JPS6078903A - Snake repellent composition and composition for repelling noxious life of tree - Google Patents

Abstract

PURPOSE:To provide the titled composition containing a pyridazine derivative, an aryl-sulfonic acid and a coating base or an adhesive base as essential components, and capable of semi-permanently preventing the troubles caused by the snake ascending the pole attracted by the animal or bird dung attached to the electric wire or transformer, etc. CONSTITUTION:The objective composition is produced by compounding a pyridazine derivative, an arylsulfonic acid, and a coating base or an adhesive base, as essential components, and preferably containing an insecticidal component such as dimethyl phthalate. The pyridazine derivative is the one having particular ill odor or stimulative odor and forming an insoluble salt with the arylsulfonic acid, e.g. 3-chloro-6-phenylthiopyridazine, etc. of formula. The arylsulfonic acid is preferably dodecylbenzenesulfonic acid, etc., and the coating base is preferably a solution obtained by dissolving 40% 2-hydroxyethyl methacrylate resin in a mixture of xylene and butanol.

Description

DETAILED DESCRIPTION OF THE INVENTION A snake repellent composition comprising an acid, a neo-1 base, a viscous base, and a viscous base, and in addition to these components, phthalic acid dimethyl ester is also an essential component. - tree pest repellent, i. Regarding l-acids.

Wires, transformers, clamp force bars
Ly. It is generally not well known that snakes are attracted to the droppings and feathers of animals and can cause short circuits in power distribution lines. However, power distribution line accidents caused by snakes are far more frequent than generally expected, and the cost to repair them is between 1,010 to 11,000 yen per year. To prevent damage to power distribution lines, apply a suitable snake repellent to utility poles (=J method is already known)
(Refer to 4! J Publication No. 55-19578), 3. However, such known methods are effective immediately after applying the snake repellent, but over time, the active ingredients of the repellent leak out or volatilize, and the snake repellent loses its effectiveness in a relatively short period of time. Resulting in. As a result of extensive research to develop a permanent snake repellent without the disadvantage of scorching, the inventors have discovered that certain pyridazine derivatives, ary-sulfonic acids, and paint agents have been developed. The present invention was completed after discovering that a composition containing an adhesive base as an essential ingredient can be used as a semi-permanent lawn snake repellent.

1. The pyridazine derivative used in the present invention may have a distinct malodor and/or an irritating odor, and may form a salt insoluble with the arylsulfonic acid. Representative pyridazine derivatives: 3-chloro-6-::phenylthiopyridazine represented by the following formula (1) and 3-chloro-6-(dimethyl-chloro)phenoxypyridazine represented by formula (II) It is.

The arylsulfonic acid, which is another essential component of the composition according to the present invention, may be any aryl sulfonic acid as long as it reacts with the above-mentioned pyridazine derivative to form an insoluble 11 salt. The paint base or adhesion base which is the third essential component is preferably 2/acid or polystyrene sulfonic acid.
It supports the reaction product of the two components of straw and other components added as desired as described later, and it is convenient to apply and adhere these components directly to utility poles or trees. 6J), therefore, all known 4K-1 bases and adhesive bases can be used.

A particularly preferred paint base is a water-absorbing acrylic resin, for example, a mixture of xylene and butanol (50:50) in a ratio of 40 qb of 2-hydroxyethyl methacrylate resin, commercially available under the trade name DIANAL L. The solution dissolved in is of high practical value. Particularly preferred viscous bases are pine resin, sesame oil, castor oil, beef tallow, boy's oil and ice cream.
ET: Oh. 1 When the above three components are mixed, the pyridazine derivative and the arylsulfonic acid react to form a salt.

This salt retains the different malodor and/or pungent odor of pyridazine derivatives, which are repellent to snakes, and is insoluble in water, so the composition is carried on a suitable cloth or synthetic resin tape. If you wrap it around a telephone pole, it will semi-permanently prevent snakes from approaching the pole ((Avoid: Ruko□,... 3, Care 15. Yu, Eyu, Yo, 4, 1 Wa.

