」案して過賞決定づ
れ(、よよい。
Car 1-Ridge's (roj old...') departure (1, basic l life 1
Stop C required A1 Article A1,! The straw has water absorption 11 and filtration performance (Yuka IR treatment [Raw etc. 1!1]) and the award was decided (, Yoyoi.

マ、イクロ波を加熱手段として用いる場合に1よ、JJ
−1〜リツジの供給系からマイクロ波がa洩づることを
防止づる為に、例えば円(1型の場合、その直径は約1
0cm程度以下であることが望ましい。またカー1ヘリ
ツジの組成kl、目的とする固化体の種類にI、i5 
シて適宜選択づればよい。
1. When using microwave as a heating means, JJ
-1 ~ In order to prevent microwaves from leaking from the supply system of the cartridge, for example, a circle (in the case of type 1, the diameter is approximately 1
It is desirable that it be about 0 cm or less. In addition, the composition of Kerr 1 heritage is kl, the type of solidified material is I, i5
You can select it as appropriate.

第2図は本発明の他の実施例を示づものである。この実
施例ではマーイク[1波!Jll熱の他に直接通墨式ジ
1−ル加熱が171用されている。炉本体1の内部下方
に電極1゛1が形成さ4’l、ガラスの溶融を主に直接
通電で11ない、?(り【二1波で補助加熱づるように
した構成である。勿論この場合、マイクロ波を用いない
て甲に溶剛1した刀ラスからの伝熱ヤ輻口」によりカー
トリッジの溶融を行なうことも可11ヒである。尚、で
の他の構成は第1図の場合と同様で1ll)るの(゛刈
1,6づる部分に同一符号を付しそれらについての記載
は省略づる。
FIG. 2 shows another embodiment of the invention. In this example, Mark [1 wave! In addition to Jll heating, direct ink type Jill heating is also used. An electrode 1'1 is formed in the lower part of the inside of the furnace body 1, and the glass is melted mainly by direct current supply. (This is a configuration in which auxiliary heating is performed using 21 waves. Of course, in this case, the cartridge is melted by heat transfer from the sword lath that is heated to the instep without using microwaves.) Note that the other configurations are the same as in the case of FIG.

ところて教則性廃液の)桑凝(1シをしみ込ませたカー
1−リッジを第2図に示した如きカラス溶融装置に投下
して加熱溶Eil+ していく状態を調べた結果、模]
疑油がし1ノ出すこともなく徐々に溶融していくことが
明らかどなった。また、その際微粉の発生が倹め−C少
イ丁いことし確認された。
By the way, as a result of investigating the state in which a cartridge impregnated with mulberry coagulate (educational waste liquid) was dropped into a glass melting device as shown in Fig. 2 and heated to melt Eil+, it was found that
It was obvious that the suspected oil was gradually melting without a single drop coming out. In addition, generation of fine powder was confirmed at this time.