Although the purpose can be fully achieved, the composition according to the present invention may contain various other components having similar repellent and/or other effects. Other ingredients added as desired and 14+, J, 4+7
-k l]I 诹-J/ty 对礒J+r+τoil小子forward 1 Specific examples of such other components that may be added as desired include gel tar aldehyde, thiophenol, mercaptals, such as gel Taraldehyde bis(diphenylmercaptal), 0-7 taraldehyde bis(diphenylmercaptal), etc.
, 3-dipyridyl, sulfur, phthalic acid dimethyl ester, naphthalene, cyclohexanol, thiophenolsulfonic acid, etc. The other components added as desired above are insoluble or sparingly soluble in water, but the present invention ((A salt of a pyridazine derivative and an arylsulfonic acid, which are essential components of such a composition,
Since the mixture of the paint base and the paint base has a remarkable viscosity, the retention of these components is enhanced and their effectiveness is retained with a semi-permanent quality.

Among the other ingredients added as desired, the composition of the present invention contains a substance having an insect repellent effect, such as dimethyl phthalate, which is effective as a snake repellent, but is not harmful to trees. Organisms (e.g., pathogens, pests,
It is also effective for protecting against small animals such as rats. .

Accordingly, the present invention also provides a tree pest repellent composition containing a pyridazine derivative, an arylsulfonic acid, a dimethyl fucuric acid ester, and a paint base or adhesive base as essential components.

All of the various substances constituting the composition according to the present invention are known substances, and are either commercially available or can be easily produced by known methods.

For example, the pyridazine derivative 1 of the formula (Pharmaceutical Journal, 211
59 (1974), the pyridazine derivative of formula (11) is prepared by adding an equivalent amount of 3,6-dichloropyridazine to an aqueous solution of chloro-dimethylphenolate under stirring at VC9 and heating to complete the reaction. In fact, it can be manufactured.

The salts of the pyridazine derivatives represented by the formula (I) or the formula (U) and dodecylbenzenesulfonic acid or polystyrenesulfonic acid are respectively stable compounds having a melting point of 300°C or higher and extremely sparingly soluble in water.

The snake repellent set 1 according to the present invention and the tree pest repellent composition (snake), when the third essential component is a paint base, are placed directly on the base of a telephone pole or hardwood (usually about 50 cm to 50 cm above the ground).
100 (part J) or spray it, or simply apply it in an appropriate manner; wrap a resin tape, such as a polyether or polyester resin tape, around the base and use no. On the other hand, when the third essential component is an adhesive base, it is preferable to use the present invention by wrapping a cloth coated with and impregnated with the base. It is possible to prevent snakes and tree pests from approaching utility poles and trees, causing the above-mentioned wiring problems and causing significant damage to trees.

Examples of the repellent composition according to the present invention are listed below.

Example 1 Ingredients Parts by weight 3-Chloro-6-phenylthio 5 Pyridazine 3-chloro-6-(dimethyl chloride 50) Phenoxypyridazine Dodecylbenzenesulfonic acid 12 Dianal L IL 36 8 The above components were mixed well at room temperature, Snake repellent, get all the benefits.

Example 2 1 part by weight 3-Chloro-6-phenylthiopyridazine 3-chloro-6-(dimeteri.o)7x) 2.225 Polystyrene sulfonic acid aqueous solution (204%) 32 Dial I No L
30 2 The above components are thoroughly mixed at room temperature to obtain a tree pest repellent composition.

Example 3 Ingredients Parts by weight Glucuraldehyde 2 Thiophenol 1 3-chloro-6-phenylthiopyridazine 3-chloro-6-(dimethyl chloride 0) phenoxypyridazine 3.3-dipyridyl 1 Sulfur 18 Dimethyl phthalate 25 Naphthalene 5 Cyclohexanol 2 Dotecylbenzenesulfonic acid 12 Naophenol sulfonic acid 2 Dianal L It 7.0 [48] Mix all of the above ingredients well in a bowl. ? ! ) Radica compositions are effective both as snake repellents and as tree pest repellents.

Example 4 Ingredients - It gel tar aldehyde bis-3 (diphenyl mercaptal) 0-nocuraldehyde bis (diphenyl mercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthi-pyridazine 3.3 -Dipyridyl 1 Sulfur 8 Dimethyl phthalate 15 Naphthalene 5 Cyclohexanol 2 Dodecylbenzenesulfonic acid 12 Dianaru LR80 49 The above components are mixed well at room temperature.The resulting composition is as follows:
It is effective both as a snake repellent and as a tree pest repellent.

Example 5 Ingredients Geltar aldehyde bis- (diphenyl mercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthipyridazine 3-chloro-6-(dimethyl chloride 0) phenoxypyridazine 3,3-dipyridyl 1 Sulfur 8 Phthalic acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Polystyrene sulfonic acid aqueous solution (20.4%) 16 Dodecylbenzenesulfonic acid 6 Dianal L R70 46 Mix 1 scoop of each of the above at room temperature and use the snake repellent Jill. Get what's yours.

Example 6 Glutaraldehyde bis- (diphenylmercaptal) O-phthalaldehyde bissu (diphenylmercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthi pyridazine 3-chloro-6-(dimethylchloride) 0 mouth) Phenoxypyridazine 3.3'-dipyridyl 1 Sulfur 8 Phthalic acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Dodenlebenzenesulfonic acid 12 9 The above components are mixed at room temperature to form Part A.

Castor oil 1,500 Beef tallow 770 Red lead 615 2.885 The above ingredients are mixed at 250'0 to 270°C to prepare a sticky base and use it as agent B.

A repellent composition is obtained by kneading 40 parts of agent A and 60 parts of agent B at 50°C or less.

Example 7 Glutaraldehyde bis- (diphenylmercaptal) P-dichlorobenzene 10 3-chloro-6-phenylthiarypyridazine 3-chloro-6-(dimethylchloride)phenoxypyridazine 3.3-dipyridyl 1 Sulfur 8 Phthal Acid dimethyl ester 15 Naphthalene 5 Cyclohexanol 2 Aqueous solution of boristyrethysulfonic acid (20.4%) 16 Totecylbenzenesulfonic acid 6 6 The above 1 portions were mixed at room temperature to prepare Part A.

A repellent composition is obtained by blending 40 parts of Agent A with 60 parts of Agent B of Example 6 at 50°C or below. .

Test ■ Two steel poles with a height of 2 m and a direct pressure of 0.06 m with a live frog fixed to the top were placed in a sealed chamber into which a snake was placed, and only one of them was covered with a repellent fabric made in Example 6 made of cloth with a thickness of 1.5 mm. Wrap a cloth (width 30C7n) coated with the agent. The frog that was not wrapped in treated fabric disappeared overnight, but the other one
Despite being left alone during the life of the ri frog, no changes were observed.

Test II Height 1 with 10 g of molasses and sugar mixture placed on top
．． Two steel poles with a diameter of 5 m and a diameter of 0.06 fi were erected on the ground where ants live, with an interval of about 5 m or more, and one of them was placed in the example;
The repellent prepared in step 5 is applied (11] 20 C1n, thickness 70 tt). Approximately 2 (
After 147 days, ants began to gather on the top, and within a week they had all disappeared into the sugar, but the sugar on the side where it was applied had not changed at all even after 3 months, and no ants were observed climbing the iron pillar.

Test ■ Insects often nest at the base of cold-region birches, safflower trees, rowan trees, etc., or fruit trees such as plums, mandarin oranges, peaches, pears, and azaleas. When directly applied (10 to 2Qc+++) to the tree, sap secretion and wood chips were no longer observed after a few days. This shows that these trees are protected from the encroaching power of pests.

Claims (1)

[Scope of Claims] 1. A pyridazine derivative, an arylsulfonic acid, and a coating base or a viscous substance. -phenylthiopyridazine and/or 3-chloro-6-(dimethyl-
The composition according to item ff51, wherein the aryl sulfonic acid is dobuflubenzenesulfonic acid or polystyrene sulfonic acid. A substitute for repelling tree pests, which contains a 3-pyridazine derivative, arylsulfonic acid, dimethyl phthalate, and a paint base or adhesive base as essential ingredients. 4-pyridazine-derived f4j is 3-chloro-6-phenylthiopyridazine and/or &-13-chloro-6-/
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3. The composition according to item 3, wherein 6L aryl sulfonic acid is used as dobuflubenzenesulfonic acid or polysteredysulfonic acid as 1.