なa5本発明は前記の如きガラス同化処理以外のS合に
し適用・Jることが−Cさる。炉本体内において被処理
1カがプレス用ピストンにJ、って加1干されなから+
Jll熱され1′目J、でれによって微粉が多量に発生
づることな(、に焼払体4牛)戊さけることしで・きる
一 本発明は」−記のよ)に構成した欣QJ性廃油の固(ヒ
処理装置であり、被り処理物を111I熱処理づ−る炉
本体に被処理物ill絡路はじめとしてカー1−リッジ
供給配管ヤ)カー1〜リツジ押出共置入゛)廃:1′2
供給配管等か 体どし−C取付1プられた(71)成−
Cあり、しかも乾燥溶融のための炉が一つで(古・むの
て装置は非゛帛に簡+1−iな溝)告(・)斉み、乾(
ヘリ生成物のf」着しIニカー1−リッジて゛はなく、
げ6(12のしみ込んたカートリッジを炉本体に直接供
給りるどともにJJIカス管か炉水1本上部n直接II
/ jす(]られる偶成て゛あるの(−、]JIカス列
埋がスムースに口つ容易に出来るIJか、全体としく固
化姐理土(qを著しく簡素化することができるどいった
Iu Jlた効果を俟し1qるものである。
The present invention can be applied to S combinations other than glass assimilation treatment as described above. In the furnace main body, one piece to be processed is not applied to the press piston.
The present invention is designed so that a large amount of fine powder will not be generated due to the heat generated by the heat (as described in the following). This is a waste oil processing equipment, in which the treated material is heated to 111I.The treated material is connected to the furnace body, and the car 1 to the ridge supply piping is co-located with the car 1 to the ridge extrusion.) Waste: 1'2
Supply piping, etc. Body-C mounting 1 (71) connected
Moreover, there is one furnace for drying and melting (the old Munote equipment has a very simple +1-i groove).
There is no helical product f'' and I nika 1-ridge.
6 (Feed the soaked cartridge of 12 directly to the reactor main body, and use a JJI waste pipe or 1 reactor water at the top n Direct II
/ Is there a contingency that can be made (-,) IJ that can be smoothly and easily filled with JI debris, or IU that can significantly simplify solidification as a whole? It adds up to 1q of the effect of Jl.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に係る固化事理装置の一実施例を示す説
明図、第2図(j本発明の池の実Il1色例を示す゛説
明図(ある。 1・・・炉本体、2・・・被処理物イj1.治路、3・
・・ツノ−1〜リツジ供給配管、/1・・・カートリッ
ジ押出駅冒、5・・・廃液供給配室、6・・・IJ1カ
ス慎、7・・・マ、イクロ波導波答、8・・・カー1〜
リツジ、9・・・被処理物、10・・・カラス(ム出し
ノス゛ル。 特み(出顆人 動)J炉・(b撚゛(」開発小業団代 
理 人 尾 リit <l:、 1.If同 荒 本 
友4に助 第1図 7 第2図
FIG. 1 is an explanatory diagram showing one embodiment of the solidification device according to the present invention, and FIG.・・・Processing object Ij1.Jirge, 3.
...Tsuno-1 ~ Ritsuji supply piping, /1... Cartridge extrusion station opening, 5... Waste liquid supply distribution room, 6... IJ1 cassette, 7... Ma, Microwave waveguide answer, 8. ...Car 1~
Ritsuji, 9...Product to be processed, 10...Crow (Made-up nozzle.Special feature (Deconduration human motion) J furnace/(b twist) Development small business group
Rito Riit <l:, 1. If same rough book
Tomo 4 Nisuke Figure 1 Figure 7 Figure 2

Claims (1)

【特許請求の範囲】[Claims] 1、欣躬姓廃液を吸水1!4のカー[・リッジに吸収ざ
ぜた被処理物を加熱処理でる炉本体と、該炉本体の上部
ど連通し略水平1こ延びる被処理物(1(給路と、該被
処理物供給路の基端側に位置するカートリッジ供給配管
並びにカートリッジ押出装置と、被処理物供給路の中間
部に接IAさ4゛えるσF)1シ惧u7配管と、炉本体
上部に接続されたIt刀ス管と力口うなることを特i敗
とづる敢用性げe Hシの固化処理装置。
1. A furnace body in which the waste liquid is absorbed into a 1!4 car [ridge] and the treated material is heat-treated, and the treated material (1 ( a supply path, a cartridge supply pipe and a cartridge extrusion device located on the proximal end side of the workpiece supply path, and a pipe connected to an intermediate portion of the workpiece supply path; This is a solidification processing device that uses the pipes connected to the upper part of the furnace body and the force-roaring.
JP18770883A 1983-10-08 1983-10-08 HOSHASEIHAIEKINOKOKASHORISOCHI Expired - Lifetime JPH0249679B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP18770883A JPH0249679B2 (en) 1983-10-08 1983-10-08 HOSHASEIHAIEKINOKOKASHORISOCHI

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP18770883A JPH0249679B2 (en) 1983-10-08 1983-10-08 HOSHASEIHAIEKINOKOKASHORISOCHI

Publications (2)

Publication Number Publication Date
JPS6080796A true JPS6080796A (en) 1985-05-08
JPH0249679B2 JPH0249679B2 (en) 1990-10-30

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Country Link
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4943395A (en) * 1988-03-28 1990-07-24 Doryokuro Kakunenryo Kaihatsu Jigyodan Process of vitrifying radioactive liquid waste with suppressed formation of gaseous ruthenium

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4943395A (en) * 1988-03-28 1990-07-24 Doryokuro Kakunenryo Kaihatsu Jigyodan Process of vitrifying radioactive liquid waste with suppressed formation of gaseous ruthenium

Also Published As

Publication number Publication date
JPH0249679B2 (en) 1990-10-30

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